Lithium (from el, λίθος, lithos, lit=stone) is a
chemical element
A chemical element is a species of atoms that have a given number of protons in their nuclei, including the pure substance consisting only of that species. Unlike chemical compounds, chemical elements cannot be broken down into simpler sub ...
with the
symbol Li and
atomic number
The atomic number or nuclear charge number (symbol ''Z'') of a chemical element is the charge number of an atomic nucleus. For ordinary nuclei, this is equal to the proton number (''n''p) or the number of protons found in the nucleus of every ...
3. It is a soft, silvery-white
alkali metal. Under
standard conditions
Standard temperature and pressure (STP) are standard sets of conditions for experimental measurements to be established to allow comparisons to be made between different sets of data. The most used standards are those of the International Union ...
, it is the least dense metal and the least dense solid element. Like all alkali metals, lithium is highly
reactive
Reactive may refer to:
*Generally, capable of having a reaction (disambiguation)
*An adjective abbreviation denoting a bowling ball coverstock made of reactive resin
*Reactivity (chemistry)
*Reactive mind
*Reactive programming
See also
*Reactanc ...
and flammable, and must be stored in vacuum, inert atmosphere, or inert liquid such as purified kerosene or mineral oil. When cut, it exhibits a metallic
luster, but moist air
corrodes it quickly to a dull silvery gray, then black tarnish. It never occurs freely in nature, but only in (usually ionic)
compounds, such as
pegmatitic
A pegmatite is an igneous rock showing a very coarse texture, with large interlocking crystals usually greater in size than and sometimes greater than . Most pegmatites are composed of quartz, feldspar, and mica, having a similar silicic com ...
minerals, which were once the main source of lithium. Due to its solubility as an ion, it is present in ocean water and is commonly obtained from
brines. Lithium metal is isolated
electrolytically from a mixture of
lithium chloride
Lithium chloride is a chemical compound with the formula Li Cl. The salt is a typical ionic compound (with certain covalent characteristics), although the small size of the Li+ ion gives rise to properties not seen for other alkali metal chlorid ...
and
potassium chloride.
The
nucleus
Nucleus ( : nuclei) is a Latin word for the seed inside a fruit. It most often refers to:
*Atomic nucleus, the very dense central region of an atom
* Cell nucleus, a central organelle of a eukaryotic cell, containing most of the cell's DNA
Nucl ...
of the lithium atom verges on instability, since the two stable lithium
isotope
Isotopes are two or more types of atoms that have the same atomic number (number of protons in their nuclei) and position in the periodic table (and hence belong to the same chemical element), and that differ in nucleon numbers (mass numb ...
s found in nature have among the lowest
binding energies
In physics and chemistry, binding energy is the smallest amount of energy required to remove a particle from a system of particles or to disassemble a system of particles into individual parts. In the former meaning the term is predominantly use ...
per
nucleon
In physics and chemistry, a nucleon is either a proton or a neutron, considered in its role as a component of an atomic nucleus. The number of nucleons in a nucleus defines the atom's mass number (nucleon number).
Until the 1960s, nucleons were ...
of all stable
nuclides. Because of its relative nuclear instability, lithium is less common in the solar system than 25 of the first 32 chemical elements even though its nuclei are very light: it is an exception to the trend that heavier nuclei are less common.
[Numerical data from: Graphed at :File:SolarSystemAbundances.jpg] For related reasons, lithium has important uses in
nuclear physics
Nuclear physics is the field of physics that studies atomic nuclei and their constituents and interactions, in addition to the study of other forms of nuclear matter.
Nuclear physics should not be confused with atomic physics, which studies the ...
. The
transmutation of lithium atoms to
helium
Helium (from el, ἥλιος, helios, lit=sun) is a chemical element with the symbol He and atomic number 2. It is a colorless, odorless, tasteless, non-toxic, inert, monatomic gas and the first in the noble gas group in the periodic table. ...
in 1932 was the first fully man-made
nuclear reaction
In nuclear physics and nuclear chemistry, a nuclear reaction is a process in which two nuclei, or a nucleus and an external subatomic particle, collide to produce one or more new nuclides. Thus, a nuclear reaction must cause a transformatio ...
, and
lithium deuteride
Lithium hydride is an inorganic compound with the formula Li H. This alkali metal hydride is a colorless solid, although commercial samples are grey. Characteristic of a salt-like (ionic) hydride, it has a high melting point, and it is not sol ...
serves as a
fusion
Fusion, or synthesis, is the process of combining two or more distinct entities into a new whole.
Fusion may also refer to:
Science and technology Physics
*Nuclear fusion, multiple atomic nuclei combining to form one or more different atomic nucl ...
fuel in
staged thermonuclear weapons.
Lithium and its compounds have several industrial applications, including heat-resistant glass and
ceramic
A ceramic is any of the various hard, brittle, heat-resistant and corrosion-resistant materials made by shaping and then firing an inorganic, nonmetallic material, such as clay, at a high temperature. Common examples are earthenware, porcelain ...
s,
lithium grease lubricants, flux additives for iron, steel and aluminium production,
lithium metal batteries, and
lithium-ion batteries. These uses consume more than three-quarters of lithium production.
Lithium is present in biological systems in trace amounts; its functions are uncertain. Lithium salts have proven to be useful as a mood stabilizer and
antidepressant in the treatment of mental illness such as
bipolar disorder
Bipolar disorder, previously known as manic depression, is a mental disorder characterized by periods of depression and periods of abnormally elevated mood that last from days to weeks each. If the elevated mood is severe or associated with ...
.
Properties
Atomic and physical
![Limetal](https://upload.wikimedia.org/wikipedia/commons/2/21/Limetal.JPG)
The
alkali metals are also called the
lithium family, after its leading element. Like the other alkali metals (which are
sodium
Sodium is a chemical element with the symbol Na (from Latin ''natrium'') and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 of the periodic table. Its only stable ...
(Na),
potassium
Potassium is the chemical element with the symbol K (from Neo-Latin ''kalium'') and atomic number19. Potassium is a silvery-white metal that is soft enough to be cut with a knife with little force. Potassium metal reacts rapidly with atmosph ...
(K),
rubidium (Rb),
caesium (Cs), and
francium (Fr)), lithium has a single
valence electron
In chemistry and physics, a valence electron is an electron in the outer shell associated with an atom, and that can participate in the formation of a chemical bond if the outer shell is not closed. In a single covalent bond, a shared pair form ...
that is easily given up to form a
cation.
Because of this, lithium is a good conductor of heat and electricity as well as a highly reactive element, though it is the least reactive of the alkali metals. Lithium's low reactivity is due to the proximity of its valence electron to its
nucleus
Nucleus ( : nuclei) is a Latin word for the seed inside a fruit. It most often refers to:
*Atomic nucleus, the very dense central region of an atom
* Cell nucleus, a central organelle of a eukaryotic cell, containing most of the cell's DNA
Nucl ...
(the remaining
two electrons are in the
1s orbital
1S or 1s may refer to:
* 1s electron, in an atomic orbital
* Sabre (computer system)'s IATA code
* 1S, a series of Toyota S engines
* SSH 1S (WA); see Washington State Route 502, Washington State Route 503
See also
* Shilling
* Second
* Ones ( ...
, much lower in energy, and do not participate in chemical bonds).
Molten lithium is significantly more reactive than its solid form.
Lithium metal is soft enough to be cut with a knife. When cut, it possesses a silvery-white color that quickly changes to gray as it oxidizes to
lithium oxide
Lithium oxide ( O) or lithia is an inorganic chemical compound. It is a white solid. Although not specifically important, many materials are assessed on the basis of their Li2O content. For example, the Li2O content of the principal lithium miner ...
.
Its
melting point
The melting point (or, rarely, liquefaction point) of a substance is the temperature at which it changes state from solid to liquid. At the melting point the solid and liquid phase exist in equilibrium. The melting point of a substance depen ...
of
and its
boiling point of
are each the highest of all the alkali metals while its
density
Density (volumetric mass density or specific mass) is the substance's mass per unit of volume. The symbol most often used for density is ''ρ'' (the lower case Greek letter rho), although the Latin letter ''D'' can also be used. Mathematical ...
of 0.534
g/cm3 is the lowest.
Lithium has a very low density (0.534 g/cm
3), comparable with
pine wood
A pine is any conifer tree or shrub in the genus ''Pinus'' () of the family Pinaceae. ''Pinus'' is the sole genus in the subfamily Pinoideae. The World Flora Online created by the Royal Botanic Gardens, Kew and Missouri Botanical Garden accepts ...
. It is the least dense of all elements that are solids at room temperature; the next lightest solid element (potassium, at 0.862 g/cm
3) is more than 60% denser. Apart from
helium
Helium (from el, ἥλιος, helios, lit=sun) is a chemical element with the symbol He and atomic number 2. It is a colorless, odorless, tasteless, non-toxic, inert, monatomic gas and the first in the noble gas group in the periodic table. ...
and
hydrogen
Hydrogen is the chemical element with the symbol H and atomic number 1. Hydrogen is the lightest element. At standard conditions hydrogen is a gas of diatomic molecules having the formula . It is colorless, odorless, tasteless, non-toxic ...
, as a solid it is less dense than any other element as a liquid, being only two-thirds as dense as
liquid nitrogen (0.808 g/cm
3). Lithium can float on the lightest hydrocarbon oils and is one of only three metals that can float on water, the other two being
sodium
Sodium is a chemical element with the symbol Na (from Latin ''natrium'') and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 of the periodic table. Its only stable ...
and
potassium
Potassium is the chemical element with the symbol K (from Neo-Latin ''kalium'') and atomic number19. Potassium is a silvery-white metal that is soft enough to be cut with a knife with little force. Potassium metal reacts rapidly with atmosph ...
