![Cedar of Lebanon cone](https://upload.wikimedia.org/wikipedia/commons/c/c4/Cedar_of_Lebanon_cone.JPG)
In
polymer chemistry
Polymer chemistry is a sub-discipline of chemistry that focuses on the structures of chemicals, chemical synthesis, and chemical and physical properties of polymers and macromolecules. The principles and methods used within polymer chemistry are ...
and
materials science, a resin is a
solid
Solid is one of the State of matter#Four fundamental states, four fundamental states of matter (the others being liquid, gas, and Plasma (physics), plasma). The molecules in a solid are closely packed together and contain the least amount o ...
or highly
viscous
The viscosity of a fluid is a measure of its resistance to deformation at a given rate. For liquids, it corresponds to the informal concept of "thickness": for example, syrup has a higher viscosity than water.
Viscosity quantifies the inter ...
substance of plant or synthetic origin that is typically convertible into
polymer
A polymer (; Greek '' poly-'', "many" + ''-mer'', "part")
is a substance or material consisting of very large molecules called macromolecules, composed of many repeating subunits. Due to their broad spectrum of properties, both synthetic a ...
s. Resins are usually mixtures of
organic compound
In chemistry, organic compounds are generally any chemical compounds that contain carbon-hydrogen or carbon-carbon bonds. Due to carbon's ability to catenate (form chains with other carbon atoms), millions of organic compounds are known. The ...
s. This article focuses on naturally occurring resins.
Plants secrete resins for their protective benefits in response to injury. The resin protects the plant from insects and pathogens. Resins confound a wide range of herbivores, insects, and pathogens, while the
volatile phenolic compounds may attract benefactors such as
parasitoid
In evolutionary ecology, a parasitoid is an organism that lives in close association with its host (biology), host at the host's expense, eventually resulting in the death of the host. Parasitoidism is one of six major evolutionarily stable str ...
s or predators of the herbivores that attack the plant.
Composition
Most plant resins are composed of
terpenes
Terpenes () are a class of natural products consisting of compounds with the formula (C5H8)n for n > 1. Comprising more than 30,000 compounds, these unsaturated hydrocarbons are produced predominantly by plants, particularly conifers. Terpenes ar ...
. Specific components are
alpha-pinene
α-Pinene is an organic compound of the terpene class, one of two isomers of pinene. It is an alkene and it contains a reactive four-membered ring. It is found in the oils of many species of many coniferous trees, notably the pine. It is also ...
,
beta-pinene,
delta-3 carene, and
sabinene
Sabinene is a natural bicyclic monoterpene with the molecular formula C10H16. It is isolated from the essential oils of a variety of plants including Marjoram, holm oak (''Quercus ilex'') and Norway spruce (''Picea abies''). It has a strained ...
, the monocyclic terpenes
limonene
Limonene is a colorless liquid aliphatic hydrocarbon classified as a cyclic monoterpene, and is the major component in the oil of citrus fruit peels. The -isomer, occurring more commonly in nature as the fragrance of oranges, is a flavoring ag ...
and
terpinolene
The terpinenes are a group of isomeric hydrocarbons that are classified as monoterpenes. They each have the same molecular formula and carbon framework, but they differ in the position of carbon-carbon double bonds. α-Terpinene has been isolate ...
, and smaller amounts of the tricyclic
sesquiterpene
Sesquiterpenes are a class of terpenes that consist of three isoprene units and often have the molecular formula C15H24. Like monoterpenes, sesquiterpenes may be cyclic or contain rings, including many unique combinations. Biochemical modificatio ...
s,
longifolene
Longifolene is the common (or trivial) chemical name of a naturally occurring, oily liquid hydrocarbon found primarily in the high-boiling fraction of certain pine resins. The name is derived from that of a pine species from which the compound wa ...
,
caryophyllene
Caryophyllene (), more formally (−)-β-caryophyllene, (BCP), is a natural bicyclic sesquiterpene that is a constituent of many essential oils, especially clove oil, the oil from the stems and flowers of '' Syzygium aromaticum'' (cloves), the ess ...
, and
delta-cadinene. Some resins also contain a high proportion of
resin acid Resin acid refers to mixtures of several related carboxylic acids, primarily abietic acid, found in tree resins. Nearly all resin acids have the same basic skeleton: three fused rings having the empirical formula C19H29COOH. Resin acids are tacky, ...
s.
Rosin
Rosin (), also called colophony or Greek pitch ( la, links=no, pix graeca), is a solid form of resin obtained from pines and some other plants, mostly conifers, produced by heating fresh liquid resin to vaporize the volatile liquid terpene comp ...
s on the other hand are less volatile and consist of diterpenes among other compounds.
