Synthetic fibers or synthetic fibres (in

British English British English (BrE, en-GB, or BE) is, according to Lexico, Oxford Dictionaries, "English language, English as used in Great Britain, as distinct from that used elsewhere". More narrowly, it can refer specifically to the English language in ...

; see spelling differences) are

fiber Fiber or fibre (from la, fibra, links=no) is a natural or artificial substance that is significantly longer than it is wide. Fibers are often used in the manufacture of other materials. The strongest engineering materials often incorporate ...

s made by humans through

chemical synthesis As a topic of chemistry, chemical synthesis (or combination) is the artificial execution of chemical reactions to obtain one or several products. This occurs by physical and chemical manipulations usually involving one or more reactions. In moder ...

, as opposed to

natural fiber Natural fibers or natural fibres (see spelling differences) are fibers that are produced by geological processes, or from the bodies of plants or animals. They can be used as a component of composite materials, where the orientation of fibers ...

s that are directly derived from

living Living or The Living may refer to: Common meanings *Life, a condition that distinguishes organisms from inorganic objects and dead organisms ** Living species, one that is not extinct *Personal life, the course of an individual human's life * ...

organisms, such as plants (like cotton) or fur from animals. They are the result of extensive research by

scientist A scientist is a person who conducts Scientific method, scientific research to advance knowledge in an Branches of science, area of the natural sciences. In classical antiquity, there was no real ancient analog of a modern scientist. Instead, ...

s to replicate naturally occurring

animal Animals are multicellular, eukaryotic organisms in the Kingdom (biology), biological kingdom Animalia. With few exceptions, animals Heterotroph, consume organic material, Cellular respiration#Aerobic respiration, breathe oxygen, are Motilit ...

and plant fibers. In general, synthetic fibers are created by

extruding Extrusion is a process used to create objects of a fixed cross-sectional profile by pushing material through a die of the desired cross-section. Its two main advantages over other manufacturing processes are its ability to create very complex ...

fiber-forming materials through

spinnerets A spinneret is a silk-spinning organ of a spider or the larva of an insect. Some adult insects also have spinnerets, such as those borne on the forelegs of Embioptera. Spinnerets are usually on the underside of a spider's opisthosoma, and are ...

, forming a fiber. These are called synthetic or artificial fibers. The word polymer comes from a Greek prefix "poly" which means "many" and suffix "mer" which means "single units". (Note: each single unit of a polymer is called a monomer).

Early experiments

The first fully synthetic

was glass.

Joseph Swan Sir Joseph Wilson Swan FRS (31 October 1828 – 27 May 1914) was an English physicist, chemist, and inventor. He is known as an independent early developer of a successful incandescent light bulb, and is the person responsible for develop ...

invented one of the first artificial fibers in the early 1880s; today it would be called

semisynthetic Semisynthesis, or partial chemical synthesis, is a type of chemical synthesis that uses chemical compounds isolated from natural sources (such as microbial cell cultures or plant material) as the starting materials to produce novel compounds with ...

in precise usage. His fiber was drawn from a

cellulose Cellulose is an organic compound with the formula , a polysaccharide consisting of a linear chain of several hundred to many thousands of β(1→4) linked D-glucose units. Cellulose is an important structural component of the primary cell wall ...

liquid, formed by chemically modifying the fiber contained in tree bark. The synthetic fiber produced through this process was chemically similar in its potential applications to the carbon filament Swan had developed for his

incandescent light bulb An incandescent light bulb, incandescent lamp or incandescent light globe is an electric light with a wire filament heated until it glows. The filament is enclosed in a glass bulb with a vacuum or inert gas to protect the filament from oxida ...

, but Swan soon realized the potential of the fiber to revolutionize

textile manufacturing Textile Manufacturing or Textile Engineering is a major industry. It is largely based on the conversion of fibre into yarn, then yarn into fabric. These are then dyed or printed, fabricated into cloth which is then converted into useful goods ...

