polymer
A polymer () is a chemical substance, substance or material that consists of very large molecules, or macromolecules, that are constituted by many repeat unit, repeating subunits derived from one or more species of monomers. Due to their br ...
ized form of
water
Water is an inorganic compound with the chemical formula . It is a transparent, tasteless, odorless, and Color of water, nearly colorless chemical substance. It is the main constituent of Earth's hydrosphere and the fluids of all known liv ...
that was the subject of much scientific controversy during the late 1960s, first described by Soviet scientist Nikolai Fedyakin. By 1969 the popular press had taken notice of Western attempts to recreate the substance and sparked fears of a "polywater gap" between the United States and Soviet Union. Increased press attention also brought with it increased scientific attention, and as early as 1970 doubts about its authenticity were being circulated. By 1973 it was found to be illusory, being just water with any number of common compounds contaminating it. Today, polywater is best known as an example of pathological science.
Background
In 1961, the
Soviet
The Union of Soviet Socialist Republics. (USSR), commonly known as the Soviet Union, was a List of former transcontinental countries#Since 1700, transcontinental country that spanned much of Eurasia from 1922 until Dissolution of the Soviet ...
physicist Nikolai Fedyakin, working at the Technological Institute of Kostroma,
Russia
Russia, or the Russian Federation, is a country spanning Eastern Europe and North Asia. It is the list of countries and dependencies by area, largest country in the world, and extends across Time in Russia, eleven time zones, sharing Borders ...
, performed measurements on the properties of water which had been condensed in, or repeatedly forced through, narrow quartz capillary tubes. Some of these experiments resulted in what was seemingly a new form of water with a higher boiling point, lower freezing point, and much higher
viscosity
Viscosity is a measure of a fluid's rate-dependent drag (physics), resistance to a change in shape or to movement of its neighboring portions relative to one another. For liquids, it corresponds to the informal concept of ''thickness''; for e ...
than ordinary water – about that of a
syrup
In cooking, syrup (less commonly sirup; from ; , beverage, wine and ) is a condiment that is a thick, viscous liquid consisting primarily of a Solution (chemistry), solution of sugar in water, containing a large amount of dissolved sugars but ...
.
Boris Derjaguin, director of the laboratory for surface physics at the Institute for Physical Chemistry in
Moscow
Moscow is the Capital city, capital and List of cities and towns in Russia by population, largest city of Russia, standing on the Moskva (river), Moskva River in Central Russia. It has a population estimated at over 13 million residents with ...
, heard about Fedyakin's experiments. He improved on the method to produce the new water, and though he still produced very small quantities of this mysterious material, he did so substantially faster than Fedyakin did. Investigations of the material properties showed a substantially lower freezing point of −40 °C or less, a boiling point of 150 °C or greater, a density of approx. 1.1 to 1.2 g/cm3, and increased expansion with increasing temperature. The results were published in Soviet science journals, and short summaries were published in ''Chemical Abstracts'' in English, but Western scientists took no notice of the work.
In 1966, Derjaguin travelled to England for the "Discussions of the Faraday Society" in
Nottingham
Nottingham ( , East Midlands English, locally ) is a City status in the United Kingdom, city and Unitary authorities of England, unitary authority area in Nottinghamshire, East Midlands, England. It is located south-east of Sheffield and nor ...
. There, he presented the work again, and this time English scientists took note of what he referred to as ''anomalous water''. English scientists then started researching the effect as well, and by 1968 it was also under study in the United States.
By 1969, the concept had spread to
newspapers
A newspaper is a Periodical literature, periodical publication containing written News, information about current events and is often typed in black ink with a white or gray background. Newspapers can cover a wide variety of fields such as poli ...
and
magazines
A magazine is a periodical literature, periodical publication, print or digital, produced on a regular schedule, that contains any of a variety of subject-oriented textual and visual content (media), content forms. Magazines are generally fin ...