Examples
Examples of plant resins include
amber
Amber is fossilized tree resin that has been appreciated for its color and natural beauty since Neolithic times. Much valued from antiquity to the present as a gemstone, amber is made into a variety of decorative objects."Amber" (2004). In Ma ...
,
Balm of Gilead
Balm of Gilead was a rare perfume used medicinally, that was mentioned in the Hebrew Bible, and named for the region of Gilead, where it was produced. The expression stems from William Tyndale's language in the King James Bible of 1611, and has c ...
,
balsam
Balsam is the resinous exudate (or sap) which forms on certain kinds of trees and shrubs. Balsam (from Latin balsamum "gum of the balsam tree", ultimately from Semitic, Aramaic ''busma'', Arabic ''balsam'' and Hebrew ''basam'', "spice", "perfume ...
,
Canada balsam,
copal
Copal is tree resin, particularly the aromatic resins from the copal tree ''Protium copal'' (Burseraceae) used by the cultures of pre-Columbian Mesoamerica as ceremonially burned incense and for other purposes. More generally, copal includes re ...
from trees of ''
Protium copal'' and ''
Hymenaea courbaril
''Hymenaea courbaril'', the courbaril or West Indian locust, is a tree common in the Caribbean, Central America, and South America. It is a hardwood that is used for furniture, flooring, and decoration. Its hard fruit pods have edible dry pulp ...
'',
dammar gum
Dammar, also called dammar gum, or damar gum, is a resin obtained from the tree family Dipterocarpaceae in India and Southeast Asia, principally those of the genera ''Shorea'' or ''Hopea'' (synonym ''Balanocarpus''). The resin of some species of ...
from trees of the family
Dipterocarpaceae
Dipterocarpaceae is a family of 16 genera and about 695 known species of mainly tropical lowland rainforest trees. The family name, from the type genus ''Dipterocarpus'', is derived from Greek (''di'' = two, ''pteron'' = wing and ''karpos'' = fru ...
,
dragon's blood
Dragon's blood is a bright red resin which is obtained from different species of a number of distinct plant genera: ''Calamus'' spp. (previously ''Daemonorops'') also including ''Calamus rotang'', '' Croton'', '' Dracaena'' and ''Pterocarpus''. ...
from the dragon trees (''
Dracaena'' species),
elemi
''Canarium luzonicum'', commonly known as elemi, is a tree native to the Philippines. The oleoresin harvested from it is also known as elemi.
Synonyms
* ''Canarium carapifolium'' G.Perkins
* ''Canarium oliganthum'' Merr.
* ''Canarium polyanthu ...
,
frankincense
Frankincense (also known as olibanum) is an aromatic resin used in incense and perfumes, obtained from trees of the genus ''Boswellia'' in the family Burseraceae. The word is from Old French ('high-quality incense').
There are several species o ...
from ''
Boswellia sacra
''Boswellia sacra'' (commonly known as frankincense or olibanum-tree) is a tree in the Burseraceae family. It is the primary tree in the genus ''Boswellia'' from which frankincense, a resinous dried sap, is harvested. It is native to the Arabian ...
'',
galbanum
Galbanum is an aromatic gum resin and a product of certain umbelliferous Persian plant species in the genus ''Ferula'', chiefly ''Ferula gummosa'' (synonym ''F. galbaniflua'') and ''Ferula rubricaulis''. Galbanum-yielding plants grow plentifull ...
from ''
Ferula gummosa
''Ferula gummosa'' is a perennial herb of ''Ferula'' in the family Apiaceae. It is native to Iran and Turkmenistan. Its gum resin is called galbanum
Galbanum is an aromatic gum resin and a product of certain umbelliferous Persian plant specie ...
'',
gum guaiacum from the
lignum vitae
Lignum vitae () is a wood, also called guayacan or guaiacum, and in parts of Europe known as Pockholz or pokhout, from trees of the genus ''Guaiacum''. The trees are indigenous to the Caribbean and the northern coast of South America (e.g: Col ...
trees of the genus ''
Guaiacum
''Guaiacum'' (''OED'' 2nd edition, 1989.[Entry "guaiacum"](_blank)
in
kauri gum
Kauri gum is resin from kauri trees (''Agathis australis''), which historically had several important industrial uses. It can also be used to make crafts such as jewellery. Kauri forests once covered much of the North Island of New Zealand, be ...
from trees of ''
Agathis australis
''Agathis australis'', commonly known by its Māori name kauri (), is a coniferous tree in the family ''Araucariaceae'', found north of 38°S in the northern regions of New Zealand's North Island.
It is the largest (by volume) but not t ...
