Magma Crystallization
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Magma () is the molten or semi-molten natural material from which all igneous rocks are formed. Magma is found beneath the surface of the Earth, and evidence of magmatism has also been discovered on other terrestrial planets and some natural satellites. Besides molten rock, magma may also contain suspended crystals and gas bubbles. Magma is produced by melting of the
mantle A mantle is a piece of clothing, a type of cloak. Several other meanings are derived from that. Mantle may refer to: *Mantle (clothing), a cloak-like garment worn mainly by women as fashionable outerwear **Mantle (vesture), an Eastern Orthodox ve ...
or the crust in various tectonic settings, which on Earth include
subduction zone Subduction is a geological process in which the oceanic lithosphere is recycled into the Earth's mantle at convergent boundaries. Where the oceanic lithosphere of a tectonic plate converges with the less dense lithosphere of a second plate, the ...
s, continental rift zones, mid-ocean ridges and
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. Mantle and crustal melts migrate upwards through the crust where they are thought to be stored in magma chambers or trans-crustal crystal-rich mush zones. During magma's storage in the crust, its composition may be modified by
fractional crystallization Fractional crystallization may refer to: * Fractional crystallization (chemistry), a process to separate different solutes from a solution * Fractional crystallization (geology) Fractional crystallization, or crystal fractionation, is one of the ...
, contamination with crustal melts, magma mixing, and degassing. Following its ascent through the crust, magma may feed a volcano and be extruded as lava, or it may solidify underground to form an
intrusion In geology, an igneous intrusion (or intrusive body or simply intrusion) is a body of intrusive igneous rock that forms by crystallization of magma slowly cooling below the surface of the Earth. Intrusions have a wide variety of forms and com ...
, such as a
dike Dyke (UK) or dike (US) may refer to: General uses * Dyke (slang), a slang word meaning "lesbian" * Dike (geology), a subvertical sheet-like intrusion of magma or sediment * Dike (mythology), ''Dikē'', the Greek goddess of moral justice * Dikes, ...
, a
sill Sill may refer to: * Sill (dock), a weir at the low water mark retaining water within a dock * Sill (geology), a subhorizontal sheet intrusion of molten or solidified magma * Sill (geostatistics) * Sill (river), a river in Austria * Sill plate, a ...
, a laccolith, a
pluton In geology, an igneous intrusion (or intrusive body or simply intrusion) is a body of intrusive igneous rock that forms by crystallization of magma slowly cooling below the surface of the Earth. Intrusions have a wide variety of forms and com ...
, or a
batholith A batholith () is a large mass of intrusive igneous rock (also called plutonic rock), larger than in area, that forms from cooled magma deep in Earth's crust. Batholiths are almost always made mostly of felsic or intermediate rock types, such ...
. While the study of magma has relied on observing magma after its transition into a
lava flow Lava is molten or partially molten rock (magma) that has been expelled from the interior of a terrestrial planet (such as Earth) or a moon onto its surface. Lava may be erupted at a volcano or through a fracture in the crust, on land or und ...
, magma has been encountered in situ three times during geothermal drilling projects, twice in Iceland (see Use in energy production) and once in Hawaii.


Physical and chemical properties

Magma consists of liquid rock that usually contains suspended solid crystals. As magma approaches the surface and the overburden pressure drops, dissolved gases bubble out of the liquid, so that magma near the surface consists of materials in solid, liquid, and gas phases.


Composition

Most magma is rich in silica. Rare nonsilicate magma can form by local melting of nonsilicate mineral deposits or by separation of a magma into separate
immiscible Miscibility () is the property of two chemical substance, substances to mix in all mixing ratio, proportions (that is, to fully dissolution (chemistry), dissolve in each other at any concentration), forming a homogeneity and heterogeneity, homoge ...
silicate and nonsilicate liquid phases. Silicate magmas are molten mixtures dominated by oxygen and silicon, the most abundant chemical elements in the Earth's crust, with smaller quantities of aluminium, calcium, magnesium, iron, sodium, and potassium, and minor amounts of many other elements. Petrologists routinely express the composition of a silicate magma in terms of the weight or molar mass fraction of the oxides of the major elements (other than oxygen) present in the magma. Because many of the properties of a magma (such as its viscosity and temperature) are observed to correlate with silica content, silicate magmas are divided into four chemical types based on silica content: ''felsic'', ''intermediate'', ''mafic'', and ''ultramafic''.


