In
chemistry
Chemistry is the science, scientific study of the properties and behavior of matter. It is a natural science that covers the Chemical element, elements that make up matter to the chemical compound, compounds made of atoms, molecules and ions ...
, a corrosion inhibitor or anti-corrosive is a
chemical compound
A chemical compound is a chemical substance composed of many identical molecules (or molecular entities) containing atoms from more than one chemical element held together by chemical bonds. A molecule consisting of atoms of only one element ...
that, when added to a liquid or gas, decreases the
corrosion
Corrosion is a natural process that converts a refined metal into a more chemically stable oxide. It is the gradual deterioration of materials (usually a metal) by chemical or electrochemical reaction with their environment. Corrosion engine ...
rate of a material, typically a
metal
A metal (from Greek μέταλλον ''métallon'', "mine, quarry, metal") is a material that, when freshly prepared, polished, or fractured, shows a lustrous appearance, and conducts electricity and heat relatively well. Metals are typicall ...
or an
alloy
An alloy is a mixture of chemical elements of which at least one is a metal. Unlike chemical compounds with metallic bases, an alloy will retain all the properties of a metal in the resulting material, such as electrical conductivity, ductility, ...
, that comes into contact with the fluid. The effectiveness of a corrosion inhibitor depends on fluid composition, quantity of water, and
flow regime
A bedform is a geological feature that develops at the interface of fluid and a moveable bed, the result of bed material being moved by fluid flow. Examples include ripples and dunes on the bed of a river. Bedforms are often preserved in the roc ...
. Corrosion inhibitors are common in industry, and also found in over-the-counter products, typically in spray form in combination with a
lubricant
A lubricant (sometimes shortened to lube) is a substance that helps to reduce friction between surfaces in mutual contact, which ultimately reduces the heat generated when the surfaces move. It may also have the function of transmitting forces, t ...
and sometimes a
penetrating oil
Penetrating oil, also known as penetrating fluid, is very low-viscosity oil. It can be used to free rusted mechanical parts (such as nuts and bolts) so that they can be removed, because it can penetrate into the narrow space between the threads ...
. They may be added to water to prevent leaching of lead or copper from pipes.
A common mechanism for inhibiting corrosion involves formation of a coating, often a
passivation layer, which prevents access of the corrosive substance to the metal. Permanent treatments such as
chrome plating
Chrome plating (less commonly chromium plating) is a technique of electroplating a thin layer of chromium onto a metal object. A chrome-plated item is called ''chrome''. The chromed layer can be decorative, provide corrosion resistance, ease ...
are not generally considered inhibitors, however: corrosion inhibitors are additives to the fluids that surround the metal or related object.
Types
![CuBTApolymer](https://upload.wikimedia.org/wikipedia/commons/6/6e/CuBTApolymer.png)
The nature of the corrosive inhibitor depends on (i) the material being protected, which are most commonly metal objects, and (ii) on the corrosive agent(s) to be neutralized. The corrosive agents are generally oxygen, hydrogen sulfide, and
carbon dioxide
Carbon dioxide (chemical formula ) is a chemical compound made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in the gas state at room temperature. In the air, carbon dioxide is transpar ...
. Oxygen is generally removed by reductive inhibitors such as
amine
In chemistry, amines (, ) are compounds and functional groups that contain a basic nitrogen atom with a lone pair. Amines are formally derivatives of ammonia (), wherein one or more hydrogen atoms have been replaced by a substituen ...
s and
hydrazine
Hydrazine is an inorganic compound with the chemical formula . It is a simple pnictogen hydride, and is a colourless flammable liquid with an ammonia-like odour. Hydrazine is highly toxic unless handled in solution as, for example, hydrazine ...
s:
:
O2 + N2H4 -> 2 H2O + N2
In this example,
hydrazine
Hydrazine is an inorganic compound with the chemical formula . It is a simple pnictogen hydride, and is a colourless flammable liquid with an ammonia-like odour. Hydrazine is highly toxic unless handled in solution as, for example, hydrazine ...
converts oxygen, a common corrosive agent, to water, which is generally benign. Related inhibitors of oxygen corrosion are
hexamine
Hexamethylenetetramine, also known as methenamine, hexamine, or urotropin, is a heterocyclic organic compound with the formula (CH2)6N4. This white crystalline compound is highly soluble in water and polar organic solvents. It has a cage-like s ...