'',
hashish
Hashish ( ar, حشيش, ()), also known as hash, "dry herb, hay" is a drug made by compressing and processing parts of the cannabis plant, typically focusing on flowering buds (female flowers) containing the most trichomes. European Monitorin ...
(Cannabis resin) from ''
Cannabis indica
''Cannabis indica'' is an annual plant species in the family Cannabaceae which produces large amounts of tetrahydrocannabinol (THC) and is cultivated for purposes including hashish in India. The high concentrations of THC provide euphoric effect ...
'',
labdanum
Labdanum, also called ladanum, ladan, or ladanon, is a sticky brown resin obtained from the shrubs ''Cistus ladanifer'' (western Mediterranean) and ''Cistus creticus'' (eastern Mediterranean), species of rockrose. It was historically used in her ...
from mediterranean species of ''
Cistus
''Cistus'' (from the Greek ''kistos'') is a genus of flowering plants in the rockrose family Cistaceae, containing about 20 species (Ellul ''et al.'' 2002). They are perennial shrubs found on dry or rocky soils throughout the Mediterranean region ...
'',
mastic (plant resin)
Mastic ( el, Μαστίχα) is a resin obtained from the mastic tree (''Pistacia lentiscus''). It is also known as tears of Chios, being traditionally produced on the island Chios, and, like other natural resins, is produced in "tears" or dropl ...
from the mastic tree ''
Pistacia lentiscus
''Pistacia lentiscus'' (also lentisk or mastic) is a dioecious evergreen shrub or small tree of the genus ''Pistacia'' native to the Mediterranean Basin. It grows up to tall and is cultivated for its aromatic resin, mainly on the Greek islan ...
'',
myrrh
Myrrh (; from Semitic, but see '' § Etymology'') is a gum-resin extracted from a number of small, thorny tree species of the genus ''Commiphora''. Myrrh resin has been used throughout history as a perfume, incense and medicine. Myrrh mi ...
from shrubs of ''
Commiphora
The genus of the myrrhs, ''Commiphora'', is the most species-rich genus of flowering plants in the frankincense and myrrh family, Burseraceae. The genus contains approximately 190 species of shrubs and trees, which are distributed throughout th ...
'',
sandarac
Sandarac (or sandarach) is a resin obtained from the small cypress-like tree '' Tetraclinis articulata''. The tree is native to the northwest of Africa with a notable presence in the Southern Morocco part of the Atlas mountains. The resin exudes ...
resin from ''
Tetraclinis articulata
''Tetraclinis'' (also called arar, araar or Sictus tree) is a genus of evergreen coniferous trees in the cypress family Cupressaceae, containing only one species, ''Tetraclinis articulata'', also known as Thuja articulata,[styrax
''Styrax'' (common names storax or snowbell) is a genus of about 130 species of large shrubs or small trees in the family Styracaceae, mostly native to warm temperate to tropical regions of the Northern Hemisphere, with the majority in eastern ...]
(a
Benzoin resin
Benzoin or benjamin (corrupted pronunciation) is a balsamic resin obtained from the bark of several species of trees in the genus ''Styrax''. It is used in perfumes and some kinds of incense and as a flavoring and medicine (see tincture of benz ...
from various ''
Styrax
''Styrax'' (common names storax or snowbell) is a genus of about 130 species of large shrubs or small trees in the family Styracaceae, mostly native to warm temperate to tropical regions of the Northern Hemisphere, with the majority in eastern ...
'' species) and
spinifex resin
Spinifex resin is a gum coating of some species of spinifex grasses. This sticky resin was traditionally used as an adhesive in tool making by Aboriginal Australians. Many species of spinifex are extremely resinous, to the extent that resin may ...
from Australian grasses.
Amber
Amber is fossilized tree resin that has been appreciated for its color and natural beauty since Neolithic times. Much valued from antiquity to the present as a gemstone, amber is made into a variety of decorative objects."Amber" (2004). In Ma ...
is
fossil
A fossil (from Classical Latin , ) is any preserved remains, impression, or trace of any once-living thing from a past geological age. Examples include bones, shells, exoskeletons, stone imprints of animals or microbes, objects preserved ...
resin (also called resinite) from coniferous and other tree species. Copal, kauri gum, dammar and other resins may also be found as subfossil deposits. Subfossil copal can be distinguished from genuine fossil amber because it becomes tacky when a drop of a solvent such as
acetone
Acetone (2-propanone or dimethyl ketone), is an organic compound with the formula . It is the simplest and smallest ketone (). It is a colorless, highly volatile and flammable liquid with a characteristic pungent odour.