.
![Lithium element](https://upload.wikimedia.org/wikipedia/commons/b/ba/Lithium_element.jpg)
Lithium's
coefficient of thermal expansion
Thermal expansion is the tendency of matter to change its shape, area, volume, and density in response to a change in temperature, usually not including phase transitions.
Temperature is a monotonic function of the average molecular kineti ...
is twice that of
aluminium
Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. I ...
and almost four times that of
iron
Iron () is a chemical element with Symbol (chemistry), symbol Fe (from la, Wikt:ferrum, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 element, group 8 of the periodic table. It is, Abundanc ...
. Lithium is
superconductive
Superconductivity is a set of physical properties observed in certain materials where electrical resistance vanishes and magnetic flux fields are expelled from the material. Any material exhibiting these properties is a superconductor. Unlike ...
below 400
μK at standard pressure and at higher temperatures (more than 9 K) at very high pressures (>20 GPa). At temperatures below 70 K, lithium, like sodium, undergoes
diffusionless phase change transformations. At 4.2 K it has a
rhombohedral crystal system
In crystallography, the hexagonal crystal family is one of the six crystal families, which includes two crystal systems (hexagonal and trigonal) and two lattice systems (hexagonal and rhombohedral). While commonly confused, the trigonal crysta ...
(with a nine-layer repeat spacing); at higher temperatures it transforms to
face-centered cubic
In crystallography, the cubic (or isometric) crystal system is a crystal system where the unit cell is in the shape of a cube. This is one of the most common and simplest shapes found in crystals and minerals.
There are three main varieties of ...
and then
body-centered cubic
In crystallography, the cubic (or isometric) crystal system is a crystal system where the unit cell is in the shape of a cube. This is one of the most common and simplest shapes found in crystals and minerals.
There are three main varieties of ...
. At liquid-helium temperatures (4 K) the rhombohedral structure is prevalent.
Multiple allotropic forms have been identified for lithium at high pressures.
Lithium has a mass
specific heat capacity
In thermodynamics, the specific heat capacity (symbol ) of a substance is the heat capacity of a sample of the substance divided by the mass of the sample, also sometimes referred to as massic heat capacity. Informally, it is the amount of heat t ...
of 3.58 kilojoules per kilogram-kelvin, the highest of all solids.
Because of this, lithium metal is often used in
coolant
A coolant is a substance, typically liquid, that is used to reduce or regulate the temperature of a system. An ideal coolant has high thermal capacity, low viscosity, is low-cost, non-toxic, chemically inert and neither causes nor promotes corrosi ...
s for
heat transfer
Heat transfer is a discipline of thermal engineering that concerns the generation, use, conversion, and exchange of thermal energy (heat) between physical systems. Heat transfer is classified into various mechanisms, such as thermal conduction, ...
applications.
Isotopes
Naturally occurring lithium is composed of two stable
isotope
Isotopes are two or more types of atoms that have the same atomic number (number of protons in their nuclei) and position in the periodic table (and hence belong to the same chemical element), and that differ in nucleon numbers (mass numb ...
s,
6Li and
7Li, the latter being the more abundant (92.5%
natural abundance
In physics, natural abundance (NA) refers to the abundance of isotopes of a chemical element as naturally found on a planet. The relative atomic mass (a weighted average, weighted by mole-fraction abundance figures) of these isotopes is the atomi ...
).
Both natural isotopes have anomalously low
nuclear binding energy per nucleon (compared to the neighboring elements on the
periodic table,
helium
Helium (from el, ἥλιος, helios, lit=sun) is a chemical element with the symbol He and atomic number 2. It is a colorless, odorless, tasteless, non-toxic, inert, monatomic gas and the first in the noble gas group in the periodic table. ...
and
beryllium
Beryllium is a chemical element with the symbol Be and atomic number 4. It is a steel-gray, strong, lightweight and brittle alkaline earth metal. It is a divalent element that occurs naturally only in combination with other elements to form m ...
); lithium is the only low numbered element that can produce net energy through
nuclear fission. The two lithium nuclei have lower binding energies per nucleon than any other stable nuclides other than
hydrogen-1
Hydrogen (1H) has three naturally occurring isotopes, sometimes denoted , , and . and are stable, while has a half-life of years. Heavier isotopes also exist, all of which are synthetic and have a half-life of less than one zeptosecond (10 ...
,
deuterium
Deuterium (or hydrogen-2, symbol or deuterium, also known as heavy hydrogen) is one of two stable isotopes of hydrogen (the other being protium, or hydrogen-1). The nucleus of a deuterium atom, called a deuteron, contains one proton and one ...
and
helium-3.
[ :File:Binding energy curve - common isotopes.svg shows binding energies of stable nuclides graphically; the source of the data-set is given in the figure background.] As a result of this, though very light in atomic weight, lithium is less common in the Solar System than 25 of the first 32 chemical elements.
Seven
radioisotope
A radionuclide (radioactive nuclide, radioisotope or radioactive isotope) is a nuclide that has excess nuclear energy, making it unstable. This excess energy can be used in one of three ways: emitted from the nucleus as gamma radiation; transferr ...
s have been characterized, the most stable being
8Li with a
half-life
Half-life (symbol ) is the time required for a quantity (of substance) to reduce to half of its initial value. The term is commonly used in nuclear physics to describe how quickly unstable atoms undergo radioactive decay or how long stable at ...
of 838
ms and
9Li with a half-life of 178 ms. All of the remaining
radioactive
Radioactive decay (also known as nuclear decay, radioactivity, radioactive disintegration, or nuclear disintegration) is the process by which an unstable atomic nucleus loses energy by radiation. A material containing unstable nuclei is consi ...
isotopes have half-lives that are shorter than 8.6 ms. The shortest-lived isotope of lithium is
4Li, which decays through
proton emission
Proton emission (also known as proton radioactivity) is a rare type of radioactive decay in which a proton is ejected from a nucleus. Proton emission can occur from high-lying excited states in a nucleus following a beta decay, in which case t ...
and has a half-life of 7.6 × 10
−23 s.
The
6Li isotope is one of only
five stable nuclides to have both an odd number of protons and an odd number of neutrons, the other four stable
odd-odd nuclides being
hydrogen-2
Deuterium (or hydrogen-2, symbol or deuterium, also known as heavy hydrogen) is one of two stable isotopes of hydrogen (the other being protium, or hydrogen-1). The nucleus of a deuterium atom, called a deuteron, contains one proton and one n ...
,
boron-10
Boron is a chemical element with the symbol B and atomic number 5. In its crystalline form it is a brittle, dark, lustrous metalloid; in its amorphous form it is a brown powder. As the lightest element of the ''boron group'' it has ...
,
nitrogen-14
Natural nitrogen (7N) consists of two stable isotopes: the vast majority (99.6%) of naturally occurring nitrogen is nitrogen-14, with the remainder being nitrogen-15. Fourteen radioisotopes are also known, with atomic masses ranging from 10 to 25, ...
, and
tantalum-180m
Natural tantalum (73Ta) consists of two stable isotopes: 181Ta (99.988%) and (0.012%).
There are also 35 known artificial radioisotopes, the longest-lived of which are 179Ta with a half-life of 1.82 years, 182Ta with a half-life of 114.43 days, ...
.
7Li is one of the
primordial elements
In geochemistry, geophysics and nuclear physics, primordial nuclides, also known as primordial isotopes, are nuclides found on Earth that have existed in their current form since before Earth was formed. Primordial nuclides were present in the ...
(or, more properly, primordial
nuclides) produced in
Big Bang nucleosynthesis
In physical cosmology, Big Bang nucleosynthesis (abbreviated BBN, also known as primordial nucleosynthesis) is the production of nuclei other than those of the lightest isotope of hydrogen ( hydrogen-1, 1H, having a single proton as a nucleu ...
. A small amount of both
6Li and
7Li are produced in stars during
stellar nucleosynthesis, but it is further "
burned" as fast as produced.
7Li can also be generated in
carbon stars. Additional small amounts of both
6Li and
7Li may be generated from solar wind, cosmic rays hitting heavier atoms, and from early solar system
7 Be and
10Be radioactive decay.
Lithium isotopes fractionate substantially during a wide variety of natural processes, including mineral formation (chemical precipitation),
metabolism
Metabolism (, from el, μεταβολή ''metabolē'', "change") is the set of life-sustaining chemical reactions in organisms. The three main functions of metabolism are: the conversion of the energy in food to energy available to run c ...
, and
ion exchange
Ion exchange is a reversible interchange of one kind of ion present in an insoluble solid with another of like charge present in a solution surrounding the solid with the reaction being used especially for softening or making water demineralised, ...
. Lithium ions substitute for
magnesium
Magnesium is a chemical element with the symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 of the periodic ta ...
and iron in octahedral sites in
clay
Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2 Si2 O5( OH)4).
Clays develop plasticity when wet, due to a molecular film of water surrounding the clay par ...
minerals, where
6Li is preferred to
7Li, resulting in enrichment of the light isotope in processes of hyperfiltration and rock alteration. The exotic
11Li is known to exhibit a
neutron halo, with 2 neutrons orbiting around its nucleus of 3 protons and 6 neutrons. The process known as
laser isotope separation can be used to separate lithium isotopes, in particular
7Li from
6Li.
