Paper Pollution
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The environmental effects of
paper Paper is a thin sheet material produced by mechanically or chemically processing cellulose fibres derived from wood, rags, grasses or other vegetable sources in water, draining the water through fine mesh leaving the fibre evenly distributed ...
are significant, which has led to changes in
industry Industry may refer to: Economics * Industry (economics), a generally categorized branch of economic activity * Industry (manufacturing), a specific branch of economic activity, typically in factories with machinery * The wider industrial sector ...
and behaviour at both business and personal levels. With the use of modern technology such as the
printing press A printing press is a mechanical device for applying pressure to an inked surface resting upon a printing, print medium (such as paper or cloth), thereby transferring the ink. It marked a dramatic improvement on earlier printing methods in wh ...
and the highly mechanized harvesting of wood,
disposable A disposable (also called disposable product) is a product designed for a single use after which it is recycled or is disposed as solid waste. The term is also sometimes used for products that may last several months (e.g. disposable air filte ...
paper became a relatively cheap commodity, which led to a high level of consumption and
waste Waste (or wastes) are unwanted or unusable materials. Waste is any substance discarded after primary use, or is worthless, defective and of no use. A by-product, by contrast is a joint product of relatively minor economic value. A waste prod ...
. The rise in global environmental issues such as air and water pollution, climate change, overflowing landfills and
clearcutting Clearcutting, clearfelling or clearcut logging is a forestry/ logging practice in which most or all trees in an area are uniformly cut down. Along with shelterwood and seed tree harvests, it is used by foresters to create certain types of fore ...
have all lead to increased government regulations. There is now a trend towards
sustainability Specific definitions of sustainability are difficult to agree on and have varied in the literature and over time. The concept of sustainability can be used to guide decisions at the global, national, and individual levels (e.g. sustainable livi ...
in the
pulp and paper industry The pulp and paper industry comprises companies that use wood as raw material and produce pulp, paper, paperboard and other cellulose-based products. Manufacturing process The pulp is fed to a paper machine where it is formed as a paper web an ...
as it moves to reduce clear cutting, water use,
greenhouse gas emissions Greenhouse gas emissions from human activities strengthen the greenhouse effect, contributing to climate change. Most is carbon dioxide from burning fossil fuels: coal, oil, and natural gas. The largest emitters include coal in China and lar ...
, fossil fuel consumption and clean up its influence on local water supplies and air pollution. According to a Canadian citizens' organization, "People need paper products and we need sustainable, environmentally safe production." Environmental product declarations or product scorecards are available to collect and evaluate the environmental and social performance of paper products, such as the Paper Calculator, Environmental Paper Assessment Tool (EPAT), or Paper Profile. Both the U.S. and Canada generate interactive maps of environmental indicators which show pollution emissions of individual facilities.


Issues

Pulp and paper mill A paper mill is a factory devoted to making paper from vegetable fibres such as wood pulp, old rags, and other ingredients. Prior to the invention and adoption of the Fourdrinier machine and other types of paper machine that use an endless belt, ...
s contribute to
air The atmosphere of Earth is the layer of gases, known collectively as air, retained by Earth's gravity that surrounds the planet and forms its planetary atmosphere. The atmosphere of Earth protects life on Earth by creating pressure allowing f ...
,
water Water (chemical formula ) is an inorganic, transparent, tasteless, odorless, and nearly colorless chemical substance, which is the main constituent of Earth's hydrosphere and the fluids of all known living organisms (in which it acts as a ...
and
land Land, also known as dry land, ground, or earth, is the solid terrestrial surface of the planet Earth that is not submerged by the ocean or other bodies of water. It makes up 29% of Earth's surface and includes the continents and various islan ...
pollution and discarded paper and paperboard make up roughly 26% of solid municipal waste in
landfill A landfill site, also known as a tip, dump, rubbish dump, garbage dump, or dumping ground, is a site for the disposal of waste materials. Landfill is the oldest and most common form of waste disposal, although the systematic burial of the waste ...
sites. Pulp and paper generates the third largest amount of industrial air, water, and land emissions in Canada and the sixth largest in the United States. In 2015, the industry released 174,000 tonnes of emissions to air, water and land (or 5.3%) out of a total of 3.3 million tonnes of emissions released by all industries in Canada. In the United States the pulp and paper industry released about 79, 000 tonnes or about 5% of all industrial pollutant releases in 2015 Of this total waste released by the pulp and paper industry in the U.S., 66% was released into the air, 10% into water and 24% onto land whereas in Canada, most of the waste (96%) was released into the air. Worldwide, the pulp and paper industry is the fifth largest consumer of energy, accounting for four percent of all the world's energy use. However, the entire paper and printing sector contributes less than 1% to the global greenhouse gas inventory due to the very high use of renewable energy, mostly biomass. The pulp and paper industry uses more water to produce a ton of product than any other industry. The de-inking process during paper recycling is also a source of emissions due to chemicals released in the effluent. The European Recovered Paper Council has developed the ‘deinkability scorecard’ so that the printed paper products which have the best recyclability when they are deinked can be identified. Worldwide consumption of paper has risen by 400% in the past 40 years, with 35% of harvested trees being used for paper manufacture. Plantation forests, from where the majority of wood for
pulping Pulp is a Lignocellulosic biomass, lignocellulosic fibrous material prepared by chemically or mechanically separating cellulose fibers from wood, fiber crops, Paper recycling, waste paper, or cotton paper, rags. Mixed with water and other chemica ...
is obtained, is generally a
monoculture In agriculture, monoculture is the practice of growing one crop species in a field at a time. Monoculture is widely used in intensive farming and in organic farming: both a 1,000-hectare/acre cornfield and a 10-ha/acre field of organic kale are ...
and this raises concerns over the
ecological effects Ecology () is the study of the relationships between living organisms, including humans, and their physical environment. Ecology considers organisms at the individual, population, community, ecosystem, and biosphere level. Ecology overlaps wi ...
of the practice. Much of the wood harvested in North America goes into lumber and other non-paper products. In the U.S., 36% of the annual timber harvest is used for paper and paperboard and in Canada 21% comes directly from harvested trees. The rest comes from sawmill residues (55%) and recycled paper (24%). Deforestation is often seen as a problem in developing countries but also occurs in the developed world.
Woodchipping Woodchips are small- to medium-sized pieces of wood formed by cutting or chipping larger pieces of wood such as trees, branches, logging residues, stumps, roots, and wood waste. Woodchips may be used as a biomass solid fuel and are raw material ...
to produce paper pulp is a contentious
environmental issue Environmental issues are effects of human activity on the biophysical environment, most often of which are harmful effects that cause environmental degradation. Environmental protection is the practice of protecting the natural environment on th ...
in
Australia Australia, officially the Commonwealth of Australia, is a Sovereign state, sovereign country comprising the mainland of the Australia (continent), Australian continent, the island of Tasmania, and numerous List of islands of Australia, sma ...
. In the 1990s, the New Zealand government stopped the export of
woodchips Woodchips are small- to medium-sized pieces of wood formed by cutting or chipping larger pieces of wood such as trees, branches, logging residues, stumps, roots, and wood waste. Woodchips may be used as a biomass solid fuel and are raw material ...
from native forests after campaigning by environmentalists. Over 6.5 million trees were cut down to make 16 billion
paper cup A paper cup is a disposable cup made out of paper and often lined or coated with plastic or wax to prevent liquid from leaking out or soaking through the paper. It may be made of recycled paper and is widely used around the world. History Paper ...
s used by US consumers only for coffee in 2006, using of water and resulting in 253 million pounds of waste. Overall, North Americans use 58% of all paper cups, amounting to 130 billion cups.


