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Rayon
Rayon is a semi-synthetic fiber, made from natural sources of regenerated cellulose, such as wood and related agricultural products. It has the same molecular structure as cellulose. It is also called viscose. Many types and grades of viscose fibers and films exist. Some imitate the feel and texture of natural fibers such as silk, wool, cotton, and linen. The types that resemble silk are often called artificial silk. The fibre is used to make textiles for clothing and other purposes. Rayon production involves solubilizing cellulose to allow turning the fibers into required form. Three common ways to solubilize are the cuprammonium process, not in use today, using ammoniacal solutions of copper salts; the viscose process, the most common today, using alkali and carbon sulfide; and the Lyocell process, using amine oxide. The last avoids the neurotoxic carbon sulfide of the viscose process but is also more expensive. Rayon and its variants Rayon is produced by dissolving cel ...
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Rayon Synthesis
Rayon is a semi-synthetic fiber, made from natural sources of regenerated cellulose fiber, cellulose, such as wood and related agricultural products. It has the same molecular structure as cellulose. It is also called viscose. Many types and grades of viscose fibers and films exist. Some imitate the feel and texture of natural fibers such as silk, wool, cotton, and linen. The types that resemble silk are often called Art silk, artificial silk. The fibre is used to make textiles for clothing and other purposes. Rayon production involves solubilizing cellulose to allow turning the fibers into required form. Three common ways to solubilize are the Cuprammonium rayon, cuprammonium process, not in use today, using ammoniacal solutions of copper salts; the viscose process, the most common today, using alkali and Carbon_disulfide, carbon sulfide; and the Lyocell process, using amine oxide. The last avoids the neurotoxic carbon sulfide of the viscose process but is also more expensive. ...
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Vereinigte Glanzstoff Fabriken AG
Vereinigte Glanzstoff-Fabriken (VGF, United Rayon Factories) was a German manufacturer of artificial fiber founded in 1899 that became one of the leading European producers of rayon. During the first thirty years VGF cooperated closely with the British manufacturer Courtaulds and other companies to share technology and maintain prices by avoiding competition. It merged with the Dutch firm Enka in 1929 under the holding company Algemene Kunstzijde Unie (AKU), but the two retained their legal identities. AKU made significant investments in rayon production in the United States. The company suffered government interference in Nazi Germany (1933–45) and lost competitive strength during World War II, but partly recovered after the war with American assistance. In 1969 AKU merged with the Dutch manufacturer KZO to form AKZO, now part of AkzoNobel. Successor companies formed during various divestitures, mergers and acquisitions continue to be active in various related industries. Origi ...
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Carbon Disulfide
Carbon disulfide (also spelled as carbon disulphide) is a neurotoxic, colorless, volatile liquid with the formula and structure . The compound is used frequently as a building block in organic chemistry as well as an industrial and chemical non-polar solvent. It has an "ether-like" odor, but commercial samples are typically contaminated with foul-smelling impurities.. It is of comparable toxicity to carbon monoxide. History In 1796, the German chemist Wilhelm August Lampadius (1772–1842) first prepared carbon disulfide by heating pyrite with moist charcoal. He called it "liquid sulfur" (''flüssig Schwefel''). The composition of carbon disulfide was finally determined in 1813 by the team of the Swedish chemist Jöns Jacob Berzelius (1779–1848) and the Swiss-British chemist Alexander Marcet (1770–1822). Their analysis was consistent with an empirical formula of CS2. Occurrence, manufacture, properties Small amounts of carbon disulfide are released by volcanic eruptio ...
