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NASA The National Aeronautics and Space Administration (NASA ) is an independent agency of the US federal government responsible for the civil space program, aeronautics research, and space research. NASA was established in 1958, succeeding t ...
's 2003
Mars Exploration Rover Mission Mars is the fourth planet from the Sun and the second-smallest planet in the Solar System, only being larger than Mercury. In the English language, Mars is named for the Roman god of war. Mars is a terrestrial planet with a thin atmosphe ...
has amassed an enormous amount of scientific information related to the Martian geology and atmosphere, as well as providing some astronomical observations from Mars. This article covers information gathered by the
Opportunity rover ''Opportunity'', also known as MER-B (Mars Exploration Rover – B) or MER-1, is a robotic rover that was active on Mars from 2004 until 2018. ''Opportunity'' was operational on Mars for sols (). Launched on July 7, 2003, as part of NASA's M ...
during the initial phase of its mission. Information on science gathered by Spirit can be found mostly in the
Spirit rover Spirit or spirits may refer to: Liquor and other volatile liquids * Spirits, a.k.a. liquor, distilled alcoholic drinks * Spirit or tincture, an extract of plant or animal material dissolved in ethanol * Volatile (especially flammable) liquids, ...
article. The
unmanned An uncrewed vehicle or unmanned vehicle is a vehicle without a person on board. Uncrewed vehicles can either be under telerobotic control—remote controlled or remote guided vehicles—or they can be autonomously controlled—autonomous vehicl ...
Mars Mars is the fourth planet from the Sun and the second-smallest planet in the Solar System, only being larger than Mercury (planet), Mercury. In the English language, Mars is named for the Mars (mythology), Roman god of war. Mars is a terr ...
exploration mission, commenced in 2003 sent two
robot A robot is a machine—especially one programmable by a computer—capable of carrying out a complex series of actions automatically. A robot can be guided by an external control device, or the control may be embedded within. Robots may be c ...
ic rovers, ''Spirit'' and ''Opportunity'', to explore the Martian surface and
geology Geology () is a branch of natural science concerned with Earth and other astronomical objects, the features or rocks of which it is composed, and the processes by which they change over time. Modern geology significantly overlaps all other Ear ...
. The mission was led by Project Manager Peter Theisinger of
NASA The National Aeronautics and Space Administration (NASA ) is an independent agency of the US federal government responsible for the civil space program, aeronautics research, and space research. NASA was established in 1958, succeeding t ...
's
Jet Propulsion Laboratory The Jet Propulsion Laboratory (JPL) is a federally funded research and development center and NASA field center in the City of La Cañada Flintridge, California, United States. Founded in the 1930s by Caltech researchers, JPL is owned by NASA an ...
and Principal Investigator
Steven Squyres Steven Weldon Squyres (born January 9, 1956) is an American geologist and planetary scientist. He was the James A. Weeks Professor of Physical Sciences at Cornell University in Ithaca, New York. His research area is in planetary sciences, with a f ...
, professor of
astronomy Astronomy () is a natural science that studies astronomical object, celestial objects and phenomena. It uses mathematics, physics, and chemistry in order to explain their origin and chronology of the Universe, evolution. Objects of interest ...
at
Cornell University Cornell University is a private statutory land-grant research university based in Ithaca, New York. It is a member of the Ivy League. Founded in 1865 by Ezra Cornell and Andrew Dickson White, Cornell was founded with the intention to teach an ...
. Primary among the mission's scientific goals is to search for and characterize a wide range of
rocks In geology, rock (or stone) is any naturally occurring solid mass or aggregate of minerals or mineraloid matter. It is categorized by the minerals included, its chemical composition, and the way in which it is formed. Rocks form the Earth's ...
and
soil Soil, also commonly referred to as earth or dirt, is a mixture of organic matter, minerals, gases, liquids, and organisms that together support life. Some scientific definitions distinguish ''dirt'' from ''soil'' by restricting the former te ...
s that hold clues to past water activity on Mars. In recognition of the vast amount of scientific information amassed by both rovers, two
asteroid An asteroid is a minor planet of the inner Solar System. Sizes and shapes of asteroids vary significantly, ranging from 1-meter rocks to a dwarf planet almost 1000 km in diameter; they are rocky, metallic or icy bodies with no atmosphere. ...
s have been named in their honor:
