Tungsten, or wolfram, is a

chemical element A chemical element is a species of atoms that have a given number of protons in their nuclei, including the pure substance consisting only of that species. Unlike chemical compounds, chemical elements cannot be broken down into simpler sub ...

with the

symbol A symbol is a mark, sign, or word that indicates, signifies, or is understood as representing an idea, object, or relationship. Symbols allow people to go beyond what is known or seen by creating linkages between otherwise very different conc ...

W and

atomic number The atomic number or nuclear charge number (symbol ''Z'') of a chemical element is the charge number of an atomic nucleus. For ordinary nuclei, this is equal to the proton number (''n''p) or the number of protons found in the nucleus of every ...

74. Tungsten is a rare metal found naturally on

Earth Earth is the third planet from the Sun and the only astronomical object known to harbor life. While large volumes of water can be found throughout the Solar System, only Earth sustains liquid surface water. About 71% of Earth's surfa ...

almost exclusively as compounds with other elements. It was identified as a new element in 1781 and first isolated as a metal in 1783. Its important

ore Ore is natural rock or sediment that contains one or more valuable minerals, typically containing metals, that can be mined, treated and sold at a profit.Encyclopædia Britannica. "Ore". Encyclopædia Britannica Online. Retrieved 7 April 2 ...

s include scheelite and wolframite, the latter lending the element its alternate name. The

free element In chemistry, a free element is a chemical element that is not combined with or chemical bond, chemically bonded to other elements. Examples of elements which can occur as free elements include the oxygen molecule (O) and carbon.A. Earnshaw and No ...

is remarkable for its robustness, especially the fact that it has the highest

melting point The melting point (or, rarely, liquefaction point) of a substance is the temperature at which it changes state from solid to liquid. At the melting point the solid and liquid phase exist in equilibrium. The melting point of a substance depends ...

of all known elements barring

carbon Carbon () is a chemical element with the symbol C and atomic number 6. It is nonmetallic and tetravalent In chemistry, the valence (US spelling) or valency (British spelling) of an element is the measure of its combining capacity with o ...

(which sublimes at normal pressure), melting at . It also has the highest

boiling point The boiling point of a substance is the temperature at which the vapor pressure of a liquid equals the pressure surrounding the liquid and the liquid changes into a vapor. The boiling point of a liquid varies depending upon the surrounding envir ...

, at . Its density is , comparable with that of

uranium Uranium is a chemical element with the symbol U and atomic number 92. It is a silvery-grey metal in the actinide series of the periodic table. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. Uranium is weak ...

and

gold Gold is a chemical element with the symbol Au (from la, aurum) and atomic number 79. This makes it one of the higher atomic number elements that occur naturally. It is a bright, slightly orange-yellow, dense, soft, malleable, and ductile met ...

, and much higher (about 1.7 times) than that of

lead Lead is a chemical element with the symbol Pb (from the Latin ) and atomic number 82. It is a heavy metal that is denser than most common materials. Lead is soft and malleable, and also has a relatively low melting point. When freshly cu ...

. Polycrystalline tungsten is an intrinsically brittle and

hard Hard may refer to: * Hardness, resistance of physical materials to deformation or fracture * Hard water, water with high mineral content Arts and entertainment * ''Hard'' (TV series), a French TV series * Hard (band), a Hungarian hard rock super ...

material (under standard conditions, when uncombined), making it difficult to work. However, pure single-crystalline tungsten is more ductile and can be cut with a hard-steel hacksaw. Tungsten occurs in many alloys, which have numerous applications, including incandescent

light bulb An electric light, lamp, or light bulb is an electrical component that produces light. It is the most common form of artificial lighting. Lamps usually have a base made of ceramic, metal, glass, or plastic, which secures the lamp in the soc ...

filaments, X-ray tubes, electrodes in gas tungsten arc welding,

superalloy A superalloy, or high-performance alloy, is an alloy with the ability to operate at a high fraction of its melting point. Several key characteristics of a superalloy are excellent mechanical strength, resistance to thermal creep deformation, g ...

s, and radiation shielding. Tungsten's hardness and high

density Density (volumetric mass density or specific mass) is the substance's mass per unit of volume. The symbol most often used for density is ''ρ'' (the lower case Greek letter rho), although the Latin letter ''D'' can also be used. Mathematical ...

make it suitable for military applications in penetrating projectiles. Tungsten compounds are often used as industrial

catalyst Catalysis () is the process of increasing the rate of a chemical reaction by adding a substance known as a catalyst (). Catalysts are not consumed in the reaction and remain unchanged after it. If the reaction is rapid and the catalyst recyc ...

s. Tungsten is the only metal in the third transition series that is known to occur in

biomolecule A biomolecule or biological molecule is a loosely used term for molecules present in organisms that are essential to one or more typically biological processes, such as cell division, morphogenesis, or development. Biomolecules include large ...

s, being found in a few species of bacteria and

archaea Archaea ( ; singular archaeon ) is a domain of single-celled organisms. These microorganisms lack cell nuclei and are therefore prokaryotes. Archaea were initially classified as bacteria, receiving the name archaebacteria (in the Archaebac ...

. However, tungsten interferes with

molybdenum Molybdenum is a chemical element with the symbol Mo and atomic number 42 which is located in period 5 and group 6. The name is from Neo-Latin ''molybdaenum'', which is based on Ancient Greek ', meaning lead, since its ores were confused with lea ...

and

copper Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkis ...

metabolism and is somewhat toxic to most forms of animal life.

Characteristics

Physical properties

In its raw form, tungsten is a hard steel-grey

metal A metal (from Greek μέταλλον ''métallon'', "mine, quarry, metal") is a material that, when freshly prepared, polished, or fractured, shows a lustrous appearance, and conducts electricity and heat relatively well. Metals are typicall ...

that is often brittle and hard to work. Purified, monocrystalline tungsten retains its

hardness In materials science, hardness (antonym: softness) is a measure of the resistance to localized plastic deformation induced by either mechanical indentation or abrasion. In general, different materials differ in their hardness; for example hard ...

(which exceeds that of many steels), and becomes malleable enough that it can be worked easily. It is worked by

forging Forging is a manufacturing process involving the shaping of metal using localized compressive forces. The blows are delivered with a hammer (often a power hammer) or a die. Forging is often classified according to the temperature at which i ...

drawing Drawing is a form of visual art in which an artist uses instruments to mark paper or other two-dimensional surface. Drawing instruments include graphite pencils, pen and ink, various kinds of paints, inked brushes, colored pencils, crayons, ...

, or

extruding Extrusion is a process used to create objects of a fixed cross-sectional profile by pushing material through a die of the desired cross-section. Its two main advantages over other manufacturing processes are its ability to create very complex ...

but it is more commonly formed by

sintering Clinker nodules produced by sintering Sintering or frittage is the process of compacting and forming a solid mass of material by pressure or heat without melting it to the point of liquefaction. Sintering happens as part of a manufacturing ...

. Of all metals in pure form, tungsten has the highest

(), lowest

vapor pressure Vapor pressure (or vapour pressure in English-speaking countries other than the US; see spelling differences) or equilibrium vapor pressure is defined as the pressure exerted by a vapor in thermodynamic equilibrium with its condensed phases ...

(at temperatures above ), and the highest

tensile strength Ultimate tensile strength (UTS), often shortened to tensile strength (TS), ultimate strength, or F_\text within equations, is the maximum stress that a material can withstand while being stretched or pulled before breaking. In brittle materials t ...

. Although

remains solid at higher temperatures than tungsten, carbon

sublimes Sublimation is the transition of a substance directly from the solid to the gas state, without passing through the liquid state. Sublimation is an endothermic process that occurs at temperatures and pressures below a substance's triple point i ...

at atmospheric pressure instead of melting, so it has no melting point. Moreover, tungsten's most stable

crystal phase A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macrosc ...

does not exhibit any high-pressure-induced structural transformations for pressures up to at least 364 gigapascals. Tungsten has the lowest coefficient of thermal expansion of any pure metal. The low thermal expansion and high melting point and

of tungsten originate from strong metallic bonds formed between tungsten atoms by the 5d electrons. Alloying small quantities of tungsten with

steel Steel is an alloy made up of iron with added carbon to improve its strength and fracture resistance compared to other forms of iron. Many other elements may be present or added. Stainless steels that are corrosion- and oxidation-resistant ty ...

greatly increases its

toughness In materials science and metallurgy, toughness is the ability of a material to absorb energy and plastically deform without fracturing. Tungsten exists in two major crystalline forms: α and β. The former has a body-centered cubic structure and is the more stable form. The structure of the β phase is called A15 cubic; it is metastable, but can coexist with the α phase at ambient conditions owing to non-equilibrium synthesis or stabilization by impurities. Contrary to the α phase which crystallizes in isometric grains, the β form exhibits a columnar

habit A habit (or wont as a humorous and formal term) is a routine of behavior that is repeated regularly and tends to occur subconsciously.

