Mercury Cycle
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Mercury Cycle
The mercury cycle is a biogeochemical cycle influenced by natural and anthropogenic processes that transform mercury through multiple chemical forms and environments. Mercury is present in the Earth's crust and in various forms on the Earth’s surface. It can be elemental, inorganic, or organic. Mercury exists in three oxidation states: 0 (elemental mercury), I (mercurous mercury), and II (mercuric mercury). Mercury emissions to the atmosphere can be primary sources, which release mercury from the lithosphere, or secondary sources, which exchange mercury between surface reservoirs. Annually, over 5000 metric tons of mercury is released to the atmosphere by primary emissions and secondary re-emissions. Sources of mercury Primary sources Primary sources of mercury emissions can be natural or anthropogenic. Most natural mercury occurs as the mercury sulfide mineral, cinnabar, which is one of the only significant ores of mercury. Organic-rich sedimentary rocks can also c ...
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Wet Deposition
In the physics of aerosols, deposition is the process by which aerosol particles collect or deposit themselves on solid surfaces, decreasing the concentration of the particles in the air. It can be divided into two sub-processes: ''dry'' and ''wet'' deposition. The rate of deposition, or the deposition velocity, is slowest for particles of an intermediate size. Mechanisms for deposition are most effective for either very small or very large particles. Very large particles will settle out quickly through sedimentation (settling) or impaction processes, while Brownian diffusion has the greatest influence on small particles. This is because very small particles coagulate in few hours until they achieve a diameter of 0.5 micrometres. At this size they no longer coagulate. This has a great influence in the amount of PM-2.5 present in the air. ''Deposition velocity'' is defined from , where is flux density, is deposition velocity and is concentration. In gravitational deposit ...
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COLEX Process (isotopic Separation)
The COLEX process (or COLEX separation) is a chemical method of isotopic separation of lithium-6 and lithium-7, based on the use of mercury. COLEX stands for column exchange. Since the beginning of the atomic era, a variety of lithium enrichments methods have been developed (such as chemical exchange, electromagnetic, laser, centrifugal) and the COLEX process has been the most extensively implemented method so far. Early development In the US, several chemical exchange methods for lithium isotope separation have been under investigation in the 1930s and 1940s to develop a process for lithium-6 production, so that tritium could be obtained for thermonuclear weapons research. The system finally selected was the COLEX process, with aqueous lithium hydroxide (LiOH) contacted with lithium-mercury amalgam. This process was initially used in the US between 1955 and 1963 in the Y12 plant in Oak Ridge, Tennessee. The COLEX plants in Oak Ridge had a very rough start in 1955 with major prob ...
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Mercury Poisoning
Mercury poisoning is a type of metal poisoning due to exposure to mercury. Symptoms depend upon the type, dose, method, and duration of exposure. They may include muscle weakness, poor coordination, numbness in the hands and feet, skin rashes, anxiety, memory problems, trouble speaking, trouble hearing, or trouble seeing. High-level exposure to methylmercury is known as Minamata disease. Methylmercury exposure in children may result in acrodynia (pink disease) in which the skin becomes pink and peels. Long-term complications may include kidney problems and decreased intelligence. The effects of long-term low-dose exposure to methylmercury are unclear. Forms of mercury exposure include metal, vapor, salt, and organic compound. Most exposure is from eating fish, amalgam-based dental fillings, or exposure at a workplace. In fish, those higher up in the food chain generally have higher levels of mercury, a process known as biomagnification. Less commonly, poisoning may occur a ...
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Minamata Convention On Mercury
The Minamata Convention on Mercury is an international treaty designed to protect human health and the environment from anthropogenic emissions and releases of mercury and mercury compounds. The convention was a result of three years of meeting and negotiating, after which the text of the convention was approved by delegates representing close to 140 countries on 19 January 2013 in Geneva and adopted and signed later that year on 10 October 2013 at a diplomatic conference held in Kumamoto, Japan. The convention is named after the Japanese city Minamata. This naming is of symbolic importance as the city went through a devastating incident of mercury poisoning. It is expected that over the next few decades, this international agreement will enhance the reduction of mercury pollution from the targeted activities responsible for the major release of mercury to the immediate environment. The objective of the Minamata Convention is to protect the human health and the environment f ...
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Mercury In Fish
The presence of mercury in fish is a health concern for people who eat them, especially for women who are or may become pregnant, nursing mothers, and young children. Fish and shellfish concentrate mercury in their bodies, often in the form of methylmercury, a highly toxic organomercury compound. This element is known to bioaccumulate in humans, so bioaccumulation in seafood carries over into human populations, where it can result in mercury poisoning. Mercury is dangerous to both natural ecosystems and humans because it is a metal known to be highly toxic, especially due to its neurotoxic ability to damage the central nervous system. In human-controlled ecosystems of fish, usually done for market production of wanted seafood species, mercury clearly rises through the food chain via fish consuming small plankton, as well as through non-food sources such as underwater sediment. Fish products have been shown to contain varying amounts of heavy metals, particularly mercury and fat- ...