37452 Spirit 37452 Spirit, provisional designation , is a dark Hildian asteroid from the outermost region of the asteroid belt, approximately 9 kilometers in diameter. The asteroid was discovered on 24 September 1960, by Dutch astronomers Ingrid and Cornelis ...
and
39382 Opportunity 39382 Opportunity, also designated , is a dark Hilidan asteroid from the outermost region of the asteroid belt, approximately 7.5 kilometers in diameter. Discovered during the Palomar–Leiden survey at Palomar Observatory in 1960, it was named fo ...
. On January 24, 2014, NASA reported that current studies on the planet
Mars Mars is the fourth planet from the Sun and the second-smallest planet in the Solar System, only being larger than Mercury (planet), Mercury. In the English language, Mars is named for the Mars (mythology), Roman god of war. Mars is a terr ...
by the ''Curiosity'' and ''Opportunity'' rovers will now be searching for evidence of ancient life, including a
biosphere The biosphere (from Greek βίος ''bíos'' "life" and σφαῖρα ''sphaira'' "sphere"), also known as the ecosphere (from Greek οἶκος ''oîkos'' "environment" and σφαῖρα), is the worldwide sum of all ecosystems. It can also be ...
based on
autotroph An autotroph or primary producer is an organism that produces complex organic compounds (such as carbohydrates, fats, and proteins) using carbon from simple substances such as carbon dioxide,Morris, J. et al. (2019). "Biology: How Life Works", ...
ic,
chemotroph A Chemotroph is an organism that obtains energy by the oxidation of electron donors in their environments. These molecules can be organic ( chemoorganotrophs) or inorganic (chemolithotrophs). The chemotroph designation is in contrast to phototro ...
ic or
chemolithoautotrophic A lithoautotroph is an organism which derives energy from reactions of reduced compounds of mineral (inorganic) origin. Two types of lithoautotrophs are distinguished by their energy source; photolithoautotrophs derive their energy from light while ...
microorganism A microorganism, or microbe,, ''mikros'', "small") and ''organism'' from the el, ὀργανισμός, ''organismós'', "organism"). It is usually written as a single word but is sometimes hyphenated (''micro-organism''), especially in olde ...
s, as well as ancient water, including fluvio-lacustrine environments (
plain In geography, a plain is a flat expanse of land that generally does not change much in elevation, and is primarily treeless. Plains occur as lowlands along valleys or at the base of mountains, as coastal plains, and as plateaus or uplands ...
s related to ancient
river A river is a natural flowing watercourse, usually freshwater, flowing towards an ocean, sea, lake or another river. In some cases, a river flows into the ground and becomes dry at the end of its course without reaching another body of wate ...
s or
lake A lake is an area filled with water, localized in a basin, surrounded by land, and distinct from any river or other outlet that serves to feed or drain the lake. Lakes lie on land and are not part of the ocean, although, like the much large ...
s) that may have been
habitable Habitability refers to the adequacy of an environment for human living. Where housing is concerned, there are generally local ordinances which define habitability. If a residence complies with those laws it is said to be habitable. In extreme e ...
. The search for evidence of
habitability Habitability refers to the adequacy of an environment for human living. Where housing is concerned, there are generally local ordinances which define habitability. If a residence complies with those laws it is said to be habitable. In extreme e ...
,
taphonomy Taphonomy is the study of how organisms decay and become fossilized or preserved in the paleontological record. The term ''taphonomy'' (from Greek , 'burial' and , 'law') was introduced to paleontology in 1940 by Soviet scientist Ivan Efremov t ...
(related to
fossils A fossil (from Classical Latin , ) is any preserved remains, impression, or trace of any once-living thing from a past geological age. Examples include bones, shells, exoskeletons, stone imprints of animals or microbes, objects preserved in ...
), and
organic carbon Total organic carbon (TOC) is the amount of carbon found in an organic compound and is often used as a non-specific indicator of water quality or cleanliness of pharmaceutical manufacturing equipment. TOC may also refer to the amount of organic c ...
on the planet
Mars Mars is the fourth planet from the Sun and the second-smallest planet in the Solar System, only being larger than Mercury (planet), Mercury. In the English language, Mars is named for the Mars (mythology), Roman god of war. Mars is a terr ...
is now a primary
NASA The National Aeronautics and Space Administration (NASA ) is an independent agency of the US federal government responsible for the civil space program, aeronautics research, and space research. NASA was established in 1958, succeeding t ...
objective.


