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Sulfosalt minerals are sulfide minerals with the general formula , where *A represents a
metal A metal (from Greek μέταλλον ''métallon'', "mine, quarry, metal") is a material that, when freshly prepared, polished, or fractured, shows a lustrous appearance, and conducts electricity and heat relatively well. Metals are typi ...
such as
copper Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish ...
,
lead Lead is a chemical element with the Symbol (chemistry), symbol Pb (from the Latin ) and atomic number 82. It is a heavy metals, heavy metal that is density, denser than most common materials. Lead is Mohs scale of mineral hardness#Intermediate ...
,
silver Silver is a chemical element with the Symbol (chemistry), symbol Ag (from the Latin ', derived from the Proto-Indo-European wikt:Reconstruction:Proto-Indo-European/h₂erǵ-, ''h₂erǵ'': "shiny" or "white") and atomic number 47. A soft, whi ...
,
iron Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in ...
, and rarely mercury,
zinc Zinc is a chemical element with the symbol Zn and atomic number 30. Zinc is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodic t ...
,
vanadium Vanadium is a chemical element with the symbol V and atomic number 23. It is a hard, silvery-grey, malleable transition metal. The elemental metal is rarely found in nature, but once isolated artificially, the formation of an oxide layer ( pass ...
*B usually represents semi-metal such as
arsenic Arsenic is a chemical element with the symbol As and atomic number 33. Arsenic occurs in many minerals, usually in combination with sulfur and metals, but also as a pure elemental crystal. Arsenic is a metalloid. It has various allotropes, bu ...
,
antimony Antimony is a chemical element with the symbol Sb (from la, stibium) and atomic number 51. A lustrous gray metalloid, it is found in nature mainly as the sulfide mineral stibnite (Sb2S3). Antimony compounds have been known since ancient ti ...
,
bismuth Bismuth is a chemical element with the symbol Bi and atomic number 83. It is a post-transition metal and one of the pnictogens, with chemical properties resembling its lighter group 15 siblings arsenic and antimony. Elemental bismuth occurs ...
, and rarely
germanium Germanium is a chemical element with the symbol Ge and atomic number 32. It is lustrous, hard-brittle, grayish-white and similar in appearance to silicon. It is a metalloid in the carbon group that is chemically similar to its group neighbo ...
, or metals like tin and rarely
vanadium Vanadium is a chemical element with the symbol V and atomic number 23. It is a hard, silvery-grey, malleable transition metal. The elemental metal is rarely found in nature, but once isolated artificially, the formation of an oxide layer ( pass ...
*X is
sulfur Sulfur (or sulphur in British English) is a chemical element with the symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with a chemical formul ...
or rarely
selenium Selenium is a chemical element with the symbol Se and atomic number 34. It is a nonmetal (more rarely considered a metalloid) with properties that are intermediate between the elements above and below in the periodic table, sulfur and telluriu ...
and/or
tellurium Tellurium is a chemical element with the symbol Te and atomic number 52. It is a brittle, mildly toxic, rare, silver-white metalloid. Tellurium is chemically related to selenium and sulfur, all three of which are chalcogens. It is occasionally fo ...
. The Strunz classification includes the sulfosalts in a ''sulfides and sulfosalts'' superclass. A group which have similar appearing formulas are the sulfarsenides (for example cobaltite (Co,Fe)AsS). In sulfarsenides the arsenic substitutes for
sulfide Sulfide (British English also sulphide) is an inorganic anion of sulfur with the chemical formula S2− or a compound containing one or more S2− ions. Solutions of sulfide salts are corrosive. ''Sulfide'' also refers to chemical compounds l ...
anion An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by conve ...
s whereas in the sulfosalts the arsenic substitutes for a metal
cation An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by conve ...
.Klein, Cornelis and Cornelius S. Hurlbut (1985). ''Manual of Mineralogy'', 20th ed., John Wiley and Sons, New York . About 200 sulfosalt minerals are known. Examples include: File:Proustite (long prismatic crystal) - Chanarcillo, Copiapo Province, Atacama Region, Chile.jpg, As illustrated by this specimen of
proustite Proustite is a sulfosalt mineral consisting of silver sulfarsenide, Ag3 As S3, known also as light red silver or ruby silver ore, and an important source of the metal. It is closely allied to the corresponding sulfantimonide, pyrargyrite, from w ...
, sulfosalt minerals are often deeply colored.
* type ** Pyrargyrite **
Proustite Proustite is a sulfosalt mineral consisting of silver sulfarsenide, Ag3 As S3, known also as light red silver or ruby silver ore, and an important source of the metal. It is closely allied to the corresponding sulfantimonide, pyrargyrite, from w ...
