rocks
In geology, rock (or stone) is any naturally occurring solid mass or aggregate of minerals or mineraloid matter. It is categorized by the minerals included, its chemical composition, and the way in which it is formed. Rocks form the Earth's ...
,
soil
Soil, also commonly referred to as earth or dirt, is a mixture of organic matter, minerals, gases, liquids, and organisms that together support life. Some scientific definitions distinguish ''dirt'' from ''soil'' by restricting the former te ...
s and
mineral
In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. ( ...
s as well as
wood
Wood is a porous and fibrous structural tissue found in the stems and roots of trees and other woody plants. It is an organic materiala natural composite of cellulose fibers that are strong in tension and embedded in a matrix of lignin th ...
and artificial materials through contact with water,
atmospheric gases
The atmosphere of Earth is the layer of gases, known collectively as air, retained by Earth's gravity that surrounds the planet and forms its planetary atmosphere. The atmosphere of Earth protects life on Earth by creating pressure allowing for ...
, and biological organisms. Weathering occurs ''
in situ
''In situ'' (; often not italicized in English) is a Latin phrase that translates literally to "on site" or "in position." It can mean "locally", "on site", "on the premises", or "in place" to describe where an event takes place and is used in ...
'' (on site, with little or no movement), and so is distinct from
erosion
Erosion is the action of surface processes (such as water flow or wind) that removes soil, rock, or dissolved material from one location on the Earth's crust, and then transports it to another location where it is deposited. Erosion is distin ...
, which involves the transport of rocks and minerals by agents such as
water
Water (chemical formula ) is an inorganic, transparent, tasteless, odorless, and nearly colorless chemical substance, which is the main constituent of Earth's hydrosphere and the fluids of all known living organisms (in which it acts as a ...
,
ice
Ice is water frozen into a solid state, typically forming at or below temperatures of 0 degrees Celsius or Depending on the presence of impurities such as particles of soil or bubbles of air, it can appear transparent or a more or less opaq ...
,
snow
Snow comprises individual ice crystals that grow while suspended in the atmosphere—usually within clouds—and then fall, accumulating on the ground where they undergo further changes.
It consists of frozen crystalline water throughout ...
,
wind
Wind is the natural movement of air or other gases relative to a planet's surface. Winds occur on a range of scales, from thunderstorm flows lasting tens of minutes, to local breezes generated by heating of land surfaces and lasting a few hou ...
,
waves
Waves most often refers to:
*Waves, oscillations accompanied by a transfer of energy that travel through space or mass.
* Wind waves, surface waves that occur on the free surface of bodies of water.
Waves may also refer to:
Music
* Waves (ban ...
and
gravity
In physics, gravity () is a fundamental interaction which causes mutual attraction between all things with mass or energy. Gravity is, by far, the weakest of the four fundamental interactions, approximately 1038 times weaker than the stro ...
.
Weathering processes are divided into ''physical'' and ''chemical weathering''. Physical weathering involves the breakdown of rocks and soils through the mechanical effects of heat, water, ice, or other agents. Chemical weathering involves the chemical reaction of water, atmospheric gases, and biologically produced chemicals with rocks and soils. Water is the principal agent behind both physical and chemical weathering, though atmospheric oxygen and carbon dioxide and the activities of biological organisms are also important. Chemical weathering by biological action is also known as biological weathering.
The materials left over after the rock breaks down combine with organic material to create
soil
Soil, also commonly referred to as earth or dirt, is a mixture of organic matter, minerals, gases, liquids, and organisms that together support life. Some scientific definitions distinguish ''dirt'' from ''soil'' by restricting the former te ...
. Many of Earth's
landform
A landform is a natural or anthropogenic land feature on the solid surface of the Earth or other planetary body. Landforms together make up a given terrain, and their arrangement in the landscape is known as topography. Landforms include hills, ...
s and landscapes are the result of weathering processes combined with erosion and re-deposition. Weathering is a crucial part of the
rock cycle
The rock cycle is a basic concept in geology that describes transitions through geologic time among the three main rock types: sedimentary, metamorphic, and igneous. Each rock type is altered when it is forced out of its equilibrium conditio ...
, and
sedimentary rock
Sedimentary rocks are types of rock that are formed by the accumulation or deposition of mineral or organic particles at Earth's surface, followed by cementation. Sedimentation is the collective name for processes that cause these particles ...
, formed from the weathering products of older rock, covers 66% of the
Earth's continents
A continent is any of several large landmasses. Generally identified by convention rather than any strict criteria, up to seven geographical regions are commonly regarded as continents. Ordered from largest in area to smallest, these seven ...
and much of its
ocean floor
The seabed (also known as the seafloor, sea floor, ocean floor, and ocean bottom) is the bottom of the ocean. All floors of the ocean are known as 'seabeds'.
The structure of the seabed of the global ocean is governed by plate tectonics. Most of ...
.
Physical weathering
Physical weathering, also called mechanical weathering or ''disaggregation'', is the class of processes that causes the disintegration of rocks without chemical change.Physical weathering involves the breakdown of rocks into smaller fragments through processes such as expansion and contraction, mainly due to temperature changes. Two types of physical breakdown are freeze-thaw weathering and thermal fracturing. Pressure release can also cause weathering without temperature change. It is usually much less important than chemical weathering, but can be significant in subarctic or alpine environments. Furthermore, chemical and physical weathering often go hand in hand. For example, cracks extended by physical weathering will increase the surface area exposed to chemical action, thus amplifying the rate of disintegration.
Frost weathering is the most important form of physical weathering. Next in importance is wedging by plant roots, which sometimes enter cracks in rocks and pry them apart. The burrowing of worms or other animals may also help disintegrate rock, as can "plucking" by lichens.