Water hypothesis

On March 2, 2004, NASA announced that "Opportunity has landed in an area of Mars where liquid water once drenched the surface". Associate administrator
Ed Weiler Edward J. Weiler (born 1949) was the Associate Administrator for the Science Mission Directorate of the National Aeronautics and Space Administration until his retirement on September 30, 2011. Career Edward J. Weiler received his PhD in astro ...
told reporters that the area "would have been good habitable environment", although no traces of life have been found. This statement was made during a press conference, where mission scientists listed a number of observations that strongly support this view: *Distributions of spherules :''Hypothesis'': Spherules are
concretion A concretion is a hard, compact mass of matter formed by the precipitation of mineral cement within the spaces between particles, and is found in sedimentary rock or soil. Concretions are often ovoid or spherical in shape, although irregular ...
s created in water as a solvent. :''Competing hypothesis'': Spherules are rehardened molten rock droplets, created by volcanoes or meteor strikes. :''Supporting data'': Location of spherules in the rock matrix is random and evenly spread. :''Quote from Steve Squyres'': "The little spherules like blueberries in a muffin are embedded in this rock and
weathering Weathering is the deterioration of rocks, soils and minerals as well as wood and artificial materials through contact with water, atmospheric gases, and biological organisms. Weathering occurs ''in situ'' (on site, with little or no movement), ...
out of it. Three ideas,
lapilli Lapilli is a size classification of tephra, which is material that falls out of the air during a volcanic eruption or during some meteorite impacts. ''Lapilli'' (singular: ''lapillus'') is Latin for "little stones". By definition lapilli range f ...
, little volcanic hailstones, one possibility. Two, droplets of volcanic glass or impact. We've looked at these things very carefully. Probably concretions. If so, it's pointing towards water." Detailed analysis of environmental, chemical, and mineralogical data taken from the Opportunity rover led to the elimination of the competing hypotheses, and the confirmation of the conclusion that the spherules were formed in place as post-depositional sedimentary
concretion A concretion is a hard, compact mass of matter formed by the precipitation of mineral cement within the spaces between particles, and is found in sedimentary rock or soil. Concretions are often ovoid or spherical in shape, although irregular ...
s from an aqueous source *
Vug A vug, vugh, or vugg ( ) is a small- to medium-sized cavity inside rock. It may be formed through a variety of processes. Most commonly, cracks and fissures opened by tectonic activity (folding and faulting) are partially filled by quartz, cal ...
s :''Hypothesis'': Rock was formed in water, for instance by
precipitation In meteorology, precipitation is any product of the condensation of atmospheric water vapor that falls under gravitational pull from clouds. The main forms of precipitation include drizzle, rain, sleet, snow, ice pellets, graupel and hail. ...
. :''Competing hypothesis'': Rock were formed by ash deposits. :''Supporting data'': Voids found in bedrock resemble "
vug A vug, vugh, or vugg ( ) is a small- to medium-sized cavity inside rock. It may be formed through a variety of processes. Most commonly, cracks and fissures opened by tectonic activity (folding and faulting) are partially filled by quartz, cal ...
s" which are left by eroded away, disk-shaped crystals, possibly dissolved in a watery environment. :''Quote from Steve Squyres'': The second piece of evidence is that when we looked at it close-up, it was shot through with tabular holes. Familiar forms. When crystals grow within rocks, precipitated from water. If they're tabular, as they grow you can get tabular crystals and water chem changes and they go away or they weather away." *Sulfates and
jarosite Jarosite is a basic hydrous sulfate of potassium and ferric iron (Fe-III) with a chemical formula of KFe3(SO4)2(OH)6. This sulfate mineral is formed in ore deposits by the oxidation of iron sulfides. Jarosite is often produced as a byproduct duri ...
:''Hypothesis'': Water created tell-tale salt chemicals in the rock. :''Competing hypothesis'': Chemistry of rocks is determined by volcanic processes. :''Supporting data'': Sulfate salts and jarosite mineral were found in the rock. On Earth they are made in standing water (possibly during evaporation). :''Quote from Steve Squyres'': "Next piece of evidence comes from APXS. We found it looked like a lot of sulfur. That was the outside of the rock. We brought with us a grinding tool, the
RAT Rats are various medium-sized, long-tailed rodents. Species of rats are found throughout the order Rodentia, but stereotypical rats are found in the genus ''Rattus''. Other rat genera include ''Neotoma'' ( pack rats), ''Bandicota'' (bandicoot ...
and we ground away 2-4 mm and found even more sulfur. Too much to explain by other than that this rock is full of sulfate salts. That's a telltale sign of liquid water.
Mini-TES The Miniature Thermal Emission Spectrometer (Mini-TES) is an infrared spectrometer used for detecting the composition of a material (typically rocks) from a distance. By making its measurements in the thermal infrared part of the electromagneti ...
also found evidence of sulfate salts. Most compelling of all, the Mössbauer spectrometer in the RATted space showed compelling evidence of jarosite, an iron-(III) sulfate basic hydrate. Fairly rare, found on Earth and had been predicted that it might be found on Mars some day. This is a mineral that you got to have water around to make." On March 23, 2004, NASA announced that they believe that ''Opportunity'' had not landed in a location merely "drenched in water", but on what was once a coastal area. "We think ''Opportunity'' is parked on what was once the shoreline of a salty sea on Mars," said Dr. Steve Squyres of
Cornell University Cornell University is a private statutory land-grant research university based in Ithaca, New York. It is a member of the Ivy League. Founded in 1865 by Ezra Cornell and Andrew Dickson White, Cornell was founded with the intention to teach an ...
. The announcement was based on evidence of
sedimentary rock Sedimentary rocks are types of rock that are formed by the accumulation or deposition of mineral or organic particles at Earth's surface, followed by cementation. Sedimentation is the collective name for processes that cause these particles ...
s that are consistent with those formed by water and not wind. "Bedding patterns in some finely layered rocks indicate the sand-sized grains of sediment that eventually bonded together were shaped into
ripple Ripple may refer to: Science and technology * Capillary wave, commonly known as ripple, a wave traveling along the phase boundary of a fluid ** Ripple, more generally a disturbance, for example of spacetime in gravitational waves * Ripple (electri ...
s by water at least five centimeters (two inches) deep, possibly much deeper, and flowing at a speed of 10 to 50 centimeters (four to 20 inches) per second," said Dr. John Grotzinger, from
MIT The Massachusetts Institute of Technology (MIT) is a private land-grant research university in Cambridge, Massachusetts. Established in 1861, MIT has played a key role in the development of modern technology and science, and is one of the mo ...
. The landing site was likely a salt flat on the edge of a large body of water that was covered by shallow water. Other evidence includes findings of
chlorine Chlorine is a chemical element with the Symbol (chemistry), symbol Cl and atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the periodic table and its properties are mostly intermediate betwee ...
and
bromine Bromine is a chemical element with the symbol Br and atomic number 35. It is the third-lightest element in group 17 of the periodic table (halogens) and is a volatile red-brown liquid at room temperature that evaporates readily to form a simila ...
in the rocks which indicates the rocks had at least soaked in mineral-rich water, possibly from underground sources, after they formed. Increased assurance of the bromine findings strengthens the case that rock-forming particles precipitated from surface water as salt concentrations climbed past saturation while water was evaporating. The evidence for water was published in a series of scientific papers, with the initial results appearing in the journal ''Science'' and then with a detailed discussion of the
sedimentary geology ''Sedimentary Geology'' is a peer-reviewed scientific journal about sediments in a geological context published by Elsevier Elsevier () is a Dutch academic publishing company specializing in scientific, technical, and medical content. Its p ...
of the landing site appearing in a special issue of the journal ''Earth and Planetary Science Letters''