. In 1885, he unveiled fabrics he had manufactured from his synthetic material at the

International Inventions Exhibition The International Inventions Exhibition was a world's fair held in South Kensington in 1885. As with the earlier exhibitions in a series of fairs in South Kensington following the Great Exhibition, Queen Victoria was patron and her son Albert Edw ...

London London is the capital and largest city of England and the United Kingdom, with a population of just under 9 million. It stands on the River Thames in south-east England at the head of a estuary down to the North Sea, and has been a majo ...

. The next step was taken by

Hilaire de Chardonnet Louis-Marie Hilaire Bernigaud de Grange, Count (''Comte'') de Chardonnet (1 May 1839 – 11 March 1924) was a French engineer and industrialist from Besançon, and inventor of artificial silk. In the late 1870s, Chardonnet was working with Loui ...

, a French

engineer Engineers, as practitioners of engineering, are professionals who invent, design, analyze, build and test machines, complex systems, structures, gadgets and materials to fulfill functional objectives and requirements while considering the l ...

and

industrialist A business magnate, also known as a tycoon, is a person who has achieved immense wealth through the ownership of multiple lines of enterprise. The term characteristically refers to a powerful entrepreneur or investor who controls, through perso ...

, who invented the first artificial

silk Silk is a natural protein fiber, some forms of which can be woven into textiles. The protein fiber of silk is composed mainly of fibroin and is produced by certain insect larvae to form cocoons. The best-known silk is obtained from the coc ...

, which he called "Chardonnet silk". In the late 1870s, Chardonnet was working with

Louis Pasteur Louis Pasteur (, ; 27 December 1822 – 28 September 1895) was a French chemist and microbiologist renowned for his discoveries of the principles of vaccination, microbial fermentation and pasteurization, the latter of which was named afte ...

on a remedy to the epidemic that was destroying French

silkworms The domestic silk moth (''Bombyx mori''), is an insect from the moth family Bombycidae. It is the closest relative of ''Bombyx mandarina'', the wild silk moth. The silkworm is the larva or caterpillar of a silk moth. It is an economically imp ...

. Failure to clean up a spill in the darkroom resulted in Chardonnet's discovery of

nitrocellulose Nitrocellulose (also known as cellulose nitrate, flash paper, flash cotton, guncotton, pyroxylin and flash string, depending on form) is a highly flammable compound formed by nitrating cellulose through exposure to a mixture of nitric acid and ...

as a potential replacement for real silk. Realizing the value of such a discovery, Chardonnet began to develop his new product, which he displayed at the Paris Exhibition of 1889. Chardonnet's material was extremely flammable, and subsequently replaced with other, more stable materials.

Commercial products

The first successful process was developed in 1894 by English chemist

Charles Frederick Cross Charles Frederick Cross FRS (11 December 1855 – 15 April 1935) was a British chemist. Born in Brentford, Middlesex, his fatherCharles James Cross (14 October 1827 - 19 November 1910) was a schoolmaster turned soap manufacturer. After graduatin ...

, and his collaborators

Edward John Bevan Edward John Bevan (11 December 1856 – 17 October 1921) was an English chemist. He became a leader in the affairs of the Society of Public Analysts and editor of The Analyst. Bevan was notable for his caustic wit. He was born in Birkenhead. Af ...

and Clayton Beadle. They named the fiber "

viscose Rayon is a semi-synthetic fiber, made from natural sources of regenerated cellulose, such as wood and related agricultural products. It has the same molecular structure as cellulose. It is also called viscose. Many types and grades of viscose ...

", because the reaction product of

carbon disulfide Carbon disulfide (also spelled as carbon disulphide) is a neurotoxic, colorless, volatile liquid with the formula and structure . The compound is used frequently as a building block in organic chemistry as well as an industrial and chemical non ...

and

in basic conditions gave a highly viscous solution of

xanthate 150px, Sodium salt of ethyl xanthate Xanthate usually refers to a salt with the formula (R = alkyl; M+ = Na+, K+), thus they are the metal-thioate/''O''-esters of dithiocarbonate. The name ''xanthates'' is derived from Ancient Greek ''xanthos' ...

