Guettardite
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Guettardite
Guettardite is a rare arsenic-antimony lead sulfosalt mineral with the chemical formula . It forms gray black metallic prismatic to acicular crystals with monoclinic symmetry. It is a dimorph of the triclinic twinnite. Discovery and occurrence It was first described in 1967 for an occurrence in the Taylor Pit, Madoc, Hastings County, Ontario, Canada. It was named for French naturalist Jean-Étienne Guettard (1715–1786). It occurs in hydrothermal veins within marble at the type locality in Modoc. It occurs associated with pyrite, sphalerite, wurtzite, galena, stibnite, orpiment, realgar, enargite, tetrahedrite, zinkenite, jordanite, bournonite, sterryite, boulangerite, jamesonite and sartorite at Madoc. In addition to the type locality, it has been reported from the Brobdingnag mine, near Silverton, Colorado; the Jas Roux deposit in Hautes-Alpes, France; from various marble quarries near Seravezza, Tuscany, Italy; a marble quarry in Valais, Switzerland and from Khayda ...
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Sulfosalt Mineral
Sulfosalt minerals are sulfide minerals with the general formula , where *A represents a metal such as copper, lead, silver, iron, and rarely mercury (element), mercury, zinc, vanadium *B usually represents semi-metal such as arsenic, antimony, bismuth, and rarely germanium, or metals like tin and rarely vanadium *X is sulfur or rarely selenium and/or tellurium. The Strunz classification includes the sulfosalts in a ''sulfides and sulfosalts'' superclass. A group which have similar appearing formulas are the Sulfarsenide mineral, sulfarsenides (for example cobaltite (Co,Fe)AsS). In sulfarsenides the arsenic substitutes for sulfide anions whereas in the sulfosalts the arsenic substitutes for a metal cation.Klein, Cornelis and Cornelius S. Hurlbut (1985). ''Manual of Mineralogy'', 20th ed., John Wiley and Sons, New York . About 200 sulfosalt minerals are known. Examples include: File:Proustite (long prismatic crystal) - Chanarcillo, Copiapo Province, Atacama Region, Chile.jpg, As ...
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Sulfosalt Mineral
Sulfosalt minerals are sulfide minerals with the general formula , where *A represents a metal such as copper, lead, silver, iron, and rarely mercury (element), mercury, zinc, vanadium *B usually represents semi-metal such as arsenic, antimony, bismuth, and rarely germanium, or metals like tin and rarely vanadium *X is sulfur or rarely selenium and/or tellurium. The Strunz classification includes the sulfosalts in a ''sulfides and sulfosalts'' superclass. A group which have similar appearing formulas are the Sulfarsenide mineral, sulfarsenides (for example cobaltite (Co,Fe)AsS). In sulfarsenides the arsenic substitutes for sulfide anions whereas in the sulfosalts the arsenic substitutes for a metal cation.Klein, Cornelis and Cornelius S. Hurlbut (1985). ''Manual of Mineralogy'', 20th ed., John Wiley and Sons, New York . About 200 sulfosalt minerals are known. Examples include: File:Proustite (long prismatic crystal) - Chanarcillo, Copiapo Province, Atacama Region, Chile.jpg, As ...
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Marble
Marble is a metamorphic rock composed of recrystallized carbonate minerals, most commonly calcite or Dolomite (mineral), dolomite. Marble is typically not Foliation (geology), foliated (layered), although there are exceptions. In geology, the term ''marble'' refers to metamorphosed limestone, but its use in stonemasonry more broadly encompasses unmetamorphosed limestone. Marble is commonly used for Marble sculpture, sculpture and as a building material. Etymology The word "marble" derives from the Ancient Greek (), from (), "crystalline rock, shining stone", perhaps from the verb (), "to flash, sparkle, gleam"; Robert S. P. Beekes, R. S. P. Beekes has suggested that a "Pre-Greek origin is probable". This Stem (linguistics), stem is also the ancestor of the English language, English word "marmoreal," meaning "marble-like." While the English term "marble" resembles the French language, French , most other European languages (with words like "marmoreal") more closely resemb ...