Spherules and hematite

Early in the mission, mission scientists were able to prove that the abundant spherules at Eagle crater were the source of
hematite Hematite (), also spelled as haematite, is a common iron oxide compound with the formula, Fe2O3 and is widely found in rocks and soils. Hematite crystals belong to the rhombohedral lattice system which is designated the alpha polymorph of . ...
in the area discovered from orbit.


Hematite

Geologists were eager to reach a
hematite Hematite (), also spelled as haematite, is a common iron oxide compound with the formula, Fe2O3 and is widely found in rocks and soils. Hematite crystals belong to the rhombohedral lattice system which is designated the alpha polymorph of . ...
-rich area (in the center of the picture at right) to closely examine the soil, which may reveal secrets about how the hematite got to this location. Knowing how the hematite on Mars was formed may help scientists characterize the past environment and determine whether that environment provided favorable conditions for life. "Grey hematite is a mineral indicator of past water," said Dr. Joy Crisp,
JPL The Jet Propulsion Laboratory (JPL) is a federally funded research and development center and NASA field center in the City of La Cañada Flintridge, California, United States. Founded in the 1930s by Caltech researchers, JPL is owned by NASA an ...
project scientist. "It is not always associated with water, but it often is." Scientists have wanted to find out which of these processes created grey hematite on Mars since 1998, when
Mars Global Surveyor ''Mars Global Surveyor'' (MGS) was an American robotic space probe developed by NASA's Jet Propulsion Laboratory and launched November 1996. MGS was a global mapping mission that examined the entire planet, from the ionosphere down through the a ...
spotted large concentrations of the mineral near the planet's
equator The equator is a circle of latitude, about in circumference, that divides Earth into the Northern and Southern hemispheres. It is an imaginary line located at 0 degrees latitude, halfway between the North and South poles. The term can als ...
(seen in the right picture). This discovery provided the first mineral evidence that Mars' history may have included water. "We want to know if the grains of hematite appear to be rounded and cemented together by the action of liquid water or if they're crystals that grew from a volcanic melt," said Crisp. "Is the hematite in layers, which would suggest that it was laid down by water, or in veins in the rock, which would be more characteristic of water having flowed through the rocks." The next picture shows a mineral map, the first ever made on the surface of another planet, which was generated from a section of the panorama picture overlaid with data taken from the rover's Mini-TES. The Mini-TES spectral data was analyzed in a way that the concentration of the mineral hematite was deduced and its level coded in color. Red and orange mean high concentration, green and blue low concentration. The next picture shows a hematite abundance "index map" that helps geologists choose hematite-rich locations to visit around ''Opportunity'''s landing site. Blue dots equal areas low in hematite and red dots equal areas high in hematite. The colored dots represent data collected by the miniature
Thermal Emission Spectrometer The Thermal Emission Spectrometer (TES) is an instrument on board Mars Global Surveyor. TES collects two types of data, hyperspectral thermal infrared data from 6 to 50 micrometres (μm) and bolometric visible-NIR (0.3 to 2.9 μm) measurements. TE ...
on Sol 11, after ''Opportunity'' had rolled off of the lander and the rover was located at the center of the blue semicircle (the spectrometer is located on the panoramic camera mast). The area to the left (with high concentration of hematite) was selected by mission members for further investigation, and called ''Hematite Slope''. During Sol 23 (February 16) ''Opportunity'' successfully trenched the soil at ''Hematite Slope'' and started to investigate the details of the layering.


