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In
mathematical physics Mathematical physics refers to the development of mathematics, mathematical methods for application to problems in physics. The ''Journal of Mathematical Physics'' defines the field as "the application of mathematics to problems in physics and t ...
and
mathematics Mathematics is an area of knowledge that includes the topics of numbers, formulas and related structures, shapes and the spaces in which they are contained, and quantities and their changes. These topics are represented in modern mathematics ...
, the Pauli matrices are a set of three
complex Complex commonly refers to: * Complexity, the behaviour of a system whose components interact in multiple ways so possible interactions are difficult to describe ** Complex system, a system composed of many components which may interact with each ...
matrices Matrix most commonly refers to: * ''The Matrix'' (franchise), an American media franchise ** ''The Matrix'', a 1999 science-fiction action film ** "The Matrix", a fictional setting, a virtual reality environment, within ''The Matrix'' (franchis ...
which are
Hermitian {{Short description, none Numerous things are named after the French mathematician Charles Hermite (1822–1901): Hermite * Cubic Hermite spline, a type of third-degree spline * Gauss–Hermite quadrature, an extension of Gaussian quadrature m ...
, involutory and
unitary Unitary may refer to: Mathematics * Unitary divisor * Unitary element * Unitary group * Unitary matrix * Unitary morphism * Unitary operator * Unitary transformation * Unitary representation * Unitarity (physics) * ''E''-unitary inverse semigrou ...
. Usually indicated by the
Greek Greek may refer to: Greece Anything of, from, or related to Greece, a country in Southern Europe: *Greeks, an ethnic group. *Greek language, a branch of the Indo-European language family. **Proto-Greek language, the assumed last common ancestor ...
letter sigma (), they are occasionally denoted by
tau Tau (uppercase Τ, lowercase τ, or \boldsymbol\tau; el, ταυ ) is the 19th letter of the Greek alphabet, representing the voiceless dental or alveolar plosive . In the system of Greek numerals, it has a value of 300. The name in English ...
() when used in connection with
isospin In nuclear physics and particle physics, isospin (''I'') is a quantum number related to the up- and down quark content of the particle. More specifically, isospin symmetry is a subset of the flavour symmetry seen more broadly in the interactions ...
symmetries. \begin \sigma_1 = \sigma_\mathrm &= \begin 0&1\\ 1&0 \end \\ \sigma_2 = \sigma_\mathrm &= \begin 0& -i \\ i&0 \end \\ \sigma_3 = \sigma_\mathrm &= \begin 1&0\\ 0&-1 \end \\ \end These matrices are named after the physicist
Wolfgang Pauli Wolfgang Ernst Pauli (; ; 25 April 1900 – 15 December 1958) was an Austrian theoretical physicist and one of the pioneers of quantum physics. In 1945, after having been nominated by Albert Einstein, Pauli received the Nobel Prize in Physics fo ...
. In
quantum mechanics Quantum mechanics is a fundamental theory in physics that provides a description of the physical properties of nature at the scale of atoms and subatomic particles. It is the foundation of all quantum physics including quantum chemistry, ...
, they occur in the
Pauli equation In quantum mechanics, the Pauli equation or Schrödinger–Pauli equation is the formulation of the Schrödinger equation for spin-½ particles, which takes into account the interaction of the particle's spin with an external electromagnetic f ...
which takes into account the interaction of the spin of a particle with an external
electromagnetic field An electromagnetic field (also EM field or EMF) is a classical (i.e. non-quantum) field produced by (stationary or moving) electric charges. It is the field described by classical electrodynamics (a classical field theory) and is the classical c ...
. They also represent the interaction states of two polarization filters for horizontal/vertical polarization, 45 degree polarization (right/left), and circular polarization (right/left). Each Pauli matrix is
Hermitian {{Short description, none Numerous things are named after the French mathematician Charles Hermite (1822–1901): Hermite * Cubic Hermite spline, a type of third-degree spline * Gauss–Hermite quadrature, an extension of Gaussian quadrature m ...
, and together with the identity matrix (sometimes considered as the zeroth Pauli matrix ), the Pauli matrices form a
basis Basis may refer to: Finance and accounting * Adjusted basis, the net cost of an asset after adjusting for various tax-related items *Basis point, 0.01%, often used in the context of interest rates * Basis trading, a trading strategy consisting ...
for the real
vector space In mathematics and physics, a vector space (also called a linear space) is a set whose elements, often called ''vectors'', may be added together and multiplied ("scaled") by numbers called '' scalars''. Scalars are often real numbers, but can ...
of Hermitian matrices. This means that any
Hermitian matrix In mathematics, a Hermitian matrix (or self-adjoint matrix) is a complex square matrix that is equal to its own conjugate transpose—that is, the element in the -th row and -th column is equal to the complex conjugate of the element in the -th ...
can be written in a unique way as a linear combination of Pauli matrices, with all coefficients being real numbers. Hermitian operators represent
observable In physics, an observable is a physical quantity that can be measured. Examples include position and momentum. In systems governed by classical mechanics, it is a real-valued "function" on the set of all possible system states. In quantum ph ...
s in quantum mechanics, so the Pauli matrices span the space of observables of the
complex Complex commonly refers to: * Complexity, the behaviour of a system whose components interact in multiple ways so possible interactions are difficult to describe ** Complex system, a system composed of many components which may interact with each ...
-dimensional
Hilbert space In mathematics, Hilbert spaces (named after David Hilbert) allow generalizing the methods of linear algebra and calculus from (finite-dimensional) Euclidean vector spaces to spaces that may be infinite-dimensional. Hilbert spaces arise natural ...
. In the context of Pauli's work, represents the observable corresponding to spin along the th coordinate axis in three-dimensional
Euclidean space Euclidean space is the fundamental space of geometry, intended to represent physical space. Originally, that is, in Euclid's Elements, Euclid's ''Elements'', it was the three-dimensional space of Euclidean geometry, but in modern mathematics ther ...
\mathbb^3. The Pauli matrices (after multiplication by to make them
anti-Hermitian __NOTOC__ In linear algebra, a square matrix with complex entries is said to be skew-Hermitian or anti-Hermitian if its conjugate transpose is the negative of the original matrix. That is, the matrix A is skew-Hermitian if it satisfies the relatio ...
) also generate transformations in the sense of
Lie algebra In mathematics, a Lie algebra (pronounced ) is a vector space \mathfrak g together with an Binary operation, operation called the Lie bracket, an Alternating multilinear map, alternating bilinear map \mathfrak g \times \mathfrak g \rightarrow ...
s: the matrices form a basis for the real Lie algebra \mathfrak(2), which exponentiates to the special unitary group
SU(2) In mathematics, the special unitary group of degree , denoted , is the Lie group of unitary matrices with determinant 1. The more general unitary matrices may have complex determinants with absolute value 1, rather than real 1 in the special ...
. The
algebra Algebra () is one of the broad areas of mathematics. Roughly speaking, algebra is the study of mathematical symbols and the rules for manipulating these symbols in formulas; it is a unifying thread of almost all of mathematics. Elementary a ...
generated by the three matrices is
isomorphic In mathematics, an isomorphism is a structure-preserving mapping between two structures of the same type that can be reversed by an inverse mapping. Two mathematical structures are isomorphic if an isomorphism exists between them. The word is ...
to the
Clifford algebra In mathematics, a Clifford algebra is an algebra generated by a vector space with a quadratic form, and is a unital associative algebra. As -algebras, they generalize the real numbers, complex numbers, quaternions and several other hyperc ...
of , and the (unital associative) algebra generated by is effectively identical (isomorphic) to that of
quaternion In mathematics, the quaternion number system extends the complex numbers. Quaternions were first described by the Irish mathematician William Rowan Hamilton in 1843 and applied to mechanics in three-dimensional space. Hamilton defined a quatern ...
s (\mathbb).