Frost weathering
''Frost weathering'' is the collective name for those forms of physical weathering that are caused by the formation of ice within rock outcrops. It was long believed that the most important of these is ''frost wedging'', which results from the expansion of pore water when it freezes. However, a growing body of theoretical and experimental work suggests that ''ice segregation'', in which supercooled water migrates to lenses of ice forming within the rock, is the more important mechanism.
When water freezes, its volume increases by 9.2%. This expansion can theoretically generate pressures greater that , though a more realistic upper limit is . This is still much greater than the tensile strength of granite, which is about . This makes frost wedging, in which pore water freezes and its volumetric expansion fractures the enclosing rock, appear to be a plausible mechanism for frost weathering. However, ice will simply expand out of a straight, open fracture before it can generate significant pressure. Thus frost wedging can only take place in small, tortuous fractures. The rock must also be almost completely saturated with water, or the ice will simply expand into the air spaces in the unsaturated rock without generating much pressure. These conditions are unusual enough that frost wedging is unlikely to be the dominant process of frost weathering. Frost wedging is most effective where there are daily cycles of melting and freezing of water-saturated rock, so it is unlikely to be significant in the tropics, in polar regions or in arid climates.
Ice segregation is a less well characterized mechanism of physical weathering. It takes place because ice grains always have a surface layer, often just a few molecules thick, that resembles liquid water more than solid ice, even at temperatures well below the freezing point. This ''premelted liquid layer'' has unusual properties, including a strong tendency to draw in water by
capillary action
Capillary action (sometimes called capillarity, capillary motion, capillary rise, capillary effect, or wicking) is the process of a liquid flowing in a narrow space without the assistance of, or even in opposition to, any external forces li ...
from warmer parts of the rock. This results in growth of the ice grain that puts considerable pressure on the surrounding rock, up to ten times greater than is likely with frost wedging. This mechanism is most effective in rock whose temperature averages just below the freezing point, . Ice segregation results in growth of ice needles and
ice lens
Ice lenses are bodies of ice formed when moisture, diffused within soil or rock, accumulates in a localized zone. The ice initially accumulates within small collocated pores or pre-existing crack, and, as long as the conditions remain favorable, ...
es within fractures in the rock and parallel to the rock surface, that gradually pry the rock apart.
Thermal stress
''Thermal stress weathering'' results from the expansion and contraction of rock due to temperature changes. Thermal stress weathering is most effective when the heated portion of the rock is buttressed by surrounding rock, so that it is free to expand in only one direction.
Thermal stress weathering comprises two main types,
thermal shock
Thermal shock is a type of rapidly transient mechanical load.
By definition, it is a mechanical load caused by a rapid change of temperature of a certain point.
It can be also extended to the case of a thermal gradient, which makes different par ...
and
thermal fatigue Thermo-mechanical fatigue (short TMF) is the overlay of a cyclical mechanical loading, that leads to fatigue of a material, with a cyclical thermal loading. Thermo-mechanical fatigue is an important point that needs to be considered, when constructi ...
. Thermal shock takes place when the stresses are so great that the rock cracks immediately, but this is uncommon. More typical is thermal fatigue, in which the stresses are not great enough to cause immediate rock failure, but repeated cycles of stress and release gradually weaken the rock.
Thermal stress weathering is an important mechanism in
deserts
A desert is a barren area of landscape where little precipitation occurs and, consequently, living conditions are hostile for plant and animal life. The lack of vegetation exposes the unprotected surface of the ground to denudation. About one ...
, where there is a large diurnal temperature range, hot in the day and cold at night. As a result, thermal stress weathering is sometimes called insolation weathering, but this is misleading. Thermal stress weathering can be caused by any large change of temperature, and not just intense solar heating. It is likely as important in cold climates as in hot, arid climates. Wildfires can also be a significant cause of rapid thermal stress weathering.
The importance of thermal stress weathering has long been discounted by geologists, based on experiments in the early 20th century that seemed to show that its effects were unimportant. These experiments have since been criticized as unrealistic, since the rock samples were small, were polished (which reduces nucleation of fractures), and were not buttressed. These small samples were thus able to expand freely in all directions when heated in experimental ovens, which failed to produce the kinds of stress likely in natural settings. The experiments were also more sensitive to thermal shock than thermal fatigue, but thermal fatigue is likely the more important mechanism in nature. Geomorphologists have begun to reemphasize the importance of thermal stress weathering, particularly in cold climates.
Pressure release
''Pressure release'' or ''unloading'' is a form of physical weathering seen when deeply buried rock is exhumed. Intrusive igneous rocks, such as
granite
Granite () is a coarse-grained (phaneritic) intrusive igneous rock composed mostly of quartz, alkali feldspar, and plagioclase. It forms from magma with a high content of silica and alkali metal oxides that slowly cools and solidifies undergro ...
, are formed deep beneath the Earth's surface. They are under tremendous
pressure
Pressure (symbol: ''p'' or ''P'') is the force applied perpendicular to the surface of an object per unit area over which that force is distributed. Gauge pressure (also spelled ''gage'' pressure)The preferred spelling varies by country and e ...
because of the overlying rock material. When erosion removes the overlying rock material, these intrusive rocks are exposed and the pressure on them is released. The outer parts of the rocks then tend to expand. The expansion sets up stresses which cause fractures parallel to the rock surface to form. Over time, sheets of rock break away from the exposed rocks along the fractures, a process known as exfoliation. Exfoliation due to pressure release is also known as ''sheeting''.
