Uranium Deposits
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Uranium ore deposits are economically recoverable concentrations of
uranium Uranium is a chemical element with the symbol U and atomic number 92. It is a silvery-grey metal in the actinide series of the periodic table. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. Uranium is weak ...
within the
Earth Earth is the third planet from the Sun and the only astronomical object known to harbor life. While large volumes of water can be found throughout the Solar System, only Earth sustains liquid surface water. About 71% of Earth's surfa ...
's crust. Uranium is one of the more common elements in the Earth's crust, being 40 times more common than
silver Silver is a chemical element with the Symbol (chemistry), symbol Ag (from the Latin ', derived from the Proto-Indo-European wikt:Reconstruction:Proto-Indo-European/h₂erǵ-, ''h₂erǵ'': "shiny" or "white") and atomic number 47. A soft, whi ...
and 500 times more common than
gold Gold is a chemical element with the symbol Au (from la, aurum) and atomic number 79. This makes it one of the higher atomic number elements that occur naturally. It is a bright, slightly orange-yellow, dense, soft, malleable, and ductile met ...
. It can be found almost everywhere in rock, soil, rivers, and oceans. The challenge for commercial uranium extraction is to find those areas where the concentrations are adequate to form an economically viable deposit. The primary use for uranium obtained from mining is in fuel for nuclear reactors. Globally, the distribution of uranium ore deposits is widespread on all continents, with the largest deposits found in Australia,
Kazakhstan Kazakhstan, officially the Republic of Kazakhstan, is a transcontinental country located mainly in Central Asia and partly in Eastern Europe. It borders Russia to the north and west, China to the east, Kyrgyzstan to the southeast, Uzbeki ...
, and Canada. To date, high-grade deposits are only found in the
Athabasca Basin The Athabasca Basin is a region in the Canadian Shield of northern Saskatchewan and Alberta, Canada. It is best known as the world's leading source of high-grade uranium and currently supplies about 20% of the world's uranium. The basin i ...
region of Canada. Uranium deposits are generally classified based on host rocks, structural setting, and mineralogy of the deposit. The most widely used classification scheme was developed by the
International Atomic Energy Agency The International Atomic Energy Agency (IAEA) is an intergovernmental organization that seeks to promote the peaceful use of nuclear energy and to inhibit its use for any military purpose, including nuclear weapons. It was established in 1957 ...
(IAEA) and subdivides deposits into 15 categories. __TOC__


Uranium

Uranium is a silvery-gray
metal A metal (from Greek μέταλλον ''métallon'', "mine, quarry, metal") is a material that, when freshly prepared, polished, or fractured, shows a lustrous appearance, and conducts electricity and heat relatively well. Metals are typicall ...
lic weakly
radioactive Radioactive decay (also known as nuclear decay, radioactivity, radioactive disintegration, or nuclear disintegration) is the process by which an unstable atomic nucleus loses energy by radiation. A material containing unstable nuclei is consid ...
chemical element A chemical element is a species of atoms that have a given number of protons in their nuclei, including the pure substance consisting only of that species. Unlike chemical compounds, chemical elements cannot be broken down into simpler sub ...
. It has the
chemical symbol Chemical symbols are the abbreviations used in chemistry for chemical elements, functional groups and chemical compounds. Element symbols for chemical elements normally consist of one or two letters from the Latin alphabet and are written with th ...
U and
atomic number The atomic number or nuclear charge number (symbol ''Z'') of a chemical element is the charge number of an atomic nucleus. For ordinary nuclei, this is equal to the proton number (''n''p) or the number of protons found in the nucleus of every ...
92. The most common
isotope Isotopes are two or more types of atoms that have the same atomic number (number of protons in their nuclei) and position in the periodic table (and hence belong to the same chemical element), and that differ in nucleon numbers (mass numbers) ...
s in natural uranium are 238U (99.27%) and 235U (0.72%). All uranium isotopes present in natural uranium are
radioactive Radioactive decay (also known as nuclear decay, radioactivity, radioactive disintegration, or nuclear disintegration) is the process by which an unstable atomic nucleus loses energy by radiation. A material containing unstable nuclei is consid ...
and
fissionable In nuclear engineering, fissile material is material capable of sustaining a nuclear fission chain reaction. By definition, fissile material can sustain a chain reaction with neutrons of thermal energy. The predominant neutron energy may be typi ...
, and 235U is
fissile In nuclear engineering, fissile material is material capable of sustaining a nuclear fission chain reaction. By definition, fissile material can sustain a chain reaction with neutrons of thermal energy. The predominant neutron energy may be typ ...
(will support a neutron-mediated chain reaction). Uranium,
thorium Thorium is a weakly radioactive metallic chemical element with the symbol Th and atomic number 90. Thorium is silvery and tarnishes black when it is exposed to air, forming thorium dioxide; it is moderately soft and malleable and has a high me ...
, and one radioactive isotope of
potassium Potassium is the chemical element with the symbol K (from Neo-Latin ''kalium'') and atomic number19. Potassium is a silvery-white metal that is soft enough to be cut with a knife with little force. Potassium metal reacts rapidly with atmosphe ...
() as well as their decay products are the main elements contributing to natural terrestrial radioactivity. Cosmogenic radionuclides are of less importance but unlike the aforementioned
primordial radionuclide In geochemistry, geophysics and nuclear physics, primordial nuclides, also known as primordial isotopes, are nuclides found on Earth that have existed in their current form since before Earth was formed. Primordial nuclides were present in the ...
s, which date back to the formation of the planet and have since slowly decayed away, they are replenished at roughly the same rate they decay by the bombardment of earth with
cosmic rays Cosmic rays are high-energy particles or clusters of particles (primarily represented by protons or atomic nuclei) that move through space at nearly the speed of light. They originate from the Sun, from outside of the Solar System in our own ...
. Uranium has the highest atomic weight of the naturally occurring elements and is approximately 70%
denser Density (volumetric mass density or specific mass) is the substance's mass per unit of volume. The symbol most often used for density is ''ρ'' (the lower case Greek language, Greek letter Rho (letter), rho), although the Latin letter ''D'' ca ...
than
lead Lead is a chemical element with the symbol Pb (from the Latin ) and atomic number 82. It is a heavy metal that is denser than most common materials. Lead is soft and malleable, and also has a relatively low melting point. When freshly cu ...
, but not as dense as
tungsten Tungsten, or wolfram, is a chemical element with the symbol W and atomic number 74. Tungsten is a rare metal found naturally on Earth almost exclusively as compounds with other elements. It was identified as a new element in 1781 and first isolat ...
,
gold Gold is a chemical element with the symbol Au (from la, aurum) and atomic number 79. This makes it one of the higher atomic number elements that occur naturally. It is a bright, slightly orange-yellow, dense, soft, malleable, and ductile met ...
,
platinum Platinum is a chemical element with the symbol Pt and atomic number 78. It is a dense, malleable, ductile, highly unreactive, precious, silverish-white transition metal. Its name originates from Spanish , a diminutive of "silver". Platinu ...
,
iridium Iridium is a chemical element with the symbol Ir and atomic number 77. A very hard, brittle, silvery-white transition metal of the platinum group, it is considered the second-densest naturally occurring metal (after osmium) with a density of ...
, or
osmium Osmium (from Greek grc, ὀσμή, osme, smell, label=none) is a chemical element with the symbol Os and atomic number 76. It is a hard, brittle, bluish-white transition metal in the platinum group that is found as a trace element in alloys, mos ...
. It is always found combined with other elements. Along with all elements having
atomic weight Relative atomic mass (symbol: ''A''; sometimes abbreviated RAM or r.a.m.), also known by the deprecated synonym atomic weight, is a dimensionless physical quantity defined as the ratio of the average mass of atoms of a chemical element in a giv ...
s higher than that of
iron Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in f ...
, it is only naturally formed in
supernova A supernova is a powerful and luminous explosion of a star. It has the plural form supernovae or supernovas, and is abbreviated SN or SNe. This transient astronomical event occurs during the last evolutionary stages of a massive star or when ...
explosions.