Algebraic properties

All three of the Pauli matrices can be compacted into a single expression: : \sigma_j = \begin \delta_ & \delta_ - i\,\delta_\\ \delta_ + i\,\delta_ & -\delta_ \end where the solution to is the "
imaginary unit The imaginary unit or unit imaginary number () is a solution to the quadratic equation x^2+1=0. Although there is no real number with this property, can be used to extend the real numbers to what are called complex numbers, using addition an ...
", and is the
Kronecker delta In mathematics, the Kronecker delta (named after Leopold Kronecker) is a function of two variables, usually just non-negative integers. The function is 1 if the variables are equal, and 0 otherwise: \delta_ = \begin 0 &\text i \neq j, \\ 1 & ...
, which equals +1 if and 0 otherwise. This expression is useful for "selecting" any one of the matrices numerically by substituting values of , in turn useful when any of the matrices (but no particular one) is to be used in algebraic manipulations. The matrices are ''involutory'': :\sigma_1^2 = \sigma_2^2 = \sigma_3^2 = -i\,\sigma_1 \sigma_2 \sigma_3 = \begin 1 & 0 \\ 0 & 1 \end = I where is the identity matrix. The
determinant In mathematics, the determinant is a scalar value that is a function of the entries of a square matrix. It characterizes some properties of the matrix and the linear map represented by the matrix. In particular, the determinant is nonzero if and ...
s and
trace Trace may refer to: Arts and entertainment Music * ''Trace'' (Son Volt album), 1995 * ''Trace'' (Died Pretty album), 1993 * Trace (band), a Dutch progressive rock band * ''The Trace'' (album) Other uses in arts and entertainment * ''Trace'' ...
s of the Pauli matrices are: :\begin \det \sigma_j &~=\, -1\,, \\ \operatorname \sigma_j &~=~~~\; 0 ~. \end From which, we can deduce that each matrix has
eigenvalues In linear algebra, an eigenvector () or characteristic vector of a linear transformation is a nonzero vector that changes at most by a scalar factor when that linear transformation is applied to it. The corresponding eigenvalue, often denoted b ...
+1 and −1. With the inclusion of the identity matrix, (sometimes denoted ), the Pauli matrices form an orthogonal basis (in the sense of Hilbert–Schmidt) of the
Hilbert space In mathematics, Hilbert spaces (named after David Hilbert) allow generalizing the methods of linear algebra and calculus from (finite-dimensional) Euclidean vector spaces to spaces that may be infinite-dimensional. Hilbert spaces arise natural ...
of Hermitian matrices, \mathcal_2 over \mathbb, and the Hilbert space of all
complex Complex commonly refers to: * Complexity, the behaviour of a system whose components interact in multiple ways so possible interactions are difficult to describe ** Complex system, a system composed of many components which may interact with each ...
matrices, \mathcal_(\mathbb).


Eigenvectors and eigenvalues

Each of the (
Hermitian {{Short description, none Numerous things are named after the French mathematician Charles Hermite (1822–1901): Hermite * Cubic Hermite spline, a type of third-degree spline * Gauss–Hermite quadrature, an extension of Gaussian quadrature m ...
) Pauli matrices has two
eigenvalues In linear algebra, an eigenvector () or characteristic vector of a linear transformation is a nonzero vector that changes at most by a scalar factor when that linear transformation is applied to it. The corresponding eigenvalue, often denoted b ...
, and . The corresponding normalized
eigenvectors In linear algebra, an eigenvector () or characteristic vector of a linear transformation is a nonzero vector that changes at most by a scalar factor when that linear transformation is applied to it. The corresponding eigenvalue, often denoted ...
are: :\begin \psi_ &= \frac\sqrt \begin 1 \\ 1 \end \; , & \psi_ &= \frac\sqrt \begin 1 \\ -1 \end \; , \\ \psi_ &= \frac\sqrt \begin 1 \\ i \end \; , & \psi_ &= \frac\sqrt \begin 1 \\ -i \end \; , \\ \psi_ &= \begin 1 \\ 0 \end \; , & \psi_ &= \begin 0 \\ 1 \end ~. \end