. The α phase has one third of the electrical resistivity and a much lower

superconducting transition temperature Superconductivity is a set of physical properties observed in certain materials where electrical resistance vanishes and magnetic flux fields are expelled from the material. Any material exhibiting these properties is a superconductor. Unlike ...

T_C relative to the β phase: ca. 0.015 K vs. 1–4 K; mixing the two phases allows obtaining intermediate T_C values. The T_C value can also be raised by

alloy An alloy is a mixture of chemical elements of which at least one is a metal. Unlike chemical compounds with metallic bases, an alloy will retain all the properties of a metal in the resulting material, such as electrical conductivity, ductility, ...

ing tungsten with another metal (e.g. 7.9 K for W- Tc). Such tungsten alloys are sometimes used in low-temperature superconducting circuits.

Isotopes

Naturally occurring tungsten consists of four stable

isotope Isotopes are two or more types of atoms that have the same atomic number (number of protons in their nuclei) and position in the periodic table (and hence belong to the same chemical element), and that differ in nucleon numbers (mass numbers) ...

s (¹⁸²W, ¹⁸³W, ¹⁸⁴W, and ¹⁸⁶W) and one very long-lived radioisotope, ¹⁸⁰W. Theoretically, all five can decay into isotopes of element 72 (

hafnium Hafnium is a chemical element with the symbol Hf and atomic number 72. A lustrous, silvery gray, tetravalent transition metal, hafnium chemically resembles zirconium and is found in many zirconium minerals. Its existence was predicted by Dmitri M ...

) by alpha emission, but only ¹⁸⁰W has been observed to do so, with a half-life of years; on average, this yields about two alpha decays of ¹⁸⁰W per gram of natural tungsten per year. This rate is equivalent to a specific activity of roughly 63 micro- becquerel per kilogram. This rate of decay is orders of magnitude lower than that observed in carbon or potassium as found on earth, which likewise contain small amounts of long-lived radioactive isotopes. Bismuth was long thought to be non-radioactive, but (its longest lived isotope) actually decays with a half life of years or about a factor 10 slower than . However, due to naturally occurring bismuth being 100% , its specific activity is actually higher than that of natural tungsten at 3 milli-becquerel per kilogram. The other naturally occurring isotopes of tungsten have not been observed to decay, constraining their half-lives to be at least 4 × 10²¹ years - if they decay at all. Another 30 artificial radioisotopes of tungsten have been characterized, the most stable of which are ¹⁸¹W with a half-life of 121.2 days, ¹⁸⁵W with a half-life of 75.1 days, ¹⁸⁸W with a half-life of 69.4 days, ¹⁷⁸W with a half-life of 21.6 days, and ¹⁸⁷W with a half-life of 23.72 h. All of the remaining

radioactive Radioactive decay (also known as nuclear decay, radioactivity, radioactive disintegration, or nuclear disintegration) is the process by which an unstable atomic nucleus loses energy by radiation. A material containing unstable nuclei is consid ...

isotopes have half-lives of less than 3 hours, and most of these have half-lives below 8 minutes. Tungsten also has 11 meta states, with the most stable being ^179mW (''t''_1/2 6.4 minutes).

Chemical properties

Tungsten is a mostly non-reactive element: it does not react with water, is immune to attack by most acids and bases, and does not react with oxygen or air at room temperature. At elevated temperatures (i.e., when red-hot) it reacts with oxygen to form the

trioxide A trioxide is a compound with three oxygen atoms. For metals with the M2O3 formula there are several common structures. Al2O3, Cr2O3, Fe2O3, and V2O3 adopt the corundum structure. Many rare earth oxides adopt the "A-type rare earth structure" w ...

compound tungsten(VI), WO₃. It will, however, react directly with fluorine (F₂) at room temperature to form

tungsten(VI) fluoride Tungsten(VI) fluoride, also known as tungsten hexafluoride, is an inorganic compound with the formula W F6. It is a toxic, corrosive, colorless gas, with a density of about (roughly 11 times heavier than air). It is one of the densest known ga ...

(WF₆), a colorless gas. At around 250 °C it will react with chlorine or bromine, and under certain hot conditions will react with iodine. Finely divided tungsten is

pyrophoric A substance is pyrophoric (from grc-gre, πυροφόρος, , 'fire-bearing') if it ignites spontaneously in air at or below (for gases) or within 5 minutes after coming into contact with air (for liquids and solids). Examples are organolith ...

. The most common formal

oxidation state In chemistry, the oxidation state, or oxidation number, is the hypothetical charge of an atom if all of its bonds to different atoms were fully ionic. It describes the degree of oxidation (loss of electrons) of an atom in a chemical compound. C ...

of tungsten is +6, but it exhibits all oxidation states from −2 to +6. Tungsten typically combines with oxygen to form the yellow tungstic oxide, WO₃, which dissolves in aqueous alkaline solutions to form tungstate ions, .

Tungsten carbide Tungsten carbide (chemical formula: WC) is a chemical compound (specifically, a carbide) containing equal parts of tungsten and carbon atoms. In its most basic form, tungsten carbide is a fine gray powder, but it can be pressed and formed into ...

s (W₂C and WC) are produced by heating powdered tungsten with carbon. W₂C is resistant to chemical attack, although it reacts strongly with

chlorine Chlorine is a chemical element with the Symbol (chemistry), symbol Cl and atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the periodic table and its properties are mostly intermediate betwee ...

to form

tungsten hexachloride Tungsten hexachloride is the chemical compound of tungsten and chlorine with the formula WCl6. This dark violet blue species exists as a volatile solid under standard conditions. It is an important starting reagent in the preparation of tungsten ...

(WCl₆). In aqueous solution, tungstate gives the

heteropoly acid In chemistry, the heteropolymetalates are a subset of the polyoxometalates, which consist of three or more transition metal oxyanions linked together by shared oxygen atoms to form a closed 3-dimensional molecular framework. In contrast to isopo ...

s and polyoxometalate

anion An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by convent ...

s under neutral and acidic conditions. As

tungstate In chemistry, a tungstate is a compound that contains an oxyanion of tungsten or is a mixed oxide containing tungsten. The simplest tungstate ion is , "orthotungstate". Many other tungstates belong to a large group of polyatomic ions that are ter ...

is progressively treated with acid, it first yields the soluble, metastable "paratungstate A"

, , which over time converts to the less soluble "paratungstate B" anion, . Further acidification produces the very soluble metatungstate anion, , after which equilibrium is reached. The metatungstate ion exists as a symmetric cluster of twelve tungsten-

oxygen Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as wel ...

octahedra known as the Keggin anion. Many other polyoxometalate anions exist as metastable species. The inclusion of a different atom such as

phosphorus Phosphorus is a chemical element with the symbol P and atomic number 15. Elemental phosphorus exists in two major forms, white phosphorus and red phosphorus, but because it is highly reactive, phosphorus is never found as a free element on Ear ...

in place of the two central

hydrogen Hydrogen is the chemical element with the symbol H and atomic number 1. Hydrogen is the lightest element. At standard conditions hydrogen is a gas of diatomic molecules having the formula . It is colorless, odorless, tasteless, non-toxic, an ...

s in metatungstate produces a wide variety of heteropoly acids, such as phosphotungstic acid H₃PW₁₂O₄₀. Tungsten trioxide can form

intercalation Intercalation may refer to: * Intercalation (chemistry), insertion of a molecule (or ion) into layered solids such as graphite *Intercalation (timekeeping), insertion of a leap day, week or month into some calendar years to make the calendar foll ...

compounds with alkali metals. These are known as ''bronzes''; an example is

sodium tungsten bronze Sodium tungsten bronze is a form of insertion compound with the formula Na''x''WO3, where ''x'' is equal to or less than 1. So named because of its metallic lustre, its electrical properties range from semiconducting to metallic depending on the ...