Air pollution

The National Emissions Inventory in the U.S. and the Air Pollutant Emission Inventory (APEI) in Canada compile annual emissions of air pollutants that contribute to smog, acid rain, greenhouse gases and diminished air quality including particulate matter (PM), sulphur oxides (SOx), nitrogen oxides (NOx), cadmium, lead, mercury, and
persistent organic pollutant Persistent organic pollutants (POPs), sometimes known as "forever chemicals", are organic compounds that are resistant to environmental degradation through chemical, biological, and photolytic processes. They are toxic chemicals that adversely ...
s (POPs) such as
dioxin Dioxin may refer to: * 1,2-Dioxin or 1,4-Dioxin, two unsaturated heterocyclic 6-membered rings where two carbon atoms have been replaced by oxygen atoms, giving the molecular formula C4H4O2 *Dibenzo-1,4-dioxin, the parent compound also known as ...
s and
furan Furan is a heterocyclic organic compound, consisting of a five-membered aromatic ring with four carbon atoms and one oxygen atom. Chemical compounds containing such rings are also referred to as furans. Furan is a colorless, flammable, highly ...
s,
hexachlorobenzene Hexachlorobenzene, or perchlorobenzene, is an organochloride with the molecular formula C6Cl6. It is a fungicide formerly used as a seed treatment, especially on wheat to control the fungal disease bunt. It has been banned globally under the Sto ...
(HCB) and
polycyclic aromatic hydrocarbons A polycyclic aromatic hydrocarbon (PAH) is a class of organic compounds that is composed of multiple aromatic rings. The simplest representative is naphthalene, having two aromatic rings and the three-ring compounds anthracene and phenanthrene. P ...
(PAH). In addition, the
Toxics Release Inventory The Toxics Release Inventory (TRI) is a publicly available database containing information on toxic chemical releases and other waste management activities in the United States. Summary of requirements The database is available from the United St ...
(TRI) is a publicly available database maintained by the EPA's TRI Program that tracks the management in the U.S. of certain toxic chemicals that may pose a threat to human health and the environment. In the U.S., total industrial releases of toxic waste into the air were 690 million pounds (313,000 tonnes) in 2015 and pulp and paper accounted for 20%. Of the releases to air by the pulp and paper industry, 60% were methanol which is not a
persistent, bioaccumulative, and toxic Persistent, bioaccumulative and toxic substances (PBTs) are a class of compounds that have high resistance to degradation from abiotic and biotic factors, high mobility in the environment and high toxicity. Because of these factors PBTs have been ...
(PBT) chemical and is not a carcinogen. Several PBTs are emitted by the pulp and paper industry at measurable levels, including lead, hexachlorobenzene (HCB), dioxins, furans and polycyclic aromatic hydrocarbons. In Canada emissions of these chemicals by the industry were less than 2% of total emissions in 2015. In the U.S., the pulp and paper industry accounted for 22% of total HCB emissions but other PBT emissions were under 2% of national totals. There are other important releases to air by the pulp and paper industry. Fine particulate matter (PM2.5) consists of particles 2.5 microns in diameter or less which can penetrate the respiratory system and have a serious effect on health. The pulp and paper industry in the U.S. and Canada is responsible for roughly 10% of the industrial releases of PM2.5. However, the majority of PM2.5 in the air comes from non-industrial sources such as residential wood combustion, construction, and dust from unpaved roads and when these sources are taken into account, the pulp and paper industry in North America produced only about 0.5% of the total in 2014.
Nitrogen oxides Nitrogen oxide may refer to a binary compound of oxygen and nitrogen, or a mixture of such compounds: Charge-neutral *Nitric oxide (NO), nitrogen(II) oxide, or nitrogen monoxide *Nitrogen dioxide (), nitrogen(IV) oxide *Nitrogen trioxide (), or ni ...
(NOx)
sulfur oxides Sulfur oxide refers to many types of sulfur and oxygen containing compounds such as SO, SO2, SO3, S7O2, S6O2, S2O2, etc. Sulfur oxide (SO''x'') refers to one or more of the following: * Lower sulfur oxides (S''n''O, S7O2 and S6O2) * Sulfur monox ...
(SOx) and
carbon dioxide Carbon dioxide (chemical formula ) is a chemical compound made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in the gas state at room temperature. In the air, carbon dioxide is transpar ...
(CO2) are all emitted during pulp and paper manufacturing. NOx and SOx are major contributors of
acid rain Acid rain is rain or any other form of precipitation that is unusually acidic, meaning that it has elevated levels of hydrogen ions (low pH). Most water, including drinking water, has a neutral pH that exists between 6.5 and 8.5, but acid ...
and CO2 is a
greenhouse gas A greenhouse gas (GHG or GhG) is a gas that Absorption (electromagnetic radiation), absorbs and Emission (electromagnetic radiation), emits radiant energy within the thermal infrared range, causing the greenhouse effect. The primary greenhouse ...
responsible for
climate change In common usage, climate change describes global warming—the ongoing increase in global average temperature—and its effects on Earth's climate system. Climate change in a broader sense also includes previous long-term changes to E ...
. In 2014, the pulp and paper industry in North America was responsible for about 0.5% of the total SOx and NOx releases from industrial and non-industrial sources.