Felsic magma

''Felsic'' or silicic magmas have a silica content greater than 63%. They include
rhyolite Rhyolite ( ) is the most silica-rich of volcanic rocks. It is generally glassy or fine-grained (aphanitic) in texture, but may be porphyritic, containing larger mineral crystals (phenocrysts) in an otherwise fine-grained groundmass. The mineral ...
and dacite magmas. With such a high silica content, these magmas are extremely viscous, ranging from 108 cP (105 Pa⋅s) for hot rhyolite magma at to 1011 cP (108 Pa⋅s) for cool rhyolite magma at . For comparison, water has a viscosity of about 1 cP (0.001 Pa⋅s). Because of this very high viscosity, felsic lavas usually erupt explosively to produce
pyroclastic Pyroclastic rocks (derived from the el, πῦρ, links=no, meaning fire; and , meaning broken) are clastic rocks composed of rock fragments produced and ejected by explosive volcanic eruptions. The individual rock fragments are known as pyroc ...
(fragmental) deposits. However, rhyolite lavas occasionally erupt effusively to form
lava spine Lava is molten or partially molten rock (magma) that has been expelled from the interior of a terrestrial planet (such as Earth) or a moon onto its surface. Lava may be erupted at a volcano or through a fracture in the crust, on land or un ...
s,
lava dome In volcanology, a lava dome is a circular mound-shaped protrusion resulting from the slow extrusion of viscous lava from a volcano. Dome-building eruptions are common, particularly in convergent plate boundary settings. Around 6% of eruptions on ...
s or "coulees" (which are thick, short lava flows). The lavas typically fragment as they extrude, producing block lava flows. These often contain
obsidian Obsidian () is a naturally occurring volcanic glass formed when lava extrusive rock, extruded from a volcano cools rapidly with minimal crystal growth. It is an igneous rock. Obsidian is produced from felsic lava, rich in the lighter elements s ...
. Felsic lavas can erupt at temperatures as low as . Unusually hot (>950 °C; >1,740 °F) rhyolite lavas, however, may flow for distances of many tens of kilometres, such as in the
Snake River Plain image:Snake River view near Twin Falls, Idaho.jpg, The Snake River cutting through the plain leaves many canyons and Canyon#List of gorges, gorges, such as this one near Twin Falls, Idaho The Snake River Plain is a geology, geologic feature ...
of the northwestern United States.


Intermediate magma

''Intermediate'' or andesitic magmas contain 52% to 63% silica, and are lower in aluminium and usually somewhat richer in magnesium and iron than felsic magmas. Intermediate lavas form andesite domes and block lavas, and may occur on steep composite volcanoes, such as in the Andes. They are also commonly hotter, in the range of ). Because of their lower silica content and higher eruptive temperatures, they tend to be much less viscous, with a typical viscosity of 3.5 × 106 cP (3,500 Pa⋅s) at . This is slightly greater than the viscosity of smooth
peanut butter Peanut butter is a food paste or spread made from ground, dry-roasted peanuts. It commonly contains additional ingredients that modify the taste or texture, such as salt, sweeteners, or emulsifiers. Peanut butter is consumed in many countri ...
. Intermediate magmas show a greater tendency to form phenocrysts, Higher iron and magnesium tends to manifest as a darker
groundmass The matrix or groundmass of a rock is the finer-grained mass of material in which larger grains, crystals, or clasts are embedded. The matrix of an igneous rock consists of finer-grained, often microscopic, crystals in which larger crystals, ca ...
, including amphibole or pyroxene phenocrysts.


Mafic magmas

''Mafic'' or basaltic magmas have a silica content of 52% to 45%. They are typified by their high ferromagnesian content, and generally erupt at temperatures of . Viscosities can be relatively low, around 104 to 105 cP (10 to 100 Pa⋅s), although this is still many orders of magnitude higher than water. This viscosity is similar to that of ketchup. Basalt lavas tend to produce low-profile
shield volcano A shield volcano is a type of volcano named for its low profile, resembling a warrior's shield lying on the ground. It is formed by the eruption of highly fluid (low viscosity) lava, which travels farther and forms thinner flows than the more v ...
es or flood basalts, because the fluidal lava flows for long distances from the vent. The thickness of a basalt lava, particularly on a low slope, may be much greater than the thickness of the moving lava flow at any one time, because basalt lavas may "inflate" by supply of lava beneath a solidified crust. Most basalt lavas are of '' ʻAʻā'' or '' pāhoehoe'' types, rather than block lavas. Underwater, they can form pillow lavas, which are rather similar to entrail-type pahoehoe lavas on land.


Ultramafic magmas

''Ultramafic'' magmas, such as picritic basalt,
komatiite Komatiite () is a type of ultramafic mantle-derived volcanic rock defined as having crystallised from a lava of at least 18 wt% MgO. Komatiites have low silicon, potassium and aluminium, and high to extremely high magnesium content. Komatiite wa ...
, and highly magnesian magmas that form
boninite Boninite is an extrusive rock high in both magnesium and silica, thought to be usually formed in fore-arc environments, typically during the early stages of subduction. The rock is named for its occurrence in the Izu-Bonin arc south of Japan. It ...
, take the composition and temperatures to the extreme. All have a silica content under 45%. Komatiites contain over 18% magnesium oxide, and are thought to have erupted at temperatures of . At this temperature there is practically no polymerization of the mineral compounds, creating a highly mobile liquid. Viscosities of komatiite magmas are thought to have been as low as 100 to 1000 cP (0.1 to 1 Pa⋅s), similar to that of light motor oil. Most ultramafic lavas are no younger than the
Proterozoic The Proterozoic () is a geological eon spanning the time interval from 2500 to 538.8million years ago. It is the most recent part of the Precambrian "supereon". It is also the longest eon of the Earth's geologic time scale, and it is subdivided ...
, with a few ultramafic magmas known from the
Phanerozoic The Phanerozoic Eon is the current geologic eon in the geologic time scale, and the one during which abundant animal and plant life has existed. It covers 538.8 million years to the present, and it began with the Cambrian Period, when anima ...
in Central America that are attributed to a hot mantle plume. No modern komatiite lavas are known, as the Earth's mantle has cooled too much to produce highly magnesian magmas.