Spherules

Microscopic images of the
soil Soil, also commonly referred to as earth or dirt, is a mixture of organic matter, minerals, gases, liquids, and organisms that together support life. Some scientific definitions distinguish ''dirt'' from ''soil'' by restricting the former te ...
taken by ''Opportunity'' revealed small spherically shaped granules. They were first seen on pictures taken on Sol 10, right after the rover drove from the lander onto martian soil. When ''Opportunity'' dug her first trench (Sol 23), pictures of the lower layers showed similar round spherules. But this time they had a very shiny surface that created strong glints and glares. "They appear shiny or polished," said Albert Yen, science team member, during a press conference on February 19. He said: "Data will hopefully help us figure out what's altering them." At the same press briefing, Dr. Squyres noted this as one of the main question: "Where did those spherules come from, dropped from above or grown in place?" Mission scientists reported on March 2 that they concluded a survey of the distribution of spherules in the bedrock. They found that they spread out evenly and randomly inside the rocks, and not in layers. This supports the notion that they grew in place, since if their origin was related to volcanic or meteoric episodes one would expect layers of spherules as a "record in time" for each event. This observation was added to the list of evidence for liquid water being present at this rock site, where it is thought the spherules formed.


Berry Bowl

On March 18 the results of the investigation of the area called "Berry Bowl" was announced. This site is a large rock with a small, bowl-shaped depression, in which a large number of spherules had accumulated. The
MIMOS II MIMOS II is the miniaturised Mössbauer spectrometer, developed by Dr. Göstar Klingelhöfer at the Johannes Gutenberg University in Mainz, Germany, that is used on the Mars Exploration Rovers '' Spirit'' and '' Opportunity'' for close-up investiga ...
Mössbauer spectrometer was used to analyze the depression and then the area of the rock right beside it. Any difference in the measured data was then attributed to the material in the spherules. A large difference in the obtained "spectra" was found. "This is the fingerprint of
hematite Hematite (), also spelled as haematite, is a common iron oxide compound with the formula, Fe2O3 and is widely found in rocks and soils. Hematite crystals belong to the rhombohedral lattice system which is designated the alpha polymorph of . ...
, so we conclude that the major iron-bearing mineral in the berries is hematite," said Daniel Rodionov, a rover science team collaborator from the
University of Mainz The Johannes Gutenberg University Mainz (german: Johannes Gutenberg-Universität Mainz) is a public research university in Mainz, Rhineland Palatinate, Germany, named after the printer Johannes Gutenberg since 1946. With approximately 32,000 stu ...
,
Germany Germany,, officially the Federal Republic of Germany, is a country in Central Europe. It is the second most populous country in Europe after Russia, and the most populous member state of the European Union. Germany is situated betwe ...
. This discovery seems to strengthen the conclusion, that spherules are concretions, grown in wet condition with dissolved iron.


Rocks and minerals

The rocks on the plains of Gusev are a type of
basalt Basalt (; ) is an aphanite, aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the planetary surface, surface of a terrestrial ...
. They contain the
mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. ( ...
s
olivine The mineral olivine () is a magnesium iron silicate with the chemical formula . It is a type of nesosilicate or orthosilicate. The primary component of the Earth's upper mantle, it is a common mineral in Earth's subsurface, but weathers quickl ...
,
pyroxene The pyroxenes (commonly abbreviated to ''Px'') are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula , where X represents calcium (Ca), sodium (Na), iron (Fe II) ...
,
plagioclase Plagioclase is a series of tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continuous solid solution series, more prope ...
, and magnetite, and they look like volcanic basalt as they are fine-grained with irregular holes (geologists would say they have vesicles and vugs). Much of the soil on the plains came from the breakdown of the local rocks. Fairly high levels of
nickel Nickel is a chemical element with symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel is a hard and ductile transition metal. Pure nickel is chemically reactive but large pieces are slow to ...
were found in some soils; probably from
meteorites A meteorite is a solid piece of debris from an object, such as a comet, asteroid, or meteoroid, that originates in outer space and survives its passage through the atmosphere to reach the surface of a planet or moon. When the original object en ...
. Analysis shows that the rocks have been slightly altered by tiny amounts of water. Outside coatings and cracks inside the rocks suggest water deposited minerals, maybe
bromine Bromine is a chemical element with the symbol Br and atomic number 35. It is the third-lightest element in group 17 of the periodic table (halogens) and is a volatile red-brown liquid at room temperature that evaporates readily to form a simila ...
compounds. All the rocks contain a fine coating of dust and one or more harder rinds of material. One type can be brushed off, while another needed to be ground off by the
Rock Abrasion Tool The Rock Abrasion Tool (RAT) is a grinding and brushing installation on NASA’s twin Mars Exploration Rovers, ''Spirit'' (MER-A) and ''Opportunity'' (MER-B), which landed on Mars in January 2004. It was designed, developed and continues to be op ...
(RAT). There are a variety of rocks in the
Columbia Hills (Mars) The Columbia Hills are a range of low hills inside Gusev crater on Mars. They were observed by the Mars Exploration Rover ''Spirit'' when it landed within the crater in 2004. They were promptly given an unofficial name by NASA since they were the ...
, some of which have been altered by water, but not by very much water. The dust in Gusev Crater is the same as dust all around the planet. All the dust was found to be magnetic. Moreover, Spirit found the
magnetism Magnetism is the class of physical attributes that are mediated by a magnetic field, which refers to the capacity to induce attractive and repulsive phenomena in other entities. Electric currents and the magnetic moments of elementary particles ...
was caused by the mineral
magnetite Magnetite is a mineral and one of the main iron ores, with the chemical formula Fe2+Fe3+2O4. It is one of the oxides of iron, and is ferrimagnetic; it is attracted to a magnet and can be magnetized to become a permanent magnet itself. With the ...
, especially magnetite that contained the element
titanium Titanium is a chemical element with the symbol Ti and atomic number 22. Found in nature only as an oxide, it can be reduced to produce a lustrous transition metal with a silver color, low density, and high strength, resistant to corrosion in ...
. One magnet was able to completely divert all dust hence all Martian dust is thought to be magnetic. The spectra of the dust was similar to spectra of bright, low thermal inertia regions like
Tharsis Tharsis () is a vast volcanic plateau centered near the equator in the western hemisphere of Mars. The region is home to the largest volcanoes in the Solar System, including the three enormous shield volcanoes Arsia Mons, Pavonis Mons, and Asc ...
and Arabia that have been detected by orbiting satellites. A thin layer of dust, maybe less than one millimeter thick covers all surfaces. Something in it contains a small amount of chemically bound water.