. In gaseous form, tungsten forms the diatomic species W₂. These molecules feature a sextuple bond between tungsten atoms — the highest known bond order among

stable A stable is a building in which livestock, especially horses, are kept. It most commonly means a building that is divided into separate stalls for individual animals and livestock. There are many different types of stables in use today; the ...

atoms.

History

In 1781,

Carl Wilhelm Scheele Carl Wilhelm Scheele (, ; 9 December 1742 – 21 May 1786) was a Swedish German pharmaceutical chemist. Scheele discovered oxygen (although Joseph Priestley published his findings first), and identified molybdenum, tungsten, barium, hydrog ...

discovered that a new

acid In computer science, ACID ( atomicity, consistency, isolation, durability) is a set of properties of database transactions intended to guarantee data validity despite errors, power failures, and other mishaps. In the context of databases, a sequ ...

tungstic acid Tungstic acid refers to hydrated forms of tungsten trioxide, WO3. Both a monohydrate (WO3·H2O) and hemihydrate (WO3·1/2 H2O) are known. Molecular species akin to sulfuric acid, i.e. (HO)2WO2 are not observed. The solid-state structure of ...

, could be made from scheelite (at the time called tungsten). Scheele and Torbern Bergman suggested that it might be possible to obtain a new metal by reducing this acid. In 1783,

José José is a predominantly Spanish and Portuguese form of the given name Joseph. While spelled alike, this name is pronounced differently in each language: Spanish ; Portuguese (or ). In French, the name ''José'', pronounced , is an old vernacul ...

and Fausto Elhuyar found an acid made from wolframite that was identical to tungstic acid. Later that year, at the Royal Basque Society in the town of

Bergara es, vergarés, vergaresa , population_note = , population_density_km2 = auto , blank_name_sec1 = Official language(s) , blank_info_sec1 = BasqueSpanish , timezone = CET , utc_offset = +1 ...

, Spain, the brothers succeeded in isolating tungsten by reduction of this acid with

charcoal Charcoal is a lightweight black carbon residue produced by strongly heating wood (or other animal and plant materials) in minimal oxygen to remove all water and volatile constituents. In the traditional version of this pyrolysis process, cal ...

, and they are credited with the discovery of the element (they called it "wolfram" or "volfram"). The strategic value of tungsten came to notice in the early 20th century. British authorities acted in 1912 to free the Carrock mine from the German owned Cumbrian Mining Company and, during

World War I World War I (28 July 1914 11 November 1918), often abbreviated as WWI, was one of the deadliest global conflicts in history. Belligerents included much of Europe, the Russian Empire, the United States, and the Ottoman Empire, with fightin ...

, restrict German access elsewhere. In

World War II World War II or the Second World War, often abbreviated as WWII or WW2, was a world war that lasted from 1939 to 1945. It involved the vast majority of the world's countries—including all of the great powers—forming two opposin ...

, tungsten played a more significant role in background political dealings. Portugal, as the main European source of the element, was put under pressure from both sides, because of its deposits of wolframite ore at Panasqueira. Tungsten's desirable properties such as resistance to high temperatures, its hardness and density, and its strengthening of alloys made it an important raw material for the arms industry, both as a constituent of weapons and equipment and employed in production itself, e.g., in

tungsten carbide Tungsten carbide (chemical formula: WC) is a chemical compound (specifically, a carbide) containing equal parts of tungsten and carbon atoms. In its most basic form, tungsten carbide is a fine gray powder, but it can be pressed and formed into ...

cutting tools for machining steel. Now tungsten is used in many more applications such as aircraft & motorsport ballast weights, darts, anti-vibration tooling, and sporting equipment. Tungsten is unique amongst the elements in that it has been the subject of patent proceedings. In 1928, a US court rejected

General Electric General Electric Company (GE) is an American multinational conglomerate founded in 1892, and incorporated in New York state and headquartered in Boston. The company operated in sectors including healthcare, aviation, power, renewable energ ...

's attempt to patent it, overturning granted in 1913 to

William D. Coolidge William David Coolidge (; October 23, 1873 – February 3, 1975) was an American physicist and engineer, who made major contributions to X-ray machines. He was the director of the General Electric Research Laboratory and a vice-president of t ...

Etymology

The name "tungsten" (which means "heavy stone" in

Swedish Swedish or ' may refer to: Anything from or related to Sweden, a country in Northern Europe. Or, specifically: * Swedish language, a North Germanic language spoken primarily in Sweden and Finland ** Swedish alphabet, the official alphabet used by ...

) is used in English, French, and many other languages as the name of the element, but not in the

Nordic countries The Nordic countries (also known as the Nordics or ''Norden''; literal translation, lit. 'the North') are a geographical and cultural region in Northern Europe and the Atlantic Ocean, North Atlantic. It includes the sovereign states of Denmar ...

. "Tungsten" was the old Swedish name for the mineral scheelite. "Wolfram" (or "volfram") is used in most European (especially Germanic, Spanish and Slavic) languages and is derived from the mineral wolframite, which is the origin of the chemical symbol W. The name "wolframite" is derived from German "''wolf rahm''" ("wolf soot" or "wolf cream"), the name given to tungsten by

Johan Gottschalk Wallerius Johan Gottschalk Wallerius (11 July 1709 – 16 November 1785) was a Swedish chemist and mineralogist. Biography Wallerius was born at Stora Mellösa in Närke (now Örebro County), Sweden. He was a son of provost Erik Nilsson Wallerius and hi ...

in 1747. This, in turn, derives from

Latin Latin (, or , ) is a classical language belonging to the Italic branch of the Indo-European languages. Latin was originally a dialect spoken in the lower Tiber area (then known as Latium) around present-day Rome, but through the power of the ...

"''lupi spuma''", the name

Georg Agricola Georgius Agricola (; born Georg Pawer or Georg Bauer; 24 March 1494 – 21 November 1555) was a German Humanist scholar, mineralogist and metallurgist. Born in the small town of Glauchau, in the Electorate of Saxony of the Holy Roman Empire ...

used for the element in 1546, which translates into English as "wolf's froth" and is a reference to the large amounts of

tin Tin is a chemical element with the symbol Sn (from la, stannum) and atomic number 50. Tin is a silvery-coloured metal. Tin is soft enough to be cut with little force and a bar of tin can be bent by hand with little effort. When bent, t ...

consumed by the mineral during its extraction, as though the mineral devoured it like a wolf. This naming follows a tradition of colorful names miners from the Ore Mountains would give various minerals, out of a superstition that certain ones that looked as if they contained then-known valuable metals but didn't were somehow "hexed".

Cobalt Cobalt is a chemical element with the symbol Co and atomic number 27. As with nickel, cobalt is found in the Earth's crust only in a chemically combined form, save for small deposits found in alloys of natural meteoric iron. The free element, pr ...

(c.f.

Kobold A kobold (occasionally cobold) is a mythical sprite. Having spread into Europe with various spellings including "goblin" and "hobgoblin", and later taking root and stemming from Germanic mythology, the concept survived into modern times in Ger ...

), pitchblende (c.f. German " blenden" for "to blind" or "to deceive") and

nickel Nickel is a chemical element with symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel is a hard and ductile transition metal. Pure nickel is chemically reactive but large pieces are slow to ...

(c.f. "Old Nick") derive their names from the same miner's idiom.

Occurrence

Tungsten has thus far not been found in nature in its pure form. Instead, tungsten is found mainly in the minerals wolframite and scheelite. Wolframite is

iron Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in f ...

–

manganese Manganese is a chemical element with the symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese is a transition metal with a multifaceted array of industrial alloy use ...

tungstate , a solid solution of the two minerals ferberite (FeWO₄) and hübnerite (MnWO₄), while scheelite is

calcium Calcium is a chemical element with the symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar to ...

tungstate (CaWO₄). Other tungsten minerals range in their level of abundance from moderate to very rare, and have almost no economic value.