Alkaline magmas

Some silicic magmas have an elevated content of alkali metal oxides (sodium and potassium), particularly in regions of
continental rifting In geology, a rift is a linear zone where the lithosphere is being pulled apart and is an example of extensional tectonics. Typical rift features are a central linear downfaulted depression, called a graben, or more commonly a half-graben wi ...
, areas overlying deeply
subducted Subduction is a geological process in which the oceanic lithosphere is recycled into the Earth's mantle at convergent boundaries. Where the oceanic lithosphere of a tectonic plate converges with the less dense lithosphere of a second plate, the ...
plates, or at intraplate
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. Their silica content can range from ultramafic ( nephelinites,
basanite Basanite () is an igneous, volcanic (extrusive) rock with aphanitic to porphyritic texture. It is composed mostly of feldspathoids, pyroxenes, olivine, and plagioclase and forms from magma low in silica and enriched in alkali metal oxides that s ...
s and tephrites) to felsic ( trachytes). They are more likely to be generated at greater depths in the mantle than subalkaline magmas. Olivine nephelinite magmas are both ultramafic and highly alkaline, and are thought to have come from much deeper in the
mantle A mantle is a piece of clothing, a type of cloak. Several other meanings are derived from that. Mantle may refer to: *Mantle (clothing), a cloak-like garment worn mainly by women as fashionable outerwear **Mantle (vesture), an Eastern Orthodox ve ...
of the Earth than other magmas.


Nonsilicic magmas

Some lavas of unusual composition have erupted onto the surface of the Earth. These include: * Carbonatite and natrocarbonatite lavas are known from Ol Doinyo Lengai volcano in Tanzania, which is the sole example of an active carbonatite volcano. Carbonatites in the geologic record are typically 75% carbonate minerals, with lesser amounts of silica-undersaturated silicate minerals (such as
mica Micas ( ) are a group of silicate minerals whose outstanding physical characteristic is that individual mica crystals can easily be split into extremely thin elastic plates. This characteristic is described as perfect basal cleavage. Mica is ...
s and olivine),
apatite Apatite is a group of phosphate minerals, usually hydroxyapatite, fluorapatite and chlorapatite, with high concentrations of OH−, F− and Cl− ions, respectively, in the crystal. The formula of the admixture of the three most common e ...
, magnetite, and pyrochlore. This may not reflect the original composition of the lava, which may have included
sodium carbonate Sodium carbonate, , (also known as washing soda, soda ash and soda crystals) is the inorganic compound with the formula Na2CO3 and its various hydrates. All forms are white, odourless, water-soluble salts that yield moderately alkaline solutions ...
that was subsequently removed by hydrothermal activity, though laboratory experiments show that a calcite-rich magma is possible. Carbonatite lavas show stable isotope ratios indicating they are derived from the highly alkaline silicic lavas with which they are always associated, probably by separation of an immiscible phase. Natrocarbonatite lavas of Ol Doinyo Lengai are composed mostly of sodium carbonate, with about half as much calcium carbonate and half again as much potassium carbonate, and minor amounts of halides, fluorides, and sulphates. The lavas are extremely fluid, with viscosities only slightly greater than water, and are very cool, with measured temperatures of . *
Iron oxide Iron oxides are chemical compounds composed of iron and oxygen. Several iron oxides are recognized. All are black magnetic solids. Often they are non-stoichiometric. Oxyhydroxides are a related class of compounds, perhaps the best known of whic ...
magmas are thought to be the source of the
iron ore Iron ores are rocks and minerals from which metallic iron can be economically extracted. The ores are usually rich in iron oxides and vary in color from dark grey, bright yellow, or deep purple to rusty red. The iron is usually found in the fo ...
at
Kiruna (; se, Giron ; fi, Kiiruna ) is the northernmost Stad (Sweden), city in Sweden, situated in the province of Lapland, Sweden, Lapland. It had 17,002 inhabitants in 2016 and is the seat of Kiruna Municipality (population: 23,167 in 2016) in Norr ...
,
Sweden Sweden, formally the Kingdom of Sweden,The United Nations Group of Experts on Geographical Names states that the country's formal name is the Kingdom of SwedenUNGEGN World Geographical Names, Sweden./ref> is a Nordic country located on ...
which formed during the
Proterozoic The Proterozoic () is a geological eon spanning the time interval from 2500 to 538.8million years ago. It is the most recent part of the Precambrian "supereon". It is also the longest eon of the Earth's geologic time scale, and it is subdivided ...
. Iron oxide lavas of Pliocene age occur at the El Laco volcanic complex on the Chile-Argentina border. Iron oxide lavas are thought to be the result of
immiscible Miscibility () is the property of two chemical substance, substances to mix in all mixing ratio, proportions (that is, to fully dissolution (chemistry), dissolve in each other at any concentration), forming a homogeneity and heterogeneity, homoge ...
separation of iron oxide magma from a parental magma of calc-alkaline or alkaline composition. *
Sulfur Sulfur (or sulphur in British English) is a chemical element with the symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with a chemical formula ...
lava flows up to long and wide occur at
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volcano, Chile. They were formed by the melting of sulfur deposits at temperatures as low as .


Magmatic gases

The concentrations of different gases can vary considerably. Water vapor is typically the most abundant magmatic gas, followed by carbon dioxide and
sulfur dioxide Sulfur dioxide (IUPAC-recommended spelling) or sulphur dioxide (traditional Commonwealth English) is the chemical compound with the formula . It is a toxic gas responsible for the odor of burnt matches. It is released naturally by volcanic activ ...
. Other principal magmatic gases include
hydrogen sulfide Hydrogen sulfide is a chemical compound with the formula . It is a colorless chalcogen-hydride gas, and is poisonous, corrosive, and flammable, with trace amounts in ambient atmosphere having a characteristic foul odor of rotten eggs. The unde ...
, hydrogen chloride, and
hydrogen fluoride Hydrogen fluoride (fluorane) is an inorganic compound with the chemical formula . This colorless gas or liquid is the principal industrial source of fluorine, often as an aqueous solution called hydrofluoric acid. It is an important feedstock i ...
. The solubility of magmatic gases in magma depends on pressure, magma composition, and temperature. Magma that is extruded as lava is extremely dry, but magma at depth and under great pressure can contain a dissolved water content in excess of 10%. Water is somewhat less soluble in low-silica magma than high-silica magma, so that at 1,100 °C and 0.5 GPa, a basaltic magma can dissolve 8% while a granite pegmatite magma can dissolve 11% . However, magmas are not necessarily saturated under typical conditions. Carbon dioxide is much less soluble in magmas than water, and frequently separates into a distinct fluid phase even at great depth. This explains the presence of carbon dioxide fluid inclusions in crystals formed in magmas at great depth.