Uranium minerals

The primary uranium ore mineral is
uraninite Uraninite, formerly pitchblende, is a radioactive, uranium-rich mineral and ore with a chemical composition that is largely UO2 but because of oxidation typically contains variable proportions of U3O8. Radioactive decay of the uranium causes t ...
(UO2) (previously known as pitchblende). A range of other uranium minerals can be found in various deposits. These include
carnotite Carnotite is a potassium uranium vanadate radioactive mineral with chemical formula K2( U O2)2( VO4)2·3 H2O. The water content can vary and small amounts of calcium, barium, magnesium, iron, and sodium are often present. Occurrence Carnotite i ...
,
tyuyamunite Tyuyamunite (pronounced tuh-YOO-ya-moon-ite) is a very rare uranium mineral with formula Ca(UO2)2V2O8·(5-8)H2O. It is a member of the carnotite group. It is a bright, canary-yellow color because of its high uranium content. Also, because of tyuyam ...
,
torbernite Torbernite is a radioactive, hydrated green copper uranyl phosphate mineral, found in granites and other uranium-bearing deposits as a secondary mineral. Its name derives from the Swedish chemist Torbern Bergman (1735–1784), It is also known a ...
and
autunite Autunite (hydrated calcium uranyl phosphate), with formula Ca(UO2)2(PO4)2·10–12H2O, is a yellow-greenish fluorescent phosphate mineral with a hardness of 2–. Autunite crystallizes in the orthorhombic system and often occurs as tabular square ...
.Klein, Cornelis and Cornelius S. Hurlbut, Jr., ''Manual of Mineralogy,'' Wiley, 1985, 20th ed. pp. 307–308 The
davidite Davidite is a rare earth oxide mineral with chemical end members La and Ce. It exists in two forms: *Davidite-(La) discovered at Radium Hill mine, South Australia in 1906 and named by Douglas Mawson for Australian geologist Tannatt William Ed ...
- brannerite- absite type uranium titanates, and the
euxenite Euxenite, or euxenite-(Y) (the official mineralogical name), is a brownish black mineral with a metallic luster. Chemistry It contains calcium, niobium, tantalum, cerium, titanium, yttrium, and typically uranium and thorium, with some other meta ...
-
fergusonite Fergusonite is a mineral comprising a complex oxide of various rare-earth elements. The general chemical formula of fergusonite is (Y,REE)NbO4, where REE = rare-earth elements in solid solution with Y. Yttrium is usually dominant (the mineral in ...
-
samarskite Samarskite is a radioactive rare earth mineral series which includes samarskite-(Y), with the chemical formula and samarskite-(Yb), with the chemical formula . The formula for samarskite-(Y) is also given as . Samarskite crystallizes in the orth ...
group are other uranium minerals. A large variety of secondary uranium
mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. ( ...
s are known, many of which are brilliantly coloured and fluorescent. The most common are gummite (a mixture of minerals),
autunite Autunite (hydrated calcium uranyl phosphate), with formula Ca(UO2)2(PO4)2·10–12H2O, is a yellow-greenish fluorescent phosphate mineral with a hardness of 2–. Autunite crystallizes in the orthorhombic system and often occurs as tabular square ...
(with
calcium Calcium is a chemical element with the symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar to ...
),
saleeite Saleeite is a secondary uranium mineral occurring in the oxidized zones of uranium deposits, or as disseminations in carnotite-bearing sandstones. Its chemical formula is Mg(UO2)2(PO4)2·10(H2O). It was discovered in 1932 at Shinkolobwe, Katang ...
(
magnesium Magnesium is a chemical element with the symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 of the periodic ta ...
) and
torbernite Torbernite is a radioactive, hydrated green copper uranyl phosphate mineral, found in granites and other uranium-bearing deposits as a secondary mineral. Its name derives from the Swedish chemist Torbern Bergman (1735–1784), It is also known a ...
(with
copper Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkis ...
); and hydrated uranium silicates such as
coffinite Coffinite is a uranium-bearing silicate mineral with formula: U(SiO4)1−x(OH)4x. It occurs as black incrustations, dark to pale-brown in thin section. It has a grayish-black streak. It has a brittle to conchoidal fracture. The hardness of coffini ...
,
uranophane Uranophane ( Ca( U O2)2( SiO3O H)2·5 H2O), also known as uranotile, is a rare calcium uranium silicate hydrate mineral that forms from the oxidation of other uranium-bearing minerals. It has a yellow color and is radioactive. Alice Mary Weeks, a ...
(with calcium) and
sklodowskite Sklodowskite is a uranium mineral with the chemical formula: Mg(UO2)2(HSiO4)2·5H2O. It is a secondary mineral which contains magnesium and is a bright yellow colour, its crystal habit is acicular, but can form in other shapes. It has a Mohs ha ...
(magnesium).


Ore genesis

There are several themes of uranium ore deposit formation, which are caused by geological and chemical features of rocks and the element uranium. The basic themes of uranium
ore genesis Various theories of ore genesis explain how the various types of mineral deposits form within Earth's crust. Ore-genesis theories vary depending on the mineral or commodity examined. Ore-genesis theories generally involve three components: sour ...
are host mineralogy, reduction-oxidation potential, and
porosity Porosity or void fraction is a measure of the void (i.e. "empty") spaces in a material, and is a fraction of the volume of voids over the total volume, between 0 and 1, or as a percentage between 0% and 100%. Strictly speaking, some tests measure ...
. Uranium is a highly soluble, as well as a radioactive, heavy metal. It can be easily dissolved, transported and precipitated within
ground water Groundwater is the water present beneath Earth's surface in rock and soil pore spaces and in the fractures of rock formations. About 30 percent of all readily available freshwater in the world is groundwater. A unit of rock or an unconsolidated ...
s by subtle changes in oxidation conditions. Uranium also does not usually form very insoluble mineral species, which is a further factor in the wide variety of geological conditions and places in which uranium mineralization may accumulate. Uranium is an incompatible element within
magma Magma () is the molten or semi-molten natural material from which all igneous rocks are formed. Magma is found beneath the surface of the Earth, and evidence of magmatism has also been discovered on other terrestrial planets and some natural sa ...
s, and as such it tends to become accumulated within highly
fractionated Fractionation is a separation process in which a certain quantity of a mixture (of gases, solids, liquids, enzymes, or isotopes, or a suspension) is divided during a phase transition, into a number of smaller quantities ( fractions) in which t ...
and evolved
granite Granite () is a coarse-grained (phaneritic) intrusive igneous rock composed mostly of quartz, alkali feldspar, and plagioclase. It forms from magma with a high content of silica and alkali metal oxides that slowly cools and solidifies undergro ...
melts, particularly alkaline examples. These melts tend to become highly enriched in uranium,
thorium Thorium is a weakly radioactive metallic chemical element with the symbol Th and atomic number 90. Thorium is silvery and tarnishes black when it is exposed to air, forming thorium dioxide; it is moderately soft and malleable and has a high me ...
and
potassium Potassium is the chemical element with the symbol K (from Neo-Latin ''kalium'') and atomic number19. Potassium is a silvery-white metal that is soft enough to be cut with a knife with little force. Potassium metal reacts rapidly with atmosphe ...
, and may in turn create internal
pegmatite A pegmatite is an igneous rock showing a very coarse texture, with large interlocking crystals usually greater in size than and sometimes greater than . Most pegmatites are composed of quartz, feldspar, and mica, having a similar silicic com ...
s or
hydrothermal Hydrothermal circulation in its most general sense is the circulation of hot water (Ancient Greek ὕδωρ, ''water'',Liddell, H.G. & Scott, R. (1940). ''A Greek-English Lexicon. revised and augmented throughout by Sir Henry Stuart Jones. with th ...
systems into which uranium may dissolve.


Classification schemes


IAEA Classification (1996)

The
International Atomic Energy Agency The International Atomic Energy Agency (IAEA) is an intergovernmental organization that seeks to promote the peaceful use of nuclear energy and to inhibit its use for any military purpose, including nuclear weapons. It was established in 1957 ...
(IAEA) assigns uranium deposits to 15 main categories of deposit types, according to their geological setting and genesis of mineralization, arranged according to their approximate economic significance. # Unconformity-related deposits # Sandstone deposits # Quartz-pebble conglomerate deposits # Breccia complex deposits # Vein deposits # Intrusive deposits (Alaskites) # Phosphorite deposits # Collapse breccia pipe deposits # Volcanic deposits # Surficial deposits # Metasomatite deposits # Metamorphic deposits #
Lignite Lignite, often referred to as brown coal, is a soft, brown, combustible, sedimentary rock formed from naturally compressed peat. It has a carbon content around 25–35%, and is considered the lowest rank of coal due to its relatively low heat ...
# Black shale deposits # Other types of deposits


Alternate scheme

The IAEA classification scheme works well, but is far from ideal, as it does not consider that similar processes may form many deposit types, yet in a different geological setting. The following table groups the above deposit types based on their environment of deposition.