Chemical compounds

upStructure of W₆Cl₁₈ ("tungsten trichloride") Tungsten forms chemical compounds in oxidation states from -II to VI. Higher oxidation states, always as oxides, are relevant to its terrestrial occurrence and its biological roles, mid-level oxidation states are often associated with metal clusters, and very low oxidation states are typically associated with CO complexes. The chemistries of tungsten and

show strong similarities to each other, as well as contrasts with their lighter congener,

chromium Chromium is a chemical element with the symbol Cr and atomic number 24. It is the first element in group 6. It is a steely-grey, lustrous, hard, and brittle transition metal. Chromium metal is valued for its high corrosion resistance and hardne ...

. The relative rarity of tungsten(III), for example, contrasts with the pervasiveness of the chromium(III) compounds. The highest oxidation state is seen in

tungsten(VI) oxide Tungsten(VI) oxide, also known as tungsten trioxide is a chemical compound of oxygen and the transition metal tungsten, with formula WO3. The compound is also called tungstic anhydride, reflecting its relation to tungstic acid . It is a light ye ...

(WO₃). Tungsten(VI) oxide is soluble in aqueous base, forming tungstate (WO₄²⁻). This oxyanion condenses at lower pH values, forming polyoxotungstates. The broad range of

s of tungsten is reflected in its various chlorides: *

Tungsten(II) chloride Tungsten(II) chloride is the inorganic compound with the formula W6Cl12. It is a polymeric cluster compound. The material dissolves in concentrated hydrochloric acid, forming (H3O)2 6Cl14H2O)x. Heating this salt gives yellow-brown W6Cl12. The ...

, which exists as the hexamer W₆Cl₁₂ *

Tungsten(III) chloride Tungsten(III) chloride is the inorganic compound with the formula W6Cl18. It is a cluster compound. It is a brown solid, obtainable by chlorination of tungsten(II) chloride. Featuring twelve doubly bridging chloride ligands, the cluster adopts ...

, which exists as the hexamer W₆Cl₁₈ *

Tungsten(IV) chloride Tungsten(IV) chloride is an inorganic compound with the formula WCl4. It is a diamagnetic black solid. The compound is of interest in research as one of a handful of binary tungsten chlorides. Structure and preparation WCl4 is usually prepar ...

, WCl₄, a black solid, which adopts a polymeric structure. *

Tungsten(V) chloride Tungsten(V) chloride is an inorganic compound with the formula W2 Cl10. This compound is analogous in many ways to the more familiar molybdenum pentachloride. The material is prepared by reduction of tungsten hexachloride. One method involves ...

WCl₅, a black solid which adopts a dimeric structure. * Tungsten(VI) chloride WCl₆, which contrasts with the instability of MoCl₆. Organotungsten compounds are numerous and also span a range of oxidation states. Notable examples include the trigonal prismatic and octahedral .

Production

A full trolly coming from one of the galleries (27072015764)

Reserves

The world's reserves of tungsten are 3,200,000 tonnes; they are mostly located in

China China, officially the People's Republic of China (PRC), is a country in East Asia. It is the world's most populous country, with a population exceeding 1.4 billion, slightly ahead of India. China spans the equivalent of five time zones and ...

(1,800,000 t),

Canada Canada is a country in North America. Its ten provinces and three territories extend from the Atlantic Ocean to the Pacific Ocean and northward into the Arctic Ocean, covering over , making it the world's second-largest country by tot ...

(290,000 t),

Russia Russia (, , ), or the Russian Federation, is a List of transcontinental countries, transcontinental country spanning Eastern Europe and North Asia, Northern Asia. It is the List of countries and dependencies by area, largest country in the ...

(160,000 t),

Vietnam Vietnam or Viet Nam ( vi, Việt Nam, ), officially the Socialist Republic of Vietnam,., group="n" is a country in Southeast Asia, at the eastern edge of mainland Southeast Asia, with an area of and population of 96 million, making i ...

(95,000 t) and

Bolivia , image_flag = Bandera de Bolivia (Estado).svg , flag_alt = Horizontal tricolor (red, yellow, and green from top to bottom) with the coat of arms of Bolivia in the center , flag_alt2 = 7 × 7 square p ...

. As of 2017, China, Vietnam and Russia are the leading suppliers with 79,000, 7,200 and 3,100 tonnes, respectively. Canada had ceased production in late 2015 due to the closure of its sole tungsten mine. Meanwhile, Vietnam had significantly increased its output in the 2010s, owing to the major optimization of its domestic refining operations, and overtook Russia and Bolivia. China remains the world's leader not only in production, but also in export and consumption of tungsten products. Tungsten production is gradually increasing outside China because of the rising demand. Meanwhile, its supply by China is strictly regulated by the Chinese Government, which fights illegal mining and excessive pollution originating from mining and refining processes.Tungsten
''Mineral Commodity Summaries''. USGS (2018) There is a large deposit of tungsten ore on the edge of Dartmoor in the

United Kingdom The United Kingdom of Great Britain and Northern Ireland, commonly known as the United Kingdom (UK) or Britain, is a country in Europe, off the north-western coast of the continental mainland. It comprises England, Scotland, Wales and North ...

, which was exploited during

and

as the

Hemerdon Mine Drakelands Mine, also known as Hemerdon Mine or Hemerdon Ball Mine, is a tungsten and tin mine. It is located northeast of Plymouth, near Plympton, in Devon, England. It lies to the north of the villages of Sparkwell and Hemerdon, and adjacen ...

. Following increases in tungsten prices, this mine was reactivated in 2014, but ceased activities in 2018. Within the EU, the

Austria Austria, , bar, Östareich officially the Republic of Austria, is a country in the southern part of Central Europe, lying in the Eastern Alps. It is a federation of nine states, one of which is the capital, Vienna, the most populous ...

n Felbertal scheelite deposit is one of the few producing tungsten mines.

Portugal Portugal, officially the Portuguese Republic ( pt, República Portuguesa, links=yes ), is a country whose mainland is located on the Iberian Peninsula of Southwestern Europe, and whose territory also includes the Atlantic archipelagos of ...

is one of Europe's main tungsten producers, with 121 kt of contained tungsten in mineral concentrates from 1910 to 2020, accounting for roughly 3.3% of the global production. Tungsten is considered to be a

conflict mineral The eastern Democratic Republic of the Congo (DRC) has a history of conflict, where various armies, rebel groups, and outside actors have profited from mining while contributing to violence and exploitation during wars in the region. The four mai ...

due to the unethical mining practices observed in the

Democratic Republic of the Congo The Democratic Republic of the Congo (french: République démocratique du Congo (RDC), colloquially "La RDC" ), informally Congo-Kinshasa, DR Congo, the DRC, the DROC, or the Congo, and formerly and also colloquially Zaire, is a country in ...

Extraction

Tungsten is extracted from its ores in several stages. The ore is eventually converted to

(WO₃), which is heated with

or carbon to produce powdered tungsten. Because of tungsten's high melting point, it is not commercially feasible to cast tungsten ingots. Instead, powdered tungsten is mixed with small amounts of powdered nickel or other metals, and

sintered Clinker nodules produced by sintering Sintering or frittage is the process of compacting and forming a solid mass of material by pressure or heat without melting it to the point of liquefaction. Sintering happens as part of a manufacturing ...

. During the sintering process, the nickel diffuses into the tungsten, producing an alloy. Tungsten can also be extracted by hydrogen reduction of WF₆: :WF₆ + 3 H₂ → W + 6 HF or pyrolytic decomposition: :WF₆ → W + 3 F₂ ( Δ''H''_r = +) Tungsten is not traded as a futures contract and cannot be tracked on exchanges like the London Metal Exchange. The tungsten industry often uses independent pricing references such as

Argus Media Argus (formerly known as Petroleum Argus Ltd) is an independent provider of price information, consultancy services, conferences, market data and business intelligence for the global petroleum, natural gas, electricity, emissions, biofuels, bi ...

