Spectroradiometry For Earth And Planetary Remote Sensing
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Spectroradiometry is a technique in Earth and planetary remote sensing, which makes use of light behaviour, specifically how light energy is reflected, emitted, and
scattered Scattered may refer to: Music * ''Scattered'' (album), a 2010 album by The Handsome Family * "Scattered" (The Kinks song), 1993 * "Scattered", a song by Ace Young * "Scattered", a song by Lauren Jauregui * "Scattered", a song by Green Day from ' ...
by substances, to explore their properties in the electromagnetic (light) spectrum and identify or differentiate between them. The interaction between light radiation and the surface of a given material determines the manner in which the radiation reflects back to a detector, i.e., a
spectroradiometer A spectroradiometer is a light measurement tool that is able to measure both the wavelength and amplitude of the light emitted from a light source. Spectrometers discriminate the wavelength based on the position the light hits at the detector array ...
. Combining the elements of
spectroscopy Spectroscopy is the field of study that measures and interprets the electromagnetic spectra that result from the interaction between electromagnetic radiation and matter as a function of the wavelength or frequency of the radiation. Matter wa ...
and
radiometry Radiometry is a set of techniques for measurement, measuring electromagnetic radiation, including visible light. Radiometric techniques in optics characterize the distribution of the radiation's power (physics), power in space, as opposed to phot ...
, spectroradiometry carries out precise measurements of electromagnetic radiation and associated parameters within different wavelength ranges. This technique forms the basis of multi- and hyperspectral imaging and reflectance spectroscopy, commonly applied across numerous geoscience disciplines, which evaluates the spectral properties exhibited by various materials found on Earth and planetary bodies. Spectral properties such as brightness and reflectance patterns vary depending on the mineralogical compositions and crystalline structures of the given material. This variation is contributed by the presence of spectrally active components within the material, such as metallic
oxide An oxide () is a chemical compound that contains at least one oxygen atom and one other element in its chemical formula. "Oxide" itself is the dianion of oxygen, an O2– (molecular) ion. with oxygen in the oxidation state of −2. Most of the E ...
s and
clay mineral Clay minerals are hydrous aluminium phyllosilicates (e.g. kaolin, Al2 Si2 O5( OH)4), sometimes with variable amounts of iron, magnesium, alkali metals, alkaline earths, and other cations found on or near some planetary surfaces. Clay minerals ...
s, which give rise to unique
absorption Absorption may refer to: Chemistry and biology * Absorption (biology), digestion **Absorption (small intestine) *Absorption (chemistry), diffusion of particles of gas or liquid into liquid or solid materials *Absorption (skin), a route by which ...
features. Upon measurements with a
spectroradiometer A spectroradiometer is a light measurement tool that is able to measure both the wavelength and amplitude of the light emitted from a light source. Spectrometers discriminate the wavelength based on the position the light hits at the detector array ...
, these absorption features can be quantified as characteristic absorption bands in a reflectance spectra. The specific shapes associated with the bands that occur at distinctive wavelength positions enable the identification of minerals and facilitate lithological interpretations. Conventionally, spectroradiometry is applied to the following portions of wavelengths in the electromagnetic (light) spectrum: * Ultraviolet (UV): 1 nm – 400 nm * Visible-near Infrared (VNIR): 400 nm – 750 nm * Short-wave Infrared (SWIR): 750 nm – 2500 nm * Mid Infrared (MIR): 2500 nm – 5000 nm * Thermal Infrared (TIR): 7500 nm – 15000 nm Today, most geological applications with spectroradiometry are focused within the visible-near infrared and
short-wave infrared Infrared (IR), sometimes called infrared light, is electromagnetic radiation (EMR) with wavelengths longer than those of visible light. It is therefore invisible to the human eye. IR is generally understood to encompass wavelengths from around ...
wavelength ranges. Spectroradiometry offers a simple, non-destructive, rapid, and efficient approach that complements traditional and heavy-duty geochemical methods, to characterize mineral assemblages and rock textures. It thereby facilitates the study of geological processes, exploration for natural resources, and reconstruction of past environments and climates. Its application extends not only to Earth but also to extraterrestrial planets, broadening our understanding of geological processes beyond our own planet. __TOC__


How spectroradiometry works

In spectroradiometry, spectral features can be recognized and quantified by making use of the spectra containing different parameters measured by
spectroradiometer A spectroradiometer is a light measurement tool that is able to measure both the wavelength and amplitude of the light emitted from a light source. Spectrometers discriminate the wavelength based on the position the light hits at the detector array ...
s. The most widely used spectral parameter in spectroradiometry for applications in geosciences is reflectance. Spectroradiometry can be imaging and non-imaging in practice. Imaging spectroradiometry captures spectral data from a specific region or a scene, creating a two-dimensional
image An image is a visual representation of something. It can be two-dimensional, three-dimensional, or somehow otherwise feed into the visual system to convey information. An image can be an artifact, such as a photograph or other two-dimensiona ...
with recorded spectral information dedicated to each pixel. Non-imaging spectroradiometry, on the contrary, measures spectral data from a single point or a small focused area, offering more detailed information about the spectral properties of a specific material.


Experimental set-up

The experimental set-up for imaging spectroradiometry is simple because
image processing An image is a visual representation of something. It can be two-dimensional, three-dimensional, or somehow otherwise feed into the visual system to convey information. An image can be an artifact, such as a photograph or other two-dimensiona ...
can be conducted through computer software to show the spectral parameters for analysis, such as reflectance and brightness. Most images are freely available worldwide, widely used by different institutions, and have an extensive spatial coverage. Values of spectral parameters like reflectance can then be directly extracted from all pixels in the
imagery Imagery is visual symbolism, or figurative language that evokes a mental image or other kinds of sense impressions, especially in a literary work, but also in other activities such as psychotherapy. Forms There are five major types of sensory ima ...
, aggregated and averaged to produce a reflectance curve for spectral analysis. In terms of non-imaging spectroradiometry, data collection and sampling are usually conducted through direct scanning with
spectroradiometer A spectroradiometer is a light measurement tool that is able to measure both the wavelength and amplitude of the light emitted from a light source. Spectrometers discriminate the wavelength based on the position the light hits at the detector array ...
s in the laboratory or in the field. To ensure data accuracy, it is important to carry out the experiment under a stable and controlled environment. For instance, most laboratory scanning practices are performed in the dark to minimize ambient light and
scattering Scattering is a term used in physics to describe a wide range of physical processes where moving particles or radiation of some form, such as light or sound, are forced to deviate from a straight trajectory by localized non-uniformities (including ...
, while field scanning is typically conducted with a contact scanning probe, such that measurements are taken in direct contact with the sample surface, free from external light sources, and in a localized setting. In both scenarios, the
spectroradiometer A spectroradiometer is a light measurement tool that is able to measure both the wavelength and amplitude of the light emitted from a light source. Spectrometers discriminate the wavelength based on the position the light hits at the detector array ...
s are frequently calibrated with a white diffusion reflectance panel, which provides a reference reflectance value (99%) to maintain experimental accuracy. During spectral measurements, they exert homogeneous illumination straight towards the sample surface. Spectral data acquired will then be presented through digital software associated with the
spectroradiometer A spectroradiometer is a light measurement tool that is able to measure both the wavelength and amplitude of the light emitted from a light source. Spectrometers discriminate the wavelength based on the position the light hits at the detector array ...
s.