Deposit types (IAEA Classification)


Unconformity-related deposits

Unconformity-type uranium deposits host high grades relative to other uranium deposits and include some of the largest and richest deposits known. They occur in close proximity to
unconformities An unconformity is a buried erosional or non-depositional surface separating two rock masses or strata of different ages, indicating that sediment deposition was not continuous. In general, the older layer was exposed to erosion for an interval o ...
between relatively
quartz Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical form ...
-rich
sandstone Sandstone is a clastic sedimentary rock composed mainly of sand-sized (0.0625 to 2 mm) silicate grains. Sandstones comprise about 20–25% of all sedimentary rocks. Most sandstone is composed of quartz or feldspar (both silicates) ...
s comprising the basal portion of relatively undeformed
sedimentary basin Sedimentary basins are region-scale depressions of the Earth's crust where subsidence has occurred and a thick sequence of sediments have accumulated to form a large three-dimensional body of sedimentary rock. They form when long-term subsidence ...
s and deformed
metamorphic Metamorphic rocks arise from the transformation of existing rock to new types of rock in a process called metamorphism. The original rock (protolith) is subjected to temperatures greater than and, often, elevated pressure of or more, causin ...
basement rock In geology, basement and crystalline basement are crystalline rocks lying above the mantle and beneath all other rocks and sediments. They are sometimes exposed at the surface, but often they are buried under miles of rock and sediment. The baseme ...
s. These sedimentary basins are typically of
Proterozoic The Proterozoic () is a geological eon spanning the time interval from 2500 to 538.8million years ago. It is the most recent part of the Precambrian "supereon". It is also the longest eon of the Earth's geologic time scale, and it is subdivided ...
age, however some
Phanerozoic The Phanerozoic Eon is the current geologic eon in the geologic time scale, and the one during which abundant animal and plant life has existed. It covers 538.8 million years to the present, and it began with the Cambrian Period, when anima ...
examples exist. Phanerozoic unconformity-related deposits occur in Proterozoic metasediments below an unconformity at the base of overlying Phanerozoic sandstone. These deposits are small and low-grade ( Bertholene and
Aveyron Aveyron (; oc, Avairon; ) is a department in the region of Occitania, Southern France. It was named after the river Aveyron. Its inhabitants are known as ''Aveyronnais'' (masculine) or ''Aveyronnaises'' (feminine) in French. The inhabitants o ...
deposits, in France). The two most significant areas for this style of deposit are currently the
Athabasca Basin The Athabasca Basin is a region in the Canadian Shield of northern Saskatchewan and Alberta, Canada. It is best known as the world's leading source of high-grade uranium and currently supplies about 20% of the world's uranium. The basin i ...
in
Saskatchewan Saskatchewan ( ; ) is a Provinces and territories of Canada, province in Western Canada, western Canada, bordered on the west by Alberta, on the north by the Northwest Territories, on the east by Manitoba, to the northeast by Nunavut, and on t ...
, Canada, and the
McArthur Basin The McArthur Basin is a large intracratonic sedimentary basin in northern Australia, with an exposed area of about 180,000 km2. Most of it lies within the northeastern Northern Territory, but extends over the border into the state of Qu ...
in the
Northern Territory The Northern Territory (commonly abbreviated as NT; formally the Northern Territory of Australia) is an states and territories of Australia, Australian territory in the central and central northern regions of Australia. The Northern Territory ...
, Australia.


Athabasca Basin

The highest grade uranium deposits are found in the
Athabasca Basin The Athabasca Basin is a region in the Canadian Shield of northern Saskatchewan and Alberta, Canada. It is best known as the world's leading source of high-grade uranium and currently supplies about 20% of the world's uranium. The basin i ...
in Canada, including the two largest high grade uranium deposits in the world,
Cigar Lake The Cigar Lake Mine is a large high-grade underground uranium mine, located in the uranium-rich Athabasca Basin of northern Saskatchewan, Canada, at the south-west corner of Waterbury Lake. The deposit, discovered in 1981, is second in size of h ...
with 217 million pounds (99,000 t) U3O8 at an average grade of 18% and
McArthur River The McArthur River is a river in the Northern Territory of Australia which flows into the Gulf of Carpentaria at Port McArthur, opposite the Sir Edward Pellew Group of Islands. The river was named by Ludwig Leichhardt while he explored the are ...
with 324 million pounds (147,000 t) U3O8 at an average grade of 17%. These deposits occur below, across and immediately above the unconformity. Additionally, another high grade discovery is in the development stage at Patterson Lake (Triple R deposit) with an estimated mineral resource identified as; "Indicated Mineral Resources" estimated to total 2,291,000 tons at an average grade of 1.58% U3O8 containing 79,610,000 pounds of U3O8. "Inferred Mineral Resources" are estimated to total 901,000 tons at an average grade of 1.30% U3O8 containing 25,884,000 pounds of U3O8.


McArthur Basin

The deposits of the McArthur River basin in the East
Alligator Rivers Alligator Rivers is the name of an area in an Arnhem Land region of the Northern Territory of Australia, containing three rivers, the East, West, and South Alligator Rivers. It is regarded as one of the richest biological regions in Australia, ...
region of the
Northern Territory The Northern Territory (commonly abbreviated as NT; formally the Northern Territory of Australia) is an states and territories of Australia, Australian territory in the central and central northern regions of Australia. The Northern Territory ...
of Australia (including Jabiluka,
Ranger A Ranger is typically someone in a military/paramilitary or law enforcement role specializing in patrolling a given territory, called “ranging”. The term most often refers to: * Park ranger or forest ranger, a person charged with protecting and ...
, and
Nabarlek Nabarleks (''Petrogale concinna''), are a tiny species of macropod found in northern Australia. They are a shy and nocturnal animal that resides in rocky hollows and forages in the surrounding area. Their diet is grasses, sedges, and ferns foun ...
) are below the unconformity and are at the low-grade end of the unconformity deposit range but are still high grade compared to most uranium deposit types. There has been very little exploration in Australia to locate deeply concealed deposits lying above the unconformity similar to those in Canada. It is possible that very high grade deposits occur in the sandstones above the unconformity in the Alligator Rivers/
Arnhem Land Arnhem Land is a historical region of the Northern Territory of Australia, with the term still in use. It is located in the north-eastern corner of the territory and is around from the territory capital, Darwin. In 1623, Dutch East India Compan ...
area.


Sandstone deposits

Sandstone deposits are contained within medium to coarse-grained sandstones deposited in a continental fluvial or marginal marine
sedimentary environment In geology, depositional environment or sedimentary environment describes the combination of physical, chemical, and biological processes associated with the deposition of a particular type of sediment and, therefore, the rock types that will be ...
. Impermeable
shale Shale is a fine-grained, clastic sedimentary rock formed from mud that is a mix of flakes of clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2 Si2 O5( OH)4) and tiny fragments (silt-sized particles) of other minerals, especial ...
or
mudstone Mudstone, a type of mudrock, is a fine-grained sedimentary rock whose original constituents were clays or muds. Mudstone is distinguished from '' shale'' by its lack of fissility (parallel layering).Blatt, H., and R.J. Tracy, 1996, ''Petrology. ...
units are interbedded in the sedimentary sequence and often occur immediately above and below the mineralised horizon. Uranium is mobile under oxidising conditions and precipitates under reducing conditions, and thus the presence of a reducing environment is essential for the formation of uranium deposits in sandstone. Primary mineralization consists of pitchblende and coffinite, with
weathering Weathering is the deterioration of rocks, soils and minerals as well as wood and artificial materials through contact with water, atmospheric gases, and biological organisms. Weathering occurs ''in situ'' (on site, with little or no movement), ...
producing secondary mineralization. Sandstone deposits constitute about 18% of world uranium resources. Orebodies of this type are commonly low to medium grade (0.05–0.4% U3O8) and individual orebodies are small to medium in size (ranging up to a maximum of 50,000 t U3O8). Sandstone hosted uranium deposits are widespread globally and span a broad range of host rock ages. Some of the major provinces and production centers include: # the
Wyoming Wyoming () is a U.S. state, state in the Mountain states, Mountain West subregion of the Western United States. It is bordered by Montana to the north and northwest, South Dakota and Nebraska to the east, Idaho to the west, Utah to the south ...
basins # the Grants District of
New Mexico ) , population_demonym = New Mexican ( es, Neomexicano, Neomejicano, Nuevo Mexicano) , seat = Santa Fe , LargestCity = Albuquerque , LargestMetro = Tiguex , OfficialLang = None , Languages = English, Spanish ( New Mexican), Navajo, Ker ...
# deposits in
Central Europe Central Europe is an area of Europe between Western Europe and Eastern Europe, based on a common historical, social and cultural identity. The Thirty Years' War (1618–1648) between Catholicism and Protestantism significantly shaped the area' ...
and #
Kazakhstan Kazakhstan, officially the Republic of Kazakhstan, is a transcontinental country located mainly in Central Asia and partly in Eastern Europe. It borders Russia to the north and west, China to the east, Kyrgyzstan to the southeast, Uzbeki ...
Significant potential remains in most of these centers as well as in Australia,
Mongolia Mongolia; Mongolian script: , , ; lit. "Mongol Nation" or "State of Mongolia" () is a landlocked country in East Asia, bordered by Russia to the north and China to the south. It covers an area of , with a population of just 3.3 million, ...
,
South America South America is a continent entirely in the Western Hemisphere and mostly in the Southern Hemisphere, with a relatively small portion in the Northern Hemisphere at the northern tip of the continent. It can also be described as the southe ...
, and
Africa Africa is the world's second-largest and second-most populous continent, after Asia in both cases. At about 30.3 million km2 (11.7 million square miles) including adjacent islands, it covers 6% of Earth's total surface area ...
. This model type can be further subdivided into the following sub-types: * tabular * roll front * basal channel * structurally related Many deposits represent combinations of these types.