Pauli vector

The Pauli vector is defined by \vec = \sigma_1 \hat_1 + \sigma_2 \hat_2 + \sigma_3 \hat_3 ~, where \hat_1, \hat_2, and \hat_3 are an equivalent notation for the more familiar \hat, \hat, and \hat; the subscripted notation \hat_1, \hat_2, \hat_3 is more compact than the old \hat, \hat, \hat form. The Pauli vector provides a mapping mechanism from a vector basis to a Pauli matrix basis as follows, \begin \vec \cdot \vec &= \left(a_k \hat_k\right) \cdot \left(\sigma_\ell \hat_\ell \right) = a_k \sigma_\ell \hat_k \cdot \hat_\ell \\ \\ &= a_k \sigma_\ell \delta_ = a_k \sigma_k \\ \\ &= ~ a_1\; \begin 0 & 1 \\ 1 & 0 \end ~ + ~ a_2\; \begin 0 & -i \\ i & \;\;0 \end ~ + ~ a_3\; \begin 1 & 0 \\ 0 & -1 \end ~ = ~ \begin a_3 & a_1 - i a_2 \\ a_1 + i a_2 & -a_3 \end \end using
Einstein's summation convention In mathematics, especially the usage of linear algebra in Mathematical physics, Einstein notation (also known as the Einstein summation convention or Einstein summation notation) is a notational convention that implies summation over a set of ...
. More formally, this defines a map from \mathbb^3 to the vector space of traceless Hermitian 2\times 2 matrices. This map encodes structures of \mathbb^3 as a normed vector space and as a Lie algebra (with the cross-product as its Lie bracket) via functions of matrices, making the map an isomorphism of Lie algebras. This makes the Pauli matrices intertwiners from the point of view of representation theory. Another way to view the Pauli vector is as a 2\times 2 Hermitian traceless matrix-valued dual vector, that is, an element of \text_(\mathbb) \otimes (\mathbb^3)^* which maps \vec a \mapsto \vec a \cdot \vec \sigma.


Completeness relation

Each component of \vec a can be recovered from the matrix (see completeness relation below) \frac \operatorname \Bigl( \bigl( \vec \cdot \vec \bigr) \vec \Bigr) = \vec ~. This constitutes an inverse to the map \vec a \mapsto \vec a \cdot \vec \sigma, making it manifest that the map is a bijection.


Determinant

The norm is given by the determinant (up to a minus sign) \det \bigl( \vec \cdot \vec \bigr) = -\vec \cdot \vec = -\left, \vec\^2. Then considering the conjugation action of an \text(2) matrix U on this space of matrices, :U * \vec a \cdot \vec \sigma := U \; \vec a \cdot \vec \sigma \; U^, we find \det(U * \vec a \cdot \vec\sigma) = \det(\vec a \cdot \vec \sigma), and that U * \vec a \cdot \vec \sigma is Hermitian and traceless. It then makes sense to define U * \vec a \cdot \vec\sigma = \vec a' \cdot \vec\sigma where \vec a' has the same norm as \vec a, and therefore interpret U as a rotation of 3-dimensional space. In fact, it turns out that the ''special'' restriction on U implies that the rotation is orientation preserving. This allows the definition of a map R: \text(2) \rightarrow \text(3) given by :U * \vec a \cdot \vec \sigma = \vec a' \cdot \vec \sigma =: (R(U)\vec a) \cdot \vec \sigma, where R(U)\in \text(3). This map is the concrete realization of the double cover of \text(3) by \text(2), and therefore shows that \text(2) \cong \text(3). The components of R(U) can be recovered using the tracing process above: :R(U)_ = \frac\text\left(\sigma_i U \sigma_j U^\right)


Cross-product

The cross-product is given by the matrix commutator (up to a factor of 2i) vec a \cdot \vec \sigma, \vec b \cdot \vec \sigma= 2i (\vec a \times \vec b) \cdot \vec \sigma. In fact, the existence of a norm follows from the fact that \mathbb^3 is a Lie algebra: see Killing form. This cross-product can be used to prove the orientation-preserving property of the map above.


Eigenvalues and eigenvectors

The eigenvalues of \vec a \cdot \vec \sigma are \pm , \vec, . This follows immediately from tracelessness and explicitly computing the determinant. More abstractly, without computing the determinant which requires explicit properties of the Pauli matrices, this follows from (\vec a \cdot \vec \sigma)^2 - , \vec a, ^2 = 0, since this can be factorised into (\vec a \cdot \vec \sigma - , \vec a, )(\vec a \cdot \vec \sigma + , \vec a, )= 0. A standard result in linear algebra (a linear map which satisfies a polynomial equation written in distinct linear factors is diagonal) means this implies \vec a \cdot \vec \sigma is diagonal with possible eigenvalues \pm , \vec a, . The tracelessness of \vec a \cdot \vec \sigma means it has exactly one of each eigenvalue. Its normalized eigenvectors are \psi_+ = \frac \begin a_3 + , \vec, \\ a_1 + ia_2 \end; \qquad \psi_- = \frac \begin ia_2 - a_1 \\ a_3 + , \vec, \end ~ .


