Sulfosalts
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Sulfosalt minerals are
sulfide minerals The sulfide minerals are a class of minerals containing sulfide (S2−) or disulfide (S22−) as the major anion. Some sulfide minerals are economically important as metal ores. The sulfide class also includes the selenides, the tellurides, the ...
with the general formula , where *A represents a metal such as copper, lead, silver, iron, and rarely
mercury Mercury commonly refers to: * Mercury (planet), the nearest planet to the Sun * Mercury (element), a metallic chemical element with the symbol Hg * Mercury (mythology), a Roman god Mercury or The Mercury may also refer to: Companies * Merc ...
, zinc,
vanadium Vanadium is a chemical element with the symbol V and atomic number 23. It is a hard, silvery-grey, malleable transition metal. The elemental metal is rarely found in nature, but once isolated artificially, the formation of an oxide layer ( pas ...
*B usually represents semi-metal such as arsenic, antimony, bismuth, and rarely
germanium Germanium is a chemical element with the symbol Ge and atomic number 32. It is lustrous, hard-brittle, grayish-white and similar in appearance to silicon. It is a metalloid in the carbon group that is chemically similar to its group neighbors s ...
, or metals like tin and rarely
vanadium Vanadium is a chemical element with the symbol V and atomic number 23. It is a hard, silvery-grey, malleable transition metal. The elemental metal is rarely found in nature, but once isolated artificially, the formation of an oxide layer ( pas ...
*X is
sulfur Sulfur (or sulphur in British English) is a chemical element with the symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with a chemical formula ...
or rarely selenium and/or tellurium. The Strunz classification includes the sulfosalts in a ''sulfides and sulfosalts'' superclass. A group which have similar appearing formulas are the
sulfarsenide The sulfarsenide minerals are a subgroup of the sulfide minerals which include arsenic replacing sulfur as an anion in the formula.Klein, Cornelis and Cornelius S. Hurlbut, 1985, ''Manual of Mineralogy,'' 20th ed., John Wiley and Sons, New York, p. ...
s (for example cobaltite (Co,Fe)AsS). In sulfarsenides the arsenic substitutes for
sulfide Sulfide (British English also sulphide) is an inorganic anion of sulfur with the chemical formula S2− or a compound containing one or more S2− ions. Solutions of sulfide salts are corrosive. ''Sulfide'' also refers to chemical compounds lar ...
anions whereas in the sulfosalts the arsenic substitutes for a metal
cation An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by convent ...
.Klein, Cornelis and Cornelius S. Hurlbut (1985). ''Manual of Mineralogy'', 20th ed., John Wiley and Sons, New York . About 200 sulfosalt minerals are known. Examples include: File:Proustite (long prismatic crystal) - Chanarcillo, Copiapo Province, Atacama Region, Chile.jpg, As illustrated by this specimen of proustite, sulfosalt minerals are often deeply colored. * type ** Pyrargyrite ** Proustite **
Tetrahedrite Tetrahedrite is a copper antimony sulfosalt mineral with formula: . It is the antimony endmember of the continuous solid solution series with arsenic-bearing tennantite. Pure endmembers of the series are seldom if ever seen in nature. Of the two, ...
** Tennantite * type ** Enargite ** Sulvanite ** Samsonite **
Geocronite Geocronite is a mineral, a mixed sulfosalt containing lead, antimony, and arsenic with a formula of Pb14(Sb, As)6S23. Geocronite is the antimony-rich endmember of a solid solution series. The arsenic-rich endmember is named jordanite. It occurs a ...
**
Gratonite Gratonite is a lead-arsenic sulfosalt mineral, with the chemical composition Pb9As4S15. Gratonite was discovered in 1939 at the Excelsior Mine, Cerro de Pasco, Peru , image_flag = Flag of Peru.svg , image_coat = E ...