**
Tetrahedrite Tetrahedrite is a copper antimony sulfosalt mineral with formula: . It is the antimony endmember of the continuous solid solution series with arsenic-bearing tennantite. Pure endmembers of the series are seldom if ever seen in nature. Of the t ...
** Tennantite * type ** Enargite ** Sulvanite ** Samsonite ** Geocronite **
Gratonite Gratonite is a lead-arsenic sulfosalt mineral, with the chemical composition Pb9As4S15. Gratonite was discovered in 1939 at the Excelsior Mine, Cerro de Pasco, Peru , image_flag = Flag of Peru.svg , image_coat = E ...
* type ** Bournonite **
Seligmannite Seligmanite is a rare mineral, with the chemical formula PbCuAsS3. Originally described from the Lengenbach Quarry, Valais, Valais Canton, Switzerland; it has also been found in the Raura district, Lima Region, Peru; at Tsumeb, Oshikoto Region, Na ...
** Aikinite * type ** Boulangerite ** Matildite ** Smithite ** Chalcostibite ** Emplectite ** Teallite * type ** Ramdohrite ** Jamesonite ** Cosalite * type ** Andorite ** Lindstromite * type ** Zinkenite ** Berthierite ** Cylindrite


Nickel–Strunz Classification -02- Sulfosalts

IMA-CNMNC proposes a new hierarchical scheme (Mills et al., 2009). This list uses the Classification of Nickel–Strunz (
mindat.org Mindat.org is a non-commercial online database, claiming to be the largest mineral database and mineralogy, mineralogical reference website on the Internet. It is used by professional mineralogists, geologists, and amateur mineral collecting, mi ...
, 10 ed, pending publication). *Abbreviations: **"*" - discredited (IMA/CNMNC status). **"?" - questionable/doubtful (IMA/CNMNC status). **"REE" -
Rare-earth element The rare-earth elements (REE), also called the rare-earth metals or (in context) rare-earth oxides or sometimes the lanthanides (yttrium and scandium are usually included as rare earths), are a set of 17 nearly-indistinguishable lustrous silv ...
(Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu) **"PGE" - Platinum-group element (Ru, Rh, Pd, Os, Ir, Pt) **03.C Aluminofluorides, 06 Borates, 08 Vanadates (04.H V ,6/sup> Vanadates), 09 Silicates: ***Neso: insular (from
Greek Greek may refer to: Greece Anything of, from, or related to Greece, a country in Southern Europe: *Greeks, an ethnic group. *Greek language, a branch of the Indo-European language family. **Proto-Greek language, the assumed last common ancestor ...
νῆσος ''nēsos'', island) ***Soro: grouping (from
Greek Greek may refer to: Greece Anything of, from, or related to Greece, a country in Southern Europe: *Greeks, an ethnic group. *Greek language, a branch of the Indo-European language family. **Proto-Greek language, the assumed last common ancestor ...
σωρός ''sōros'', heap, mound (especially of corn)) ***Cyclo: ring (from
Greek Greek may refer to: Greece Anything of, from, or related to Greece, a country in Southern Europe: *Greeks, an ethnic group. *Greek language, a branch of the Indo-European language family. **Proto-Greek language, the assumed last common ancestor ...
κύκλος ''kyklos'', wheel, ring, round) ***Ino: chain (from
Greek Greek may refer to: Greece Anything of, from, or related to Greece, a country in Southern Europe: *Greeks, an ethnic group. *Greek language, a branch of the Indo-European language family. **Proto-Greek language, the assumed last common ancestor ...
ἴς enitive: ἰνός ''inos'' fibre) ***Phyllo: sheet (from
Greek Greek may refer to: Greece Anything of, from, or related to Greece, a country in Southern Europe: *Greeks, an ethnic group. *Greek language, a branch of the Indo-European language family. **Proto-Greek language, the assumed last common ancestor ...
φύλλον ''phyllon'', leaf) ***Tekto: three-dimensional framework (from
Greek Greek may refer to: Greece Anything of, from, or related to Greece, a country in Southern Europe: *Greeks, an ethnic group. *Greek language, a branch of the Indo-European language family. **Proto-Greek language, the assumed last common ancestor ...
stem τεκτ- ''tekt-'' in words having to do with carpentry) *Nickel–Strunz code scheme: NN.XY.##x **NN: Nickel–Strunz mineral class number **X: Nickel–Strunz mineral division letter **Y: Nickel–Strunz mineral family letter **##x: Nickel–Strunz mineral/group number, x add-on letter


Class: sulfosalts

* 02.G Sulfarsenites, sulfantimonites, sulfobismuthites ** 02.G: IMA2007-010 ** 02.GA Neso-sulfarsenites, etc., without additional S: 05
Proustite Proustite is a sulfosalt mineral consisting of silver sulfarsenide, Ag3 As S3, known also as light red silver or ruby silver ore, and an important source of the metal. It is closely allied to the corresponding sulfantimonide, pyrargyrite, from w ...