Water pollution

Wastewater Wastewater is water generated after the use of freshwater, raw water, drinking water or saline water in a variety of deliberate applications or processes. Another definition of wastewater is "Used water from any combination of domestic, industr ...
discharges for a pulp and paper mill contains solids, nutrients and dissolved organic matter such as
lignin Lignin is a class of complex organic polymers that form key structural materials in the support tissues of most plants. Lignins are particularly important in the formation of cell walls, especially in wood and bark, because they lend rigidity ...
. It also contains
alcohol Alcohol most commonly refers to: * Alcohol (chemistry), an organic compound in which a hydroxyl group is bound to a carbon atom * Alcohol (drug), an intoxicant found in alcoholic drinks Alcohol may also refer to: Chemicals * Ethanol, one of sev ...
s, and
chelating Chelation is a type of bonding of ions and molecules to metal ions. It involves the formation or presence of two or more separate coordinate bonds between a Denticity, polydentate (multiple bonded) ligand and a single central metal atom. These l ...
agents and inorganic materials like
chlorate The chlorate anion has the formula ClO3-. In this case, the chlorine atom is in the +5 oxidation state. "Chlorate" can also refer to chemical compounds containing this anion; chlorates are the salts of chloric acid. "Chlorate", when followed by ...
s and
transition metal In chemistry, a transition metal (or transition element) is a chemical element in the d-block of the periodic table (groups 3 to 12), though the elements of group 12 (and less often group 3) are sometimes excluded. They are the elements that can ...
compounds. Nutrients such as nitrogen and phosphorus can cause or exacerbate
eutrophication Eutrophication is the process by which an entire body of water, or parts of it, becomes progressively enriched with minerals and nutrients, particularly nitrogen and phosphorus. It has also been defined as "nutrient-induced increase in phytopla ...
of fresh water bodies such as lakes and rivers. Organic matter dissolved in fresh water, measured by
biological oxygen demand Biochemical oxygen demand (BOD) is the amount of dissolved oxygen (DO) needed (i.e. demanded) by aerobic biological organisms to break down organic material present in a given water sample at a certain temperature over a specific time period. T ...
(BOD), changes ecological characteristics. Wastewater may also be polluted with
organochlorine An organochloride, organochlorine compound, chlorocarbon, or chlorinated hydrocarbon is an organic compound containing at least one covalent bond, covalently bonded atom of chlorine. The chloroalkane class (alkanes with one or more hydrogens subst ...
compounds. Some of these are naturally occurring in the wood, but chlorine bleaching of the pulp produces far larger amounts. Recent studies underline as an appropriate pre-treatment of the wastewater (e.g. the coagulation) is cost-effective solution for the removal of Chemical Oxygen Demand (COD) and the reduction of the pressures on the aquatic environment. In Canada, the pulp and paper industry released 5% of the total industrial waste disposed of to water in 2015. In 2014, 97.5%, 99.9% and 99.8% of effluent samples from pulp and paper mills met regulatory requirements for toxicity tests on fish, biochemical oxygen demand, and total suspended solids, respectively. The pulp and paper industry is also associated with important emissions of heavy metals. In Canada, for example, this industry is the third source of lead (Pb) emissions to water In the U.S., the pulp and paper industry is responsible for 9% of industrial releases to water. In 2015, the pulp and paper sector was ranked first in the amount of toxic weighted pound equivalents (TWPE) discharged to water by industry.EPA (2016)
"2015 Annual Effluent Guidelines Review Report."
/ref> Over 92% of this TWPE came from hydrogen sulphide, dioxin and dioxin-like compounds and manganese (Mn) and manganese compounds. Note that 7 pulp and paper facilities accounted for 80% of the hydrogen sulphide discharged and 5 facilities accounted for 93% of the dioxin discharged out of a total of 226 facilities. The last time the EPA reviewed Mn and Mn compounds (2006) it concluded that discharges were below treatable levels. Levels of discharge have not changed significantly since that time. Recycling the effluent (see black liquor) and burning it, using
bioremediation Bioremediation broadly refers to any process wherein a biological system (typically bacteria, microalgae, fungi, and plants), living or dead, is employed for removing environmental pollutants from air, water, soil, flue gasses, industrial effluent ...
ponds and employing less damaging agents in the pulping and bleaching processes can help reduce water pollution. Discharges can also discolour the water leading to reduced aesthetics. This has happened with the
Tarawera River The Tarawera River is in the Bay of Plenty Region in the North Island of New Zealand. It flows from Lake Tarawera, northeastwards across the northern flanks of the active volcano Mount Tarawera, and past the town of Kawerau before turning north, ...
in New Zealand which subsequently became known as the "black drain".


Paper waste

Discarded paper and paperboard make up roughly 26% (or 67 million tons) of the 258 million tons of solid municipal waste generated in 2014 and over 14% of the 136 million tons solid municipal waste that ended up in landfills in 2014. Paper waste, like other wastes, faces the additional hazard of toxic inks, dyes and polymers that could be potentially carcinogenic when incinerated, or commingled with groundwater via traditional burial methods such as modern
landfills A landfill site, also known as a tip, dump, rubbish dump, garbage dump, or dumping ground, is a site for the disposal of waste materials. Landfill is the oldest and most common form of waste disposal, although the systematic burial of the waste ...
.
Paper recycling The recycling of paper is the process by which waste paper is turned into new paper products. It has a number of important benefits: It saves waste paper from occupying homes of people and producing methane as it breaks down. Because paper fi ...
mitigates this impact, but not the environmental and economic impact of the energy consumed by manufacturing, transporting and burying and or reprocessing paper products.


Wood pulping process


Chlorine and chlorine-based materials

Chlorine Chlorine is a chemical element with the Symbol (chemistry), symbol Cl and atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the periodic table and its properties are mostly intermediate betwee ...
and compounds of chlorine are used in the
bleaching of wood pulp Bleaching of wood pulp is the chemical processing of wood pulp to lighten its color and whiten the pulp. The primary product of wood pulp is paper, for which whiteness (similar to, but distinct from brightness) is an important characteristic. These ...
, especially chemical pulps produced by the
kraft process The kraft process (also known as kraft pulping or sulfate process) is a process for conversion of wood into wood pulp, which consists of almost pure cellulose fibres, the main component of paper. The kraft process involves treatment of wood chip ...
or
sulfite process The sulfite process produces wood pulp that is almost pure cellulose fibers by treating wood chips with solutions of sulfite and bisulfite ions. These chemicals cleave the bonds between the cellulose and lignin components of the lignocellulose. A ...
. In the past, plants using elemental chlorine produced significant quantities of
dioxins Dioxin may refer to: * 1,2-Dioxin or 1,4-Dioxin, two unsaturated heterocyclic 6-membered rings where two carbon atoms have been replaced by oxygen atoms, giving the molecular formula C4H4O2 *Dibenzo-1,4-dioxin, the parent compound also known as ...
, Catalog no. En40-215/2E persistent and very toxic organic pollutants. From the 1990s onward, the use of elemental chlorine in the delignification process was substantially reduced and replaced with ECF (Elemental Chlorine Free) and TCF (Totally Chlorine Free) bleaching processes. As a result, dioxin production was also significantly reduced. In 2005, elemental chlorine was used in 19–20% of kraft pulp production globally, down from over 90% in 1990. 75% of kraft pulp used ECF, with the remaining 5–6% using TCF. A study based on
U.S. Environmental Protection Agency The Environmental Protection Agency (EPA) is an independent executive agency of the United States federal government tasked with environmental protection matters. President Richard Nixon proposed the establishment of EPA on July 9, 1970; it be ...
(EPA) data concluded that "Studies of effluents from mills that use oxygen delignification and extended delignification to produce ECF (elemental chlorine free) and TCF pulps suggest that the environmental effects of these processes are low and similar."Paper Task Force (1995)
"Environmental Comparison of Bleached Kraft Pulp Manufacturing Technologies."
White paper no. 5. Joint publication of Duke University, Environmental Defense Fund, Johnson & Johnson, McDonald's, Prudential Insurance Company of America and Time Inc.
Most TCF pulp is produced in Sweden and Finland for sale in Germany, all markets with a high level of environmental awareness. In 1999, TCF pulp represented 25% of the European market. TCF bleaching, by removing chlorine from the process, reduces chlorinated organic compounds to background levels in pulp mill effluent. ECF bleaching can substantially reduce but not fully eliminate chlorinated organic compounds, including dioxins, from effluent. While modern ECF plants can achieve chlorinated organic compounds (AOX) emissions of less than 0.05 kg per tonne of pulp produced, most do not achieve this level of emissions. Within the EU, the average chlorinated organic compound emissions for ECF plants is 0.15 kg per tonne. However, there has been disagreement about the comparative environmental effects of ECF and TCF bleaching. On the one hand, paper and chemical industry-funded studies have generally found that there is no environmental difference between ECF and TCF effluents. On the other hand, an independent peer-reviewed study has found that, comparing conventional, ECF and TCF effluents before and after
secondary treatment Secondary treatment is the removal of biodegradable organic matter (in solution or suspension) from sewage or similar kinds of wastewater. The aim is to achieve a certain degree of effluent quality in a sewage treatment plant suitable for the ...
, "TCF effluents are the least toxic."