,
phenylenediamine
Phenylenediamine may refer to:
* ''o''-phenylenediamine or OPD, a chemical compound C6H4(NH2)2
* ''m''-phenylenediamine or MPD, a chemical compound C6H4(NH2)2
* ''p''-phenylenediamine or PPD, a chemical compound C6H4(NH2)2
* ''N,N''-dimethyl-''p'' ...
, and
dimethylethanolamine
Dimethylethanolamine (DMAE or DMEA) is an organic compound with the formula (CH3)2NCH2CH2OH. It is bifunctional, containing both a tertiary amine and primary alcohol functional groups. It is a colorless viscous liquid. It is used in skin care produ ...
, and their derivatives.
Antioxidant
Antioxidants are compounds that inhibit oxidation, a chemical reaction that can produce free radicals. This can lead to polymerization and other chain reactions. They are frequently added to industrial products, such as fuels and lubricant ...
s such as sulfite and
ascorbic acid
Vitamin C (also known as ascorbic acid and ascorbate) is a water-soluble vitamin found in citrus and other fruits and vegetables, also sold as a dietary supplement and as a topical 'serum' ingredient to treat melasma (dark pigment spots) an ...
are sometimes used. Some corrosion inhibitors form a
passivating coating on the surface by
chemisorption
Chemisorption is a kind of adsorption which involves a chemical reaction between the surface and the adsorbate. New chemical bonds are generated at the adsorbent surface. Examples include macroscopic phenomena that can be very obvious, like cor ...
.
Benzotriazole
Benzotriazole (BTA) is a heterocyclic compound with the chemical formula C6H5N3. Its five-membered ring contains three consecutive nitrogen atoms. This bicyclic compound may be viewed as fused rings of the aromatic compounds benzene and triazole. ...
is one such species used to protect
copper
Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkis ...
. For
lubrication
Lubrication is the process or technique of using a lubricant to reduce friction and wear and tear in a contact between two surfaces. The study of lubrication is a discipline in the field of tribology.
Lubrication mechanisms such as fluid-lubric ...
,
zinc dithiophosphate
Zinc dialkyldithiophosphates (often referred to as ZDDP) are a family of coordination compounds developed in the 1940s that feature zinc bound to the anion of a dialkyldithiophosphoric salt (e.g., ammonium diethyl dithiophosphate). These uncharg ...
s are common - they deposit sulfide on surfaces.
The suitability of any given chemical for a task in hand depends on many factors, including their
operating temperature
An operating temperature is the allowable temperature range of the local ambient environment at which an electrical or mechanical device operates. The device will operate effectively within a specified temperature range which varies based on the de ...
.
Illustrative applications
*Volatile amines are used in
boiler
A boiler is a closed vessel in which fluid (generally water) is heated. The fluid does not necessarily boil. The heated or vaporized fluid exits the boiler for use in various processes or heating applications, including water heating, central h ...
s to minimize the effects of acid. In some cases, the amines form a protective film on the steel surface and, at the same time, act as an anodic inhibitor. An inhibitor that acts both in a cathodic and anodic manner is termed a ''mixed inhibitor''.
*
Benzotriazole
Benzotriazole (BTA) is a heterocyclic compound with the chemical formula C6H5N3. Its five-membered ring contains three consecutive nitrogen atoms. This bicyclic compound may be viewed as fused rings of the aromatic compounds benzene and triazole. ...
inhibits the corrosion and staining of copper surfaces.
