Robert Garrels
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Robert Minard Garrels (August 24, 1916 – March 8, 1988) was an American
geochemist Geochemistry is the science that uses the tools and principles of chemistry to explain the mechanisms behind major geological systems such as the Earth's crust and its oceans. The realm of geochemistry extends beyond the Earth, encompassing the ...
. Garrels applied experimental
physical chemistry Physical chemistry is the study of macroscopic and microscopic phenomena in chemical systems in terms of the principles, practices, and concepts of physics such as motion, energy, force, time, thermodynamics, quantum chemistry, statistical mecha ...
data and techniques to
geology Geology () is a branch of natural science concerned with Earth and other astronomical objects, the features or rocks of which it is composed, and the processes by which they change over time. Modern geology significantly overlaps all other Ear ...
and
geochemistry Geochemistry is the science that uses the tools and principles of chemistry to explain the mechanisms behind major geological systems such as the Earth's crust and its oceans. The realm of geochemistry extends beyond the Earth, encompassing the e ...
problems. The book ''Solutions, Minerals, and Equilibria'' co-authored in 1965 by Garrels and Charles L. Christ revolutionized aqueous geochemistry. Garrels earned a bachelor's degree in geology from The
University of Michigan , mottoeng = "Arts, Knowledge, Truth" , former_names = Catholepistemiad, or University of Michigania (1817–1821) , budget = $10.3 billion (2021) , endowment = $17 billion (2021)As o ...
in 1937. He went on to earn an M.S. degree from Northwestern in 1939, his thesis work was on iron ores of
Newfoundland Newfoundland and Labrador (; french: Terre-Neuve-et-Labrador; frequently abbreviated as NL) is the easternmost province of Canada, in the country's Atlantic region. The province comprises the island of Newfoundland and the continental region ...
in 1938. His Ph.D was awarded in 1941 based on lab studies of complex formation between
lead Lead is a chemical element with the symbol Pb (from the Latin ) and atomic number 82. It is a heavy metal that is denser than most common materials. Lead is soft and malleable, and also has a relatively low melting point. When freshly cu ...
and
chloride The chloride ion is the anion (negatively charged ion) Cl−. It is formed when the element chlorine (a halogen) gains an electron or when a compound such as hydrogen chloride is dissolved in water or other polar solvents. Chloride salts ...
ion An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by conven ...
s in
aqueous solution An aqueous solution is a solution in which the solvent is water. It is mostly shown in chemical equations by appending (aq) to the relevant chemical formula. For example, a solution of table salt, or sodium chloride (NaCl), in water would be re ...
.