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Cuprammonium Rayon
Cuprammonium rayon is a rayon fiber made from cellulose dissolved in a cuprammonium solution, Schweizer's reagent. It is produced by making cellulose a soluble compound by combining it with copper and ammonia with caustic soda. The solution is passed through a spinneret and the cellulose is regenerated in hardening baths that remove the copper and ammonia and neutralize the caustic soda. Cuprammonium rayon is usually made in fine filaments that are used in lightweight summer dresses and blouses, sometimes in combination with cotton to make textured fabrics with slubbed, uneven surfaces. The fabric is commonly known by the trade name "Bemberg", owned by the J.P. Bemberg company. The fabric may also be known as "cupro" or "cupra". It is also known as "ammonia silk" on Chinese fashion retail websites. History Cuprammonium rayon was invented in 1890. Swiss chemist Matthias Eduard Schweizer (1818–1860) discovered that cellulose dissolves in tetraaminecopper dihydroxide. Max Fr ...
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Cuprammonium Rayon
Cuprammonium rayon is a rayon fiber made from cellulose dissolved in a cuprammonium solution, Schweizer's reagent. It is produced by making cellulose a soluble compound by combining it with copper and ammonia with caustic soda. The solution is passed through a spinneret and the cellulose is regenerated in hardening baths that remove the copper and ammonia and neutralize the caustic soda. Cuprammonium rayon is usually made in fine filaments that are used in lightweight summer dresses and blouses, sometimes in combination with cotton to make textured fabrics with slubbed, uneven surfaces. The fabric is commonly known by the trade name "Bemberg", owned by the J.P. Bemberg company. The fabric may also be known as "cupro" or "cupra". It is also known as "ammonia silk" on Chinese fashion retail websites. History Cuprammonium rayon was invented in 1890. Swiss chemist Matthias Eduard Schweizer (1818–1860) discovered that cellulose dissolves in tetraaminecopper dihydroxide. Max Fr ...
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Oberbruch Industry Park
Oberbruch Industry Park (German: Industriepark Oberbruch), is a former site of Akzo Nobel in Heinsberg, Germany's most western district, near the Dutch border. It was founded in 1891 as a location for fiber industries. It is the birthplace of the German rayon and man-made fiber industry. Today, it is a diversified multi-user site, hosting companies from fields of industry such as high-performance fibers and energy technologies as well as from industrial biotechnology. Oberbruch Industry Park is the competency center for carbon (fiber) technology in North Rhine-Westphalia (NRW). Since 2000, the industry park has been operated by the Dutch energy company Nuon, the first independent industrial park operator not to come from the chemical industry. Since January 7, 2009 N.V. Nuon Energy has been part of Vattenfall. Rayon and man-made fibre industry Rheinische Glühlampenfabrik Dr. Max Fremery & Co Today's Oberbruch Industry Park was founded as "Rheinische Glühlampenfabrik Dr. M ...
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Lyocell
Lyocell, originally trademarked in 1982 as Tencel, is a form of regenerated cellulose. It consists of cellulose fibers, made by dissolving pulp and then reconstituting it by dry jet-wet spinning. The fiber is used to make textiles for clothing and other purposes. Unlike rayon made by some of the more common viscose processes, Lyocell production does not use carbon disulfide, which is toxic to workers and the environment. "Lyocell" has become a genericized trademark, used to refer to the Lyocell process for making cellulose fibers. The U.S. Federal Trade Commission defines Lyocell as "a fiber composed of cellulose precipitated from an organic solution in which no substitution of the hydroxy groups takes place, and no chemical intermediates are formed". It classifies the fiber as a sub-category of rayon. Names Other trademarked names for Lyocell fibers are Lenzing Lyocell (Lenzing), Newcell (Akzo Nobel), and Seacell (Zimmer AG).B. Ozipek, H. Karakas, in Advances in Filament Yar ...
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Carbon (fiber)
Carbon fibers or carbon fibres (alternatively CF, graphite fiber or graphite fibre) are fibers about in diameter and composed mostly of carbon atoms. Carbon fibers have several advantages: high stiffness, high tensile strength, high strength to weight ratio, high chemical resistance, high-temperature tolerance, and low thermal expansion. These properties have made carbon fiber very popular in aerospace, civil engineering, military, motorsports, and other competition sports. However, they are relatively expensive compared to similar fibers, such as glass fiber, basalt fibers, or plastic fibers. To produce a carbon fiber, the carbon atoms are bonded together in crystals that are more or less aligned parallel to the fiber's long axis as the crystal alignment gives the fiber a high strength-to-volume ratio (in other words, it is strong for its size). Several thousand carbon fibers are bundled together to form a tow, which may be used by itself or woven into a fabric. Carbon f ...