. The first commercial viscose

rayon Rayon is a semi-synthetic fiber, made from natural sources of regenerated cellulose, such as wood and related agricultural products. It has the same molecular structure as cellulose. It is also called viscose. Many types and grades of viscose f ...

was produced by the UK company

Courtaulds Courtaulds was a United Kingdom-based manufacturer of fabric, clothing, artificial fibres, and chemicals. It was established in 1794 and became the world's leading man-made fibre production company before being broken up in 1990 into Courtaulds ...

in 1905. The name "rayon" was adopted in 1924, with "viscose" being used for the viscous organic liquid used to make both rayon and

cellophane Cellophane is a thin, transparent sheet made of regenerated cellulose. Its low permeability to air, oils, greases, bacteria, and liquid water makes it useful for food packaging. Cellophane is highly permeable to water vapour, but may be coated w ...

. A similar product known as

cellulose acetate In biochemistry, cellulose acetate refers to any acetate ester of cellulose, usually cellulose diacetate. It was first prepared in 1865. A bioplastic, cellulose acetate is used as a film base in photography, as a component in some coatings, and ...

was discovered in 1865. Rayon and acetate are both artificial fibers, but not truly synthetic, being made from

wood Wood is a porous and fibrous structural tissue found in the stems and roots of trees and other woody plants. It is an organic materiala natural composite of cellulose fibers that are strong in tension and embedded in a matrix of lignin th ...

Nylon Nylon is a generic designation for a family of synthetic polymers composed of polyamides ( repeating units linked by amide links).The polyamides may be aliphatic or semi-aromatic. Nylon is a silk-like thermoplastic, generally made from petro ...

, the first synthetic fiber in the "fully synthetic" sense of that term, was developed by

Wallace Carothers Wallace Hume Carothers (; April 27, 1896 – April 29, 1937) was an American chemist, inventor and the leader of organic chemistry at DuPont, who was credited with the invention of nylon. Carothers was a group leader at the DuPont Experiment ...

, an American researcher at the chemical firm

DuPont DuPont de Nemours, Inc., commonly shortened to DuPont, is an American multinational chemical company first formed in 1802 by French-American chemist and industrialist Éleuthère Irénée du Pont de Nemours. The company played a major role in ...

in the 1930s. It soon made its debut in the

United States The United States of America (U.S.A. or USA), commonly known as the United States (U.S. or US) or America, is a country primarily located in North America. It consists of 50 states, a federal district, five major unincorporated territorie ...

as a replacement for

, just in time for the introduction of rationing during

World War II World War II or the Second World War, often abbreviated as WWII or WW2, was a world war that lasted from 1939 to 1945. It involved the vast majority of the world's countries—including all of the great powers—forming two opposin ...

. Its novel use as a material for women's

stockings Stockings (also known as hose, especially in a historical context) are close-fitting, variously elastic garments covering the leg from the foot up to the knee or possibly part or all of the thigh. Stockings vary in color, design, and transparen ...

overshadowed more practical uses, such as a replacement for the silk in

parachute A parachute is a device used to slow the motion of an object through an atmosphere by creating drag or, in a ram-air parachute, aerodynamic lift. A major application is to support people, for recreation or as a safety device for aviators, who ...

s and other

military A military, also known collectively as armed forces, is a heavily armed, highly organized force primarily intended for warfare. It is typically authorized and maintained by a sovereign state, with its members identifiable by their distinct ...

uses like

rope A rope is a group of yarns, plies, fibres, or strands that are twisted or braided together into a larger and stronger form. Ropes have tensile strength and so can be used for dragging and lifting. Rope is thicker and stronger than similarly ...

s. The first

polyester Polyester is a category of polymers that contain the ester functional group in every repeat unit of their main chain. As a specific material, it most commonly refers to a type called polyethylene terephthalate (PET). Polyesters include natural ...

fiber was patented in Britain in 1928 by the International General Electric company. It was also produced by British chemists working at the

Calico Printers' Association The Calico Printers' Association Ltd was a British textile company founded in 1899, from the amalgamation of 46 textile printing companies and 13 textile merchants. The industry had prospered in the latter half of the 19th century but the fierce ...