As with thermal weathering, pressure release is most effective in buttressed rock. Here the differential stress directed towards the unbuttressed surface can be as high as , easily enough to shatter rock. This mechanism is also responsible for
spalling
Spall are fragments of a material that are broken off a larger solid body. It can be produced by a variety of mechanisms, including as a result of projectile impact, corrosion, weathering, cavitation, or excessive rolling pressure (as in a ball ...
in mines and quarries, and for the formation of joints in rock outcrops.
Retreat of an overlying glacier can also lead to exfoliation due to pressure release. This can be enhanced by other physical wearing mechanisms.
Salt-crystal growth
''Salt crystallization'' (also known as salt weathering, salt wedging or
haloclasty
Haloclasty is a type of physical weathering caused by the growth of salt crystals. The process is first started when saline water seeps into cracks and evaporates depositing salt crystals. When the rocks are then heated, the crystals will expan ...
) causes disintegration of rocks when saline solutions seep into cracks and joints in the rocks and evaporate, leaving salt
crystals
A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macrosc ...
behind. As with ice segregation, the surfaces of the salt grains draw in additional dissolved salts through capillary action, causing the growth of salt lenses that exert high pressure on the surrounding rock. Sodium and magnesium salts are the most effective at producing salt weathering. Salt weathering can also take place when
pyrite
The mineral pyrite (), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula Iron, FeSulfur, S2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral.
Pyrite's metallic Luster (mineralogy), lust ...
in sedimentary rock is chemically weathered to
iron(II) sulfate
Iron(II) sulfate (British English: iron(II) sulphate) or ferrous sulfate denotes a range of salts with the formula Fe SO4·''x''H2O. These compounds exist most commonly as the heptahydrate (''x'' = 7) but several values for x are know ...
and
gypsum
Gypsum is a soft sulfate mineral composed of calcium sulfate dihydrate, with the chemical formula . It is widely mined and is used as a fertilizer and as the main constituent in many forms of plaster, blackboard or sidewalk chalk, and drywall. ...
, which then crystallize as salt lenses.
Salt crystallization can take place wherever salts are concentrated by evaporation. It is thus most common in
arid
A region is arid when it severely lacks available water, to the extent of hindering or preventing the growth and development of plant and animal life. Regions with arid climates tend to lack vegetation and are called xeric or desertic. Most ar ...
climates where strong heating causes strong evaporation and along coasts. Salt weathering is likely important in the formation of
tafoni
Although various definitions can be found in the scientific literature, tafoni (singular: tafone) are commonly defined as small (less than ) to large (greater than ) cavity features that develop in either natural or manmade, vertical to steeply s ...
, a class of cavernous rock weathering structures.
Biological effects on mechanical weathering
Living organisms may contribute to mechanical weathering, as well as chemical weathering (see § Biological weathering below).
Lichen
A lichen ( , ) is a composite organism that arises from algae or cyanobacteria living among filaments of multiple fungi species in a mutualistic relationship.moss
Mosses are small, non-vascular flowerless plants in the taxonomic division Bryophyta (, ) '' sensu stricto''. Bryophyta (''sensu lato'', Schimp. 1879) may also refer to the parent group bryophytes, which comprise liverworts, mosses, and hor ...
es grow on essentially bare rock surfaces and create a more humid chemical microenvironment. The attachment of these organisms to the rock surface enhances physical as well as chemical breakdown of the surface microlayer of the rock. Lichens have been observed to pry mineral grains loose from bare shale with their
hyphae
A hypha (; ) is a long, branching, filamentous structure of a fungus, oomycete, or actinobacterium. In most fungi, hyphae are the main mode of vegetative growth, and are collectively called a mycelium.
Structure
A hypha consists of one or ...
(rootlike attachment structures), a process described as ''plucking'', and to pull the fragments into their body, where the fragments then undergo a process of chemical weathering not unlike digestion. On a larger scale, seedlings sprouting in a crevice and plant roots exert physical pressure as well as providing a pathway for water and chemical infiltration.
Chemical weathering
Most rock forms at elevated temperature and pressure, and the minerals making up the rock are often chemically unstable in the relatively cool, wet, and oxidizing conditions typical of the Earth's surface. Chemical weathering takes place when water, oxygen, carbon dioxide, and other chemical substances react with rock to change its composition. These reactions convert some of the original ''primary'' minerals in the rock to ''secondary'' minerals, remove other substances as solutes, and leave the most stable minerals as a chemically unchanged ''resistate''. In effect, chemical weathering changes the original set of minerals in the rock into a new set of minerals that is in closer equilibrium with surface conditions. However, true equilibrium is rarely reached, because weathering is a slow process, and leaching carries away solutes produced by weathering reactions before they can accumulate to equilibrium levels. This is particularly true in tropical environments.
Water is the principal agent of chemical weathering, converting many primary minerals to clay minerals or hydrated oxides via reactions collectively described as
hydrolysis
Hydrolysis (; ) is any chemical reaction in which a molecule of water breaks one or more chemical bonds. The term is used broadly for substitution reaction, substitution, elimination reaction, elimination, and solvation reactions in which water ...
. Oxygen is also important, acting to
oxidize
Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or a d ...
many minerals, as is carbon dioxide, whose weathering reactions are described as
carbonation
Carbonation is the chemical reaction of carbon dioxide to give carbonates, bicarbonates, and carbonic acid. In chemistry, the term is sometimes used in place of carboxylation, which refers to the formation of carboxylic acids.
In inorganic ch ...
.
The process of mountain block uplift is important in exposing new rock strata to the atmosphere and moisture, enabling important chemical weathering to occur; significant release occurs of Ca2+ and other ions into surface waters.