Metal Bulletin Fastmarkets MB, previously known as Metal Bulletin, is a specialist international publisher and information provider for the global steel, non-ferrous and scrap metals markets. History What was later known as ''Metal Bulletin'' was started in 191 ...

as a basis for contracts. The prices are usually quoted for tungsten concentrate or WO₃.Shedd, Kim B. (December 2018
Tungsten
''2016 Minerals Yearbook''. USGS

Applications

Approximately half of the tungsten is consumed for the production of hard materials – namely

– with the remaining major use being in alloys and steels. Less than 10% is used in other chemical compounds. Because of the high ductile-brittle transition temperature of tungsten, its products are conventionally manufactured through powder metallurgy,

spark plasma sintering Spark plasma sintering (SPS), also known as field assisted sintering technique (FAST) or pulsed electric current sintering (PECS), or plasma pressure compaction (P2C) is a sintering technique. The main characteristic of SPS is that the pulsed or u ...

chemical vapor deposition Chemical vapor deposition (CVD) is a vacuum deposition method used to produce high quality, and high-performance, solid materials. The process is often used in the semiconductor industry to produce thin films. In typical CVD, the wafer (substra ...

hot isostatic pressing Hot isostatic pressing (HIP) is a manufacturing process, used to reduce the porosity of metals and increase the density of many ceramic materials. This improves the material's mechanical properties and workability. The process can be used to pro ...

, and

thermoplastic A thermoplastic, or thermosoft plastic, is any plastic polymer material that becomes pliable or moldable at a certain elevated temperature and solidifies upon cooling. Most thermoplastics have a high molecular weight. The polymer chains associate ...

routes. A more flexible manufacturing alternative is selective laser melting, which is a form of

3D printing 3D printing or additive manufacturing is the Manufacturing, construction of a three-dimensional object from a computer-aided design, CAD model or a digital 3D modeling, 3D model. It can be done in a variety of processes in which material is ...

and allows creating complex three-dimensional shapes.

Industrial

Tungsten is mainly used in the production of hard materials based on

(WC), one of the hardest

carbide In chemistry, a carbide usually describes a compound composed of carbon and a metal. In metallurgy, carbiding or carburizing is the process for producing carbide coatings on a metal piece. Interstitial / Metallic carbides The carbides of the ...

s. WC is an efficient electrical conductor, but W₂C is less so. WC is used to make wear-resistant abrasives, and "carbide" cutting tools such as knives, drills,

circular saw A circular saw is a power-saw using a toothed or abrasive disc or blade to cut different materials using a rotary motion spinning around an arbor. A hole saw and ring saw also use a rotary motion but are different from a circular saw. ''Cir ...

dies Dies may refer to: * Dies (deity), the Roman counterpart of the Greek goddess Hemera, the personification of day, daughter of Nox (Night) and Erebus (Darkness). * Albert Christoph Dies (1755–1822), German painter, composer, and biographer * Jos ...

milling Milling may refer to: * Milling (minting), forming narrow ridges around the edge of a coin * Milling (grinding), breaking solid materials into smaller pieces by grinding, crushing, or cutting in a mill * Milling (machining), a process of using rota ...

and

turning Turning is a machining process in which a cutting tool, typically a non-rotary tool bit, describes a helix toolpath by moving more or less linearly while the workpiece rotates. Usually the term "turning" is reserved for the generation of ...

tools used by the metalworking, woodworking,

mining Mining is the extraction of valuable minerals or other geological materials from the Earth, usually from an ore body, lode, vein, seam, reef, or placer deposit. The exploitation of these deposits for raw material is based on the economic via ...

petroleum Petroleum, also known as crude oil, or simply oil, is a naturally occurring yellowish-black liquid mixture of mainly hydrocarbons, and is found in geological formations. The name ''petroleum'' covers both naturally occurring unprocessed crud ...

and construction industries. Carbide tooling is actually a ceramic/metal composite, where metallic cobalt acts as a binding (matrix) material to hold the WC particles in place. This type of industrial use accounts for about 60% of current tungsten consumption. The

jewelry Jewellery ( UK) or jewelry (U.S.) consists of decorative items worn for personal adornment, such as brooches, rings, necklaces, earrings, pendants, bracelets, and cufflinks. Jewellery may be attached to the body or the clothes. From a western ...

industry makes rings of sintered

, tungsten carbide/metal composites, and also metallic tungsten. WC/metal composite rings use nickel as the metal matrix in place of

cobalt Cobalt is a chemical element with the symbol Co and atomic number 27. As with nickel, cobalt is found in the Earth's crust only in a chemically combined form, save for small deposits found in alloys of natural meteoric iron. The free element, pr ...

because it takes a higher luster when polished. Sometimes manufacturers or retailers refer to

as a metal, but it is a

ceramic A ceramic is any of the various hard, brittle, heat-resistant and corrosion-resistant materials made by shaping and then firing an inorganic, nonmetallic material, such as clay, at a high temperature. Common examples are earthenware, porcelain ...

. Because of tungsten carbide's hardness, rings made of this material are extremely abrasion resistant, and will hold a burnished finish longer than rings made of metallic tungsten. Tungsten carbide rings are brittle, however, and may crack under a sharp blow.

Alloys

The hardness and heat resistance of tungsten can contribute to useful

s. A good example is high-speed steel, which can contain as much as 18% tungsten. Tungsten's high melting point makes tungsten a good material for applications like rocket nozzles, for example in the

UGM-27 Polaris The UGM-27 Polaris missile was a two-stage solid-fueled nuclear-armed submarine-launched ballistic missile (SLBM). As the United States Navy's first SLBM, it served from 1961 to 1980. In the mid-1950s the Navy was involved in the Jupiter missile ...

submarine-launched ballistic missile A submarine-launched ballistic missile (SLBM) is a ballistic missile capable of being launched from submarines. Modern variants usually deliver multiple independently targetable reentry vehicles (MIRVs), each of which carries a nuclear warhead ...

. Tungsten alloys are used in a wide range of applications, including the aerospace and automotive industries and radiation shielding.

Superalloy A superalloy, or high-performance alloy, is an alloy with the ability to operate at a high fraction of its melting point. Several key characteristics of a superalloy are excellent mechanical strength, resistance to thermal creep deformation, g ...

s containing tungsten, such as Hastelloy and

Stellite Stellite is a range of cobalt-chromium alloys designed for wear resistance. The alloys may also contain tungsten or molybdenum and a small, but important, amount of carbon. History Stellite is a trademarked name of Kennametal Inc. Prior to tha ...

, are used in

turbine A turbine ( or ) (from the Greek , ''tyrbē'', or Latin ''turbo'', meaning vortex) is a rotary mechanical device that extracts energy from a fluid flow and converts it into useful work. The work produced by a turbine can be used for generating e ...

blades and wear-resistant parts and coatings. Tungsten's heat resistance makes it useful in arc welding applications when combined with another highly-conductive metal such as silver or copper. The silver or copper provides the necessary conductivity and the tungsten allows the welding rod to withstand the high temperatures of the arc welding environment.

Permanent magnets

Quenched (martensitic) tungsten steel (approx. 5.5% to 7.0% W with 0.5% to 0.7% C) was used for making hard permanent magnets, due to its high

remanence Remanence or remanent magnetization or residual magnetism is the magnetization left behind in a ferromagnetic material (such as iron) after an external magnetic field is removed. Colloquially, when a magnet is "magnetized", it has remanence. The ...

and coercivity, as noted by

John Hopkinson John Hopkinson, FRS, (27 July 1849 – 27 August 1898) was a British physicist, electrical engineer, Fellow of the Royal Society and President of the IEE (now the IET) twice in 1890 and 1896. He invented the three-wire (three-phase) system for ...

(1849–1898) as early as 1886. The magnetic properties of a metal or an alloy are very sensitive to microstructure. For example, while the element tungsten is not ferromagnetic (but

is), when it is present in steel in these proportions, it stabilizes the

martensite Martensite is a very hard form of steel crystalline structure. It is named after German metallurgist Adolf Martens. By analogy the term can also refer to any crystal structure that is formed by diffusionless transformation. Properties Mart ...

phase, which has greater ferromagnetism than the ferrite (iron) phase due to its greater resistance to magnetic domain wall motion.