. There was fear by the
United States military
The United States Armed Forces are the Military, military forces of the United States. U.S. United States Code, federal law names six armed forces: the United States Army, Army, United States Marine Corps, Marine Corps, United States Navy, Na ...
that there was a so-called "polywater gap" with the
Soviet Union
The Union of Soviet Socialist Republics. (USSR), commonly known as the Soviet Union, was a List of former transcontinental countries#Since 1700, transcontinental country that spanned much of Eurasia from 1922 until Dissolution of the Soviet ...
, a popular media term indicating a possible capability "gap", or discrepancy, between the US and the USSR, popularized by media hype of the " bomber gap" and the " missile gap", during periods when the USSR appeared to be outstripping the US in numbers of these various weapons.
A scientific furore followed. Some experiments carried out were able to reproduce Derjaguin's findings, while others failed. Several theories were advanced to explain the phenomenon. Some proposed it was the cause for increasing resistance on trans-Atlantic phone cables, while others predicted that if polywater were to contact ordinary water, it would convert that water into polywater, echoing the doomsday scenario in
Kurt Vonnegut
Kurt Vonnegut ( ; November 11, 1922 – April 11, 2007) was an American author known for his Satire, satirical and darkly humorous novels. His published work includes fourteen novels, three short-story collections, five plays, and five nonfict ...
's novel ''
Cat's Cradle
''Cat's Cradle'' is a satirical postmodern novel, with science fiction elements, by American writer Kurt Vonnegut. Vonnegut's fourth novel, it was first published on March 18, 1963, exploring and satirizing issues of science, technology, the p ...
''. By the 1970s, polywater was well known in the general population.
During this time, several people questioned the authenticity of what had come to be known in the West as polywater. The main concern was contamination of the water, but the papers went to great lengths to note the care taken to avoid this.
Denis Rousseau
Denis L. Rousseau (signing papers as D. L. Rousseau) is an American scientist. He is currently professor and university chairman of the department of physiology and biophysics at Albert Einstein College of Medicine.Sergio Porto of
Bell Labs
Nokia Bell Labs, commonly referred to as ''Bell Labs'', is an American industrial research and development company owned by Finnish technology company Nokia. With headquarters located in Murray Hill, New Jersey, Murray Hill, New Jersey, the compa ...
carried out infrared spectrum analysis, which showed polywater to be mostly chlorine and sodium.
Denis Rousseau
Denis L. Rousseau (signing papers as D. L. Rousseau) is an American scientist. He is currently professor and university chairman of the department of physiology and biophysics at Albert Einstein College of Medicine.sweat
Perspiration, also known as sweat, is the fluid secreted by sweat glands in the skin of mammals.
Two types of sweat glands can be found in humans: eccrine glands and Apocrine sweat gland, apocrine glands. The eccrine sweat glands are distribu ...
after playing a
handball
Handball (also known as team handball, European handball, Olympic handball or indoor handball) is a team sport in which two teams of seven players each (six outcourt players and a goalkeeper) pass a ball using their hands with the aim of thr ...
game at the lab and found it had identical properties. He then published a paper suggesting polywater was nothing more than water with small amounts of biological impurities.
Another wave of research followed, this time more tightly controlled. Invariably, polywater could no longer be made. Chemical analysis found the samples of polywater to be contaminated with other substances (explaining the changes in melting and boiling points due to
colligative properties
In chemistry, colligative properties are those properties of solutions that depend on the ratio of the number of solute particles to the number of solvent particles in a solution, and not on the nature of the chemical species present. The numb ...
), and examination of polywater by
electron microscopy
An electron microscope is a microscope that uses a beam of electrons as a source of illumination. It uses electron optics that are analogous to the glass lenses of an optical light microscope to control the electron beam, for instance focusing i ...
showed it also contained small particles of various solids – from silica to
phospholipid
Phospholipids are a class of lipids whose molecule has a hydrophilic "head" containing a phosphate group and two hydrophobic "tails" derived from fatty acids, joined by an alcohol residue (usually a glycerol molecule). Marine phospholipids typ ...
s, explaining its greater viscosity.
When the experiments which had initially produced polywater were repeated with thoroughly cleaned
glassware
upTypical drinkware.