Rheology

Viscosity is a key melt property in understanding the behaviour of magmas. Whereas temperatures in common silicate lavas range from about for felsic lavas to for mafic lavas, the viscosity of the same lavas ranges over seven orders of magnitude, from 104 cP (10 Pa⋅s) for mafic lava to 1011 cP (108 Pa⋅s) for felsic magmas. The viscosity is mostly determined by composition but is also dependent on temperature. The tendency of felsic lava to be cooler than mafic lava increases the viscosity difference. The silicon ion is small and highly charged, and so it has a strong tendency to coordinate with four oxygen ions, which form a tetrahedral arrangement around the much smaller silicon ion. This is called a ''silica tetrahedron''. In a magma that is low in silicon, these silica tetrahedra are isolated, but as the silicon content increases, silica tetrahedra begin to partially polymerize, forming chains, sheets, and clumps of silica tetrahedra linked by bridging oxygen ions. These greatly increase the viscosity of the magma. File:Single tet.png, A single silica tetrahedron File:Double tet.png, Two silica tetrahedra joined by a bridging oxygen ion (tinted pink) The tendency towards polymerization is expressed as NBO/T, where NBO is the number of non-bridging oxygen ions and T is the number of network-forming ions. Silicon is the main network-forming ion, but in magmas high in sodium, aluminium also acts as a network former, and ferric iron can act as a network former when other network formers are lacking. Most other metallic ions reduce the tendency to polymerize and are described as network modifiers. In a hypothetical magma formed entirely from melted silica, NBO/T would be 0, while in a hypothetical magma so low in network formers that no polymerization takes place, NBO/T would be 4. Neither extreme is common in nature, but basalt magmas typically have NBO/T between 0.6 and 0.9, andesitic magmas have NBO/T of 0.3 to 0.5, and rhyolitic magmas have NBO/T of 0.02 to 0.2. Water acts as a network modifier, and dissolved water drastically reduces melt viscosity. Carbon dioxide neutralizes network modifiers, so dissolved carbon dioxide increases the viscosity. Higher-temperature melts are less viscous, since more thermal energy is available to break bonds between oxygen and network formers. Most magmas contain solid crystals of various minerals, fragments of exotic rocks known as xenoliths and fragments of previously solidified magma. The crystal content of most magmas gives them thixotropic and shear thinning properties. In other words, most magmas do not behave like Newtonian fluids, in which the rate of flow is proportional to the shear stress. Instead, a typical magma is a Bingham fluid, which shows considerable resistance to flow until a stress threshold, called the yield stress, is crossed. This results in plug flow of partially crystalline magma. A familiar example of plug flow is toothpaste squeezed out of a toothpaste tube. The toothpaste comes out as a semisolid plug, because shear is concentrated in a thin layer in the toothpaste next to the tube, and only here does the toothpaste behave as a fluid. Thixotropic behavior also hinders crystals from settling out of the magma. Once the crystal content reaches about 60%, the magma ceases to behave like a fluid and begins to behave like a solid. Such a mixture of crystals with melted rock is sometimes described as ''crystal mush''. Magma is typically also viscoelastic, meaning it flows like a liquid under low stresses, but once the applied stress exceeds a critical value, the melt cannot dissipate the stress fast enough through relaxation alone, resulting in transient fracture propagation. Once stresses are reduced below the critical threshold, the melt viscously relaxes once more and heals the fracture.


Temperature

Temperatures of lava, which is magma extruded onto the surface, are in the range , but very rare carbonatite magmas may be as cool as , and
komatiite Komatiite () is a type of ultramafic mantle-derived volcanic rock defined as having crystallised from a lava of at least 18 wt% MgO. Komatiites have low silicon, potassium and aluminium, and high to extremely high magnesium content. Komatiite wa ...
magmas may have been as hot as . Magma has occasionally been encountered during drilling in geothermal fields, including drilling in Hawaii that penetrated a dacitic magma body at a depth of . The temperature of this magma was estimated at . Temperatures of deeper magmas must be inferred from theoretical computations and the geothermal gradient. Most magmas contain some solid crystals suspended in the liquid phase. This indicates that the temperature of the magma lies between the solidus, which is defined as the temperature at which the magma completely solidifies, and the
liquidus The liquidus temperature, TL or Tliq, specifies the temperature above which a material is completely liquid, and the maximum temperature at which crystals can co-exist with the melt in thermodynamic equilibrium. It is mostly used for impure subst ...
, defined as the temperature at which the magma is completely liquid. Calculations of solidus temperatures at likely depths suggests that magma generated beneath areas of rifting starts at a temperature of about . Magma generated from mantle plumes may be as hot as . The temperature of magma generated in subduction zones, where water vapor lowers the melting temperature, may be as low as .