Plains

Observations of rocks on the plains show they contain the minerals pyroxene, olivine, plagioclase, and magnetite. These rocks can be classified in different ways. The amounts and types of minerals make the rocks primitive basalts—also called picritic basalts. The rocks are similar to ancient terrestrial rocks called basaltic
komatiites Komatiite () is a type of ultramafic mantle-derived volcanic rock defined as having crystallised from a lava of at least 18 wt% MgO. Komatiites have low silicon, potassium and aluminium, and high to extremely high magnesium content. Komatiite wa ...
. Rocks of the plains also resemble the basaltic
shergottite A Martian meteorite is a rock that formed on Mars, was ejected from the planet by an impact event, and traversed interplanetary space before landing on Earth as a meteorite. , 277 meteorites had been classified as Martian, less than half a percen ...
s, meteorites which came from Mars. One classification system compares the amount of alkali elements to the amount of silica on a graph; in this system, Gusev plains rocks lay near the junction of basalt,
picrobasalt Picrite basalt or picrobasalt is a variety of high-magnesium olivine basalt that is very rich in the mineral olivine. It is dark with yellow-green olivine phenocrysts (20-50%) and black to dark brown pyroxene, mostly augite. The olivine-rich p ...
, and tephrite. The Irvine-Barager classification calls them basalts. Plain's rocks have been very slightly altered, probably by thin films of water because they are softer and contain veins of light colored material that may be bromine compounds, as well as coatings or rinds. It is thought that small amounts of water may have gotten into cracks inducing mineralization processes. Coatings on the rocks may have occurred when rocks were buried and interacted with thin films of water and dust. One sign that they were altered was that it was easier to grind these rocks compared to the same types of rocks found on Earth. The first rock that Spirit studied was Adirondack. It turned out to be typical of the other rocks on the plains. Image:Spirit's First Color Photograph Mars.jpg, First color picture from Gusev crater. Rocks were found to be basalt. Everything was covered with a fine dust that Spirit determined was magnetic because of the mineral magnetite. Image:Rockgusev.jpg, Cross-sectional drawing of a typical rock from the plains of Gusev crater. Most rocks contain a coating of dust and one or more harder coatings. Veins of water-deposited minerals are visible, along with crystals of olvine. Veins may contain bromine salts.