Sulfur, hydrogen sulfide and sulfur dioxide

Sulfur Sulfur (or sulphur in British English) is a chemical element with the symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with a chemical formula ...
-based compounds are used in both the
kraft process The kraft process (also known as kraft pulping or sulfate process) is a process for conversion of wood into wood pulp, which consists of almost pure cellulose fibres, the main component of paper. The kraft process involves treatment of wood chip ...
and the
sulfite process The sulfite process produces wood pulp that is almost pure cellulose fibers by treating wood chips with solutions of sulfite and bisulfite ions. These chemicals cleave the bonds between the cellulose and lignin components of the lignocellulose. A ...
for making wood pulp. Sulfur is generally recovered, with the exception of ammonia-based sulfite processes, but some is released as sulfur dioxide during combustion of black liquor, a byproduct of the kraft process, or "red liquor" from the sulfite process.
Sulfur dioxide Sulfur dioxide (IUPAC-recommended spelling) or sulphur dioxide (traditional Commonwealth English) is the chemical compound with the formula . It is a toxic gas responsible for the odor of burnt matches. It is released naturally by volcanic activ ...
is of particular concern because it is water-soluble and is a major cause of
acid rain Acid rain is rain or any other form of precipitation that is unusually acidic, meaning that it has elevated levels of hydrogen ions (low pH). Most water, including drinking water, has a neutral pH that exists between 6.5 and 8.5, but acid ...
. In 2006 the
pulp and paper industry in Canada The pulp and paper industry in Canada is one of the country's most important and profitable industries.. It is especially concentrated in Ontario and Quebec and plays an important role in many other provinces.. Leading companies The leading for ...
released about 60,000 tonnes of
sulfur oxide Sulfur oxide refers to many types of sulfur and oxygen containing compounds such as SO, SO2, SO3, S7O2, S6O2, S2O2, etc. Sulfur oxide (SO''x'') refers to one or more of the following: * Lower sulfur oxides (S''n''O, S7O2 and S6O2) * Sulfur monox ...
s (SOx) into the atmosphere, accounting for just over 4% of the total SOx emission from all Canadian industries. A modern kraft pulp mill is more than self-sufficient in its electrical generation and normally will provide a net flow of energy to the local electrical grid. Additionally, bark and wood residues are often burned in a separate power boiler to generate steam. Air emissions of
hydrogen sulfide Hydrogen sulfide is a chemical compound with the formula . It is a colorless chalcogen-hydride gas, and is poisonous, corrosive, and flammable, with trace amounts in ambient atmosphere having a characteristic foul odor of rotten eggs. The unde ...
,
methyl mercaptan Methanethiol (also known as methyl mercaptan) is an organosulfur compound with the chemical formula . It is a colorless gas with a distinctive putrid smell. It is a natural substance found in the blood, brain and feces of animals (including huma ...
,
dimethyl sulfide Dimethyl sulfide (DMS) or methylthiomethane is an organosulfur compound with the formula (CH3)2S. Dimethyl sulfide is a flammable liquid that boils at and has a characteristic disagreeable odor. It is a component of the smell produced from cook ...
,
dimethyl disulfide Dimethyl disulfide (DMDS) is an organic chemical compound with the molecular formula which is the simplest disulfide. It is a flammable liquid with an unpleasant, garlic-like odor. Occurrence Dimethyl disulfide is a widespread natural odoriferou ...
, and other volatile sulfur compounds are the cause of the odor characteristic of pulp mills utilizing the kraft process. Other chemicals that are released into the air and water from most paper mills include the following: *
carbon monoxide Carbon monoxide (chemical formula CO) is a colorless, poisonous, odorless, tasteless, flammable gas that is slightly less dense than air. Carbon monoxide consists of one carbon atom and one oxygen atom connected by a triple bond. It is the simple ...
*
ammonia Ammonia is an inorganic compound of nitrogen and hydrogen with the formula . A stable binary hydride, and the simplest pnictogen hydride, ammonia is a colourless gas with a distinct pungent smell. Biologically, it is a common nitrogenous was ...
*
nitrogen oxide Nitrogen oxide may refer to a binary compound of oxygen and nitrogen, or a mixture of such compounds: Charge-neutral *Nitric oxide (NO), nitrogen(II) oxide, or nitrogen monoxide *Nitrogen dioxide (), nitrogen(IV) oxide * Nitrogen trioxide (), or n ...
*
mercury Mercury commonly refers to: * Mercury (planet), the nearest planet to the Sun * Mercury (element), a metallic chemical element with the symbol Hg * Mercury (mythology), a Roman god Mercury or The Mercury may also refer to: Companies * Merc ...
*
nitrate Nitrate is a polyatomic ion A polyatomic ion, also known as a molecular ion, is a covalent bonded set of two or more atoms, or of a metal complex, that can be considered to behave as a single unit and that has a net charge that is not zer ...
s *
methanol Methanol (also called methyl alcohol and wood spirit, amongst other names) is an organic chemical and the simplest aliphatic alcohol, with the formula C H3 O H (a methyl group linked to a hydroxyl group, often abbreviated as MeOH). It is a ...
*
benzene Benzene is an organic chemical compound with the molecular formula C6H6. The benzene molecule is composed of six carbon atoms joined in a planar ring with one hydrogen atom attached to each. Because it contains only carbon and hydrogen atoms, ...
*
volatile organic compound Volatile organic compounds (VOCs) are organic compounds that have a high vapour pressure at room temperature. High vapor pressure correlates with a low boiling point, which relates to the number of the sample's molecules in the surrounding air, a ...
s,
chloroform Chloroform, or trichloromethane, is an organic compound with chemical formula, formula Carbon, CHydrogen, HChlorine, Cl3 and a common organic solvent. It is a colorless, strong-smelling, dense liquid produced on a large scale as a precursor to ...
. Bleaching mechanical pulp is not a major cause for environmental concern since most of the organic material is retained in the pulp, and the chemicals used (
hydrogen peroxide Hydrogen peroxide is a chemical compound with the formula . In its pure form, it is a very pale blue liquid that is slightly more viscous than water. It is used as an oxidizer, bleaching agent, and antiseptic, usually as a dilute solution (3% ...
and
sodium dithionite Sodium dithionite (also known as sodium hydrosulfite) is a white crystalline powder with a sulfurous odor. Although it is stable in dry air, it decomposes in hot water and in acid solutions. Structure The structure has been examined by Raman s ...
) produce benign byproducts (water and, eventually,
sodium sulfate Sodium sulfate (also known as sodium sulphate or sulfate of soda) is the inorganic compound with formula Na2SO4 as well as several related hydrates. All forms are white solids that are highly soluble in water. With an annual production of 6 milli ...
, respectively). However, the bleaching of chemical pulps has the potential to cause significant environmental damage, primarily through the release of organic materials into waterways. Pulp mills are almost always located near large bodies of water because they require substantial quantities of water for their processes. An increased public awareness of environmental issues from the 1970s and 1980s, as evidenced by the formation of organizations like
Greenpeace Greenpeace is an independent global campaigning network, founded in Canada in 1971 by Irving Stowe and Dorothy Stowe, immigrant environmental activists from the United States. Greenpeace states its goal is to "ensure the ability of the Earth t ...
, influenced the pulping industry and governments to address the release of these materials into the environment. Environmental NGO pressure was especially intense on Swedish and Finnish pulp and paper companies. Conventional bleaching using elemental chlorine produces and releases into the environment large amounts of chlorinated organic compounds, including chlorinated
dioxins Dioxin may refer to: * 1,2-Dioxin or 1,4-Dioxin, two unsaturated heterocyclic 6-membered rings where two carbon atoms have been replaced by oxygen atoms, giving the molecular formula C4H4O2 *Dibenzo-1,4-dioxin, the parent compound also known as ...
. Dioxins are recognized as a persistent environmental pollutant, regulated internationally by the
Stockholm Convention on Persistent Organic Pollutants Stockholm Convention on Persistent Organic Pollutants is an international environmental treaty, signed on 22 May 2001 in Stockholm and effective from 17 May 2004, that aims to eliminate or restrict the production and use of persistent organic ...
. Dioxins are highly toxic, and health effects on humans include reproductive, developmental, immune and hormonal problems. They are known to be carcinogenic. Over 90% of human exposure is through food, primarily meat, dairy, fish and shellfish, as dioxins accumulate in the food chain in the fatty tissue of animals.