This list of glassware includes drinking vessels (drinkware), tableware used to set a table for eating a meal and generally glass items such as vases, and glasses used in the catering industry. It does not include laboratory ...
, the anomalous properties of the resulting water vanished, and even the scientists who had originally advanced the case for polywater agreed it did not exist.
In August 1973, Derjaguin and N. V. Churaev published a letter in the journal ''
Nature
Nature is an inherent character or constitution, particularly of the Ecosphere (planetary), ecosphere or the universe as a whole. In this general sense nature refers to the Scientific law, laws, elements and phenomenon, phenomena of the physic ...
'' in which they wrote; "these nomalousproperties should be attributed to impurities rather than to the existence of polymeric water molecules".
Denis Rousseau
Denis L. Rousseau (signing papers as D. L. Rousseau) is an American scientist. He is currently professor and university chairman of the department of physiology and biophysics at Albert Einstein College of Medicine.pathological science and has since written on other examples as well.
It has been suggested that polywater should have been dismissed on theoretical grounds. The laws of thermodynamics predicted that, since polywater had a higher boiling point than ordinary water, it meant it was more stable, and thus all of Earth's water should have turned spontaneously into polywater, instead of just part of it.
Richard Feynman
Richard Phillips Feynman (; May 11, 1918 – February 15, 1988) was an American theoretical physicist. He is best known for his work in the path integral formulation of quantum mechanics, the theory of quantum electrodynamics, the physics of t ...
remarked that if such a material existed, then an animal would exist that would ingest water and excrete polywater, using the energy released from the process to survive. The above paper cites this review from Eisenberg:
Star Trek
''Star Trek'' is an American science fiction media franchise created by Gene Roddenberry, which began with the Star Trek: The Original Series, series of the same name and became a worldwide Popular culture, pop-culture Cultural influence of ...
'', 1966) and its sequel, " The Naked Now" ('' Star Trek: The Next Generation'', 1987) involve forms of polywater intoxication. In the original episode, a scientific research outpost falls victim to polywater, which causes the crew to become so incapacitated that they all died after shutting off environmental controls in the compound. In the sequel, a Starfleet vessel is discovered adrift, its crew frozen in various states due to polywater intoxication. The '' Star Trek: Lower Decks'' episode " I, Excretus" briefly features a simulated version of the USS ''Cerritos'' plagued by polywater intoxication, leading to a shipwide orgy, as part of a holodeck drill. Beckett Mariner attempts the simulation, but is unable to stomach the scenario and chooses to eject herself from an airlock.
The story "Polywater Doodle" by Howard L. Myers appeared in the February 1971 issue of ''
Analog Science Fiction and Fact
''Analog Science Fiction and Fact'' is an American science fiction magazine published under various titles since 1930. Originally titled ''Astounding Stories of Super-Science'', the first issue was dated January 1930, published by William Cla ...
''. It features an animal composed entirely of polywater, with the metabolism described by Richard Feynman. (The title of the story is a pun on " Polly Wolly Doodle".)
Polywater is the central idea of the 1972 espionage/thriller novel ''
A Report from Group 17
''A Report from Group 17'', published in 1972,O'Sullivan, EmerHistorical Dictionary of Children's Literature Lanham, Maryland: Scarecrow Press, 2010. is a science-fiction Thriller (genre), thriller written by Robert Leslie Conly under his pen ...
'' by Robert C. O'Brien. The story revolves around the use of a type of polywater to make people controllable and incapable of independent thought or action.
Business
There is a company named American Polywater Corporation, which is unrelated to the hypothesized form of water. The company is based in Stillwater, Minnesota.
ice-nine
Ice-nine is a fictional material that appears in Kurt Vonnegut's 1963 novel ''Cat's Cradle''. Ice-nine is described as a Polymorphism (materials science), polymorph of ice which instead of melting at 0 °C (32 °F), melts at 45.8 � ...
References
Further reading
*
*
*Franks, F., ''Polywater''
MIT Press
The MIT Press is the university press of the Massachusetts Institute of Technology (MIT), a private research university in Cambridge, Massachusetts. The MIT Press publishes a number of academic journals and has been a pioneer in the Open Ac ...