, 05 Pyrargyrite; 10 Xanthoconite, 10 Pyrostilpnite; 15 Samsonite; 20 Wittichenite, 20 Skinnerite, 25 Malyshevite, 25 Lisiguangite, 25 Muckeite, 25 Lapieite; 30
Aktashite Aktashite is a rare arsenic sulfosalt mineral with formula Cu6Hg3As4S12. It is a copper Mercury (element), mercury-bearing sulfosalt and is the only sulfosalt mineral with essential Cu and Hg yet known. It is of hydrothermal origin. It was publish ...
, 30 Nowackiite, 30 Gruzdevite; 35 Laffittite; 40 Stalderite, 40
Routhierite Routhierite is a rare thallium sulfosalt mineral with formula . It was first described in 1974 for an occurrence in the Jas Roux deposit in the French Alps. It was named after French geologist Pierre Routhier (1916–2008).Erniggliite; 50
Seligmannite Seligmanite is a rare mineral, with the chemical formula PbCuAsS3. Originally described from the Lengenbach Quarry, Valais, Valais Canton, Switzerland; it has also been found in the Raura district, Lima Region, Peru; at Tsumeb, Oshikoto Region, Na ...
, 50 Soucekite, 50 Bournonite ** 02.GB Neso-sulfarsenites, etc.: 05 Argentotennantite, 05 Giraudite, 05 Goldfieldite, 05 Freibergite, 05 Hakite, 05 Tennantite, 05
Tetrahedrite Tetrahedrite is a copper antimony sulfosalt mineral with formula: . It is the antimony endmember of the continuous solid solution series with arsenic-bearing tennantite. Pure endmembers of the series are seldom if ever seen in nature. Of the t ...
; 10 Selenostephanite, 10
Stephanite Stephanite is a silver antimony sulfosalt mineral with formula: Ag5 Sb S4. It is composed of 68.8% silver, and sometimes is of importance as an ore of this metal. History Under the name Schwarzerz it was mentioned by Georgius Agricola in 1546, ...
; 15 Cupropearceite, 15 Selenopolybasite, 15 Cupropolybasite, 15 Polybasite, 15 Pearceite, 15 Antimonpearceite, 15 Arsenpolybasite, 20 Galkhaite ** 02.GC Poly-sulfarsenites: 05 Hatchite, 05 Wallisite; 10 Sinnerite, 15 Watanabeite, 20 Simonite, 25 Q­ratite, 30 Smithite, 35 Trechmannite, 40a
Aleksite Aleksite ( IMA symbol: Alk) is a rare lead bismuth tellurium sulfosalt mineral Sulfosalt minerals are sulfide minerals with the general formula , where *A represents a metal such as copper, lead, silver, iron, and rarely mercury, zinc, vanad ...
, 40b Kochkarite, 40c Rucklidgeite, 40c Poubaite, 40d Saddlebackite, 40e Babkinite; 45 Tvalchrelidzeite, 50 Mutnovskite * 02.H Sulfosalts of SnS Archetype ** 02.HA With Cu, Ag, Fe (without Pb): 05 Emplectite, 05 Chalcostibite; 10
Miargyrite Miargyrite is a mineral, a sulfide of silver and antimony with the formula Ag Sb S2. It is a dimorph of cuboargyrite. Originally discovered in the Freiberg district of Germany in 1824, it has subsequently been found in many places where silver i ...
, 15 Livingstonite; 20 Berthierite, 20 Clerite, 20 Garavellite; 25 Baumstarkite, 25
Aramayoite Aramayoite ( IMA symbol: Ary) is a mineral with the chemical formula . Its type locality is Sud Chichas, Potosí, Bolivia.Aramayoite
o ...
** 02.HB With Cu, Ag, Hg, Fe, Sn and Pb: 05a Krupkaite, 05a Aikinite, 05a Hammarite, 05a Gladite, 05a Friedrichite, 05a Lindstromite, 05a Pekoite, 05a Paarite, 05a Emilite, 05a
Salzburgite Salzburgite has a general empirical formula of Pb2Cu2Bi7S12 and an orthorhombic crystal structure.Ralph, Joylon, and Ida ChauSalzburgite Joylon Ralph, 1993-2010. Web. 14 September 2010. This mineral is very similar to paarite in that they both ...
