Harmon Craig
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Harmon Craig (March 15, 1926 – March 14, 2003) was an American geochemist who worked briefly for the
University of Chicago The University of Chicago (UChicago, Chicago, U of C, or UChi) is a private university, private research university in Chicago, Illinois. Its main campus is located in Chicago's Hyde Park, Chicago, Hyde Park neighborhood. The University of Chic ...
(1951-1955) before spending the majority of his career at Scripps Institution of Oceanography (1955-2003). Craig was involved in numerous research expeditions, which visited the
Great Rift Valley The Great Rift Valley is a series of contiguous geographic trenches, approximately in total length, that runs from Lebanon in Asia to Mozambique in Southeast Africa. While the name continues in some usages, it is rarely used in geology as it ...
of East Africa, the crater of Loihi (now known as Kamaʻehuakanaloa), the
Afar Depression The Afar Triangle (also called the Afar Depression) is a geological depression caused by the Afar Triple Junction, which is part of the Great Rift Valley in East Africa. The region has disclosed fossil specimens of the very earliest hominins; th ...
of
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,
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's ice cores, and
Yellowstone Yellowstone National Park is an American national park located in the western United States, largely in the northwest corner of Wyoming and extending into Montana and Idaho. It was established by the 42nd U.S. Congress with the Yellowston ...
's
geysers A geyser (, ) is a spring characterized by an intermittent discharge of water ejected turbulently and accompanied by steam. As a fairly rare phenomenon, the formation of geysers is due to particular hydrogeological conditions that exist only in ...
, among many others. This led to him being described as "the Indiana Jones of the
earth sciences Earth science or geoscience includes all fields of natural science related to the planet Earth. This is a branch of science dealing with the physical, chemical, and biological complex constitutions and synergistic linkages of Earth's four spheres ...
", someone "whose overriding impulse was to get out and see the world they were studying". Craig made many significant discoveries in
geochemistry Geochemistry is the science that uses the tools and principles of chemistry to explain the mechanisms behind major geological systems such as the Earth's crust and its oceans. The realm of geochemistry extends beyond the Earth, encompassing the ...
. He is credited with establishing the field of carbon
isotope geochemistry Isotope geochemistry is an aspect of geology based upon the study of natural variations in the relative abundances of isotopes of various elements. Variations in isotopic abundance are measured by isotope ratio mass spectrometry, and can reveal ...
by characterizing
carbon Carbon () is a chemical element with the symbol C and atomic number 6. It is nonmetallic and tetravalent—its atom making four electrons available to form covalent chemical bonds. It belongs to group 14 of the periodic table. Carbon mak ...
's stable isotopic signatures in various
natural materials A natural material is any product or physical matter stop changing it. Minerals and the metals that can be extracted from them (without further modification) are also considered to belong into this category. Natural materials are used as building ma ...
. This had immediate applications in radiocarbon dating. By studying stable and radioactive carbon isotopes in the
biosphere The biosphere (from Greek βίος ''bíos'' "life" and σφαῖρα ''sphaira'' "sphere"), also known as the ecosphere (from Greek οἶκος ''oîkos'' "environment" and σφαῖρα), is the worldwide sum of all ecosystems. It can also ...
and air-sea system, he derived the atmospheric
residence time The residence time of a fluid parcel is the total time that the parcel has spent inside a control volume (e.g.: a chemical reactor, a lake, a human body). The residence time of a set of parcels is quantified in terms of the frequency distributi ...
of
carbon dioxide Carbon dioxide ( chemical formula ) is a chemical compound made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in the gas state at room temperature. In the air, carbon dioxide is trans ...
with respect to oceanic uptake. His work laid the foundation for isotopic studies of the
carbon cycle The carbon cycle is the biogeochemical cycle by which carbon is exchanged among the biosphere, pedosphere, geosphere, hydrosphere, and atmosphere of the Earth. Carbon is the main component of biological compounds as well as a major componen ...
, and was fundamental to understanding carbon sequestering in the oceanic and the terrestrial biosphere and the modulation of
global warming In common usage, climate change describes global warming—the ongoing increase in global average temperature—and its effects on Earth's climate system. Climate change in a broader sense also includes previous long-term changes to E ...
. In addition, from 1969 to 1989, Harmon Craig served as an editor for ''
Earth and Planetary Science Letters ''Earth and Planetary Science Letters'' (EPSL) is a bimonthly peer-reviewed scientific journal covering research on physical, chemical and mechanical processes of the Earth and other planets, including extrasolar ones. Topics covered range from ...
''.


