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Natrocarbonatite
Natrocarbonatite is a rare carbonatite lava which erupts from the Ol Doinyo Lengai volcano in Tanzania within the East African Rift of eastern Africa. Natrocarbonatite lavas were first documented in 1962, by J B Dawson. Composition Whereas most lavas are rich in silicate minerals, the natrocarbonatite lavas of Ol Doinyo Lengai are rich in the rare sodium and potassium carbonate minerals, nyerereite and gregoryite. Due to this unusual composition, the lava is erupted at relatively low temperatures (approximately 500-600 °C).https://www.science.org/doi/10.1126/science.245.4914.168 This temperature is so low that the molten lava appears black in sunlight, rather than having the red glow common to most lavas. It is also much more fluid than silicate lavas. Impact The sodium and potassium carbonate minerals of the lavas erupted at Ol Doinyo Lengai are unstable at the Earth's surface and susceptible to rapid weathering, the minerals are anhydrous A substance is anhydrous if it ...
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Ol Doinyo Lengai
Ol Doinyo Lengai (Oldoinyo Lengai), "Mountain of God" in the Maasai language, is an active volcano located in the Gregory Rift, south of Lake Natron within the Arusha Region of Tanzania, Africa. Part of the volcanic system of the East African Rift, it uniquely produces natrocarbonatite lava. The 1960 eruption of Ol Doinyo Lengai led to geological investigations that finally confirmed the view that carbonatite rock is derived from magma. Geology Ol Doinyo Lengai is unique among active volcanoes in that it produces natrocarbonatite lava, a unique occurrence of volcanic carbonatite. A few older extinct carbonatite volcanoes are located nearby, including Homa Mountain. Lava Whereas most lavas are rich in silicate minerals, the lava of Ol Doinyo Lengai is a carbonatite. It is rich in the rare sodium and potassium carbonates, nyerereite and gregoryite. Due to this unusual composition, the lava erupts at relatively low temperatures of approximately . This temperature is so low that the ...
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Lava Lengai
Lava is molten or partially molten rock (magma) that has been expelled from the interior of a terrestrial planet (such as Earth) or a moon onto its surface. Lava may be erupted at a volcano or through a fracture in the crust, on land or underwater, usually at temperatures from . The volcanic rock resulting from subsequent cooling is also often called ''lava''. A lava flow is an outpouring of lava during an effusive eruption. (An explosive eruption, by contrast, produces a mixture of volcanic ash and other fragments called tephra, not lava flows.) The viscosity of most lava is about that of ketchup, roughly 10,000 to 100,000 times that of water. Even so, lava can flow great distances before cooling causes it to solidify, because lava exposed to air quickly develops a solid crust that insulates the remaining liquid lava, helping to keep it hot and inviscid enough to continue flowing. The word ''lava'' comes from Italian and is probably derived from the Latin word ''labes'', w ...
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Carbonatite
Carbonatite () is a type of intrusive rock, intrusive or extrusive rock, extrusive igneous rock defined by mineralogic composition consisting of greater than 50% carbonate minerals. Carbonatites may be confused with marble and may require geochemical verification. Carbonatites usually occur as small volcanic plug, plugs within zoned alkalic intrusive complexes, or as dike (geology), dikes, sill (geology), sills, breccias, and vein (geology), veins. They are almost exclusively associated with continental rift-related tectonic settings. It seems that there has been a steady increase in the carbonatitic igneous activity through the Earth's history, from the Archean Eon (geology), eon to the present. Nearly all carbonatite occurrences are intrusives or subvolcanic rock, subvolcanic intrusives. This is because carbonatite lava flows, being composed largely of soluble carbonates, are easily weathered and are therefore unlikely to be preserved in the geologic record. Carbonatite erupti ...