Pauli 4-vector

The Pauli 4-vector, used in spinor theory, is written \sigma^\mu with components :\sigma^\mu = (I, \vec\sigma). This defines a map from \mathbb^ to the vector space of Hermitian matrices, :x_\mu \mapsto x_\mu\sigma^\mu, which also encodes the
Minkowski metric In mathematical physics, Minkowski space (or Minkowski spacetime) () is a combination of three-dimensional Euclidean space and time into a four-dimensional manifold where the spacetime interval between any two events is independent of the iner ...
(with ''mostly minus'' convention) in its determinant: :\det (x_\mu\sigma^\mu) = \eta(x,x). This 4-vector also has a completeness relation. It is convenient to define a second Pauli 4-vector :\bar\sigma^\mu = (I, -\vec\sigma). and allow raising and lowering using the Minkowski metric tensor. The relation can then be written x_\nu = \frac \operatorname \Bigl( \bar\sigma_\nu\bigl( x_\mu \sigma^\mu \bigr) \Bigr) ~. Similarly to the Pauli 3-vector case, we can find a matrix group which acts as isometries on \mathbb^; in this case the matrix group is \text(2,\mathbb), and this shows \text(2,\mathbb) \cong \text(1,3). Similarly to above, this can be explicitly realized for S \in \text(2,\mathbb) with components :\Lambda(S)^\mu_\nu = \frac\text\left(\bar\sigma_\nu S \sigma^\mu S^\right). In fact, the determinant property follows abstractly from trace properties of the \sigma^\mu. For 2\times 2 matrices, the following identity holds: :\det(A + B) = \det(A) + \det(B) + \text(A)\text(B) - \text(AB). That is, the 'cross-terms' can be written as traces. When A,B are chosen to be different \sigma^\mu, the cross-terms vanish. It then follows, now showing summation explicitly, \det\left(\sum_\mu x_\mu \sigma^\mu\right) = \sum_\mu \det\left(x_\mu\sigma^\mu\right). Since the matrices are 2 \times 2, this is equal to \sum_\mu x_\mu^2 \det(\sigma^\mu) = \eta(x,x).


(Anti-)Commutation relations

The Pauli matrices obey the following
commutation Commute, commutation or commutative may refer to: * Commuting, the process of travelling between a place of residence and a place of work Mathematics * Commutative property, a property of a mathematical operation whose result is insensitive to th ...
relations: : sigma_i, \sigma_j= 2 i \varepsilon_\,\sigma_k ~ , where the
structure constant In mathematics, the structure constants or structure coefficients of an algebra over a field are used to explicitly specify the product of two basis vectors in the algebra as a linear combination. Given the structure constants, the resulting pr ...
is the
Levi-Civita symbol In mathematics, particularly in linear algebra, tensor analysis, and differential geometry, the Levi-Civita symbol or Levi-Civita epsilon represents a collection of numbers; defined from the parity of a permutation, sign of a permutation of the n ...
and Einstein summation notation is used. These commutation relations make the Pauli matrices the generators of a representation of the Lie algebra (\mathbb^3, \times) \cong \mathfrak(2) \cong \mathfrak(3). They also satisfy the anticommutation relations: :\ = 2 \delta_\,I ~ , where is the
Kronecker delta In mathematics, the Kronecker delta (named after Leopold Kronecker) is a function of two variables, usually just non-negative integers. The function is 1 if the variables are equal, and 0 otherwise: \delta_ = \begin 0 &\text i \neq j, \\ 1 & ...
, and is the identity matrix. These anti-commutation relations make the Pauli matrices the generators of a representation of the
Clifford algebra In mathematics, a Clifford algebra is an algebra generated by a vector space with a quadratic form, and is a unital associative algebra. As -algebras, they generalize the real numbers, complex numbers, quaternions and several other hyperc ...
for \mathbb^3, denoted \text_3(\mathbb). The usual construction of generators \sigma_ = \frac sigma_i,\sigma_j/math> of \mathfrak(3) using the Clifford algebra recovers the commutation relations above, up to unimportant numerical factors. A few explicit commutators and anti-commutators are given below as examples:


Relation to dot and cross product

Pauli vectors elegantly map these commutation and anticommutation relations to corresponding vector products. Adding the commutator to the anticommutator gives : \begin \left sigma_j, \sigma_k\right+ \ &= (\sigma_j \sigma_k - \sigma_k \sigma_j ) + (\sigma_j \sigma_k + \sigma_k \sigma_j) \\ 2i\varepsilon_\,\sigma_\ell + 2 \delta_I &= 2\sigma_j \sigma_k \end so that, Contracting each side of the equation with components of two -vectors and (which commute with the Pauli matrices, i.e., for each matrix and vector component (and likewise with ) yields :~~ \begin a_j b_k \sigma_j \sigma_k & = a_j b_k \left(i\varepsilon_\,\sigma_\ell + \delta_I\right) \\ a_j \sigma_j b_k \sigma_k & = i\varepsilon_\,a_j b_k \sigma_\ell + a_j b_k \delta_I \end ~.~ Finally, translating the index notation for the
dot product In mathematics, the dot product or scalar productThe term ''scalar product'' means literally "product with a scalar as a result". It is also used sometimes for other symmetric bilinear forms, for example in a pseudo-Euclidean space. is an algebra ...
and
cross product In mathematics, the cross product or vector product (occasionally directed area product, to emphasize its geometric significance) is a binary operation on two vectors in a three-dimensional oriented Euclidean vector space (named here E), and is ...
results in If is identified with the pseudoscalar then the right hand side becomes a \cdot b + a \wedge b which is also the definition for the product of two vectors in geometric algebra. If we define the spin operator as , then satisfies the commutation relation:\mathbf \times \mathbf = i\hbar \mathbfOr equivalently, the Pauli vector satisfies:\frac \times \frac = i\frac


Some trace relations

The following traces can be derived using the commutation and anticommutation relations. :\begin \operatorname\left(\sigma_j \right) &= 0 \\ \operatorname\left(\sigma_j \sigma_k \right) &= 2\delta_ \\ \operatorname\left(\sigma_j \sigma_k \sigma_\ell \right) &= 2i\varepsilon_ \\ \operatorname\left(\sigma_j \sigma_k \sigma_\ell \sigma_m \right) &= 2\left(\delta_\delta_ - \delta_\delta_ + \delta_\delta_\right) \end If the matrix is also considered, these relationships become :\begin \operatorname\left(\sigma_\alpha \right) &= 2\delta_ \\ \operatorname\left(\sigma_\alpha \sigma_\beta \right) &= 2\delta_ \\ \operatorname\left(\sigma_\alpha \sigma_\beta \sigma_\gamma \right) &= 2 \sum_ \delta_ \delta_ - 4 \delta_ \delta_ \delta_ + 2i\varepsilon_ \\ \operatorname\left(\sigma_\alpha \sigma_\beta \sigma_\gamma \sigma_\mu \right) &= 2\left(\delta_\delta_ - \delta_\delta_ + \delta_\delta_\right) + 4\left(\delta_ \delta_ \delta_ + \delta_ \delta_ \delta_\right) - 8 \delta_ \delta_ \delta_ \delta_ + 2 i \sum_ \varepsilon_ \delta_ \end where Greek indices and assume values from and the notation \sum_ is used to denote the sum over the
cyclic permutation In mathematics, and in particular in group theory, a cyclic permutation (or cycle) is a permutation of the elements of some set ''X'' which maps the elements of some subset ''S'' of ''X'' to each other in a cyclic fashion, while fixing (that is, ma ...
of the included indices.