Nuclear weapons manufacture and other nuclear physics applications are a major source of artificial lithium fractionation, with the light isotope
6Li being retained by industry and military stockpiles to such an extent that it has caused slight but measurable change in the
6Li to
7Li ratios in natural sources, such as rivers. This has led to unusual uncertainty in the standardized
atomic weight
Relative atomic mass (symbol: ''A''; sometimes abbreviated RAM or r.a.m.), also known by the deprecated synonym atomic weight, is a dimensionless physical quantity defined as the ratio of the average mass of atoms of a chemical element in a giv ...
of lithium, since this quantity depends on the natural abundance ratios of these naturally-occurring stable lithium isotopes, as they are available in commercial lithium mineral sources.
Both stable isotopes of lithium can be
laser cooled and were used to produce the first quantum degenerate
Bose
Bose may refer to:
* Bose (crater), a lunar crater
* ''Bose'' (film), a 2004 Indian Tamil film starring Srikanth and Sneha
* Bose (surname), a surname (and list of people with the name)
* Bose, Italy, a ''frazioni'' in Magnano, Province of Biella ...
-
Fermi
Enrico Fermi (; 29 September 1901 – 28 November 1954) was an Italian (later naturalized American) physicist and the creator of the world's first nuclear reactor, the Chicago Pile-1. He has been called the "architect of the nuclear age" and ...
mixture.
Occurrence
Astronomical
Although it was synthesized in the
Big Bang, lithium (together with beryllium and boron) is markedly less abundant in the universe than other elements. This is a result of the comparatively low stellar temperatures necessary to destroy lithium, along with a lack of common processes to produce it.
According to modern cosmological theory, lithium—in both stable isotopes (lithium-6 and lithium-7)—was one of the three elements synthesized in the Big Bang. Though the amount of lithium generated in
Big Bang nucleosynthesis
In physical cosmology, Big Bang nucleosynthesis (abbreviated BBN, also known as primordial nucleosynthesis) is the production of nuclei other than those of the lightest isotope of hydrogen ( hydrogen-1, 1H, having a single proton as a nucleu ...
is dependent upon the number of
photon
A photon () is an elementary particle that is a quantum of the electromagnetic field, including electromagnetic radiation such as light and radio waves, and the force carrier for the electromagnetic force. Photons are massless, so they a ...
s per
baryon
In particle physics, a baryon is a type of composite subatomic particle which contains an odd number of valence quarks (at least 3). Baryons belong to the hadron family of particles; hadrons are composed of quarks. Baryons are also classif ...
, for accepted values the lithium abundance can be calculated, and there is a "
cosmological lithium discrepancy" in the universe: older stars seem to have less lithium than they should, and some younger stars have much more. The lack of lithium in older stars is apparently caused by the "mixing" of lithium into the interior of stars, where it is destroyed,
while lithium is produced in younger stars. Although it
transmutes into two atoms of
helium
Helium (from el, ἥλιος, helios, lit=sun) is a chemical element with the symbol He and atomic number 2. It is a colorless, odorless, tasteless, non-toxic, inert, monatomic gas and the first in the noble gas group in the periodic table. ...
due to collision with a
proton at temperatures above 2.4 million degrees Celsius (most stars easily attain this temperature in their interiors), lithium is more abundant than computations would predict in later-generation stars.
![Nova Centauri 2013 ESO](https://upload.wikimedia.org/wikipedia/commons/1/10/Nova_Centauri_2013_ESO.jpg)
Lithium is also found in
brown dwarf
Brown dwarfs (also called failed stars) are substellar objects that are not massive enough to sustain nuclear fusion of ordinary hydrogen ( 1H) into helium in their cores, unlike a main-sequence star. Instead, they have a mass between the most ...
substellar objects and certain anomalous orange stars. Because lithium is present in cooler, less-massive brown dwarfs, but is destroyed in hotter
red dwarf stars, its presence in the stars' spectra can be used in the "lithium test" to differentiate the two, as both are smaller than the Sun.
Certain orange stars can also contain a high concentration of lithium. Those orange stars found to have a higher than usual concentration of lithium (such as
Centaurus X-4) orbit massive objects—neutron stars or black holes—whose gravity evidently pulls heavier lithium to the surface of a hydrogen-helium star, causing more lithium to be observed.
On 27 May 2020, astronomers reported that
classical nova
A nova (plural novae or novas) is a transient astronomical event that causes the sudden appearance of a bright, apparently "new" star (hence the name "nova", which is Latin for "new") that slowly fades over weeks or months. Causes of the dramat ...
explosions are galactic producers of lithium-7.
Terrestrial
Although lithium is widely distributed on Earth, it does not naturally occur in elemental form due to its high reactivity.
The total lithium content of seawater is very large and is estimated as 230 billion tonnes, where the element exists at a relatively constant concentration of 0.14 to 0.25 parts per million (ppm),
or 25
micromolar
Molar concentration (also called molarity, amount concentration or substance concentration) is a measure of the concentration of a chemical species, in particular of a solute in a solution, in terms of amount of substance per unit volume of sol ...
; higher concentrations approaching 7 ppm are found near
hydrothermal vents.
Estimates for the Earth's
crustal content range from 20 to 70 ppm by weight.
Lithium constitutes about 0.002 percent of Earth's crust. In keeping with its name, lithium forms a minor part of
igneous rock
Igneous rock (derived from the Latin word ''ignis'' meaning fire), or magmatic rock, is one of the three main rock types, the others being sedimentary and metamorphic. Igneous rock is formed through the cooling and solidification of magma o ...
s, with the largest concentrations in
granite
Granite () is a coarse-grained ( phaneritic) intrusive igneous rock composed mostly of quartz, alkali feldspar, and plagioclase. It forms from magma with a high content of silica and alkali metal oxides that slowly cools and solidifies under ...
s. Granitic
pegmatites also provide the greatest abundance of lithium-containing minerals, with
spodumene
Spodumene is a pyroxene mineral consisting of lithium aluminium inosilicate, Li Al( Si O3)2, and is a source of lithium. It occurs as colorless to yellowish, purplish, or lilac kunzite (see below), yellowish-green or emerald-green hiddenite, pr ...
and
petalite
Petalite, also known as castorite, is a lithium aluminum phyllosilicate mineral Li Al Si4 O10, crystallizing in the monoclinic system. Petalite occurs as colorless, pink, grey, yellow, yellow grey, to white tabular crystals and columnar masses. ...
being the most commercially viable sources.
Another significant mineral of lithium is
lepidolite
Lepidolite is a lilac-gray or rose-colored member of the mica group of minerals with chemical formula . It is the most abundant lithium-bearing mineral and is a secondary source of this metal. It is the major source of the alkali metal rubidi ...
which is now an obsolete name for a series formed by polylithionite and trilithionite. A newer source for lithium is
hectorite clay, the only active development of which is through the Western Lithium Corporation in the United States. At 20 mg lithium per kg of Earth's crust, lithium is the 25th most abundant element.
According to the ''Handbook of Lithium and Natural Calcium'', "Lithium is a comparatively rare element, although it is found in many rocks and some brines, but always in very low concentrations. There are a fairly large number of both lithium mineral and brine deposits but only comparatively few of them are of actual or potential commercial value. Many are very small, others are too low in grade."
Chile is estimated (2020) to have the largest reserves by far (9.2 million tonnes),
and Australia the highest annual production (40,000 tonnes).
One of the largest ''reserve bases''
[Appendixes]
. By USGS definitions, the reserve base "may encompass those parts of the resources that have a reasonable potential for becoming economically available within planning horizons beyond those that assume proven technology and current economics. The reserve base includes those resources that are currently economic (reserves), marginally economic (marginal reserves), and some of those that are currently subeconomic (subeconomic resources)." of lithium is in the
Salar de Uyuni area of Bolivia, which has 5.4 million tonnes. Other major suppliers include Australia, Argentina and China.
As of 2015, the
Czech Geological Survey
Czech may refer to:
* Anything from or related to the Czech Republic, a country in Europe
** Czech language
** Czechs, the people of the area
** Czech culture
** Czech cuisine
* One of three mythical brothers, Lech, Czech, and Rus'
Places
*Czech ...
considered the entire
Ore Mountains in the Czech Republic as lithium province. Five deposits are registered, one near is considered as a potentially economical deposit, with 160 000 tonnes of lithium. In December 2019, Finnish mining company Keliber Oy reported its Rapasaari lithium deposit has estimated proven and probable ore reserves of 5.280 million tonnes.
In June 2010, ''
The New York Times
''The New York Times'' (''the Times'', ''NYT'', or the Gray Lady) is a daily newspaper based in New York City with a worldwide readership reported in 2020 to comprise a declining 840,000 paid print subscribers, and a growing 6 million paid d ...
'' reported that American geologists were conducting ground surveys on
dry salt lakes in western
Afghanistan
Afghanistan, officially the Islamic Emirate of Afghanistan,; prs, امارت اسلامی افغانستان is a landlocked country located at the crossroads of Central Asia and South Asia. Referred to as the Heart of Asia, it is bordere ...
believing that large deposits of lithium are located there. These estimates are "based principally on old data, which was gathered mainly by the
Soviets
Soviet people ( rus, сове́тский наро́д, r=sovyétsky naród), or citizens of the USSR ( rus, гра́ждане СССР, grázhdanye SSSR), was an umbrella demonym for the population of the Soviet Union.
Nationality policy in ...
during their
occupation of Afghanistan from 1979–1989". The
Department of Defense Department of Defence or Department of Defense may refer to:
Current departments of defence
* Department of Defence (Australia)
* Department of National Defence (Canada)
* Department of Defence (Ireland)
* Department of National Defense (Philipp ...
estimated the lithium reserves in Afghanistan to amount to the ones in Bolivia and dubbed it as a potential "Saudi-Arabia of lithium". In
Cornwall
Cornwall (; kw, Kernow ) is a historic county and ceremonial county in South West England. It is recognised as one of the Celtic nations, and is the homeland of the Cornish people. Cornwall is bordered to the north and west by the Atlantic ...
