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Sienna (from it, terra di Siena, meaning "Siena earth") is an earth pigment containing
iron oxide Iron oxides are chemical compounds composed of iron and oxygen. Several iron oxides are recognized. All are black magnetic solids. Often they are non-stoichiometric. Oxyhydroxides are a related class of compounds, perhaps the best known of whic ...
and manganese oxide. In its natural state, it is yellowish brown and is called raw sienna. When heated, it becomes a reddish brown and is called burnt sienna.''Shorter Oxford English Dictionary'', 5th Edition (2002) It takes its name from the city-state of Siena, where it was produced during the Renaissance. Along with
ochre Ochre ( ; , ), or ocher in American English, is a natural clay earth pigment, a mixture of ferric oxide and varying amounts of clay and sand. It ranges in colour from yellow to deep orange or brown. It is also the name of the colours produced ...
and umber, it was one of the first pigments to be used by humans, and is found in many
cave painting In archaeology, Cave paintings are a type of parietal art (which category also includes petroglyphs, or engravings), found on the wall or ceilings of caves. The term usually implies prehistoric origin, and the oldest known are more than 40,000 ye ...
s. Since the Renaissance, it has been one of the brown pigments most widely used by artists. The first recorded use of ''sienna'' as a color name in English was in 1760. The
normalized color coordinates Normalization or normalisation refers to a process that makes something more normal or regular. Most commonly it refers to: * Normalization (sociology) or social normalization, the process through which ideas and behaviors that may fall outside of ...
for sienna are identical to
kobe Kobe ( , ; officially , ) is the capital city of Hyōgo Prefecture Japan. With a population around 1.5 million, Kobe is Japan's seventh-largest city and the third-largest port city after Tokyo and Yokohama. It is located in Kansai region, whic ...
, first recorded as a color name in English in 1924.


Earth colors

Like the other earth colors, such as yellow ochre and umber, sienna is a clay containing
iron oxide Iron oxides are chemical compounds composed of iron and oxygen. Several iron oxides are recognized. All are black magnetic solids. Often they are non-stoichiometric. Oxyhydroxides are a related class of compounds, perhaps the best known of whic ...
, called
limonite Limonite () is an iron ore consisting of a mixture of hydrated iron(III) oxide-hydroxides in varying composition. The generic formula is frequently written as FeO(OH)·H2O, although this is not entirely accurate as the ratio of oxide to hydroxid ...
, which in its natural state has a yellowish colour. In addition to iron oxide, natural or raw sienna also contains about five percent of manganese oxide, which makes it darker than ochre. When heated, the iron oxide is dehydrated and turns partially to
haematite Hematite (), also spelled as haematite, is a common iron oxide compound with the formula, Fe2O3 and is widely found in rocks and soils. Hematite crystals belong to the rhombohedral lattice system which is designated the alpha polymorph of . ...
, which gives it a reddish-brown colour. Sienna is lighter in shade than raw umber, which is also clay with iron oxide, but which has a higher content of manganese (5 to 20 percent) which makes it greenish brown or dark brown. When heated, raw umber becomes burnt umber, a very dark brown. File:Monteriggioni0001.jpg, The clay soil of Tuscany (here near
Monteriggioni Monteriggioni is a ''comune'' in the province of Siena in the Italian region of Tuscany. It borders on the communes of Casole d'Elsa, Castellina in Chianti, Castelnuovo Berardenga, Colle di Val d'Elsa, Poggibonsi, Siena, and Sovicille. The ...
) is rich in limonite, or hydrated iron oxide, the main ingredient of sienna pigment. File:LimoniteUSGOV.jpg,
Limonite Limonite () is an iron ore consisting of a mixture of hydrated iron(III) oxide-hydroxides in varying composition. The generic formula is frequently written as FeO(OH)·H2O, although this is not entirely accurate as the ratio of oxide to hydroxid ...
, a clay containing iron oxide, which gives the color to sienna pigment File:Hematite.jpg,
Haematite Hematite (), also spelled as haematite, is a common iron oxide compound with the formula, Fe2O3 and is widely found in rocks and soils. Hematite crystals belong to the rhombohedral lattice system which is designated the alpha polymorph of . ...
. When limonite is roasted, it turns partially to
haematite Hematite (), also spelled as haematite, is a common iron oxide compound with the formula, Fe2O3 and is widely found in rocks and soils. Hematite crystals belong to the rhombohedral lattice system which is designated the alpha polymorph of . ...
and becomes more reddish. File:Pigment sienna burnt iconofile.jpg, After being heated, the pigment has become the color known as burnt sienna.