Analysis of spectral features

Reflectance appears as individual absorption bands spanning the electromagnetic spectra, which vary with
mineralogy Mineralogy is a subject of geology specializing in the scientific study of the chemistry, crystal structure, and physical (including optical) properties of minerals and mineralized artifacts. Specific studies within mineralogy include the proces ...
and
chemical composition A chemical composition specifies the identity, arrangement, and ratio of the elements making up a compound. Chemical formulas can be used to describe the relative amounts of elements present in a compound. For example, the chemical formula for ...
s. Reflectance spectra obtained directly from the
spectroradiometer A spectroradiometer is a light measurement tool that is able to measure both the wavelength and amplitude of the light emitted from a light source. Spectrometers discriminate the wavelength based on the position the light hits at the detector array ...
s without data processing are known as raw reflectance spectra. Although some prominent patterns of
absorption Absorption may refer to: Chemistry and biology * Absorption (biology), digestion **Absorption (small intestine) *Absorption (chemistry), diffusion of particles of gas or liquid into liquid or solid materials *Absorption (skin), a route by which ...
may be identified, they are prone to influence from the overall spectra trends, and features like
amplitudes The amplitude of a periodic variable is a measure of its change in a single period (such as time or spatial period). The amplitude of a non-periodic signal is its magnitude compared with a reference value. There are various definitions of amplit ...
and magnitudes could mislead the interpretations under such circumstances. In order to facilitate data analysis, the raw reflectance spectra are commonly normalized to provide better visualization and quantification of trends and patterns of spectral parameters. This is commonly done by
statistical Statistics (from German: ''Statistik'', "description of a state, a country") is the discipline that concerns the collection, organization, analysis, interpretation, and presentation of data. In applying statistics to a scientific, industria ...
techniques including ''detrending'' and ''
continuum Continuum may refer to: * Continuum (measurement), theories or models that explain gradual transitions from one condition to another without abrupt changes Mathematics * Continuum (set theory), the real line or the corresponding cardinal number ...
removal''. 1. Detrending: Removing the trend components present in the raw reflectance spectra to produce detrended spectra (usually flattened) revealing the true shapes, patterns, and distributions of
absorption Absorption may refer to: Chemistry and biology * Absorption (biology), digestion **Absorption (small intestine) *Absorption (chemistry), diffusion of particles of gas or liquid into liquid or solid materials *Absorption (skin), a route by which ...
features. 2.
Continuum Continuum may refer to: * Continuum (measurement), theories or models that explain gradual transitions from one condition to another without abrupt changes Mathematics * Continuum (set theory), the real line or the corresponding cardinal number ...
removal (
Convex hull In geometry, the convex hull or convex envelope or convex closure of a shape is the smallest convex set that contains it. The convex hull may be defined either as the intersection of all convex sets containing a given subset of a Euclidean space ...
transformation):
Removing overall shape, level changes, and slopes induced by other materials in the raw reflectance spectra (indicated as
continuum Continuum may refer to: * Continuum (measurement), theories or models that explain gradual transitions from one condition to another without abrupt changes Mathematics * Continuum (set theory), the real line or the corresponding cardinal number ...
lines) to produce
continuum Continuum may refer to: * Continuum (measurement), theories or models that explain gradual transitions from one condition to another without abrupt changes Mathematics * Continuum (set theory), the real line or the corresponding cardinal number ...
-removed spectra which allows effective comparison of the individual
absorption Absorption may refer to: Chemistry and biology * Absorption (biology), digestion **Absorption (small intestine) *Absorption (chemistry), diffusion of particles of gas or liquid into liquid or solid materials *Absorption (skin), a route by which ...
features under a common baseline. From the normalized spectra, spectral features can be accurately identified, analyzed, and compared to that among different materials.
Spectrograms A spectrogram is a visual representation of the spectrum of frequencies of a signal as it varies with time. When applied to an audio signal, spectrograms are sometimes called sonographs, voiceprints, or voicegrams. When the data are represen ...
can also be generated using the normalized spectra to further enhance visualization. The features can be characterized using
geometrical Geometry (; ) is, with arithmetic, one of the oldest branches of mathematics. It is concerned with properties of space such as the distance, shape, size, and relative position of figures. A mathematician who works in the field of geometry is ca ...
parameters describing the shapes and appearance of a particular reflectance spectrum: * ''Position (P)'': The ''position'' of
absorption band According to quantum mechanics, atoms and molecules can only hold certain defined quantities of energy, or exist in specific states. When such quanta of electromagnetic radiation are emitted or absorbed by an atom or molecule, energy of the ...
at a certain wavelength interval. * ''Depth (D)'': The ''depth'' of
absorption band According to quantum mechanics, atoms and molecules can only hold certain defined quantities of energy, or exist in specific states. When such quanta of electromagnetic radiation are emitted or absorbed by an atom or molecule, energy of the ...
(absorption value) at a certain wavelength interval. * ''Width (W)'': The ''width'' of
absorption band According to quantum mechanics, atoms and molecules can only hold certain defined quantities of energy, or exist in specific states. When such quanta of electromagnetic radiation are emitted or absorbed by an atom or molecule, energy of the ...
at a certain wavelength interval. * ''Full width at half maximum (F)'': The ''width'' of an imaginary horizontal line positioned at half of the maximum
absorption Absorption may refer to: Chemistry and biology * Absorption (biology), digestion **Absorption (small intestine) *Absorption (chemistry), diffusion of particles of gas or liquid into liquid or solid materials *Absorption (skin), a route by which ...
strength of a particular
absorption band According to quantum mechanics, atoms and molecules can only hold certain defined quantities of energy, or exist in specific states. When such quanta of electromagnetic radiation are emitted or absorbed by an atom or molecule, energy of the ...
. * ''Asymmetry (AS)'': The ''asymmetry'' of shape with respect to an
absorption band According to quantum mechanics, atoms and molecules can only hold certain defined quantities of energy, or exist in specific states. When such quanta of electromagnetic radiation are emitted or absorbed by an atom or molecule, energy of the ...
. It can be quantified by the ratio between left and right widths with respect to the half maximum. Hence, an AS value of 1.0 will represent a ''symmetrical''
absorption band According to quantum mechanics, atoms and molecules can only hold certain defined quantities of energy, or exist in specific states. When such quanta of electromagnetic radiation are emitted or absorbed by an atom or molecule, energy of the ...
, while AS < 1.0 and AS > 1.0 will indicate ''leftward'' and ''rightward asymmetry''. The investigation of spectral features is often followed by building spectral indices to characterize specific minerals, i.e., parameterizing. The indices are based on the unique spectral properties exhibited by the materials, such as the positions and depths of absorption bands. A similar example of such indices is the Normalized difference vegetation index (NDVI).


