Geochemical cycle
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In Earth science, a geochemical cycle is the pathway that chemical elements take in the surface and
crust of the Earth Earth's crust is Earth's thin outer shell of rock, referring to less than 1% of Earth's radius and volume. It is the top component of the lithosphere, a division of Earth's layers that includes the crust and the upper part of the mantle. The ...
. The term " geochemical" tells us that geological and chemical factors are all included. The migration of heated and compressed chemical elements and compounds such as
silicon Silicon is a chemical element with the symbol Si and atomic number 14. It is a hard, brittle crystalline solid with a blue-grey metallic luster, and is a tetravalent metalloid and semiconductor. It is a member of group 14 in the periodic ta ...
,
aluminium Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. I ...
, and general
alkali metals The alkali metals consist of the chemical elements lithium (Li), sodium (Na), potassium (K),The symbols Na and K for sodium and potassium are derived from their Latin names, ''natrium'' and ''kalium''; these are still the origins of the names ...
through the means of subduction and
volcanism Volcanism, vulcanism or volcanicity is the phenomenon of eruption of molten rock (magma) onto the surface of the Earth or a solid-surface planet or moon, where lava, pyroclastics, and volcanic gases erupt through a break in the surface called a ...
is known in the
geological Geology () is a branch of natural science concerned with Earth and other astronomical objects, the features or rocks of which it is composed, and the processes by which they change over time. Modern geology significantly overlaps all other E ...
world as geochemical cycles. The geochemical cycle encompasses the natural separation and concentration of elements and heat-assisted recombination processes. Changes may not be apparent over a short term, such as with
biogeochemical cycles A biogeochemical cycle (or more generally a cycle of matter) is the pathway by which a chemical substance cycles (is turned over or moves through) the biotic and the abiotic compartments of Earth. The biotic compartment is the biosphere and th ...
, but over a long term changes of great magnitude occur, including the evolution of continents and oceans.


Differentiating biogeochemical cycles

Some may use the terms biogeochemical cycle and geochemical cycle interchangeably because both cycles deal with Earth's
reservoirs A reservoir (; from French ''réservoir'' ) is an enlarged lake behind a dam. Such a dam may be either artificial, built to store fresh water or it may be a natural formation. Reservoirs can be created in a number of ways, including control ...
. However, a biogeochemical cycle refers to the chemical interactions in surface reservoirs such as the atmosphere,
hydrosphere The hydrosphere () is the combined mass of water found on, under, and above the surface of a planet, minor planet, or natural satellite. Although Earth's hydrosphere has been around for about 4 billion years, it continues to change in shape. This ...
, lithosphere, and
biosphere The biosphere (from Greek βίος ''bíos'' "life" and σφαῖρα ''sphaira'' "sphere"), also known as the ecosphere (from Greek οἶκος ''oîkos'' "environment" and σφαῖρα), is the worldwide sum of all ecosystems. It can also ...
whereas a geochemical cycle refers to the chemical interactions that exist in crustal and sub crustal reservoirs such as the deep earth and lithosphere.


Earth system

The
Earth Earth is the third planet from the Sun and the only astronomical object known to harbor life. While large volumes of water can be found throughout the Solar System, only Earth sustains liquid surface water. About 71% of Earth's surfa ...
, as a system, is open to radiation from the sun and space, but is practically closed with regard to
matter In classical physics and general chemistry, matter is any substance that has mass and takes up space by having volume. All everyday objects that can be touched are ultimately composed of atoms, which are made up of interacting subatomic part ...
. As all closed systems, it follows the law of
conservation of mass In physics and chemistry, the law of conservation of mass or principle of mass conservation states that for any system closed to all transfers of matter and energy, the mass of the system must remain constant over time, as the system's mass can ...
which states that matter cannot be created nor destroyed, thus, the matter, although transformed and migrated, remains the same as when the
Earth Earth is the third planet from the Sun and the only astronomical object known to harbor life. While large volumes of water can be found throughout the Solar System, only Earth sustains liquid surface water. About 71% of Earth's surfa ...
was formed. The
Earth Earth is the third planet from the Sun and the only astronomical object known to harbor life. While large volumes of water can be found throughout the Solar System, only Earth sustains liquid surface water. About 71% of Earth's surfa ...
system contains seven different
reservoir A reservoir (; from French ''réservoir'' ) is an enlarged lake behind a dam. Such a dam may be either artificial, built to store fresh water or it may be a natural formation. Reservoirs can be created in a number of ways, including contro ...
s that are separated into surface reservoirs, which include atmosphere,
hydrosphere The hydrosphere () is the combined mass of water found on, under, and above the surface of a planet, minor planet, or natural satellite. Although Earth's hydrosphere has been around for about 4 billion years, it continues to change in shape. This ...
,
biosphere The biosphere (from Greek βίος ''bíos'' "life" and σφαῖρα ''sphaira'' "sphere"), also known as the ecosphere (from Greek οἶκος ''oîkos'' "environment" and σφαῖρα), is the worldwide sum of all ecosystems. It can also ...
,
pedosphere The pedosphere (from Greek ''pedon'' "ground" or "earth" and ''sphaira'' "sphere") is the outermost layer of the Earth that is composed of soil and subject to soil formation processes. It exists at the interface of the lithosphere, atmosphere, h ...
, and lithosphere and the isolated reservoirs that include deep Earth and
outer space Outer space, commonly shortened to space, is the expanse that exists beyond Earth and its atmosphere and between celestial bodies. Outer space is not completely empty—it is a near-perfect vacuum containing a low density of particles, pred ...
. Geochemical cycles are concerned with the interactions between deep earth which consists of Earth's mantle and core, and the lithosphere which consists of the Earth's crust.