Military

Tungsten, usually alloyed with

, or

to form heavy alloys, is used in

kinetic energy penetrator A kinetic energy penetrator (KEP), also known as long-rod penetrator (LRP), is a type of ammunition designed to penetrate vehicle armour using a flechette-like, high-sectional density projectile. Like a bullet or kinetic energy weapon, this type ...

s as an alternative to

depleted uranium Depleted uranium (DU; also referred to in the past as Q-metal, depletalloy or D-38) is uranium with a lower content of the fissile isotope than natural uranium.: "Depleted uranium possesses only 60% of the radioactivity of natural uranium, hav ...

, in applications where uranium's radioactivity is problematic even in depleted form, or where uranium's additional

properties are not desired (for example, in ordinary small arms bullets designed to penetrate body armor). Similarly, tungsten alloys have also been used in shells,

grenade A grenade is an explosive weapon typically thrown by hand (also called hand grenade), but can also refer to a shell (explosive projectile) shot from the muzzle of a rifle (as a rifle grenade) or a grenade launcher. A modern hand grenade genera ...

s, and

missile In military terminology, a missile is a guided airborne ranged weapon capable of self-propelled flight usually by a jet engine or rocket motor. Missiles are thus also called guided missiles or guided rockets (when a previously unguided rocket i ...

s, to create supersonic shrapnel. Germany used tungsten during World War II to produce shells for anti-tank gun designs using the Gerlich squeeze bore principle to achieve very high muzzle velocity and enhanced armor penetration from comparatively small caliber and light weight field artillery. The weapons were highly effective but a shortage of tungsten used in the shell core, caused in part by the

Wolfram Crisis The Wolfram Crisis (Spanish: ''Crisis del wolframio'') was a diplomatic conflict during World War II between Francoist Spain and the Allies of World War II, Allied powers, which sought to block Spanish exports of Tungsten, tungsten ore to Nazi Ger ...

, limited their use. Tungsten has also been used in

Dense inert metal explosive Dense inert metal explosive (DIME) is an experimental type of explosive that has a relatively small but effective blast radius. It is manufactured by producing a homogeneous mixture of an explosive material (such as phlegmatized, HMX or RDX) and ...

s, which use it as dense powder to reduce collateral damage while increasing the lethality of explosives within a small radius.

Chemical applications

Tungsten(IV) sulfide Tungsten disulfide is an inorganic chemical compound composed of tungsten and sulfur with the chemical formula WS2. This compound is part of the group of materials called the transition metal dichalcogenides. It occurs naturally as the rare miner ...

is a high temperature

lubricant A lubricant (sometimes shortened to lube) is a substance that helps to reduce friction between surfaces in mutual contact, which ultimately reduces the heat generated when the surfaces move. It may also have the function of transmitting forces, t ...

and is a component of catalysts for

hydrodesulfurization Hydrodesulfurization (HDS) is a catalytic chemical process widely used to remove sulfur (S) from natural gas and from refined petroleum products, such as gasoline or petrol, jet fuel, kerosene, diesel fuel, and fuel oils. The purpose of remov ...

. MoS₂ is more commonly used for such applications. Tungsten

oxide An oxide () is a chemical compound that contains at least one oxygen atom and one other element in its chemical formula. "Oxide" itself is the dianion of oxygen, an O2– (molecular) ion. with oxygen in the oxidation state of −2. Most of the E ...

s are used in

glazes and

magnesium Magnesium is a chemical element with the symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 of the periodic ta ...

tungstates are used widely in fluorescent lighting. Crystal

s are used as

scintillation detectors A scintillator is a material that exhibits scintillation, the property of luminescence, when excited by ionizing radiation. Luminescent materials, when struck by an incoming particle, absorb its energy and scintillate (i.e. re-emit the absorbed ...

nuclear physics Nuclear physics is the field of physics that studies atomic nuclei and their constituents and interactions, in addition to the study of other forms of nuclear matter. Nuclear physics should not be confused with atomic physics, which studies the ...

and

nuclear medicine Nuclear medicine or nucleology is a medical specialty involving the application of radioactive substances in the diagnosis and treatment of disease. Nuclear imaging, in a sense, is "radiology done inside out" because it records radiation emitting ...

. Other salts that contain tungsten are used in the chemical and

tanning Tanning may refer to: *Tanning (leather), treating animal skins to produce leather *Sun tanning, using the sun to darken pale skin **Indoor tanning, the use of artificial light in place of the sun **Sunless tanning, application of a stain or dye t ...

industries. Tungsten oxide (WO₃) is incorporated into

selective catalytic reduction Selective catalytic reduction (SCR) is a means of converting nitrogen oxides, also referred to as with the aid of a catalyst into diatomic nitrogen (), and water (). A reductant, typically anhydrous ammonia (), aqueous ammonia (), or a urea () s ...

(SCR) catalysts found in coal-fired power plants. These catalysts convert

nitrogen oxide Nitrogen oxide may refer to a binary compound of oxygen and nitrogen, or a mixture of such compounds: Charge-neutral *Nitric oxide (NO), nitrogen(II) oxide, or nitrogen monoxide *Nitrogen dioxide (), nitrogen(IV) oxide * Nitrogen trioxide (), or n ...

s ( NO_x) to nitrogen (N₂) and water (H₂O) using ammonia (NH₃). The tungsten oxide helps with the physical strength of the catalyst and extends catalyst life. Tungsten containing catalysts are promising for epoxidation, oxidation, and hydrogenolysis reactions. Tungsten heteropoly acids are key component of multifunctional catalysts. Tungstates can be used as photocatalyst, while the tungsten sulfide as electrocatalyst.

Niche uses

Applications requiring its high density include weights,

counterweights A counterweight is a weight that, by applying an opposite force, provides balance and stability of a mechanical system. The purpose of a counterweight is to make lifting the load faster and more efficient, which saves energy and causes less wear ...

, ballast keels for yachts, tail ballast for commercial aircraft, rotor weights for civil and military helicopters, and as ballast in race cars for

NASCAR The National Association for Stock Car Auto Racing, LLC (NASCAR) is an American auto racing sanctioning and operating company that is best known for stock car racing. The privately owned company was founded by Bill France Sr. in 1948, and hi ...

and

Formula One Formula One (also known as Formula 1 or F1) is the highest class of international racing for open-wheel single-seater formula racing cars sanctioned by the Fédération Internationale de l'Automobile (FIA). The World Drivers' Championship, ...

. Being slightly less than twice the density, Tungsten is seen as an alternative (albeit more expensive) to lead fishing sinkers.

Depleted uranium Depleted uranium (DU; also referred to in the past as Q-metal, depletalloy or D-38) is uranium with a lower content of the fissile isotope than natural uranium.: "Depleted uranium possesses only 60% of the radioactivity of natural uranium, hav ...

is also used for these purposes, due to similarly high density. Seventy-five-kg blocks of tungsten were used as "cruise balance mass devices" on the entry vehicle portion of the 2012 Mars Science Laboratory spacecraft. It is an ideal material to use as a

dolly Dolly may refer to: Tools *Dolly (tool), a portable anvil * A posser, also known as a dolly, used for laundering * A variety of wheeled tools, including: **Dolly (trailer), for towing behind a vehicle **Boat dolly or launching dolly, a device fo ...

for riveting, where the mass necessary for good results can be achieved in a compact bar. High-density alloys of tungsten with nickel, copper or iron are used in high-quality darts (to allow for a smaller diameter and thus tighter groupings) or for artificial flys (tungsten beads allow the fly to sink rapidly). Tungsten is also used as a heavy bolt to lower the rate of fire of the SWD M11/9 sub-machine gun from 1300 RPM to 700 RPM. Tungsten has seen use recently in nozzles for

; the high wear resistance and thermal conductivity of tungsten carbide improves the printing of abrasive filaments. Some

string instrument String instruments, stringed instruments, or chordophones are musical instruments that produce sound from vibrating strings when a performer plays or sounds the strings in some manner. Musicians play some string instruments by plucking the ...

strings are wound with tungsten. Tungsten is used as an absorber on the electron telescope on the

Cosmic Ray System Cosmic Ray Subsystem (CRS, or Cosmic Ray System) is an instrument aboard the ''Voyager 1'' and ''Voyager 2'' spacecraft of the NASA Voyager program, and it is an experiment to detect cosmic rays. The CRS includes a High-Energy Telescope System ( ...

of the two

Voyager spacecraft The Voyager program is an American scientific program that employs two robotic interstellar probes, ''Voyager 1'' and ''Voyager 2''. They were launched in 1977 to take advantage of a favorable alignment of Jupiter and Saturn, to fly near the ...