Mineral identification

Minerals are identified with spectroradiometry by examining their spectral response to incoming
radiation In physics, radiation is the emission or transmission of energy in the form of waves or particles through space or through a material medium. This includes: * ''electromagnetic radiation'', such as radio waves, microwaves, infrared, visi ...
, such as brightness and reflectance, across different wavelengths. In particular, absorption bands observed in the reflectance spectra can be unique towards different minerals which allow the differentiation between one another. These
absorption Absorption may refer to: Chemistry and biology * Absorption (biology), digestion **Absorption (small intestine) *Absorption (chemistry), diffusion of particles of gas or liquid into liquid or solid materials *Absorption (skin), a route by which ...
features arise from the distinct electronic and vibrational processes associated with the energy,
molecular A molecule is a group of two or more atoms held together by attractive forces known as chemical bonds; depending on context, the term may or may not include ions which satisfy this criterion. In quantum physics, organic chemistry, and bioche ...
components, and internal structures of minerals. Electronic processes of minerals comprise charge transfers,
crystal field Crystal field theory (CFT) describes the breaking of degeneracies of electron orbital states, usually ''d'' or ''f'' orbitals, due to a static electric field produced by a surrounding charge distribution (anion neighbors). This theory has been used ...
effects ( electrons achieving higher
energy states In physics, energy (from Ancient Greek: ἐνέργεια, ''enérgeia'', “activity”) is the quantitative property that is transferred to a body or to a physical system, recognizable in the performance of work and in the form of heat a ...
), conduction bands, and colour centres, whereas vibrational processes in minerals involve stretching, bending, and
rotation Rotation, or spin, is the circular movement of an object around a '' central axis''. A two-dimensional rotating object has only one possible central axis and can rotate in either a clockwise or counterclockwise direction. A three-dimensional ...
, which are influenced by the functional groups present in the minerals. For example, water-bearing minerals commonly share distinctive
absorption Absorption may refer to: Chemistry and biology * Absorption (biology), digestion **Absorption (small intestine) *Absorption (chemistry), diffusion of particles of gas or liquid into liquid or solid materials *Absorption (skin), a route by which ...
features indicating the presence of hydroxyl groups (-OH) and
molecular A molecule is a group of two or more atoms held together by attractive forces known as chemical bonds; depending on context, the term may or may not include ions which satisfy this criterion. In quantum physics, organic chemistry, and bioche ...
water (H2O), which include the asymmetrical
absorption Absorption may refer to: Chemistry and biology * Absorption (biology), digestion **Absorption (small intestine) *Absorption (chemistry), diffusion of particles of gas or liquid into liquid or solid materials *Absorption (skin), a route by which ...
features due to overtones near 1400 nm (AS1400), as well as absorption peaks near 1900 (D1900) and 2200 nm (D2200). With higher
molecular A molecule is a group of two or more atoms held together by attractive forces known as chemical bonds; depending on context, the term may or may not include ions which satisfy this criterion. In quantum physics, organic chemistry, and bioche ...
water contents, the AS1400 feature becomes more asymmetrical, the
absorption Absorption may refer to: Chemistry and biology * Absorption (biology), digestion **Absorption (small intestine) *Absorption (chemistry), diffusion of particles of gas or liquid into liquid or solid materials *Absorption (skin), a route by which ...
near 2200 nm strengthens, but the one near 1900 nm weakens. Hence, the asymmetrical
absorption Absorption may refer to: Chemistry and biology * Absorption (biology), digestion **Absorption (small intestine) *Absorption (chemistry), diffusion of particles of gas or liquid into liquid or solid materials *Absorption (skin), a route by which ...
feature (AS1400), together with the ratio between absorption depths near 2200 and 1900 nm (D2200/D1900) are used a parameter to quantify water contents. In practice, however, certain minerals may exhibit absorption features that coincide with those of water in similar wavelength intervals. This can potentially lead to the overlapping or masking of
absorption Absorption may refer to: Chemistry and biology * Absorption (biology), digestion **Absorption (small intestine) *Absorption (chemistry), diffusion of particles of gas or liquid into liquid or solid materials *Absorption (skin), a route by which ...
features associated with the original minerals. Such situations may arise during field scanning or when dealing with wet samples, introducing confusion in mineral identification. Therefore, to minimize such interference,
drying Drying is a mass transfer process consisting of the removal of water or another solvent by evaporation from a solid, semi-solid or liquid. This process is often used as a final production step before selling or packaging products. To be considered ...
of samples prior to spectral scanning for mineral identification is essential. The drying process should be conducted at a temperature of 105 °C or below, which can ensure the removal of adsorbed water without causing any disruption to the internal structures of minerals. Considering the identification capabilities of spectroradiometry for different minerals and
rocks In geology, rock (or stone) is any naturally occurring solid mass or aggregate of minerals or mineraloid matter. It is categorized by the minerals included, its chemical composition, and the way in which it is formed. Rocks form the Earth's ...
, the comprehensive databases that encompass spectral signatures are crucial. Such databases serve as valuable resources which contributes to advancing our understanding and characterization of
Earth materials Earth materials include minerals, rocks, soil and water. These are the naturally occurring materials found on Earth that constitute the raw materials upon which our global society exists. Earth materials are vital resources that provide the basic c ...
. Notably, th
United States Geological Survey (USGS) spectral library
and th
ECOSTRESS spectral library
represent present examples of such databases. The USGS spectral library provides a collection of reflectance spectra for rock-forming minerals and other Earth materials, spanning from ultraviolet (350 nm) to shortwave infrared (SWIR) regions (2500 nm). Likewise, the ECOSTRESS spectral library integrates spectral data from multiple spectral libraries, consolidating information on minerals and rocks into a standardized data format. These spectral libraries serve as essential references for ongoing research on spectroradiometry, providing a solid foundation for data analysis and interpretation.


Geomorphology and surface mapping

Geomorphology Geomorphology (from Ancient Greek: , ', "earth"; , ', "form"; and , ', "study") is the scientific study of the origin and evolution of topographic and bathymetric features created by physical, chemical or biological processes operating at or n ...
is the study of geological processes occurring at the surface of Earth that subsequently shape different kinds of
landform A landform is a natural or anthropogenic land feature on the solid surface of the Earth or other planetary body. Landforms together make up a given terrain, and their arrangement in the landscape is known as topography. Landforms include hills, ...
s. Surface mapping is a common approach to understand these processes and their effects, which can be done by using spectroradiometry. Chemical weathering is one of the dominant processes controlling the morphology of Earth's surface, which produces iron oxides as coatings on particle surfaces, as well as
clay minerals Clay minerals are hydrous aluminium phyllosilicates (e.g. kaolin, Al2 Si2 O5( OH)4), sometimes with variable amounts of iron, magnesium, alkali metals, alkaline earths, and other cations found on or near some planetary surfaces. Clay mineral ...
that evolve from hydrothermal alteration and decomposition of feldspars in surface soils and granitic rock bodies. These minerals are sensitive to spectral parameters like brightness and reflectance, and they exhibit distinctive
absorption Absorption may refer to: Chemistry and biology * Absorption (biology), digestion **Absorption (small intestine) *Absorption (chemistry), diffusion of particles of gas or liquid into liquid or solid materials *Absorption (skin), a route by which ...
features on reflectance spectra, which facilitates easy diagnosis and determination of weathering states. (1)
Clay minerals Clay minerals are hydrous aluminium phyllosilicates (e.g. kaolin, Al2 Si2 O5( OH)4), sometimes with variable amounts of iron, magnesium, alkali metals, alkaline earths, and other cations found on or near some planetary surfaces. Clay mineral ...
( Phyllosilicates) * Illite: Narrow absorption peaks at 1400, 1900, 2200, and 2300 nm. *
Chlorite The chlorite ion, or chlorine dioxide anion, is the halite with the chemical formula of . A chlorite (compound) is a compound that contains this group, with chlorine in the oxidation state of +3. Chlorites are also known as salts of chlorous ac ...
: Triple absorption features near 2300 nm. * Vermiculite: Pairs of narrow absorption peaks situated at 1400 and 1900 nm; weak absorption features present near 2200 and 2300 nm. * Smectite: Strong and sharp absorption features at 1400, 1900, and 2200 nm; The peaks at 1400 and 1900 nm comes with weak absorption features attached to their right sides. *
Kaolinite Kaolinite ( ) is a clay mineral, with the chemical composition Al2 Si2 O5( OH)4. It is an important industrial mineral. It is a layered silicate mineral, with one tetrahedral sheet of silica () linked through oxygen atoms to one octahedral ...
: Doublet absorption peaks near 1400 and 2200 nm. The genesis of
clay minerals Clay minerals are hydrous aluminium phyllosilicates (e.g. kaolin, Al2 Si2 O5( OH)4), sometimes with variable amounts of iron, magnesium, alkali metals, alkaline earths, and other cations found on or near some planetary surfaces. Clay mineral ...
occurs in a progressive sequence, starting with illite and
chlorite The chlorite ion, or chlorine dioxide anion, is the halite with the chemical formula of . A chlorite (compound) is a compound that contains this group, with chlorine in the oxidation state of +3. Chlorites are also known as salts of chlorous ac ...
, then vermiculite , smectite, and finally forming
kaolinite Kaolinite ( ) is a clay mineral, with the chemical composition Al2 Si2 O5( OH)4. It is an important industrial mineral. It is a layered silicate mineral, with one tetrahedral sheet of silica () linked through oxygen atoms to one octahedral ...
.
Kaolinite Kaolinite ( ) is a clay mineral, with the chemical composition Al2 Si2 O5( OH)4. It is an important industrial mineral. It is a layered silicate mineral, with one tetrahedral sheet of silica () linked through oxygen atoms to one octahedral ...
, being the ultimate product of
clay minerals Clay minerals are hydrous aluminium phyllosilicates (e.g. kaolin, Al2 Si2 O5( OH)4), sometimes with variable amounts of iron, magnesium, alkali metals, alkaline earths, and other cations found on or near some planetary surfaces. Clay mineral ...
, represents the most advanced stage of weathering. (2) Iron oxides *
Hematite Hematite (), also spelled as haematite, is a common iron oxide compound with the formula, Fe2O3 and is widely found in rocks and soils. Hematite crystals belong to the rhombohedral lattice system which is designated the alpha polymorph of . ...
: Broad absorption features near 500 and 920 nm. * Goethite: Broad absorption features near 500, 700, and 920 nm. Based on the above, three groups of distinctive spectral parameters are distinguished which can serve as the indicators of weathering states. The first group of parameters deals with the
absorption Absorption may refer to: Chemistry and biology * Absorption (biology), digestion **Absorption (small intestine) *Absorption (chemistry), diffusion of particles of gas or liquid into liquid or solid materials *Absorption (skin), a route by which ...
features at 500, 700, and 920 nm due to ferric iron components. The peaks positioned at 920 nm (P920), and the ratio between absorption depths near 500 and 700 nm (D700/D500) are inversely proportional to the concentration of
hematite Hematite (), also spelled as haematite, is a common iron oxide compound with the formula, Fe2O3 and is widely found in rocks and soils. Hematite crystals belong to the rhombohedral lattice system which is designated the alpha polymorph of . ...
, thus smaller values will mean higher degree of weathering. The second group of parameters is related to
hydroxyl group In chemistry, a hydroxy or hydroxyl group is a functional group with the chemical formula and composed of one oxygen atom covalently bonded to one hydrogen atom. In organic chemistry, alcohols and carboxylic acids contain one or more hydroxy g ...
(-OH) and water (H2O). Stronger absorption absorption features near 1400 nm (AS1400), and larger ratio between absorptions near 2200 and 1900 nm (D2200/D1900), reflect higher molecular water contents, hence more
alteration Alteration(s) may refer to: * Alteration (music), the use of a neighboring pitch in the chromatic scale in place of its diatonic neighbor. ** Alteration, in the mensural notation used by renaissance music, the lengthening of a breve, semibreve or ...
and weathering. The third group of parameters concerns the effects of
absorption Absorption may refer to: Chemistry and biology * Absorption (biology), digestion **Absorption (small intestine) *Absorption (chemistry), diffusion of particles of gas or liquid into liquid or solid materials *Absorption (skin), a route by which ...
contributed by Al-OH bonds in
clay minerals Clay minerals are hydrous aluminium phyllosilicates (e.g. kaolin, Al2 Si2 O5( OH)4), sometimes with variable amounts of iron, magnesium, alkali metals, alkaline earths, and other cations found on or near some planetary surfaces. Clay mineral ...
including illite and
kaolinite Kaolinite ( ) is a clay mineral, with the chemical composition Al2 Si2 O5( OH)4. It is an important industrial mineral. It is a layered silicate mineral, with one tetrahedral sheet of silica () linked through oxygen atoms to one octahedral ...
, which is situated near 2200 nm. These absorption bands become more asymmetric (AS2200 > 1, showing leftward asymmetry) with increasing kaolinite contents as a result of transformation from illite, implying greater extents of mineral alteration, degree of hydrolysis, and
silicate In chemistry, a silicate is any member of a family of polyatomic anions consisting of silicon and oxygen, usually with the general formula , where . The family includes orthosilicate (), metasilicate (), and pyrosilicate (, ). The name is al ...
decomposition, which serves as signals that indicate more advanced weathering stages. Determining the above spectral parameters will enable the quantification of weathering rates, thus providing implications to
paleoclimatic Paleoclimatology (British spelling, palaeoclimatology) is the study of climates for which direct measurements were not taken. As instrumental records only span a tiny part of Earth's history, the reconstruction of ancient climate is important to ...
conditions. The application of spectroradiometry in geomorphological studies brings opportunities into rapid mapping of weathered outcrops and the study of weathering
kinetics Kinetics ( grc, κίνησις, , kinesis, ''movement'' or ''to move'') may refer to: Science and medicine * Kinetics (physics), the study of motion and its causes ** Rigid body kinetics, the study of the motion of rigid bodies * Chemical ki ...
and
paleoclimate Paleoclimatology (British spelling, palaeoclimatology) is the study of climates for which direct measurements were not taken. As instrumental records only span a tiny part of Earth's history, the reconstruction of ancient climate is important to ...
particularly in remote and inaccessible regions.


