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Superconducting
Superconductivity is a set of physical properties observed in certain materials where Electrical resistance and conductance, electrical resistance vanishes and magnetic field, magnetic flux fields are expelled from the material. Any material exhibiting these properties is a superconductor. Unlike an ordinary metallic electrical conductor, conductor, whose resistance decreases gradually as its temperature is lowered even down to near absolute zero, a superconductor has a characteristic Phase transition, critical temperature below which the resistance drops abruptly to zero. An electric current through a loop of superconducting wire can persist indefinitely with no power source. The superconductivity phenomenon was discovered in 1911 by Dutch physicist Heike Kamerlingh Onnes. Like ferromagnetism and atomic spectral lines, superconductivity is a phenomenon which can only be explained by quantum mechanics. It is characterized by the Meissner effect, the complete ejection of magne ...
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High-temperature Superconductors
High-temperature superconductors (abbreviated high-c or HTS) are defined as materials that behave as superconductors at temperatures above , the boiling point of liquid nitrogen. The adjective "high temperature" is only in respect to previously known superconductors, which function at even colder temperatures close to absolute zero. In absolute terms, these "high temperatures" are still far below ambient, and therefore require cooling. The first high-temperature superconductor was discovered in 1986, by IBM researchers Bednorz and Müller, who were awarded the Nobel Prize in Physics in 1987 "for their important break-through in the discovery of superconductivity in ceramic materials". Most high-c materials are type-II superconductors. The major advantage of high-temperature superconductors is that they can be cooled by using liquid nitrogen, as opposed to the previously known superconductors which require expensive and hard-to-handle coolants, primarily liquid helium. A ...
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Superconducting Wire
Superconducting wires are electrical wires made of superconductive material. When cooled below their transition temperatures, they have zero electrical resistance. Most commonly, conventional superconductors such as niobium-titanium are used, but high-temperature superconductors such as YBCO are entering the market. Superconducting wire's advantages over copper or aluminum include higher maximum current densities and zero power dissipation. Its disadvantages include the cost of refrigeration of the wires to superconducting temperatures (often requiring cryogens such as liquid nitrogen or liquid helium), the danger of the wire quenching (a sudden loss of superconductivity), the inferior mechanical properties of some superconductors, and the cost of wire materials and construction. Its main application is in superconducting magnets, which are used in scientific and medical equipment where high magnetic fields are necessary. Important parameters The construction and operating ...
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Cuprate Superconductor
Cuprate superconductors are a family of high-temperature superconducting materials made of layers of copper oxides (CuO2) alternating with layers of other metal oxides, which act as charge reservoirs. At ambient pressure, cuprate superconductors are the highest temperature superconductors known. However, the mechanism by which superconductivity occurs is still not understood. History The first cuprate superconductor was found in 1986 in the non-stoichiometric cuprate lanthanum barium copper oxide by IBM researchers Georg Bednorz and Karl Alex Müller. The critical temperature for this material was 35K, well above the previous record of 23 K. The discovery led to a sharp increase in research on the cuprates, resulting in thousands of publications between 1986 and 2001. Bednorz and Müller were awarded the Nobel Prize in Physics in 1987, only a year after their discovery.
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Critical Field
For a given temperature, the critical field refers to the maximum magnetic field strength below which a material remains superconducting. Superconductivity is characterized both by perfect conductivity (zero resistance) and by the complete expulsion of magnetic fields (the Meissner effect). Changes in either temperature or magnetic flux density can cause the phase transition between normal and superconducting states.High Temperature Superconductivity, Jeffrey W. Lynn Editor, Springer-Verlag (1990) The highest temperature under which the superconducting state is seen is known as the critical temperature. At that temperature even the weakest external magnetic field will destroy the superconducting state, so the strength of the critical field is zero. As temperature decreases, the critical field increases generally to a maximum at absolute zero. For a type-I superconductor the discontinuity in heat capacity seen at the superconducting transition is generally related to the slope of the ...
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Meissner Effect
The Meissner effect (or Meissner–Ochsenfeld effect) is the expulsion of a magnetic field from a superconductor during its transition to the superconducting state when it is cooled below the critical temperature. This expulsion will repel a nearby magnet. The German physicists Walther Meissner and Robert Ochsenfeld discovered this phenomenon in 1933 by measuring the magnetic field distribution outside superconducting tin and lead samples. The samples, in the presence of an applied magnetic field, were cooled below their superconducting transition temperature, whereupon the samples cancelled nearly all interior magnetic fields. They detected this effect only indirectly because the magnetic flux is conserved by a superconductor: when the interior field decreases, the exterior field increases. The experiment demonstrated for the first time that superconductors were more than just perfect conductors and provided a uniquely defining property of the superconductor state. The abili ...
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Type II Superconductor
In superconductivity, a type-II superconductor is a superconductor that exhibits an intermediate phase of mixed ordinary and superconducting properties at intermediate temperature and fields above the superconducting phases. It also features the formation of magnetic field vortices with an applied external magnetic field. This occurs above a certain critical field strength ''Hc1''. The vortex density increases with increasing field strength. At a higher critical field ''Hc2'', superconductivity is destroyed. Type-II superconductors do not exhibit a complete Meissner effect. History In 1935, Rjabinin and Shubnikov experimentally discovered the Type-II superconductors. In 1950, the theory of the two types of superconductors was further developed by Lev Landau and Vitaly Ginzburg in their paper on Ginzburg–Landau theory. In their argument, a type-I superconductor had positive free energy of the superconductor-normal metal boundary. Ginzburg and Landau pointed out the possibilit ...
