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Nitryl is the
nitrogen dioxide
Nitrogen dioxide is a chemical compound with the formula . It is one of several nitrogen oxides. is an intermediate in the industrial synthesis of nitric acid, millions of tons of which are produced each year for use primarily in the producti ...
(NO
2)
moiety
Moiety may refer to:
Chemistry
* Moiety (chemistry), a part or functional group of a molecule
** Moiety conservation, conservation of a subgroup in a chemical species
Anthropology
* Moiety (kinship), either of two groups into which a society is ...
when it occurs in a larger compound as a univalent fragment. Examples include
nitryl fluoride
Nitryl fluoride, NO2F, is a colourless gas and strong oxidizing agent, which is used as a fluorinating agent and has been proposed as an oxidiser in rocket propellants (though never flown).
It is a molecular species, not ionic, consistent with it ...
(NO
2F) and
nitryl chloride
Nitryl chloride is a volatile inorganic compound with formula ClNO2. At standard conditions it is a gas.
Formation
Nitryl chloride can be formed in the reaction of dinitrogen pentoxide with chlorides or hydrogen chloride:
:N2O5 + 2HCl → 2ClNO2 ...
(NO
2Cl).
Like nitrogen dioxide, the nitryl moiety contains a nitrogen atom with two bonds to the two oxygen atoms, and a third bond shared equally between the nitrogen and the two oxygen atoms. The nitrogen-centred radical is then free to form a bond with another univalent fragment (X) to produce an N−X bond, where X can be F, Cl, OH, etc.
In organic nomenclature, the nitryl moiety is known as the
nitro group
In organic chemistry, nitro compounds are organic compounds that contain one or more nitro functional groups (). The nitro group is one of the most common explosophores (functional group that makes a compound explosive) used globally. The nitr ...
. For instance, nitryl benzene is normally called nitrobenzene (PhNO
2).
See also
*
Dinitrogen tetroxide
Dinitrogen tetroxide, commonly referred to as nitrogen tetroxide (NTO), and occasionally (usually among ex-USSR/Russia rocket engineers) as amyl, is the chemical compound N2O4. It is a useful reagent in chemical synthesis. It forms an equilibrium ...
*
Nitro compound
In organic chemistry, nitro compounds are organic compounds that contain one or more nitro functional groups (). The nitro group is one of the most common explosophores (functional group that makes a compound explosive) used globally. The nitr ...
*
Nitrosyl
In organic chemistry, nitroso refers to a functional group in which the nitric oxide () group is attached to an organic moiety. As such, various nitroso groups can be categorized as ''C''-nitroso compounds (e.g., nitrosoalkanes; ), ''S''-nitroso ...
(R−N=O)
*
Isocyanide
An isocyanide (also called isonitrile or carbylamine) is an organic compound with the functional group –. It is the isomer of the related nitrile (–C≡N), hence the prefix is ''isocyano''.IUPAC Goldboo''isocyanides''/ref> The organic fragme ...
(R−N≡C)
*
Nitryl fluoride
Nitryl fluoride, NO2F, is a colourless gas and strong oxidizing agent, which is used as a fluorinating agent and has been proposed as an oxidiser in rocket propellants (though never flown).
It is a molecular species, not ionic, consistent with it ...
*
Nitrate
Nitrate is a polyatomic ion
A polyatomic ion, also known as a molecular ion, is a covalent bonded set of two or more atoms, or of a metal complex, that can be considered to behave as a single unit and that has a net charge that is not zer ...
References
Inorganic nitrogen compounds
Oxides
Free radicals
Nitrogen–oxygen compounds
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