Acetone is miscib ...
or
chloroform
Chloroform, or trichloromethane, is an organic compound with chemical formula, formula Carbon, CHydrogen, HChlorine, Cl3 and a common organic solvent. It is a colorless, strong-smelling, dense liquid produced on a large scale as a precursor to ...
is placed on it.
African
copal
Copal is tree resin, particularly the aromatic resins from the copal tree ''Protium copal'' (Burseraceae) used by the cultures of pre-Columbian Mesoamerica as ceremonially burned incense and for other purposes. More generally, copal includes re ...
and the kauri gum of New Zealand are also procured in a semi-fossil condition.
Rosin
Rosin
Rosin (), also called colophony or Greek pitch ( la, links=no, pix graeca), is a solid form of resin obtained from pines and some other plants, mostly conifers, produced by heating fresh liquid resin to vaporize the volatile liquid terpene comp ...
is a solidified resin from which the
volatile terpene
Terpenes () are a class of natural products consisting of compounds with the formula (C5H8)n for n > 1. Comprising more than 30,000 compounds, these unsaturated hydrocarbons are produced predominantly by plants, particularly conifers. Terpenes ar ...
s have been removed by distillation. Typical rosin is a transparent or translucent mass, with a vitreous fracture and a faintly yellow or brown colour, non-odorous or having only a slight turpentine odour and taste. Rosin is insoluble in water, mostly soluble in alcohol,
essential oil
An essential oil is a concentrated hydrophobic liquid containing volatile (easily evaporated at normal temperatures) chemical compounds from plants. Essential oils are also known as volatile oils, ethereal oils, aetheroleum, or simply as the o ...
s,
ether
In organic chemistry, ethers are a class of compounds that contain an ether group—an oxygen atom connected to two alkyl or aryl groups. They have the general formula , where R and R′ represent the alkyl or aryl groups. Ethers can again be c ...
, and hot fatty oils. Rosin softens and melts when heated and burns with a bright but smoky flame.
Rosin consists of a complex mixture of different substances including organic acids named the
resin acid Resin acid refers to mixtures of several related carboxylic acids, primarily abietic acid, found in tree resins. Nearly all resin acids have the same basic skeleton: three fused rings having the empirical formula C19H29COOH. Resin acids are tacky, ...
s. Related to the terpenes, resin acid is
oxidized
Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or a d ...
terpenes. Resin acids dissolve in
alkali
In chemistry, an alkali (; from ar, القلوي, al-qaly, lit=ashes of the saltwort) is a basic, ionic salt of an alkali metal or an alkaline earth metal. An alkali can also be defined as a base that dissolves in water. A solution of a ...
s to form
resin soap
Resin soap is a mix of salts (usually sodium) of resin acids (usually mainly abietic acid). It is a yellow gelatinous pasty soap with use in bleaching and cleaning and as a compound of some varnishes. It also finds use in rubber industry.
Resin so ...
s, from which the resin acids are regenerated upon treatment with acids. Examples of resin acids are
abietic acid
Abietic acid (also known as ''abietinic acid'' or ''sylvic acid'') is an organic compound that occurs widely in trees. It is the primary component of resin acid, is the primary irritant in pine wood and resin, isolated from rosin (via isomerizat ...
(sylvic acid), C
20H
30O
2,
plicatic acid
Plicatic acid is a carboxylic acid from the resin acid group. It is naturally found in '' Thuja'' and cypress resin. It is the main irritant and contact allergen present in thuja wood. (''Cf.'' pine, where the primary irritant is abietic acid.)
T ...
contained in cedar, and
pimaric acid
Pimaric acid is a carboxylic acid from the resin acid group, often found in the oleoresins of pine trees. It can be prepared by dehydration of abietic acid, which it usually accompanies in mixtures like rosin. It is soluble in alcohols, acetone, a ...
, C
20H
30O
2, a constituent of
galipot Galipot is an impure resin of turpentine. It is obtained from pine, pine trees by evaporation of the essential oil and once purified is called yellow pitch, white pitch or Burgundy (region), Burgundy pitch.
External links
*
Alcohols
{{alcoho ...
resin. Abietic acid can also be extracted from rosin by means of hot alcohol. Pimaric acid closely resembles abietic acid into which it passes when distilled in a vacuum; it has been supposed to consist of three isomers.
Rosin is obtained from
pine
A pine is any conifer tree or shrub in the genus ''Pinus'' () of the family Pinaceae. ''Pinus'' is the sole genus in the subfamily Pinoideae. The World Flora Online created by the Royal Botanic Gardens, Kew and Missouri Botanical Garden accep ...
s and some other
plant
Plants are predominantly photosynthetic eukaryotes of the kingdom Plantae. Historically, the plant kingdom encompassed all living things that were not animals, and included algae and fungi; however, all current definitions of Plantae exclud ...
s, mostly
conifers
Conifers are a group of cone-bearing seed plants, a subset of gymnosperms. Scientifically, they make up the division Pinophyta (), also known as Coniferophyta () or Coniferae. The division contains a single extant class, Pinopsida. All extan ...