, England, the presence of brine rich in lithium was well known due to the region's historic
mining industry
Mining is the extraction of valuable minerals or other geological materials from the Earth, usually from an ore body, lode, vein, seam, reef, or placer deposit. The exploitation of these deposits for raw material is based on the economic via ...
, and private investors have conducted tests to investigate potential lithium extraction in this area.
Biological
Lithium is found in trace amount in numerous plants, plankton, and invertebrates, at concentrations of 69 to 5,760 parts per billion (ppb). In vertebrates the concentration is slightly lower, and nearly all vertebrate tissue and body fluids contain lithium ranging from 21 to 763 ppb.
Marine organisms tend to bioaccumulate lithium more than terrestrial organisms. Whether lithium has a physiological role in any of these organisms is unknown.
Studies of lithium concentrations in mineral-rich soil give ranges between around 0.1 and 50−100
ppm, with some concentrations as high as 100−400 ppm, although it is unlikely that all of it is available for uptake by
plant
Plants are predominantly photosynthetic eukaryotes of the kingdom Plantae. Historically, the plant kingdom encompassed all living things that were not animals, and included algae and fungi; however, all current definitions of Plantae exclu ...
s.
Lithium concentration in plant tissue is typically around 1
ppm, with some plant
families
Family (from la, familia) is a group of people related either by consanguinity (by recognized birth) or affinity (by marriage or other relationship). The purpose of the family is to maintain the well-being of its members and of society. Ideal ...
bioaccumulating more lithium than others; lithium accumulation does not appear to affect the
essential nutrient composition of plants.
Tolerance to lithium varies by plant species and typically parallels
sodium tolerance;
maize
Maize ( ; ''Zea mays'' subsp. ''mays'', from es, maíz after tnq, mahiz), also known as corn (North American and Australian English), is a cereal grain first domesticated by indigenous peoples in southern Mexico about 10,000 years ago. The ...
and
Rhodes grass
''Chloris gayana'' is a species of Poaceae, grass known by the common name Rhodes grass. It is native to Africa but it can be found throughout the tropical and subtropical world as a introduced species, naturalized species.
It can grow in many t ...
, for example, are highly tolerant to lithium injury while
avocado
The avocado (''Persea americana'') is a medium-sized, evergreen tree in the laurel family ( Lauraceae). It is native to the Americas and was first domesticated by Mesoamerican tribes more than 5,000 years ago. Then as now it was prized for ...
and
soybean
The soybean, soy bean, or soya bean (''Glycine max'') is a species of legume native to East Asia, widely grown for its edible bean, which has numerous uses.
Traditional unfermented food uses of soybeans include soy milk, from which tofu a ...
are very sensitive.
Similarly, lithium at concentrations of 5 ppm reduces
seed germination
Germination is the process by which an organism grows from a seed or spore. The term is applied to the sprouting of a seedling from a seed of an angiosperm or gymnosperm, the growth of a sporeling from a spore, such as the spores of fungi, fern ...
in some species (e.g.
Asian rice
''Oryza sativa'', commonly known as Asian rice or indica rice, is the plant species most commonly referred to in English as ''rice''. It is the type of farmed rice whose cultivars are most common globally, and was first domesticated in the Yan ...
and
chickpea) but not in others (e.g.
barley
Barley (''Hordeum vulgare''), a member of the grass family, is a major cereal grain grown in temperate climates globally. It was one of the first cultivated grains, particularly in Eurasia as early as 10,000 years ago. Globally 70% of barley p ...
and
wheat
Wheat is a grass widely cultivated for its seed, a cereal grain that is a worldwide staple food. The many species of wheat together make up the genus ''Triticum'' ; the most widely grown is common wheat (''T. aestivum''). The archaeologi ...
).
Many of lithium's major biological effects can be explained by its competition with other ions.
The
monovalent lithium
ion
An ion () is an atom or molecule with a net electrical charge.
The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by conve ...
competes with other ions such as
sodium
Sodium is a chemical element with the symbol Na (from Latin ''natrium'') and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 of the periodic table. Its only stable ...
(immediately below lithium on the
periodic table), which like lithium is also a monovalent
alkali metal.
Lithium also competes with
bivalent Bivalent may refer to:
* Bivalent (chemistry), a molecule formed from two or more atoms bound together
*Bivalent (engine), an engine that can operate on two different types of fuel
*Bivalent (genetics), a pair of homologous chromosomes
*Bivalent log ...
magnesium
Magnesium is a chemical element with the symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 of the periodic ta ...
ions, whose
ionic radius
Ionic radius, ''r''ion, is the radius of a monatomic ion in an ionic crystal structure. Although neither atoms nor ions have sharp boundaries, they are treated as if they were hard spheres with radii such that the sum of ionic radii of the catio ...
(86
pm) is approximately that of the lithium ion
(90 pm).
Mechanisms that transport sodium across cellular membranes also transport lithium.
For instance,
sodium channel
Sodium channels are integral membrane proteins that form ion channels, conducting sodium ions (Na+) through a cell's membrane. They belong to the superfamily of cation channels and can be classified according to the trigger that opens the chann ...
s (both
voltage-gated
Voltage-gated ion channels are a class of transmembrane proteins that form ion channels that are activated by changes in the electrical membrane potential near the channel. The membrane potential alters the conformation of the channel proteins ...
and
epithelial
Epithelium or epithelial tissue is one of the four basic types of animal tissue, along with connective tissue, muscle tissue and nervous tissue. It is a thin, continuous, protective layer of compactly packed cells with a little intercell ...
) are particularly major pathways of entry for lithium.
Lithium ions can also
permeate
In physics and engineering, permeation (also called imbuing) is the penetration of a permeate (a fluid such as a liquid, gas, or vapor) through a solid. It is directly related to the concentration gradient of the permeate, a material's intrins ...
through
ligand-gated ion channel
Ligand-gated ion channels (LICs, LGIC), also commonly referred to as ionotropic receptors, are a group of transmembrane ion-channel proteins which open to allow ions such as Na+, K+, Ca2+, and/or Cl− to pass through the membrane in res ...
s as well as cross both
nuclear
Nuclear may refer to:
Physics
Relating to the nucleus of the atom:
* Nuclear engineering
*Nuclear physics
*Nuclear power
*Nuclear reactor
*Nuclear weapon
*Nuclear medicine
*Radiation therapy
*Nuclear warfare
Mathematics
*Nuclear space
*Nuclear ...
and
mitochondrial membrane
A membrane is a selective barrier; it allows some things to pass through but stops others. Such things may be molecules, ions, or other small particles. Membranes can be generally classified into synthetic membranes and biological membranes. ...
s.
Like sodium, lithium can enter and partially block (although not
permeate
In physics and engineering, permeation (also called imbuing) is the penetration of a permeate (a fluid such as a liquid, gas, or vapor) through a solid. It is directly related to the concentration gradient of the permeate, a material's intrins ...
)
potassium channel
Potassium channels are the most widely distributed type of ion channel found in virtually all organisms. They form potassium-selective pores that span cell membranes. Potassium channels are found in most cell types and control a wide variety of c ...
s and
calcium channels.
The biological effects of lithium are many and varied but its
mechanisms of action
In pharmacology, the term mechanism of action (MOA) refers to the specific biochemical interaction through which a drug substance produces its pharmacological effect. A mechanism of action usually includes mention of the specific molecular targe ...
are only partially understood.
For instance, studies of
lithium-treated patients with
bipolar disorder
Bipolar disorder, previously known as manic depression, is a mental disorder characterized by periods of depression and periods of abnormally elevated mood that last from days to weeks each. If the elevated mood is severe or associated with ...
show that, among many other effects, lithium partially reverses
telomere
A telomere (; ) is a region of repetitive nucleotide sequences associated with specialized proteins at the ends of linear chromosomes. Although there are different architectures, telomeres, in a broad sense, are a widespread genetic feature mos ...
shortening
Shortening is any fat that is a solid at room temperature and used to make crumbly pastry and other food products. Although butter is solid at room temperature and is frequently used in making pastry, the term ''shortening'' seldom refers to b ...
in these patients and also increases mitochondrial function, although how lithium produces these
pharmacological effect
In pharmacology, biological activity or pharmacological activity describes the beneficial or adverse effects of a drug on living matter. When a drug is a complex chemical mixture, this activity is exerted by the substance's active ingredient or p ...
s is not understood.
Even the exact mechanisms involved in
lithium toxicity
Lithium toxicity, also known as lithium overdose, is the condition of having too much lithium. Symptoms may include a tremor, increased reflexes, trouble walking, kidney problems, and an altered level of consciousness. Some symptoms may last for a ...
are not fully understood.
History
Petalite
Petalite, also known as castorite, is a lithium aluminum phyllosilicate mineral Li Al Si4 O10, crystallizing in the monoclinic system. Petalite occurs as colorless, pink, grey, yellow, yellow grey, to white tabular crystals and columnar masses. ...
(LiAlSi
4O
10) was discovered in 1800 by the Brazilian chemist and statesman
José Bonifácio de Andrada e Silva
José Bonifácio de Andrada e Silva (; 13 June 17636 April 1838) was a Brazilian statesman, naturalist, mineralist, professor and poet, born in Santos, São Paulo, then part of the Portuguese Empire. He was one of the most important mentors ...
in a mine on the island of
Utö, Sweden.
However, it was not until 1817 that
Johan August Arfwedson
Johan August Arfwedson (12 January 1792 – 28 October 1841) was a Swedish chemist who discovered the chemical element lithium in 1817 by isolating it as a salt.
