Earth Pigment
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Earth Pigment
Earth pigments are naturally occurring minerals containing metal oxides, principally iron oxides and manganese oxides, that have been used since prehistoric times as pigments. The primary types are ochre, sienna and umber. Earth pigments are known for their fast drying time in oil painting, relative inexpensiveness, and lightfastness. Cave paintings done in sienna still survive today. Production After mining, the mineral used for making a pigment is ground to a very fine powder (if not already in the form of clay), washed to remove water-soluble components, dried, and ground again to powder. For some pigments, notably sienna and umber, the color can be deepened by heating (calcination) in a process known as "burning", although it does not involve oxidation but instead dehydration In physiology, dehydration is a lack of total body water, with an accompanying disruption of metabolic processes. It occurs when free water loss exceeds free water intake, usually due to exercise, d ...
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Mineral
In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2011): Minerals'; p. 1. In the series ''Geology: Landforms, Minerals, and Rocks''. Rosen Publishing Group. The geological definition of mineral normally excludes compounds that occur only in living organisms. However, some minerals are often biogenic (such as calcite) or are organic compounds in the sense of chemistry (such as mellite). Moreover, living organisms often synthesize inorganic minerals (such as hydroxylapatite) that also occur in rocks. The concept of mineral is distinct from rock, which is any bulk solid geologic material that is relatively homogeneous at a large enough scale. A rock may consist of one type of mineral, or may be an aggregate of two or more different types of minerals, spacially segregated into distinct ...
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Iron Oxide
Iron oxides are chemical compounds composed of iron and oxygen. Several iron oxides are recognized. All are black magnetic solids. Often they are non-stoichiometric. Oxyhydroxides are a related class of compounds, perhaps the best known of which is rust. Iron oxides and oxyhydroxides are widespread in nature and play an important role in many geological and biological processes. They are used as iron ores, pigments, catalysts, and in thermite, and occur in hemoglobin. Iron oxides are inexpensive and durable pigments in paints, coatings and colored concretes. Colors commonly available are in the "earthy" end of the yellow/orange/red/brown/black range. When used as a food coloring, it has E number E172. Stoichiometries Iron oxides feature as ferrous ( Fe(II)) or ferric ( Fe(III)) or both. They adopt octahedral or tetrahedral coordination geometry. Only a few oxides are significant at the earth's surface, particularly wüstite, magnetite, and hematite. * Oxides of FeII ...
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Manganese Oxide
Manganese oxide is any of a variety of manganese oxides and hydroxides.Wells A.F. (1984) ''Structural inorganic chemistry'' 5th edition Oxford Science Publications, . These include * Manganese(II) oxide, MnO * Manganese(II,III) oxide, Mn3O4 * Manganese(III) oxide, Mn2O3 * Manganese dioxide, MnO2 * Manganese(VI) oxide, MnO3 * Manganese(VII) oxide, Mn2O7 Other manganese oxides include Mn5O8, Mn7O12 and Mn7O13. Minerals It may refer more specifically to the following manganese minerals: * Birnessite * Buserite * Hausmannite * Manganite * Manganosite * Psilomelane * Pyrolusite Manganese may also form mixed oxides with other metals : * Bixbyite, a manganese iron oxide mineral * Jacobsite, a manganese iron oxide mineral * Columbite * Tantalite, a mineral group close to columbite * Coltan, a mixture of columbite and tantalite * Galaxite, a spinel mineral * Todorokite Todorokite is a rare complex hydrous manganese oxide mineral with the chemical formula . It was named in 1934 f ...
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Pigment
A pigment is a colored material that is completely or nearly insoluble in water. In contrast, dyes are typically soluble, at least at some stage in their use. Generally dyes are often organic compounds whereas pigments are often inorganic compounds. Pigments of prehistoric and historic value include ochre, charcoal, and lapis lazuli. Economic impact In 2006, around 7.4 million tons of inorganic, organic, and special pigments were marketed worldwide. Estimated at around US$14.86 billion in 2018 and will rise at over 4.9% CAGR from 2019 to 2026. The global demand for pigments was roughly US$20.5 billion in 2009. According to an April 2018 report by ''Bloomberg Businessweek'', the estimated value of the pigment industry globally is $30 billion. The value of titanium dioxide – used to enhance the white brightness of many products – was placed at $13.2 billion per year, while the color Ferrari red is valued at $300 million each year. Physical principles ...
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Ochre
Ochre ( ; , ), or ocher in American English, is a natural clay earth pigment, a mixture of ferric oxide and varying amounts of clay and sand. It ranges in colour from yellow to deep orange or brown. It is also the name of the colours produced by this pigment, especially a light brownish-yellow. A variant of ochre containing a large amount of hematite, or dehydrated iron oxide, has a reddish tint known as "red ochre" (or, in some dialects, ruddle). The word ochre also describes clays coloured with iron oxide derived during the extraction of tin and copper. Earth pigments Ochre is a family of earth pigments, which includes yellow ochre, red ochre, purple ochre, sienna, and umber. The major ingredient of all the ochres is iron(III) oxide-hydroxide, known as limonite, which gives them a yellow colour. * Yellow ochre, , is a hydrated iron hydroxide (limonite) also called gold ochre. * Red ochre, , takes its reddish colour from the mineral hematite, which is an anhydrous iron ...
