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In ionizing radiation detection physics, a semiconductor detector is a device that uses a semiconductor (usually
silicon Silicon is a chemical element; it has symbol Si and atomic number 14. It is a hard, brittle crystalline solid with a blue-grey metallic lustre, and is a tetravalent metalloid (sometimes considered a non-metal) and semiconductor. It is a membe ...
or
germanium Germanium is a chemical element; it has Symbol (chemistry), symbol Ge and atomic number 32. It is lustrous, hard-brittle, grayish-white and similar in appearance to silicon. It is a metalloid or a nonmetal in the carbon group that is chemically ...
) to measure the effect of incident charged particles or photons. Semiconductor detectors find broad application for
radiation protection Radiation protection, also known as radiological protection, is defined by the International Atomic Energy Agency (IAEA) as "The protection of people from harmful effects of exposure to ionizing radiation, and the means for achieving this". Exposu ...
,
gamma Gamma (; uppercase , lowercase ; ) is the third letter of the Greek alphabet. In the system of Greek numerals it has a value of 3. In Ancient Greek, the letter gamma represented a voiced velar stop . In Modern Greek, this letter normally repr ...
and X-ray spectrometry, and as
particle detector In experimental and applied particle physics, nuclear physics, and nuclear engineering, a particle detector, also known as a radiation detector, is a device used to detect, track, and/or identify ionizing elementary particle, particles, such as t ...
s.


Detection mechanism

In semiconductor detectors, ionizing radiation is measured by the number of
charge carrier In solid state physics, a charge carrier is a particle or quasiparticle that is free to move, carrying an electric charge, especially the particles that carry electric charges in electrical conductors. Examples are electrons, ions and holes. ...
s set free in the detector material which is arranged between two
electrode An electrode is an electrical conductor used to make contact with a nonmetallic part of a circuit (e.g. a semiconductor, an electrolyte, a vacuum or a gas). In electrochemical cells, electrodes are essential parts that can consist of a varie ...
s, by the radiation. Ionizing radiation produces free
electron The electron (, or in nuclear reactions) is a subatomic particle with a negative one elementary charge, elementary electric charge. It is a fundamental particle that comprises the ordinary matter that makes up the universe, along with up qua ...
s and
electron hole In physics, chemistry, and electronic engineering, an electron hole (often simply called a hole) is a quasiparticle denoting the lack of an electron at a position where one could exist in an atom or crystal structure, atomic lattice. Since in ...
s. The number of electron-hole pairs is proportional to the energy of the radiation to the semiconductor. As a result, a number of electrons are transferred from the
valence band In solid-state physics, the valence band and conduction band are the bands closest to the Fermi level, and thus determine the electrical conductivity of the solid. In nonmetals, the valence band is the highest range of electron energies in ...
to the
conduction band In solid-state physics, the valence band and conduction band are the bands closest to the Fermi level, and thus determine the electrical conductivity of the solid. In nonmetals, the valence band is the highest range of electron energies in ...
, and an equal number of holes are created in the valence band. Under the influence of an
electric field An electric field (sometimes called E-field) is a field (physics), physical field that surrounds electrically charged particles such as electrons. In classical electromagnetism, the electric field of a single charge (or group of charges) descri ...
, electrons and holes travel to the electrodes, where they result in a pulse that can be measured in an outer circuit, as described by the Shockley-Ramo theorem. The holes travel in the opposite direction and can also be measured. As the amount of energy required to create an electron-hole pair is known, and is independent of the energy of the incident radiation, measuring the number of electron-hole pairs allows the energy of the incident radiation to be determined. The energy required to produce electron-hole-pairs is very low compared to the energy required to produce paired ions in a gas detector. Consequently, in semiconductor detectors the statistical variation of the pulse height is smaller and the energy resolution is higher. As the electrons travel fast, the time resolution is also very good, and is dependent upon
rise time In electronics, when describing a voltage or current step function, rise time is the time taken by a signal to change from a specified low value to a specified high value. These values may be expressed as ratiosSee for example , and . or, equiva ...
. Compared with gaseous ionization detectors, the
density Density (volumetric mass density or specific mass) is the ratio of a substance's mass to its volume. The symbol most often used for density is ''ρ'' (the lower case Greek letter rho), although the Latin letter ''D'' (or ''d'') can also be u ...
of a semiconductor detector is very high, and charged particles of high energy can give off their energy in a semiconductor of relatively small dimensions.