Dissolution
Dissolution (also called ''simple solution'' or ''congruent dissolution'') is the process in which a mineral dissolves completely without producing any new solid substance. Rainwater easily dissolves soluble minerals, such as
halite
Halite (), commonly known as rock salt, is a type of salt, the mineral (natural) form of sodium chloride ( Na Cl). Halite forms isometric crystals. The mineral is typically colorless or white, but may also be light blue, dark blue, purple, p ...
or
gypsum
Gypsum is a soft sulfate mineral composed of calcium sulfate dihydrate, with the chemical formula . It is widely mined and is used as a fertilizer and as the main constituent in many forms of plaster, blackboard or sidewalk chalk, and drywall. ...
, but can also dissolve highly resistant minerals such as
quartz
Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical form ...
, given sufficient time. Water breaks the bonds between atoms in the crystal:
The overall reaction for dissolution of quartz is
:
The dissolved quartz takes the form of
silicic acid
Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is one ...
.
A particularly important form of dissolution is carbonate dissolution, in which atmospheric
carbon dioxide
Carbon dioxide (chemical formula ) is a chemical compound made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in the gas state at room temperature. In the air, carbon dioxide is transpar ...
enhances solution weathering. Carbonate dissolution affects rocks containing calcium carbonate, such as
limestone
Limestone ( calcium carbonate ) is a type of carbonate sedimentary rock which is the main source of the material lime. It is composed mostly of the minerals calcite and aragonite, which are different crystal forms of . Limestone forms whe ...
and
chalk
Chalk is a soft, white, porous, sedimentary carbonate rock. It is a form of limestone composed of the mineral calcite and originally formed deep under the sea by the compression of microscopic plankton that had settled to the sea floor. Chalk ...
. It takes place when rainwater combines with
carbon dioxide
Carbon dioxide (chemical formula ) is a chemical compound made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in the gas state at room temperature. In the air, carbon dioxide is transpar ...
weak acid
Acid strength is the tendency of an acid, symbolised by the chemical formula HA, to dissociate into a hydron (chemistry), proton, H+, and an anion, A-. The Dissociation (chemistry), dissociation of a strong acid in solution is effectively comple ...
, which dissolves calcium carbonate (limestone) and forms soluble
calcium bicarbonate
Calcium bicarbonate, also called calcium hydrogencarbonate, has the chemical formula Ca(HCO3)2. The term does not refer to a known solid compound; it exists only in aqueous solution containing calcium (Ca2+), bicarbonate (), and carbonate () ions ...
. Despite a slower
reaction kinetics
Chemical kinetics, also known as reaction kinetics, is the branch of physical chemistry that is concerned with understanding the rates of chemical reactions. It is to be contrasted with chemical thermodynamics, which deals with the direction in w ...
, this process is thermodynamically favored at low temperature, because colder water holds more dissolved carbon dioxide gas (due to the retrograde
solubility
In chemistry, solubility is the ability of a substance, the solute, to form a solution with another substance, the solvent. Insolubility is the opposite property, the inability of the solute to form such a solution.
The extent of the solubil ...
of gases). Carbonate dissolution is therefore an important feature of glacial weathering.
Carbonate dissolution involves the following steps:
:CO2 + H2O → H2CO3
:carbon dioxide + water → carbonic acid
:H2CO3 + CaCO3 → Ca(HCO3)2
:carbonic acid + calcium carbonate → calcium bicarbonate
Carbonate dissolution on the surface of well-jointed limestone produces a dissected
limestone pavement
A limestone pavement is a natural karst landform consisting of a flat, incised surface of exposed limestone that resembles an artificial pavement. The term is mainly used in the UK and Ireland, where many of these landforms have developed dist ...
. This process is most effective along the joints, widening and deepening them.
In unpolluted environments, the pH of rainwater due to dissolved carbon dioxide is around 5.6.
Acid rain
Acid rain is rain or any other form of precipitation that is unusually acidic, meaning that it has elevated levels of hydrogen ions (low pH). Most water, including drinking water, has a neutral pH that exists between 6.5 and 8.5, but acid ...
occurs when gases such as sulfur dioxide and nitrogen oxides are present in the atmosphere. These oxides react in the rain water to produce stronger acids and can lower the pH to 4.5 or even 3.0.
Sulfur dioxide
Sulfur dioxide (IUPAC-recommended spelling) or sulphur dioxide (traditional Commonwealth English) is the chemical compound with the formula . It is a toxic gas responsible for the odor of burnt matches. It is released naturally by volcanic activ ...
, SO2, comes from volcanic eruptions or from fossil fuels, can become
sulfuric acid
Sulfuric acid (American spelling and the preferred IUPAC name) or sulphuric acid ( Commonwealth spelling), known in antiquity as oil of vitriol, is a mineral acid composed of the elements sulfur, oxygen and hydrogen, with the molecular formu ...
within rainwater, which can cause solution weathering to the rocks on which it falls.
Hydrolysis and carbonation
Hydrolysis
Hydrolysis (; ) is any chemical reaction in which a molecule of water breaks one or more chemical bonds. The term is used broadly for substitution reaction, substitution, elimination reaction, elimination, and solvation reactions in which water ...
(also called ''incongruent dissolution'') is a form of chemical weathering in which only part of a mineral is taken into solution. The rest of the mineral is transformed into a new solid material, such as a
clay mineral
Clay minerals are hydrous aluminium phyllosilicates (e.g. kaolin, Al2 Si2 O5( OH)4), sometimes with variable amounts of iron, magnesium, alkali metals, alkaline earths, and other cations found on or near some planetary surfaces.
Clay minerals ...