Family and early life

Harmon Craig was born in
Manhattan Manhattan (), known regionally as the City, is the most densely populated and geographically smallest of the five boroughs of New York City. The borough is also coextensive with New York County, one of the original counties of the U.S. state ...
, in
New York City New York, often called New York City or NYC, is the most populous city in the United States. With a 2020 population of 8,804,190 distributed over , New York City is also the most densely populated major city in the Un ...
, to John Richard Craig, Jr. (1896-1945) and his wife Virginia (Stanley) Craig. He was named after his uncle, Harmon Bushnell Craig (1895-1917), but does not use his middle name. Harmon Craig's grandparents on his father's side were actors, directors and producers. During
World War I World War I (28 July 1914 11 November 1918), often abbreviated as WWI, was one of the deadliest global conflicts in history. Belligerents included much of Europe, the Russian Empire, the United States, and the Ottoman Empire, with fightin ...
, John Craig (1868-1931) and his wife, actress Mary Young, led the first professional American stock theater company to travel to France and entertain troops at the front. While they entertained the troops, their sons Harmon Bushnell Craig (1895-1917) and John Richard Craig, Jr. (1896-1945) served in the war effort. John Craig, Jr. received a French Croix de Guerre for his efforts as a second lieutenant of artillery, working with French 75s. Harmon Bushnell Craig died serving with an ambulatory corps run by the
American Field Service AFS Intercultural Programs (or AFS, originally the American Field Service) is an international youth exchange organization. It consists of over 50 independent, not-for-profit organizations, each with its own network of volunteers, professional ...
, and was posthumously awarded the French Croix de Guerre. In November 1924, John Craig, Jr. married Virginia Stanley of
Wichita, Kansas Wichita ( ) is the largest city in the U.S. state of Kansas and the county seat of Sedgwick County. As of the 2020 census, the population of the city was 397,532. The Wichita metro area had a population of 647,610 in 2020. It is located in ...
. They had three children: Harmon (named after his uncle), John Richard III (named after his father and grandfather), and Stanley Craig. Harmon Craig's mother, Virginia Stanley, was descended from
Quakers Quakers are people who belong to a historically Protestant Christian set of denominations known formally as the Religious Society of Friends. Members of these movements ("theFriends") are generally united by a belief in each human's abil ...
who helped found schools for freed slaves. His mother's involvement with the Quakers was a strong influence on Harmon Craig.