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BCS Theory
BCS theory or Bardeen–Cooper–Schrieffer theory (named after John Bardeen, Leon Cooper, and John Robert Schrieffer) is the first microscopic theory of superconductivity since Heike Kamerlingh Onnes's 1911 discovery. The theory describes superconductivity as a microscopic effect caused by a condensation of Cooper pairs. The theory is also used in nuclear physics to describe the pairing interaction between nucleons in an atomic nucleus. It was proposed by Bardeen, Cooper, and Schrieffer in 1957; they received the Nobel Prize in Physics for this theory in 1972. History Rapid progress in the understanding of superconductivity gained momentum in the mid-1950s. It began with the 1948 paper, "On the Problem of the Molecular Theory of Superconductivity", where Fritz London proposed that the phenomenological London equations may be consequences of the coherence of a quantum state. In 1953, Brian Pippard, motivated by penetration experiments, proposed that this would modify the Lo ...
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Unconventional Superconductor
Unconventional superconductors are materials that display superconductivity which does not conform to either the conventional BCS theory or Nikolay Bogolyubov's theory or its extensions. History The superconducting properties of CeCu2Si2, a type of heavy fermion material, were reported in 1979 by Frank Steglich. For a long time it was believed that CeCu2Si2 was a singlet d-wave superconductor, but since the mid 2010s, this notion has been strongly contested. In the early eighties, many more unconventional, heavy fermion superconductors were discovered, including UBe13, UPt3 and URu2Si2. In each of these materials, the anisotropic nature of the pairing was implicated by the power-law dependence of the nuclear magnetic resonance (NMR) relaxation rate and specific heat capacity on temperature. The presence of nodes in the superconducting gap of UPt3 was confirmed in 1986 from the polarization dependence of the ultrasound attenuation. The first unconventional triplet superconduct ...
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Type I Superconductor
The interior of a bulk superconductor cannot be penetrated by a weak magnetic field, a phenomenon known as the Meissner effect. When the applied magnetic field becomes too large, superconductivity breaks down. Superconductors can be divided into two types according to how this breakdown occurs. In type-I superconductors, superconductivity is abruptly destroyed via a first order phase transition when the strength of the applied field rises above a critical value ''H''c. This type of superconductivity is normally exhibited by pure metals, e.g. aluminium, lead, and mercury. The only alloy known up to now which exhibits type I superconductivity is TaSi2. The covalent superconductor SiC:B, silicon carbide heavily doped with boron, is also type-I. Depending on the demagnetization factor, one may obtain an intermediate state. This state, first described by Lev Landau, is a phase separation into macroscopic non-superconducting and superconducting domains forming a Husimi Q representation ...
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Order Parameter
In chemistry, thermodynamics, and other related fields, a phase transition (or phase change) is the physical process of transition between one state of a medium and another. Commonly the term is used to refer to changes among the basic states of matter: solid, liquid, and gas, and in rare cases, plasma. A phase of a thermodynamic system and the states of matter have uniform physical properties. During a phase transition of a given medium, certain properties of the medium change as a result of the change of external conditions, such as temperature or pressure. This can be a discontinuous change; for example, a liquid may become gas upon heating to its boiling point, resulting in an abrupt change in volume. The identification of the external conditions at which a transformation occurs defines the phase transition point. Types of phase transition At the phase transition point for a substance, for instance the boiling point, the two phases involved - liquid and vapor, have identical ...
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Phase Transition
In chemistry, thermodynamics, and other related fields, a phase transition (or phase change) is the physical process of transition between one state of a medium and another. Commonly the term is used to refer to changes among the basic states of matter: solid, liquid, and gas, and in rare cases, plasma. A phase of a thermodynamic system and the states of matter have uniform physical properties. During a phase transition of a given medium, certain properties of the medium change as a result of the change of external conditions, such as temperature or pressure. This can be a discontinuous change; for example, a liquid may become gas upon heating to its boiling point, resulting in an abrupt change in volume. The identification of the external conditions at which a transformation occurs defines the phase transition point. Types of phase transition At the phase transition point for a substance, for instance the boiling point, the two phases involved - liquid and vapor, have identic ...
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Perovskite (structure)
A perovskite is any material with a crystal structure following the formula ABX3, which was first discovered as the mineral called perovskite, which consists of calcium titanium oxide (CaTiO3). The mineral was first discovered in the Ural mountains of Russia by Gustav Rose in 1839 and named after Russian mineralogist L. A. Perovski (1792–1856). 'A' and 'B' are two positively charged ions (i.e. cations), often of very different sizes, and X is a negatively charged ion (an anion, frequently oxide) that bonds to both cations. The 'A' atoms are generally larger than the 'B' atoms. The ideal cubic structure has the B cation in 6-fold coordination, surrounded by an octahedron of anions, and the A cation in 12-fold cuboctahedral coordination. Additional perovskite forms may exist where either/both the A and B sites have a configuration of A1x-1A2x and/or B1y-1B2y and the X may deviate from the ideal coordination configuration as ions within the A and B sites undergo changes in thei ...
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