, 05b
Meneghinite Meneghinite is a sulfosalt mineral with the chemical formula CuPb13 Sb7S24. In the orthorhombic crystal system, meneghinite has a Mohs hardness of , one perfect cleavage and a conchoidal fracture. It is a blackish lead-grey in colour and gives a ...
, 05c Jaskolskiite; 10a
Kobellite Kobellite is a gray, fibrous, metallic mineral with the chemical formula . It is also a sulfide mineral consisting of antimony, bismuth, and lead. It is a member of the izoklakeite – berryite series with silver and iron substituting in the coppe ...
, 10a Tintinaite, 10b Giessenite, 10b Izoklakeite, 10c Eclarite; 15 Jamesonite, 15 Benavidesite; 20a Nagyagite, 20b Buckhornite, 20c Museumite, 20d Berryite, 20e Watkinsonite ** 02.HC With only Pb: 05a Sartorite, 05a Twinnite, 05a
Guettardite Guettardite is a rare arsenic-antimony lead sulfosalt mineral with the chemical formula . It forms gray black metallic prismatic to acicular crystals with monoclinic symmetry. It is a dimorph of the triclinic twinnite. Discovery and occurrence ...
, 05b
Baumhauerite Baumhauerite (Pb3As4S9) is a rare lead sulfosalt mineral. It crystallizes in the triclinic system, is gray-black to blue-gray and its lustre is metallic to dull. Baumhauerite has a hardness of 3. Baumhauerite occurs as small crystals embedded in ...
, 05b Baumhauerite-2a, 05c Liveingite, 05d Dufrenoysite, 05d Veenite, 05d Rathite, 05e Chabourneite, 05f Pierrotite, 05f Parapierrotite, 05g Marumoite; 10a Fuloppite, 10b Bismutoplagionite*, 10b Plagionite, 10c Heteromorphite, 10d Semseyite, 10d Rayite; 15 Boulangerite, 15 Falkmanite, 15 Plumosite*; 20 Robinsonite, 25 Moeloite, 30 Dadsonite, 35 Zoubekite, 35 Owyheeite ** 02.HD With Tl: 05 Lorandite, 05 Weissbergite; 15
Christite Christite is a mineral with the chemical formula Tl Hg As S3. It is named after Dr. Charles L. Christ, a member of the U.S. Geological Survey. It usually comes in a crimson red or bright orange color. It has a density of 6.2 and has a rating bet ...
, 20 Jankovicite, 25 Rebulite, 30 Imhofite, 35 Edenharterite, 40 Jentschite, 45 Hutchinsonite, 50 Bernardite, 55 Sicherite, 60
Gabrielite Gabrielite is a rare thallium sulfosalt mineral with a chemical formula of or . It was first reported in 2002 for its occurrence in the Lengenbach quarry, Binntal, Valais, Switzerland, and named after Walter Gabriel (born 1943), a Swiss min ...
** 02.HE With alkalies, : 05 Gerstleyite ** 02.HF With SnS and PbS archetype structure units: 20 Vrbaite; 25a Abramovite, 25a Levyclaudite, 25a Cylindrite, 25b Coiraite, 25b Incaite, 25b Potosiite, 25b
Franckeite Franckeite, chemical formula Pb5Sn3Sb2S14, belongs to a family of complex sulfide minerals. Franckeite is a sulfosalt. It is closely related to cylindrite. It was first described in 1893 for an occurrence in Chocaya, Potosí Department, Bolivia. ...
; 30 Lengenbachite * 02.J Sulfosalts of PbS Archetype ** 02.JA Galena derivatives with little or no Pb: 05a IMA2005-036, 05a IMA2008-058, 05a Cupropavonite, 05a Pavonite, 05b Grumiplucite, 05c Kudriavite, 05d Cupromakovickyite, 05d Makovickyite, 05e Benjaminite, 05f Mummeite, 05g Borodaevite, 05h Mozgovaite; 10a Cuprobismutite, 10b Kupcikite, 10c Hodrushite, 10d Pizgrischite, 10e Paderaite; 15 Cuboargyrite, 15 Schapbachite; 20 Bohdanowiczite, 20 Matildite, 20 Volynskite ** 02.JB Galena derivatives, with Pb: 05 Diaphorite, 10 Cosalite; 15
Marrite Marrite (mar'-ite) is a mineral with the chemical formula PbAgAsS3. It is the arsenic equivalent of freieslebenite (PbAgSbS3), but also displays close polyhedral characteristics with sicherite and diaphorite.Berlepsch, P., Makovicky E., and Ar ...