* type ** Bournonite **
Seligmannite Seligmanite is a rare mineral, with the chemical formula PbCuAsS3. Originally described from the Lengenbach Quarry, Valais, Valais Canton, Switzerland; it has also been found in the Raura district, Lima Region, Peru; at Tsumeb, Oshikoto Region, Na ...
** Aikinite * type ** Boulangerite ** Matildite ** Smithite **
Chalcostibite Chalcostibite is a copper antimony sulfide mineral. Příbramite is related, having selenium instead of sulfur. Emplectite contains bismuth instead of antimony. Occurrences * Argentina ** Salta Province *** Los Andes department **** San Ant ...
** Emplectite ** Teallite * type ** Ramdohrite ** Jamesonite ** Cosalite * type **
Andorite Andorite is a sulfosalt minerals, sulfosalt mineral with the chemical formula PbAgSb3S6. It was first described in 1892 for an occurrence in the Baia Sprie mine, Baia Sprie, in what is now Maramureș County, Romania, and named for Hungarian amate ...
** Lindstromite * type ** Zinkenite **
Berthierite Berthierite is a mineral, a sulfide of iron and antimony with formula FeSb2S4. It is steel grey in colour with a metallic lustre which can be covered by an iridescent tarnish. Because of its appearance it is often mistaken for stibnite. It was ...
** Cylindrite


Nickel–Strunz Classification -02- Sulfosalts

IMA-CNMNC proposes a new hierarchical scheme (Mills et al., 2009). This list uses the Classification of Nickel–Strunz (
mindat.org Mindat.org is a non-commercial online database, claiming to be the largest mineral database and mineralogy, mineralogical reference website on the Internet. It is used by professional mineralogists, geologists, and amateur mineral collecting, mi ...
, 10 ed, pending publication). *Abbreviations: **"*" - discredited (IMA/CNMNC status). **"?" - questionable/doubtful (IMA/CNMNC status). **"REE" - Rare-earth element (Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu) **"PGE" - Platinum-group element (Ru, Rh, Pd, Os, Ir, Pt) **03.C Aluminofluorides, 06 Borates, 08 Vanadates (04.H V ,6/sup> Vanadates), 09 Silicates: ***Neso: insular (from Greek νῆσος ''nēsos'', island) ***Soro: grouping (from Greek σωρός ''sōros'', heap, mound (especially of corn)) ***Cyclo: ring (from Greek κύκλος ''kyklos'', wheel, ring, round) ***Ino: chain (from Greek ἴς enitive: ἰνός ''inos'' fibre) ***Phyllo: sheet (from Greek φύλλον ''phyllon'', leaf) ***Tekto: three-dimensional framework (from Greek stem τεκτ- ''tekt-'' in words having to do with carpentry) *Nickel–Strunz code scheme: NN.XY.##x **NN: Nickel–Strunz mineral class number **X: Nickel–Strunz mineral division letter **Y: Nickel–Strunz mineral family letter **##x: Nickel–Strunz mineral/group number, x add-on letter


Class: sulfosalts

* 02.G Sulfarsenites, sulfantimonites, sulfobismuthites ** 02.G: IMA2007-010 ** 02.GA Neso-sulfarsenites, etc., without additional S: 05 Proustite, 05 Pyrargyrite; 10 Xanthoconite, 10 Pyrostilpnite; 15 Samsonite; 20 Wittichenite, 20 Skinnerite, 25 Malyshevite, 25 Lisiguangite, 25 Muckeite, 25 Lapieite; 30
Aktashite Aktashite is a rare arsenic sulfosalt mineral with formula Cu6Hg3As4S12. It is a copper Mercury (element), mercury-bearing sulfosalt and is the only sulfosalt mineral with essential Cu and Hg yet known. It is of hydrothermal origin. It was publish ...