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Bournonite
Bournonite is a sulfosalt mineral species, trithioantimoniate of lead and copper with the formula PbCuSbS3. It was first mentioned by Philip Rashleigh in 1797 as an ore of antimony and was more completely described in 1804 by French crystallographer and mineralogist Jacques Louis, Comte de Bournon (1751–1825), after whom it was named. The name given by Bournon himself (in 1813) was endellione, since used in the form endellionite, after St Endellion, the locality in Cornwall where the mineral was first found. The crystals are orthorhombic, and are generally tabular in habit owing to the predominance of the basal pinacoid; numerous smooth bright faces are often developed on the edges and corners of the crystals. They are usually twinned, the twin-plane being a face of the prism (m); the angle between the faces of this prism being nearly a right angle (86° 20′), the twinning gives rise to cruciform groups and when it is often repeated the group has the appearance of a cog- ...
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Jordanite
Jordanite is a sulfosalt mineral with chemical formula in the monoclinic crystal system, named after the German scientist H. Jordan (1808–1887) who discovered it in 1864. Lead-grey in colour (frequently displaying an iridescent tarnish), its streak is black and its lustre is metallic. Jordanite has a hardness of 3 on Mohs scale, has a density of approximately 6.4, and a conchoidal fracture. The type locality is the Lengenbach Quarry in the Binn Binn (Walser German: ''Bìi'') is a municipality in the district of Goms in the canton of Valais in Switzerland. The Binn Valley is known for its rich mineral deposits, some types of which are unique to the area. The notable Lengenbach Quar ... Valley, Wallis, Switzerland. References Sulfosalt minerals Lead minerals Monoclinic minerals Minerals in space group 11 Arsenic minerals Antimony minerals {{sulfide-mineral-stub ...
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Zinkenite
Zinkenite is a steel-gray metallic sulfosalt mineral composed of lead antimony sulfide Pb9 Sb22 S42. Zinkenite occurs as acicular needle-like crystals. It was first described in 1826 for an occurrence in the Harz Mountains, Saxony-Anhalt, Germany and named after its discoverer, German mineralogist and mining geologist, Johann Karl Ludwig Zinken Johann, typically a male given name, is the German form of ''Iohannes'', which is the Latin form of the Greek name ''Iōánnēs'' (), itself derived from Hebrew name '' Yochanan'' () in turn from its extended form (), meaning "Yahweh is Gracious ... (1790–1862).http://www.mindat.org/min-4417.html Mindat References Lead minerals Antimony minerals Sulfosalt minerals Hexagonal minerals Minerals in space group 173 {{sulfide-mineral-stub ...
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Tetrahedrite
Tetrahedrite is a copper antimony sulfosalt mineral with formula: . It is the antimony endmember of the continuous solid solution series with arsenic-bearing tennantite. Pure endmembers of the series are seldom if ever seen in nature. Of the two, the antimony rich phase is more common. Other elements also substitute in the structure, most notably iron and zinc, along with less common silver, mercury and lead. Bismuth also substitutes for the antimony site and ''bismuthian tetrahedrite'' or ''annivite'' is a recognized variety. The related, silver dominant, mineral species freibergite, although rare, is notable in that it can contain up to 18% silver. Mineralogy Tetrahedrite gets its name from the distinctive tetrahedron shaped cubic crystals. The mineral usually occurs in massive form, it is a steel gray to black metallic mineral with Mohs hardness of 3.5 to 4 and specific gravity of 4.6 to 5.2. Tetrahedrite occurs in low to moderate temperature hydrothermal veins and in some co ...
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Enargite
Enargite is a copper arsenic sulfosalt mineral with formula Cu3AsS4. It takes its name from the Greek word , "distinct". Enargite is a steel gray, blackish gray, to violet black mineral with metallic luster. It forms slender orthorhombic prisms as well as massive aggregates. It has a hardness of 3 and a specific gravity of 4.45. Enargite is dimorph of the tetragonal luzonite. Occurrence It is a medium to low temperature hydrothermal mineral occurring with quartz, pyrite, sphalerite, galena, bornite, tetrahedrite–tennantite, chalcocite, covellite and baryte. It occurs in the mineral deposits at Butte, Montana, San Juan Mountains, Colorado and at both Bingham Canyon and Tintic, Utah. It is also found in the copper mines of Canada, Mexico, Argentina, Chile, Peru, and the Philippines. Enargite was originally described as a new species from the copper mines of the San Francisco vein, Junin Department, Peru , image_flag = Flag of Peru.svg , image_coat ...