Exponential of a Pauli vector

For :\vec = a\hat, \quad , \hat, = 1, one has, for even powers, :(\hat \cdot \vec)^ = I which can be shown first for the case using the anticommutation relations. For convenience, the case is taken to be by convention. For odd powers, :\left(\hat \cdot \vec\right)^ = \hat \cdot \vec \, . Matrix exponentiating, and using the Taylor series for sine and cosine, :\begin e^ &= \sum_^\infty \\ &= \sum_^\infty + i\sum_^\infty \\ &= I\sum_^\infty + i (\hat\cdot \vec) \sum_^\infty\\ \end. In the last line, the first sum is the cosine, while the second sum is the sine; so, finally, which is
analogous Analogy (from Greek ''analogia'', "proportion", from ''ana-'' "upon, according to" lso "against", "anew"+ ''logos'' "ratio" lso "word, speech, reckoning" is a cognitive process of transferring information or meaning from a particular subject ...
to
Euler's formula Euler's formula, named after Leonhard Euler, is a mathematical formula in complex analysis that establishes the fundamental relationship between the trigonometric functions and the complex exponential function. Euler's formula states that fo ...
, extended to
quaternions In mathematics, the quaternion number system extends the complex numbers. Quaternions were first described by the Irish mathematician William Rowan Hamilton in 1843 and applied to mechanics in three-dimensional space. Hamilton defined a quater ...
. Note that :\det a(\hat \cdot \vec)= a^2, while the determinant of the exponential itself is just , which makes it the generic group element of
SU(2) In mathematics, the special unitary group of degree , denoted , is the Lie group of unitary matrices with determinant 1. The more general unitary matrices may have complex determinants with absolute value 1, rather than real 1 in the special ...
. A more abstract version of formula for a general matrix can be found in the article on matrix exponentials. A general version of for an analytic (at ''a'' and −''a'') function is provided by application of
Sylvester's formula In matrix theory, Sylvester's formula or Sylvester's matrix theorem (named after J. J. Sylvester) or Lagrange−Sylvester interpolation expresses an analytic function of a matrix as a polynomial in , in terms of the eigenvalues and eigenvectors ...
, :f(a(\hat \cdot \vec)) = I\frac + \hat \cdot \vec \frac ~.


The group composition law of

A straightforward application of formula provides a parameterization of the composition law of the group . One may directly solve for in :\begin e^ e^ &= I\left(\cos a \cos b - \hat \cdot \hat \sin a \sin b\right) + i\left(\hat \sin a \cos b + \hat \sin b \cos a - \hat \times \hat ~ \sin a \sin b \right) \cdot \vec \\ &= I\cos + i \left(\hat \cdot \vec\right) \sin c \\ &= e^, \end which specifies the generic group multiplication, where, manifestly, :\cos c = \cos a \cos b - \hat \cdot \hat \sin a \sin b~, the
spherical law of cosines In spherical trigonometry, the law of cosines (also called the cosine rule for sides) is a theorem relating the sides and angles of spherical triangles, analogous to the ordinary law of cosines from plane trigonometry. Given a unit sphere, a "sph ...
. Given , then, :\hat = \frac\left(\hat \sin a \cos b + \hat \sin b \cos a - \hat\times\hat \sin a \sin b\right) ~. Consequently, the composite rotation parameters in this group element (a closed form of the respective BCH expansion in this case) simply amount to (Of course, when \hat is parallel to \hat, so is \hat, and .)


Adjoint action

It is also straightforward to likewise work out the adjoint action on the Pauli vector, namely rotation of any angle a along any axis \hat n: : R_n(-a) ~ \vec ~ R_n(a) = e^ ~ \vec ~ e^ = \vec\cos (a) + \hat \times \vec ~ \sin(a) + \hat ~ \hat \cdot \vec ~ (1 - \cos(a)) ~ . Taking the dot product of any unit vector with the above formula generates the expression of any single qubit operator under any rotation. For example, it can be shown that R_y\mathord\left(-\frac\right)\, \sigma_x\, R_y\mathord\left(\frac\right) = \hat \cdot \left(\hat \times \vec\right) = \sigma_z.


