Technetium-99
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Technetium-99
Technetium-99 (99Tc) is an isotope of technetium which decays with a half-life of 211,000 years to stable ruthenium-99, emitting beta particles, but no gamma rays. It is the most significant long-lived fission product of uranium fission, producing the largest fraction of the total long-lived radiation emissions of nuclear waste. Technetium-99 has a fission product yield of 6.0507% for thermal neutron fission of uranium-235. The metastable technetium-99m (99mTc) is a short-lived (half-life about 6 hours) nuclear isomer used in nuclear medicine, produced from molybdenum-99. It decays by isomeric transition to technetium-99, a desirable characteristic, since the very long half-life and type of decay of technetium-99 imposes little further radiation burden on the body. Radiation The weak beta emission is stopped by the walls of laboratory glassware. Soft X-rays are emitted when the beta particles are stopped, but as long as the body is kept more than 30 cm away these should p ...
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Technetium-99m
Technetium-99m (99mTc) is a metastable nuclear isomer of technetium-99 (itself an isotope of technetium), symbolized as 99mTc, that is used in tens of millions of medical diagnostic procedures annually, making it the most commonly used medical radioisotope in the world. Technetium-99m is used as a radioactive tracer and can be detected in the body by medical equipment (gamma cameras). It is well suited to the role, because it emits readily detectable gamma rays with a photon energy of 140 keV (these 8.8 pm photons are about the same wavelength as emitted by conventional X-ray diagnostic equipment) and its half-life for gamma emission is 6.0058 hours (meaning 93.7% of it decays to 99Tc in 24 hours). The relatively "short" physical half-life of the isotope and its biological half-life of 1 day (in terms of human activity and metabolism) allows for scanning procedures which collect data rapidly but keep total patient radiation exposure low. The same characteristics make the ...
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Technetium
Technetium is a chemical element with the symbol Tc and atomic number 43. It is the lightest element whose isotopes are all radioactive. All available technetium is produced as a synthetic element. Naturally occurring technetium is a spontaneous fission product in uranium ore and thorium ore, the most common source, or the product of neutron capture in molybdenum ores. This silvery gray, crystalline transition metal lies between manganese and rhenium in group 7 of the periodic table, and its chemical properties are intermediate between those of both adjacent elements. The most common naturally occurring isotope is 99Tc, in traces only. Many of technetium's properties had been predicted by Dmitri Mendeleev before it was discovered. Mendeleev noted a gap in his periodic table and gave the undiscovered element the provisional name '' ekamanganese'' (''Em''). In 1937, technetium (specifically the technetium-97 isotope) became the first predominantly artificial element to be produ ...
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Nuclear Medicine
Nuclear medicine or nucleology is a medical specialty involving the application of radioactive substances in the diagnosis and treatment of disease. Nuclear imaging, in a sense, is "radiology done inside out" because it records radiation emitting from within the body rather than radiation that is generated by external sources like X-rays. In addition, nuclear medicine scans differ from radiology, as the emphasis is not on imaging anatomy, but on the function. For such reason, it is called a physiological imaging modality. Single photon emission computed tomography (SPECT) and positron emission tomography (PET) scans are the two most common imaging modalities in nuclear medicine. Diagnostic medical imaging Diagnostic In nuclear medicine imaging, radiopharmaceuticals are taken internally, for example, through inhalation, intravenously or orally. Then, external detectors (gamma cameras) capture and form images from the radiation emitted by the radiopharmaceuticals. This process ...
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Sellafield
Sellafield is a large multi-function nuclear site close to Seascale on the coast of Cumbria, England. As of August 2022, primary activities are nuclear waste processing and storage and nuclear decommissioning. Former activities included nuclear power generation from 1956 to 2003, and nuclear fuel reprocessing from 1952 to 2022. Reprocessing ceased on 17 July 2022, when the Magnox Reprocessing Plant completed its last batch of fuel after 58 years of operation. The licensed site covers an area of , and comprises more than 200 nuclear facilities and more than 1,000 buildings. It is Europe's largest nuclear site and has the most diverse range of nuclear facilities in the world situated on a single site. The site's workforce size varies, and before the COVID-19 pandemic was approximately 10,000 people. The UK's National Nuclear Laboratory has its Central Laboratory and headquarters on the site. Originally built as a Royal Ordnance Factory in 1942, the site briefly passed into the ...
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Long-lived Fission Product
Long-lived fission products (LLFPs) are radioactive materials with a long half-life (more than 200,000 years) produced by nuclear fission of uranium and plutonium. Because of their persistent radiotoxicity it is necessary to isolate them from man and biosphere and to confine them in nuclear waste repositories for geological period of times. Evolution of radioactivity in nuclear waste Nuclear fission produces fission products, as well as actinides from nuclear fuel nuclei that capture neutrons but fail to fission, and activation products from neutron activation of reactor or environmental materials. Short-term The high short-term radioactivity of spent nuclear fuel is primarily from fission products with short half-life. The radioactivity in the fission product mixture is mostly short-lived isotopes such as 131I and 140Ba, after about four months 141Ce, 95Zr/95Nb and 89Sr take the largest share, while after about two or three years the largest share is taken by 144Ce/144Pr, 1 ...