.
Plant resins are generally produced as stem secretions, but in some Central and South American species of ''
Dalechampia
''Dalechampia'' is a genus of plant of the family Euphorbiaceae and of the monogeneric subtribe Dalechampiinae. It is widespread across lowland tropical areas (generally below 2,000 m ASL) primarily in the Americas with smaller numbers of spec ...
'' and ''
Clusia
''Clusia'' is the type genus of the plant family Clusiaceae. Comprising 300-400 species, it is native to the tropics of the Americas. The genus is named by Carl Linnaeus in honor of the botanist Carolus Clusius.
The closest relatives of ''Clus ...
'' they are produced as pollination rewards, and used by some
stingless bee
Stingless bees, sometimes called stingless honey bees or simply meliponines, are a large group of bees (about 550 described species), comprising the tribe Meliponini (or subtribe Meliponina according to other authors). They belong in the family A ...
species in nest construction.
Propolis
Propolis or bee glue is a resinous mixture that honey bees produce by mixing saliva and beeswax with exudate gathered from tree buds, sap flows, or other botanical sources. It is used as a sealant for unwanted open spaces in the beehive. Pro ...
, consisting largely of resins collected from plants such as
poplars
''Populus'' is a genus of 25–30 species of deciduous flowering plants in the family Salicaceae, native to most of the Northern Hemisphere. English names variously applied to different species include poplar (), aspen, and cottonwood.
The we ...
and
conifer
Conifers are a group of conifer cone, cone-bearing Spermatophyte, seed plants, a subset of gymnosperms. Scientifically, they make up the phylum, division Pinophyta (), also known as Coniferophyta () or Coniferae. The division contains a single ...
s, is used by
honey bee
A honey bee (also spelled honeybee) is a eusocial flying insect within the genus ''Apis'' of the bee clade, all native to Afro-Eurasia. After bees spread naturally throughout Africa and Eurasia, humans became responsible for the current co ...
s to seal small gaps in their hives, while larger gaps are filled with beeswax.
Petroleum- and insect-derived resins
Shellac
Shellac () is a resin secreted by the female lac bug on trees in the forests of India and Thailand. It is processed and sold as dry flakes and dissolved in alcohol to make liquid shellac, which is used as a brush-on colorant, food glaze and ...
is an example of an insect-derived resin.
Asphaltite
Asphaltite (also known as uintahite, asphaltum, gilsonite or oil sands) is a naturally occurring soluble solid hydrocarbon, a form of asphalt (or bitumen) with a relatively high melting temperature. Its large-scale production occurs in the Uintah ...
and Utah resin are petroleum
bitumen
Asphalt, also known as bitumen (, ), is a sticky, black, highly viscous liquid or semi-solid form of petroleum. It may be found in natural deposits or may be a refined product, and is classed as a pitch. Before the 20th century, the term a ...
s.
History and etymology
![Resin on Almond tree](https://upload.wikimedia.org/wikipedia/commons/9/97/Resin_on_Almond_tree.jpg)
Human use of plant resins has a very long history that was documented in
ancient Greece
Ancient Greece ( el, Ἑλλάς, Hellás) was a northeastern Mediterranean civilization, existing from the Greek Dark Ages of the 12th–9th centuries BC to the end of classical antiquity ( AD 600), that comprised a loose collection of cult ...
by
Theophrastus
Theophrastus (; grc-gre, Θεόφραστος ; c. 371c. 287 BC), a Greek philosopher and the successor to Aristotle in the Peripatetic school. He was a native of Eresos in Lesbos.Gavin Hardy and Laurence Totelin, ''Ancient Botany'', Routledge ...
, in ancient Rome by
Pliny the Elder
Gaius Plinius Secundus (AD 23/2479), called Pliny the Elder (), was a Roman author, naturalist and natural philosopher, and naval and army commander of the early Roman Empire, and a friend of the emperor Vespasian. He wrote the encyclopedic '' ...
, and especially in the resins known as
frankincense
Frankincense (also known as olibanum) is an aromatic resin used in incense and perfumes, obtained from trees of the genus ''Boswellia'' in the family Burseraceae. The word is from Old French ('high-quality incense').
There are several species o ...
and
myrrh
Myrrh (; from Semitic, but see '' § Etymology'') is a gum-resin extracted from a number of small, thorny tree species of the genus ''Commiphora''. Myrrh resin has been used throughout history as a perfume, incense and medicine. Myrrh mi ...