Tabular

Tabular deposits consist of irregular tabular or elongate lenticular zones of uranium mineralisation within selectively reduced sediments. The mineralised zones are oriented parallel to the direction of
groundwater Groundwater is the water present beneath Earth's surface in rock and soil pore spaces and in the fractures of rock formations. About 30 percent of all readily available freshwater in the world is groundwater. A unit of rock or an unconsolidate ...
flow, but on a small scale the ore zones may cut across sedimentary features of the host sandstone. Deposits of this nature commonly occur within palaeochannels cut in the underlying basement rocks. Tabular sandstone uranium deposits contains many of the highest grades of the sandstone class, however the average deposit size is very small.


Roll front

Roll-front uranium deposits are generally hosted within
permeable Permeability, permeable, and semipermeable may refer to: Chemistry *Semipermeable membrane, a membrane which will allow certain molecules or ions to pass through it by diffusion *Vascular permeability, the movement of fluids and molecules betwe ...
and
porous Porosity or void fraction is a measure of the void (i.e. "empty") spaces in a material, and is a fraction of the volume of voids over the total volume, between 0 and 1, or as a percentage between 0% and 100%. Strictly speaking, some tests measure ...
sandstone Sandstone is a clastic sedimentary rock composed mainly of sand-sized (0.0625 to 2 mm) silicate grains. Sandstones comprise about 20–25% of all sedimentary rocks. Most sandstone is composed of quartz or feldspar (both silicates) ...
s or conglomerates. The mechanism for deposit formation is dissolution of uranium from the formation or nearby
strata In geology and related fields, a stratum ( : strata) is a layer of rock or sediment characterized by certain lithologic properties or attributes that distinguish it from adjacent layers from which it is separated by visible surfaces known as ei ...
and the transport of this soluble uranium into the host unit. When the fluids change
redox Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate (chemistry), substrate change. Oxidation is the loss of Electron, electrons or an increase in the oxidation state, while reduction ...
state, generally in contact with
carbon Carbon () is a chemical element with the symbol C and atomic number 6. It is nonmetallic and tetravalent In chemistry, the valence (US spelling) or valency (British spelling) of an element is the measure of its combining capacity with o ...
-rich organic matter, uranium precipitates to form a 'front'. The Rollfront subtype deposits typically represent the largest of the sandstone-hosted uranium deposits and one of the largest uranium deposit types with an average of 21 million lb (9,500 t) U3O8. Included in this class are the Inkai deposit in
Kazakhstan Kazakhstan, officially the Republic of Kazakhstan, is a transcontinental country located mainly in Central Asia and partly in Eastern Europe. It borders Russia to the north and west, China to the east, Kyrgyzstan to the southeast, Uzbeki ...
and the Smith Ranch deposit in
Wyoming Wyoming () is a U.S. state, state in the Mountain states, Mountain West subregion of the Western United States. It is bordered by Montana to the north and northwest, South Dakota and Nebraska to the east, Idaho to the west, Utah to the south ...
. Probably more significant than their larger size, rollfront deposits have the advantage of being amenable to low cost
in-situ leach In-situ leaching (ISL), also called in-situ recovery (ISR) or solution mining, is a mining process used to recover minerals such as copper and uranium through boreholes drilled into a deposit, ''in situ''. In situ leach works by artificially disso ...
recovery. Typical characteristics: *roll-front deposits are crescent-shaped bodies that transect the host
lithology The lithology of a rock unit is a description of its physical characteristics visible at outcrop, in hand or core samples, or with low magnification microscopy. Physical characteristics include colour, texture, grain size, and composition. Lit ...
*typically the convex side points down the
hydraulic gradient Hydraulic head or piezometric head is a specific measurement of liquid pressure above a vertical datum., 410 pages. See pp. 43–44., 650 pages. See p. 22. It is usually measured as a liquid surface elevation, expressed in units of length, ...
. *the limbs or tails tend to be peneconcordant with the lithology. *most ore-bodies consist of several interconnected rolls. *individual roll-front deposits are quite small but collectively can extend for considerable distances.


Basal channel (palaeochannel)

Basal channel deposits are often grouped with tabular or rollfront deposits, depending on their unique characteristics. The model for formation of
palaeochannel A palaeochannel, also spelt paleochannel and also known as palaeovalley or palaeoriver, is a geological term describing a remnant of an inactive river or stream channel that has been filled or buried by younger sediment. The sediments that the ...
deposits is similar to that for roll-front deposits, above, except that the source of uranium may be in the watershed leading into a stream, or the bed load of the palaeochannel itself. This uranium is transported through the groundwaters and is deposited either at a reduced boundary, or in ephemeral drainage systems such as those in deserts of Namibia and Australia, it is deposited in calcretised evaporation sites or even in
saline lake A salt lake or saline lake is a landlocked body of water that has a concentration of salts (typically sodium chloride) and other dissolved minerals significantly higher than most lakes (often defined as at least three grams of salt per litre). ...
s as the ground water evaporates. Some particularly rich uranium deposits are formed in palaeochannels which are filled in the lower parts by
lignite Lignite, often referred to as brown coal, is a soft, brown, combustible, sedimentary rock formed from naturally compressed peat. It has a carbon content around 25–35%, and is considered the lowest rank of coal due to its relatively low heat ...
or brown
coal Coal is a combustible black or brownish-black sedimentary rock, formed as rock strata called coal seams. Coal is mostly carbon with variable amounts of other elements, chiefly hydrogen, sulfur, oxygen, and nitrogen. Coal is formed when dea ...
, which acts as a particularly efficient reductive trap for uranium. Sometimes, elements such as
scandium Scandium is a chemical element with the symbol Sc and atomic number 21. It is a silvery-white metallic d-block element. Historically, it has been classified as a rare-earth element, together with yttrium and the Lanthanides. It was discovered in ...
,
gold Gold is a chemical element with the symbol Au (from la, aurum) and atomic number 79. This makes it one of the higher atomic number elements that occur naturally. It is a bright, slightly orange-yellow, dense, soft, malleable, and ductile met ...
and
silver Silver is a chemical element with the Symbol (chemistry), symbol Ag (from the Latin ', derived from the Proto-Indo-European wikt:Reconstruction:Proto-Indo-European/h₂erǵ-, ''h₂erǵ'': "shiny" or "white") and atomic number 47. A soft, whi ...
may be concentrated within these lignite-hosted uranium deposits. The Frome Embayment in
South Australia South Australia (commonly abbreviated as SA) is a state in the southern central part of Australia. It covers some of the most arid parts of the country. With a total land area of , it is the fourth-largest of Australia's states and territories ...
hosts several deposits of this type including
Honeymoon A honeymoon is a vacation taken by newlyweds immediately after their wedding, to celebrate their marriage. Today, honeymoons are often celebrated in destinations considered exotic or romantic. In a similar context, it may also refer to the phase ...
, Oban,
Beverley Beverley is a market town, market and minster (church), minster town and a civil parishes in England, civil parish in the East Riding of Yorkshire, England, of which it is the county town. The town centre is located south-east of York's centre ...
and our-Mile (which is the largest deposit of this class). These deposits are hosted in palaeochannels filled with Cainozoic sediments and sourced their uranium from uranium-rich Palaeo- to Mesoproterozoic rocks of the
Mount Painter Mount is often used as part of the name of specific mountains, e.g. Mount Everest. Mount or Mounts may also refer to: Places * Mount, Cornwall, a village in Warleggan parish, England * Mount, Perranzabuloe, a hamlet in Perranzabuloe parish, ...
Inlier and the Olary Domain of the Curnamona Province.