Completeness relation

An alternative notation that is commonly used for the Pauli matrices is to write the vector index in the superscript, and the matrix indices as subscripts, so that the element in row and column of the -th Pauli matrix is In this notation, the ''completeness relation'' for the Pauli matrices can be written :\vec_\cdot\vec_\equiv \sum_^3 \sigma^k_\,\sigma^k_ = 2\,\delta_ \,\delta_ - \delta_\,\delta_~. As noted above, it is common to denote the 2 × 2 unit matrix by so The completeness relation can alternatively be expressed as \sum_^3 \sigma^k_\,\sigma^k_ = 2\,\delta_\,\delta_ ~ . The fact that any Hermitian
complex Complex commonly refers to: * Complexity, the behaviour of a system whose components interact in multiple ways so possible interactions are difficult to describe ** Complex system, a system composed of many components which may interact with each ...
2 × 2 matrices can be expressed in terms of the identity matrix and the Pauli matrices also leads to the
Bloch sphere In quantum quantum mechanics, mechanics and Quantum computing, computing, the Bloch sphere is a geometrical representation of the pure state space of a two-level system, two-level quantum mechanical system (qubit), named after the physicist Felix ...
representation of 2 × 2 mixed states’ density matrix, ( positive semidefinite 2 × 2 matrices with unit trace. This can be seen by first expressing an arbitrary Hermitian matrix as a real linear combination of as above, and then imposing the positive-semidefinite and
trace Trace may refer to: Arts and entertainment Music * ''Trace'' (Son Volt album), 1995 * ''Trace'' (Died Pretty album), 1993 * Trace (band), a Dutch progressive rock band * ''The Trace'' (album) Other uses in arts and entertainment * ''Trace'' ...
conditions. For a pure state, in polar coordinates, \vec = \begin\sin\theta \cos\phi & \sin\theta \sin\phi & \cos\theta\end, the
idempotent Idempotence (, ) is the property of certain operations in mathematics and computer science whereby they can be applied multiple times without changing the result beyond the initial application. The concept of idempotence arises in a number of pl ...
density matrix \tfrac \left(\mathbf + \vec \cdot \vec\right) = \begin \cos^2\left(\frac\right) & e^\sin\left(\frac\right)\cos\left(\frac\right) \\ e^\sin\left(\frac\right)\cos\left(\frac\right) & \sin^2\left(\frac\right) \end acts on the state eigenvector \begin\cos\left(\frac\right) & e^\,\sin\left(\frac\right) \end with eigenvalue +1, hence it acts like a
projection operator In linear algebra and functional analysis, a projection is a linear transformation P from a vector space to itself (an endomorphism) such that P\circ P=P. That is, whenever P is applied twice to any vector, it gives the same result as if it wer ...
.


Relation with the permutation operator

Let be the transposition (also known as a permutation) between two spins and living in the
tensor product In mathematics, the tensor product V \otimes W of two vector spaces and (over the same field) is a vector space to which is associated a bilinear map V\times W \to V\otimes W that maps a pair (v,w),\ v\in V, w\in W to an element of V \otime ...
space :P_ \left, \sigma_j \sigma_k \right\rangle = \left, \sigma_k \sigma_j \right\rangle ~. This operator can also be written more explicitly as Dirac's spin exchange operator, :P_ = \frac\,\left(\vec_j \cdot \vec_k + 1\right) ~ . Its eigenvalues are therefore 1 or −1. It may thus be utilized as an interaction term in a Hamiltonian, splitting the energy eigenvalues of its symmetric versus antisymmetric eigenstates.


SU(2)

The group
SU(2) In mathematics, the special unitary group of degree , denoted , is the Lie group of unitary matrices with determinant 1. The more general unitary matrices may have complex determinants with absolute value 1, rather than real 1 in the special ...
is the
Lie group In mathematics, a Lie group (pronounced ) is a group that is also a differentiable manifold. A manifold is a space that locally resembles Euclidean space, whereas groups define the abstract concept of a binary operation along with the additio ...
of
unitary Unitary may refer to: Mathematics * Unitary divisor * Unitary element * Unitary group * Unitary matrix * Unitary morphism * Unitary operator * Unitary transformation * Unitary representation * Unitarity (physics) * ''E''-unitary inverse semigrou ...
matrices with unit determinant; its
Lie algebra In mathematics, a Lie algebra (pronounced ) is a vector space \mathfrak g together with an Binary operation, operation called the Lie bracket, an Alternating multilinear map, alternating bilinear map \mathfrak g \times \mathfrak g \rightarrow ...
is the set of all anti-Hermitian matrices with trace 0. Direct calculation, as above, shows that the
Lie algebra In mathematics, a Lie algebra (pronounced ) is a vector space \mathfrak g together with an Binary operation, operation called the Lie bracket, an Alternating multilinear map, alternating bilinear map \mathfrak g \times \mathfrak g \rightarrow ...
\mathfrak_2 is the 3-dimensional real algebra spanned by the set . In compact notation, : \mathfrak(2) = \operatorname \~. As a result, each can be seen as an infinitesimal generator of SU(2). The elements of SU(2) are exponentials of linear combinations of these three generators, and multiply as indicated above in discussing the Pauli vector. Although this suffices to generate SU(2), it is not a proper representation of , as the Pauli eigenvalues are scaled unconventionally. The conventional normalization is so that : \mathfrak(2) = \operatorname \left\~. As SU(2) is a compact group, its
Cartan decomposition In mathematics, the Cartan decomposition is a decomposition of a semisimple Lie group or Lie algebra, which plays an important role in their structure theory and representation theory. It generalizes the polar decomposition or singular value decom ...
is trivial.


SO(3)

The Lie algebra \mathfrak(2) is
isomorphic In mathematics, an isomorphism is a structure-preserving mapping between two structures of the same type that can be reversed by an inverse mapping. Two mathematical structures are isomorphic if an isomorphism exists between them. The word is ...
to the Lie algebra \mathfrak(3), which corresponds to the Lie group
SO(3) In mechanics and geometry, the 3D rotation group, often denoted SO(3), is the group of all rotations about the origin of three-dimensional Euclidean space \R^3 under the operation of composition. By definition, a rotation about the origin is a tr ...
, the
group A group is a number of persons or things that are located, gathered, or classed together. Groups of people * Cultural group, a group whose members share the same cultural identity * Ethnic group, a group whose members share the same ethnic ide ...
of
rotation Rotation, or spin, is the circular movement of an object around a '' central axis''. A two-dimensional rotating object has only one possible central axis and can rotate in either a clockwise or counterclockwise direction. A three-dimensional ...
s in three-dimensional space. In other words, one can say that the are a realization (and, in fact, the lowest-dimensional realization) of ''infinitesimal'' rotations in three-dimensional space. However, even though \mathfrak(2) and \mathfrak(3) are isomorphic as Lie algebras, and are not isomorphic as Lie groups. is actually a double cover of , meaning that there is a two-to-one group homomorphism from to , see relationship between SO(3) and SU(2).