Life and work
Arfwedson belonged to a wealthy bourgeois family, the son of t ...
, then working in the laboratory of the chemist
Jöns Jakob Berzelius
Jöns is a Swedish given name and a surname.
Notable people with the given name include:
* Jöns Jacob Berzelius (1779–1848), Swedish chemist
* Jöns Budde (1435–1495), Franciscan friar from the Brigittine monastery in NaantaliVallis Grati ...
,
detected the presence of a new element while analyzing petalite ore.
This element formed compounds similar to those of
sodium
Sodium is a chemical element with the symbol Na (from Latin ''natrium'') and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 of the periodic table. Its only stable ...
and
potassium
Potassium is the chemical element with the symbol K (from Neo-Latin ''kalium'') and atomic number19. Potassium is a silvery-white metal that is soft enough to be cut with a knife with little force. Potassium metal reacts rapidly with atmosph ...
, though its
carbonate
A carbonate is a salt of carbonic acid (H2CO3), characterized by the presence of the carbonate ion, a polyatomic ion with the formula . The word ''carbonate'' may also refer to a carbonate ester, an organic compound containing the carbonate ...
and
hydroxide
Hydroxide is a diatomic anion with chemical formula OH−. It consists of an oxygen and hydrogen atom held together by a single covalent bond, and carries a negative electric charge. It is an important but usually minor constituent of water. I ...
were less
soluble in water and less
alkaline.
Berzelius gave the alkaline material the name "''lithion''/''lithina''", from the Greek word ''λιθoς'' (transliterated as ''lithos'', meaning "stone"), to reflect its discovery in a solid mineral, as opposed to potassium, which had been discovered in plant ashes, and sodium, which was known partly for its high abundance in animal blood. He named the metal inside the material "lithium".
Arfwedson later showed that this same element was present in the minerals
spodumene
Spodumene is a pyroxene mineral consisting of lithium aluminium inosilicate, Li Al( Si O3)2, and is a source of lithium. It occurs as colorless to yellowish, purplish, or lilac kunzite (see below), yellowish-green or emerald-green hiddenite, pr ...
and
lepidolite
Lepidolite is a lilac-gray or rose-colored member of the mica group of minerals with chemical formula . It is the most abundant lithium-bearing mineral and is a secondary source of this metal. It is the major source of the alkali metal rubidi ...
.
In 1818,
Christian Gmelin
Christian Gottlob Gmelin (12 October 1792 – 13 May 1860) was a German chemist. He was born in Tübingen, Germany, and was a grandson of Johann Konrad Gmelin and a great-grandson of Johann Georg Gmelin.
Scientific career
In 1818, Gmelin was one ...
was the first to observe that lithium salts give a bright red color to flame.
However, both Arfwedson and Gmelin tried and failed to isolate the pure element from its salts.
It was not isolated until 1821, when
William Thomas Brande
William Thomas Brande FRS FRSE (11 January 178811 February 1866) was an English chemist.
Biography
Brande was born in Arlington Street, London, England, the youngest son of six children to Augustus Everard Brande an apothecary, originally fr ...
obtained it by
electrolysis of
lithium oxide
Lithium oxide ( O) or lithia is an inorganic chemical compound. It is a white solid. Although not specifically important, many materials are assessed on the basis of their Li2O content. For example, the Li2O content of the principal lithium miner ...
, a process that had previously been employed by the chemist Sir
Humphry Davy
Sir Humphry Davy, 1st Baronet, (17 December 177829 May 1829) was a British chemist and inventor who invented the Davy lamp and a very early form of arc lamp. He is also remembered for isolating, by using electricity, several elements for t ...
to isolate the alkali metals potassium and sodium.
Brande also described some pure salts of lithium, such as the chloride, and, estimating that lithia (
lithium oxide
Lithium oxide ( O) or lithia is an inorganic chemical compound. It is a white solid. Although not specifically important, many materials are assessed on the basis of their Li2O content. For example, the Li2O content of the principal lithium miner ...
) contained about 55% metal, estimated the atomic weight of lithium to be around 9.8 g/mol (modern value ~6.94 g/mol). In 1855, larger quantities of lithium were produced through the electrolysis of
lithium chloride
Lithium chloride is a chemical compound with the formula Li Cl. The salt is a typical ionic compound (with certain covalent characteristics), although the small size of the Li+ ion gives rise to properties not seen for other alkali metal chlorid ...
by
Robert Bunsen
Robert Wilhelm Eberhard Bunsen (;
30 March 1811
– 16 August 1899) was a German chemist. He investigated emission spectra of heated elements, and discovered caesium (in 1860) and rubidium (in 1861) with the physicist Gustav Kirchhoff. The Bu ...
and
Augustus Matthiessen
Augustus Matthiessen, FRS (2 January 1831, in London – 6 October 1870, in London), the son of a merchant, was a British chemist and physicist who obtained his PhD in Germany at the University of Gießen in 1852 with Johann Heinrich Buff. He ...
.
The discovery of this procedure led to commercial production of lithium in 1923 by the German company
Metallgesellschaft AG
Metallgesellschaft AG was formerly one of Germany's largest industrial conglomerates based in Frankfurt. It had over 20,000 employees and revenues in excess of 10 billion US dollars. It had over 250 subsidiaries specializing in mining, specialty c ...
, which performed an electrolysis of a liquid mixture of lithium chloride and
potassium chloride.
Australian psychiatrist
John Cade
John Frederick Joseph Cade AO
(18 January 1912 – 16 November 1980) was an Australian psychiatrist who in 1948 discovered the effects of lithium carbonate as a mood stabilizer in the treatment of bipolar disorder, then known as manic depres ...
is credited with reintroducing and popularizing the use of lithium to treat
mania in 1949. Shortly after, throughout the mid 20th century, lithium's mood stabilizing applicability for mania and
depression took off in Europe and the United States.
The production and use of lithium underwent several drastic changes in history. The first major application of lithium was in high-temperature
lithium greases for aircraft engines and similar applications in
World War II
World War II or the Second World War, often abbreviated as WWII or WW2, was a world war that lasted from 1939 to 1945. It involved the vast majority of the world's countries—including all of the great powers—forming two opposing ...
and shortly after. This use was supported by the fact that lithium-based soaps have a higher melting point than other alkali soaps, and are less corrosive than calcium based soaps. The small demand for lithium soaps and lubricating greases was supported by several small mining operations, mostly in the US.
The demand for lithium increased dramatically during the
Cold War with the production of
nuclear fusion weapons. Both lithium-6 and lithium-7 produce
tritium
Tritium ( or , ) or hydrogen-3 (symbol T or H) is a rare and radioactive isotope of hydrogen with half-life about 12 years. The nucleus of tritium (t, sometimes called a ''triton'') contains one proton and two neutrons, whereas the nucleus of ...
when irradiated by neutrons, and are thus useful for the production of tritium by itself, as well as a form of solid fusion fuel used inside hydrogen bombs in the form of
lithium deuteride
Lithium hydride is an inorganic compound with the formula Li H. This alkali metal hydride is a colorless solid, although commercial samples are grey. Characteristic of a salt-like (ionic) hydride, it has a high melting point, and it is not sol ...
. The US became the prime producer of lithium between the late 1950s and the mid-1980s. At the end, the stockpile of lithium was roughly 42,000 tonnes of lithium hydroxide. The stockpiled lithium was depleted in lithium-6 by 75%, which was enough to affect the measured
atomic weight
Relative atomic mass (symbol: ''A''; sometimes abbreviated RAM or r.a.m.), also known by the deprecated synonym atomic weight, is a dimensionless physical quantity defined as the ratio of the average mass of atoms of a chemical element in a giv ...
of lithium in many standardized chemicals, and even the atomic weight of lithium in some "natural sources" of lithium ion which had been "contaminated" by lithium salts discharged from isotope separation facilities, which had found its way into ground water.
Lithium is used to decrease the melting temperature of glass and to improve the melting behavior of
aluminium oxide in the
Hall-Héroult process.
These two uses dominated the market until the middle of the 1990s. After the end of the
nuclear arms race
The nuclear arms race was an arms race competition for supremacy in nuclear warfare between the United States, the Soviet Union, and their respective allies during the Cold War. During this same period, in addition to the American and Soviet nuc ...
, the demand for lithium decreased and the sale of department of energy stockpiles on the open market further reduced prices.
In the mid-1990s, several companies started to isolate lithium from
brine which proved to be a less expensive option than underground or open-pit mining. Most of the mines closed or shifted their focus to other materials because only the ore from zoned pegmatites could be mined for a competitive price. For example, the US mines near
Kings Mountain, North Carolina closed before the beginning of the 21st century.
The development of lithium ion batteries increased the demand for lithium and became the dominant use in 2007.
With the surge of lithium demand in batteries in the 2000s, new companies have expanded brine isolation efforts to meet the rising demand.
It has been argued that lithium will be one of the main objects of geopolitical competition in a world running on renewable energy and dependent on batteries, but this perspective has also been criticised for underestimating the power of economic incentives for expanded production.
Chemistry
Of lithium metal
Lithium reacts with water easily, but with noticeably less vigor than other alkali metals. The reaction forms
hydrogen
Hydrogen is the chemical element with the symbol H and atomic number 1. Hydrogen is the lightest element. At standard conditions hydrogen is a gas of diatomic molecules having the formula . It is colorless, odorless, tasteless, non-toxic ...
gas and
lithium hydroxide
Lithium hydroxide is an inorganic compound with the formula LiOH. It can exist as anhydrous or hydrated, and both forms are white hygroscopic solids. They are soluble in water and slightly soluble in ethanol. Both are available commercially. While ...