Gold substitution

Its density, similar to that of gold, allows tungsten to be used in jewelry as an alternative to

platinum Platinum is a chemical element with the symbol Pt and atomic number 78. It is a dense, malleable, ductile, highly unreactive, precious, silverish-white transition metal. Its name originates from Spanish , a diminutive of "silver". Platinu ...

. Metallic tungsten is

hypoallergenic Hypoallergenic, meaning "below average" or "slightly" allergenic, is a term meaning that something (usually cosmetics, pets, textiles, food, etc.) causes fewer allergic reactions. The term was first used in 1953 in an advertising campaign for cosm ...

, and is harder than gold alloys (though not as hard as tungsten carbide), making it useful for rings that will resist scratching, especially in designs with a brushed finish. Because the density is so similar to that of gold (tungsten is only 0.36% less dense), and its price of the order of one-thousandth, tungsten can also be used in

counterfeiting To counterfeit means to imitate something authentic, with the intent to steal, destroy, or replace the original, for use in illegal transactions, or otherwise to deceive individuals into believing that the fake is of equal or greater value tha ...

gold bar A gold bar, also called gold bullion or gold ingot, is a quantity of refined metallic gold of any shape that is made by a bar producer meeting standard conditions of manufacture, labeling, and record keeping. Larger gold bars that are produced ...

s, such as by plating a tungsten bar with gold, which has been observed since the 1980s, or taking an existing gold bar, drilling holes, and replacing the removed gold with tungsten rods. The densities are not exactly the same, and other properties of gold and tungsten differ, but gold-plated tungsten will pass superficial tests. Gold-plated tungsten is available commercially from China (the main source of tungsten), both in jewelry and as bars.

Electronics

Because it retains its strength at high temperatures and has a high

, elemental tungsten is used in many high-temperature applications, such as

incandescent light bulb An incandescent light bulb, incandescent lamp or incandescent light globe is an electric light with a wire filament heated until it glows. The filament is enclosed in a glass bulb with a vacuum or inert gas to protect the filament from oxida ...

cathode-ray tube A cathode-ray tube (CRT) is a vacuum tube containing one or more electron guns, which emit electron beams that are manipulated to display images on a phosphorescent screen. The images may represent electrical waveforms (oscilloscope), pictur ...

, and

vacuum tube A vacuum tube, electron tube, valve (British usage), or tube (North America), is a device that controls electric current flow in a high vacuum between electrodes to which an electric voltage, potential difference has been applied. The type kn ...

filaments, heating elements, and

rocket engine A rocket engine uses stored rocket propellants as the reaction mass for forming a high-speed propulsive jet of fluid, usually high-temperature gas. Rocket engines are reaction engines, producing thrust by ejecting mass rearward, in accordanc ...

nozzles. Its high melting point also makes tungsten suitable for aerospace and high-temperature uses such as electrical, heating, and welding applications, notably in the gas tungsten arc welding process (also called tungsten inert gas (TIG) welding). TIG torch breakdown

Because of its conductive properties and relative chemical inertness, tungsten is also used in

electrode An electrode is an electrical conductor used to make contact with a nonmetallic part of a circuit (e.g. a semiconductor, an electrolyte, a vacuum or air). Electrodes are essential parts of batteries that can consist of a variety of materials de ...

s, and in the emitter tips in electron-beam instruments that use

field emission gun A field emission gun (FEG) is a type of electron gun in which a sharply pointed Müller-type emitter is held at several kilovolts negative potential relative to a nearby electrode, so that there is sufficient potential gradient at the emitter su ...

s, such as

electron microscope An electron microscope is a microscope that uses a beam of accelerated electrons as a source of illumination. As the wavelength of an electron can be up to 100,000 times shorter than that of visible light photons, electron microscopes have a hi ...

s. In electronics, tungsten is used as an interconnect material in

integrated circuit An integrated circuit or monolithic integrated circuit (also referred to as an IC, a chip, or a microchip) is a set of electronic circuits on one small flat piece (or "chip") of semiconductor material, usually silicon. Large numbers of tiny ...

s, between the

silicon dioxide Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is one ...

dielectric In electromagnetism, a dielectric (or dielectric medium) is an electrical insulator that can be polarised by an applied electric field. When a dielectric material is placed in an electric field, electric charges do not flow through the mate ...

material and the transistors. It is used in metallic films, which replace the wiring used in conventional electronics with a coat of tungsten (or

) on

silicon Silicon is a chemical element with the symbol Si and atomic number 14. It is a hard, brittle crystalline solid with a blue-grey metallic luster, and is a tetravalent metalloid and semiconductor. It is a member of group 14 in the periodic tab ...

. The electronic structure of tungsten makes it one of the main sources for

X-ray An X-ray, or, much less commonly, X-radiation, is a penetrating form of high-energy electromagnetic radiation. Most X-rays have a wavelength ranging from 10 picometers to 10 nanometers, corresponding to frequencies in the range 30&nb ...

targets,Hasz, Wayne Charles ''et al.'' (August 6, 2002) "X-ray target" and also for shielding from high-energy radiations (such as in the radiopharmaceutical industry for shielding radioactive samples of FDG). It is also used in gamma imaging as a material from which coded apertures are made, due to its excellent shielding properties. Tungsten powder is used as a filler material in

plastic Plastics are a wide range of synthetic or semi-synthetic materials that use polymers as a main ingredient. Their plasticity makes it possible for plastics to be moulded, extruded or pressed into solid objects of various shapes. This adaptab ...

composites, which are used as a nontoxic substitute for

bullet A bullet is a kinetic projectile, a component of firearm ammunition that is shot from a gun barrel. Bullets are made of a variety of materials, such as copper, lead, steel, polymer, rubber and even wax. Bullets are made in various shapes and co ...

shot Shot may refer to: Arts, entertainment, and media * ''Shot'' (album), by The Jesus Lizard *''Shot, Illusion, New God'', an EP by Gruntruck *''Shot Rev 2.0'', a video album by The Sisters of Mercy * "Shot" (song), by The Rasmus * ''Shot'' (2017 fi ...

, and radiation shields. Since this element's thermal expansion is similar to borosilicate glass, it is used for making glass-to-metal seals. In addition to its high melting point, when tungsten is doped with potassium, it leads to an increased shape stability (compared with non-doped tungsten). This ensures that the filament does not sag, and no undesired changes occur.

Nanowires

Through top-down nanofabrication processes, tungsten nanowires have been fabricated and studied since 2002. Due to a particularly high surface to volume ratio, the formation of a surface oxide layer and the single crystal nature of such material, the mechanical properties differ fundamentally from those of bulk tungsten. Such tungsten nanowires have potential applications in nanoelectronics and importantly as pH probes and gas sensors. In similarity to silicon nanowires, tungsten nanowires are frequently produced from a bulk tungsten precursor followed by a thermal oxidation step to control morphology in terms of length and aspect ratio. Using the

Deal–Grove model The Deal–Grove model mathematically describes the growth of an oxide layer on the surface of a material. In particular, it is used to predict and interpret thermal oxidation of silicon in semiconductor device fabrication. The model was first pub ...

it is possible to predict the oxidation kinetics of nanowires fabricated through such thermal oxidation processing.

Fusion power

Due to its high melting point and good erosion resistance, tungsten is a lead candidate for the most exposed sections of the plasma-facing inner wall of nuclear fusion reactors. It will be used as the plasma-facing material of the

divertor In nuclear fusion power research, a divertor is a device within a tokamak or a stellarator that allows the online removal of waste material from the plasma while the reactor is still operating. This allows control over the buildup of fusion prod ...

in the

ITER ITER (initially the International Thermonuclear Experimental Reactor, ''iter'' meaning "the way" or "the path" in Latin) is an international nuclear fusion research and engineering megaproject aimed at creating energy by replicating, on Earth ...

reactor, and is currently in use in the

JET Jet, Jets, or The Jet(s) may refer to: Aerospace * Jet aircraft, an aircraft propelled by jet engines ** Jet airliner ** Jet engine ** Jet fuel * Jet Airways, an Indian airline * Wind Jet (ICAO: JET), an Italian airline * Journey to Enceladus a ...

test reactor.