Structurally related

Tectonic-lithologic controlled uranium deposits occur in sandstones adjacent to a permeable
fault zone In geology, a fault is a planar fracture or discontinuity in a volume of rock across which there has been significant displacement as a result of rock-mass movements. Large faults within Earth's crust result from the action of plate tectonic ...
which cuts the sandstone/mudstone sequence. Mineralisation forms tongue-shaped ore zones along the permeable sandstone layers adjacent to the fault. Often there are a number of mineralised zones 'stacked' vertically on top of each other within sandstone units adjacent to the fault zone.


Quartz-pebble conglomerate deposits

Quartz pebble conglomerate hosted uranium deposits are of historical significance as the major source of primary production for several decades after
World War II World War II or the Second World War, often abbreviated as WWII or WW2, was a world war that lasted from 1939 to 1945. It involved the vast majority of the world's countries—including all of the great powers—forming two opposin ...
. This type of deposit has been identified in eight localities around the world, however the most significant deposits are in the
Huronian Supergroup The Huronian Supergroup is a Proterozoic assemblage of geologic formations of the Superior craton of the Canadian Shield in Ontario and Quebec. It extends from west of the city of Sault Ste. Marie in the west to the Ontario-Quebec border to the ...
in
Ontario Ontario ( ; ) is one of the thirteen provinces and territories of Canada.Ontario is located in the geographic eastern half of Canada, but it has historically and politically been considered to be part of Central Canada. Located in Central Ca ...
, Canada and in the Witwatersrand Supergroup of
South Africa South Africa, officially the Republic of South Africa (RSA), is the southernmost country in Africa. It is bounded to the south by of coastline that stretch along the South Atlantic and Indian Oceans; to the north by the neighbouring countri ...
. These deposits make up approximately 13% of the world's uranium resources. Two main sub-types have been identified: *
Elliot Lake Elliot Lake is a city in Algoma District, Ontario, Canada. It is north of Lake Huron, midway between the cities of Sudbury and Sault Ste. Marie in the Northern Ontario region. Once dubbed the "uranium capital of the world," Elliot Lake has since ...
*
Witwatersrand The Witwatersrand () (locally the Rand or, less commonly, the Reef) is a , north-facing scarp in South Africa. It consists of a hard, erosion-resistant quartzite metamorphic rock, over which several north-flowing rivers form waterfalls, which ...
Quartz pebble conglomerate hosted uranium deposits formed from the transport and deposition of uraninite in a fluvial sedimentary environment and are defined as stratiform and stratabound paleoplacer deposits. Host rocks are typically submature to supermature, polymictic conglomerates and sandstones deposited in
alluvial fan An alluvial fan is an accumulation of sediments that fans outwards from a concentrated source of sediments, such as a narrow canyon emerging from an escarpment. They are characteristic of mountainous terrain in arid to semiarid climates, but a ...
and
braided stream A braided river, or braided channel, consists of a network of river channels separated by small, often temporary, islands called braid bars or, in English usage, ''aits'' or ''eyots''. Braided streams tend to occur in rivers with high sediment lo ...
environments. The host conglomerates of the Huronian deposits in Canada are situated at the base of the sequence, whereas the mineralized horizons in the Witwatersand are arguably along tectonized intraformational unconformities. Uranium minerals were derived from uraniferous pegmatites in the sediment source areas. These deposits are restricted to the
Archean The Archean Eon ( , also spelled Archaean or Archæan) is the second of four geologic eons of Earth's history, representing the time from . The Archean was preceded by the Hadean Eon and followed by the Proterozoic. The Earth Earth ...
and early
Paleoproterozoic The Paleoproterozoic Era (;, also spelled Palaeoproterozoic), spanning the time period from (2.5–1.6  Ga), is the first of the three sub-divisions (eras) of the Proterozoic Eon. The Paleoproterozoic is also the longest era of the Earth's ...
and do not occur in sediments younger than about 2,200 million years when oxygen levels in the atmosphere reached a critical level, making simple uranium oxides no longer stable in near-surface environments. Quartz pebble conglomerate uranium deposits are typically low grade but characterized by high tonnages. The Huronian deposits in Canada generally contain higher grades (0.15% U3O8) and greater resources (as shown by the Denison and Quirke mines), however some of the South African gold deposits also contain sizeable low grade (0.01% U3O8) uranium resources.


Witwatersrand sub-type

In the
Witwatersrand The Witwatersrand () (locally the Rand or, less commonly, the Reef) is a , north-facing scarp in South Africa. It consists of a hard, erosion-resistant quartzite metamorphic rock, over which several north-flowing rivers form waterfalls, which ...
deposits ores are found along unconformities, shale and siltstone beds, and carbonaceous seams. The West Rand Group of sediments tend to host the most uranium within the Witwatersrand Supergroup. The uranium rich Dominion Reef is located at the base of the West Rand Supergroup. The Vaal Reef is the most uranium rich reef of the Central Rand Group of sediments. Structural controls on the regional scale are normal faults while on the deposit scale are bedding parallel shears and thrusts. Textural evidence indicates that the uranium and gold have been remobilized to their current sites; however the debate continues if the original deposition was detrital or was entirely hydrothermal, or alternatively related to high grade
diagenesis Diagenesis () is the process that describes physical and chemical changes in sediments first caused by water-rock interactions, microbial activity, and compaction after their deposition. Increased pressure and temperature only start to play a ...
. Uranium minerals in the Witwatersrand deposits are typically uraninite with lesser uranothorite, brannerite, and coffinite. The uranium is especially concentrated along thin carbonaceous seams or carbon leaders. Strong regional scale alteration consists of
pyrophyllite Pyrophyllite is a phyllosilicate mineral composed of aluminium silicate hydroxide: Al2Si4O10(OH)2. It occurs in two forms (habits): crystalline folia and compact masses; distinct crystals are not known. The folia have a pronounced pearly luster ...
,
chloritoid Chloritoid is a silicate mineral of Metamorphism, metamorphic origin. It is an iron magnesium manganese alumino-silicate hydroxide with formula . It occurs as greenish grey to black platy micaceous crystals and foliation (geology), foliated masses. ...
,
muscovite Muscovite (also known as common mica, isinglass, or potash mica) is a hydrated phyllosilicate mineral of aluminium and potassium with formula K Al2(Al Si3 O10)( F,O H)2, or ( KF)2( Al2O3)3( SiO2)6( H2O). It has a highly perfect basal cleavage ...
,
chlorite The chlorite ion, or chlorine dioxide anion, is the halite with the chemical formula of . A chlorite (compound) is a compound that contains this group, with chlorine in the oxidation state of +3. Chlorites are also known as salts of chlorous ac ...
, quartz,
rutile Rutile is an oxide mineral composed of titanium dioxide (TiO2), the most common natural form of TiO2. Rarer Polymorphism (materials science), polymorphs of TiO2 are known, including anatase, akaogiite, and brookite. Rutile has one of the highest ...
, and
pyrite The mineral pyrite (), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula Iron, FeSulfur, S2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral. Pyrite's metallic Luster (mineralogy), lust ...
. The main elements associated with the uranium are gold and silver. Gold contents are much higher than in the Elliot Lake type with U:Au ranging between 5:1 and 500:1, which indicates that these gold-rich ores are essentially very low grade uranium deposits with gold.