University of Chicago

Harmon Craig studied geology and chemistry at the
University of Chicago The University of Chicago (UChicago, Chicago, U of C, or UChi) is a private university, private research university in Chicago, Illinois. Its main campus is located in Chicago's Hyde Park, Chicago, Hyde Park neighborhood. The University of Chic ...
. In 1944, he joined the
U.S. Navy The United States Navy (USN) is the maritime service branch of the United States Armed Forces and one of the eight uniformed services of the United States. It is the largest and most powerful navy in the world, with the estimated tonnage o ...
, serving as a communications and radar officer during
World War II World War II or the Second World War, often abbreviated as WWII or WW2, was a world war that lasted from 1939 to 1945. It involved the vast majority of the world's countries—including all of the great powers—forming two opposing ...
. After the war, he continued his education at University of Chicago, working with Nobel Laureate
Harold Urey Harold Clayton Urey ( ; April 29, 1893 – January 5, 1981) was an American physical chemist whose pioneering work on isotopes earned him the Nobel Prize in Chemistry in 1934 for the discovery of deuterium. He played a significant role in th ...
. Craig credits Urey with giving him valuable advice on how to choose scientific problems: "If you go into a project, it's got to be a scientific problem that has rooms that continue into other rooms." Craig earned his Ph.D. in 1951, with ''The geochemistry of the stable carbon isotopes'', a thesis on carbon
isotope geochemistry Isotope geochemistry is an aspect of geology based upon the study of natural variations in the relative abundances of isotopes of various elements. Variations in isotopic abundance are measured by isotope ratio mass spectrometry, and can reveal ...
. Craig created his thesis to find the measurement of ancient sea temperature. Craig used the
carbon dioxide Carbon dioxide ( chemical formula ) is a chemical compound made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in the gas state at room temperature. In the air, carbon dioxide is trans ...
released from calcium carbonate fossils as a basis for future researches involving the carbon system. The masses of carbon dioxide that are produced by 18O and 16O were used to calculate respective masses. Craig's study of the carbon isotope produced corrections that deal with mass fractionation and radiocarbon ages. Craig's thesis work is considered a foundational accomplishment for its studies of 13 C and 12 C in a wide range of natural materials, including everything from ocean water to the atmosphere; volcanic gases; plants, coal, diamonds, and petroleum; sediments, igneous rocks and meteorites. His theory has been applied to applications as varied as determining food chains and the identifying the sources of stone for ancient statues.
Karl Turekian Karl Karekin Turekian (October 25, 1927 – March 15, 2013) was a geochemist and Sterling Professor at Yale University. During his career at Yale, he examined an uncommonly broad range of topics in planetary science — including the sediments of t ...
has stated that "Craig's 35-year-old dissertation is still the measure of all subsequent work in the field." Craig joined the
Enrico Fermi Institute __NOTOC__ The Institute for Nuclear Studies was founded September 1945 as part of the University of Chicago with Samuel King Allison as director. On November 20, 1955, it was renamed The Enrico Fermi Institute for Nuclear Studies. The name was s ...
at the University of Chicago as a research associate in 1951. In 1953, Urey and Craig published results showing that chondrites, meteors from the
Solar System The Solar System Capitalization of the name varies. The International Astronomical Union, the authoritative body regarding astronomical nomenclature, specifies capitalizing the names of all individual astronomical objects but uses mixed "Solar ...
, did not have a single fixed composition, as had been assumed. After carrying out analyses of the chemical composition of hundreds of different meteorites, they reported that chondrites fell into two distinguishable groups, high iron (H) and low iron (L) chondrites. Their work "underscored the value of reliable chemical data" and led to significant improvements in data analysis in the field. It led to a better understanding of the materials and processes involved in forming planets.