Greenhouse gas emissions

Globally, 69% of
greenhouse gas emissions Greenhouse gas emissions from human activities strengthen the greenhouse effect, contributing to climate change. Most is carbon dioxide from burning fossil fuels: coal, oil, and natural gas. The largest emitters include coal in China and lar ...
come from the energy and transportation industries. The global print and paper industry accounts for about 1% of global carbon dioxide emissions. Greenhouse gas emissions from the pulp and paper industry are generated from the combustion of fossil fuels required for raw material production and transportation, wastewater treatment facilities, purchased power, paper transportation, printed product transportation, disposal and recycling. Disposing of paper in landfill sites, and subsequent breakdown and production of methane (a potent greenhouse gas) also adds to the carbon footprint of paper products. This is another reason why paper recycling is beneficial for the environment. Paper recovery, instead of landfilling can reduce the
global warming potential Global warming potential (GWP) is the heat absorbed by any greenhouse gas in the atmosphere, as a multiple of the heat that would be absorbed by the same mass of carbon dioxide (). GWP is 1 for . For other gases it depends on the gas and the time f ...
of paper products by 15 to 25%. At pulp and paper mills in the U.S., the GHG emission rate expressed in tons of carbon dioxide equivalents per ton of production has been reduced by 55.8% since 1972, 23.1% since 2000, and 3.9% compared to 2010. Between 2005 and 2012, U.S. pulp and paper mill purchased energy (from fossil fuels) use per ton of production has been reduced by 8.8%. In Canada, between 2000 and 2012, direct GHG emissions declined by 56% and total energy use by 30%. Some of this decline is due to the contraction of the forest industry but a large part is due to reduced use of fossil fuels and increased self-generation of power from renewable biomass. Bioenergy accounted for 56% of forest industry energy use in 2012, up from 49% in 2000.Natural Resources Canada. 2016. The State of Canada’s Forests. Annual Report 2015


Non-renewable resources

Clay or calcium carbonate are used as fillers for some papers.
Kaolin Kaolinite ( ) is a clay mineral, with the chemical composition Al2 Si2 O5( OH)4. It is an important industrial mineral. It is a layered silicate mineral, with one tetrahedral sheet of silica () linked through oxygen atoms to one octahedral ...
is the most commonly used clay for
coated paper Coated paper (also known as enamel paper, gloss paper, and thin paper) is paper that has been coated by a mixture of materials or a polymer to impart certain qualities to the paper, including weight, surface gloss, smoothness, or reduced ink absor ...
s.


Tree invasive species

Trees particularly suited for pulp production have been introduced in various regions worldwide. Some of those have now come to be recognized as aggressive
invasive species An invasive species otherwise known as an alien is an introduced organism that becomes overpopulated and harms its new environment. Although most introduced species are neutral or beneficial with respect to other species, invasive species ad ...
. In
Malaysia Malaysia ( ; ) is a country in Southeast Asia. The federation, federal constitutional monarchy consists of States and federal territories of Malaysia, thirteen states and three federal territories, separated by the South China Sea into two r ...
, the ''
Acacia auriculaeformis ''Acacia'', commonly known as the wattles or acacias, is a large genus of shrubs and trees in the subfamily Mimosoideae of the pea family Fabaceae. Initially, it comprised a group of plant species native to Africa and Australasia. The genus nam ...
'' and '' Acacia mangium'' are counted as invasive trees. The fast-growing and highly profitable
eucalyptus ''Eucalyptus'' () is a genus of over seven hundred species of flowering trees, shrubs or mallees in the myrtle family, Myrtaceae. Along with several other genera in the tribe Eucalypteae, including '' Corymbia'', they are commonly known as euca ...
must be regarded an invasive species in various part of the world.


Mitigation

Some of the environmental impacts of the pulp and paper industry have been addressed and there is movement towards sustainable practices. Using wood from plantation forests addresses concerns about loss of old growth forests.


Sustainable forest management

Cutting down trees to make forest products such as pulp and paper creates temporary or long-term environmental disturbances in forest habitats depending on how carefully the harvest is carried out. There might be impacts on plant and animal biodiversity, soil fertility and water quality. However, sustainable forest management practices are a way of using and caring for forests so as to maintain their environmental, social and economic values and benefits over time. In the U.S., increasing demand for responsibly produced paper provides a financial incentive for landowners to keep their land forested and manage it in a sustainable way - rather than selling it for industrial or housing developments, a primary cause of
deforestation Deforestation or forest clearance is the removal of a forest or stand of trees from land that is then converted to non-forest use. Deforestation can involve conversion of forest land to farms, ranches, or urban use. The most concentrated d ...
in the U.S., according to the U.S. Forest Service. This managed land, in turn, provides a host of continuing eco-system services, from clean water, healthy soil and climate change mitigation to recreational opportunities and aesthetic beauty. In Canada, sustainable forest management is supported by a forest management planning process; a science-based approach to decision-making, assessment and planning as well as by regulations and policies.


Forest certification

Promoting and supporting forest certification and the ability to trace the origin of wood fiber helps ensure sustainable forest management and legal logging. The forest certification systems that are currently the most used are: * The Program for the Endorsement of Forest Certification (PEFC), in most European countries as well as growing in other regions of the world. * The Sustainable Forestry Initiative (SFI), * The American Tree Farm System (ATFS) * Canadian Standards Association (CSA). * The Forest Stewardship Council (FSC).