, prized in
ancient Egypt.
[
] These were highly prized substances, and required as
incense
Incense is aromatic biotic material that releases fragrant smoke when burnt. The term is used for either the material or the aroma. Incense is used for aesthetic reasons, religious worship, aromatherapy, meditation, and ceremony. It may also be ...
in some religious rites.
The word ''resin'' comes from French ''resine'', from Latin ''resina'' "resin", which either derives from or is a
cognate
In historical linguistics, cognates or lexical cognates are sets of words in different languages that have been inherited in direct descent from an etymology, etymological ancestor in a proto-language, common parent language. Because language c ...
of the Greek ''rhētínē'' "resin of the pine", of unknown earlier origin, though probably non-
Indo-European
The Indo-European languages are a language family native to the overwhelming majority of Europe, the Iranian plateau, and the northern Indian subcontinent. Some European languages of this family, English, French, Portuguese, Russian, Dutch ...
.
The word "resin" has been applied in the modern world to nearly any component of a liquid that will set into a hard
lacquer
Lacquer is a type of hard and usually shiny coating or finish applied to materials such as wood or metal. It is most often made from resin extracted from trees and waxes and has been in use since antiquity.
Asian lacquerware, which may be ca ...
or
enamel-like finish. An example is nail polish. Certain "casting resins" and
synthetic resin
Synthetic resins are industrially produced resins, typically viscous substances that convert into rigid polymers by the process of curing. In order to undergo curing, resins typically contain reactive end groups, such as acrylates or epoxides. ...
s (such as
epoxy resin
Epoxy is the family of basic components or cured end products of epoxy resins. Epoxy resins, also known as polyepoxides, are a class of reactive prepolymers and polymers which contain epoxide groups. The epoxide functional group is also coll ...
) have also been given the name "resin".
Some naturally-derived resins, when soft, are known as 'oleoresins', and when containing
benzoic acid
Benzoic acid is a white (or colorless) solid organic compound with the formula , whose structure consists of a benzene ring () with a carboxyl () substituent. It is the simplest aromatic carboxylic acid. The name is derived from gum benzoin, wh ...
or
cinnamic acid
Cinnamic acid is an organic compound with the formula C6H5-CH=CH- COOH. It is a white crystalline compound that is slightly soluble in water, and freely soluble in many organic solvents. Classified as an unsaturated carboxylic acid, it occurs n ...
they are called balsams. Oleoresins are naturally-occurring mixtures of an oil and a resin; they can be extracted from various plants. Other resinous products in their natural condition are a mix with
gum or mucilaginous substances and known as
gum resin
Gum may refer to:
Types of gum
* Adhesive
* Bubble gum
* Chewing gum
* Gum (botany), sap or other resinous material associated with certain species of the plant kingdom
** Gum arabic, made from the sap of ''Acacia senegal'', an Old World tree sp ...
s. Several natural resins are used as ingredients in perfumes, e.g., balsams of Peru and tolu, elemi, styrax, and certain turpentines.
[
]
Non-resinous exudates
Other liquid compounds found inside plants or exuded by plants, such as sap
Sap is a fluid transported in xylem cells (vessel elements or tracheids) or phloem sieve tube elements of a plant. These cells transport water and nutrients throughout the plant.
Sap is distinct from latex, resin, or cell sap; it is a separa ...
, latex
Latex is an emulsion (stable dispersion) of polymer microparticles in water. Latexes are found in nature, but synthetic latexes are common as well.
In nature, latex is found as a milky fluid found in 10% of all flowering plants (angiosperms ...
, or mucilage
Mucilage is a thick, gluey substance produced by nearly all plants and some microorganisms. These microorganisms include protists which use it for their locomotion. The direction of their movement is always opposite to that of the secretion of m ...
, are sometimes confused with resin but are not the same. Saps, in particular, serve a nutritive function that resins do not.
Uses
Plant resins
Plant resins are valued for the production of varnish
Varnish is a clear transparent hard protective coating or film. It is not a stain. It usually has a yellowish shade from the manufacturing process and materials used, but it may also be pigmented as desired, and is sold commercially in various ...
es, adhesive
Adhesive, also known as glue, cement, mucilage, or paste, is any non-metallic substance applied to one or both surfaces of two separate items that binds them together and resists their separation.
The use of adhesives offers certain advant ...
s, and food glazing agent
A glazing agent is a natural or synthetic substance that provides a waxy, homogeneous, coating to prevent water loss from a surface and provide other protection.