Quaternions

The real linear span of is isomorphic to the real algebra of
quaternions In mathematics, the quaternion number system extends the complex numbers. Quaternions were first described by the Irish mathematician William Rowan Hamilton in 1843 and applied to mechanics in three-dimensional space. Hamilton defined a quater ...
, \mathbb, represented by the span of the basis vectors \left\ . The isomorphism from \mathbb to this set is given by the following map (notice the reversed signs for the Pauli matrices): : \mathbf \mapsto I, \quad \mathbf \mapsto - \sigma_2\sigma_3 = - i\,\sigma_1, \quad \mathbf \mapsto - \sigma_3\sigma_1 = - i\,\sigma_2, \quad \mathbf \mapsto - \sigma_1\sigma_2 = - i\,\sigma_3. Alternatively, the isomorphism can be achieved by a map using the Pauli matrices in reversed order, : \mathbf \mapsto I, \quad \mathbf \mapsto i\,\sigma_3 \, , \quad \mathbf \mapsto i\,\sigma_2 \, , \quad \mathbf \mapsto i\,\sigma_1 ~ . As the set of
versor In mathematics, a versor is a quaternion of norm one (a ''unit quaternion''). The word is derived from Latin ''versare'' = "to turn" with the suffix ''-or'' forming a noun from the verb (i.e. ''versor'' = "the turner"). It was introduced by Will ...
s forms a group isomorphic to , gives yet another way of describing . The two-to-one homomorphism from to may be given in terms of the Pauli matrices in this formulation.


Physics


Classical mechanics

In
classical mechanics Classical mechanics is a physical theory describing the motion of macroscopic objects, from projectiles to parts of machinery, and astronomical objects, such as spacecraft, planets, stars, and galaxies. For objects governed by classical ...
, Pauli matrices are useful in the context of the Cayley-Klein parameters. The matrix corresponding to the position \vec of a point in space is defined in terms of the above Pauli vector matrix, :P = \vec \cdot \vec = x\,\sigma_x + y\,\sigma_y + z\,\sigma_z ~. Consequently, the transformation matrix for rotations about the -axis through an angle may be written in terms of Pauli matrices and the unit matrix as :Q_\theta = \boldsymbol\,\cos\frac + i\,\sigma_x \sin\frac ~. Similar expressions follow for general Pauli vector rotations as detailed above.


Quantum mechanics

In
quantum mechanics Quantum mechanics is a fundamental theory in physics that provides a description of the physical properties of nature at the scale of atoms and subatomic particles. It is the foundation of all quantum physics including quantum chemistry, ...
, each Pauli matrix is related to an
angular momentum operator In quantum mechanics, the angular momentum operator is one of several related operators analogous to classical angular momentum. The angular momentum operator plays a central role in the theory of atomic and molecular physics and other quantum prob ...
that corresponds to an
observable In physics, an observable is a physical quantity that can be measured. Examples include position and momentum. In systems governed by classical mechanics, it is a real-valued "function" on the set of all possible system states. In quantum ph ...
describing the spin of a spin particle, in each of the three spatial directions. As an immediate consequence of the Cartan decomposition mentioned above, are the generators of a
projective representation In the field of representation theory in mathematics, a projective representation of a group ''G'' on a vector space ''V'' over a field ''F'' is a group homomorphism from ''G'' to the projective linear group \mathrm(V) = \mathrm(V) / F^*, where G ...
(spin representation) of the
rotation group SO(3) In mechanics and geometry, the 3D rotation group, often denoted SO(3), is the group of all rotations about the origin of three-dimensional Euclidean space \R^3 under the operation of composition. By definition, a rotation about the origin is a ...
acting on non-relativistic particles with spin . The states of the particles are represented as two-component
spinors In geometry and physics, spinors are elements of a complex vector space that can be associated with Euclidean space. Like geometric vectors and more general tensors, spinors transform linearly when the Euclidean space is subjected to a slight ...
. In the same way, the Pauli matrices are related to the isospin operator. An interesting property of spin particles is that they must be rotated by an angle of 4 in order to return to their original configuration. This is due to the two-to-one correspondence between SU(2) and SO(3) mentioned above, and the fact that, although one visualizes spin up/down as the north/south pole on the 2-sphere they are actually represented by orthogonal vectors in the two dimensional complex
Hilbert space In mathematics, Hilbert spaces (named after David Hilbert) allow generalizing the methods of linear algebra and calculus from (finite-dimensional) Euclidean vector spaces to spaces that may be infinite-dimensional. Hilbert spaces arise natural ...
. For a spin particle, the spin operator is given by , the
fundamental representation In representation theory of Lie groups and Lie algebras, a fundamental representation is an irreducible representation, irreducible finite-dimensional representation of a semisimple Lie algebra, semisimple Lie group or Lie algebra whose highest weig ...
of
SU(2) In mathematics, the special unitary group of degree , denoted , is the Lie group of unitary matrices with determinant 1. The more general unitary matrices may have complex determinants with absolute value 1, rather than real 1 in the special ...
. By taking
Kronecker product In mathematics, the Kronecker product, sometimes denoted by ⊗, is an operation on two matrices of arbitrary size resulting in a block matrix. It is a generalization of the outer product (which is denoted by the same symbol) from vectors ...
s of this representation with itself repeatedly, one may construct all higher irreducible representations. That is, the resulting
spin operator Spin is a conserved quantity carried by elementary particles, and thus by composite particles (hadrons) and atomic nuclei. Spin is one of two types of angular momentum in quantum mechanics, the other being ''orbital angular momentum''. The orbita ...
s for higher spin systems in three spatial dimensions, for arbitrarily large ''j'', can be calculated using this
spin operator Spin is a conserved quantity carried by elementary particles, and thus by composite particles (hadrons) and atomic nuclei. Spin is one of two types of angular momentum in quantum mechanics, the other being ''orbital angular momentum''. The orbita ...
and
ladder operators In linear algebra (and its application to quantum mechanics), a raising or lowering operator (collectively known as ladder operators) is an operator that increases or decreases the eigenvalue of another operator. In quantum mechanics, the raisin ...
. They can be found in . The analog formula to the above generalization of Euler's formula for Pauli matrices, the group element in terms of spin matrices, is tractable, but less simple. Also useful in the
quantum mechanics Quantum mechanics is a fundamental theory in physics that provides a description of the physical properties of nature at the scale of atoms and subatomic particles. It is the foundation of all quantum physics including quantum chemistry, ...
of multiparticle systems, the general
Pauli group In physics and mathematics, the Pauli group G_1 on 1 qubit is the 16-element matrix group consisting of the 2 × 2 identity matrix I and all of the Pauli matrices :X = \sigma_1 = \begin 0&1\\ 1&0 \end,\quad Y = \sigma_2 = \begin ...
is defined to consist of all -fold
tensor In mathematics, a tensor is an algebraic object that describes a multilinear relationship between sets of algebraic objects related to a vector space. Tensors may map between different objects such as vectors, scalars, and even other tenso ...
products of Pauli matrices.