. For example,
forsterite
Forsterite (Mg2SiO4; commonly abbreviated as Fo; also known as white olivine) is the magnesium-rich end-member of the olivine solid solution series. It is isomorphous with the iron-rich end-member, fayalite. Forsterite crystallizes in the orthor ...
(magnesium
olivine
The mineral olivine () is a magnesium iron silicate with the chemical formula . It is a type of nesosilicate or orthosilicate. The primary component of the Earth's upper mantle, it is a common mineral in Earth's subsurface, but weathers quickl ...
) is hydrolyzed into solid
brucite
Brucite is the mineral form of magnesium hydroxide, with the chemical formula Mg( OH)2. It is a common alteration product of periclase in marble; a low-temperature hydrothermal vein mineral in metamorphosed limestones and chlorite schists; and ...
and dissolved silicic acid:
:Mg2SiO4 + 4 H2O ⇌ 2 Mg(OH)2 + H4SiO4
:forsterite + water ⇌ brucite + silicic acid
Most hydrolysis during weathering of minerals is ''acid hydrolysis'', in which protons (hydrogen ions), which are present in acidic water, attack chemical bonds in mineral crystals. The bonds between different cations and oxygen ions in minerals differ in strength, and the weakest will be attacked first. The result is that minerals in igneous rock weather in roughly the same order in which they were originally formed ( Bowen's Reaction Series). Relative bond strength is shown in the following table:
This table is only a rough guide to order of weathering. Some minerals, such as
illite
Illite is a group of closely related non-expanding clay minerals. Illite is a secondary mineral precipitate, and an example of a phyllosilicate, or layered alumino-silicate. Its structure is a 2:1 sandwich of silica tetrahedron (T) – alumina ...
, are unusually stable, while silica is unusually unstable given the strength of the silicon-oxygen bond.
Carbon dioxide that dissolves in water to form carbonic acid is the most important source of protons, but organic acids are also important natural sources of acidity. Acid hydrolysis from dissolved carbon dioxide is sometimes described as ''carbonation'', and can result in weathering of the primary minerals to secondary carbonate minerals. For example, weathering of forsterite can produce
magnesite
Magnesite is a mineral with the chemical formula (magnesium carbonate). Iron, manganese, cobalt, and nickel may occur as admixtures, but only in small amounts.
Occurrence
Magnesite occurs as veins in and an alteration product of ultramafic ro ...
instead of brucite via the reaction:
:Mg2SiO4 + 2 CO2 + 2 H2O ⇌ 2 MgCO3 + H4SiO4
:forsterite + carbon dioxide + water ⇌ magnesite + silicic acid in solution
Carbonic acid is consumed by
silicate
In chemistry, a silicate is any member of a family of polyatomic anions consisting of silicon and oxygen, usually with the general formula , where . The family includes orthosilicate (), metasilicate (), and pyrosilicate (, ). The name is al ...
weathering, resulting in more
alkaline
In chemistry, an alkali (; from ar, القلوي, al-qaly, lit=ashes of the saltwort) is a base (chemistry), basic, ionic compound, ionic salt (chemistry), salt of an alkali metal or an alkaline earth metal. An alkali can also be defined as ...
solutions because of the
bicarbonate
In inorganic chemistry, bicarbonate (IUPAC-recommended nomenclature: hydrogencarbonate) is an intermediate form in the deprotonation of carbonic acid. It is a polyatomic anion with the chemical formula .
Bicarbonate serves a crucial biochemic ...
. This is an important reaction in controlling the amount of CO2 in the atmosphere and can affect climate.
Aluminosilicate
Aluminosilicate minerals ( IMA symbol: Als) are minerals composed of aluminium, silicon, and oxygen, plus countercations. They are a major component of kaolin and other clay minerals.
Andalusite, kyanite, and sillimanite are naturally occurr ...
s containing highly soluble cations, such as sodium or potassium ions, will release the cations as dissolved bicarbonates during acid hydrolysis:
:2 KAlSi3O8 + 2 H2CO3 + 9 H2O ⇌ Al2Si2O5(OH)4 + 4 H4SiO4 + 2 K+ + 2 HCO3−
:
orthoclase
Orthoclase, or orthoclase feldspar (endmember formula K Al Si3 O8), is an important tectosilicate mineral which forms igneous rock. The name is from the Ancient Greek for "straight fracture," because its two cleavage planes are at right angles t ...
(aluminosilicate feldspar) + carbonic acid + water ⇌
kaolinite
Kaolinite ( ) is a clay mineral, with the chemical composition Al2 Si2 O5( OH)4. It is an important industrial mineral. It is a layered silicate mineral, with one tetrahedral sheet of silica () linked through oxygen atoms to one octahedral ...
(a clay mineral) + silicic acid in solution + potassium and bicarbonate ions in solution
Oxidation
Within the weathering environment, chemical
oxidation
Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or a d ...
of a variety of metals occurs. The most commonly observed is the oxidation of Fe2+ (
iron
Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in f ...
) by oxygen and water to form Fe3+ oxides and hydroxides such as
goethite
Goethite (, ) is a mineral of the diaspore group, consisting of iron(III) oxide-hydroxide, specifically the "α" polymorph. It is found in soil and other low-temperature environments such as sediment. Goethite has been well known since ancient t ...
,
limonite
Limonite () is an iron ore consisting of a mixture of hydrated iron(III) oxide-hydroxides in varying composition. The generic formula is frequently written as FeO(OH)·H2O, although this is not entirely accurate as the ratio of oxide to hydroxid ...
, and
hematite
Hematite (), also spelled as haematite, is a common iron oxide compound with the formula, Fe2O3 and is widely found in rocks and soils. Hematite crystals belong to the rhombohedral lattice system which is designated the alpha polymorph of . ...