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Xenophyophorea
Xenophyophorea is a clade of foraminiferans. Members of this class are multinucleate unicellular organisms found on the ocean floor throughout the world's oceans, at depths of . They are a kind of foraminiferan that extract minerals from their surroundings and use them to form an exoskeleton known as a test. They were first described by Henry Bowman Brady in 1883. They are abundant on abyssal plains, and in some regions are the dominant species. Fifteen genera and 75 species have been described, varying widely in size. The largest, ''Syringammina fragilissima'', is among the largest known coenocytes, reaching up to in diameter. Naming and classification The name Xenophyophora means "bearer of foreign bodies", from the Greek. This refers to the sediments, called xenophyae, which are cemented together to construct their tests. In 1883, Henry Bowman Brady classified them as primitive Foraminifera. Later they were placed within the sponges. In the beginning of the 20th ce ...
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Biomagnification
Biomagnification, also known as bioamplification or biological magnification, is any concentration of a toxin, such as pesticides, in the tissues of tolerant organisms at successively higher levels in a food chain. This increase can occur as a result of: * Persistence – where the substance cannot be broken down by environmental processes * Food chain energetics – where the substance's concentration increases progressively as it moves up a food chain * Low or non-existent rate of internal degradation or excretion of the substance – mainly due to water-insolubility Biological magnification often refers to the process whereby certain substances such as pesticides or heavy metals work their way into lakes, rivers and the ocean, and then move up the food chain in progressively greater concentrations as they are incorporated into the diet of aquatic organisms such as zooplankton, which in turn are eaten perhaps by fish, which then may be eaten by bigger fish, large birds, ani ...
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Swordfish
Swordfish (''Xiphias gladius''), also known as broadbills in some countries, are large, highly migratory predatory fish characterized by a long, flat, pointed bill. They are a popular sport fish of the billfish category, though elusive. Swordfish are elongated, round-bodied, and lose all teeth and scales by adulthood. These fish are found widely in tropical and temperate parts of the Atlantic, Pacific, and Indian Oceans, and can typically be found from near the surface to a depth of , and exceptionally up to depths of 2,234 m. They commonly reach in length, and the maximum reported is in length and in weight.Gardieff, S. Swordfish.' Florida Museum of Natural History. Accessed 26 December 2011 They are the sole member of their family, Xiphiidae. Taxonomy and etymology The swordfish is named after its long pointed, flat bill, which resembles a sword. The species name, ''Xiphias gladius'', derives from Greek (''xiphias'', "swordfish"), itself from (''xiphos'', "sword") and ...
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Tuna
A tuna is a saltwater fish that belongs to the tribe Thunnini, a subgrouping of the Scombridae (mackerel) family. The Thunnini comprise 15 species across five genera, the sizes of which vary greatly, ranging from the bullet tuna (max length: , weight: ) up to the Atlantic bluefin tuna (max length: , weight: ), which averages and is believed to live up to 50 years. Tuna, opah and mackerel sharks are the only species of fish that can maintain a body temperature higher than that of the surrounding water. An active and agile predator, the tuna has a sleek, streamlined body, and is among the fastest-swimming pelagic fish – the yellowfin tuna, for example, is capable of speeds of up to . Greatly inflated speeds can be found in early scientific reports and are still widely reported in the popular literature. Found in warm seas, the tuna is commercially fished extensively as a food fish, and is popular as a bluewater game fish. As a result of overfishing, some tuna species, s ...
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Bioaccumulate
Bioaccumulation is the gradual accumulation of substances, such as pesticides or other chemicals, in an organism. Bioaccumulation occurs when an organism absorbs a substance at a rate faster than that at which the substance is lost or eliminated by catabolism and excretion. Thus, the longer the biological half-life of a toxic substance, the greater the risk of chronic poisoning, even if environmental levels of the toxin are not very high. Bioaccumulation, for example in fish, can be predicted by models. Hypothesis for molecular size cutoff criteria for use as bioaccumulation potential indicators are not supported by data. Biotransformation can strongly modify bioaccumulation of chemicals in an organism. Toxicity induced by metals is associated with bioaccumulation and biomagnification. Storage or uptake of metals faster than the rate at which an organism metabolizes and excretes lead to the accumulation of that metal. The presence of various chemicals and harmful substances in ...
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Methyl Group
In organic chemistry, a methyl group is an alkyl derived from methane, containing one carbon atom bonded to three hydrogen atoms, having chemical formula . In formulas, the group is often abbreviated as Me. This hydrocarbon group occurs in many organic compounds. It is a very stable group in most molecules. While the methyl group is usually part of a larger molecule, bounded to the rest of the molecule by a single covalent bond (), it can be found on its own in any of three forms: methanide anion (), methylium cation () or methyl radical (). The anion has eight valence electrons, the radical seven and the cation six. All three forms are highly reactive and rarely observed. Methyl cation, anion, and radical Methyl cation The methylium cation () exists in the gas phase, but is otherwise not encountered. Some compounds are considered to be sources of the cation, and this simplification is used pervasively in organic chemistry. For example, protonation of methanol gives an elect ...
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