Elliot Lake sub-type

Sedimentological controls on the Huronian deposits of the
Elliot Lake Elliot Lake is a city in Algoma District, Ontario, Canada. It is north of Lake Huron, midway between the cities of Sudbury and Sault Ste. Marie in the Northern Ontario region. Once dubbed the "uranium capital of the world," Elliot Lake has since ...
district appear to be much stronger than in the Witwatersrand deposits. Ores grade from uranium through
thorium Thorium is a weakly radioactive metallic chemical element with the symbol Th and atomic number 90. Thorium is silvery and tarnishes black when it is exposed to air, forming thorium dioxide; it is moderately soft and malleable and has a high me ...
to
titanium Titanium is a chemical element with the symbol Ti and atomic number 22. Found in nature only as an oxide, it can be reduced to produce a lustrous transition metal with a silver color, low density, and high strength, resistant to corrosion in ...
-rich with decreasing pebble size and increasing distance from their source. While evidence of post-
diagenetic Diagenesis () is the process that describes physical and chemical changes in sediments first caused by water-rock interactions, microbial activity, and compaction after their deposition. Increased pressure and temperature only start to play a ...
remobilization has been identified, these effects appear far subordinate to the sedimentological controls. Ore consists of
uraninite Uraninite, formerly pitchblende, is a radioactive, uranium-rich mineral and ore with a chemical composition that is largely UO2 but because of oxidation typically contains variable proportions of U3O8. Radioactive decay of the uranium causes t ...
with lesser brannerite and thucholite. These occur in thin beds exhibiting
graded bedding In geology, a graded bed is one characterized by a systematic change in grain or clast size from one side of the bed to the other. Most commonly this takes the form of normal grading, with coarser sediments at the base, which grade upward into pro ...
reminiscent of placer sorting. Alteration is nonexistent to very weak at best and the weak chlorite and
sericite Sericite is the name given to very fine, ragged grains and aggregates of white (colourless) micas, typically made of muscovite, illite, or paragonite. Sericite is produced by the alteration of orthoclase or plagioclase feldspars in areas that hav ...
are believed to be mainly post-ore effects. Other post-depositional alteration includes
pyritization Permineralization is a process of fossilization of bones and tissues in which mineral deposits form internal casts of organisms. Carried by water, these minerals fill the spaces within organic tissue. Because of the nature of the casts, perminera ...
,
silicification In geology, silicification is a petrification process in which silica-rich fluids seep into the voids of Earth materials, e.g., rocks, wood, bones, shells, and replace the original materials with silica (SiO2). Silica is a naturally existing and ...
, and alteration of titanium minerals. The most prominent geochemical associations with the uranium are thorium and titanium. This schematic model represents the original depositional setting. The Huronian underwent mild post-depositional folding during the
Penokean orogeny The Penokean orogeny was a mountain-building episode that occurred in the early Proterozoic about 1.86 to 1.83 billion years ago, in the area of Lake Superior, North America. The core of this orogeny, the Churchill Craton, is composed of terranes ...
around 1.9 billion years. The main regional structure is the Quirke
syncline In structural geology, a syncline is a fold with younger layers closer to the center of the structure, whereas an anticline is the inverse of a syncline. A synclinorium (plural synclinoriums or synclinoria) is a large syncline with superimpose ...
along the margins of which the majority of the known deposits are situated. Due to this structural overprint ore bodies range from subhorizontal to steeply dipping.


Breccia complex deposits (IOCG-U)

Only one iron-ore-copper-gold (IOCG) deposit of this type is known to contain economically significant quantities of uranium. Olympic Dam in
South Australia South Australia (commonly abbreviated as SA) is a state in the southern central part of Australia. It covers some of the most arid parts of the country. With a total land area of , it is the fourth-largest of Australia's states and territories ...
is the world's largest resource of low-grade uranium and accounts for about 66% of Australia's reserves plus resources. Uranium occurs with copper, gold, silver, and
rare earth elements The rare-earth elements (REE), also called the rare-earth metals or (in context) rare-earth oxides or sometimes the lanthanides (yttrium and scandium are usually included as rare earths), are a set of 17 nearly-indistinguishable lustrous silve ...
(REE) in a large
hematite Hematite (), also spelled as haematite, is a common iron oxide compound with the formula, Fe2O3 and is widely found in rocks and soils. Hematite crystals belong to the rhombohedral lattice system which is designated the alpha polymorph of . ...
-rich
granite Granite () is a coarse-grained (phaneritic) intrusive igneous rock composed mostly of quartz, alkali feldspar, and plagioclase. It forms from magma with a high content of silica and alkali metal oxides that slowly cools and solidifies undergro ...
breccia Breccia () is a rock composed of large angular broken fragments of minerals or rocks cemented together by a fine-grained matrix. The word has its origins in the Italian language, in which it means "rubble". A breccia may have a variety of di ...
complex in the
Gawler Craton The Gawler Craton covers approximately 440,000 square kilometres of central South Australia. Its Precambrian crystalline basement crustal block was cratonised ca. 1550–1450 Ma. Prior to 1550 Ma the craton comprised a number of active Proter ...
overlain by approximately 300 metres of flat-lying sedimentary rocks of the Stuart Shelf geological province. Another example for the Breccia type is the Mount Gee area in the Mount Painter Inlier, South Australia. Uranium mineralised quartz-hematite breccia is related to Palaeoproterozoic granites with uranium contents of up to 100 ppm. Hydrothermal processes at about 300 million years ago remobilised uranium from these granites and enriched them in the quartz-hematite breccias. The breccias in the area host a low grade resource of about 31,400 t U3O8 at 615 ppm in average.


Vein deposits

Vein Veins are blood vessels in humans and most other animals that carry blood towards the heart. Most veins carry deoxygenated blood from the tissues back to the heart; exceptions are the pulmonary and umbilical veins, both of which carry oxygenated b ...
deposits play a special role in the history of uranium: the term "pitchblende" ("Pechblende") originates from German vein deposits when they were mined for silver in the 16th century. F.E. Brückmann made the first mineralogical description of the mineral in 1727 and the vein deposit Jachymov in the
Czech Republic The Czech Republic, or simply Czechia, is a landlocked country in Central Europe. Historically known as Bohemia, it is bordered by Austria to the south, Germany to the west, Poland to the northeast, and Slovakia to the southeast. The ...
became the type locality for uraninite. In 1789 the German chemist M. H. Klaproth discovered the element of uranium in a sample of pitchblende from the Johanngeorgenstadt vein deposit. The first industrial production of uranium was made from the Jachymov deposit and
Marie Marie may refer to: People Name * Marie (given name) * Marie (Japanese given name) * Marie (murder victim), girl who was killed in Florida after being pushed in front of a moving vehicle in 1973 * Marie (died 1759), an enslaved Cree person in Tr ...
and
Pierre Curie Pierre Curie ( , ; 15 May 1859 – 19 April 1906) was a French physicist, a pioneer in crystallography, magnetism, piezoelectricity, and radioactivity. In 1903, he received the Nobel Prize in Physics with his wife, Marie Curie, and Henri Becqu ...
used the tailings of the mine for their discovery of
polonium Polonium is a chemical element with the symbol Po and atomic number 84. Polonium is a chalcogen. A rare and highly radioactive metal with no stable isotopes, polonium is chemically similar to selenium and tellurium, though its metallic character ...
and
radium Radium is a chemical element with the symbol Ra and atomic number 88. It is the sixth element in group 2 of the periodic table, also known as the alkaline earth metals. Pure radium is silvery-white, but it readily reacts with nitrogen (rather t ...
. Vein deposits consist of uranium minerals filling in cavities such as cracks, veins, fractures, breccias, and stockworks associated with steeply dipping fault systems. There are three major subtypes of vein style uranium mineralisation: *intragranitic veins (Central Massif, France) *veins in metasedimentary rocks in exocontacts of granites **quartz-carbonate uranium veins (Erzgebirge Mts, Germany/Czech Republic; Bohemian Massif, Czech Republic) **uranium-polymetal veins (Erzgebirge Mts, Germany/Czech Republic; Saskatchewan, Canada) *mineralised fault and shear zones (central Africa; Bohemian Massif, Czech Republic) Intragranitic veins form in the late phase of magmatic activity when hot fluids derived from the magma precipitate uranium on cracks within the newly formed granite. Such mineralisation contributed much to the uranium production of France. Veins hosted by metasedimentary units in the exocontact of granites are the most important sources of uranium mineralisation in central Europe including the world class deposits Schneeberg-Schlema-Alberoda in Germany (96,000 t uranium content) as well as Pribram (50,000 t uranium content) and Jachymov (~10,000 t uranium content) in the Czech Republic. Also they are closely related to the granites, the mineralization is much younger with a time gap between granite formation and mineralisation of 20 million years. The initial uranium mineralisation consists of
quartz Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical form ...
,
carbonate A carbonate is a salt of carbonic acid (H2CO3), characterized by the presence of the carbonate ion, a polyatomic ion with the formula . The word ''carbonate'' may also refer to a carbonate ester, an organic compound containing the carbonate g ...
,
fluorite Fluorite (also called fluorspar) is the mineral form of calcium fluoride, CaF2. It belongs to the halide minerals. It crystallizes in isometric cubic habit, although octahedral and more complex isometric forms are not uncommon. The Mohs sca ...
and
pitchblende Uraninite, formerly pitchblende, is a radioactive, uranium-rich mineral and ore with a chemical composition that is largely UO2 but because of oxidation typically contains variable proportions of U3O8. Radioactive decay of the uranium causes th ...
. Remobilisation of uranium occurred at later stages producing polymetal veins containing
silver Silver is a chemical element with the Symbol (chemistry), symbol Ag (from the Latin ', derived from the Proto-Indo-European wikt:Reconstruction:Proto-Indo-European/h₂erǵ-, ''h₂erǵ'': "shiny" or "white") and atomic number 47. A soft, whi ...
,
cobalt Cobalt is a chemical element with the symbol Co and atomic number 27. As with nickel, cobalt is found in the Earth's crust only in a chemically combined form, save for small deposits found in alloys of natural meteoric iron. The free element, pr ...
,
nickel Nickel is a chemical element with symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel is a hard and ductile transition metal. Pure nickel is chemically reactive but large pieces are slow to ...
,
arsenic Arsenic is a chemical element with the symbol As and atomic number 33. Arsenic occurs in many minerals, usually in combination with sulfur and metals, but also as a pure elemental crystal. Arsenic is a metalloid. It has various allotropes, but ...
and other elements. Large deposits of this type can contain more than 1,000 individual mineralized veins. However, only 5 to 12% of the vein areas carry mineralization and although massive lenses of pitchblende can occur, the overall ore grade is only about 0.1% uranium. The
Bohemian Massif The Bohemian Massif ( cs, Česká vysočina or ''Český masiv'', german: Böhmische Masse or ''Böhmisches Massiv'') is a geomorphological province in Central Europe. It is a large massif stretching over most of the Czech Republic, eastern Germ ...
also contains shear zone hosted uranium deposits with the most important one being Rozna-Olsi in Moravia northwest of
Brno Brno ( , ; german: Brünn ) is a city in the South Moravian Region of the Czech Republic. Located at the confluence of the Svitava and Svratka rivers, Brno has about 380,000 inhabitants, making it the second-largest city in the Czech Republic ...
. Rozna is currently the only operating uranium mine in central Europe with a total uranium content of 23,000 t and an average grade of 0.24%. The formation of this mineralisation occurred in several stages. After the
Variscan Orogeny The Variscan or Hercynian orogeny was a geologic mountain-building event caused by Late Paleozoic continental collision between Euramerica (Laurussia) and Gondwana to form the supercontinent of Pangaea. Nomenclature The name ''Variscan'', comes f ...
, extension took place and hydrothermal fluids overprinted fine grained materials in shear zones with a sulfide-chlorite alteration. Fluids from the overlying sediments entered the basement mobilising uranium and while uprising on the shear zone, the chlorite-pyrite material caused precipitation of uranium minerals in form of coffinite, pitchblende and U-Zr-silicates. This initial mineralisation event took place at about 277 million to 264 million years. During the Triassic a further mineralisation event took place relocating uranium into quartz-carbonate-uranium veins. Another example of this mineralisation style is the Shinkolobwe deposit in Congo, Africa, containing about 30,000 t of uranium.