John Rex Whinfield John Rex Whinfield CBE (16 February 1901 in Sutton, Surrey, England – 6 July 1966 in Dorking, Surrey) was a British chemist. Together with James Tennant Dickson, Whinfield investigated polyesters and produced and patented the first polyeste ...

and James Tennant Dickson, in 1941. They produced and patented one of the first polyester fibers which they named

Terylene Polyethylene terephthalate (or poly(ethylene terephthalate), PET, PETE, or the obsolete PETP or PET-P), is the most common thermoplastic polymer resin of the polyester family and is used in fibres for clothing, containers for liquids and foods ...

, also known as

Dacron Polyethylene terephthalate (or poly(ethylene terephthalate), PET, PETE, or the obsolete PETP or PET-P), is the most common thermoplastic polymer resin of the polyester family and is used in fibres for clothing, containers for liquids and foods ...

, equal to or surpassing

nylon Nylon is a generic designation for a family of synthetic polymers composed of polyamides ( repeating units linked by amide links).The polyamides may be aliphatic or semi-aromatic. Nylon is a silk-like thermoplastic, generally made from petro ...

in toughness and resilience.Frank Greenaway, ‘Whinfield, John Rex (1901–1966)’, rev. Oxford Dictionary of National Biography, Oxford University Press, 200
accessed 20 June 2011
/ref> ICI and

went on to produce their own versions of the fiber. The world production of synthetic fibers was 55.2 million tonnes in 2014.

Descriptions

Synthetic fibers account for about half of all fiber usage, with applications in every field of fiber and textile technology. Although many classes of fibers based on synthetic polymers have been evaluated as potentially valuable commercial products, four of them -

acrylic Acrylic may refer to: Chemicals and materials * Acrylic acid, the simplest acrylic compound * Acrylate polymer, a group of polymers (plastics) noted for transparency and elasticity * Acrylic resin, a group of related thermoplastic or thermosett ...

and

polyolefin A polyolefin is a type of polymer with the general formula (CH2CHR)n where R is an alkyl group. They are usually derived from a small set of simple olefins (alkenes). Dominant in a commercial sense are polyethylene and polypropylene. More speciali ...

- dominate the market. These four account for approximately 98 percent by volume of synthetic fiber production, with polyester alone accounting for around 60 percent.

Pros

Synthetic fibers are more durable than most natural fibers and will readily pick-up different dyes. In addition, many synthetic fibers offer consumer-friendly functions such as stretching, waterproofing and stain resistance. Sunlight, moisture, and oils from human skin cause all fibers to break down and wear away. Natural fibers tend to be much more sensitive than synthetic blends. This is mainly because natural products are biodegradable. Natural fibers are susceptible to larval insect infestation; synthetic fibers are not a good food source for fabric-damaging insects. Compared to natural fibers, many synthetic fibers are more water-resistant and stain-resistant. Some are even specially enhanced to withstand damage from water or stains.

Cons

Most of synthetic fibers' disadvantages are related to their low melting temperature: * Mono-fibers do not trap air pockets like cotton and thus provide poor insulation. * Synthetic fibers burn more rapidly than natural fibers. * Prone to heat damage like damage by hot washing. * Melt relatively easily. * More electrostatic charge is generated by rubbing than with natural fibers. * Some consumers claim that textiles made with synthetic fibers are less skin-friendly or may cause discomfort over long periods of wear. * Non-biodegradable or far less biodegradable in comparison to natural fibers. * Most synthetic fibers absorb very little moisture and thus may become sticky when the body sweats. * Synthetic fibers are a source of microplastic pollution from laundry machines.

Common synthetic fibers

Common synthetic fibers include: *

(1931) *

Modacrylic A modacrylic is a synthetic copolymer. Modacrylics are soft, strong, resilient and dimensionally stable. They can be easily dyed, show good press and shape retention, and are quick to dry. They have outstanding resistance to chemicals and solvents, ...