Pulp bleaching

The move to non-elemental chlorine for the
bleaching Bleach is the generic name for any chemical product that is used industrially or domestically to remove color (whitening) from a fabric or fiber or to clean or to remove stains in a process called bleaching. It often refers specifically, to ...
process reduced the emission of the carcinogenic
organochlorines An organochloride, organochlorine compound, chlorocarbon, or chlorinated hydrocarbon is an organic compound containing at least one covalently bonded atom of chlorine. The chloroalkane class (alkanes with one or more hydrogens substituted by chlo ...
.
Peracetic acid Peracetic acid (also known as peroxyacetic acid, or PAA) is an organic compound with the formula CH3CO3H. This peroxy acid is a colorless liquid with a characteristic acrid odor reminiscent of acetic acid. It can be highly corrosive. Peracetic a ...
,
ozone Ozone (), or trioxygen, is an inorganic molecule with the chemical formula . It is a pale blue gas with a distinctively pungent smell. It is an allotrope of oxygen that is much less stable than the diatomic allotrope , breaking down in the lo ...
and
hydrogen peroxide Hydrogen peroxide is a chemical compound with the formula . In its pure form, it is a very pale blue liquid that is slightly more viscous than water. It is used as an oxidizer, bleaching agent, and antiseptic, usually as a dilute solution (3% ...
and
oxygen Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as wel ...
are used in bleaching sequences in the pulp industry to produce totally chlorine free (TCF) paper.


Recycling

There are three categories of paper that can be used as feedstocks for making recycled paper: mill broke, pre-consumer waste, and
post-consumer waste Post-consumer waste is a waste type produced by the end consumer of a material stream; that is, where the waste-producing use did not involve the production of another product. The terms of pre-consumer and post-consumer recycled materials are ...
. Mill broke is paper trimmings and other paper scrap from the manufacture of paper, and is recycled internally in a
paper mill A paper mill is a factory devoted to making paper from vegetable fibres such as wood pulp, old rags, and other ingredients. Prior to the invention and adoption of the Fourdrinier machine and other types of paper machine that use an endless belt, ...
. Pre-consumer waste is material that was discarded before it was ready for consumer use. Post-consumer waste is material discarded after consumer use such as old magazines, old telephone directories, and residential mixed paper. One concern about recycling
wood pulp Pulp is a lignocellulosic fibrous material prepared by chemically or mechanically separating cellulose fibers from wood, fiber crops, waste paper, or rags. Mixed with water and other chemical or plant-based additives, pulp is the major raw mate ...
paper is that the fibers are degraded with each and after being recycled four or five times the fibers become too short and weak to be useful in making paper. EPA has found that recycling causes 35% less water pollution and 74% less air pollution than making virgin paper.
Pulp mill A pulp mill is a manufacturing facility that converts wood chips or other plant fiber sources into a thick fiber board which can be shipped to a paper mill for further processing. Pulp can be manufactured using mechanical, semi-chemical, or ful ...
s can be sources of both air and water pollution, especially if they are producing bleached pulp. Recycling paper decreases the demand for virgin pulp and thus reduces the overall amount of air and water pollution associated with paper manufacture. Recycled pulp can be bleached with the same chemicals used to bleach virgin pulp, but
hydrogen peroxide Hydrogen peroxide is a chemical compound with the formula . In its pure form, it is a very pale blue liquid that is slightly more viscous than water. It is used as an oxidizer, bleaching agent, and antiseptic, usually as a dilute solution (3% ...
and
sodium hydrosulfite Sodium dithionite (also known as sodium hydrosulfite) is a white crystalline powder with a sulfurous odor. Although it is stable in dry air, it Chemical decomposition, decomposes in hot water and in acid Solution (chemistry), solutions. Structu ...
are the most common bleaching agents. Recycled pulp, or paper made from it, is known as PCF (process chlorine free) if no chlorine-containing compounds were used in the recycling process.


Recycled paper and paper mills

Recycling as an alternative to the use of landfills and recycled paper is one of the less complicated procedures in the recycling industry. Recycled Fiber Paper: Longevity Study." N.p., n.d. Web. 5 Nov. 2014./ref> Although there is not a landfill crisis at this point in time, it is commonly believed that measures should to be taken in order to lower the negative impacts of landfills, for many hazardous elements are produced and spread because of this enclosure of trash. Most recycled paper is priced higher than freshly made paper, and this tends to plays a deciding factor for the consumer. Because most of the recycled pulp is purchased in an open market, virgin paper is produced cheaper with the pulp that was made by the specific paper mill. Virgin paper contains no recycled content and is made directly from the pulp of trees or cotton. Materials recovered after the initial paper manufacturing process are considered recycled paper. Because that original standard was so vague, some “recycled papers” contained only mill scraps that would have been included in virgin paper anyway. Standards have recently been set to prevent companies from making it seem like they were selling recycled paper. The collection and recycling industries have fixated on the scraps of paper that is thrown away by customers daily in order to increase the amount of recycled paper. Different paper mills are structured for different types of paper, and most “recovered office paper can be sent to a deinking mill”. A deinking mill serves as a step in the recycling paper process. This type of mill detaches the ink from the paper fibers, along with any other excess materials which are also removed from the remaining paper. In the deinking mill, after all of the unwanted coatings of paper are stripped, the refurbished paper is sent to the paper machine. The old scraps are now constructed into new paper at the paper machine. Many papers mills have recycled business papers by transforming the old business papers into beneficial letters and envelopes. The production process for recycled paper is more costly than the well-developed paper mills that create paper with the use of trees. This process in making recycled paper is also much more time-consuming. However, recycled paper has a multitude of benefits from an environmental perspective. “For all the state-of-the-art technology now incorporated into modern paper mills, the industry's underlying structure is still based upon a worldview that was transformative in the 19th-century but is out-of-date as the 21st century approaches”.


Regulations

Pulp and paper is a heavily regulated industry in North America. U.S. and Canadian regulations are summarized below.