Intrusive associated deposits

Intrusive deposits make up a large proportion of the world's uranium resources. Included in this type are those associated with intrusive rocks including
alaskite Leucogranite is a light-colored, granitic, igneous rock containing almost no dark minerals. Alaskite is a synonym.granite Granite () is a coarse-grained (phaneritic) intrusive igneous rock composed mostly of quartz, alkali feldspar, and plagioclase. It forms from magma with a high content of silica and alkali metal oxides that slowly cools and solidifies undergro ...
,
pegmatite A pegmatite is an igneous rock showing a very coarse texture, with large interlocking crystals usually greater in size than and sometimes greater than . Most pegmatites are composed of quartz, feldspar, and mica, having a similar silicic com ...
and
monzonite Monzonite is an igneous intrusive rock, formed by slow cooling of underground magma that has a moderate silica content and is enriched in alkali metal oxides. Monzonite is composed mostly of plagioclase and alkali feldspar. Syenodiorite is an o ...
s. Major world deposits include Rossing (
Namibia Namibia (, ), officially the Republic of Namibia, is a country in Southern Africa. Its western border is the Atlantic Ocean. It shares land borders with Zambia and Angola to the north, Botswana to the east and South Africa to the south and ea ...
),
Ilimaussaq intrusive complex The Ilimaussaq intrusive complex is a large alkalic layered intrusion located on the southwest coast of Greenland. It is Mesoproterozoic in age, about 1.16 Ga. It is the type locality of agpaitic nepheline syenite and hosts a variety of unusual ...
(
Greenland Greenland ( kl, Kalaallit Nunaat, ; da, Grønland, ) is an island country in North America that is part of the Kingdom of Denmark. It is located between the Arctic and Atlantic oceans, east of the Canadian Arctic Archipelago. Greenland is t ...
) and
Palabora Palabora Mining Company Limited (founded August 1956) is a publicly traded mining company headquartered in Phalaborwa, Limpopo province, South Africa. The company operates a single cluster of open-pit and underground mines producing mainly copp ...
(
South Africa South Africa, officially the Republic of South Africa (RSA), is the southernmost country in Africa. It is bounded to the south by of coastline that stretch along the South Atlantic and Indian Oceans; to the north by the neighbouring countri ...
).


Phosphorite deposits

Marine sedimentary phosphorite deposits can contain low grade concentrations of uranium, up to 0.01–0.015% U3O8, within
fluorite Fluorite (also called fluorspar) is the mineral form of calcium fluoride, CaF2. It belongs to the halide minerals. It crystallizes in isometric cubic habit, although octahedral and more complex isometric forms are not uncommon. The Mohs sca ...
or
apatite Apatite is a group of phosphate minerals, usually hydroxyapatite, fluorapatite and chlorapatite, with high concentrations of OH−, F− and Cl− ions, respectively, in the crystal. The formula of the admixture of the three most common e ...
. These deposits can have a significant tonnage. Very large phosphorite deposits occur in
Florida Florida is a state located in the Southeastern region of the United States. Florida is bordered to the west by the Gulf of Mexico, to the northwest by Alabama, to the north by Georgia, to the east by the Bahamas and Atlantic Ocean, and to ...
and
Idaho Idaho ( ) is a state in the Pacific Northwest region of the Western United States. To the north, it shares a small portion of the Canada–United States border with the province of British Columbia. It borders the states of Montana and Wyom ...
in the United States,
Morocco Morocco (),, ) officially the Kingdom of Morocco, is the westernmost country in the Maghreb region of North Africa. It overlooks the Mediterranean Sea to the north and the Atlantic Ocean to the west, and has land borders with Algeria to ...
, and some middle eastern countries.


Collapse breccia pipe deposits

Collapse
breccia pipe A breccia pipe, also referred to as a chimney, is a mass of breccia (rock composed of broken fragments of minerals or rock cemented together by a fine-grained matrix), often in an irregular and cylindrical shape. Characteristics When exposed a ...
deposits occur within vertical, circular solution collapse structures, formed by the
dissolution Dissolution may refer to: Arts and entertainment Books * ''Dissolution'' (''Forgotten Realms'' novel), a 2002 fantasy novel by Richard Lee Byers * ''Dissolution'' (Sansom novel), a 2003 historical novel by C. J. Sansom Music * Dissolution, in mu ...
of
limestone Limestone ( calcium carbonate ) is a type of carbonate sedimentary rock which is the main source of the material lime. It is composed mostly of the minerals calcite and aragonite, which are different crystal forms of . Limestone forms whe ...
by groundwater. Pipes are typically filled with down-dropped coarse fragments of limestone and overlying sediments and can be from wide and up to deep. Primary ore minerals are
uraninite Uraninite, formerly pitchblende, is a radioactive, uranium-rich mineral and ore with a chemical composition that is largely UO2 but because of oxidation typically contains variable proportions of U3O8. Radioactive decay of the uranium causes t ...
and
pitchblende Uraninite, formerly pitchblende, is a radioactive, uranium-rich mineral and ore with a chemical composition that is largely UO2 but because of oxidation typically contains variable proportions of U3O8. Radioactive decay of the uranium causes th ...
, which occur as cavity fills and coatings on
quartz Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical form ...
grains within permeable sandstone breccias within the pipe. Resources within individual pipes can range up to 2500
tonnes The tonne ( or ; symbol: t) is a unit of mass equal to 1000 kilograms. It is a non-SI unit accepted for use with SI. It is also referred to as a metric ton to distinguish it from the non-metric units of the short ton ( United States ...
U3O8 at an average grade of between 0.3 and 1.0% U3O8. The best known examples of this deposit type are in the
Arizona breccia pipe uranium mineralization During the late 1970s and through the 1980s, Mohave County, Arizona, Mohave and Coconino County, Arizona, immediately north and south of the Grand Canyon and west of the Navajo Indian Reservation were explored for Arizona breccia pipe uranium minera ...
in the US, where several of these deposits have been mined.