. This gives the affected rocks a reddish-brown coloration on the surface which crumbles easily and weakens the rock. Many other metallic ores and minerals oxidize and hydrate to produce colored deposits, as does sulfur during the weathering of
sulfide mineral
The sulfide minerals are a class of minerals containing sulfide (S2−) or disulfide (S22−) as the major anion. Some sulfide minerals are economically important as metal ores. The sulfide class also includes the selenides, the tellurides, the ...
s such as
chalcopyrite
Chalcopyrite ( ) is a copper iron sulfide mineral and the most abundant copper ore mineral. It has the chemical formula CuFeS2 and crystallizes in the tetragonal system. It has a brassy to golden yellow color and a hardness of 3.5 to 4 on the Mo ...
iron oxide
Iron oxides are chemical compounds composed of iron and oxygen. Several iron oxides are recognized. All are black magnetic solids. Often they are non-stoichiometric. Oxyhydroxides are a related class of compounds, perhaps the best known of whic ...
s.
Hydration
Mineral hydration
In chemistry, mineral hydration is an inorganic chemical reaction which adds water to the crystal structure of a mineral, usually creating a new mineral, usually called a ''hydrate''.
In geological terms, the process of mineral hydration is know ...
is a form of chemical weathering that involves the rigid attachment of water molecules or H+ and OH- ions to the atoms and molecules of a mineral. No significant dissolution takes place. For example,
iron oxide
Iron oxides are chemical compounds composed of iron and oxygen. Several iron oxides are recognized. All are black magnetic solids. Often they are non-stoichiometric. Oxyhydroxides are a related class of compounds, perhaps the best known of whic ...
s are converted to
iron hydroxide
Iron oxides are chemical compounds composed of iron and oxygen. Several iron oxides are recognized. All are black magnetic solids. Often they are non-stoichiometric. Oxyhydroxides are a related class of compounds, perhaps the best known of which ...
s and the hydration of
anhydrite
Anhydrite, or anhydrous calcium sulfate, is a mineral with the chemical formula CaSO4. It is in the orthorhombic crystal system, with three directions of perfect cleavage parallel to the three planes of symmetry. It is not isomorphous with the ...
forms
gypsum
Gypsum is a soft sulfate mineral composed of calcium sulfate dihydrate, with the chemical formula . It is widely mined and is used as a fertilizer and as the main constituent in many forms of plaster, blackboard or sidewalk chalk, and drywall. ...
.
Bulk hydration of minerals is secondary in importance to dissolution, hydrolysis, and oxidation, but hydration of the crystal surface is the crucial first step in hydrolysis. A fresh surface of a mineral crystal exposes ions whose electrical charge attracts water molecules. Some of these molecules break into H+ that bonds to exposed anions (usually oxygen) and OH- that bonds to exposed cations. This further disrupts the surface, making it susceptible to various hydrolysis reactions. Additional protons replace cations exposed in the surface, freeing the cations as solutes. As cations are removed, silicon-oxygen and silicon-aluminium bonds become more susceptible to hydrolysis, freeing silicic acid and aluminium hydroxides to be leached away or to form clay minerals. Laboratory experiments show that weathering of feldspar crystals begins at dislocations or other defects on the surface of the crystal, and that the weathering layer is only a few atoms thick. Diffusion within the mineral grain does not appear to be significant.
Biological weathering
Mineral weathering can also be initiated or accelerated by soil microorganisms. Soil organisms make up about 10 mg/cm3 of typical soils, and laboratory experiments have demonstrated that
albite
Albite is a plagioclase feldspar mineral. It is the sodium endmember of the plagioclase solid solution series. It represents a plagioclase with less than 10% anorthite content. The pure albite endmember has the formula . It is a tectosilicate. I ...
and
muscovite
Muscovite (also known as common mica, isinglass, or potash mica) is a hydrated phyllosilicate mineral of aluminium and potassium with formula K Al2(Al Si3 O10)( F,O H)2, or ( KF)2( Al2O3)3( SiO2)6( H2O). It has a highly perfect basal cleavage ...
weather twice as fast in live versus sterile soil.
chelating
Chelation is a type of bonding of ions and molecules to metal ions. It involves the formation or presence of two or more separate coordinate bonds between a Denticity, polydentate (multiple bonded) ligand and a single central metal atom. These l ...
compounds (such as certain organic acids and
siderophore
Siderophores (Greek: "iron carrier") are small, high-affinity iron-chelating compounds that are secreted by microorganisms such as bacteria and fungi. They help the organism accumulate iron. Although a widening range of siderophore functions is no ...
s) and of carbon dioxide and organic acids by plants. Roots can build up the carbon dioxide level to 30% of all soil gases, aided by adsorption of on clay minerals and the very slow diffusion rate of out of the soil. The and organic acids help break down
aluminium
Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. I ...
- and
iron
Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in f ...
-containing compounds in the soils beneath them. Roots have a negative electrical charge balanced by protons in the soil next to the roots, and these can be exchanged for essential nutrient cations such as potassium. Decaying remains of dead plants in soil may form organic acids which, when dissolved in water, cause chemical weathering. Chelating compounds, mostly low molecular weight organic acids, are capable of removing metal ions from bare rock surfaces, with aluminium and silicon being particularly susceptible. The ability to break down bare rock allows lichens to be among the first colonizers of dry land. The accumulation of chelating compounds can easily affect surrounding rocks and soils, and may lead to
podsol
In soil science, podzols are the typical soils of coniferous or boreal forests and also the typical soils of eucalypt forests and heathlands in southern Australia. In Western Europe, podzols develop on heathland, which is often a construct of huma ...
isation of soils.