, 30 Nowackiite, 30 Gruzdevite; 35 Laffittite; 40 Stalderite, 40
Routhierite Routhierite is a rare thallium sulfosalt mineral with formula . It was first described in 1974 for an occurrence in the Jas Roux deposit in the French Alps. It was named after French geologist Pierre Routhier (1916–2008).Erniggliite; 50
Seligmannite Seligmanite is a rare mineral, with the chemical formula PbCuAsS3. Originally described from the Lengenbach Quarry, Valais, Valais Canton, Switzerland; it has also been found in the Raura district, Lima Region, Peru; at Tsumeb, Oshikoto Region, Na ...
, 50 Soucekite, 50 Bournonite ** 02.GB Neso-sulfarsenites, etc.: 05 Argentotennantite, 05 Giraudite, 05 Goldfieldite, 05
Freibergite Freibergite is a complex sulfosalt mineral of silver, copper, iron, antimony and arsenic with formula . It has cubic crystals and is formed in hydrothermal deposits. It forms one solid solution series with tetrahedrite and another with argentoten ...
, 05 Hakite, 05 Tennantite, 05
Tetrahedrite Tetrahedrite is a copper antimony sulfosalt mineral with formula: . It is the antimony endmember of the continuous solid solution series with arsenic-bearing tennantite. Pure endmembers of the series are seldom if ever seen in nature. Of the two, ...
; 10 Selenostephanite, 10 Stephanite; 15 Cupropearceite, 15 Selenopolybasite, 15 Cupropolybasite, 15
Polybasite Polybasite is a sulfosalt mineral of silver, copper, antimony and arsenic. Its chemical formula is . It forms black monoclinic crystals (thin, tabular, with six corners) which can show dark red internal reflections. It has a Mohs hardness of 2.5 ...
, 15 Pearceite, 15 Antimonpearceite, 15 Arsenpolybasite, 20 Galkhaite ** 02.GC Poly-sulfarsenites: 05 Hatchite, 05 Wallisite; 10 Sinnerite, 15 Watanabeite, 20 Simonite, 25 Q­ratite, 30 Smithite, 35 Trechmannite, 40a
Aleksite Aleksite ( IMA symbol: Alk) is a rare lead bismuth tellurium sulfosalt mineral Sulfosalt minerals are sulfide minerals with the general formula , where *A represents a metal such as copper, lead, silver, iron, and rarely mercury, zinc, vanad ...
, 40b Kochkarite, 40c Rucklidgeite, 40c Poubaite, 40d Saddlebackite, 40e Babkinite; 45 Tvalchrelidzeite, 50 Mutnovskite * 02.H Sulfosalts of SnS Archetype ** 02.HA With Cu, Ag, Fe (without Pb): 05 Emplectite, 05
Chalcostibite Chalcostibite is a copper antimony sulfide mineral. Příbramite is related, having selenium instead of sulfur. Emplectite contains bismuth instead of antimony. Occurrences * Argentina ** Salta Province *** Los Andes department **** San Ant ...
; 10
Miargyrite Miargyrite is a mineral, a sulfide of silver and antimony with the formula Ag Sb S2. It is a dimorph of cuboargyrite. Originally discovered in the Freiberg district of Germany in 1824, it has subsequently been found in many places where silver i ...
, 15
Livingstonite Livingstonite is a mercury antimony sulfosalt mineral. It occurs in low-temperature hydrothermal veins associated with cinnabar, stibnite, sulfur and gypsum. It was first described in 1874 for an occurrence in Huitzuco de los Figueroa, Guerrer ...
; 20
Berthierite Berthierite is a mineral, a sulfide of iron and antimony with formula FeSb2S4. It is steel grey in colour with a metallic lustre which can be covered by an iridescent tarnish. Because of its appearance it is often mistaken for stibnite. It was ...
, 20 Clerite, 20 Garavellite; 25 Baumstarkite, 25
Aramayoite Aramayoite ( IMA symbol: Ary) is a mineral with the chemical formula . Its type locality is Sud Chichas, Potosí, Bolivia.Aramayoite
o ...