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Nuclear Waste
Radioactive waste is a type of hazardous waste that contains radioactive material. Radioactive waste is a result of many activities, including nuclear medicine, nuclear research, nuclear power generation, rare-earth mining, and nuclear weapons reprocessing. The storage and disposal of radioactive waste is regulated by government agencies in order to protect human health and the environment. Radioactive waste is broadly classified into low-level waste (LLW), such as paper, rags, tools, clothing, which contain small amounts of mostly short-lived radioactivity, intermediate-level waste (ILW), which contains higher amounts of radioactivity and requires some shielding, and high-level waste (HLW), which is highly radioactive and hot due to decay heat, so requires cooling and shielding. In nuclear reprocessing plants about 96% of spent nuclear fuel is recycled back into uranium-based and mixed-oxide (MOX) fuels. The residual 4% is minor actinides and fission products the latter of wh ...
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Trace Radioisotope
A trace radioisotope is a radioisotope that occurs naturally in trace amounts (i.e. extremely small). Generally speaking, trace radioisotopes have half-lives that are short in comparison with the age of the Earth, since primordial nuclides tend to occur in larger than trace amounts. Trace radioisotopes are therefore present only because they are continually produced on Earth by natural processes. Natural processes which produce trace radioisotopes include cosmic ray bombardment of stable nuclides, ordinary alpha and beta decay of the long-lived heavy nuclides, thorium-232, uranium-238, and uranium-235, spontaneous fission of uranium-238, and nuclear transmutation reactions induced by natural radioactivity, such as the production of plutonium-239 and uranium-236 from neutron capture by natural uranium. Elements The elements that occur on Earth only in traces are listed below. Isotopes of other elements (not exhaustive): *Tritium * Beryllium-7 *Beryllium-10 *Carbon-14 *Fluorin ...
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Nuclear Fuel Reprocessing
Nuclear reprocessing is the chemical separation of fission products and actinides from spent nuclear fuel. Originally, reprocessing was used solely to extract plutonium for producing nuclear weapons. With commercialization of nuclear power, the reprocessed plutonium was recycled back into MOX nuclear fuel for thermal reactors. The reprocessed uranium, also known as the spent fuel material, can in principle also be re-used as fuel, but that is only economical when uranium supply is low and prices are high. A breeder reactor is not restricted to using recycled plutonium and uranium. It can employ all the actinides, closing the nuclear fuel cycle and potentially multiplying the energy extracted from natural uranium by about 60 times. Reprocessing must be highly controlled and carefully executed in advanced facilities by highly specialized personnel. Fuel bundles which arrive at the sites from nuclear power plants (after having cooled down for several years) are completely dissolv ...
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Irish Sea
The Irish Sea or , gv, Y Keayn Yernagh, sco, Erse Sie, gd, Muir Èireann , Ulster-Scots: ''Airish Sea'', cy, Môr Iwerddon . is an extensive body of water that separates the islands of Ireland and Great Britain. It is linked to the Celtic Sea in the south by St George's Channel and to the Inner Seas off the West Coast of Scotland in the north by the North Channel. Anglesey, North Wales, is the largest island in the Irish Sea, followed by the Isle of Man. The term ''Manx Sea'' may occasionally be encountered ( cy, Môr Manaw, ga, Muir Meann gv, Mooir Vannin, gd, Muir Mhanainn). On its shoreline are Scotland to the north, England to the east, Wales to the southeast, Northern Ireland and the Republic of Ireland to the west. The Irish Sea is of significant economic importance to regional trade, shipping and transport, as well as fishing and power generation in the form of wind power and nuclear power plants. Annual traffic between Great Britain and Ireland amounts t ...
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Anion
An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by convention. The net charge of an ion is not zero because its total number of electrons is unequal to its total number of protons. A cation is a positively charged ion with fewer electrons than protons while an anion is a negatively charged ion with more electrons than protons. Opposite electric charges are pulled towards one another by electrostatic force, so cations and anions attract each other and readily form ionic compounds. Ions consisting of only a single atom are termed atomic or monatomic ions, while two or more atoms form molecular ions or polyatomic ions. In the case of physical ionization in a fluid (gas or liquid), "ion pairs" are created by spontaneous molecule collisions, where each generated pair consists of a free electron and ...
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High-level Radioactive Waste
High-level waste (HLW) is a type of nuclear waste created by the reprocessing of spent nuclear fuel. It exists in two main forms: * First and second cycle raffinate and other waste streams created by nuclear reprocessing. * Waste formed by vitrification of liquid high-level waste. Liquid high-level waste is typically held temporarily in underground tanks pending vitrification. Most of the high-level waste created by the Manhattan Project and the weapons programs of the cold war exists in this form because funding for further processing was typically not part of the original weapons programs. Both spent nuclear fuel and vitrified waste are considered as suitable forms for long term disposal, after a period of temporary storage in the case of spent nuclear fuel. HLW contains many of the fission products and transuranic elements generated in the reactor core and is the type of nuclear waste with the highest activity. HLW accounts for over 95% of the total radioactivity produce ...
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Iodine-129
Iodine-129 (129I) is a long-lived radioisotope of iodine which occurs naturally, but also is of special interest in the monitoring and effects of man-made nuclear fission products, where it serves as both tracer and potential radiological contaminant. Formation and decay 129I is one of seven long-lived fission products. It is primarily formed from the fission of uranium and plutonium in nuclear reactors. Significant amounts were released into the atmosphere as a result of nuclear weapons testing in the 1950s and 1960s. It is also naturally produced in small quantities, due to the spontaneous fission of natural uranium, by cosmic ray spallation of trace levels of xenon in the atmosphere, and by cosmic ray muons striking tellurium-130. 129I decays with a half-life of 15.7 million years, with low-energy beta and gamma emissions, to stable xenon-129 (129Xe). Fission product 129I is one of the seven long-lived fission products that are produced in significant amounts. Its yield ...
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