.
When placed over a flame, lithium compounds give off a striking crimson color, but when the metal burns strongly, the flame becomes a brilliant silver. Lithium will ignite and burn in oxygen when exposed to water or water vapor. In moist air, lithium rapidly tarnishes to form a black coating of
lithium hydroxide
Lithium hydroxide is an inorganic compound with the formula LiOH. It can exist as anhydrous or hydrated, and both forms are white hygroscopic solids. They are soluble in water and slightly soluble in ethanol. Both are available commercially. While ...
(LiOH and LiOH·H
2O),
lithium nitride
Lithium nitride is a compound with the formula Li3N. It is the only stable alkali metal nitride. The solid has a reddish-pink color and high melting point.
Preparation and handling
Lithium nitride is prepared by direct combination of elemental ...
(Li
3N) and
lithium carbonate (Li
2CO
3, the result of a secondary reaction between LiOH and
CO2).
Lithium is one of the few metals that react with
nitrogen
Nitrogen is the chemical element with the symbol N and atomic number 7. Nitrogen is a nonmetal and the lightest member of group 15 of the periodic table, often called the pnictogens. It is a common element in the universe, estimated at se ...
gas.
Because of its reactivity with water, and especially nitrogen, lithium metal is usually stored in a hydrocarbon sealant, often
petroleum jelly. Although the heavier alkali metals can be stored under
mineral oil
Mineral oil is any of various colorless, odorless, light mixtures of higher alkanes from a mineral source, particularly a distillate of petroleum, as distinct from usually edible vegetable oils.
The name 'mineral oil' by itself is imprecise, ...
, lithium is not dense enough to fully submerge itself in these liquids.
Lithium has a
diagonal relationship
A diagonal relationship is said to exist between certain pairs of diagonally adjacent elements in the second and third periods (first 20 elements) of the periodic table. These pairs (lithium (Li) and magnesium (Mg), beryllium (Be) and aluminium ...
with
magnesium
Magnesium is a chemical element with the symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 of the periodic ta ...
, an element of similar atomic and
ionic radius
Ionic radius, ''r''ion, is the radius of a monatomic ion in an ionic crystal structure. Although neither atoms nor ions have sharp boundaries, they are treated as if they were hard spheres with radii such that the sum of ionic radii of the catio ...
. Chemical resemblances between the two metals include the formation of a
nitride
In chemistry, a nitride is an inorganic compound of nitrogen. The "nitride" anion, N3- ion, is very elusive but compounds of nitride are numerous, although rarely naturally occuring. Some nitrides have a find applications, such as wear-resistant ...
by reaction with N
2, the formation of an
oxide () and peroxide () when burnt in O
2,
salts
In chemistry, a salt is a chemical compound consisting of an ionic assembly of positively charged cations and negatively charged anions, which results in a compound with no net electric charge. A common example is table salt, with positively c ...
with similar
solubilities, and thermal instability of the
carbonate
A carbonate is a salt of carbonic acid (H2CO3), characterized by the presence of the carbonate ion, a polyatomic ion with the formula . The word ''carbonate'' may also refer to a carbonate ester, an organic compound containing the carbonate ...
s and nitrides.
The metal reacts with hydrogen gas at high temperatures to produce
lithium hydride
Lithium hydride is an inorganic compound with the formula Li H. This alkali metal hydride is a colorless solid, although commercial samples are grey. Characteristic of a salt-like (ionic) hydride, it has a high melting point, and it is not solub ...
(LiH).
Lithium forms a variety of binary and ternary materials by direct reaction with the main group elements. These
Zintl phase
In chemistry, a Zintl phase is a product of a reaction between a group 1 (alkali metal) or group 2 ( alkaline earth metal) and main group metal or metalloid (from groups 13, 14, 15, or 16). It is characterized by intermediate metallic/ ionic bond ...
s, although highly covalent, can be viewed as salts of polyatomic anions such as Si
44-, P
73-, and Te
52-. With graphite, lithium forms a variety of
intercalation compound
In chemistry, intercalation is the reversible inclusion or insertion of a molecule (or ion) into layered materials with layered structures. Examples are found in graphite and transition metal dichalcogenides.
:
Examples Graphite
One famous int ...
s.
It dissolves in ammonia (and amines) to give
3)4">i(NH3)4sup>+ and the
solvated electron
A solvated electron is a free electron in (solvated in) a solution, and is the smallest possible anion. Solvated electrons occur widely. Often, discussions of solvated electrons focus on their solutions in ammonia, which are stable for days, but s ...
.
Inorganic compounds
![Butyllithium-hexamer-from-xtal-3D-balls-A](https://upload.wikimedia.org/wikipedia/commons/8/8d/Butyllithium-hexamer-from-xtal-3D-balls-A.png)
Lithium forms salt-like derivatives with all
halides and pseudohalides. Some examples include the halides
LiF
Lithium fluoride is an inorganic compound with the chemical formula LiF. It is a colorless solid, that transitions to white with decreasing crystal size. Although odorless, lithium fluoride has a bitter-saline taste. Its structure is analogous to ...
,
LiCl,
LiBr,
LiI, as well as the
pseudohalide
Pseudohalogens are polyatomic analogues of halogens, whose chemistry, resembling that of the true halogens, allows them to substitute for halogens in several classes of chemical compounds. Pseudohalogens occur in pseudohalogen molecules, inorganic ...
s and related anions. Lithium carbonate has been described as the most important compound of lithium.
This white solid is the principal product of beneficiation of lithium ores. It is a precursor to other salts including ceramics and materials for lithium batteries.
The compounds
and
are useful
reagents. These salts and many other lithium salts exhibit distinctively high solubility in ethers, in contrast with salts of heavier alkali metals.
In aqueous solution, the
coordination complex
A coordination complex consists of a central atom or ion, which is usually metallic and is called the ''coordination centre'', and a surrounding array of bound molecules or ions, that are in turn known as '' ligands'' or complexing agents. ...
2O)4">i(H2O)4sup>+ predominates for many lithium salts. Related complexes are known with amines and ethers.
Organic chemistry
Organolithium compounds are numerous and useful. They are defined by the presence of a
bond
Bond or bonds may refer to:
Common meanings
* Bond (finance), a type of debt security
* Bail bond, a commercial third-party guarantor of surety bonds in the United States
* Chemical bond, the attraction of atoms, ions or molecules to form chemica ...
between
carbon
Carbon () is a chemical element with the symbol C and atomic number 6. It is nonmetallic and tetravalent—its atom making four electrons available to form covalent chemical bonds. It belongs to group 14 of the periodic table. Carbon mak ...
and lithium. They serve as metal-stabilized
carbanions, although their solution and solid-state structures are more complex than this simplistic view. Thus, these are extremely powerful
bases and
nucleophiles
In chemistry, a nucleophile is a chemical species that forms bonds by donating an electron pair. All molecules and ions with a free pair of electrons or at least one pi bond can act as nucleophiles. Because nucleophiles donate electrons, they are ...
. They have also been applied in asymmetric synthesis in the pharmaceutical industry. For laboratory organic synthesis, many organolithium reagents are commercially available in solution form. These reagents are highly reactive, and are sometimes
pyrophoric
A substance is pyrophoric (from grc-gre, πυροφόρος, , 'fire-bearing') if it ignites spontaneously in air at or below (for gases) or within 5 minutes after coming into contact with air (for liquids and solids). Examples are organolit ...
.
Like its inorganic compounds, almost all organic compounds of lithium formally follow the duet rule (e.g., BuLi, MeLi). However, it is important to note that in the absence of coordinating solvents or ligands, organolithium compounds form dimeric, tetrameric, and hexameric clusters (e.g., BuLi is actually
uLi
Uli may refer to:
*Uli, Iran, a village
*Uli, Anambra, a town in Nigeria
* Uli I of Mali
* Uli (design), by the Igbo people of Nigeria
* Uli figure, from New Ireland, Papua New Guinea
*Uli (food), a rice-based food
* ISO 639 code for the Ulithian ...
sub>6 and MeLi is actually
eLi
Eli most commonly refers to:
* Eli (name), a given name, nickname and surname
* Eli (biblical figure)
Eli or ELI may also refer to:
Film
* ''Eli'' (2015 film), a Tamil film
* ''Eli'' (2019 film), an American horror film
Music
* ''Eli'' (Jan ...
sub>4) which feature multi-center bonding and increase the coordination number around lithium. These clusters are broken down into smaller or monomeric units in the presence of solvents like
dimethoxyethane
Dimethoxyethane, also known as glyme, monoglyme, dimethyl glycol, ethylene glycol dimethyl ether, dimethyl cellosolve, and DME, is a colorless, aprotic, and liquid ether that is used as a solvent, especially in batteries. Dimethoxyethane is mi ...
(DME) or ligands like
tetramethylethylenediamine
Tetramethylethylenediamine (TMEDA or TEMED) is a chemical compound with the formula (CH3)2NCH2CH2N(CH3)2. This species is derived from ethylenediamine by replacement of the four amine hydrogens with four methyl groups. It is a colorless liquid, ...
(TMEDA). As an exception to the duet rule, a two-coordinate lithate complex with four electrons around lithium,
4">i(thf)4sup>+
3Si)3C)2Li">(Me3Si)3C)2Lisup>–, has been characterized crystallographically.
Production
Lithium production has greatly increased since the end of
World War II
World War II or the Second World War, often abbreviated as WWII or WW2, was a world war that lasted from 1939 to 1945. It involved the vast majority of the world's countries—including all of the great powers—forming two opposing ...