Geochronology

Geochronology is the study of age and timing of geological events that have occurred throughout
Earth's history The history of Earth concerns the development of planet Earth from its formation to the present day. Nearly all branches of natural science have contributed to understanding of the main events of Earth's past, characterized by constant geologic ...
. Many different geochronological methods have been developed, using various
Earth materials Earth materials include minerals, rocks, soil and water. These are the naturally occurring materials found on Earth that constitute the raw materials upon which our global society exists. Earth materials are vital resources that provide the basic c ...
and geological processes as proxies. Among these methods, spectroradiometry has recently emerged as a valuable tool in dating techniques, particularly in tephrochronology and surface dating applications.


Tephrochronology

Tephrochronology refers to the age determination of sedimentary strata using tephra, i.e., volcanic ashes and fragments. They serve as viable chronological markers and are precisely dated due to their instantaneous deposition over wide regions. The
ashes Ashes may refer to: *Ash, the solid remnants of fires. Media and entertainment Art * ''Ashes'' (Munch), an 1894 painting by Edvard Munch Film * ''The Ashes'' (film), a 1965 Polish film by director Andrzej Wajda * ''Ashes'' (1922 film), a ...
typically have a high purity, composed of silicates (such as quartz), and phyllosilicates (such as
kaolinite Kaolinite ( ) is a clay mineral, with the chemical composition Al2 Si2 O5( OH)4. It is an important industrial mineral. It is a layered silicate mineral, with one tetrahedral sheet of silica () linked through oxygen atoms to one octahedral ...
,
serpentine Serpentine may refer to: Shapes * Serpentine shape, a shape resembling a serpent * Serpentine curve, a mathematical curve * Serpentine, a type of riding figure Science and nature * Serpentine subgroup, a group of minerals * Serpentinite, a ...
), which are highly sensitive towards spectral parameters such that they demonstrate characteristic spectral features when compared to the background sediments. Volcanic ashes with a high silica content, known as
felsic In geology, felsic is a modifier describing igneous rocks that are relatively rich in elements that form feldspar and quartz.Marshak, Stephen, 2009, ''Essentials of Geology,'' W. W. Norton & Company, 3rd ed. It is contrasted with mafic rocks, whi ...
ashes, stand out from the background sediments due to their high albedo and reflectance values. In contrast, mafic ashes, which have low silica content, exhibit lower reflectance due to their purity compared to the mixed compositions of the background sediments. Additionally, phyllosilicate minerals in volcanic ashes display strong
absorption Absorption may refer to: Chemistry and biology * Absorption (biology), digestion **Absorption (small intestine) *Absorption (chemistry), diffusion of particles of gas or liquid into liquid or solid materials *Absorption (skin), a route by which ...
features near 2200 nm, attributed to the stretching of hydroxyl groups (-OH bonds) with aluminium. Consequently, these spectral signatures enable the detection and differentiation of volcanic ashes from other sediments. Imaging spectroradiometry can be used for regional-scale mapping of volcanic ash deposits, as well as core
logging Logging is the process of cutting, processing, and moving trees to a location for transport. It may include skidding, on-site processing, and loading of trees or logs onto trucks or skeleton cars. Logging is the beginning of a supply chain ...
. Meanwhile, non-imaging spectroradiometry, combined with field scanning and sampling, is suitable for localized applications, providing
age Age or AGE may refer to: Time and its effects * Age, the amount of time someone or something has been alive or has existed ** East Asian age reckoning, an Asian system of marking age starting at 1 * Ageing or aging, the process of becoming older ...
implications and constraints for stratigraphic units.