** 02.HB With Cu, Ag, Hg, Fe, Sn and Pb: 05a Krupkaite, 05a Aikinite, 05a Hammarite, 05a Gladite, 05a Friedrichite, 05a Lindstromite, 05a Pekoite, 05a Paarite, 05a Emilite, 05a
Salzburgite Salzburgite has a general empirical formula of Pb2Cu2Bi7S12 and an orthorhombic crystal structure.Ralph, Joylon, and Ida ChauSalzburgite Joylon Ralph, 1993-2010. Web. 14 September 2010. This mineral is very similar to paarite in that they both ...
, 05b
Meneghinite Meneghinite is a sulfosalt mineral with the chemical formula CuPb13 Sb7S24. In the orthorhombic crystal system, meneghinite has a Mohs hardness of , one perfect cleavage and a conchoidal fracture. It is a blackish lead-grey in colour and gives a ...
, 05c Jaskolskiite; 10a
Kobellite Kobellite is a gray, fibrous, metallic mineral with the chemical formula . It is also a sulfide mineral consisting of antimony, bismuth, and lead. It is a member of the izoklakeite – berryite series with silver and iron substituting in the coppe ...
, 10a Tintinaite, 10b Giessenite, 10b Izoklakeite, 10c Eclarite; 15 Jamesonite, 15 Benavidesite; 20a Nagyagite, 20b Buckhornite, 20c Museumite, 20d
Berryite Berryite is a mineral with the formula . It occurs as gray to blue-gray monoclinic prisms. It is opaque and has a metallic Lustre (mineralogy), luster. It has a Mohs hardness of 3.5 and a specific gravity of 6.7. It was first identified in 1965 u ...
, 20e Watkinsonite ** 02.HC With only Pb: 05a Sartorite, 05a Twinnite, 05a
Guettardite Guettardite is a rare arsenic-antimony lead sulfosalt mineral with the chemical formula . It forms gray black metallic prismatic to acicular crystals with monoclinic symmetry. It is a dimorph of the triclinic twinnite. Discovery and occurrence ...
, 05b
Baumhauerite Baumhauerite (Pb3As4S9) is a rare lead sulfosalt mineral. It crystallizes in the triclinic system, is gray-black to blue-gray and its lustre is metallic to dull. Baumhauerite has a hardness of 3. Baumhauerite occurs as small crystals embedded in ...
, 05b Baumhauerite-2a, 05c Liveingite, 05d Dufrenoysite, 05d Veenite, 05d Rathite, 05e Chabourneite, 05f Pierrotite, 05f Parapierrotite, 05g Marumoite; 10a Fuloppite, 10b Bismutoplagionite*, 10b Plagionite, 10c Heteromorphite, 10d Semseyite, 10d
Rayite Rayite, a monoclinic mineral containing Lead-Silver-Thallium-Antimony, was found during microscopic and electron microprobe study of specimens from the complex, polymetallic sulphide-native metal sulpho-salt paragenesis of Rajpura- Dariba, Rajast ...
; 15 Boulangerite, 15 Falkmanite, 15
Plumosite Plumosite is a questionable mineral. Most of the time, it can refer to any feather ore, i.e. any ore that forms fine capillaries within the surrounding rock. Older specimens could be either boulangerite, jamesonite or zinkenite Zinkenite is ...
*; 20 Robinsonite, 25 Moeloite, 30 Dadsonite, 35 Zoubekite, 35 Owyheeite ** 02.HD With Tl: 05 Lorandite, 05 Weissbergite; 15 Christite, 20 Jankovicite, 25 Rebulite, 30 Imhofite, 35 Edenharterite, 40 Jentschite, 45 Hutchinsonite, 50 Bernardite, 55 Sicherite, 60
Gabrielite Gabrielite is a rare thallium sulfosalt mineral with a chemical formula of or . It was first reported in 2002 for its occurrence in the Lengenbach quarry, Binntal, Valais, Switzerland, and named after Walter Gabriel (born 1943), a Swiss min ...