Density

Magma densities depend mostly on composition, iron content being the most important parameter.usu.edu - ''Geology'' 326, "Properties of Magmas"
2005-02-11
Magma expands slightly at lower pressure or higher temperature. When magma approaches the surface, its dissolved gases begin to bubble out of the liquid. These bubbles had significantly reduced the density of the magma at depth and helped drive it toward the surface in the first place.


Origins

The temperature within the interior of the earth is described by the geothermal gradient, which is the rate of temperature change with depth. The geothermal gradient is established by the balance between heating through
radioactive decay Radioactive decay (also known as nuclear decay, radioactivity, radioactive disintegration, or nuclear disintegration) is the process by which an unstable atomic nucleus loses energy by radiation. A material containing unstable nuclei is consid ...
in the Earth's interior and heat loss from the surface of the earth. The geothermal gradient averages about 25 °C/km in the Earth's upper crust, but this varies widely by region, from a low of 5–10 °C/km within oceanic trenches and subduction zones to 30–80 °C/km along mid-ocean ridges or near mantle plumes. The gradient becomes less steep with depth, dropping to just 0.25 to 0.3  °C/km in the mantle, where slow convection efficiently transports heat. The average geothermal gradient is not normally steep enough to bring rocks to their melting point anywhere in the crust or upper mantle, so magma is produced only where the geothermal gradient is unusually steep or the melting point of the rock is unusually low. However, the ascent of magma towards the surface in such settings is the most important process for transporting heat through the crust of the Earth. Rocks may melt in response to a decrease in pressure, to a change in composition (such as an addition of water), to an increase in temperature, or to a combination of these processes. Other mechanisms, such as melting from a meteorite impact, are less important today, but impacts during the
accretion Accretion may refer to: Science * Accretion (astrophysics), the formation of planets and other bodies by collection of material through gravity * Accretion (meteorology), the process by which water vapor in clouds forms water droplets around nucl ...
of the Earth led to extensive melting, and the outer several hundred kilometers of our early Earth was probably an ocean of magma. Impacts of large meteorites in the last few hundred million years have been proposed as one mechanism responsible for the extensive basalt magmatism of several large igneous provinces.


Decompression

Decompression melting occurs because of a decrease in pressure. It is the most important mechanism for producing magma from the upper mantle. The solidus temperatures of most rocks (the temperatures below which they are completely solid) increase with increasing pressure in the absence of water.
Peridotite Peridotite ( ) is a dense, coarse-grained igneous rock consisting mostly of the silicate minerals olivine and pyroxene. Peridotite is ultramafic, as the rock contains less than 45% silica. It is high in magnesium (Mg2+), reflecting the high prop ...
at depth in the Earth's mantle may be hotter than its solidus temperature at some shallower level. If such rock rises during the convection of solid mantle, it will cool slightly as it expands in an adiabatic process, but the cooling is only about 0.3 °C per kilometer. Experimental studies of appropriate
peridotite Peridotite ( ) is a dense, coarse-grained igneous rock consisting mostly of the silicate minerals olivine and pyroxene. Peridotite is ultramafic, as the rock contains less than 45% silica. It is high in magnesium (Mg2+), reflecting the high prop ...
samples document that the solidus temperatures increase by 3 °C to 4 °C per kilometer. If the rock rises far enough, it will begin to melt. Melt droplets can coalesce into larger volumes and be intruded upwards. This process of melting from the upward movement of solid mantle is critical in the evolution of the Earth. Decompression melting creates the ocean crust at mid-ocean ridges, making it by far the most important source of magma on Earth. It also causes volcanism in intraplate regions, such as Europe, Africa and the Pacific sea floor. Intraplate volcanism is attributed to the rise of mantle plumes or to intraplate extension, with the importance of each mechanism being a topic of continuing research.


Effects of water and carbon dioxide

The change of rock composition most responsible for the creation of magma is the addition of water. Water lowers the solidus temperature of rocks at a given pressure. For example, at a depth of about 100 kilometers, peridotite begins to melt near 800 °C in the presence of excess water, but near 1,500 °C in the absence of water. Water is driven out of the oceanic
lithosphere A lithosphere () is the rigid, outermost rocky shell of a terrestrial planet or natural satellite. On Earth, it is composed of the crust (geology), crust and the portion of the upper mantle (geology), mantle that behaves elastically on time sca ...
in
subduction zone Subduction is a geological process in which the oceanic lithosphere is recycled into the Earth's mantle at convergent boundaries. Where the oceanic lithosphere of a tectonic plate converges with the less dense lithosphere of a second plate, the ...
s, and it causes melting in the overlying mantle. Hydrous magmas with the composition of basalt or andesite are produced directly and indirectly as results of dehydration during the subduction process. Such magmas, and those derived from them, build up island arcs such as those in the Pacific Ring of Fire. These magmas form rocks of the calc-alkaline series, an important part of the continental crust. The addition of carbon dioxide is relatively a much less important cause of magma formation than the addition of water, but genesis of some silica-undersaturated magmas has been attributed to the dominance of carbon dioxide over water in their mantle source regions. In the presence of carbon dioxide, experiments document that the peridotite solidus temperature decreases by about 200 °C in a narrow pressure interval at pressures corresponding to a depth of about 70 km. At greater depths, carbon dioxide can have more effect: at depths to about 200 km, the temperatures of initial melting of a carbonated peridotite composition were determined to be 450 °C to 600 °C lower than for the same composition with no carbon dioxide. Magmas of rock types such as nephelinite, carbonatite, and kimberlite are among those that may be generated following an influx of carbon dioxide into mantle at depths greater than about 70 km.