The symbiotic
mycorrhizal fungi
A mycorrhiza (from Greek μύκης ', "fungus", and ῥίζα ', "root"; pl. mycorrhizae, mycorrhiza or mycorrhizas) is a symbiotic association between a fungus and a plant. The term mycorrhiza refers to the role of the fungus in the plant ...
associated with tree root systems can release inorganic nutrients from minerals such as apatite or biotite and transfer these nutrients to the trees, thus contributing to tree nutrition. It was also recently evidenced that bacterial communities can impact mineral stability leading to the release of inorganic nutrients. A large range of bacterial strains or communities from diverse genera have been reported to be able to colonize mineral surfaces or to weather minerals, and for some of them a plant growth promoting effect has been demonstrated. The demonstrated or hypothesised mechanisms used by bacteria to weather minerals include several oxidoreduction and dissolution reactions as well as the production of weathering agents, such as protons, organic acids and chelating molecules.
Weathering on the ocean floor
Weathering of basaltic oceanic crust differs in important respects from weathering in the atmosphere. Weathering is relatively slow, with basalt becoming less dense, at a rate of about 15% per 100 million years. The basalt becomes hydrated, and is enriched in total and ferric iron, magnesium, and sodium at the expense of silica, titanium, aluminum, ferrous iron, and calcium.
Building weathering
Buildings made of any stone, brick or concrete are susceptible to the same weathering agents as any exposed rock surface. Also
statue
A statue is a free-standing sculpture in which the realistic, full-length figures of persons or animals are carved or cast in a durable material such as wood, metal or stone. Typical statues are life-sized or close to life-size; a sculpture t ...
s, monuments and ornamental stonework can be badly damaged by natural weathering processes. This is accelerated in areas severely affected by
acid rain
Acid rain is rain or any other form of precipitation that is unusually acidic, meaning that it has elevated levels of hydrogen ions (low pH). Most water, including drinking water, has a neutral pH that exists between 6.5 and 8.5, but acid ...
.
Accelerated building weathering may be a threat to the environment and occupant safety. Design strategies can moderate the impact of environmental effects, such as using of pressure-moderated rain screening, ensuring that the HVAC system is able to effectively control humidity accumulation and selecting concrete mixes with reduced water content to minimize the impact of freeze-thaw cycles.
Properties of well-weathered soils
Granitic rock, which is the most abundant crystalline rock exposed at the Earth's surface, begins weathering with destruction of
hornblende
Hornblende is a complex inosilicate series of minerals. It is not a recognized mineral in its own right, but the name is used as a general or field term, to refer to a dark amphibole. Hornblende minerals are common in igneous and metamorphic rocks ...
.
Biotite
Biotite is a common group of phyllosilicate minerals within the mica group, with the approximate chemical formula . It is primarily a solid-solution series between the iron-endmember annite, and the magnesium-endmember phlogopite; more alumino ...
then weathers to
vermiculite
Vermiculite is a hydrous phyllosilicate mineral which undergoes significant expansion when heated. Exfoliation occurs when the mineral is heated sufficiently, and commercial furnaces can routinely produce this effect. Vermiculite forms by the wea ...
, and finally
oligoclase
Oligoclase is a rock-forming mineral belonging to the plagioclase feldspars. In chemical composition and in its crystallographic and physical characters it is intermediate between albite ( Na Al Si3 O8) and anorthite ( CaAl2Si2O8). The albite:an ...
and
microcline
Microcline (KAlSi3O8) is an important igneous rock-forming tectosilicate mineral. It is a potassium-rich alkali feldspar. Microcline typically contains minor amounts of sodium. It is common in granite and pegmatites. Microcline forms during slow ...
are destroyed. All are converted into a mixture of clay minerals and iron oxides. The resulting soil is depleted in calcium, sodium, and ferrous iron compared with the bedrock, and magnesium is reduced 40% and silicon by 15%. At the same time, the soil is enriched in aluminium and potassium, by at least 50%; by titanium, whose abundance triples; and by ferric iron, whose abundance increases by an order of magnitude compared with the bedrock.
Basaltic rock is more easily weathered than granitic rock, due to its formation at higher temperatures and drier conditions. The fine grain size and presence of volcanic glass also hasten weathering. In tropical settings, it rapidly weathers to clay minerals, aluminium hydroxides, and titanium-enriched iron oxides. Because most basalt is relatively poor in potassium, the basalt weathers directly to potassium-poor
montmorillonite
Montmorillonite is a very soft phyllosilicate group of minerals that form when they precipitate from water solution as microscopic crystals, known as clay. It is named after Montmorillon in France. Montmorillonite, a member of the smectite gro ...
, then to
kaolinite
Kaolinite ( ) is a clay mineral, with the chemical composition Al2 Si2 O5( OH)4. It is an important industrial mineral. It is a layered silicate mineral, with one tetrahedral sheet of silica () linked through oxygen atoms to one octahedral ...
. Where leaching is continuous and intense, as in rain forests, the final weathering product is
bauxite
Bauxite is a sedimentary rock with a relatively high aluminium content. It is the world's main source of aluminium and gallium. Bauxite consists mostly of the aluminium minerals gibbsite (Al(OH)3), boehmite (γ-AlO(OH)) and diaspore (α-AlO(O ...
, the principal ore of aluminium. Where rainfall is intense but seasonal, as in monsoon climates, the final weathering product is iron- and titanium-rich
laterite
Laterite is both a soil and a rock type rich in iron and aluminium and is commonly considered to have formed in hot and wet tropical areas. Nearly all laterites are of rusty-red coloration, because of high iron oxide content. They develop by ...