Surface Dating

Surface dating is the measurement of relative age of sediment deposits on the Earth's surface. This can be achieved by utilizing weathering states as proxies, based on the principle that sediments with a higher degree of weathering have been exposed for a longer period of time. The intensity of weathering is highly correlated to the concentration of secondary iron oxides and
clay minerals Clay minerals are hydrous aluminium phyllosilicates (e.g. kaolin, Al2 Si2 O5( OH)4), sometimes with variable amounts of iron, magnesium, alkali metals, alkaline earths, and other cations found on or near some planetary surfaces. Clay mineral ...
present in the sediments. These can be identified and measured through specific
absorption Absorption may refer to: Chemistry and biology * Absorption (biology), digestion **Absorption (small intestine) *Absorption (chemistry), diffusion of particles of gas or liquid into liquid or solid materials *Absorption (skin), a route by which ...
features near 1400, 1900, and 2200 nm, thus establishing a relationship between
age Age or AGE may refer to: Time and its effects * Age, the amount of time someone or something has been alive or has existed ** East Asian age reckoning, an Asian system of marking age starting at 1 * Ageing or aging, the process of becoming older ...
and reflectance. Using multi-,
hyperspectral Hyperspectral imaging collects and processes information from across the electromagnetic spectrum. The goal of hyperspectral imaging is to obtain the spectrum for each pixel in the image of a scene, with the purpose of finding objects, identifyi ...
, and thermal imaging, the ages of surfaces of regional sediment deposits, such as alluvial fans, can be predicted and mapped. Together, spectroradiometry provides a new approach in estimating sediment ages, as a supplement to conventional
geochemical Geochemistry is the science that uses the tools and principles of chemistry to explain the mechanisms behind major geological systems such as the Earth's crust and its oceans. The realm of geochemistry extends beyond the Earth, encompassing the e ...
analysis. The advancement of this technique has the potential to expand surface age models to encompass remote regions, enhancing the understanding of regional geological history.


Earth resources

Earth resources are natural materials and substances that can be extracted from the Earth and used by humans for numerous purposes. Typical examples include minerals and
fossil fuel A fossil fuel is a hydrocarbon-containing material formed naturally in the Earth's crust from the remains of dead plants and animals that is extracted and burned as a fuel. The main fossil fuels are coal, oil, and natural gas. Fossil fuels m ...
s. Spectroradiometry, with its ability to identify
Earth materials Earth materials include minerals, rocks, soil and water. These are the naturally occurring materials found on Earth that constitute the raw materials upon which our global society exists. Earth materials are vital resources that provide the basic c ...
through capturing their distinctive spectral signals, holds significant potential in exploring and predicting the presence of ore deposits and
hydrocarbon reservoirs A petroleum reservoir or oil and gas reservoir is a subsurface accumulation of hydrocarbons contained in Porosity, porous or fractured rock formations. Such reservoirs form when kerogen (ancient plant matter) is created in surrounding rock by the ...
. Importantly, its applicability to inaccessible areas further expands its utility in assessing and investigating Earth's valuable resources.


Ore exploration

Spectroradiometry is widely utilized for the identification and prediction of ore deposits associated with hydrothermal systems. Hydrothermally altered deposits, known as epigenetic deposits, undergo multiple episodes of chemical alteration caused by interactions between hydrothermal fluids and the surrounding rock formations. These
alteration Alteration(s) may refer to: * Alteration (music), the use of a neighboring pitch in the chromatic scale in place of its diatonic neighbor. ** Alteration, in the mensural notation used by renaissance music, the lengthening of a breve, semibreve or ...
processes are often related to volcanic and geothermal activities, where hot hydrothermal fluids penetrate through
fractures Fracture is the separation of an object or material into two or more pieces under the action of stress. The fracture of a solid usually occurs due to the development of certain displacement discontinuity surfaces within the solid. If a displa ...
in pre-existing country rocks, resulting in the deposition of valuable metallic
ores Ore is natural Rock (geology), rock or sediment that contains one or more valuable minerals, typically containing metals, that can be mined, treated and sold at a profit.Encyclopædia Britannica. "Ore". Encyclopædia Britannica Online. Ret ...
such as gold and copper.
Clay minerals Clay minerals are hydrous aluminium phyllosilicates (e.g. kaolin, Al2 Si2 O5( OH)4), sometimes with variable amounts of iron, magnesium, alkali metals, alkaline earths, and other cations found on or near some planetary surfaces. Clay mineral ...
are commonly formed as
alteration Alteration(s) may refer to: * Alteration (music), the use of a neighboring pitch in the chromatic scale in place of its diatonic neighbor. ** Alteration, in the mensural notation used by renaissance music, the lengthening of a breve, semibreve or ...
products in these deposits, and their presence can be detected using spectroradiometry. Illite, for instance, is commonly observed in the vicinity of hydrothermal ore bodies. Higher concentrations of illite may indicate areas conducive to ore precipitation, and the spectral characteristics of illite, including strong
absorption Absorption may refer to: Chemistry and biology * Absorption (biology), digestion **Absorption (small intestine) *Absorption (chemistry), diffusion of particles of gas or liquid into liquid or solid materials *Absorption (skin), a route by which ...
features near 1400, 1900, and 2200 nm (D1400, D1900, D2200) in the wavelength spectra, can be utilized to identify and trace ore
fluid In physics, a fluid is a liquid, gas, or other material that continuously deforms (''flows'') under an applied shear stress, or external force. They have zero shear modulus, or, in simpler terms, are substances which cannot resist any shear ...
pathways and deposition. Regolith-hosted rare earth element (REE) deposits can also be identified and located using spectroradiometry. These deposits are conventionally situated in highly decomposed granitic rock bodies. The intense weathering processes occurring in granitic rocks give rise to the denudation and leaching of major element
oxides An oxide () is a chemical compound that contains at least one oxygen atom and one other element in its chemical formula. "Oxide" itself is the dianion of oxygen, an O2– (molecular) ion. with oxygen in the oxidation state of −2. Most of the E ...
, leaving behind the highly decomposed regolith. Throughout the weathering process,
clay minerals Clay minerals are hydrous aluminium phyllosilicates (e.g. kaolin, Al2 Si2 O5( OH)4), sometimes with variable amounts of iron, magnesium, alkali metals, alkaline earths, and other cations found on or near some planetary surfaces. Clay mineral ...
such as
kaolinite Kaolinite ( ) is a clay mineral, with the chemical composition Al2 Si2 O5( OH)4. It is an important industrial mineral. It is a layered silicate mineral, with one tetrahedral sheet of silica () linked through oxygen atoms to one octahedral ...
and halloysite are generated as
alteration Alteration(s) may refer to: * Alteration (music), the use of a neighboring pitch in the chromatic scale in place of its diatonic neighbor. ** Alteration, in the mensural notation used by renaissance music, the lengthening of a breve, semibreve or ...
products, which possess a strong affinity for adsorbing
REEs Rees may refer to: Places * Rees, Germany, a city on the lower Rhine * Rees, Illinois, United States, a community in the Jacksonville, Illinois micropolitan area * Rees River, a river in New Zealand * 4587 Rees, an Amor asteroid Other uses * Re ...
, leading to their enrichment in the regolith. One specific REE of interest is neodymium (Nd), which has extensive applications in the industry. Nd exhibits distinctive spectral features in reflectance spectroscopy that can be used for its detection and identification, centred near 740, 800, and 865 nm (D740, D800, D865) in the wavelength spectra. Making use of these spectral characteristics, combined with
geochemical Geochemistry is the science that uses the tools and principles of chemistry to explain the mechanisms behind major geological systems such as the Earth's crust and its oceans. The realm of geochemistry extends beyond the Earth, encompassing the e ...
interpretations and machine learning, the identification and mapping of Nd-enriched regolith areas can be fostered, which may provide implications towards potential REE mineralization and respective ore bodies.