Pathways

Flux in geochemical cycles is the movement of material between the deep Earth and the surface reservoirs. This occurs through two different processes:
volcanism Volcanism, vulcanism or volcanicity is the phenomenon of eruption of molten rock (magma) onto the surface of the Earth or a solid-surface planet or moon, where lava, pyroclastics, and volcanic gases erupt through a break in the surface called a ...
and subduction of
tectonic plates Plate tectonics (from the la, label=Late Latin, tectonicus, from the grc, τεκτονικός, lit=pertaining to building) is the generally accepted scientific theory that considers the Earth's lithosphere to comprise a number of large ...
. Subduction is the process that takes place at
convergent boundaries A convergent boundary (also known as a destructive boundary) is an area on Earth where two or more lithospheric plates collide. One plate eventually slides beneath the other, a process known as subduction. The subduction zone can be defined by a ...
by which one
tectonic plate Plate tectonics (from the la, label=Late Latin, tectonicus, from the grc, τεκτονικός, lit=pertaining to building) is the generally accepted scientific theory that considers the Earth's lithosphere to comprise a number of large te ...
moves under another tectonic plate and sinks into the mantle as the plates converge. This leads to the sinking of one plate into the mantle which creates a broad range of geochemical transformations or cycling.
Volcanism Volcanism, vulcanism or volcanicity is the phenomenon of eruption of molten rock (magma) onto the surface of the Earth or a solid-surface planet or moon, where lava, pyroclastics, and volcanic gases erupt through a break in the surface called a ...
is the process that takes place at divergent boundaries by which one
tectonic plate Plate tectonics (from the la, label=Late Latin, tectonicus, from the grc, τεκτονικός, lit=pertaining to building) is the generally accepted scientific theory that considers the Earth's lithosphere to comprise a number of large te ...
separates from another creating a
rift In geology, a rift is a linear zone where the lithosphere is being pulled apart and is an example of extensional tectonics. Typical rift features are a central linear downfaulted depression, called a graben, or more commonly a half-grabe ...
in which molten rock (
magma Magma () is the molten or semi-molten natural material from which all igneous rocks are formed. Magma is found beneath the surface of the Earth, and evidence of magmatism has also been discovered on other terrestrial planets and some natural sa ...
) erupts onto the surface of the
Earth Earth is the third planet from the Sun and the only astronomical object known to harbor life. While large volumes of water can be found throughout the Solar System, only Earth sustains liquid surface water. About 71% of Earth's surfa ...
. This molten rock
magma Magma () is the molten or semi-molten natural material from which all igneous rocks are formed. Magma is found beneath the surface of the Earth, and evidence of magmatism has also been discovered on other terrestrial planets and some natural sa ...
then cools and crystallizes, forming igneous rocks. If crystallization occurs at the Earth's surface, extrusive igneous rocks are formed; if crystallization occurs within the Earth's lithosphere, intrusive igneous rocks are formed which can then be brought to Earth's surface by
denudation Denudation is the geological processes in which moving water, ice, wind, and waves erode the Earth's surface, leading to a reduction in elevation and in relief of landforms and landscapes. Although the terms erosion and denudation are used interc ...


Important cycles

Categories and examples of geochemical cycles: File:Diagram of the Water Cycle.jpg, Deep water cycle File:Reservoirs and fluxes of carbon in deep Earth.png, Deep carbon cycle (is part of
carbon cycle The carbon cycle is the biogeochemical cycle by which carbon is exchanged among the biosphere, pedosphere, geosphere, hydrosphere, and atmosphere of the Earth. Carbon is the main component of biological compounds as well as a major componen ...
) File:Iron cycle7.png,
Iron cycle The iron cycle (Fe) is the biogeochemical cycle of iron through the atmosphere, hydrosphere, biosphere and lithosphere. While Fe is highly abundant in the Earth's crust, it is less common in oxygenated surface waters. Iron is a key micronutrient i ...
File:Carbonate-Silicate Cycle (Carbon Cycle focus).jpg,
Carbonate–silicate cycle The carbonate–silicate geochemical cycle, also known as the inorganic carbon cycle, describes the long-term transformation of silicate rocks to carbonate rocks by weathering and sedimentation, and the transformation of carbonate rocks back int ...
File:Phosphorus cycle.png,
Phosphorus cycle The phosphorus cycle is the biogeochemical cycle that describes the movement of phosphorus through the lithosphere, hydrosphere, and biosphere. Unlike many other biogeochemical cycles, the atmosphere does not play a significant role in the moveme ...
File:Sulfur cycle - English.jpg, Sulfur cycle File:Rockcycle.jpg,
Rock cycle The rock cycle is a basic concept in geology that describes transitions through geologic time among the three main rock types: sedimentary, metamorphic, and igneous. Each rock type is altered when it is forced out of its equilibrium conditi ...
File:PhysicalMercuryCycle.png, Mercury cycle


See also

* Geotraces * Ozone–oxygen cycle


References

{{reflist Geochemistry