. Conversion of kaolinite to bauxite occurs only with intense leaching, as ordinary river water is in equilibrium with kaolinite.
Soil formation requires between 100 and 1,000 years, a very brief interval in geologic time. As a result, some formations show numerous
paleosol
In the geosciences, paleosol (''palaeosol'' in Great Britain and Australia) is an ancient soil that formed in the past. The precise definition of the term in geology and paleontology is slightly different from its use in soil science.
In geolo ...
(fossil soil) beds. For example, the
Willwood Formation
The Willwood Formation is a sedimentary sequence deposited during the late Paleocene to early Eocene, or Clarkforkian, Wasatchian and Bridgerian in the North American land mammal age, NALMA classification.Archean
The Archean Eon ( , also spelled Archaean or Archæan) is the second of four geologic eons of Earth's history, representing the time from . The Archean was preceded by the Hadean Eon and followed by the Proterozoic.
The Earth
Earth ...
(over 2.5 billion years in age). However, paleosols are difficult to recognize in the geologic record. Indications that a sedimentary bed is a paleosol include a gradational lower boundary and sharp upper boundary, the presence of much clay, poor sorting with few sedimentary structures, rip-up clasts in overlying beds, and desiccation cracks containing material from higher beds.
The degree of weathering of a soil can be expressed as the ''chemical index of alteration'', defined as . This varies from 47 for unweathered upper crust rock to 100 for fully weathered material.
Weathering of non-geological materials
Wood can be physically and chemically weathered by hydrolysis and other processes relevant to minerals, but in addition, wood is highly susceptible to weathering induced by
ultraviolet
Ultraviolet (UV) is a form of electromagnetic radiation with wavelength from 10 nanometer, nm (with a corresponding frequency around 30 Hertz, PHz) to 400 nm (750 Hertz, THz), shorter than that of visible light, but longer than ...
radiation from sunlight. This induces photochemical reactions that degrade the wood surface. Photochemical reactions are also significant in the weathering of paint and plastics.
Gallery
File:Salt weathering in gozo.jpg, Salt weathering of building stone on the island of
Gozo
Gozo (, ), Maltese: ''Għawdex'' () and in antiquity known as Gaulos ( xpu, 𐤂𐤅𐤋, ; grc, Γαῦλος, Gaúlos), is an island in the Maltese archipelago in the Mediterranean Sea. The island is part of the Republic of Malta. After t ...
,
Malta
Malta ( , , ), officially the Republic of Malta ( mt, Repubblika ta' Malta ), is an island country in the Mediterranean Sea. It consists of an archipelago, between Italy and Libya, and is often considered a part of Southern Europe. It lies ...
File:Qobustan-salt.jpg, Salt weathering of
sandstone
Sandstone is a clastic sedimentary rock composed mainly of sand-sized (0.0625 to 2 mm) silicate grains. Sandstones comprise about 20–25% of all sedimentary rocks.
Most sandstone is composed of quartz or feldspar (both silicates) ...
near
Qobustan Qobustan or Gobustan may refer to:
* Gobustan District, Azerbaijan
* Qobustan (town), administrative center of Gobustan District, Azerbaijan
* Qobustan, Baku, a settlement and municipality in Azerbaijan
** Gobustan National Park, World Heritage S ...
,
Azerbaijan
Azerbaijan (, ; az, Azərbaycan ), officially the Republic of Azerbaijan, , also sometimes officially called the Azerbaijan Republic is a transcontinental country located at the boundary of Eastern Europe and Western Asia. It is a part of th ...
File:Weathered sandstone, Sedona.jpg,
Permian
The Permian ( ) is a geologic period and stratigraphic system which spans 47 million years from the end of the Carboniferous Period million years ago (Mya), to the beginning of the Triassic Period 251.9 Mya. It is the last period of the Paleoz ...
sandstone wall near
Sedona, Arizona
Sedona is a city that straddles the county line between Coconino and Yavapai counties in the northern Verde Valley region of the U.S. state of Arizona. As of the 2010 census, its population was 10,031. It is within the Coconino National Fo ...
, United States, weathered into a small alcove
File:Weathered sandstone DSC01497.jpg, Weathering on a sandstone pillar in
Bayreuth
Bayreuth (, ; bar, Bareid) is a town in northern Bavaria, Germany, on the Red Main river in a valley between the Franconian Jura and the Fichtelgebirge Mountains. The town's roots date back to 1194. In the 21st century, it is the capital of U ...
File:Pollution - Damaged by acid rain.jpg, Weathering effect of
acid rain
Acid rain is rain or any other form of precipitation that is unusually acidic, meaning that it has elevated levels of hydrogen ions (low pH). Most water, including drinking water, has a neutral pH that exists between 6.5 and 8.5, but acid ...
on statues
File:Skulptur aus Sandstein, Dresden 2012-09-06-0555.jpg, Weathering effect on a sandstone statue in Dresden, Germany
File:Physical weathering.jpg, Physical weathering of the pavements of Azad University Science and Research Branch, which is located in the heights of
Tehran
Tehran (; fa, تهران ) is the largest city in Tehran Province and the capital of Iran. With a population of around 9 million in the city and around 16 million in the larger metropolitan area of Greater Tehran, Tehran is the most popul ...
, the
capital
Capital may refer to:
Common uses
* Capital city, a municipality of primary status
** List of national capital cities
* Capital letter, an upper-case letter Economics and social sciences
* Capital (economics), the durable produced goods used f ...
of
Iran
Iran, officially the Islamic Republic of Iran, and also called Persia, is a country located in Western Asia. It is bordered by Iraq and Turkey to the west, by Azerbaijan and Armenia to the northwest, by the Caspian Sea and Turkmeni ...