Columbia Hills

Scientists found a variety of rock types in the Columbia Hills, and they placed them into six different categories. The six are: Clovis, Wishbone, Peace, Watchtower, Backstay, and Independence. They are named after a prominent rock in each group. Their chemical compositions, as measured by APXS, are significantly different from each other. Most importantly, all of the rocks in Columbia Hills show various degrees of alteration due to aqueous fluids. They are enriched in the elements phosphorus, sulfur, chlorine, and bromine—all of which can be carried around in water solutions. The Columbia Hills' rocks contain basaltic glass, along with varying amounts of olivine and
sulfate The sulfate or sulphate ion is a polyatomic anion with the empirical formula . Salts, acid derivatives, and peroxides of sulfate are widely used in industry. Sulfates occur widely in everyday life. Sulfates are salts of sulfuric acid and many ar ...
s. The olivine abundance varies inversely with the amount of sulfates. This is exactly what is expected because water destroys olivine but helps to produce sulfates. Acid fog is believed to have changed some of the Watchtower rocks. This was in a 200 meter long section of Cumberland Ridge and the Husband Hill summit. Certain places became less crystalline and more amorphous. Acidic water vapor from volcanoes dissolved some minerals forming a gel. When water evaporated a cement formed and produced small bumps. This type of process has been observed in the lab when basalt rocks are exposed to sulfuric and hydrochloric acids. The Clovis group is especially interesting because the Mössbauer spectrometer(MB) detected
goethite Goethite (, ) is a mineral of the diaspore group, consisting of iron(III) oxide-hydroxide, specifically the "α" polymorph. It is found in soil and other low-temperature environments such as sediment. Goethite has been well known since ancient t ...
in it. Goethite forms only in the presence of water, so its discovery is the first direct evidence of past water in the Columbia Hills's rocks. In addition, the MB spectra of rocks and outcrops displayed a strong decline in olivine presence, although the rocks probably once contained much olivine. Olivine is a marker for the lack of water because it easily decomposes in the presence of water. Sulfate was found, and it needs water to form. Wishstone contained a great deal of plagioclase, some olivine, and
anhydrate An acidic oxide is an oxide that either produces an acidic solution upon addition to water, or acts as an acceptor of hydroxide ions effectively functioning as a Lewis acid. Acidic oxides will typically have a low pKa and may be inorganic compoun ...
(a sulfate). Peace rocks showed
sulfur Sulfur (or sulphur in British English) is a chemical element with the symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with a chemical formula ...
and strong evidence for bound water, so hydrated sulfates are suspected. Watchtower class rocks lack olivine consequently they may have been altered by water. The Independence class showed some signs of clay (perhaps montmorillonite a member of the smectite group). Clays require fairly long term exposure to water to form. One type of soil, called Paso Robles, from the Columbia Hills, may be an evaporate deposit because it contains large amounts of sulfur,
phosphorus Phosphorus is a chemical element with the symbol P and atomic number 15. Elemental phosphorus exists in two major forms, white phosphorus and red phosphorus, but because it is highly reactive, phosphorus is never found as a free element on Ear ...
,
calcium Calcium is a chemical element with the symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar to ...
, and
iron Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in f ...
. Also, MB found that much of the iron in Paso Robles soil was of the oxidized, Fe+++ form, which would happen if water had been present. Towards the middle of the six-year mission (a mission that was supposed to last only 90 days), large amounts of pure
silica Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is one ...
were found in the soil. The silica could have come from the interaction of soil with acid vapors produced by volcanic activity in the presence of water or from water in a hot spring environment. After Spirit stopped working scientists studied old data from the Miniature Thermal Emission Spectrometer, or
Mini-TES The Miniature Thermal Emission Spectrometer (Mini-TES) is an infrared spectrometer used for detecting the composition of a material (typically rocks) from a distance. By making its measurements in the thermal infrared part of the electromagneti ...
and confirmed the presence of large amounts of
carbonate A carbonate is a salt of carbonic acid (H2CO3), characterized by the presence of the carbonate ion, a polyatomic ion with the formula . The word ''carbonate'' may also refer to a carbonate ester, an organic compound containing the carbonate g ...
-rich rocks, which means that regions of the planet may have once harbored water. The carbonates were discovered in an outcrop of rocks called "Comanche." In summary, Spirit found evidence of slight weathering on the plains of Gusev, but no evidence that a lake was there. However, in the Columbia Hills there was clear evidence for a moderate amount of aqueous weathering. The evidence included sulfates and the minerals goethite and carbonates which only form in the presence of water. It is believed that Gusev crater may have held a lake long ago, but it has since been covered by igneous materials. All the dust contains a magnetic component which was identified as magnetite with some titanium. Furthermore, the thin coating of dust that covers everything on Mars is the same in all parts of Mars.


First atmospheric temperature profile

During a press conference on March 11, 2004, mission scientists presented the first temperature profile of the martian atmosphere ever measured. It was obtained by combining data taken from the ''Opportunity'' Mini-TES infrared spectrometer with data from the TES instrument on board the Mars Global Surveyor (MGS) orbiter. This was necessary because ''Opportunity'' can only see up to 6 km high, and the MGS camera could not measure data all the way down to the ground. The data was acquired on February 15 (Sol 22) and is split into two data sets: Since the orbiter is in motion, some data was taken while it was approaching the ''Opportunity'' site, other when it was moving away. In the graph, these sets are marked "inbound" (black color) and "outbound" (red color). The dots represent Mini-TES (= rover) data and the straight lines are TES (=orbiter) data. Atmospheric science from the MER rovers has been published in a series of scientific papers in ''Science'' and ''Journal of Geophysical Research''