Biological role

Tungsten, at atomic number ''Z'' = 74, is the heaviest element known to be biologically functional. It is used by some bacteria and

, but not in

eukaryotes Eukaryotes () are organisms whose cells have a nucleus. All animals, plants, fungi, and many unicellular organisms, are Eukaryotes. They belong to the group of organisms Eukaryota or Eukarya, which is one of the three domains of life. Bacte ...

. For example,

enzyme Enzymes () are proteins that act as biological catalysts by accelerating chemical reactions. The molecules upon which enzymes may act are called substrates, and the enzyme converts the substrates into different molecules known as products. A ...

s called

oxidoreductase In biochemistry, an oxidoreductase is an enzyme that catalyzes the transfer of electrons from one molecule, the reductant, also called the electron donor, to another, the oxidant, also called the electron acceptor. This group of enzymes usually ut ...

s use tungsten similarly to

by using it in a tungsten- pterin complex with molybdopterin (molybdopterin, despite its name, does not contain molybdenum, but may complex with either molybdenum or tungsten in use by living organisms). Tungsten-using enzymes typically reduce carboxylic acids to aldehydes. The tungsten oxidoreductases may also catalyse oxidations. The first tungsten-requiring enzyme to be discovered also requires selenium, and in this case the tungsten-selenium pair may function analogously to the molybdenum-sulfur pairing of some molybdopterin-requiring enzymes. One of the enzymes in the oxidoreductase family which sometimes employ tungsten (bacterial

formate dehydrogenase Formate dehydrogenases are a set of enzymes that catalyse the oxidation of formate to carbon dioxide, donating the electrons to a second substrate, such as NAD+ in formate:NAD+ oxidoreductase () or to a cytochrome in formate:ferricytochrome-b1 o ...

H) is known to use a selenium-molybdenum version of molybdopterin.

Acetylene hydratase Acetylene hydratase (, AH) is a bacterial enzyme, originally discovered in the anaerobic microorganism ''Pelobactor acetylenicus'', that catalyzes the non-redox hydration of acetylene to form acetaldehyde. :C2H2 + H2O → CH3CHO The mechanism is ...

is an unusual

metalloenzyme Metalloprotein is a generic term for a protein that contains a metal ion cofactor. A large proportion of all proteins are part of this category. For instance, at least 1000 human proteins (out of ~20,000) contain zinc-binding protein domains al ...

in that it catalyzes a hydration reaction. Two reaction mechanisms have been proposed, in one of which there is a direct interaction between the tungsten atom and the C≡C triple bond. Although a tungsten-containing xanthine dehydrogenase from bacteria has been found to contain tungsten-molydopterin and also non-protein bound selenium, a tungsten-selenium molybdopterin complex has not been definitively described. In soil, tungsten metal oxidizes to the

anion. It can be selectively or non-selectively imported by some prokaryotic organisms and may substitute for

molybdate In chemistry a molybdate is a compound containing an oxoanion with molybdenum in its highest oxidation state of 6. Molybdenum can form a very large range of such oxoanions which can be discrete structures or polymeric extended structures, althoug ...

in certain

s. Its effect on the action of these enzymes is in some cases inhibitory and in others positive. The soil's chemistry determines how the tungsten polymerizes;

alkaline In chemistry, an alkali (; from ar, القلوي, al-qaly, lit=ashes of the saltwort) is a base (chemistry), basic, ionic compound, ionic salt (chemistry), salt of an alkali metal or an alkaline earth metal. An alkali can also be defined as ...

soils cause monomeric tungstates; acidic soils cause polymeric tungstates. Sodium tungstate and

have been studied for their effect on

earthworm An earthworm is a terrestrial invertebrate that belongs to the phylum Annelida. They exhibit a tube-within-a-tube body plan; they are externally segmented with corresponding internal segmentation; and they usually have setae on all segments. Th ...

s. Lead was found to be lethal at low levels and sodium tungstate was much less toxic, but the tungstate completely inhibited their reproductive ability. Tungsten has been studied as a biological copper metabolic

antagonist An antagonist is a character in a story who is presented as the chief foe of the protagonist. Etymology The English word antagonist comes from the Greek ἀνταγωνιστής – ''antagonistēs'', "opponent, competitor, villain, enemy, riv ...

, in a role similar to the action of molybdenum. It has been found that salts may be used as biological copper chelation chemicals, similar to the

tetrathiomolybdate Tetrathiomolybdate, also spelled tiomolibdate (USAN), is the anion of the following salts: * Ammonium tetrathiomolybdate, a building block in bioinorganic chemistry * Bis-choline tetrathiomolybdate Tiomolibdic acid (trade name Decuprate) is a c ...

In archaea

Tungsten is essential for some archaea. The following tungsten-utilizing enzymes are known: *

Aldehyde ferredoxin oxidoreductase In enzymology, an aldehyde ferredoxin oxidoreductase () is an enzyme that catalyzes the chemical reaction :an aldehyde + H2O + 2 oxidized ferredoxin an acid + 2 H+ + 2 reduced ferredoxin This enzyme belongs to the family of oxidoreductases, ...

(AOR) in ''

Thermococcus In taxonomy, ''Thermococcus'' is a genus of thermophilic Archaea in the family the Thermococcaceae. Members of the genus ''Thermococcus'' are typically irregularly shaped coccoid species, ranging in size from 0.6 to 2.0 μm in diameter. Some ...

'' strain ES-1 * Formaldehyde ferredoxin oxidoreductase (FOR) in '' Thermococcus litoralis'' *

Glyceraldehyde-3-phosphate ferredoxin oxidoreductase In enzymology, a glyceraldehyde-3-phosphate dehydrogenase (ferredoxin) () is an enzyme that catalyzes the chemical reaction :D-glyceraldehyde-3-phosphate + H2O + 2 oxidized ferredoxin \rightleftharpoons 3-phospho-D-glycerate + 2 H+ + 2 reduced fer ...

(GAPOR) in '' Pyrococcus furiosus'' A ''wtp'' system is known to selectively transport tungsten in archaea: * WtpA is tungsten-binding protein of ABC family of transporters * WptB is a permease * WtpC is

ATPase ATPases (, Adenosine 5'-TriPhosphatase, adenylpyrophosphatase, ATP monophosphatase, triphosphatase, SV40 T-antigen, ATP hydrolase, complex V (mitochondrial electron transport), (Ca2+ + Mg2+)-ATPase, HCO3−-ATPase, adenosine triphosphatase) are ...

Health factors

Because tungsten is a rare metal and its compounds are generally inert, the effects of tungsten on the environment are limited. The abundance of tungsten in the Earth's crust is thought to be about 1.5 parts per million. It is one of the rarer elements. It was at first believed to be relatively inert and an only slightly toxic metal, but beginning in the year 2000, the risk presented by tungsten alloys, its dusts and particulates to induce cancer and several other adverse effects in animals as well as humans has been highlighted from in vitro and in vivo experiments. The

median lethal dose In toxicology, the median lethal dose, LD50 (abbreviation for "lethal dose, 50%"), LC50 (lethal concentration, 50%) or LCt50 is a toxic unit that measures the lethal dose of a toxin, radiation, or pathogen. The value of LD50 for a substance is the ...

LD₅₀ depends strongly on the animal and the method of administration and varies between 59 mg/kg (intravenous, rabbits) and 5000 mg/kg (tungsten metal powder, intraperitoneal, rats). People can be exposed to tungsten in the workplace by breathing it in, swallowing it, skin contact, and eye contact. The National Institute for Occupational Safety and Health (NIOSH) has set a recommended exposure limit (REL) of 5 mg/m³ over an 8-hour workday and a short term limit of 10 mg/m³.

References

External links

Properties, Photos, History, MSDS

at '' The Periodic Table of Videos'' (University of Nottingham)
Picture in the collection from Heinrich Pniok

Elementymology & Elements Multidict by Peter van der Krogt – Tungsten

International Tungsten Industry Association
{{Authority control Chemical elements Transition metals Refractory metals Chemical elements with body-centered cubic structure Native element minerals