Little–Parks Effect
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The Little–Parks effect was discovered in 1962 by William A. Little and Roland D. Parks in experiments with empty and thin-walled superconducting cylinders subjected to a parallel
magnetic field A magnetic field is a vector field that describes the magnetic influence on moving electric charges, electric currents, and magnetic materials. A moving charge in a magnetic field experiences a force perpendicular to its own velocity and to ...
.W. A. Little and R. D. Parks, “Observation of Quantum Periodicity in the Transition Temperature of a Superconducting Cylinder”, ''Physical Review Letters'' 9, 9 (1962), do
10.1103/PhysRevLett.9.9
/ref> It was one of the first experiments to indicate the importance of Cooper-pairing principle in BCS theory. The essence of Little–Parks (LP) effect is slight suppression of the
superconductivity Superconductivity is a set of physical properties observed in certain materials where electrical resistance vanishes and magnetic flux fields are expelled from the material. Any material exhibiting these properties is a superconductor. Unlike ...
by persistent current.


Explanation

The electrical resistance of such cylinders shows a periodic oscillation with the magnetic flux piercing the cylinder, the period being :''h''/2''e'' ≈ where ''h'' is the Planck constant and ''e'' is the electron charge. The explanation provided by Little and Parks is that the resistance oscillation reflects a more fundamental phenomenon, i.e. periodic oscillation of the superconducting ''T''c. The Little–Parks effect consists in a periodic variation of the ''T''c with the magnetic flux, which is the product of the magnetic field (coaxial) and the cross sectional area of the cylinder. ''T''c depends on the kinetic energy of the superconducting electrons. More precisely, the ''T''c is such temperature at which the free energies of normal and superconducting electrons are equal, for a given magnetic field. To understand the periodic oscillation of the ''T''c, which constitutes the Little–Parks effect, one needs to understand the periodic variation of the kinetic energy. The kinetic energy oscillates because the applied magnetic flux increases the kinetic energy while superconducting vortices, periodically entering the cylinder, compensate for the flux effect and reduce the kinetic energy. Thus, the periodic oscillation of the kinetic energy and the related periodic oscillation of the critical temperature occur together. The Little–Parks effect is a result of collective quantum behavior of superconducting electrons. It reflects the general fact that it is the
fluxoid The magnetic flux, represented by the symbol , threading some contour or loop is defined as the magnetic field multiplied by the loop area , i.e. . Both and can be arbitrary, meaning can be as well. However, if one deals with the superconduct ...
rather than the flux which is quantized in superconductors. The Little–Parks effect can be seen as a result of the requirement that quantum physics be invariant with respect to the gauge choice for the
electromagnetic potential An electromagnetic four-potential is a relativistic vector function from which the electromagnetic field can be derived. It combines both an electric scalar potential and a magnetic vector potential into a single four-vector.Gravitation, J.A. Whe ...
, of which the
magnetic vector potential In classical electromagnetism, magnetic vector potential (often called A) is the vector quantity defined so that its curl is equal to the magnetic field: \nabla \times \mathbf = \mathbf. Together with the electric potential ''φ'', the magnetic v ...
A forms part. Electromagnetic theory implies that a particle with electric charge ''q'' travelling along some path ''P'' in a region with zero
magnetic field A magnetic field is a vector field that describes the magnetic influence on moving electric charges, electric currents, and magnetic materials. A moving charge in a magnetic field experiences a force perpendicular to its own velocity and to ...
B, but non-zero A (by \mathbf = 0 = \nabla \times \mathbf), acquires a phase shift \varphi, given in SI units by :\varphi = \frac \int_P \mathbf \cdot d\mathbf, In a superconductor, the electrons form a quantum superconducting condensate, called a Bardeen–Cooper–Schrieffer (BCS) condensate. In the BCS condensate all electrons behave coherently, i.e. as one particle. Thus the phase of the collective BCS wavefunction behaves under the influence of the vector potential A in the same way as the phase of a single electron. Therefore the BCS condensate flowing around a closed path in a multiply connected superconducting sample acquires a phase difference Δ''φ'' determined by the
magnetic flux In physics, specifically electromagnetism, the magnetic flux through a surface is the surface integral of the normal component of the magnetic field B over that surface. It is usually denoted or . The SI unit of magnetic flux is the weber ( ...
''ΦB'' through the area enclosed by the path (via
Stokes' theorem Stokes's theorem, also known as the Kelvin–Stokes theorem Nagayoshi Iwahori, et al.:"Bi-Bun-Seki-Bun-Gaku" Sho-Ka-Bou(jp) 1983/12Written in Japanese)Atsuo Fujimoto;"Vector-Kai-Seki Gendai su-gaku rekucha zu. C(1)" :ja:培風館, Bai-Fu-Kan( ...
and \nabla \times \mathbf = \mathbf), and given by: :\Delta\varphi = \frac. This phase effect is responsible for the quantized-flux requirement and the Little–Parks effect in superconducting loops and empty cylinders. The quantization occurs because the superconducting wave function must be single valued in a loop or an empty superconducting cylinder: its phase difference Δ''φ'' around a closed loop must be an integer multiple of 2π, with the charge for the BCS electronic superconducting pairs. If the period of the Little–Parks oscillations is 2π with respect to the superconducting phase variable, from the formula above it follows that the period with respect to the magnetic flux is the same as the magnetic flux quantum, namely :\Delta \Phi_B = 2\pi\hbar/2e=h/2e.


Applications

Little–Parks oscillations are a widely used proof mechanism of Cooper pairing. One of the good example is the study of the
Superconductor Insulator Transition The Superconductor Insulator Transition is an example of a quantum phase transition, whereupon tuning some parameter in the Hamiltonian, a dramatic change in the behavior of the electrons occurs. The nature of how this transition occurs is dispu ...
. The challenge here is to separate Little–Parks oscillations from weak (anti-)localization, as in
Altshuler Altschuler, Altshuler, Altschuller (russian: Альтшуллер), Altshuller (russian: Альтшуллер), Altschueler, Altshueler, or Alschuler is a Jewish surname of Ashkenazi origin. It is derived from the Altschul, Old Synagogue in Prague.J ...
et al. results, where authors observed the Aharonov–Bohm effect in a dirty metallic films.


History

Fritz London predicted that the fluxoid is quantized in a multiply connected superconductor. Experimentally has been shown, that the trapped magnetic flux existed only in discrete quantum units ''h''/2''e''. Deaver and Fairbank were able to achieve the accuracy 20–30% because of the wall thickness of the cylinder. Little and Parks examined a "thin-walled" (Materials: Al, In, Pb, Sn and Sn–In alloys) cylinder (diameter was about 1 micron) at ''T'' very close to the transition temperature in an applied magnetic field in the axial direction. They found
magnetoresistance Magnetoresistance is the tendency of a material (often ferromagnetic) to change the value of its electrical resistance in an externally-applied magnetic field. There are a variety of effects that can be called magnetoresistance. Some occur in bulk ...
oscillations with the period consistent with ''h''/2''e''. What they actually measured was an infinitely small changes of resistance versus temperature for (different) constant magnetic field, as it shown in Fig.


References

{{DEFAULTSORT:Little-Parks effect Condensed matter physics Superconductivity