Hydrocarbon exploration

Most
hydrocarbon reservoirs A petroleum reservoir or oil and gas reservoir is a subsurface accumulation of hydrocarbons contained in Porosity, porous or fractured rock formations. Such reservoirs form when kerogen (ancient plant matter) is created in surrounding rock by the ...
are situated deep underground, but their presence can be inferred from surface manifestations including micro-seepages. Micro-seepage occurs when hydrocarbon compounds, such as oil and gas, are released from small
fractures Fracture is the separation of an object or material into two or more pieces under the action of stress. The fracture of a solid usually occurs due to the development of certain displacement discontinuity surfaces within the solid. If a displa ...
and fissures, either directly to the ground surface, or indirectly through the impacts of volatile hydrocarbons on plants and vegetation. While micro-seepages are often not visually discernible, they can be detected using hyperspectral imaging and reflectance spectroscopy. Similarly, the same approach can be used towards the identification of coal reservoirs through their associated coal-bearing rocks, based on the unique spectral imprints given by hydrocarbons, which spans the infrared wavelength regions. Some of the signature spectral features of hydrocarbon molecules are as follows: * OH and CH bonds: Absorption features near 1400 nm. * Aromatic groups: Absorption features near 3280, 5250, 6200, 11000, 14000 nm. * Aliphatic groups: Broad absorption features between 1600 – 1800 nm, 2300 – 2350 nm, and 3400 – 3500 nm, accompanied by another absorption near 6800 nm. * Moisture contents: Absorption features near 1900 and 2940 nm. With spectroradiometry, the spectral properties related to hydrocarbons can be easily detected and analyzed, thereby facilitating the mapping and exploration of such
energy resources World energy resources are the estimated maximum capacity for energy production given all available resources on Earth. They can be divided by type into fossil fuel, nuclear fuel and renewable resources. Fossil fuel Remaining reserves of f ...
.


Planetary geology

The study of planetary geology looks into the geology of planets aside from Earth, as well as moons,
asteroid An asteroid is a minor planet of the inner Solar System. Sizes and shapes of asteroids vary significantly, ranging from 1-meter rocks to a dwarf planet almost 1000 km in diameter; they are rocky, metallic or icy bodies with no atmosphere. ...
s, and other
celestial bodies An astronomical object, celestial object, stellar object or heavenly body is a naturally occurring physical entity, association, or structure that exists in the observable universe. In astronomy, the terms ''object'' and ''body'' are often us ...
. Terrestrial planets have gained popularity among modern scientific research, since they offer insights into the evolution of planets and have demonstrated the potential for
extraterrestrial life Extraterrestrial life, colloquially referred to as alien life, is life that may occur outside Earth and which did not originate on Earth. No extraterrestrial life has yet been conclusively detected, although efforts are underway. Such life might ...
in the Solar System. Spectroradiometry, with its ability to characterize surficial compositions and study the geology of these
celestial bodies An astronomical object, celestial object, stellar object or heavenly body is a naturally occurring physical entity, association, or structure that exists in the observable universe. In astronomy, the terms ''object'' and ''body'' are often us ...
, is considered a key technique in
planetary science Planetary science (or more rarely, planetology) is the scientific study of planets (including Earth), celestial bodies (such as moons, asteroids, comets) and planetary systems (in particular those of the Solar System) and the processes of their f ...
. In recent years, huge efforts are devoted to the exploration of Mars, especially on its geology, which helps unravelling the planet's evolutionary history, understanding past and ongoing events occurring on the planet, and providing insights towards its habitability for human exploration.