Detector types


Silicon detectors

Most silicon
particle In the physical sciences, a particle (or corpuscle in older texts) is a small localized object which can be described by several physical or chemical properties, such as volume, density, or mass. They vary greatly in size or quantity, from s ...
detectors work, in principle, by doping narrow (usually around 100 micrometers wide) silicon strips to turn them into
diode A diode is a two-Terminal (electronics), terminal electronic component that conducts electric current primarily in One-way traffic, one direction (asymmetric electrical conductance, conductance). It has low (ideally zero) Electrical resistance ...
s, which are then reverse biased. As charged particles pass through these strips, they cause small ionization currents that can be detected and measured. Arranging thousands of these detectors around a collision point in a
particle accelerator A particle accelerator is a machine that uses electromagnetic fields to propel electric charge, charged particles to very high speeds and energies to contain them in well-defined particle beam, beams. Small accelerators are used for fundamental ...
can yield an accurate picture of what paths particles take. Silicon detectors have a much higher resolution in tracking charged particles than older technologies such as
cloud chamber A cloud chamber, also known as a Wilson chamber, is a particle detector used for visualizing the passage of ionizing radiation. A cloud chamber consists of a sealed environment containing a supersaturated vapor of water or alcohol. An energetic ...
s or wire chambers. The drawback is that silicon detectors are much more expensive than these older technologies and require sophisticated cooling to reduce leakage currents (noise source). They also suffer degradation over time from
radiation In physics, radiation is the emission or transmission of energy in the form of waves or particles through space or a material medium. This includes: * ''electromagnetic radiation'' consisting of photons, such as radio waves, microwaves, infr ...
, however, this can be greatly reduced thanks to the Lazarus effect.


Diamond detectors

Diamond Diamond is a Allotropes of carbon, solid form of the element carbon with its atoms arranged in a crystal structure called diamond cubic. Diamond is tasteless, odourless, strong, brittle solid, colourless in pure form, a poor conductor of e ...
detectors have many similarities with silicon detectors but are expected to offer significant advantages – in particular a high radiation hardness and very low drift currents. They are also suited to neutron detection. At present, however, they are much more expensive and more difficult to manufacture.