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Lava
Lava is molten or partially molten rock (magma) that has been expelled from the interior of a terrestrial planet (such as Earth) or a moon onto its surface. Lava may be erupted at a volcano or through a fracture in the crust, on land or underwater, usually at temperatures from . The volcanic rock resulting from subsequent cooling is also often called ''lava''. A lava flow is an outpouring of lava during an effusive eruption. (An explosive eruption, by contrast, produces a mixture of volcanic ash and other fragments called tephra, not lava flows.) The viscosity of most lava is about that of ketchup, roughly 10,000 to 100,000 times that of water. Even so, lava can flow great distances before cooling causes it to solidify, because lava exposed to air quickly develops a solid crust that insulates the remaining liquid lava, helping to keep it hot and inviscid enough to continue flowing. The word ''lava'' comes from Italian and is probably derived from the Latin word ''labes ...
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Nyerereite
Nyerereite is a very rare sodium calcium carbonate mineral with formula Na2 Ca( C O3)2. It forms colorless, platey pseudohexagonal orthorhombic crystals that are typically twinned. It has a specific gravity of 2.54 and indices of refraction of nα=1.511, nβ=1.533 and nγ=1.535. Nyerereite is not stable in contact with the atmosphere and rapidly breaks down. Collection specimens must be kept in a sealed argon environment. It has a Hermann–Mauguin notation of mm2 and the respective space group is Cmc21. In nature Nyerereite is naturally twinned and is pseudohexagonal with triad twinning; meaning that this is a six sided crystal that apparently has a hexagonal shape but is not in the hexagonal system. Triad twinning is the intergrowth of three orthorhombic crystals that turn at their center and form hexagonally shaped crystals. Nyerereite is biaxial negative, and has a 2v of 29 degrees. It shows a center acute bisectrix and a birefringence of approximately 0.023.Mckie, D., Fr ...
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East African Rift
The East African Rift (EAR) or East African Rift System (EARS) is an active continental rift zone in East Africa. The EAR began developing around the onset of the Miocene, 22–25 million years ago. In the past it was considered to be part of a larger Great Rift Valley that extended north to Asia Minor. A narrow zone, the rift is a developing divergent tectonic plate boundary where the African Plate is in the process of splitting into two tectonic plates, called the Somali Plate and the Nubian Plate, at a rate of 6-7 mm per year. The rift system consists of three microplates, the Victoria Microplate to the north, and the Rovuma and Lwandle microplates to the south. The Victoria Microplate is rotating anti-clockwise with respect to the African plate. Its rotation is caused by the configuration of mechanically weaker and stronger lithospheric regions in the EARS. Extent A series of distinct rift basins, the East African Rift System extends over thousands of kilometers. The ...
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Gregoryite
Gregoryite is an anhydrous carbonate mineral that is rich in potassium and sodium with the chemical formula . It is one of the two main ingredients of natrocarbonatite, found naturally in the lava of Ol Doinyo Lengai volcano, the other being nyerereite. Because of its anhydrous nature, gregoryite reacts quickly with the environment, causing the dark lava to be converted to white substance within hours. Gregoryite was first described in 1980 and named after the British geologist and author John Walter Gregory (1864–1932), who studied the East African Rift Valley. It occurs associated with nyerereite, alabandite, halite, sylvite, fluorite and calcite Calcite is a Carbonate minerals, carbonate mineral and the most stable Polymorphism (materials science), polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on .... References {{Reflist Calc-alkaline rocks Hexagonal minerals Minerals in spa ...
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Volcanology
Volcanology (also spelled vulcanology) is the study of volcanoes, lava, magma and related geological, geophysical and geochemical phenomena (volcanism). The term ''volcanology'' is derived from the Latin word ''vulcan''. Vulcan was the ancient Roman god of fire. A volcanologist is a geologist who studies the eruptive activity and formation of volcanoes and their current and historic eruptions. Volcanologists frequently visit volcanoes, especially active ones, to observe volcanic eruptions, collect eruptive products including tephra (such as ash or pumice), rock and lava samples. One major focus of enquiry is the prediction of eruptions; there is currently no accurate way to do this, but predicting eruptions, like predicting earthquakes, could save many lives. Modern volcanology image:Icelandic tephra.JPG, Volcanologist examining tephra horizons in south-central Iceland. In 1841, the first volcanological observatory, the Vesuvius Observatory, was founded in the Kingdom o ...