Temperature increase

Increase in temperature is the most typical mechanism for formation of magma within continental crust. Such temperature increases can occur because of the upward intrusion of magma from the mantle. Temperatures can also exceed the solidus of a crustal rock in continental crust thickened by compression at a plate boundary. The plate boundary between the Indian and Asian continental masses provides a well-studied example, as the Tibetan Plateau just north of the boundary has crust about 80 kilometers thick, roughly twice the thickness of normal continental crust. Studies of electrical resistivity deduced from magnetotelluric data have detected a layer that appears to contain
silicate In chemistry, a silicate is any member of a family of polyatomic anions consisting of silicon and oxygen, usually with the general formula , where . The family includes orthosilicate (), metasilicate (), and pyrosilicate (, ). The name is al ...
melt and that stretches for at least 1,000 kilometers within the middle crust along the southern margin of the Tibetan Plateau. Granite and
rhyolite Rhyolite ( ) is the most silica-rich of volcanic rocks. It is generally glassy or fine-grained (aphanitic) in texture, but may be porphyritic, containing larger mineral crystals (phenocrysts) in an otherwise fine-grained groundmass. The mineral ...
are types of igneous rock commonly interpreted as products of the melting of continental crust because of increases in temperature. Temperature increases also may contribute to the melting of
lithosphere A lithosphere () is the rigid, outermost rocky shell of a terrestrial planet or natural satellite. On Earth, it is composed of the crust (geology), crust and the portion of the upper mantle (geology), mantle that behaves elastically on time sca ...
dragged down in a subduction zone.


The melting process

When rocks melt, they do so over a range of temperature, because most rocks are made of several minerals, which all have different melting points. The temperature at which the first melt appears (the solidus) is lower than the melting temperature of any one of the pure minerals. This is similar to the lowering of the melting point of ice when it is mixed with salt. The first melt is called the '' eutectic'' and has a composition that depends on the combination of minerals present. For example, a mixture of
anorthite Anorthite is the calcium endmember of the plagioclase feldspar mineral series. The chemical formula of pure anorthite is Ca Al2 Si2O8. Anorthite is found in mafic igneous rocks. Anorthite is rare on the Earth but abundant on the Moon. Mineralo ...
and diopside, which are two of the predominant minerals in basalt, begins to melt at about 1274 °C. This is well below the melting temperatures of 1392 °C for pure diopside and 1553 °C for pure anorthite. The resulting melt is composed of about 43 wt% anorthite. As additional heat is added to the rock, the temperature remains at 1274 °C until either the anorthite or diopside is fully melted. The temperature then rises as the remaining mineral continues to melt, which shifts the melt composition away from the eutectic. For example, if the content of anorthite is greater than 43%, the entire supply of diopside will melt at 1274 °C., along with enough of the anorthite to keep the melt at the eutectic composition. Further heating causes the temperature to slowly rise as the remaining anorthite gradually melts and the melt becomes increasingly rich in anorthite liquid. If the mixture has only a slight excess of anorthite, this will melt before the temperature rises much above 1274 °C. If the mixture is almost all anorthite, the temperature will reach nearly the melting point of pure anorthite before all the anorthite is melted. If the anorthite content of the mixture is less than 43%, then all the anorthite will melt at the eutectic temperature, along with part of the diopside, and the remaining diopside will then gradually melt as the temperature continues to rise. Because of eutectic melting, the composition of the melt can be quite different from the source rock. For example, a mixture of 10% anorthite with diopside could experience about 23% partial melting before the melt deviated from the eutectic, which has the composition of about 43% anorthite. This effect of partial melting is reflected in the compositions of different magmas. A low degree of partial melting of the upper mantle (2% to 4%) can produce highly alkaline magmas such as
melilitite Melilite refers to a mineral of the melilite group. Minerals of the group are solid solutions of several endmembers, the most important of which are gehlenite and åkermanite. A generalized formula for common melilite is ( Ca, Na)2( Al, Mg, F ...
s, while a greater degree of partial melting (8% to 11%) can produce alkali olivine basalt. Oceanic magmas likely result from partial melting of 3% to 15% of the source rock. Some calk-alkaline granitoids may be produced by a high degree of partial melting, as much as 15% to 30%. High-magnesium magmas, such as
komatiite Komatiite () is a type of ultramafic mantle-derived volcanic rock defined as having crystallised from a lava of at least 18 wt% MgO. Komatiites have low silicon, potassium and aluminium, and high to extremely high magnesium content. Komatiite wa ...
and picrite, may also be the products of a high degree of partial melting of mantle rock. Certain chemical elements, called incompatible elements, have a combination of ionic radius and
ionic charge An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by convent ...
that is unlike that of the more abundant elements in the source rock. The ions of these elements fit rather poorly in the structure of the minerals making up the source rock, and readily leave the solid minerals to become highly concentrated in melts produced by a low degree of partial melting. Incompatible elements commonly include potassium,
barium Barium is a chemical element with the symbol Ba and atomic number 56. It is the fifth element in group 2 and is a soft, silvery alkaline earth metal. Because of its high chemical reactivity, barium is never found in nature as a free element. Th ...
,
caesium Caesium (IUPAC spelling) (or cesium in American English) is a chemical element with the symbol Cs and atomic number 55. It is a soft, silvery-golden alkali metal with a melting point of , which makes it one of only five elemental metals that a ...
, and
rubidium Rubidium is the chemical element with the symbol Rb and atomic number 37. It is a very soft, whitish-grey solid in the alkali metal group, similar to potassium and caesium. Rubidium is the first alkali metal in the group to have a density higher ...
, which are large and weakly charged (the large-ion lithophile elements, or LILEs), as well as elements whose ions carry a high charge (the high-field-strength elements, or HSFEs), which include such elements as zirconium,
niobium Niobium is a chemical element with chemical symbol Nb (formerly columbium, Cb) and atomic number 41. It is a light grey, crystalline, and ductile transition metal. Pure niobium has a Mohs hardness rating similar to pure titanium, and it has sim ...
, hafnium, tantalum, the rare-earth elements, and the actinides. Potassium can become so enriched in melt produced by a very low degree of partial melting that, when the magma subsequently cools and solidifies, it forms unusual potassic rock such as lamprophyre, lamproite, or kimberlite. When enough rock is melted, the small globules of melt (generally occurring between mineral grains) link up and soften the rock. Under pressure within the earth, as little as a fraction of a percent of partial melting may be sufficient to cause melt to be squeezed from its source. Melt rapidly separates from its source rock once the degree of partial melting exceeds 30%. However, usually much less than 30% of a magma source rock is melted before the heat supply is exhausted.
Pegmatite A pegmatite is an igneous rock showing a very coarse texture, with large interlocking crystals usually greater in size than and sometimes greater than . Most pegmatites are composed of quartz, feldspar, and mica, having a similar silicic com ...
may be produced by low degrees of partial melting of the crust. Some granite-composition magmas are eutectic (or cotectic) melts, and they may be produced by low to high degrees of partial melting of the crust, as well as by
fractional crystallization Fractional crystallization may refer to: * Fractional crystallization (chemistry), a process to separate different solutes from a solution * Fractional crystallization (geology) Fractional crystallization, or crystal fractionation, is one of the ...
.