Relativistic quantum mechanics

In
relativistic quantum mechanics In physics, relativistic quantum mechanics (RQM) is any Poincaré covariant formulation of quantum mechanics (QM). This theory is applicable to massive particles propagating at all velocities up to those comparable to the speed of light ''c ...
, the spinors in four dimensions are 4 × 1 (or 1 × 4) matrices. Hence the Pauli matrices or the Sigma matrices operating on these spinors have to be 4 × 4 matrices. They are defined in terms of 2 × 2 Pauli matrices as :\mathsf_k = \begin \mathsf_k & 0 \\ 0 & \mathsf_k \end. It follows from this definition that the \; \mathsf_k \; matrices have the same algebraic properties as the matrices. However,
relativistic angular momentum In physics, relativistic angular momentum refers to the mathematical formalisms and physical concepts that define angular momentum in special relativity (SR) and general relativity (GR). The relativistic quantity is subtly different from the thr ...
is not a three-vector, but a second order
four-tensor In physics, specifically for special relativity and general relativity, a four-tensor is an abbreviation for a tensor in a four-dimensional spacetime.Lambourne, Robert J A. Relativity, Gravitation and Cosmology. Cambridge University Press. 20 ...
. Hence \mathsf_k needs to be replaced by the generator of Lorentz transformations on spinors. By the antisymmetry of angular momentum, the are also antisymmetric. Hence there are only six independent matrices. The first three are the \; \Sigma_\equiv \epsilon_\mathsf_j ~. The remaining three, \;-i\,\Sigma_ \equiv \mathsf_k\;, where the Dirac matrices are defined as :\mathsf_k = \begin 0 & \mathsf_k\\ \mathsf_k & 0\end~. The relativistic spin matrices are written in compact form in terms of commutator of
gamma matrices In mathematical physics, the gamma matrices, \left\ , also called the Dirac matrices, are a set of conventional matrices with specific anticommutation relations that ensure they generate a matrix representation of the Clifford algebra Cl1,3(\ma ...
as :\Sigma_ = \frac\left gamma_\mu, \gamma_\nu\right.


Quantum information

In
quantum information Quantum information is the information of the state of a quantum system. It is the basic entity of study in quantum information theory, and can be manipulated using quantum information processing techniques. Quantum information refers to both t ...
, single-
qubit In quantum computing, a qubit () or quantum bit is a basic unit of quantum information—the quantum version of the classic binary bit physically realized with a two-state device. A qubit is a two-state (or two-level) quantum-mechanical system, ...
quantum gate In quantum computing and specifically the quantum circuit model of computation, a quantum logic gate (or simply quantum gate) is a basic quantum circuit operating on a small number of qubits. They are the building blocks of quantum circuits, lik ...
s are 2 × 2 unitary matrices. The Pauli matrices are some of the most important single-qubit operations. In that context, the Cartan decomposition given above is called the "Z–Y decomposition of a single-qubit gate". Choosing a different Cartan pair gives a similar "X–Y ''decomposition of a single-qubit gate".


See also

*
Algebra of physical space In physics, the algebra of physical space (APS) is the use of the Clifford algebra, Clifford or geometric algebra Cl3,0(R) of the three-dimensional Euclidean space as a model for (3+1)-dimensional spacetime, representing a point in spacetime via a ...
*
Spinors in three dimensions In mathematics, the spinor concept as specialised to three dimensions can be treated by means of the traditional notions of dot product and cross product. This is part of the detailed algebraic discussion of the rotation group SO(3). Formulation ...
*
Gamma matrices In mathematical physics, the gamma matrices, \left\ , also called the Dirac matrices, are a set of conventional matrices with specific anticommutation relations that ensure they generate a matrix representation of the Clifford algebra Cl1,3(\ma ...
** *
Angular momentum In physics, angular momentum (rarely, moment of momentum or rotational momentum) is the rotational analog of linear momentum. It is an important physical quantity because it is a conserved quantity—the total angular momentum of a closed syst ...
*
Gell-Mann matrices The Gell-Mann matrices, developed by Murray Gell-Mann, are a set of eight linearly independent 3×3 traceless Hermitian matrices used in the study of the strong interaction in particle physics. They span the Lie algebra of the SU(3) group in t ...
*
Poincaré group The Poincaré group, named after Henri Poincaré (1906), was first defined by Hermann Minkowski (1908) as the group of Minkowski spacetime isometries. It is a ten-dimensional non-abelian Lie group that is of importance as a model in our und ...
* Generalizations of Pauli matrices *
Bloch sphere In quantum quantum mechanics, mechanics and Quantum computing, computing, the Bloch sphere is a geometrical representation of the pure state space of a two-level system, two-level quantum mechanical system (qubit), named after the physicist Felix ...
* Euler's four-square identity * For higher spin generalizations of the Pauli matrices, see *
Exchange matrix In mathematics, especially linear algebra, the exchange matrices (also called the reversal matrix, backward identity, or standard involutory permutation) are special cases of permutation matrices, where the 1 elements reside on the antidiagonal and ...
(the first Pauli matrix is an exchange matrix of order two)


Remarks


Notes


References

* * * {{Matrix classes Lie groups Matrices Rotational symmetry Articles containing proofs Mathematical physics