. The main sources of lithium are
brines and
ore
Ore is natural rock or sediment that contains one or more valuable minerals, typically containing metals, that can be mined, treated and sold at a profit.Encyclopædia Britannica. "Ore". Encyclopædia Britannica Online. Retrieved 7 Apr ...
s.
Lithium metal is produced through
electrolysis applied to a mixture of fused 55%
lithium chloride
Lithium chloride is a chemical compound with the formula Li Cl. The salt is a typical ionic compound (with certain covalent characteristics), although the small size of the Li+ ion gives rise to properties not seen for other alkali metal chlorid ...
and 45%
potassium chloride at about 450 °C.
Reserves and occurrence
![USGS-PP-1802k-K13](https://upload.wikimedia.org/wikipedia/commons/6/60/USGS-PP-1802k-K13.png)
The
US Geological Survey
The United States Geological Survey (USGS), formerly simply known as the Geological Survey, is a scientific agency of the United States government. The scientists of the USGS study the landscape of the United States, its natural resources, and ...
(USGS) estimated worldwide identified lithium reserves in 2020 and 2021 to be 17 million and 21 million
tonne
The tonne ( or ; symbol: t) is a unit of mass equal to 1000 kilograms. It is a non-SI unit accepted for use with SI. It is also referred to as a metric ton to distinguish it from the non-metric units of the short ton ( United State ...
s, respectively.
An accurate estimate of world lithium reserves is difficult.
One reason for this is that most lithium classification schemes are developed for solid ore deposits, whereas brine is a
fluid that is problematic to treat with the same classification scheme due to varying concentrations and pumping effects.
Following a hike in lithium price in 2015 and concern for insufficiency of lithium resource for the growing
lithium-ion battery
A lithium-ion or Li-ion battery is a type of rechargeable battery which uses the reversible reduction of lithium ions to store energy. It is the predominant battery type used in portable consumer electronics and electric vehicles. It also s ...
industry, a peer-reviewed analysis of
USGS
The United States Geological Survey (USGS), formerly simply known as the Geological Survey, is a scientific agency of the United States government. The scientists of the USGS study the landscape of the United States, its natural resources, a ...
data in 2017 predicted that there will be no shortage of lithium and current estimates of reserves will increase along with the demand.
Worldwide lithium resources identified by
USGS
The United States Geological Survey (USGS), formerly simply known as the Geological Survey, is a scientific agency of the United States government. The scientists of the USGS study the landscape of the United States, its natural resources, a ...
started to increase in 2017 owing to continuing exploration. Identified resources in 2016, 2017, 2018, 2019 and 2020 were 41, 47, 54, 62 and 80 million tonnes, respectively.
In 2013, the world was estimated to contain about 15 million tonnes of lithium reserves, while 65 million tonnes of known resources were reasonable. 75% of lithium reserves could be found in the ten largest
deposits
A deposit account is a bank account maintained by a financial institution in which a customer can deposit and withdraw money. Deposit accounts can be savings accounts, current accounts or any of several other types of accounts explained below.
...
of the world.
Another study noted that 83% of the geological resources of lithium are located in six brine, two
pegmatite, and two
sedimentary
Sedimentary rocks are types of rock that are formed by the accumulation or deposition of mineral or organic particles at Earth's surface, followed by cementation. Sedimentation is the collective name for processes that cause these particles ...
deposits.
In the US, lithium is recovered from brine pools in
Nevada
Nevada ( ; ) is a state in the Western region of the United States. It is bordered by Oregon to the northwest, Idaho to the northeast, California to the west, Arizona to the southeast, and Utah to the east. Nevada is the 7th-most extensive, ...
.
A deposit discovered in 2013 in Wyoming's
Rock Springs Uplift The Rock Springs Uplift is an area of uplifted Cretaceous to Eocene rocks in Wyoming surrounded and once covered by sediments of the Green River Formation which were deposited in the Eocene Lake Gosiute.Surdam, Ronald C. and K. O. Stanley, ''Lacustr ...
is estimated to contain 228,000 tons. Additional deposits in the same formation were estimated to be as much as 18 million tons. Similarly in Nevada, the
McDermitt Caldera
The McDermitt Caldera is a large, oval-shaped caldera west of McDermitt in southeastern Oregon and northern Nevada in the United States. It is about long north–south and wide east–west. The western part of the caldera is in the Trout Cre ...
hosts lithium-bearing volcanic muds that consist of the largest known deposits of lithium within the United States.
Lithium triangle
The world's top four lithium-producing countries from 2019, as reported by the US Geological Survey are
Australia,
Chile
Chile, officially the Republic of Chile, is a country in the western part of South America. It is the southernmost country in the world, and the closest to Antarctica, occupying a long and narrow strip of land between the Andes to the east a ...
,
China and
Argentina
Argentina (), officially the Argentine Republic ( es, link=no, República Argentina), is a country in the southern half of South America. Argentina covers an area of , making it the second-largest country in South America after Brazil, th ...
.
The three countries of
Chile
Chile, officially the Republic of Chile, is a country in the western part of South America. It is the southernmost country in the world, and the closest to Antarctica, occupying a long and narrow strip of land between the Andes to the east a ...
,
Bolivia, and
Argentina
Argentina (), officially the Argentine Republic ( es, link=no, República Argentina), is a country in the southern half of South America. Argentina covers an area of , making it the second-largest country in South America after Brazil, th ...
make up a region known as the
Lithium Triangle. The Lithium Triangle is known for its high-quality salt flats, which include Bolivia's
Salar de Uyuni, Chile's
Salar de Atacama
Salar de Atacama is the largest salt flat in Chile. It is located south of San Pedro de Atacama, is surrounded by mountains, and has no drainage outlets. In the east it is enclosed by the main chain of the Andes, while to the west lies a secondar ...
, and Argentina's
Salar de Arizaro
Salar de Arizaro ("Arizaro" comes from Atacameno "crow", "condor" and , , "accommodation", "place where something is common".) is a large salt flat of the Andes in north-western Argentina.
It is located between the villages of Tolar Grande a ...
. The Lithium Triangle is believed to contain over 75% of existing known lithium reserves. Deposits are also found in South America throughout the
Andes
The Andes, Andes Mountains or Andean Mountains (; ) are the longest continental mountain range in the world, forming a continuous highland along the western edge of South America. The range is long, wide (widest between 18°S – 20°S ...
mountain chain. Chile is the leading producer, followed by Argentina. Both countries recover lithium from brine pools. According to USGS, Bolivia's
Uyuni
Uyuni (Aymara, ''uyu'' pen (enclosure), yard, cemetery, ''-ni'' a suffix to indicate ownership, "the one that has got a pen", "the one with a pen") is a city in the southwest of Bolivia.
Uyuni primarily serves as a gateway for tourists visiting t ...
Desert has 5.4 million tonnes of lithium.
Half the world's known reserves are located in
Bolivia along the central eastern slope of the Andes. The Bolivian government has invested US$900 million and in 2021 successfully produced 540 tons
The brines in the salt pans of the Lithium Triangle vary widely in lithium content.
Concentrations can also vary in time as brines are fluids that are changeable and mobile.
Since 2018 the
Democratic Republic of Congo
The Democratic Republic of the Congo (french: République démocratique du Congo (RDC), colloquially "La RDC" ), informally Congo-Kinshasa, DR Congo, the DRC, the DROC, or the Congo, and formerly and also colloquially Zaire, is a country in ...
is known to have the largest lithium
spodumene
Spodumene is a pyroxene mineral consisting of lithium aluminium inosilicate, Li Al( Si O3)2, and is a source of lithium. It occurs as colorless to yellowish, purplish, or lilac kunzite (see below), yellowish-green or emerald-green hiddenite, pr ...
hard-rock deposit in the world. The deposit located in
Manono,
DRC
The Democratic Republic of the Congo (french: République démocratique du Congo (RDC), colloquially "La RDC" ), informally Congo-Kinshasa, DR Congo, the DRC, the DROC, or the Congo, and formerly and also colloquially Zaire, is a country in ...
, may hold up to 1.5 billion tons of lithium spodumene hard-rock. The two largest pegmatites (known as the Carriere de l'Este Pegmatite and the Roche Dure Pegmatite) are each of similar size or larger than the famous Greenbushes Pegmatite in
Western Australia
Western Australia (commonly abbreviated as WA) is a state of Australia occupying the western percent of the land area of Australia excluding external territories. It is bounded by the Indian Ocean to the north and west, the Southern Ocean to th ...
. Thus, the
Democratic Republic of Congo
The Democratic Republic of the Congo (french: République démocratique du Congo (RDC), colloquially "La RDC" ), informally Congo-Kinshasa, DR Congo, the DRC, the DROC, or the Congo, and formerly and also colloquially Zaire, is a country in ...
is expected to be a significant supplier of lithium to the world with its high grade and low impurities.
According to a later 2011 study by
Lawrence Berkeley National Laboratory and the
University of California, Berkeley
The University of California, Berkeley (UC Berkeley, Berkeley, Cal, or California) is a public land-grant research university in Berkeley, California. Established in 1868 as the University of California, it is the state's first land-grant u ...
, the then-estimated reserve base of lithium should not be a limiting factor for large-scale battery production for electric vehicles because an estimated 1 billion 40
kWh Li-based batteries could be built with those reserves - about 10 kg of lithium per car. Another 2011 study at the
University of Michigan
, mottoeng = "Arts, Knowledge, Truth"
, former_names = Catholepistemiad, or University of Michigania (1817–1821)
, budget = $10.3 billion (2021)
, endowment = $17 billion (2021)As o ...
and
Ford Motor Company
Ford Motor Company (commonly known as Ford) is an American multinational automobile manufacturer headquartered in Dearborn, Michigan, United States. It was founded by Henry Ford and incorporated on June 16, 1903. The company sells automobi ...
found enough resources to support global demand until 2100, including the lithium required for the potential widespread transportation use. The study estimated global reserves at 39 million tons, and total demand for lithium during the 90-year period annualized at 12–20 million tons, depending on the scenarios regarding economic growth and recycling rates.