Evolution of magmas

Most
magmas Magma () is the molten or semi-molten natural material from which all igneous rocks are formed. Magma is found beneath the surface of the Earth, and evidence of magmatism has also been discovered on other terrestrial planets and some natural sa ...
are fully melted only for small parts of their histories. More typically, they are mixes of melt and crystals, and sometimes also of gas bubbles. Melt, crystals, and bubbles usually have different densities, and so they can separate as magmas evolve. As magma cools, minerals typically crystallize from the melt at different temperatures. This resembles the original melting process in reverse. However, because the melt has usually separated from its original source rock and moved to a shallower depth, the reverse process of crystallization is not precisely identical. For example, if a melt was 50% each of diopside and anorthite, then anorthite would begin crystallizing from the melt at a temperature somewhat higher than the eutectic temperature of 1274 °C. This shifts the remaining melt towards its eutectic composition of 43% diopside. The eutectic is reached at 1274 °C, the temperature at which diopside and anorthite begin crystallizing together. If the melt was 90% diopside, the diopside would begin crystallizing first until the eutectic was reached. If the crystals remained suspended in the melt, the crystallization process would not change the overall composition of the melt plus solid minerals. This situation is described as ''equillibrium crystallization''. However, in a series of experiments culminating in his 1915 paper, ''Crystallization-differentiation in silicate liquids'',
Norman L. Bowen Norman Levi Bowen FRS (June 21, 1887 – September 11, 1956) was a Canadian geologist. Bowen "revolutionized experimental petrology and our understanding of mineral crystallization". Beginning geology students are familiar with Bowen's reaction s ...
demonstrated that crystals of olivine and diopside that crystallized out of a cooling melt of
forsterite Forsterite (Mg2SiO4; commonly abbreviated as Fo; also known as white olivine) is the magnesium-rich end-member of the olivine solid solution series. It is isomorphous with the iron-rich end-member, fayalite. Forsterite crystallizes in the orthor ...
, diopside, and silica would sink through the melt on geologically relevant time scales. Geologists subsequently found considerable field evidence of such ''
fractional crystallization Fractional crystallization may refer to: * Fractional crystallization (chemistry), a process to separate different solutes from a solution * Fractional crystallization (geology) Fractional crystallization, or crystal fractionation, is one of the ...
''. When crystals separate from a magma, then the residual magma will differ in composition from the parent magma. For instance, a magma of gabbroic composition can produce a residual melt of granitic composition if early formed crystals are separated from the magma. Gabbro may have a
liquidus The liquidus temperature, TL or Tliq, specifies the temperature above which a material is completely liquid, and the maximum temperature at which crystals can co-exist with the melt in thermodynamic equilibrium. It is mostly used for impure subst ...
temperature near 1,200 °C, and the derivative granite-composition melt may have a liquidus temperature as low as about 700 °C. Incompatible elements are concentrated in the last residues of magma during fractional crystallization and in the first melts produced during partial melting: either process can form the magma that crystallizes to
pegmatite A pegmatite is an igneous rock showing a very coarse texture, with large interlocking crystals usually greater in size than and sometimes greater than . Most pegmatites are composed of quartz, feldspar, and mica, having a similar silicic com ...
, a rock type commonly enriched in incompatible elements. Bowen's reaction series is important for understanding the idealised sequence of fractional crystallisation of a magma. Magma composition can be determined by processes other than partial melting and fractional crystallization. For instance, magmas commonly interact with rocks they intrude, both by melting those rocks and by reacting with them. Assimilation near the roof of a magma chamber and fractional crystallization near its base can even take place simultaneously. Magmas of different compositions can mix with one another. In rare cases, melts can separate into two immiscible melts of contrasting compositions.


