Fire clay is a range of

refractory In materials science, a refractory material or refractory is a material that is resistant to decomposition by heat, pressure, or chemical attack, and retains strength and form at high temperatures. Refractories are polycrystalline, polyphase ...

clay Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2 Si2 O5( OH)4). Clays develop plasticity when wet, due to a molecular film of water surrounding the clay part ...

s used in the manufacture of

ceramic A ceramic is any of the various hard, brittle, heat-resistant and corrosion-resistant materials made by shaping and then firing an inorganic, nonmetallic material, such as clay, at a high temperature. Common examples are earthenware, porcelai ...

s, especially

fire brick A fire brick, firebrick, or refractory is a block of ceramic material used in lining furnaces, kilns, fireboxes, and fireplaces. A refractory brick is built primarily to withstand high temperature, but will also usually have a low thermal co ...

. The

United States Environmental Protection Agency The Environmental Protection Agency (EPA) is an independent executive agency of the United States federal government tasked with environmental protection matters. President Richard Nixon proposed the establishment of EPA on July 9, 1970; it ...

defines fire clay very generally as a "mineral aggregate composed of hydrous silicates of aluminium (Al₂O₃·2SiO₂·2H₂O) with or without free silica."

Properties

High-grade fire clays can withstand temperatures of 1,775 °C (3,227 °F), but to be referred to as a "fire clay" the material must withstand a minimum temperature of .Minerals Zone, World Mineral Exchange.
Retrieved 2011-6-23. Fire clays range from '' flint clays'' to ''plastic fire clays'', but there are ''semi-flint'' and ''semi-plastic'' fire clays as well. Fire clays consist of natural

argillaceous Clay minerals are hydrous aluminium phyllosilicates (e.g. kaolin, Al2 Si2 O5( OH)4), sometimes with variable amounts of iron, magnesium, alkali metals, alkaline earths, and other cations found on or near some planetary surfaces. Clay mineral ...

materials, mostly

Kaolinite Kaolinite ( ) is a clay mineral, with the chemical composition Al2 Si2 O5( OH)4. It is an important industrial mineral. It is a layered silicate mineral, with one tetrahedral sheet of silica () linked through oxygen atoms to one octahed ...

group clays, along with fine-grained micas and

quartz Quartz is a hard, crystalline mineral composed of silica ( silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical ...

, and may also contain organic matter and

sulphur Sulfur (or sulphur in British English) is a chemical element with the symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with a chemical formula ...

compounds. Fire clay is resistant to high temperatures, having fusion points higher than ; therefore it is suitable for lining furnaces, as fire brick, and for manufacture of utensils used in the

metalworking Metalworking is the process of shaping and reshaping metals to create useful objects, parts, assemblies, and large scale structures. As a term it covers a wide and diverse range of processes, skills, and tools for producing objects on every scale ...

industries, such as

crucible A crucible is a ceramic or metal container in which metals or other substances may be melted or subjected to very high temperatures. While crucibles were historically usually made from clay, they can be made from any material that withstands te ...

saggar A saggar (also misspelled as sagger or segger) is a type of kiln furniture. It is a ceramic boxlike container used in the firing of pottery to enclose or protect ware being fired inside a kiln. Traditionally, saggars were made primarily from ...

retort In a chemistry laboratory, a retort is a device used for distillation or dry distillation of substances. It consists of a spherical vessel with a long downward-pointing neck. The liquid to be distilled is placed in the vessel and heated. Th ...

s and

glassware upTypical drinkware The list of glassware includes drinking vessels (drinkware) and tableware used to set a table for eating a meal, general glass items such as vases, and glasses used in the catering industry. It does not include laboratory glas ...

. Its stability during firing in the

kiln A kiln is a thermally insulated chamber, a type of oven, that produces temperatures sufficient to complete some process, such as hardening, drying, or chemical changes. Kilns have been used for millennia to turn objects made from clay int ...

means that it can be used to make complex items of pottery such as pipes and sanitary ware.

Chemical composition

The chemical composition typical for fire clays are 23-34% Al₂O₃, 50-60% SiO₂ and 6-27%

loss on ignition Loss on ignition (LOI) is a test used in inorganic analytical chemistry and soil science, particularly in the analysis of minerals and the chemical makeup of soil. It consists of strongly heating ( "igniting") a sample of the material at a specified ...

together with various amounts of Fe₂O₃, CaO, MgO, K₂O, Na₂O and TiO₂. Chemical analyses from two 19th-century sources, shown in table below, are somewhat lower in alumina although a more contemporary source quotes analyses that are closer.

Extraction

Unlike conventional brick-making clay, some fire clays (especially flint clays) are

mined Mined may refer to: * Mined (text editor), a terminal-based text editor * Mining, the extraction of valuable geological materials from the Earth See also * Mind (disambiguation) * Mine (disambiguation) Mine, mines, miners or mining may refer ...

at depth, found as a

seatearth Seatearth is a British coal mining term, which is used in the geological literature. As noted by Jackson,Jackson, J.A., 1997, ''Glossary of geology'', 4th ed. American Geological Institute, Alexandria. a seatearth is the layer of sedimentary rock ...

, the underclay associated with

coal Coal is a combustible black or brownish-black sedimentary rock, formed as stratum, rock strata called coal seams. Coal is mostly carbon with variable amounts of other Chemical element, elements, chiefly hydrogen, sulfur, oxygen, and nitrogen ...

measures.

References

{{DEFAULTSORT:Fire Clay Ceramic materials Silicates Refractory materials Bricks Clay