Natural
Natural glazing agents keep moisture inside plants and insects. Scientists ...
s. They are also prized as raw materials for the synthesis of other organic compounds and provide constituents of incense
Incense is aromatic biotic material that releases fragrant smoke when burnt. The term is used for either the material or the aroma. Incense is used for aesthetic reasons, religious worship, aromatherapy, meditation, and ceremony. It may also be ...
and perfume
Perfume (, ; french: parfum) is a mixture of fragrant essential oils or aroma compounds (fragrances), fixatives and solvents, usually in liquid form, used to give the human body, animals, food, objects, and living-spaces an agreeable scent. Th ...
. The oldest known use of plant resin comes from the late Middle Stone Age in Southern Africa where it was used as an adhesive for hafting stone tools.
The hard transparent resins, such as the copals, dammar
Dammar, also called dammar gum, or damar gum, is a resin obtained from the tree family Dipterocarpaceae in India and Southeast Asia, principally those of the genera '' Shorea'' or '' Hopea'' (synonym ''Balanocarpus''). The resin of some species ...
s, mastic
Mastic may refer to:
Adhesives and pastes
*Mastic (plant resin)
*Mastic asphalt, or asphalt, is a sticky, black and highly viscous liquid
* Mastic cold porcelain, or salt ceramic, is a traditional salt-based modeling clay.
*Mastic, high-grade con ...
, and sandarac
Sandarac (or sandarach) is a resin obtained from the small cypress-like tree '' Tetraclinis articulata''. The tree is native to the northwest of Africa with a notable presence in the Southern Morocco part of the Atlas mountains. The resin exudes ...
, are principally used for varnishes and adhesives, while the softer odoriferous oleo-resins (frankincense
Frankincense (also known as olibanum) is an aromatic resin used in incense and perfumes, obtained from trees of the genus ''Boswellia'' in the family Burseraceae. The word is from Old French ('high-quality incense').
There are several species o ...
, elemi
''Canarium luzonicum'', commonly known as elemi, is a tree native to the Philippines. The oleoresin harvested from it is also known as elemi.
Synonyms
* ''Canarium carapifolium'' G.Perkins
* ''Canarium oliganthum'' Merr.
* ''Canarium polyanthu ...
, turpentine
Turpentine (which is also called spirit of turpentine, oil of turpentine, terebenthene, terebinthine and (colloquially) turps) is a fluid obtained by the distillation of resin harvested from living trees, mainly pines. Mainly used as a special ...
, copaiba
Copaiba is a stimulant oleoresin obtained from the trunk of several pinnate-leaved South American leguminous trees (genus '' Copaifera''). The thick, transparent exudate varies in color from light gold to dark brown, depending on the ratio of re ...
), and gum resins containing essential oils (ammoniacum
Ammoniacum or the gum ammoniac is a gum-resin exuded from the several perennial herbs in the genus ''Ferula'' of the umbel family (Apiaceae). There are three types of ammoniacum: the gums ammoniac of Cyrenaica, of Persia (the commercial one today ...
, asafoetida
Asafoetida (; also spelled asafetida)
is the dried latex ( gum oleoresin) exuded from the rhizome or tap root of several species of ''Ferula'', perennial herbs growing tall. They are part of the celery family, Umbelliferae. Asafoetida is thou ...
, gamboge
Gamboge ( , ) is a partially transparent deep saffron to mustard yellow pigment.Other forms and spellings are: cambodia, cambogium, camboge, cambugium, gambaugium, gambogia, gambozia, gamboidea, gambogium, gumbouge, gambouge, gamboge, gambooge, g ...
, myrrh
Myrrh (; from Semitic, but see '' § Etymology'') is a gum-resin extracted from a number of small, thorny tree species of the genus ''Commiphora''. Myrrh resin has been used throughout history as a perfume, incense and medicine. Myrrh mi ...
, and scammony
''Convolvulus scammonia'', known commonly as scammony, is a bindweed native to the countries of the eastern part of the Mediterranean basin; it grows in bushy waste places, from Syria in the south to the Crimea in the north, its range extending w ...
) are more used for therapeutic purposes, food and incense
Incense is aromatic biotic material that releases fragrant smoke when burnt. The term is used for either the material or the aroma. Incense is used for aesthetic reasons, religious worship, aromatherapy, meditation, and ceremony. It may also be ...
. The resin of the Aleppo Pine
''Pinus halepensis'', commonly known as the Aleppo pine, also known as the Jerusalem pine, is a pine native to the Mediterranean region.
Description
''Pinus halepensis'' is a small to medium-sized tree, tall, with a trunk diameter up to , exce ...
is used to flavour retsina
Retsina ( el, Ρετσίνα) is a Greek white (or rosé) resinated wine, which has been made for at least 2,000 years. Its unique flavor is said to have originated from the practice of sealing wine vessels, particularly amphorae, with Alepp ...