Scripps Institution of Oceanography

In 1955 Harmon Craig was recruited to Scripps Institution of Oceanography by
Roger Revelle Roger Randall Dougan Revelle (March 7, 1909 – July 15, 1991) was a scientist and scholar who was instrumental in the formative years of the University of California, San Diego and was among the early scientists to study anthropogenic global ...
. His laboratory at Scripps eventually contained five mass spectrometers, one of them a portable unit. As a professor of geochemistry and oceanography at Scripps, Craig developed new methods in radiocarbon dating and applied radioisotope and isotope distribution to various topics in marine-, geo-, and
cosmochemistry Cosmochemistry (from Greek κόσμος ''kósmos'', "universe" and χημεία ''khemeía'') or chemical cosmology is the study of the chemical composition of matter in the universe and the processes that led to those compositions. This is done ...
. Craig produced fundamental findings about how the deep earth, oceans and atmosphere work. During the 1950s Craig measured variations in the concentrations of hydrogen and oxygen isotopes in natural waters. In 1961, Craig identified the
global meteoric water line The Global Meteoric Water Line (GMWL) describes the global annual average relationship between hydrogen and oxygen isotope (Oxygen-18 and Deuterium) ratios in natural meteoric waters. The GMWL was first developed in 1961 by Harmon Craig, and has su ...
, a
linear relationship In statistics, correlation or dependence is any statistical relationship, whether causal or not, between two random variables or bivariate data. Although in the broadest sense, "correlation" may indicate any type of association, in statistic ...
describing the occurrence of hydrogen and oxygen isotopes in terrestrial waters. Craig also established the oxygen isotope shift in geothermal and volcanic fluids, demonstrating that the water is meteoric. His discovery outlined the relation between rocks and water in geothermal systems. In 1963, Craig received a Guggenheim Fellowship, using it to spend a year at the Istituto de Geologia Nucleare, Pisa, Italy. He described a framework for studying the isotopic composition of the
hydrosphere The hydrosphere () is the combined mass of water found on, under, and above the surface of a planet, minor planet, or natural satellite. Although Earth's hydrosphere has been around for about 4 billion years, it continues to change in shape. This ...
, discussing kinetics, equilibrium, and the use of isotopes for paleoenvironmental reconstructions. The work he presented with Louis I. Gordon on isotopic fractionation of the phase changes in water is known as the Craig-Gordon Model. The model is applied to problems in watershed and ecosystem studies such as the calculation of evaporation. It has been called "a corner stone of isotope geochemistry." During the Nova Expedition of 1967, Craig and colleagues W. Brian Clarke (1937–2002) and M.A. Beg from
McMaster University McMaster University (McMaster or Mac) is a public research university in Hamilton, Ontario, Canada. The main McMaster campus is on of land near the residential neighbourhoods of Ainslie Wood and Westdale, adjacent to the Royal Botanical Ga ...
in
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observed the
Kermadec Trench The Kermadec Trench is a linear ocean trench in the south Pacific Ocean. It stretches about from the Louisville Seamount Chain in the north (26°S) to the Hikurangi Plateau in the south (37°S), north-east of New Zealand's North Island. Toget ...
in the
Pacific Ocean The Pacific Ocean is the largest and deepest of Earth's five oceanic divisions. It extends from the Arctic Ocean in the north to the Southern Ocean (or, depending on definition, to Antarctica) in the south, and is bounded by the contin ...
. They found unexpectedly high proportions of the helium-3 isotope in the ocean waters. Craig concluded that the isotope was present within the earth's mantle and theorized that it was leaking into sea water through cracks in the sea floor. Craig and coworkers studied the isotopic composition of atmospheric and dissolved oxygen in the composition of dissolved gases, where he discovered the
biochemical oxygen demand Biochemical oxygen demand (BOD) is the amount of dissolved oxygen (DO) needed (i.e. demanded) by aerobic biological organisms to break down organic material present in a given water sample at a certain temperature over a specific time period. ...
and the intake in the ocean mixed layer. Craig determined by measuring that the element, 210Pb is rapidly scavenged by sinking particulate matter. In 1970, Craig teamed up with colleagues at Scripps, Columbia University's
Lamont–Doherty Earth Observatory The Lamont–Doherty Earth Observatory (LDEO) is the scientific research center of the Columbia Climate School, and a unit of The Earth Institute at Columbia University. It focuses on climate and earth sciences and is located on a 189-acre (64 ...
and the
Woods Hole Oceanographic Institution The Woods Hole Oceanographic Institution (WHOI, acronym pronounced ) is a private, nonprofit research and higher education facility dedicated to the study of marine science and engineering. Established in 1930 in Woods Hole, Massachusetts, it ...
to direct the
GEOSECS The Geochemical Ocean Sections Study (GEOSECS) was a global survey of the three-dimensional distributions of chemical, isotopic, and radiochemical tracers in the ocean. A key objective was to investigate the deep thermohaline circulation of the o ...
Programme (geochemical ocean sections study) to investigate the chemical and isotopic properties of the world's oceans. GEOSECS produced the most complete set of ocean chemistry data ever collected. In 1971, as part of the Antipode Expedition, Craig and his colleagues gathered hydrographic casts and other data, and discovered a benthic front separating the South Pacific deep and bottom water. During the 1970s Craig examined the relationship of gases such as
radon Radon is a chemical element with the symbol Rn and atomic number 86. It is a radioactive, colourless, odourless, tasteless noble gas. It occurs naturally in minute quantities as an intermediate step in the normal radioactive decay chains through ...
and
helium Helium (from el, ἥλιος, helios, lit=sun) is a chemical element with the symbol He and atomic number 2. It is a colorless, odorless, tasteless, non-toxic, inert, monatomic gas and the first in the noble gas group in the periodic table. ...
to
earthquake prediction Earthquake prediction is a branch of the science of seismology concerned with the specification of the time, location, and magnitude of future earthquakes within stated limits, and particularly "the determination of parameters for the ''next'' ...
, developing a monitoring network at thermal springs and wells near major fault lines in southernmost California. In 1979, he detected an increase in radon and helium as a precursor to an earthquake near Big Bear Lake, California. In a long-term project, Harmon Craig and Valerie Craig (his wife) used carbon and oxygen isotopes to identify the sources of the marble used in ancient Greek sculptures and temples. Craig discovered submarine Hydrothermal vents by measuring helium 3 and radon emitted from seafloor spreading centers. He made 17 dives to the bottom of the ocean in the
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submersible, including the first descent into the
Mariana Trough The Mariana Trough is an active back-arc basin in the western Pacific Ocean . It is an integral part of the Izu–Bonin–Mariana Arc system. Location and Bathymetry The Mariana Trough stretches 1300 km from north to south, about the dista ...
. There he discovered hydrothermal vents nearly 3700m deep. Craig proved that there was excess 3He instead of 4He, affecting the understanding for ocean circulation and seafloor spreading. Craig led 28 oceanographic expeditions and traveled to the
East African Rift Valley The East African Rift (EAR) or East African Rift System (EARS) is an active continental rift zone in East Africa. The EAR began developing around the onset of the Miocene, 22–25 million years ago. In the past it was considered to be part of a ...
, The Dead Sea,
Tibet Tibet (; ''Böd''; ) is a region in East Asia, covering much of the Tibetan Plateau and spanning about . It is the traditional homeland of the Tibetan people. Also resident on the plateau are some other ethnic groups such as Monpa, Taman ...
,
Yunnan Yunnan , () is a landlocked province in the southwest of the People's Republic of China. The province spans approximately and has a population of 48.3 million (as of 2018). The capital of the province is Kunming. The province borders the C ...
(China) and many other places to sample volcanic rocks and gases. He visited all the major volcanic island chains of the
Pacific Ocean The Pacific Ocean is the largest and deepest of Earth's five oceanic divisions. It extends from the Arctic Ocean in the north to the Southern Ocean (or, depending on definition, to Antarctica) in the south, and is bounded by the contin ...
and
Indian Ocean The Indian Ocean is the third-largest of the world's five oceanic divisions, covering or ~19.8% of the water on Earth's surface. It is bounded by Asia to the north, Africa to the west and Australia to the east. To the south it is bounded by t ...
to collect lava samples. He identified 16 mantle
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where volcanic plumes rise from the Earth's outer core through the deep mantle by measuring their helium 3 to helium 4 ratio, identifying the higher helium 3 content present in the hotspots as primordial helium, trapped in the earth's core when it was first formed. Craig was one of the earliest people to analyze the gases trapped in the glacier ice. Craig reported that the
methane Methane ( , ) is a chemical compound with the chemical formula (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The relative abundance of methane on Ea ...
in the atmosphere had increased twice due to human day-to-day activities in the last 300 years.