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Realgar
Realgar ( ), also known as "ruby sulphur" or "ruby of arsenic", is an arsenic sulfide mineral with the chemical formula α-. It is a soft, sectile mineral occurring in monoclinic crystals, or in granular, compact, or powdery form, often in association with the related mineral, orpiment (). It is orange-red in color, melts at 320 °C, and burns with a bluish flame releasing fumes of arsenic and sulfur. Realgar is soft with a Mohs hardness of 1.5 to 2 and has a specific gravity of 3.5. Its streak is orange colored. It is trimorphous with pararealgar and bonazziite. Its name comes from the Arabic ''rahj al-ġār'' (, "powder of the mine"), via Medieval Latin, and its earliest record in English is in the 1390s. Uses Realgar is a minor ore of arsenic extracted in China, Peru, and the Philippines. Historical uses Realgar was used by firework manufacturers to create the color white in fireworks prior to the availability of powdered metals such as aluminium, magnesium and titani ...
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Orpiment
Orpiment is a deep-colored, orange-yellow arsenic sulfide mineral with formula . It is found in volcanic fumaroles, low-temperature hydrothermal veins, and hot springs and is formed both by sublimation and as a byproduct of the decay of another arsenic sulfide mineral, realgar. Orpiment takes its name from the Latin ''auripigmentum'' (''aurum'', "gold" + ''pigmentum'', "pigment") because of its deep-yellow color. Historical uses Orpiment was traded in the Roman Empire and was used as a medicine in China, even though it is very toxic. It has been used as fly poison and to tip arrows with poison. Because of its striking color, it was of interest to alchemists, both in China and the West, searching for a way to make gold. It also has been found in the wall decorations of Tutankhamun's tomb and ancient Egyptian scrolls, and on the walls of the Taj Mahal. For centuries, orpiment was ground down and used as a pigment in painting and for sealing wax, and was even used in ancient Chi ...
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Stibnite
Stibnite, sometimes called antimonite, is a sulfide mineral with the formula Sb2 S3. This soft grey material crystallizes in an orthorhombic space group. It is the most important source for the metalloid antimony. The name is derived from the Greek στίβι ''stibi'' through the Latin ''stibium'' as the former name for the mineral and the element antimony. Structure Stibnite has a structure similar to that of arsenic trisulfide, As2S3. The Sb(III) centers, which are pyramidal and three-coordinate, are linked via bent two-coordinate sulfide ions. However, some studies suggest that the actual coordination polyhedra of antimony are SbS7, with (3+4) coordination at the M1 site and (5+2) at the M2 site. Some of the secondary bonds impart cohesion and are connected with packing. Stibnite is grey when fresh, but can turn superficially black due to oxidation in air. Properties The melting point of Sb2S3 is . The band gap is 1.88 eV at room temperature and it is a photoco ...
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Galena
Galena, also called lead glance, is the natural mineral form of lead(II) sulfide (PbS). It is the most important ore of lead and an important source of silver. Galena is one of the most abundant and widely distributed sulfide minerals. It crystallizes in the cubic crystal system often showing octahedral forms. It is often associated with the minerals sphalerite, calcite and fluorite. Occurrence Galena is the main ore of lead, used since ancient times, since lead can be smelted from galena in an ordinary wood fire. Galena typically is found in hydrothermal veins in association with sphalerite, marcasite, chalcopyrite, cerussite, anglesite, dolomite, calcite, quartz, barite, and fluorite. It is also found in association with sphalerite in low-temperature lead-zinc deposits within limestone beds. Minor amounts are found in contact metamorphic zones, in pegmatites, and disseminated in sedimentary rock. In some deposits the galena contains up to 0.5% silver, a byproduct that ...
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