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Art Silk
Artificial silk or art silk is any synthetic fiber which resembles silk, but typically costs less to produce. Frequently, "artificial silk" is just a synonym for rayon. When made out of bamboo viscose it is also sometimes called bamboo silk. The first successful artificial silks were developed in the 1890s of cellulose fiber and marketed as ''art silk'' or ''viscose'', a trade name for a specific manufacturer. In 1924, the name of the fiber was officially changed in the U.S. to rayon, although the term ''viscose'' continued to be used in Europe. The material is commonly referred to in the industry as ''viscose rayon''. In 1931, Henry Ford hired chemists Robert Boyer and Frank Calvert to produce artificial silk made with soybean fibers. They succeeded in making a textile fiber of spun soy protein fibers, hardened or tanned in a formaldehyde bath, which was given the name Azlon. It was usable for making suits, felt hats, and overcoats. Though pilot production of Azlon reached ...
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Matthias Eduard Schweizer
Matthias Eduard Schweizer (8 August 1818 – 23 October 1860) was a Swiss chemist who in 1857 invented Schweizer's reagent, in which cellulose can be dissolved to produce artificial silk or rayon. He was one of the pioneers of the synthetic textile industry. Life Matthias Eduard Schweizer was born on 8 August 1818 in Wila, Zurich canton. He was awarded his doctorate in at the University of Zurich, then worked as an assistant at the Zurich Polytechnic. He was a student and assistant of Carl Jacob Löwig, and was mainly involved in analysis of different minerals. He lectured at the university, and was an associate professor at the university from 1852. From 1855 he taught chemistry at the Higher Industrial School (''Oberen Industrieschule'') in Zurich. Schweizer published a paper in 1857 (''Das Kupferoxid-Ammoniak, ein Auflösungsmittel für die Pflanzenfaser'') in which he reported that cotton, linen cellulose and silk could be dissolved in a cuprammonium solution. He found that af ...
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Semi-synthetic Fiber
Fiber or fibre (from la, fibra, links=no) is a natural or artificial substance that is significantly longer than it is wide. Fibers are often used in the manufacture of other materials. The strongest engineering materials often incorporate fibers, for example carbon fiber and ultra-high-molecular-weight polyethylene. Synthetic fibers can often be produced very cheaply and in large amounts compared to natural fibers, but for clothing natural fibers can give some benefits, such as comfort, over their synthetic counterparts. Natural fibers Natural fibers develop or occur in the fiber shape, and include those produced by plants, animals, and geological processes. They can be classified according to their origin: *Vegetable fibers are generally based on arrangements of cellulose, often with lignin: examples include cotton, hemp, jute, flax, abaca, piña, ramie, sisal, bagasse, and banana. Plant fibers are employed in the manufacture of paper and textile (cloth), and dietar ...
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Max Fremery
Max Fremery (29 March 1859 – 1 March 1932) was a German chemist and industrialist. He was one of the founders of the (VGF) in 1899. VGF became a major manufacturer of artificial fibers. Early years (1859–85) Fremery was born in Cologne on 29 March 1859. His parents were Christian Fremery (1816–63), a wine and textile merchant, and Julie Vinman (1816–89). He worked in the workshops of the Rhenish Railway Company (') in Cologne, and then in the blast furnace and steelworks of '. He studied chemistry, graduating in Freiburg im Breisgau, then worked as a chemist, including working in England for a period. In 1883 he was employed with the ''Electriciteits Maatschappij'' in Rotterdam in developing a light filament. In the mid-1880s Fremery and the Austrian engineer Johann Urban (1863–1940), whom he had met in Amsterdam, took over the technical management of a light bulb factory in Gelnhausen. In 1885 Fremery married Margarete Alder. She died in 1892, and in 1897 he married ...
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