Life and career

Garrels worked for the
U.S. Geological Survey The United States Geological Survey (USGS), formerly simply known as the Geological Survey, is a scientific agency of the United States government. The scientists of the USGS study the landscape of the United States, its natural resources, and ...
during
World War II World War II or the Second World War, often abbreviated as WWII or WW2, was a world war that lasted from 1939 to 1945. It involved the vast majority of the world's countries—including all of the great powers—forming two opposin ...
and returned to teach at Northwestern until 1952. Also in 1952 he published a technical paper, "Origin and Classification of Chemical Sediments in Terms of pH and Oxidation-Reduction Potentials." with
W. C. Krumbein William Christian Krumbein (January 28, 1902 – August 18, 1979) was a notable geologist, after whom the Krumbein Medal of the International Association for Mathematical Geology (IAMG) was named. This medal was established at the 25th Internati ...
, which was to become a classic study of sedimentary rocks from a physical chemistry viewpoint. This and following works revolutionized sedimentary and aqueous geochemistry. He joined the
USGS The United States Geological Survey (USGS), formerly simply known as the Geological Survey, is a scientific agency of the United States government. The scientists of the USGS study the landscape of the United States, its natural resources, a ...
again for a time, but returned to academia at
Harvard Harvard University is a private Ivy League research university in Cambridge, Massachusetts. Founded in 1636 as Harvard College and named for its first benefactor, the Puritan clergyman John Harvard, it is the oldest institution of higher le ...
in 1955. He became full professor in 1957 and later department chair. His work and the lab he supervised at Harvard produced many classic works including the ''Solutions, Minerals, and Equilibria'' text. Here between 1960 and 1962 he along with his colleagues published the classic studies: *"Oxidation of Pyrite by Iron Sulfate Solutions" *"Stability of Some Carbonates at 25°C and One Atmosphere Total Pressure" *"Control of Carbonate Solubility by Carbonate Complexes" *"A Chemical Model for Sea Water at 25°C and One Atmosphere Total Pressure" He returned to Northwestern in 1965 and conducted influential studies on the
silicate In chemistry, a silicate is any member of a family of polyatomic anions consisting of silicon and oxygen, usually with the general formula , where . The family includes orthosilicate (), metasilicate (), and pyrosilicate (, ). The name is al ...
and
carbonate A carbonate is a salt of carbonic acid (H2CO3), characterized by the presence of the carbonate ion, a polyatomic ion with the formula . The word ''carbonate'' may also refer to a carbonate ester, an organic compound containing the carbonate g ...
buffering of seawaters, the genesis of groundwaters and the theoretical treatment of irreversible reactions in
geochemical processes Geochemistry is the science that uses the tools and principles of chemistry to explain the mechanisms behind major geological systems such as the Earth's crust and its oceans. The realm of geochemistry extends beyond the Earth, encompassing the ...
. In 1969 he moved to the
Scripps Institution of Oceanography The Scripps Institution of Oceanography (sometimes referred to as SIO, Scripps Oceanography, or Scripps) in San Diego, California, US founded in 1903, is one of the oldest and largest centers for oceanography, ocean and Earth science research ...
and later to the University of Hawaii. During this time he worked on thermodynamic properties of silicate minerals and also published "Cycling of Carbon, Sulfur, and Oxygen through Geologic Time" with Ed Perry in 1974. In 1974 he returned to Northwestern and published important studies on the sulfur and carbon isotopic compositions of
Phanerozoic The Phanerozoic Eon is the current geologic eon in the geologic time scale, and the one during which abundant animal and plant life has existed. It covers 538.8 million years to the present, and it began with the Cambrian Period, when anima ...
rocks with Abraham Lerman and
Fred MacKenzie Frederick Mackenzie (14 February 1880 – 26 March 1938) was a Scottish golfer of the early 20th century. He had a successful amateur career, winning the Dundee Evening Telegraph Cup three times between 1899 and 1903. He then had a brief spell ...
. Garrels had broad interests beyond geology. He enjoyed travel and wine. He was athletic, holding the world high jump record for men over 57 years of age. He was a poet-scientist: ''Cycle of P''
by Robert M. Garrels I put some P into the sea
the biomass did swell But settling down soon overcame
and P went down toward Hell From Purgatory soon released
it moved up to the land To make a perfect rose for thee
to carry in thy hand But roses wilt and die you know
then P falls on the ground Gobbled up as ferric P
a nasty brown compound The world is moral still you know
and Nature's wheels do grind Put ferric P into the sea
and a rose someday you'll find He moved to the
University of South Florida The University of South Florida (USF) is a public research university with its main campus located in Tampa, Florida, and other campuses in St. Petersburg and Sarasota. It is one of 12 members of the State University System of Florida. USF is ...
at St. Petersburg in 1979, holding the St. Petersburg Progress Chair in Marine Science, and spent summers at the Université Louis Pasteur, Strasbourg; the Université Libre, Brussels; and
Yale Yale University is a private research university in New Haven, Connecticut. Established in 1701 as the Collegiate School, it is the third-oldest institution of higher education in the United States and among the most prestigious in the wor ...
, where he held an adjunct professorship. During this time he published "The Carbonate–Silicate Geochemical Cycle and Its Effect on Atmospheric
Carbon Dioxide Carbon dioxide (chemical formula ) is a chemical compound made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in the gas state at room temperature. In the air, carbon dioxide is transpar ...
over the Past 100 Million Years" in 1983. This concerned the BLAG model, named for the collaborators including Tony Lasaga and Robert Berner. He continued to be active while fighting cancer, publishing "Modeling Atmospheric O2 in the Global Sedimentary Redox Cycle" (1986) and "A Model for the Deposition of the Microbanded Precambrian Iron Formations." (1987)