(1949) *

Olefin In organic chemistry, an alkene is a hydrocarbon containing a carbon–carbon double bond. Alkene is often used as synonym of olefin, that is, any hydrocarbon containing one or more double bonds.H. Stephen Stoker (2015): General, Organic, an ...

(1949) *

Acrylic Acrylic may refer to: Chemicals and materials * Acrylic acid, the simplest acrylic compound * Acrylate polymer, a group of polymers (plastics) noted for transparency and elasticity * Acrylic resin, a group of related thermoplastic or thermosett ...

(1950) *

Polyester Polyester is a category of polymers that contain the ester functional group in every repeat unit of their main chain. As a specific material, it most commonly refers to a type called polyethylene terephthalate (PET). Polyesters include natural ...

(1953) Specialty synthetic fibers include: *

Rayon Rayon is a semi-synthetic fiber, made from natural sources of regenerated cellulose, such as wood and related agricultural products. It has the same molecular structure as cellulose. It is also called viscose. Many types and grades of viscose f ...

(1894) artificial silk *

Vinyon Vinyon is a synthetic fiber made from polyvinyl chloride. In some countries other than the United States, vinyon fibers are referred to as polyvinyl chloride fibers. It can bind non-woven fibers and fabrics. It was invented in 1939. It has th ...

(1939) * Saran (1941) *

Spandex Spandex, Lycra, or elastane is a synthetic fiber known for its exceptional elasticity. It is a polyether-polyurea copolymer that was invented in 1958 by chemist Joseph Shivers at DuPont's Benger Laboratory in Waynesboro, Virginia, US. The ge ...

(1959) *

Vinalon Vinylon, also known as Vinalon, is a synthetic fiber produced from polyvinyl alcohol, using anthracite and limestone as raw materials. Vinylon was first developed in Japan in 1939 by Ri Sung-gi, Ichiro Sakurada, and H. Kawakami. Trial production ...

(1939) *

Aramid Aramid fibers, short for aromatic polyamide, are a class of heat-resistant and strong synthetic fibers. They are used in aerospace and military applications, for ballistic-rated body armor fabric and ballistic composites, in marine cordage, ma ...

s (1961) - known as

Nomex Nomex is a flame-resistant meta-aramid material developed in the early 1960s by DuPont and first marketed in 1967. Properties Nomex and related aramid polymers are related to nylon, but have aromatic backbones, and hence are more rigid and mo ...

Kevlar Kevlar (para-aramid) is a strong, heat-resistant synthetic fiber, related to other aramids such as Nomex and Technora. Developed by Stephanie Kwolek at DuPont in 1965, the high-strength material was first used commercially in the early 1970s a ...

and

Twaron Twaron (a brand name of Teijin Aramid) is a para-aramid. It is a heat-resistant and strong synthetic fibre developed in the early 1970s by the Dutch company Akzo Nobel's division Enka BV, later Akzo Industrial Fibers. The research name of the para ...

* Modal (1960s) * Dyneema/Spectra (1979) * PBI (Polybenzimidazole fiber) (1983) * Sulfar (1983) *

Lyocell Lyocell, originally trademarked in 1982 as Tencel, is a form of regenerated cellulose. It consists of cellulose fibers, made by dissolving pulp and then reconstituting it by dry jet-wet spinning. The fiber is used to make textiles for clothing a ...

(1992) (artificial, not synthetic) *

PLA PLA may refer to: Organizations Politics and military * People's Liberation Army, the armed forces of China and of the ruling Chinese Communist Party * People's Liberation Army (disambiguation) ** Irish National Liberation Army, formerly called ...

(2002) * M-5 (PIPD fiber) *

Orlon Acrylic fibers are synthetic fibers made from a polymer ( polyacrylonitrile) with an average molecular weight of ~100,000, about 1900 monomer units. For a fiber to be called "acrylic" in the US, the polymer must contain at least 85% acrylonitr ...