United States


= Air and water pollution

= EPA first issued national wastewater standards, known as
effluent guidelines Effluent Guidelines (also referred to as Effluent Limitation Guidelines (ELGs)) are U.S. national standards for wastewater discharges to surface waters and publicly owned treatment works (POTW) (also called municipal sewage treatment plants). The Un ...
, for pulp and paper mills in 1974, pursuant to the
Clean Water Act The Clean Water Act (CWA) is the primary federal law in the United States governing water pollution. Its objective is to restore and maintain the chemical, physical, and biological integrity of the nation's waters; recognizing the responsibiliti ...
. The agency established numeric limitations for several
conventional pollutant A conventional pollutant is a term used in the USA to describe a water pollutant that is amenable to treatment by a municipal sewage treatment plant. A basic list of conventional pollutants is defined in the U.S. Clean Water Act. The list has been ...
s. In 1982, EPA amended the regulations with numeric limitations for
pentachlorophenol Pentachlorophenol (PCP) is an organochlorine compound used as a pesticide and a disinfectant. First produced in the 1930s, it is marketed under many trade names. It can be found as pure PCP, or as the sodium salt of PCP, the latter of which diss ...
,
trichlorophenol A trichlorophenol is any organochloride of phenol that contains three covalently bonded chlorine atoms. Trichlorophenols are produced by electrophilic halogenation of phenol with chlorine. Different isomers of trichlorophenol exist according to whic ...
and
zinc Zinc is a chemical element with the symbol Zn and atomic number 30. Zinc is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodi ...
. Effluent limitations are implemented in
National Pollutant Discharge Elimination System The Clean Water Act (CWA) is the primary federal law in the United States governing water pollution. Its objective is to restore and maintain the chemical, physical, and biological integrity of the nation's waters; recognizing the responsibiliti ...
(NPDES) permits, which are renewed every five years. (''See''
United States regulation of point source water pollution Point source water pollution comes from discrete conveyances and alters the chemical, biological, and physical characteristics of water. In the United States, it is largely regulated by the Clean Water Act (CWA). Among other things, the Act requ ...
.) EPA's 1998 "Cluster Rule" (CR) addressed additional toxic wastewater pollutants, and regulated hazardous air pollutant emissions as well.EPA. "National Emission Standards for Hazardous Air Pollutants for Source Pulp and Paper Production; Effluent Limitations Guidelines, Pretreatment Standards, and New Source Performance Standards: Pulp, Paper, and Paperboard Category." ''Federal Register,'' , 1998-04-15. Because both air and water regulations were addressed in the same
rulemaking In administrative law, rulemaking is the process that executive and independent agencies use to create, or ''promulgate'', regulations. In general, legislatures first set broad policy mandates by passing statutes, then agencies create more deta ...
action, EPA made it possible for pulp and paper mills to select the best combination of air and water pollution prevention technologies rather than addressing one at a time. Some of the requirements and technologies were designed to reduce toxic air pollutants also reduced toxic wastewater pollutants and ''vice versa''. EPA's intent in promulgating the CR was to provide a coordinated set of regulatory requirements, thereby improving clarity for industry as it worked to achieve compliance, and achieving a greater level of pollution prevention. The air emission regulations in the CR, a component of the
National Emissions Standards for Hazardous Air Pollutants The National Emission Standards for Hazardous Air Pollutants (NESHAP) are air pollution standards issued by the United States Environmental Protection Agency (EPA). The standards, authorized by the Clean Air Act, are for pollutants not covered by ...
(NESHAP) under the Clean Air Act, became effective in 2001. The regulations, also known as "Maximum Achievable Control Technology" (MACT) regulations, apply to mills that use chemical pulping and call for hazardous air pollutants to be reduced by 59% and for volatile organic carbon and particulate matter to be reduced by 49% and 37%, respectively. The wastewater regulations in the CR apply to mills that combine chlorine bleaching with kraft chemical pulping and aim to reduce
dioxins Dioxin may refer to: * 1,2-Dioxin or 1,4-Dioxin, two unsaturated heterocyclic 6-membered rings where two carbon atoms have been replaced by oxygen atoms, giving the molecular formula C4H4O2 *Dibenzo-1,4-dioxin, the parent compound also known as ...
,
furan Furan is a heterocyclic organic compound, consisting of a five-membered aromatic ring with four carbon atoms and one oxygen atom. Chemical compounds containing such rings are also referred to as furans. Furan is a colorless, flammable, highly ...
, and
chloroform Chloroform, or trichloromethane, is an organic compound with chemical formula, formula Carbon, CHydrogen, HChlorine, Cl3 and a common organic solvent. It is a colorless, strong-smelling, dense liquid produced on a large scale as a precursor to ...
discharges by 96%, 96%, and 99%, respectively. EPA added numeric effluent limitations for 12 chlorinated phenolic pollutants and adsorbable organic halides (AOX). The regulation also requires the industry to implement
best management practices Best or The Best may refer to: People * Best (surname), people with the surname Best * Best (footballer, born 1968), retired Portuguese footballer Companies and organizations * Best & Co., an 1879–1971 clothing chain * Best Lock Corporation, ...
, such as
process control An industrial process control in continuous production processes is a discipline that uses industrial control systems to achieve a production level of consistency, economy and safety which could not be achieved purely by human manual control. I ...
monitoring. All air emissions in the U.S. are regulated at the federal level. The Clean Air Act establishes
National Ambient Air Quality Standards The U.S. National Ambient Air Quality Standards (NAAQS, pronounced ) are limits on atmospheric concentration of six pollutants that cause smog, acid rain, and other health hazards. Established by the United States Environmental Protection Agency ...
(NAAQS) for pollutants harmful to public health and the environment. Standards have been set for six principal pollutants:
lead Lead is a chemical element with the symbol Pb (from the Latin ) and atomic number 82. It is a heavy metal that is denser than most common materials. Lead is soft and malleable, and also has a relatively low melting point. When freshly cu ...
,
carbon monoxide Carbon monoxide (chemical formula CO) is a colorless, poisonous, odorless, tasteless, flammable gas that is slightly less dense than air. Carbon monoxide consists of one carbon atom and one oxygen atom connected by a triple bond. It is the simple ...
,
nitrogen dioxide Nitrogen dioxide is a chemical compound with the formula . It is one of several nitrogen oxides. is an intermediate in the industrial synthesis of nitric acid, millions of tons of which are produced each year for use primarily in the producti ...
(NO2),
ozone Ozone (), or trioxygen, is an inorganic molecule with the chemical formula . It is a pale blue gas with a distinctively pungent smell. It is an allotrope of oxygen that is much less stable than the diatomic allotrope , breaking down in the lo ...
(O3),
particulate matter Particulates – also known as atmospheric aerosol particles, atmospheric particulate matter, particulate matter (PM) or suspended particulate matter (SPM) – are microscopic particles of solid or liquid matter suspended in the air. The ter ...
(PM) and
sulfur dioxide Sulfur dioxide (IUPAC-recommended spelling) or sulphur dioxide (traditional Commonwealth English) is the chemical compound with the formula . It is a toxic gas responsible for the odor of burnt matches. It is released naturally by volcanic activ ...
(SO2). EPA revised the NESHAP regulations for the pulp and paper industry in 2012.


= Forest management

= Laws, regulations, and policies directing forest management on U.S. federal lands are well-documented. The
Lacey Act of 1900 The Lacey Act of 1900 is a conservation law in the United States that prohibits trade in wildlife, fish, and plants that have been illegally taken, possessed, transported, or sold.United States. Lacey Act (Game). , ch. 553. Approved May 25, 1900. ...
provides sanctions for
illegal logging Illegal logging is the harvest, transportation, purchase or sale of timber in violation of laws. The harvesting procedure itself may be illegal, including using corrupt means to gain access to forests; extraction without permission, or from a pro ...
.