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Sienna
Sienna (from it, terra di Siena, meaning "Siena earth") is an earth pigment containing iron oxide and manganese oxide. In its natural state, it is yellowish brown and is called raw sienna. When heated, it becomes a reddish brown and is called burnt sienna.''Shorter Oxford English Dictionary'', 5th Edition (2002) It takes its name from the city-state of Siena, where it was produced during the Renaissance. Along with ochre and umber, it was one of the first pigments to be used by humans, and is found in many cave paintings. Since the Renaissance, it has been one of the brown pigments most widely used by artists. The first recorded use of ''sienna'' as a color name in English was in 1760. The normalized color coordinates for sienna are identical to kobe, first recorded as a color name in English in 1924. Earth colors Like the other earth colors, such as yellow ochre and umber, sienna is a clay containing iron oxide, called limonite, which in its natural state has a yellow ...
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Umber
Umber is a natural brown earth pigment that contains iron oxide and manganese oxide. In its natural form, it is called raw umber. When Calcination, calcined, the color becomes warmer and it becomes known as burnt umber. Its name derives from ''terra d'ombra'', or earth of Umbria, the Italian name of the pigment. Umbria is a mountainous region in central Italy where the pigment was originally extracted. The word also may be related to the Latin word ''umbra'', meaning "shadow". Umber is not one precise color, but a range of different colors, from medium to dark in value, from greenish to reddish in hue. The color of the natural earth depends primarily upon the proportions of iron oxide and manganese in the clay. Umber earth pigments contain between five and twenty percent manganese oxide, which accounts for their being a darker and less saturated color than the related earth pigment, sienna. Commercial umber pigments vary in color depending on their origin and how they are proces ...
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Oil Painting
Oil painting is the process of painting with pigments with a medium of drying oil as the binder. It has been the most common technique for artistic painting on wood panel or canvas for several centuries, spreading from Europe to the rest of the world. The advantages of oil for painting images include "greater flexibility, richer and denser colour, the use of layers, and a wider range from light to dark". But the process is slower, especially when one layer of paint needs to be allowed to dry before another is applied. The oldest known oil paintings were created by Buddhist artists in Afghanistan and date back to the 7th century AD. The technique of binding pigments in oil was later brought to Europe in the 15th century, about 900 years later. The adoption of oil paint by Europeans began with Early Netherlandish painting in Northern Europe, and by the height of the Renaissance, oil painting techniques had almost completely replaced the use of tempera paints in the majority ...
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Lightfastness
Lightfastness is a property of a colourant such as dye or pigment that describes its resistance to fading when exposed to light. Dyes and pigments are used for example for dyeing of fabrics, plastics or other materials and manufacturing paints or printing inks. The bleaching of the color is caused by the impact of ultraviolet radiation in the chemical structure of the molecules giving the color of the subject. The part of a molecule responsible for its color is called the chromophore. Light encountering a painted surface can either alter or break the chemical bonds of the pigment, causing the colors to bleach or change in a process known as photodegradation. Materials that resist this effect are said to be lightfast. The electromagnetic spectrum of the sun contains wavelengths from gamma waves to radio waves. The high energy of ultraviolet radiation in particular accelerates the fading of the dye. The photon energy of UVA-radiation which is not absorbed by atmospheric ozone e ...
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Calcination
Calcination refers to thermal treatment of a solid chemical compound (e.g. mixed carbonate ores) whereby the compound is raised to high temperature without melting under restricted supply of ambient oxygen (i.e. gaseous O2 fraction of air), generally for the purpose of removing impurities or volatile substances and/or to incur thermal decomposition. The root of the word calcination refers to its most prominent use, which is to remove carbon from limestone (calcium carbonate) through combustion to yield calcium oxide (quicklime). This calcination reaction is CaCO3(s) → CaO(s) + CO2(g). Calcium oxide is a crucial ingredient in modern cement, and is also used as a chemical flux in smelting. Industrial calcination generally emits carbon dioxide (), making it a major contributor to climate change. A calciner is a steel cylinder that rotates inside a heated furnace and performs indirect high-temperature processing (550–1150 °C, or 1000–2100 °F) within a controlled ...
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Oxidation
Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or a decrease in the oxidation state. There are two classes of redox reactions: * ''Electron-transfer'' – Only one (usually) electron flows from the reducing agent to the oxidant. This type of redox reaction is often discussed in terms of redox couples and electrode potentials. * ''Atom transfer'' – An atom transfers from one substrate to another. For example, in the rusting of iron, the oxidation state of iron atoms increases as the iron converts to an oxide, and simultaneously the oxidation state of oxygen decreases as it accepts electrons released by the iron. Although oxidation reactions are commonly associated with the formation of oxides, other chemical species can serve the same function. In hydrogenation, C=C (and other) bonds ar ...
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