Germanium detectors

Germanium Germanium is a chemical element; it has Symbol (chemistry), symbol Ge and atomic number 32. It is lustrous, hard-brittle, grayish-white and similar in appearance to silicon. It is a metalloid or a nonmetal in the carbon group that is chemically ...
detectors are mostly used for
gamma spectroscopy Gamma-ray spectroscopy is the ''qualitative'' study of the energy spectra of gamma-ray sources, such as in the nuclear industry, geochemical investigation, and astrophysics. Gamma-ray spectrometry, on the other hand, is the method used to acqu ...
in
nuclear physics Nuclear physics is the field of physics that studies atomic nuclei and their constituents and interactions, in addition to the study of other forms of nuclear matter. Nuclear physics should not be confused with atomic physics, which studies th ...
, as well as
x-ray spectroscopy X-ray spectroscopy is a general term for several Spectroscopy, spectroscopic techniques for characterization of materials by using x-ray radiation. Characteristic X-ray spectroscopy When an electron from the inner shell of an atom is excited b ...
. While silicon detectors cannot be thicker than a few millimeters, germanium can have a sensitive layer (
depletion region In semiconductor physics, the depletion region, also called depletion layer, depletion zone, junction region, space charge region, or space charge layer, is an insulating region within a conductive, doped semiconductor material where the mobil ...
) thickness of centimeters, and therefore can be used as a total absorption detector for gamma rays up to a few MeV. These detectors are also called high-purity germanium detectors (HPGe) or hyperpure germanium detectors. Before current purification techniques were refined, germanium
crystals A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macrosc ...
could not be produced with purity sufficient to enable their use as spectroscopy detectors. Impurities in the crystals trap electrons and holes, ruining the performance of the detectors. Consequently, germanium crystals were doped with
lithium Lithium (from , , ) is a chemical element; it has chemical symbol, symbol Li and atomic number 3. It is a soft, silvery-white alkali metal. Under standard temperature and pressure, standard conditions, it is the least dense metal and the ...
ions (Ge(Li)), in order to produce an
intrinsic In science and engineering, an intrinsic property is a property of a specified subject that exists itself or within the subject. An extrinsic property is not essential or inherent to the subject that is being characterized. For example, mass i ...
region in which the electrons and holes would be able to reach the contacts and produce a signal. When germanium detectors were first developed, only very small crystals were available. Low efficiency was the result, and germanium detector efficiency is still often quoted in relative terms to a "standard" 3″ x 3″ NaI(Tl) scintillation detector. Crystal growth techniques have since improved, allowing detectors to be manufactured that are as large as or larger than commonly available NaI crystals, although such detectors cost more than €100,000 (US$113,000). , HPGe detectors commonly use lithium diffusion to make an n+ ohmic contact, and boron implantation to make a p+ contact. Coaxial detectors with a central n+ contact are referred to as n-type detectors, while p-type detectors have a p+ central contact. The thickness of these contacts represents a dead layer around the surface of the crystal within which energy depositions do not result in detector signals. The central contact in these detectors is opposite to the surface contact, making the dead layer in n-type detectors smaller than the dead layer in p-type detectors. Typical dead layer thicknesses are several hundred micrometers for a Li diffusion layer and a few tenths of a micrometer for a B implantation layer. The major drawback of germanium detectors is that they must be cooled to
liquid nitrogen Liquid nitrogen (LN2) is nitrogen in a liquid state at cryogenics, low temperature. Liquid nitrogen has a boiling point of about . It is produced industrially by fractional distillation of liquid air. It is a colorless, mobile liquid whose vis ...
temperatures to produce spectroscopic data. At higher temperatures, the electrons can easily cross the
band gap In solid-state physics and solid-state chemistry, a band gap, also called a bandgap or energy gap, is an energy range in a solid where no electronic states exist. In graphs of the electronic band structure of solids, the band gap refers to t ...
in the crystal and reach the conduction band, where they are free to respond to the electric field, producing too much electrical noise to be useful as a spectrometer. Cooling to liquid nitrogen temperature (77K) reduces thermal excitations of valence electrons so that only a gamma ray interaction can give an electron the energy necessary to cross the band gap and reach the conduction band. Cooling with liquid nitrogen is inconvenient, as the detector requires hours to cool down to
operating temperature An operating temperature is the allowable temperature range of the local ambient environment at which an electrical or mechanical device operates. The device will operate effectively within a specified temperature range which varies based on the de ...
before it can be used, and cannot be allowed to warm up during use. Ge(Li) crystals could never be allowed to warm up, as the lithium would drift out of the crystal, ruining the detector. HPGe detectors can be allowed to warm up to room temperature when not in use. Commercial systems became available that use advanced refrigeration techniques (for example
pulse tube refrigerator The pulse tube refrigerator (PTR) or pulse tube cryocooler is a developing technology that emerged largely in the early 1980s with a series of other innovations in the broader field of thermoacoustics. In contrast with other cryocoolers (e.g. appl ...
) to eliminate the need for liquid nitrogen cooling. Germanium detectors with multi-strip electrodes, orthogonal on opposing faces, can indicate the 2-D location of the ionization trail within a large single crystal of Ge. Detectors like this have been used in COSI balloon-born astronomy missions (NASA, 2016) and will be used in an orbital observatory (NASA, 2025) Compton Spectrometer and Imager (COSI). Because germanium detectors are highly efficient in photon detection, they can be used for a variety of additional applications. High-purity germanium detectors are used by Homeland Security to differentiate between naturally occurring radioactive material (NORM) and weaponized or otherwise harmful radioactive material. They are also used in monitering the environment due to the concern of the use of nuclear power. Finally, high-purity germanium detectors are used for medical imaging and nuclear physics research, making them a rather diverse detector as far as applications go.