*Corrosion inhibitors are often added to
paint
Paint is any pigmented liquid, liquefiable, or solid mastic composition that, after application to a substrate in a thin layer, converts to a solid film. It is most commonly used to protect, color, or provide texture. Paint can be made in many ...
s. A
pigment
A pigment is a colored material that is completely or nearly insoluble in water. In contrast, dyes are typically soluble, at least at some stage in their use. Generally dyes are often organic compounds whereas pigments are often inorganic compo ...
with anticorrosive properties is
zinc phosphate
Zinc phosphate is an inorganic compound with the formula Zn3( PO4)2. This white powder is widely used as a corrosion resistant coating on metal surfaces either as part of an electroplating process or applied as a primer pigment (see also red lead ...
. Compounds derived from
tannic acid
Tannic acid is a specific form of tannin, a type of polyphenol. Its weak acidity ( pKa around 6) is due to the numerous phenol groups in the structure. The chemical formula for commercial tannic acid is often given as C76H52O46, which correspon ...
or zinc salts of organonitrogens (e.g. Alcophor 827) can be used together with anticorrosive pigments. Other corrosion inhibitors are Anticor 70, Albaex, Ferrophos, and Molywhite MZAP.
*
Antiseptic
An antiseptic (from Greek ἀντί ''anti'', "against" and σηπτικός ''sēptikos'', "putrefactive") is an antimicrobial substance or compound that is applied to living tissue/skin to reduce the possibility of infection, sepsis, or putre ...
s are used to counter
microbial corrosion Microbial corrosion, also called microbiologically influenced corrosion (MIC), microbially induced corrosion (MIC) or biocorrosion, is "corrosion affected by the presence or activity (or both) of microorganisms in biofilms on the surface of the corr ...
.
Benzalkonium chloride
Benzalkonium chloride (BZK, BKC, BAK, BAC), also known as alkyldimethylbenzylammonium chloride (ADBAC) and by the trade name Zephiran, is a type of cationic surfactant. It is an organic salt classified as a quaternary ammonium compound. ADBACs hav ...
is commonly used in
oil field
A petroleum reservoir or oil and gas reservoir is a subsurface accumulation of hydrocarbons contained in porous or fractured rock formations.
Such reservoirs form when kerogen (ancient plant matter) is created in surrounding rock by the presence ...
industry.
*In oil refineries,
hydrogen sulfide
Hydrogen sulfide is a chemical compound with the formula . It is a colorless chalcogen-hydride gas, and is poisonous, corrosive, and flammable, with trace amounts in ambient atmosphere having a characteristic foul odor of rotten eggs. The unde ...
can corrode steels so it is removed often using air and amines by conversion to
polysulfide
Polysulfides are a class of chemical compounds containing chains of sulfur atoms. There are two main classes of polysulfides: inorganic and organic. Among the inorganic polysulfides, there are ones which contain anions, which have the general formu ...
s.
*
Orthophosphate
A phosphoric acid, in the general sense, is a phosphorus oxoacid in which each phosphorus (P) atom is in the oxidation state +5, and is bonded to four oxygen (O) atoms, one of them through a double bond, arranged as the corners of a tetrahedron. ...
s may be added in
water treatment
Water treatment is any process that improves the Water quality, quality of water to make it appropriate for a specific end-use. The end use may be drinking water, drinking, industrial water supply, irrigation, river flow maintenance, water recrea ...
systems to prevent leaching of lead and copper from pipes.
Fuels industry
Corrosion inhibitors are commonly added to
coolant
A coolant is a substance, typically liquid, that is used to reduce or regulate the temperature of a system. An ideal coolant has high thermal capacity, low viscosity, is low-cost, non-toxic, chemically inert and neither causes nor promotes corrosio ...
s, fuels,
hydraulic fluid
A hydraulic fluid or hydraulic liquid is the medium by which power is transferred in hydraulic machinery. Common hydraulic fluids are based on mineral oil or water. Examples of equipment that might use hydraulic fluids are excavators and backhoe ...
s,
boiler water
Boiler water is liquid water within a boiler, or in associated piping, pumps and other equipment, that is intended for evaporation into steam. The term may also be applied to raw water intended for use in boilers, treated boiler feedwater, steam ...