, a Greek resinated wine
Resinated wine is a type of wine which derives part of its flavor from exposure to tree resins, most generally pine resin, therefore often being known as pine wine. Prior to the widespread use of barrels in Europe, wine was stored in amphorae, of ...
.
Synthetic resins
Many materials are produced via the conversion of synthetic resins to solids. Important examples are bisphenol A diglycidyl ether
Bisphenol A diglycidyl ether (commonly abbreviated BADGE or DGEBA) is an organic compound used as constituent of epoxy resins. The compound is a colorless solid (commercial samples can appear yellow) that melts slightly above room temperature.
...
, which is a resin converted to epoxy glue upon the addition of a hardener. Silicones are often prepared from silicone resins via room temperature vulcanization
In a building or large vehicle, like a ship, a room is any enclosed space within a number of walls to which entry is possible only via a door or other dividing structure that connects it to either a passageway, another room, or the outdoors, that ...
. Alkyd resin
An alkyd is a polyester resin modified by the addition of fatty acids and other components. Alkyds are derived from polyols and organic acids including dicarboxylic acids or carboxylic acid anhydride and triglyceride oils. The term ''alkyd'' is a ...
s are used in paint
Paint is any pigmented liquid, liquefiable, or solid mastic composition that, after application to a substrate in a thin layer, converts to a solid film. It is most commonly used to protect, color, or provide texture. Paint can be made in many ...
s and varnish
Varnish is a clear transparent hard protective coating or film. It is not a stain. It usually has a yellowish shade from the manufacturing process and materials used, but it may also be pigmented as desired, and is sold commercially in various ...
es and harden or cure by exposure to oxygen
Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as wel ...
in the air.
See also
* Amber
Amber is fossilized tree resin that has been appreciated for its color and natural beauty since Neolithic times. Much valued from antiquity to the present as a gemstone, amber is made into a variety of decorative objects."Amber" (2004). In Ma ...
* Resin extraction
Resin extraction consists of incising the outer layers of a pine tree in order to collect the sap or resin.
Summary
Resin circulates throughout a coniferous tree and a few others, and serves to seal damage to the tree. Harvesting pine resin d ...
– method of harvesting resin from trees
* Balsam of Peru
Balsam of Peru or Peru balsam, also known and marketed by many other names, is a balsam derived from a tree known as ''Myroxylon balsamum'' var. ''pereirae''; it is found in El Salvador, where it is an endemic species.
Balsam of Peru is used i ...
– a balsam used in food and drink for flavoring, in perfumes and toiletries for fragrance, and in medicine and pharmaceutical items.
* Mastic (plant resin)
Mastic ( el, Μαστίχα) is a resin obtained from the mastic tree (''Pistacia lentiscus''). It is also known as tears of Chios, being traditionally produced on the island Chios, and, like other natural resins, is produced in "tears" or dropl ...
– resin from the Pistacia lentiscus
''Pistacia lentiscus'' (also lentisk or mastic) is a dioecious evergreen shrub or small tree of the genus ''Pistacia'' native to the Mediterranean Basin. It grows up to tall and is cultivated for its aromatic resin, mainly on the Greek islan ...
tree
* Pitch (resin)
Pitch is a viscoelastic polymer which can be natural or manufactured, derived from petroleum, coal tar, or plants. Various forms of pitch may also be called tar, bitumen, or asphalt. Pitch produced from plants is also known as resin. Some produc ...
* Kino (gum)
Kino is a botanical gum produced by various trees and other plants, particularly bloodwood species of eucalypts (''Angophora'', ''Corymbia'', ''Eucalyptus'') and ''Pterocarpus'', in reaction to mechanical damage, and which can be tapped by incis ...
– a plant gum similar to resin
* Biodegradable
Biodegradation is the breakdown of organic matter by microorganisms, such as bacteria and fungi. It is generally assumed to be a natural process, which differentiates it from composting. Composting is a human-driven process in which biodegradati ...
– plant resins are naturally biodegradable in many circumstances.
* Resin casting
Resin casting is a method of plastic casting where a mold is filled with a liquid synthetic resin, which then hardens. It is primarily used for small-scale production like industrial prototypes and dentistry. It can be done by amateur hobbyists wit ...
– casting with a resin, usually using a synthetic not a natural resin.
* Polyresin Polyester resins are synthetic resins formed by the reaction of dibasic acid, dibasic organic acids and polyhydric alcohols. Maleic anhydride is a commonly used raw material with diacid functionality in Unsaturated bond, unsaturated polyester resins ...
– a hard, synthetic resin for casting in molds
References
External links
*
*
{{Authority control
Non-timber forest products
Papermaking
Tree tapping