Zylon Zylon (IUPAC name: poly(''p''-phenylene-2,6-benzobisoxazole)) is a trademarked name for a range of thermoset liquid-crystalline polyoxazole. This synthetic polymer material was invented and developed by SRI International in the 1980s and manufact ...

(PBO fiber) *

Vectran Vectran is a manufactured fiber, spun from a liquid-crystal polymer (LCP) created by Celanese Corporation and now manufactured by Kuraray. Chemically it is an aromatic polyester produced by the polycondensation of 4-hydroxybenzoic acid and 6-hyd ...

(TLCP fiber) made from Vectra LCP polymer * Derclon used in manufacture of rugs Other synthetic materials used in fibers include: *

Acrylonitrile Acrylonitrile is an organic compound with the formula and the structure . It is a colorless, volatile liquid although commercial samples can be yellow due to impurities. It has a pungent odor of garlic or onions. In terms of its molecular ...

rubber (1930) Modern fibers that are made from older artificial materials include: *

Glass fiber Glass fiber ( or glass fibre) is a material consisting of numerous extremely fine fibers of glass. Glassmakers throughout history have experimented with glass fibers, but mass manufacture of glass fiber was only made possible with the inventio ...

(1938) is used for: ** industrial, automotive, and home insulation (

glass wool Glass wool is an insulating material made from glass fiber arranged using a binder into a texture similar to wool. The process traps many small pockets of air between the glass, and these small air pockets result in high thermal insulation prop ...

) ** reinforcement of

composite material A composite material (also called a composition material or shortened to composite, which is the common name) is a material which is produced from two or more constituent materials. These constituent materials have notably dissimilar chemical or ...

s (

glass-reinforced plastic Fiberglass (American English) or fibreglass (Commonwealth English) is a common type of fiber-reinforced plastic using glass fiber. The fibers may be randomly arranged, flattened into a sheet called a chopped strand mat, or woven into glass cloth ...

glass fiber reinforced concrete Glass fibre reinforced concrete (GFRC) is a type of fibre-reinforced concrete. The product is also known as glassfibre reinforced concrete or GRC in British English. Glass fibre concretes are mainly used in exterior building façade panels and ...

) ** specialty papers in

battery Battery most often refers to: * Electric battery, a device that provides electrical power * Battery (crime), a crime involving unlawful physical contact Battery may also refer to: Energy source *Automotive battery, a device to provide power t ...

separators and filtration *

Metallic fiber Metallic fibers are manufactured fibers composed of metal, metallic alloys, plastic-coated metal, metal-coated plastic, or a core completely covered by metal. Having their origin in textile and clothing applications, gold and silver fibers have ...

(1946) is used for: ** adding metallic properties to

clothing Clothing (also known as clothes, apparel, and attire) are items worn on the body. Typically, clothing is made of fabrics or textiles, but over time it has included garments made from animal skin and other thin sheets of materials and natural ...

for the purpose of

fashion Fashion is a form of self-expression and autonomy at a particular period and place and in a specific context, of clothing, footwear, lifestyle, accessories, makeup, hairstyle, and body posture. The term implies a look defined by the fashion in ...

(usually made with composite plastic and

metal foil A foil is a very thin sheet of metal, typically made by hammering or rolling.Britannica, The Editors of Encyclopaedia. "foil". Encyclopedia Britannica, 6 Nov. 2008https://www.britannica.com/technology/foil-metallurgy.Accessed 11 September 2022. Fo ...

s) ** elimination and prevention of static charge build-up ** conducting

electricity Electricity is the set of physical phenomena associated with the presence and motion of matter that has a property of electric charge. Electricity is related to magnetism, both being part of the phenomenon of electromagnetism, as described ...

to transmit information ** conduction of

heat In thermodynamics, heat is defined as the form of energy crossing the boundary of a thermodynamic system by virtue of a temperature difference across the boundary. A thermodynamic system does not ''contain'' heat. Nevertheless, the term is al ...

Early experiments

Commercial products

Descriptions

Pros

Cons

Common synthetic fibers

See also

References

Further reading