History

The pigment sienna was known and used, in its natural form, by the ancient Romans. It was mined near Arcidosso, formerly under Sienese control, now in the province of Grosseto, on Monte Amiata in southern Tuscany. It was called ''terra rossa'' (red earth), ''terra gialla'', or terra di Siena''.'' During the Renaissance, it was noted by the most widely read author about painting techniques, Giorgio Vasari, under the name terra rossa. It became, along with umber and yellow ochre, one of the standard browns used by artists from the 16th to 19th centuries, including
Caravaggio Michelangelo Merisi (Michele Angelo Merigi or Amerighi) da Caravaggio, known as simply Caravaggio (, , ; 29 September 1571 – 18 July 1610), was an Italian painter active in Rome for most of his artistic life. During the final four years of hi ...
(1571-1610) and
Rembrandt Rembrandt Harmenszoon van Rijn (, ; 15 July 1606 – 4 October 1669), usually simply known as Rembrandt, was a Dutch Golden Age painter, printmaker and draughtsman. An innovative and prolific master in three media, he is generally consid ...
(1606-1669), who used all the earth colors, including ochre, sienna and umber, in his palette.John Burnet (1880), A Treatise on Painting in Four Parts, (Google Books)David Bomfeld, Christopher Brown, Ashok Roy, (1988) Rembrandt- Art in the Making - Rembrandt. Yale University Press, (). By the 1940s, the traditional sources in Italy were nearly exhausted. Much of today's sienna production is carried out in the Italian islands of Sardinia and Sicily, while other major deposits are found in the Appalachian Mountains, where it is often found alongside the region's iron deposits. It is also still produced in the French Ardennes, in the small town of Bonne Fontaine near Ecordal. p. 30 In the 20th century, pigments began to be produced using synthetic iron oxide rather than the natural earth. The labels on paint tubes indicate whether they contain natural or synthetic ingredients. PY-43 indicates natural raw sienna, PR-102 indicates natural burnt sienna. File:Giorgio Vasari - The battle of Marciano in Val di Chiana - Google Art Project.jpg , Giorgio Vasari (1511–1574) used earth colors, including ochre and sienna, in his frescos, including this painting in the Hall of the Five Hundred at the
Palazzo Vecchio The Palazzo Vecchio ( "Old Palace") is the City hall, town hall of Florence, Italy. It overlooks the Piazza della Signoria, which holds a copy of Michelangelo's ''David (Michelangelo), David'' statue, and the gallery of statues in the adjacent ...
in Florence. In his writings Vasari called sienna terra rossa.Giorgio Vasari, Lives of the Most Eminent Painters, Sculptors and Architects. (Google Books). File:Rembrandt Self-portrait (Kenwood).jpg ,
Rembrandt Rembrandt Harmenszoon van Rijn (, ; 15 July 1606 – 4 October 1669), usually simply known as Rembrandt, was a Dutch Golden Age painter, printmaker and draughtsman. An innovative and prolific master in three media, he is generally consid ...
van Rijn used all the earth pigments, including sienna, ochre, and umber, to create his rich and complex browns.


Variations

There is no single agreed standard for the colour of sienna, and the name is used today for a wide variety of hues and shades. They vary by country and colour list, and there are many proprietary variations offered by paint companies. The colour box at the top of the article shows one variation from the ISCC-NBS colour list.


Raw sienna

Raw sienna is a yellowish-brown natural earth pigment, composed primarily of iron oxide hydroxide. The box shows the colour of the pigment in its natural, or raw state. It contains a large quantity of iron oxide and a small quantity (about five percent) of manganese oxide. This kind of pigment is known as yellow ochre, yellow earth, limonite, or terra gialla. The pigment name for natural raw sienna from the Colour Index International, shown on the labels of oil paints, is PY-43. This box at right shows a variation of raw sienna from the Italian Ferrario 1919 colour list.


Burnt sienna

Burnt sienna contains a large proportion of anhydrous iron oxide. It is made by heating raw sienna, which dehydrates the iron oxide, changing it partially to haematite, giving it rich reddish-brown colour. The pigment is also known as red earth, red ochre, and terra rossa. On the Colour Index International, the pigment is known as PR-102. This version is from the Italian Ferrario 1919 colour list. The first recorded use of ''burnt sienna'' as a colour name in English was in 1853.Maerz and Paul ''A Dictionary of Color'' 1930 New York: McGraw-Hill p. 204; Color Sample of Sienna: p. 33 Plate 5 Color Sample F12


Burnt sienna pigment (Maerz and Paul)

This variation of burnt sienna is from the Maerz and Paul "A Dictionary of Color" from 1930. It is considerably lighter than most other versions of burnt sienna. It was a mix of burnt orange and raw sienna.


Dark sienna (ISCC-NBS)

This infobox shows the colour dark sienna. This variation is from the ISCC-NBS colour list. A similar dark sienna paint was frequently used on Bob Ross's TV show, '' The Joy of Painting''.


Sienna (X11 colour)

The
web colour Web colors are colors used in displaying web pages on the World Wide Web, and the methods for describing and specifying those colors. Colors may be specified as an RGB triplet or in hexadecimal format (a ''hex triplet'') or according to their ...
sienna is defined by the list of
X11 colours In computing, on the X Window System, X11 color names are represented in a simple text file, which maps certain strings to RGB color values. It was traditionally shipped with every X11 installation, hence the name, and is usually located in ''< ...
used in web browsers and web design.


See also

*
List of colours These are the lists of colors; * List of colors: A–F * List of colors: G–M * List of colors: N–Z * List of colors (compact) * List of colors by shade * List of color palettes * List of Crayola crayon colors * List of RAL colors * List of X ...
* List of inorganic pigments


References

{{Shades of brown, sienna Iron oxide pigments Shades of brown