Astronomical observations

''Opportunity'' observed the eclipse, or transits of Phobos and transits of Deimos across the
Sun The Sun is the star at the center of the Solar System. It is a nearly perfect ball of hot plasma, heated to incandescence by nuclear fusion reactions in its core. The Sun radiates this energy mainly as light, ultraviolet, and infrared radi ...
,J. F. Bell II, ''et al.'', "Solar Eclipses of Phobos and Deimos Observed from the Surface of Mars," ''Nature, Vol. 436'', 55-57, July 2005 and photographed the
Earth Earth is the third planet from the Sun and the only astronomical object known to harbor life. While large volumes of water can be found throughout the Solar System, only Earth sustains liquid surface water. About 71% of Earth's surfa ...
, which appeared as a bright celestial object in the Martian sky. A
transit of Mercury from Mars frameless, upright=0.5 A transit of Mercury across the Sun as seen from Mars takes place when the planet Mercury passes directly between the Sun and Mars, obscuring a small part of the Sun's disc for an observer on Mars. During a transit, Mercury ...
took place on January 12, 2005 from about 14:45 UTC to 23:05 UTC, but camera resolution did not permit seeing Mercury's 6.1" angular diameter. Transits of
Deimos Deimos, a Greek word for ''dread'', may refer to: * Deimos (deity), one of the sons of Ares and Aphrodite in Greek mythology * Deimos (moon), the smaller and outermost of Mars' two natural satellites * Elecnor Deimos, a Spanish aerospace company * ...
across the Sun were seen, but at 2' angular diameter, Deimos is about 20 times larger than Mercury's 6.1" angular diameter.


See also

*
Aeolis quadrangle The Aeolis quadrangle is one of a series of 30 quadrangle maps of Mars used by the United States Geological Survey (USGS) Astrogeology Research Program. The Aeolis quadrangle is also referred to as MC-23 (Mars Chart-23). The Aeolis quadrangle co ...
*
Composition of Mars The composition of Mars covers the branch of the geology of Mars that describes the make-up of the planet Mars. Elemental composition Mars is differentiated, which—for a terrestrial planet—implies that it has a central core made up of me ...
*
Curiosity rover ''Curiosity'' is a car-sized Mars rover designed to explore the Gale crater on Mars as part of NASA's Mars Science Laboratory (MSL) mission. ''Curiosity'' was launched from Cape Canaveral (CCAFS) on November 26, 2011, at 15:02:00 UTC and lan ...
*
Exploration of Mars The planet Mars has been explored remotely by spacecraft. Probes sent from Earth, beginning in the late 20th century, have yielded a large increase in knowledge about the Martian system, focused primarily on understanding its geology and habit ...
*
Geology of Mars The geology of Mars is the scientific study of the surface, crust, and interior of the planet Mars. It emphasizes the composition, structure, history, and physical processes that shape the planet. It is analogous to the field of terrestrial geo ...
*
Groundwater on Mars During past ages, there was rain and snow on Mars; especially in the Noachian and early Hesperian epochs. Some moisture entered the ground and formed aquifers. That is, the water went into the ground, seeped down until it reached a formation tha ...
*
Margaritifer Sinus quadrangle The Margaritifer Sinus quadrangle is one of a series of 30 quadrangle maps of Mars used by the United States Geological Survey (USGS) Astrogeology Research Program. The Margaritifer Sinus quadrangle is also referred to as MC-19 (Mars Chart-19) ...
*
Mars Science Laboratory Mars Science Laboratory (MSL) is a robotic spacecraft, robotic space probe mission to Mars launched by NASA on November 26, 2011, which successfully landed ''Curiosity (rover), Curiosity'', a Mars rover, in Gale (crater), Gale Crater on August ...
*
Mars 2020 rover mission Mars 2020 is a Mars rover mission forming part of NASA's Mars Exploration Program that includes the rover ''Perseverance'', the small robotic, coaxial helicopter '' Ingenuity'', and associated delivery vehicles. Mars 2020 was launched from Ear ...
*
Opportunity Rover ''Opportunity'', also known as MER-B (Mars Exploration Rover – B) or MER-1, is a robotic rover that was active on Mars from 2004 until 2018. ''Opportunity'' was operational on Mars for sols (). Launched on July 7, 2003, as part of NASA's M ...
*
Space exploration Space exploration is the use of astronomy and space technology to explore outer space. While the exploration of space is carried out mainly by astronomers with telescopes, its physical exploration though is conducted both by robotic spacec ...
*
Unmanned space mission A robotic spacecraft is an uncrewed spacecraft, usually under telerobotic control. A robotic spacecraft designed to make scientific research measurements is often called a space probe. Many space missions are more suited to telerobotic rather t ...
s *
Water on Mars Almost all water on Mars today exists as ice, though it also exists in small quantities as vapor in the atmosphere. What was thought to be low-volume liquid brines in shallow Martian soil, also called recurrent slope lineae, may be grains of f ...


References


Further reading

* {{DEFAULTSORT:Scientific Information From The Mars Exploration Rover Mission Mars Exploration Rover mission