Cadmium telluride and cadmium zinc telluride detectors

Cadmium telluride (CdTe) and cadmium zinc telluride (CZT) detectors have been developed for use in
X-ray spectroscopy X-ray spectroscopy is a general term for several Spectroscopy, spectroscopic techniques for characterization of materials by using x-ray radiation. Characteristic X-ray spectroscopy When an electron from the inner shell of an atom is excited b ...
and
gamma spectroscopy Gamma-ray spectroscopy is the ''qualitative'' study of the energy spectra of gamma-ray sources, such as in the nuclear industry, geochemical investigation, and astrophysics. Gamma-ray spectrometry, on the other hand, is the method used to acqu ...
. The high density of these materials means they can effectively attenuate X-rays and gamma-rays with energies of greater than 20 keV that traditional
silicon Silicon is a chemical element; it has symbol Si and atomic number 14. It is a hard, brittle crystalline solid with a blue-grey metallic lustre, and is a tetravalent metalloid (sometimes considered a non-metal) and semiconductor. It is a membe ...
-based sensors are unable to detect. The wide
band gap In solid-state physics and solid-state chemistry, a band gap, also called a bandgap or energy gap, is an energy range in a solid where no electronic states exist. In graphs of the electronic band structure of solids, the band gap refers to t ...
of these materials also means they have high
resistivity Electrical resistivity (also called volume resistivity or specific electrical resistance) is a fundamental specific property of a material that measures its electrical resistance or how strongly it resists electric current. A low resistivity i ...
and are able to operate at, or close to, room temperature (~295K) unlike
germanium Germanium is a chemical element; it has Symbol (chemistry), symbol Ge and atomic number 32. It is lustrous, hard-brittle, grayish-white and similar in appearance to silicon. It is a metalloid or a nonmetal in the carbon group that is chemically ...
-based sensors. These detector materials can be used to produce sensors with different electrode structures for
imaging Imaging is the representation or reproduction of an object's form; especially a visual representation (i.e., the formation of an image). Imaging technology is the application of materials and methods to create, preserve, or duplicate images. ...
and high-resolution
spectroscopy Spectroscopy is the field of study that measures and interprets electromagnetic spectra. In narrower contexts, spectroscopy is the precise study of color as generalized from visible light to all bands of the electromagnetic spectrum. Spectro ...
. However, CZT detectors are generally unable to match the resolution of germanium detectors, with some of this difference being attributable to poor positive charge-carrier transport to the electrode. Efforts to mitigate this effect have included the development of novel electrodes to negate the need for both polarities of carriers to be collected.


Integrated Systems

Semiconductor detectors are often commercially integrated into larger systems for various radiation measurement applications.


Automated Sample Changing for Germanium Detectors

Gamma spectrometers using HPGe detectors are often used for measurement of low levels of gamma-emitting radionuclides in environmental samples, which requires a low background environment, usually achieved by enclosing the sample and detector in a lead shield known as a 'lead castle'. Automated systems have been developed to sequentially move a number of samples into and out of the lead castle for measurement. Due to the complexities of opening the shield and moving the samples, this automation has traditionally been expensive, but lower-cost autosamplers have recently been introduced.


Radioactive Waste Assay Machines

Semiconductor detectors especially HPGe are often integrated into devices for characterising packaged radioactive waste. This can be as simple as detectors being mounted on a moveable platform to be brought to an area for in-situ measurements and paired with shielding to restrict the field-of-view of the detector to the area of interest for one-shot "open detector geometry" measurements, or for waste in drums, systems such as the Segmented Gamma Scanner (SGS) combine a semiconductor detector with integrated
mechatronics Mechatronics engineering, also called mechatronics, is the synergistic integration of mechanical, electrical, and computer systems employing mechanical engineering, electrical engineering, electronic engineering and computer engineering, and also ...
to rotate the item and scan the detector across different sections. If the detector field of view is scanned across small areas of the item in multiple axes as is done with a Tomographic Gamma Scanner (TGS),
Tomography Tomography is imaging by sections or sectioning that uses any kind of penetrating wave. The method is used in radiology, archaeology, biology, atmospheric science, geophysics, oceanography, plasma physics, materials science, cosmochemistry, ast ...
can be used to extract 3D information about the density and gamma emissions of the item.


Gamma Cameras

Semiconductor detectors are used in some Gamma Cameras and Gamma imaging systems


See also

* Lazarus effect * Pandemonium effect * Synthetic diamonds * Total absorption spectroscopy *
X-ray spectroscopy X-ray spectroscopy is a general term for several Spectroscopy, spectroscopic techniques for characterization of materials by using x-ray radiation. Characteristic X-ray spectroscopy When an electron from the inner shell of an atom is excited b ...
* Microstrip detector * Hybrid pixel detector * Liulin type instruments


References


External links


Silicon Detector powerpoint
delivered for EDIT (Excellence in Detectors and Instrumentation Technologies) 2011 at CERN, M. Krammer, F. Hartmann. {{Authority control Experimental particle physics Ionising radiation detectors Medical imaging Particle detectors X-ray instrumentation