Awards and honors

* 1961 - Election to the
National Academy of Sciences The National Academy of Sciences (NAS) is a United States nonprofit, non-governmental organization. NAS is part of the National Academies of Sciences, Engineering, and Medicine, along with the National Academy of Engineering (NAE) and the Nati ...
* 1962 - President of the Geochemical Society * 1966 - Received the
Arthur L. Day Medal The Arthur L. Day Medal is a prize awarded by the Geological Society of America, established in 1948 by Arthur Louis Day for "outstanding distinction in contributing to geologic knowledge through the application of physics and chemistry to the so ...
of the
Geological Society of America The Geological Society of America (GSA) is a nonprofit organization dedicated to the advancement of the geosciences. History The society was founded in Ithaca, New York, in 1888 by Alexander Winchell, John J. Stevenson, Charles H. Hitchco ...
* 1969 - Honorary doctorate from the Université Libre de Bruxelles * 1973 - Received the
V. M. Goldschmidt Award The V. M. Goldschmidt Award is an award given by the Geochemical Society at the V. M. Goldschmidt Conference for achievements in the fields of geochemistry and cosmochemistry. The award in honor of Victor Moritz Goldschmidt, a pioneer in both tho ...
of the Geochemical Society * 1976 - Honorary doctorate from the Université Louis Pasteur, Strasbourg, France * 1978 - Received the Penrose Medal of the Geological Society of America * 1980 - Honorary doctorate from the University of Michigan, Ann Arbor, Michigan, USA * 1981 - Received the Wollaston Medal of the Geological Society of London * 1981 - Received the
Roebling Medal The Roebling Medal is the highest award of the Mineralogical Society of America for scientific eminence as represented primarily by scientific publication of outstanding original research in mineralogy. The award is named for Colonel Washington A ...
of the
Mineralogical Society of America The Mineralogical Society of America (MSA) is a scientific membership organization. MSA was founded in 1919 for the advancement of mineralogy, crystallography, geochemistry, and petrology, and promotion of their uses in other sciences, industry, ...


Selected publications

*''A Textbook of Geology,'' Harper's Geoscience Series (1951) *
Behavior of Colorado Plateau uranium minerals during oxidation
' U.S. Geological Survey Trace Elements Investigations Report No. 588 (1956) *''Mineral Equilibria at Low Temperature and Pressure,'' Harper (1960) *''Solutions, Minerals, and Equilibria'' with Charles L. Christ (1965) (2nd ed. Freeman Cooper Co, 1982 and revised ed 1990) (1990 ed.) *''Evolution of Sedimentary Rocks'' with Fred Mackenzie; Norton, (1971) () *''Water the Web of Life'' with Cynthia Garrels; Norton (1972) () *''Chemical cycles and the global environment: Assessing human influences'' with Cynthia Garrels and F. T. Mackenzie W.; Kaufmann (1975) () *''Thermodynamic Values at Low Temperature for Natural Inorganic Materials: An Uncritical Summary,'' with Terri L. Woods; Oxford University Press (1986)


References


External links



* ttp://findingaids.library.northwestern.edu/catalog/inu-ead-nua-archon-565 Robert M. Garrels Papers, 1938-1992, Northwestern University Archive, Evanston, Illinois {{DEFAULTSORT:Garrels, Robert 1916 births 1988 deaths Members of the United States National Academy of Sciences American geochemists Wollaston Medal winners University of Michigan College of Literature, Science, and the Arts alumni Northwestern University alumni Harvard University faculty University of Hawaiʻi faculty Penrose Medal winners United States Geological Survey personnel American physical chemists Presidents of the Geochemical Society Recipients of the V. M. Goldschmidt Award