** 02.HE With alkalies, : 05 Gerstleyite ** 02.HF With SnS and PbS archetype structure units: 20 Vrbaite; 25a
Abramovite Abramovite is a very rare mineral from the sulfides and sulfosalt categories. It has the chemical formula Pb2 Sn In Bi S7. It occurs as tiny elongated lamellar-shaped crystals, up 1 mm × 0.2 mm in size, and is characterized by its no ...
, 25a Levyclaudite, 25a Cylindrite, 25b Coiraite, 25b Incaite, 25b Potosiite, 25b
Franckeite Franckeite, chemical formula Pb5Sn3Sb2S14, belongs to a family of complex sulfide minerals. Franckeite is a sulfosalt. It is closely related to cylindrite. It was first described in 1893 for an occurrence in Chocaya, Potosí Department, Bolivia. ...
; 30 Lengenbachite * 02.J Sulfosalts of PbS Archetype ** 02.JA Galena derivatives with little or no Pb: 05a IMA2005-036, 05a IMA2008-058, 05a Cupropavonite, 05a Pavonite, 05b Grumiplucite, 05c Kudriavite, 05d Cupromakovickyite, 05d Makovickyite, 05e Benjaminite, 05f Mummeite, 05g Borodaevite, 05h Mozgovaite; 10a Cuprobismutite, 10b Kupcikite, 10c Hodrushite, 10d Pizgrischite, 10e Paderaite; 15 Cuboargyrite, 15 Schapbachite; 20 Bohdanowiczite, 20 Matildite, 20 Volynskite ** 02.JB Galena derivatives, with Pb: 05 Diaphorite, 10 Cosalite; 15
Marrite Marrite (mar'-ite) is a mineral with the chemical formula PbAgAsS3. It is the arsenic equivalent of freieslebenite (PbAgSbS3), but also displays close polyhedral characteristics with sicherite and diaphorite.Berlepsch, P., Makovicky E., and Ar ...
, 15 Freieslebenite; 20 Cannizzarite, 20 Wittite; 25a Junoite, 25b Felbertalite, 25c Nordstromite, 25d Proudite, 25g Nuffieldite, 25i IMA2008-053, 25i Neyite, 25j Rouxelite; 30a
Jordanite Jordanite is a sulfosalt mineral with chemical formula in the monoclinic crystal system, named after the German scientist H. Jordan (1808–1887) who discovered it in 1864. Lead-grey in colour (frequently displaying an iridescent tarnish), its ...
, 30a
Geocronite Geocronite is a mineral, a mixed sulfosalt containing lead, antimony, and arsenic with a formula of Pb14(Sb, As)6S23. Geocronite is the antimony-rich endmember of a solid solution series. The arsenic-rich endmember is named jordanite. It occurs a ...
, 30b Kirkiite, 30c Tsugaruite; 35a Zinkenite, 35b Scainiite, 35c Pillaite, 35d Pellouxite; 40a
Bursaite Bursaite is a sulfosalt of the lillianite family. It has the formula Pb5Bi4S11 and orthorhombic structure. Bursaite is named after Bursa Province, Turkey, where it was discovered.Rasit, T. (1954-55A study on the concentration tests and beneficiati ...
?, 40a Gustavite, 40a Lillianite, 40a
Xilingolite Xilingolite is a lead sulfide mineral with formula Pb3Bi2S6. It has a hardness of 3, a metallic luster, and usually exhibits a lead-grey color. It is a dimorph of lillianite, exhibiting increased Pb-Bi order and decreased symmetry. Its crystal s ...
, 40a Treasurite, 40a Vikingite, 40a Fizelyite, 40a
Andorite Andorite is a sulfosalt minerals, sulfosalt mineral with the chemical formula PbAgSb3S6. It was first described in 1892 for an occurrence in the Baia Sprie mine, Baia Sprie, in what is now Maramureș County, Romania, and named for Hungarian amate ...