, 15 Freieslebenite; 20 Cannizzarite, 20 Wittite; 25a Junoite, 25b Felbertalite, 25c Nordstromite, 25d Proudite, 25g Nuffieldite, 25i IMA2008-053, 25i Neyite, 25j Rouxelite; 30a Jordanite, 30a Geocronite, 30b Kirkiite, 30c Tsugaruite; 35a Zinkenite, 35b Scainiite, 35c Pillaite, 35d Pellouxite; 40a
Bursaite Bursaite is a sulfosalt of the lillianite family. It has the formula Pb5Bi4S11 and orthorhombic structure. Bursaite is named after Bursa Province, Turkey, where it was discovered.Rasit, T. (1954-55A study on the concentration tests and beneficiati ...
?, 40a Gustavite, 40a Lillianite, 40a Xilingolite, 40a Treasurite, 40a Vikingite, 40a Fizelyite, 40a Andorite, 40a Roshchinite, 40a Uchucchacuaite, 40a Ramdohrite, 40b
Aschamalmite Aschamalmite is a mineral with the chemical formula PbBiS. Its type locality is the High Tauern in Austria.Aschamalmite
on
, 40b Eskimoite, 40b Heyrovskyite, 40c Ourayite, 40d Schirmerite, 40e Ustarasite; 45 Angelaite, 45 Galenobismutite, 45 Weibullite; 55
Gratonite Gratonite is a lead-arsenic sulfosalt mineral, with the chemical composition Pb9As4S15. Gratonite was discovered in 1939 at the Excelsior Mine, Cerro de Pasco, Peru , image_flag = Flag of Peru.svg , image_coat = E ...
, 60 Marrucciite, 65 Vurroite ** 02.JC Galena derivatives, with Tl: 05 Ellisite, 10 Gillulyite * 02.K Sulfarsenates, Sulfantimonates ** 02.KA Sulfarsenates with tetrahedra: 05 Enargite, 05 Stibioenargite*, 05 Petrukite; 10 Briartite, 10 Famatinite, 10 Luzonite, 10 Permingeatite, 10 Barquillite; 15 Fangite ** 02.KB Sulfarsenates with additional S: 05 Billingsleyite * 02.L Unclassified Sulfosalts ** 02.LA Without essential Pb: 10 Dervillite, 15 Daomanite*, 20 Vaughanite, 25 Criddleite, 30 Fettelite, 35 Chameanite, 40 Arcubisite, 45 Mgriite, 50 Benleonardite, 55 Tsnigriite, 60 Borovskite, 65 Jonassonite ** 02.LB With essential Pb: 05 Miharaite, 20 Ardaite, 30 Madocite, 35 Larosite; 40 Petrovicite, 40 Mazzettiite; 45 Crerarite, 50 Launayite, 55
Playfairite Playfairite is a rare sulfosalt mineral with chemical formula Pb16Sb18S43 in the monoclinic crystal system, named after the Scottish scientist and mathematician John Playfair. It was discovered in 1966 by the Canadian mineralogist John Leslie Jam ...
, 60 Sorbyite, 65 Sterryite * 02.M ** 02.MA Oxysulfosalts of Alkalies and Alkali Earths: 05 Ottensite, 05 Cetineite; 10
Sarabauite Sarabauite (sar-a-bau'-ite) is a red monoclinic sulfide mineral with the chemical formula: CaSb10O10S6. Origin of name and type locality Sarabauite was first described in 1977 and named for its type locality, the Sarabau Mine (Lucky Hill mi ...
* 02.X Unclassified Strunz Sulfosalts ** 02.XX Unknown: 00 Tazieffite, 00 Horobetsuite*, 00 Kitaibelite?, 00 Parajamesonite?, 00 Sakharovaite?, 00 Volfsonite*


Synthetic sulfosalts

Many sulfosalts can be prepared in the laboratory, including many that do not occur in nature.Sheldrick, William S.; Wachhold, Michael "Chalcogenidometalates of the heavier Group 14 and 15 elements" Coordination Chemistry Reviews 1998, vol. 176, 211-322.


References

* Mozgova N.N. (2000). ''Sulfosalt mineralogy today''. In: ''Modern Approaches to Ore and Environmental Mineralogy'', MSF Mini-Symposium Espoo Finland, June 11–17, 2000, https://web.archive.org/web/20050907172937/http://www.igem.ru/igem/mine/sulfosalts.htm Retrieved July 22, 2005. * * * * {{Strunz