Awards and honors

Craig was elected to the National Academy of Sciences in 1979. Craig won the VM Goldschmidt Medal of the Geochemical Society in 1979, the National Science Foundation's Special Creativity Award in Oceanography in 1982 and the
Arthur L. Day Prize and Lectureship The Arthur L. Day Prize and Lectureship is awarded by the U.S. National Academy of Sciences "to a scientist making new contributions to the physics of the Earth whose four to six lectures would prove a solid, timely, and useful addition to the kno ...
of the National Academy of Sciences in 1987. He shared the
Vetlesen Prize The Vetlesen Prize is a prize in geology awarded jointly by Columbia University's Lamont–Doherty Earth Observatory and the G. Unger Vetlesen Foundation. The prize is generally regarded as the highest distinction in geologic studies, and the " Nob ...
with Wallace S. Broecker in 1987. In 1998 he was awarded the Balzan Prize for Geochemistry, from the International Balzan Foundation of Milan, Italy. The Foundation commended him as "a pioneer in earth sciences who uses the varied tools of isotope geochemistry to solve problems of fundamental scientific importance and immediate relevance in the atmosphere, hydrosphere and solid earth." It was the first time that the prize had gone to a geochemist. Craig was quoted as saying "The Prize's most significant effect was to establish that Geochemistry, especially Isotope Geochemistry, which began in 1947, had come of age and is a mature science. This was much more important than the specific person chosen for the award." He received an honorary degree from the
University of Paris , image_name = Coat of arms of the University of Paris.svg , image_size = 150px , caption = Coat of Arms , latin_name = Universitas magistrorum et scholarium Parisiensis , motto = ''Hic et ubique terrarum'' (Latin) , mottoeng = Here and a ...
.


Death

Craig died at Thornton Hospital in La Jolla, California on 14 March 2003 from a massive heart attack a day before his seventy-seventh birthday.


References


External links


Oral history interview transcript with Harmon Craig on 29 April 1996, American Institute of Physics, Niels Bohr Library & Archives
* {{DEFAULTSORT:Craig, Harmon 1926 births 2003 deaths American geochemists Members of the United States National Academy of Sciences American climatologists Mass spectrometrists University of Chicago alumni Recipients of the V. M. Goldschmidt Award