, 40a Roshchinite, 40a Uchucchacuaite, 40a Ramdohrite, 40b
Aschamalmite Aschamalmite is a mineral with the chemical formula PbBiS. Its type locality is the High Tauern in Austria.Aschamalmite
on
, 40b Eskimoite, 40b Heyrovskyite, 40c Ourayite, 40d Schirmerite, 40e Ustarasite; 45 Angelaite, 45 Galenobismutite, 45 Weibullite; 55
Gratonite Gratonite is a lead-arsenic sulfosalt mineral, with the chemical composition Pb9As4S15. Gratonite was discovered in 1939 at the Excelsior Mine, Cerro de Pasco, Peru , image_flag = Flag of Peru.svg , image_coat = E ...
, 60 Marrucciite, 65 Vurroite ** 02.JC Galena derivatives, with Tl: 05 Ellisite, 10 Gillulyite * 02.K Sulfarsenates, Sulfantimonates ** 02.KA Sulfarsenates with tetrahedra: 05 Enargite, 05 Stibioenargite*, 05 Petrukite; 10
Briartite Briartite is an opaque iron-grey metallic sulfide mineral, with traces of Ga and Sn, found as inclusions in other germanium- gallium-bearing sulfides. It was discovered at the Prince Léopold Mine, Kipushi, Shaba, Congo (Léopoldville) in 1965 ...
, 10 Famatinite, 10 Luzonite, 10 Permingeatite, 10 Barquillite; 15
Fangite Fangite is a sulfosalt first discovered in the Mercur gold deposit located in Tooele County Utah. The specimen was found in a boulder in the southern Oquirrh Mountains. The only available specimens of fangite are located in the National Museum ...
** 02.KB Sulfarsenates with additional S: 05 Billingsleyite * 02.L Unclassified Sulfosalts ** 02.LA Without essential Pb: 10 Dervillite, 15 Daomanite*, 20 Vaughanite, 25 Criddleite, 30 Fettelite, 35 Chameanite, 40 Arcubisite, 45 Mgriite, 50 Benleonardite, 55 Tsnigriite, 60 Borovskite, 65 Jonassonite ** 02.LB With essential Pb: 05 Miharaite, 20 Ardaite, 30 Madocite, 35 Larosite; 40 Petrovicite, 40 Mazzettiite; 45 Crerarite, 50 Launayite, 55
Playfairite Playfairite is a rare sulfosalt mineral with chemical formula Pb16Sb18S43 in the monoclinic crystal system, named after the Scottish scientist and mathematician John Playfair. It was discovered in 1966 by the Canadian mineralogist John Leslie Jam ...
, 60 Sorbyite, 65 Sterryite * 02.M ** 02.MA Oxysulfosalts of Alkalies and Alkali Earths: 05 Ottensite, 05 Cetineite; 10
Sarabauite Sarabauite (sar-a-bau'-ite) is a red monoclinic sulfide mineral with the chemical formula: CaSb10O10S6. Origin of name and type locality Sarabauite was first described in 1977 and named for its type locality, the Sarabau Mine (Lucky Hill mi ...
* 02.X Unclassified Strunz Sulfosalts ** 02.XX Unknown: 00 Tazieffite, 00 Horobetsuite*, 00 Kitaibelite?, 00 Parajamesonite?, 00 Sakharovaite?, 00 Volfsonite*


Synthetic sulfosalts

Many sulfosalts can be prepared in the laboratory, including many that do not occur in nature.Sheldrick, William S.; Wachhold, Michael "Chalcogenidometalates of the heavier Group 14 and 15 elements" Coordination Chemistry Reviews 1998, vol. 176, 211-322.


References

* Mozgova N.N. (2000). ''Sulfosalt mineralogy today''. In: ''Modern Approaches to Ore and Environmental Mineralogy'', MSF Mini-Symposium Espoo Finland, June 11–17, 2000, https://web.archive.org/web/20050907172937/http://www.igem.ru/igem/mine/sulfosalts.htm Retrieved July 22, 2005. * * * * {{Strunz