In
quantum mechanics
Quantum mechanics is a fundamental theory in physics that provides a description of the physical properties of nature at the scale of atoms and subatomic particles. It is the foundation of all quantum physics including quantum chemistry, ...
and
quantum field theory
In theoretical physics, quantum field theory (QFT) is a theoretical framework that combines classical field theory, special relativity, and quantum mechanics. QFT is used in particle physics to construct physical models of subatomic particles and ...
, the propagator is a function that specifies the
probability amplitude
In quantum mechanics, a probability amplitude is a complex number used for describing the behaviour of systems. The modulus squared of this quantity represents a probability density.
Probability amplitudes provide a relationship between the quan ...
for a particle to travel from one place to another in a given period of time, or to travel with a certain energy and momentum. In
Feynman diagram
In theoretical physics, a Feynman diagram is a pictorial representation of the mathematical expressions describing the behavior and interaction of subatomic particles. The scheme is named after American physicist Richard Feynman, who introduc ...
s, which serve to calculate the rate of collisions in
quantum field theory
In theoretical physics, quantum field theory (QFT) is a theoretical framework that combines classical field theory, special relativity, and quantum mechanics. QFT is used in particle physics to construct physical models of subatomic particles and ...
,
virtual particle
A virtual particle is a theoretical transient particle that exhibits some of the characteristics of an ordinary particle, while having its existence limited by the uncertainty principle. The concept of virtual particles arises in the perturbat ...
s contribute their propagator to the rate of the
scattering
Scattering is a term used in physics to describe a wide range of physical processes where moving particles or radiation of some form, such as light or sound, are forced to deviate from a straight trajectory by localized non-uniformities (including ...
event described by the respective diagram. These may also be viewed as the
inverse of the
wave operator
In special relativity, electromagnetism and wave theory, the d'Alembert operator (denoted by a box: \Box), also called the d'Alembertian, wave operator, box operator or sometimes quabla operator (''cf''. nabla symbol) is the Laplace operator of Mi ...
appropriate to the particle, and are, therefore, often called ''(causal)
Green's functions
In mathematics, a Green's function is the impulse response of an inhomogeneous linear differential operator defined on a domain with specified initial conditions or boundary conditions.
This means that if \operatorname is the linear differential ...
'' (called "''causal''" to distinguish it from the elliptic Laplacian Green's function).
Non-relativistic propagators
In non-relativistic quantum mechanics, the propagator gives the probability amplitude for a
particle
In the Outline of physical science, physical sciences, a particle (or corpuscule in older texts) is a small wikt:local, localized physical body, object which can be described by several physical property, physical or chemical property, chemical ...
to travel from one spatial point (x') at one time (t') to another spatial point (x) at a later time (t).
Consider a system with
Hamiltonian
Hamiltonian may refer to:
* Hamiltonian mechanics, a function that represents the total energy of a system
* Hamiltonian (quantum mechanics), an operator corresponding to the total energy of that system
** Dyall Hamiltonian, a modified Hamiltonian ...
. The
Green's function
In mathematics, a Green's function is the impulse response of an inhomogeneous linear differential operator defined on a domain with specified initial conditions or boundary conditions.
This means that if \operatorname is the linear differential ...
(
fundamental solution
In mathematics, a fundamental solution for a linear partial differential operator is a formulation in the language of distribution theory of the older idea of a Green's function (although unlike Green's functions, fundamental solutions do not ad ...
) for the
Schrödinger equation
The Schrödinger equation is a linear partial differential equation that governs the wave function of a quantum-mechanical system. It is a key result in quantum mechanics, and its discovery was a significant landmark in the development of the ...
is a function
:
satisfying
:
where denotes the Hamiltonian written in terms of the coordinates, denotes the
Dirac delta-function
In mathematics, the Dirac delta distribution ( distribution), also known as the unit impulse, is a generalized function or distribution over the real numbers, whose value is zero everywhere except at zero, and whose integral over the entire ...
, is the
Heaviside step function
The Heaviside step function, or the unit step function, usually denoted by or (but sometimes , or ), is a step function, named after Oliver Heaviside (1850–1925), the value of which is zero for negative arguments and one for positive argume ...
and is the
kernel
Kernel may refer to:
Computing
* Kernel (operating system), the central component of most operating systems
* Kernel (image processing), a matrix used for image convolution
* Compute kernel, in GPGPU programming
* Kernel method, in machine learnin ...
of the above Schrödinger differential operator in the big parentheses. The term ''propagator'' is sometimes used in this context to refer to , and sometimes to . This article will use the term to refer to (see
Duhamel's principle In mathematics, and more specifically in partial differential equations, Duhamel's principle is a general method for obtaining solutions to homogeneous differential equation, inhomogeneous linear evolution equations like the heat equation, wave equa ...
).
This propagator may also be written as the transition amplitude
:
where is the
unitary
Unitary may refer to:
Mathematics
* Unitary divisor
* Unitary element
* Unitary group
* Unitary matrix
* Unitary morphism
* Unitary operator
* Unitary transformation
* Unitary representation
* Unitarity (physics)
* ''E''-unitary inverse semigrou ...
time-evolution operator for the system taking states at time to states at time . Note the initial condition enforced by
.
The quantum-mechanical propagator may also be found by using a
path integral:
:
where the boundary conditions of the path integral include . Here denotes the
Lagrangian
Lagrangian may refer to:
Mathematics
* Lagrangian function, used to solve constrained minimization problems in optimization theory; see Lagrange multiplier
** Lagrangian relaxation, the method of approximating a difficult constrained problem with ...
of the system. The paths that are summed over move only forwards in time and are integrated with the differential