Volcanic deposits

Volcanic deposits occur in
felsic In geology, felsic is a modifier describing igneous rocks that are relatively rich in elements that form feldspar and quartz.Marshak, Stephen, 2009, ''Essentials of Geology,'' W. W. Norton & Company, 3rd ed. It is contrasted with mafic rocks, whi ...
to intermediate
volcanic A volcano is a rupture in the crust of a planetary-mass object, such as Earth, that allows hot lava, volcanic ash, and gases to escape from a magma chamber below the surface. On Earth, volcanoes are most often found where tectonic plates a ...
to volcaniclastic rocks and associated
caldera A caldera ( ) is a large cauldron-like hollow that forms shortly after the emptying of a magma chamber in a volcano eruption. When large volumes of magma are erupted over a short time, structural support for the rock above the magma chamber is ...
subsidence structures, comagmatic intrusions, ring dykes and
diatreme A diatreme, sometimes known as a maar-diatreme volcano, is a volcanic pipe formed by a gaseous explosion. When magma Magma () is the molten or semi-molten natural material from which all igneous rocks are formed. Magma is found beneath the ...
s. Mineralization occurs either as structurally controlled veins and breccias discordant to the stratigraphy and less commonly as stratabound mineralization either in extrusive rocks or permeable
sedimentary facies In geology, a facies ( , ; same pronunciation and spelling in the plural) is a body of rock with specified characteristics, which can be any observable attribute of rocks (such as their overall appearance, composition, or condition of formatio ...
. Mineralization may be primary, that is magmatic-related or as secondary mineralization due to leaching, remobilization and re-precipitation. The principal uranium mineral in volcanic deposits is pitchblende, which is usually associated with
molybdenite Molybdenite is a mineral of molybdenum disulfide, Mo S2. Similar in appearance and feel to graphite, molybdenite has a lubricating effect that is a consequence of its layered structure. The atomic structure consists of a sheet of molybdenum ato ...
and minor amounts of
lead Lead is a chemical element with the symbol Pb (from the Latin ) and atomic number 82. It is a heavy metal that is denser than most common materials. Lead is soft and malleable, and also has a relatively low melting point. When freshly cu ...
, tin and
tungsten Tungsten, or wolfram, is a chemical element with the symbol W and atomic number 74. Tungsten is a rare metal found naturally on Earth almost exclusively as compounds with other elements. It was identified as a new element in 1781 and first isolat ...
mineralization. Volcanic hosted uranium deposits occur in host rocks spanning the Precambrian to the Cenozoic but because of the shallow levels at which they form, preservation favors younger age deposits. Some of the more important deposits or districts are Krasnokamensk, Zabaykalsky Krai, Streltsovskoye, Russia; Dornod Province, Dornod, Mongolia; and McDermitt, Nevada. The average deposit size is rather small with grades of 0.02% to 0.2% U3O8. These deposits make up only a small proportion of the world's uranium resources. The only volcanic hosted deposits currently being exploited are those of the Streltsovkoye district of eastern Siberia. This is in fact not a single stand-alone deposit, but 18 individual deposits occurring within the Streltsovsk caldera complex. Nevertheless, the average size of these deposits is far greater than the average volcanic type.


Surficial deposits (calcretes)

Surficial deposits are broadly defined as Tertiary to Holocene, Recent near-surface uranium concentrations in sediments or soils. Mineralization in calcrete (calcium carbonate, calcium and magnesium carbonates) are the largest of the surficial deposits. They are interbedded with Tertiary sand and clay, which are usually cemented by calcium and magnesium carbonates. Surficial deposits also occur in peat bogs, karst caverns and soils. Surficial deposits account for approximately 4% of world uranium resources. The Yeelirrie uranium project, Yeelirrie deposit is by far the world's largest surficial deposit, averaging 0.15% U3O8. Paladin Energy, Langer Heinrich in
Namibia Namibia (, ), officially the Republic of Namibia, is a country in Southern Africa. Its western border is the Atlantic Ocean. It shares land borders with Zambia and Angola to the north, Botswana to the east and South Africa to the south and ea ...
is another significant surficial deposit.


Metasomatite deposits

Metasomatite deposits consist of disseminated uranium minerals within structurally deformed rocks that have been affected by intense sodium metasomatism. Ore minerals are
uraninite Uraninite, formerly pitchblende, is a radioactive, uranium-rich mineral and ore with a chemical composition that is largely UO2 but because of oxidation typically contains variable proportions of U3O8. Radioactive decay of the uranium causes t ...
and brannerite. Th/U ratio in the ores is mostly less than 0.1. Metasomatites are typically small in size and generally contain less than 1000 t U3O8. Giant (up to 100 thousands t U) U deposits in sodium metasomatites (albitites) are known in Central Ukraine and Brazil. Two subtypes are defined based on host lithologies: *''metasomatized granite''; ex. Ross Adams deposit in Alaska, United States, Novokostantynivka deposit in Kropyvnytskyi, Kirovogradska oblast, Ukraine. *''metasomatised metasediment''; ex. Zhovta Richka and Pervomayske deposits in Dnipropetrovska oblast, Ukraine and Valhalla deposit in northwestern Queensland, Australia.


Metamorphic deposits

Metamorphic deposits those that occur in metasediments or metavolcanic rocks where there is no direct evidence for mineralization post-dating metamorphism. These deposits were formed during regional metamorphism of uranium bearing or mineralized sediments or volcanic precursors. The most prominent deposits of this type are Mary Kathleen, Queensland, Australia, and Forstau, Austria.


Lignite

Lignite deposits (soft brown coal) can contain significant uranium mineralization. Mineralization can also be found in clay and sandstone immediately adjacent to lignite deposits. Uranium has been adsorbed onto carbonaceous matter and as a result no discrete uranium minerals have formed. Deposits of this type are known from the Serres Basin, Greece, Serres Basin, in Greece, and in Uranium mining in the United States#North Dakota, North and South Dakota in the USA. The uranium content in these deposits is very low, on average less than 0.005% U3O8, and does not currently warrant commercial extraction.


Black shale deposits

Black shale mineralisations are large low-grade resources of uranium. They form in submarine environments under oxygen-free conditions. Organic matter in clay-rich sediments will not be converted to CO2 by biological processes in this environment and it can reduce and immobilise uranium dissolved in seawater. Average uranium grades of black shales are 50 to 250 ppm. The largest explored resource is Ranstad in Sweden containing 254,000 t of uranium. However, there are estimates for black shales in the US and Brazil assuming a uranium content of over 1 million tonnes, but at grades below 100 ppm uranium. The Chattanooga Shale in the southeastern USA for example is estimated to contain 4 to 5 million tonnes at an average grade of 54 ppm. Because of their low grades, no black shale deposit ever produced significant amounts of uranium with one exception: the SDAG Wismut#Ronneburg (Object 90), Ronneburg deposit in eastern Thuringia, Germany. The Ordovician and Silurian black shales at Ronneburg have a background uranium content of 40 to 60 ppm. However, hydrothermal and Supergene (geology), supergene processes caused remobilsation and enrichment of the uranium. The production between 1950 and 1990 was about 100,000 t of uranium at average grades of 700 to 1,000 ppm. Measured and inferred resources containing 87,000 t uranium at grades between 200 and 900 ppm are left.


Other types of deposits

*There are also uranium deposits, of other types, in the Jurassic Todilto Limestone in the Grants District, New Mexico, Grants District,
New Mexico ) , population_demonym = New Mexican ( es, Neomexicano, Neomejicano, Nuevo Mexicano) , seat = Santa Fe , LargestCity = Albuquerque , LargestMetro = Tiguex , OfficialLang = None , Languages = English, Spanish ( New Mexican), Navajo, Ker ...
, USA. *The SDAG Wismut#Freital / Dresden-Gittersee (mining division "Willi-Agatz"), Freital/Dresden-Gittersee deposit in eastern Germany produced about 3.700 t of uranium from Permian hard coal and its host rocks. The average ore grade was 0.11%. The deposit formed in a combination of syngenetic and diagenetic processes. *In some countries, for example China, trials are underway to extract uranium from fly ash.


See also

* List of countries by uranium reserves * List of uranium mines * Nuclear fuel cycle * Ore genesis * Uranium mining


References


Additional sources

* * * *{{cite web , url = http://www.wise-uranium.org/uod.html , title = Uranium Ore Deposits , publisher = WISE Uranium Project , access-date = 2008-09-20 Economic geology Ore deposits Uranium Earth's crust