Mars

Minerals on Mars are largely mafic, accompanied by substantial amount of clays. Each of these minerals are found in different regions on Mars, and are detected by
spectroradiometer A spectroradiometer is a light measurement tool that is able to measure both the wavelength and amplitude of the light emitted from a light source. Spectrometers discriminate the wavelength based on the position the light hits at the detector array ...
s through their characteristic absorption features on the reflectance spectra. (1) Ices Ices composed of water and carbon dioxide are typically found in the northern and southern permanent
polar caps A polar ice cap or polar cap is a high-latitude region of a planet, dwarf planet, or natural satellite that is covered in ice. There are no requirements with respect to size or composition for a body of ice to be termed a polar ice cap, nor a ...
on Mars. They also exist as seasonal
frost Frost is a thin layer of ice on a solid surface, which forms from water vapor in an above-freezing atmosphere coming in contact with a solid surface whose temperature is below freezing, and resulting in a phase change from water vapor (a gas) ...
s and
clouds In meteorology, a cloud is an aerosol consisting of a visible mass of miniature liquid droplets, frozen crystals, or other particles suspended in the atmosphere of a planetary body or similar space. Water or various other chemicals may com ...
. * Crystalline H2O ice: Broad absorption features near 1500 nm. * CO2 ice: Narrow absorption features near 1435 nm, with minor absorption peaks near 2280 nm. (2) Mafic silicates * Olivine: Broad absorption features centred near 1000 nm. The features get deeper and wider with increasing iron contents. *
Pyroxene The pyroxenes (commonly abbreviated to ''Px'') are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula , where X represents calcium (Ca), sodium (Na), iron (Fe II) ...
: Broad absorption features near 1000 and 2000 nm. Most
pyroxenes The pyroxenes (commonly abbreviated to ''Px'') are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula , where X represents calcium (Ca), sodium (Na), iron (Fe II) ...
in Mars are calcium depleted ( dunite, pyroxenite) which slightly shifts the absorption features towards shorter wavelengths. * Plagioclase: Broad absorption features centred near 1300 nm given that there is
substitution Substitution may refer to: Arts and media *Chord substitution, in music, swapping one chord for a related one within a chord progression * Substitution (poetry), a variation in poetic scansion * "Substitution" (song), a 2009 song by Silversun Pi ...
of iron and calcium ions. The mafic silicates made up the composition of basaltic crusts on Mars. At Martian valleys and craters, such minerals are often seen associated with hydrated silica deposits resulted from
alteration Alteration(s) may refer to: * Alteration (music), the use of a neighboring pitch in the chromatic scale in place of its diatonic neighbor. ** Alteration, in the mensural notation used by renaissance music, the lengthening of a breve, semibreve or ...
. (3) Iron oxides Iron oxides (mostly
hematite Hematite (), also spelled as haematite, is a common iron oxide compound with the formula, Fe2O3 and is widely found in rocks and soils. Hematite crystals belong to the rhombohedral lattice system which is designated the alpha polymorph of . ...
) are involved in the compositions of most surface soils and dust on Mars, providing implications to Martian surficial processes. *
Hematite Hematite (), also spelled as haematite, is a common iron oxide compound with the formula, Fe2O3 and is widely found in rocks and soils. Hematite crystals belong to the rhombohedral lattice system which is designated the alpha polymorph of . ...
: Broad absorption features near 500 and 920 nm. (4)
Clay minerals Clay minerals are hydrous aluminium phyllosilicates (e.g. kaolin, Al2 Si2 O5( OH)4), sometimes with variable amounts of iron, magnesium, alkali metals, alkaline earths, and other cations found on or near some planetary surfaces. Clay mineral ...
( Phyllosilicates) Iron- and magnesium-bearing
clay minerals Clay minerals are hydrous aluminium phyllosilicates (e.g. kaolin, Al2 Si2 O5( OH)4), sometimes with variable amounts of iron, magnesium, alkali metals, alkaline earths, and other cations found on or near some planetary surfaces. Clay mineral ...
have widespread compositions on Mars. Typical examples are as follows: * Talc: Narrow absorption features at 1400 nm, strong absorption bands near 2310 and 2390 nm. * Prehnite: Absorption features near 1480 and 2350 nm. *
Serpentine Serpentine may refer to: Shapes * Serpentine shape, a shape resembling a serpent * Serpentine curve, a mathematical curve * Serpentine, a type of riding figure Science and nature * Serpentine subgroup, a group of minerals * Serpentinite, a ...
: Broad absorption peaks centred near 1390, 2320, and 2510 nm, with a weak absorption band near 2100 nm. Aluminium-bearing clays are also found on Mars. Their spectral characteristics are mentioned in the previous sections. (5)
Sulphates The sulfate or sulphate ion is a polyatomic anion with the empirical formula . Salts, acid derivatives, and peroxides of sulfate are widely used in industry. Sulfates occur widely in everyday life. Sulfates are salts of sulfuric acid and many ar ...
Sulphates The sulfate or sulphate ion is a polyatomic anion with the empirical formula . Salts, acid derivatives, and peroxides of sulfate are widely used in industry. Sulfates occur widely in everyday life. Sulfates are salts of sulfuric acid and many ar ...
on Mars are polyhydrated. They are scattered along the western hemisphere,
equator The equator is a circle of latitude, about in circumference, that divides Earth into the Northern and Southern hemispheres. It is an imaginary line located at 0 degrees latitude, halfway between the North and South poles. The term can als ...
ial and northern part of Mars, at Valles Marineris, Meridiani Planum, and Arabia. Examples of Martian sulphates include gypsum, bassanite, kieserite, jarosite, and
alunite Alunite is a hydroxylated aluminium potassium sulfate mineral, formula K Al3( S O4)2(O H)6. It was first observed in the 15th century at Tolfa, near Rome, where it was mined for the manufacture of alum. First called ''aluminilite'' by J.C. Del ...
. * Polyhydrated
sulphates The sulfate or sulphate ion is a polyatomic anion with the empirical formula . Salts, acid derivatives, and peroxides of sulfate are widely used in industry. Sulfates occur widely in everyday life. Sulfates are salts of sulfuric acid and many ar ...
: Absorption features near 1400, 1900, and 2400 nm. (6) Zeolites Zeolites are identified in craters near Martian
basins Basin may refer to: Geography and geology * Depression (geology) ** Back-arc basin, a submarine feature associated with island arcs and subduction zones ** Debris basin, designed to prevent damage from debris flow ** Drainage basin (hydrology), a ...
and highlands, providing implications towards the environments on Mars. The most distinctive zeolite mineral discovered on Mars is analcime. * Analcime: Strong absorption features near 1790 and 2500 nm. (7) Carbonates Carbonates on Mars can be iron- or magnesium-rich. Characterized by their paired absorption features near 2300 and 2500 nm, they are found along Nili Fossae, and
Tyrrhena Terra Tyrrhena Terra is a large area on Mars, centered south of the Martian equator and immediately northeast of the Hellas basin. Its coordinates are , and it covers 2300 km at its broadest extent. It was named for a classic albedo feature of the planet ...
located at the southern Martian highlands. The identification of mineral compositions on Mars offers vital clues towards Martian geological processes from the past to the present. In particular, the presence of
clay minerals Clay minerals are hydrous aluminium phyllosilicates (e.g. kaolin, Al2 Si2 O5( OH)4), sometimes with variable amounts of iron, magnesium, alkali metals, alkaline earths, and other cations found on or near some planetary surfaces. Clay mineral ...
serves as the direct evidence of basaltic weathering on Mars. The analysis of
compositional In semantics, mathematical logic and related disciplines, the principle of compositionality is the principle that the meaning of a complex expression is determined by the meanings of its constituent expressions and the rules used to combine them. ...
stratigraphy Stratigraphy is a branch of geology concerned with the study of rock (geology), rock layers (Stratum, strata) and layering (stratification). It is primarily used in the study of sedimentary rock, sedimentary and layered volcanic rocks. Stratigrap ...
provided by Martian rock samples has revealed strengthening
absorption Absorption may refer to: Chemistry and biology * Absorption (biology), digestion **Absorption (small intestine) *Absorption (chemistry), diffusion of particles of gas or liquid into liquid or solid materials *Absorption (skin), a route by which ...
features near 1400 and 1900 nm (D1400 and D1900). These features are diagnostic of elevated hydroxyl (-OH) contents owing to the increasing abundance of
kaolinite Kaolinite ( ) is a clay mineral, with the chemical composition Al2 Si2 O5( OH)4. It is an important industrial mineral. It is a layered silicate mineral, with one tetrahedral sheet of silica () linked through oxygen atoms to one octahedral ...
, in replacement of other
clay minerals Clay minerals are hydrous aluminium phyllosilicates (e.g. kaolin, Al2 Si2 O5( OH)4), sometimes with variable amounts of iron, magnesium, alkali metals, alkaline earths, and other cations found on or near some planetary surfaces. Clay mineral ...
. This reflects the increasing of weathering intensity and the occurrence of aqueous processes on Martian crust, indicating that a wet and warm climate had once existed on the planet. Importantly, the occurrence of intensive chemical weathering on ancient Mars proves the past existence of water. Other than iron oxides and clays, previously detected
sulphates The sulfate or sulphate ion is a polyatomic anion with the empirical formula . Salts, acid derivatives, and peroxides of sulfate are widely used in industry. Sulfates occur widely in everyday life. Sulfates are salts of sulfuric acid and many ar ...
, carbonates, and zeolites also serve as the proxies of water.
Sulphates The sulfate or sulphate ion is a polyatomic anion with the empirical formula . Salts, acid derivatives, and peroxides of sulfate are widely used in industry. Sulfates occur widely in everyday life. Sulfates are salts of sulfuric acid and many ar ...
commonly form as a result of the
alteration Alteration(s) may refer to: * Alteration (music), the use of a neighboring pitch in the chromatic scale in place of its diatonic neighbor. ** Alteration, in the mensural notation used by renaissance music, the lengthening of a breve, semibreve or ...
of crustal materials by groundwater and rain, and the precipitation of evaporated water bodies. Carbonates are originated from interactions between water and basalts in a CO2-rich environment, whereas zeolites are formed in
alkaline In chemistry, an alkali (; from ar, القلوي, al-qaly, lit=ashes of the saltwort) is a base (chemistry), basic, ionic compound, ionic salt (chemistry), salt of an alkali metal or an alkaline earth metal. An alkali can also be defined as ...
waters and hydrothermal environments. The presence of these minerals altogether account for the evidence for the past occurrence of water on Mars. They also imply possibility of the planet having supported life at some point.


Spectroradiometer as a tool in Spectroradiometry

Spectroradiometer A spectroradiometer is a light measurement tool that is able to measure both the wavelength and amplitude of the light emitted from a light source. Spectrometers discriminate the wavelength based on the position the light hits at the detector array ...
s are primarily used as remote sensors in spectroradiometry to detect and quantify light intensity and its associated parameters (e.g. wavelength, amplitude). Spectral reflectance and transmittance data are digitally recorded which facilitates spectral analysis.


Components of Spectroradiometers

* ''Fore optics'': Optical lenses, diffusers,
filters Filter, filtering or filters may refer to: Science and technology Computing * Filter (higher-order function), in functional programming * Filter (software), a computer program to process a data stream * Filter (video), a software component tha ...
, and slits. These components modify the source
radiation In physics, radiation is the emission or transmission of energy in the form of waves or particles through space or through a material medium. This includes: * ''electromagnetic radiation'', such as radio waves, microwaves, infrared, visi ...
to ensure that it can be delivered to the detectors appropriately and efficiently. A calibration unit is often attached to maintain data accuracy. * '' Monochromator'': Captures and splits incoming
radiation In physics, radiation is the emission or transmission of energy in the form of waves or particles through space or through a material medium. This includes: * ''electromagnetic radiation'', such as radio waves, microwaves, infrared, visi ...
(polychromatic light) into ranges of different wavelengths (monochromatic light) to foster spectral analysis. * '' Detector'': Detects and records spectra of electromagnetic radiation. Different detectors may be used depending on the wavelength intervals to be measured. Examples include CCD (Charge Coupled Device) arrays and CMOS (Complementary Metal Oxide Semiconductor) sensors. Imaging spectroradiometers generate
digital image A digital image is an image composed of picture elements, also known as ''pixels'', each with ''finite'', '' discrete quantities'' of numeric representation for its intensity or gray level that is an output from its two-dimensional functions ...
ry that captures spectral parameters with spatial variation, meaning that they record variations in spectral properties within the spectroradiometer's field of view. These instruments are typically larger in sizes and are situated far away from the targeted areas of measurement, such that can be found in spaceborne platforms, such as
satellites A satellite or artificial satellite is an object intentionally placed into orbit in outer space. Except for passive satellites, most satellites have an electricity generation system for equipment on board, such as solar panels or radioisotop ...
, or
airborne Airborne or Airborn may refer to: Arts, entertainment, and media Films * ''Airborne'' (1962 film), a 1962 American film directed by James Landis * ''Airborne'' (1993 film), a comedy–drama film * ''Airborne'' (1998 film), an action film sta ...
platforms, including aircraft and drones. In contrast, non-imaging spectroradiometers capture the spectral properties of the entire field of view without spatial variations. Many non-imaging spectroradiometers are relatively smaller in sizes and utilized in ground-based applications. Some are used in
laboratories A laboratory (; ; colloquially lab) is a facility that provides controlled conditions in which scientific or technological research, experiments, and measurement may be performed. Laboratory services are provided in a variety of settings: physicia ...
while some are portable and can be used in the field.