Primary magmas

When rock melts, the liquid is a ''primary magma''. Primary magmas have not undergone any differentiation and represent the starting composition of a magma. In practice, it is difficult to unambiguously identify primary magmas, though it has been suggested that
boninite Boninite is an extrusive rock high in both magnesium and silica, thought to be usually formed in fore-arc environments, typically during the early stages of subduction. The rock is named for its occurrence in the Izu-Bonin arc south of Japan. It ...
is a variety of andesite crystallized from a primary magma. The Great Dyke of Zimbabwe has also been interpreted as rock crystallized from a primary magma. The interpretation of
leucosomes Migmatite is a composite rock found in medium and high-grade metamorphic environments, commonly within Precambrian cratonic blocks. It consists of two or more constituents often layered repetitively: one layer is an older metamorphic rock tha ...
of migmatites as primary magmas is contradicted by zircon data, which suggests leucosomes are a residue (a
cumulate rock Cumulate rocks are igneous rocks formed by the accumulation of crystals from a magma either by settling or floating. Cumulate rocks are named according to their texture; cumulate texture is diagnostic of the conditions of formation of this group o ...
) left by extraction of a primary magma.


Parental magma

When it is impossible to find the primitive or primary magma composition, it is often useful to attempt to identify a parental magma. A parental magma is a magma composition from which the observed range of magma chemistries has been derived by the processes of
igneous differentiation In geology, igneous differentiation, or magmatic differentiation, is an umbrella term for the various processes by which magmas undergo bulk chemical change during the partial melting process, cooling, emplacement, or eruption. The sequence of (u ...
. It need not be a primitive melt. For instance, a series of basalt flows are assumed to be related to one another. A composition from which they could reasonably be produced by fractional crystallization is termed a ''parental magma''. Fractional crystallization models would be produced to test the hypothesis that they share a common parental magma.


Migration and solidification

Magma develops within the
mantle A mantle is a piece of clothing, a type of cloak. Several other meanings are derived from that. Mantle may refer to: *Mantle (clothing), a cloak-like garment worn mainly by women as fashionable outerwear **Mantle (vesture), an Eastern Orthodox ve ...
or crust where the temperature and pressure conditions favor the molten state. After its formation, magma buoyantly rises toward the Earth's surface, due to its lower density than the source rock. As it migrates through the crust, magma may collect and reside in magma chambers (though recent work suggests that magma may be stored in trans-crustal crystal-rich mush zones rather than dominantly liquid magma chambers ). Magma can remain in a chamber until it either cools and crystallizes to form
intrusive rock Intrusive rock is formed when magma penetrates existing rock, crystallizes, and solidifies underground to form ''Igneous intrusion, intrusions'', such as batholiths, dike (geology), dikes, Sill (geology), sills, laccoliths, and volcanic necks.I ...
, it erupts as a volcano, or it moves into another magma chamber.


Plutonism

When magma cools it begins to form solid mineral phases. Some of these settle at the bottom of the magma chamber forming
cumulates Cumulate rocks are igneous rocks formed by the accumulation of crystals from a magma either by settling or floating. Cumulate rocks are named according to their texture; cumulate texture is diagnostic of the conditions of formation of this group o ...
that might form mafic layered intrusions. Magma that cools slowly within a magma chamber usually ends up forming bodies of plutonic rocks such as gabbro, diorite and granite, depending upon the composition of the magma. Alternatively, if the magma is erupted it forms volcanic rocks such as basalt, andesite and
rhyolite Rhyolite ( ) is the most silica-rich of volcanic rocks. It is generally glassy or fine-grained (aphanitic) in texture, but may be porphyritic, containing larger mineral crystals (phenocrysts) in an otherwise fine-grained groundmass. The mineral ...
(the extrusive equivalents of gabbro, diorite and granite, respectively).


Volcanism

Magma that is extruded onto the surface during a volcanic eruption is called lava. Lava cools and solidifies relatively quickly compared to underground bodies of magma. This fast cooling does not allow crystals to grow large, and a part of the melt does not crystallize at all, becoming glass. Rocks largely composed of volcanic glass include
obsidian Obsidian () is a naturally occurring volcanic glass formed when lava extrusive rock, extruded from a volcano cools rapidly with minimal crystal growth. It is an igneous rock. Obsidian is produced from felsic lava, rich in the lighter elements s ...
, scoria and pumice. Before and during volcanic eruptions,
volatiles Volatiles are the group of chemical elements and chemical compounds that can be readily vaporized. In contrast with volatiles, elements and compounds that are not readily vaporized are known as refractory substances. On planet Earth, the term ' ...
such as CO2 and H2O partially leave the melt through a process known as exsolution. Magma with low water content becomes increasingly viscous. If massive exsolution occurs when magma heads upwards during a volcanic eruption, the resulting eruption is usually explosive.


Use in energy production

The
Iceland Deep Drilling Project The Iceland Deep Drilling Project (IDDP) is a geothermal project established in 2000 by a consortium of the National Energy Authority of Iceland (Orkustofnun/OS) and four of Iceland's leading energy companies: Hitaveita Sudurnesja (HS), Landsvir ...
, while drilling several 5,000 m holes in an attempt to harness the heat in the volcanic bedrock below the surface of Iceland, struck a pocket of magma at 2,100 m in 2009. Because this was only the third time in recorded history that magma had been reached, IDDP decided to invest in the hole, naming it IDDP-1. A cemented steel case was constructed in the hole with a perforation at the bottom close to the magma. The high temperatures and pressure of the magma steam were used to generate 36 MW of power, making IDDP-1 the world's first magma-enhanced geothermal system.


References

{{Authority control Igneous petrology Igneous rocks Volcanism Earth's crust