Canada

In Canada, federal and provincial environmental law is the primary source of regulations for pulp and paper mills. The following three listed Federal regulations are related to emissions to water: # Pulp and Paper Effluent Regulations: sets standards for the level of acute lethality to fish, biochemical oxygen demand and total suspended solids. Mills are also required to conduct environmental effects monitoring to determine the impact of their effluents on receiving waters and investigate the causes of, and solutions for, environmental effects associated with mill effluent. # Pulp and Paper Mill Effluent Chlorinated Dioxins and Furans Regulations: issued under the Canadian Environmental Protection Act and applies to polychlorinated dibenzo-para-dioxins and polychlorinated dibenzofurans in mill effluents. # Pulp and Paper Mill Defoamer and Wood Chip Regulation: regulates use of defoamers containing dibenzofuran or dibenzo-para-dioxin at pulp and paper mills using a chlorine bleaching process. There are also regulations in place to control the releases of contaminants into the air, including particulate matter and ground-level ozone and these include the Canadian Ambient Air Quality Standards Regulations. At the federal level, Environment and Climate Change Canada (ECCC) has a legislated, publicly accessible inventory of pollutant releases to air, water and land, as well as disposals and recycling, namely the National Pollutant Release Inventory, which companies are required to report each year. Operators of facilities that meet the reporting criteria are required to report facility greenhouse gas (GHG) emissions to ECCC each year. Some provinces have their own regulatory frameworks to manage air quality such as the Ontario provincial standards, as well as to control GHG emissions including the British Columbia Carbon Tax, Alberta Climate Leadership Plan, and the Ontario and Quebec Cap and Trade Systems. In Canada, where 94% of the country's forests are on public land, a framework of federal, provincial and territorial laws, regulations and policies enforces and guides sustainable forest management practices.


International

“The Environmental, Health, and Safety (EHS) Guidelines are technical reference documents with general and industry specific examples of Good International Industry Practice (GIIP).” In simpler terms, the EHS is what helps develop the federal regulations on industries and companies that require factories that have the potential to cause a great amount of harm to society and the environment. These Guidelines for the
environment, health and safety Environment (E), health (H) and safety (S), EHS is an acronym for the set that studies and implements the practical aspects of protecting the environment and maintaining health and safety at occupation. In simple terms it is what organizations must ...
list out the specific rules for the paper mill industries that explains what they need to follow in order to limit the pollution that is consequently distributed and by the mills.


Mechanical pulp mills

Wood pulp Pulp is a lignocellulosic fibrous material prepared by chemically or mechanically separating cellulose fibers from wood, fiber crops, waste paper, or rags. Mixed with water and other chemical or plant-based additives, pulp is the major raw mate ...
produced primarily by grinding wood is known as "mechanical pulp" and is used mainly for
newsprint Newsprint is a low-cost, non-archival paper consisting mainly of wood pulp and most commonly used to print newspapers and other publications and advertising material. Invented in 1844 by Charles Fenerty of Nova Scotia, Canada, it usually has an ...
. These mechanical processes use fewer chemicals than either kraft or sulfite mills. The primary source of pollution from these mills is organic material such as resin acids released from the wood when it is processed. Mechanical wood pulp is " brightened," as opposed to bleached, using less toxic chemicals than are needed for chemical pulps.


Inks

Three main issues with the environmental impact of printing
ink Ink is a gel, sol, or solution that contains at least one colorant, such as a dye or pigment, and is used to color a surface to produce an image, text, or design. Ink is used for drawing or writing with a pen, brush, reed pen, or quill. Thicker ...
s is the use of
volatile organic compound Volatile organic compounds (VOCs) are organic compounds that have a high vapour pressure at room temperature. High vapor pressure correlates with a low boiling point, which relates to the number of the sample's molecules in the surrounding air, a ...
s,
heavy metals upright=1.2, Crystals of osmium, a heavy metal nearly twice as dense as lead">lead.html" ;"title="osmium, a heavy metal nearly twice as dense as lead">osmium, a heavy metal nearly twice as dense as lead Heavy metals are generally defined as ...
and non-renewable oils. Standards for the amount of heavy metals in ink have been set by some regulatory bodies. There is a trend toward using
vegetable oil Vegetable oils, or vegetable fats, are oils extracted from seeds or from other parts of fruits. Like animal fats, vegetable fats are ''mixtures'' of triglycerides. Soybean oil, grape seed oil, and cocoa butter are examples of seed oils, or fat ...
s rather than
petroleum oil Mineral oil is any of various colorless, odorless, light mixtures of higher alkanes from a mineral source, particularly a distillate of petroleum, as distinct from usually edible vegetable oils. The name 'mineral oil' by itself is imprecise, ...
s in recent years due to a demand for better
sustainability Specific definitions of sustainability are difficult to agree on and have varied in the literature and over time. The concept of sustainability can be used to guide decisions at the global, national, and individual levels (e.g. sustainable livi ...
.
Deinking Deinking is the industrial process of removing printing ink from paperfibers of recycled paper to make deinked pulp. The key in the deinking process is the ability to detach ink from the fibers. This is achieved by a combination of mechanical ac ...
recycled paper pulp results in a waste slurry which may go to
landfill A landfill site, also known as a tip, dump, rubbish dump, garbage dump, or dumping ground, is a site for the disposal of waste materials. Landfill is the oldest and most common form of waste disposal, although the systematic burial of the waste ...
. De-inking at Cross Pointe's Miami, Ohio mill in the United States results in sludge weighing 22% of the weight of wastepaper recycled. In the 1970s federal regulations for inks in the United States governed the use of toxic metals such as lead, arsenic, selenium, mercury, cadmium and hexavalent chromium.


See also

*
Totally chlorine free Bleaching of wood pulp is the chemical processing of wood pulp to lighten its color and whiten the pulp. The primary product of wood pulp is paper, for which whiteness (similar to, but distinct from brightness) is an important characteristic. These ...
paper *
Elemental chlorine free Elemental chlorine free (ECF) is a technique that uses chlorine dioxide for the bleaching of wood pulp. It does not use elemental chlorine gas during the bleaching process and prevents the formation of dioxins and dioxin-like compounds, carcinogens ...
paper *
List of environmental issues This is an alphabetical list of environmental issues, harmful aspects of human activity on the biophysical environment. They are loosely divided into causes, effects and mitigation, noting that effects are interconnected and can cause new effects. ...
*
Life cycle assessment Life cycle assessment or LCA (also known as life cycle analysis) is a methodology for assessing environmental impacts associated with all the stages of the life cycle of a commercial product, process, or service. For instance, in the case of ...
* Pollution of the Tarawera River * Pollution of the Fox River * Stone paper * Tissue paper#Sustainability * Toilet paper#Environmental considerations


References


Further reading

Case Studies * Laplante, Benoît and Rilstone, Paul
Environmental Inspections and Emissions of the Pulp and Paper Industry: The Case of Quebec
April 1995, World Bank Policy Research Working Paper No. 1447. Industry Profile * World Bank Group
Pulp and Paper Mill
Pollution Prevention and Abatement Handbook, July 1998. * United States Environmental Protection Agency
Profile of the Pulp and Paper Industry 2nd Edition
November 2002. Life Cycle Assessment * Forest Products Association of Canada
Life Cycle Assessment and Forest Products:A White Paper
September 2010 New Technologies * United States Environmental Protection Agency
Available and Emerging Technologies for Reducing Greenhouse Gas Emissions from the Pulp and Paper Manufacturing Industry
Office of Air and Radiation, October 2010.


External links


Canopy , Ecopaper Database
{{Authority control Deforestation Paper recycling