Resolution of Spectroradiometers

The
resolution Resolution(s) may refer to: Common meanings * Resolution (debate), the statement which is debated in policy debate * Resolution (law), a written motion adopted by a deliberative body * New Year's resolution, a commitment that an individual mak ...
of spectroradiometers refers to the potential extent of details that can be detected by the sensors. In general, 4 kinds of resolutions are commonly specified for each spectroradiometer. '' Spectral resolution'' concerns the capability of a
sensor A sensor is a device that produces an output signal for the purpose of sensing a physical phenomenon. In the broadest definition, a sensor is a device, module, machine, or subsystem that detects events or changes in its environment and sends ...
in a
spectroradiometer A spectroradiometer is a light measurement tool that is able to measure both the wavelength and amplitude of the light emitted from a light source. Spectrometers discriminate the wavelength based on the position the light hits at the detector array ...
to measure the light intensity according to specific wavelengths on the electromagnetic spectrum. It is related to the amount of spectral detail to be detected in each
spectral band Spectral bands are parts of the electromagnetic spectrum of specific wavelengths, which can be filtered by a standard filter. In nuclear physics, spectral bands are referred to the emission of polyatomic systems, including condensed materials, larg ...
so as to discriminate among different materials. Described by the amount, wavelength interval, and width of spectral bands in which the sensor conducts wavelength measurements, a sensor with high ''spectral resolution'' would mean that it is able to capture a spectrum of light and divides it into hundreds or thousands of narrow
spectral bands Spectral bands are parts of the electromagnetic spectrum of specific wavelengths, which can be filtered by a standard filter. In nuclear physics, spectral bands are referred to the emission of polyatomic systems, including condensed materials, larg ...
or channels with typical widths up to 10 and 20 nm. In modern times, multi- and hyperspectral imaging sensors are mainly adopted in spectroradiometry. Unlike ordinary broadband sensors which possess only a few
spectral bands Spectral bands are parts of the electromagnetic spectrum of specific wavelengths, which can be filtered by a standard filter. In nuclear physics, spectral bands are referred to the emission of polyatomic systems, including condensed materials, larg ...
for measurements, they enable the extraction of spectral properties in sufficiently high
spectral resolution The spectral resolution of a spectrograph, or, more generally, of a frequency spectrum, is a measure of its ability to resolve features in the electromagnetic spectrum. It is usually denoted by \Delta\lambda, and is closely related to the resolvi ...
s, allowing for the detection and analysis of diagnostic
absorption Absorption may refer to: Chemistry and biology * Absorption (biology), digestion **Absorption (small intestine) *Absorption (chemistry), diffusion of particles of gas or liquid into liquid or solid materials *Absorption (skin), a route by which ...
features in a continuous spectrum.
Hyperspectral Hyperspectral imaging collects and processes information from across the electromagnetic spectrum. The goal of hyperspectral imaging is to obtain the spectrum for each pixel in the image of a scene, with the purpose of finding objects, identifyi ...
sensors divide the detected light intensity into many, narrow, and contiguous (i.e., adjacent)
spectral bands Spectral bands are parts of the electromagnetic spectrum of specific wavelengths, which can be filtered by a standard filter. In nuclear physics, spectral bands are referred to the emission of polyatomic systems, including condensed materials, larg ...
to reconstruct a full spectrum, while multispectral sensors measures light intensity using
spectral bands Spectral bands are parts of the electromagnetic spectrum of specific wavelengths, which can be filtered by a standard filter. In nuclear physics, spectral bands are referred to the emission of polyatomic systems, including condensed materials, larg ...
of varying bandwidths in the wavelength spectrum which might not be contiguous. Consequently, a hyperspectral sensor is often regarded as having greater ''
spectral resolution The spectral resolution of a spectrograph, or, more generally, of a frequency spectrum, is a measure of its ability to resolve features in the electromagnetic spectrum. It is usually denoted by \Delta\lambda, and is closely related to the resolvi ...
'' in comparison to a multispectral sensor, hence a better potential in mineralogical diagnosis and
lithology The lithology of a rock unit is a description of its physical characteristics visible at outcrop, in hand or core samples, or with low magnification microscopy. Physical characteristics include colour, texture, grain size, and composition. Lit ...
mapping. '' Spatial resolution'' evaluates the quality of an image captured by imaging spectroradiometers. It describes the extent of spatial detail the sensors can record, i.e., the smallest feature detected, based on pixel and grid sizes of the captured
digital image A digital image is an image composed of picture elements, also known as ''pixels'', each with ''finite'', '' discrete quantities'' of numeric representation for its intensity or gray level that is an output from its two-dimensional functions ...
ry. A sensor with fine ''spatial resolution'' would capture an image with small grid cells, thus recording more spatial details and image pixels. '' Radiometric resolution'' deals with the sensitivity of a sensor towards measuring the magnitude of electromagnetic radiation and light intensity. A sensor with high ''radiometric resolution'' can detect and discriminate subtle variations in brightness and
radiation In physics, radiation is the emission or transmission of energy in the form of waves or particles through space or through a material medium. This includes: * ''electromagnetic radiation'', such as radio waves, microwaves, infrared, visi ...
magnitudes. In the context of multispectral imaging, the greater the number of data bits per pixel (bit depth) of the
image An image is a visual representation of something. It can be two-dimensional, three-dimensional, or somehow otherwise feed into the visual system to convey information. An image can be an artifact, such as a photograph or other two-dimensiona ...
recorded, the better the quality and interpretability of the
image An image is a visual representation of something. It can be two-dimensional, three-dimensional, or somehow otherwise feed into the visual system to convey information. An image can be an artifact, such as a photograph or other two-dimensiona ...
, thus the finer the ''radiometric resolution''. '' Temporal resolution'' is the frequency or the repeat cycle of a sensor, most commonly referring to sensors on imaging spectroradiometers, to capture images and acquire spectral information. An imaging spectroradiometer with high ''temporal resolution'' typically requires less time to complete spectral measurements of an
image An image is a visual representation of something. It can be two-dimensional, three-dimensional, or somehow otherwise feed into the visual system to convey information. An image can be an artifact, such as a photograph or other two-dimensiona ...
.


Spectroradiometers in practice

The following table shows the categories and some examples of
spectroradiometer A spectroradiometer is a light measurement tool that is able to measure both the wavelength and amplitude of the light emitted from a light source. Spectrometers discriminate the wavelength based on the position the light hits at the detector array ...
s worldwide which are commonly used for spectral data collection in geoscience studies.


Other applications of spectroradiometry

* Ground truthing * Soil analysis and monitoring * Forest canopy and vegetation studies * Landscape ecology studies *
Agricultural Agriculture or farming is the practice of cultivating Plant, plants and livestock. Agriculture was the key development in the rise of Sedentism, sedentary human civilization, whereby farming of Domestication, domesticated species created food ...
studies * Biodiversity conservation * Water quality assessments * Camouflage characterization and detection


See also

*
Spectroradiometer A spectroradiometer is a light measurement tool that is able to measure both the wavelength and amplitude of the light emitted from a light source. Spectrometers discriminate the wavelength based on the position the light hits at the detector array ...
*
Radiometry Radiometry is a set of techniques for measurement, measuring electromagnetic radiation, including visible light. Radiometric techniques in optics characterize the distribution of the radiation's power (physics), power in space, as opposed to phot ...
* Multispectral imaging * Hyperspectral imaging * Reflectance * Ultraviolet-visible spectroscopy * Infrared spectroscopy


References

{{reflist Remote sensing Geological techniques