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Anhydrous
A substance is anhydrous if it contains no water. Many processes in chemistry can be impeded by the presence of water; therefore, it is important that water-free reagents and techniques are used. In practice, however, it is very difficult to achieve perfect dryness; anhydrous compounds gradually absorb water from the atmosphere so they must be stored carefully. Solids Many salts and solids can be dried using heat, or under vacuum. Desiccators can also be used to store reagents in dry conditions. Common desiccants include phosphorus pentoxide and silica gel. Chemists may also require dry glassware for sensitive reactions. This can be achieved by drying glassware in an oven, by flame, or under vacuum. Dry solids can be produced by freeze-drying, which is also known as lyophilization. Liquids or solvents In many cases, the presence of water can prevent a reaction from happening, or cause undesirable products to form. To prevent this, anhydrous solvents must be used when performi ...
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Weathering
Weathering is the deterioration of rocks, soils and minerals as well as wood and artificial materials through contact with water, atmospheric gases, and biological organisms. Weathering occurs ''in situ'' (on site, with little or no movement), and so is distinct from erosion, which involves the transport of rocks and minerals by agents such as water, ice, snow, wind, waves and gravity. Weathering processes are divided into ''physical'' and ''chemical weathering''. Physical weathering involves the breakdown of rocks and soils through the mechanical effects of heat, water, ice, or other agents. Chemical weathering involves the chemical reaction of water, atmospheric gases, and biologically produced chemicals with rocks and soils. Water is the principal agent behind both physical and chemical weathering, though atmospheric oxygen and carbon dioxide and the activities of biological organisms are also important. Chemical weathering by biological action is also known as biological wea ...
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Africa
Africa is the world's second-largest and second-most populous continent, after Asia in both cases. At about 30.3 million km2 (11.7 million square miles) including adjacent islands, it covers 6% of Earth's total surface area and 20% of its land area.Sayre, April Pulley (1999), ''Africa'', Twenty-First Century Books. . With billion people as of , it accounts for about of the world's human population. Africa's population is the youngest amongst all the continents; the median age in 2012 was 19.7, when the worldwide median age was 30.4. Despite a wide range of natural resources, Africa is the least wealthy continent per capita and second-least wealthy by total wealth, behind Oceania. Scholars have attributed this to different factors including geography, climate, tribalism, colonialism, the Cold War, neocolonialism, lack of democracy, and corruption. Despite this low concentration of wealth, recent economic expansion and the large and young population make Afr ...
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Carbonate Mineral
Carbonate minerals are those minerals containing the carbonate ion, . Carbonate divisions Anhydrous carbonates *Calcite group: trigonal **Calcite CaCO3 **Gaspéite (Ni,Mg,Fe2+)CO3 **Magnesite MgCO3 **Otavite CdCO3 **Rhodochrosite MnCO3 **Siderite FeCO3 **Smithsonite ZnCO3 **Spherocobaltite CoCO3 *Aragonite group: orthorhombic **Aragonite CaCO3 **Cerussite PbCO3 **Strontianite SrCO3 **Witherite BaCO3 **Rutherfordine UO2CO3 **Natrite Na2CO3 Anhydrous carbonates with compound formulas *Dolomite group: trigonal **Ankerite CaFe(CO3)2 **Dolomite (mineral), Dolomite CaMg(CO3)2 **Huntite Mg3Ca(CO3)4 **Minrecordite CaZn(CO3)2 **Barytocalcite BaCa(CO3)2 Carbonates with hydroxyl or halogen *Carbonate with hydroxide: monoclinic **Azurite Cu3(CO3)2(OH)2 **Hydrocerussite Pb3(CO3)2(OH)2 **Malachite Cu2CO3(OH)2 **Rosasite (Cu,Zn)2CO3(OH)2 **Phosgenite Pb2(CO3)Cl2 **Hydrozincite Zn5(CO3)2(OH)6 **Aurichalcite (Zn,Cu)5(CO3)2(OH)6 Hydrated carbonates *Hydromagnesite Mg5(CO3)4(OH)2.4H2O *Ikaite ...
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