,
engine oil
Motor oil, engine oil, or engine lubricant is any one of various substances used for the lubrication of internal combustion engines. They typically consist of base oils enhanced with various additives, particularly antiwear additives, deter ...
, and many other fluids used in industry. For fuels, various corrosion inhibitors can be used. Some components include
zinc dithiophosphate
Zinc dialkyldithiophosphates (often referred to as ZDDP) are a family of coordination compounds developed in the 1940s that feature zinc bound to the anion of a dialkyldithiophosphoric salt (e.g., ammonium diethyl dithiophosphate). These uncharg ...
s.
Octel-Starreon Refinery Fuel Additives Corrosion Inhibitors for hydrocarbon fuels - corrosion inhibitor and corrosion protection to fuel distribution system
/ref>
* DCI-4A, widely used in commercial and military jet fuel
Jet fuel or aviation turbine fuel (ATF, also abbreviated avtur) is a type of aviation fuel designed for use in aircraft powered by gas-turbine engines. It is colorless to straw-colored in appearance. The most commonly used fuels for commercial a ...
s, acts also as a lubricity
Lubricity is the measure of the reduction in friction and/or wear by a lubricant. The study of lubrication and wear mechanisms is called tribology.
Measurement of lubricity
The lubricity of a substance is not a material property, and cannot be me ...
additive. Can be also used for gasoline
Gasoline (; ) or petrol (; ) (see ) is a transparent, petroleum-derived flammable liquid that is used primarily as a fuel in most spark-ignited internal combustion engines (also known as petrol engines). It consists mostly of organic co ...
s and other distillate
Distillation, or classical distillation, is the process of separating the components or substances from a liquid mixture by using selective boiling and condensation, usually inside an apparatus known as a still. Dry distillation is the heat ...
fuels.
* DCI-6A, for motor gasoline and distillate fuels, and for U.S. military
The United States Armed Forces are the military forces of the United States. The armed forces consists of six service branches: the Army, Marine Corps, Navy, Air Force, Space Force, and Coast Guard. The president of the United States is the ...
fuels (JP-4
JP-4, or JP4 (for "Jet Propellant") was a jet fuel, specified in 1951 by the U.S. government (MIL-DTL-5624). Its NATO code is F-40. It is also known as avtag.
Usage
JP-4 was a 50-50 kerosene-gasoline blend. It had a lower flash point than JP-1, b ...
, JP-5
Jet fuel or aviation turbine fuel (ATF, also abbreviated avtur) is a type of aviation fuel designed for use in aircraft powered by gas-turbine engines. It is colorless to straw-colored in appearance. The most commonly used fuels for commercial av ...
, JP-8
JP-8, or JP8 (for "Jet Propellant 8") is a jet fuel, specified and used widely by the US military. It is specified by MIL-DTL-83133 and British Defence Standard 91-87, and similar to commercial aviation's Jet A-1, but with the addition of corrosio ...
)
* DCI-11, for alcohols and gasolines containing oxygenate
Oxygenated chemical compounds contain oxygen as a part of their chemical structure. The term usually refers to oxygenated chemical compounds added to fuels. Oxygenates are usually employed as gasoline additives to reduce carbon monoxide and soot ...
s
* DCI-28, for very low-pH alcohols and gasolines containing oxygenates
* DCI-30, for gasoline and distillate fuels, excellent for pipeline transfers and storage, caustic-resistant
* DMA-4 (solution of alkylaminophosphate in kerosene), for petroleum distillates
See also
Useful websites
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References
External links
Corrosion control informations and documents
* ttps://web.archive.org/web/20090703235638/http://electrochem.cwru.edu/encycl/art-i01-inhibitors.htm Corrosion inhibition Norman Hackerman,(August, 2006), Electrochemistry Encyclopedia
{{Authority control
Corrosion prevention
Lubricants
Oil additives
Process chemicals
Conservation and restoration of cultural heritage
Concrete admixtures