In 2014, ''The Financialist'' stated that demand for lithium was growing at more than 12% a year. According to Credit Suisse, this rate exceeded projected availability by 25%. The publication compared the 2014 lithium situation with oil, whereby "higher oil prices spurred investment in expensive deepwater and oil sands production techniques"; that is, the price of lithium would continue to rise until more expensive production methods that could boost total output would receive the attention of investors.
On 16 July 2018 2.5 million tonnes of high-grade lithium resources and 124 million pounds of uranium resources were found in the Falchani hard rock deposit in the region Puno, Peru.
In 2020, Australia granted Major Project Status (MPS) to the
Finniss Lithium Project
The Finnis Lithium Project is a lithium mine being developed near Darwin, Northern Territory, Darwin, Northern Territory, Australia. The project is being developed by Core Lithium.
The ore body was discovered in 2016, feasibility work was done ...
for a strategically important lithium deposit: an estimated 3.45 million tonnes (Mt) of mineral resource at 1.4 percent
lithium oxide
Lithium oxide ( O) or lithia is an inorganic chemical compound. It is a white solid. Although not specifically important, many materials are assessed on the basis of their Li2O content. For example, the Li2O content of the principal lithium miner ...
.
[CORE Lithium : Finnis Lithium]
retrieved 13 October 2022 Operational mining began in 2022.
In 2019, world production of lithium from spodumene was around 80,000t per annum, primarily from the
Greenbushes pegmatite and from some
Chinese
Chinese can refer to:
* Something related to China
* Chinese people, people of Chinese nationality, citizenship, and/or ethnicity
**''Zhonghua minzu'', the supra-ethnic concept of the Chinese nation
** List of ethnic groups in China, people of ...
and
Chile
Chile, officially the Republic of Chile, is a country in the western part of South America. It is the southernmost country in the world, and the closest to Antarctica, occupying a long and narrow strip of land between the Andes to the east a ...
an sources. The Talison mine in Greenbushes is reported to be the largest and to have the highest grade of ore at 2.4% Li
2O (2012 figures).
Oceans are estimated to contain 230 billion tons of lithium, but the concentration is 0.1-0.2ppm, making it more expensive to isolate with 2020 technology than from land based brine and rock.
Sources
Another potential source of lithium was identified as the leachates of
geothermal wells, which are carried to the surface.
[Parker, Ann]
Mining Geothermal Resources
. Lawrence Livermore National Laboratory Recovery of this type of lithium has been demonstrated in the field; the lithium is separated by simple filtration.
[Patel, P. (16 November 2011]
Startup to Capture Lithium from Geothermal Plants
technologyreview.com Reserves are more limited than those of brine reservoirs and hard rock.
Pricing
![Lithium prices](https://upload.wikimedia.org/wikipedia/commons/6/6f/Lithium_prices.webp)
In 1998, the price of lithium metal was about (or US$43/
lb).
After the
2007 financial crisis
7 (seven) is the natural number following 6 and preceding 8. It is the only prime number preceding a cube.
As an early prime number in the series of positive integers, the number seven has greatly symbolic associations in religion, mythology, ...
, major suppliers, such as
Sociedad Química y Minera
Sociedad Química y Minera de Chile (SQM) is a Chilean chemical company and a supplier of plant nutrients, iodine, lithium and industrial chemicals. It is the world’s biggest lithium producer.
SQM's natural resources and its main production f ...
(SQM), dropped
lithium carbonate pricing by 20%. Prices rose in 2012. A 2012
Business Week article outlined an
oligopoly in the lithium space: "SQM, controlled by billionaire
Julio Ponce, is the second-largest, followed by
Rockwood, which is backed by
Henry Kravis’s KKR & Co., and Philadelphia-based FMC", with
Talison mentioned as the biggest producer.
Global consumption may jump to 300,000 metric tons a year by 2020 from about 150,000 tons in 2012, to match the demand for lithium batteries that has been growing at about 25% a year, outpacing the 4% to 5% overall gain in lithium production.
The price information service ISE - Institute of Rare Earths Elements and Strategic Metals - gives for various lithium substances in the average of the last six months (March to August 2022) the following kilo prices stable in the course: Lithium Carbonate, purity 99.5%min, from various producers between 63 and 72 EUR/kg. Lithium Hydroxide Monohydrate LiOH 56.5%min, China, at 66 to 72 EUR/kg; Delivered South Korea - 73 EUR/kg. Lithium Metal 99.9%min, Delivered China - 42 EUR/kg.
Extraction
Lithium and its compounds were historically isolated and extracted from hard rock but by the 1990s
mineral springs
Mineral springs are naturally occurring springs that produces hard water, water that contains dissolved minerals. Salts, sulfur compounds, and gases are among the substances that can be dissolved in the spring water during its passage under ...
,
brine pools, and brine deposits had become the dominant source. Most of these were in Chile, Argentina and Bolivia.
Large lithium-clay deposits under development in the McDermitt caldera (Nevada, United States) require concentrated sulfuric acid to leach lithium from the clay ore.
By early 2021, much of the lithium mined globally comes from either "
spodumene
Spodumene is a pyroxene mineral consisting of lithium aluminium inosilicate, Li Al( Si O3)2, and is a source of lithium. It occurs as colorless to yellowish, purplish, or lilac kunzite (see below), yellowish-green or emerald-green hiddenite, pr ...
, the mineral contained in hard rocks found in places such as Australia and North Carolina"
or from the salty brine pumped directly out of the ground, as it is in locations in Chile.
In Chile's
Salar de Atacama
Salar de Atacama is the largest salt flat in Chile. It is located south of San Pedro de Atacama, is surrounded by mountains, and has no drainage outlets. In the east it is enclosed by the main chain of the Andes, while to the west lies a secondar ...
, the lithium concentration in the brine is raised by solar evaporation in a system of ponds.
[ The enrichment by evaporation process may require up to one-and-a-half years, when the brine reaches a lithium content of 6%.][ The final processing in this example is done near the city of ]Antofagasta
Antofagasta () is a port city in northern Chile, about north of Santiago. It is the capital of Antofagasta Province and Antofagasta Region. According to the 2015 census, the city has a population of 402,669.
After the Spanish American wars ...
on the coast where pure lithium carbonate, lithium hydroxide
Lithium hydroxide is an inorganic compound with the formula LiOH. It can exist as anhydrous or hydrated, and both forms are white hygroscopic solids. They are soluble in water and slightly soluble in ethanol. Both are available commercially. While ...
, and lithium chloride
Lithium chloride is a chemical compound with the formula Li Cl. The salt is a typical ionic compound (with certain covalent characteristics), although the small size of the Li+ ion gives rise to properties not seen for other alkali metal chlorid ...
are produced from the brine.[
Low- cobalt cathodes for lithium batteries are expected to require ]lithium hydroxide
Lithium hydroxide is an inorganic compound with the formula LiOH. It can exist as anhydrous or hydrated, and both forms are white hygroscopic solids. They are soluble in water and slightly soluble in ethanol. Both are available commercially. While ...
rather than lithium carbonate as a feedstock, and this trend favors rock as a source.
The use of electrodialysis
Electrodialysis (ED) is used to transport salt ions from one solution through ion-exchange membranes to another solution under the influence of an applied electric potential difference. This is done in a configuration called an electrodialysis ...
and electrochemical intercalation has been proposed to extract lithium compounds from seawater (which contains lithium at 0.2 parts per million
In science and engineering, the parts-per notation is a set of pseudo-units to describe small values of miscellaneous dimensionless quantities, e.g. mole fraction or mass fraction. Since these fractions are quantity-per-quantity measures, th ...
), but it is not yet commercially viable.
Environmental issues
The manufacturing processes of lithium, including the solvent and mining waste
In mining, tailings are the materials left over after the process of separating the valuable fraction from the uneconomic fraction (gangue) of an ore. Tailings are different to overburden, which is the waste rock or other material that overli ...
, presents significant environmental and health hazards.
Lithium extraction can be fatal to aquatic life due to water pollution
Water pollution (or aquatic pollution) is the contamination of water bodies, usually as a result of human activities, so that it negatively affects its uses. Water bodies include lakes, rivers, oceans, aquifers, reservoirs and groundwater. ...
. It is known to cause surface water contamination, drinking water contamination, respiratory problems, ecosystem degradation and landscape damage. It also leads to unsustainable water consumption in arid regions (1.9 million liters per ton of lithium). Massive byproduct generation of lithium extraction also presents unsolved problems, such as large amounts of magnesium
Magnesium is a chemical element with the symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 of the periodic ta ...
and lime
Lime commonly refers to:
* Lime (fruit), a green citrus fruit
* Lime (material), inorganic materials containing calcium, usually calcium oxide or calcium hydroxide
* Lime (color), a color between yellow and green
Lime may also refer to:
Botany ...
waste.
In the United States, there is active competition between environmentally catastrophic open-pit mining
Open-pit mining, also known as open-cast or open-cut mining and in larger contexts mega-mining, is a surface mining technique of extracting rock or minerals from the earth from an open-air pit, sometimes known as a borrow.
This form of mini ...
, mountaintop removal mining
Mountaintop removal mining (MTR), also known as mountaintop mining (MTM), is a form of surface mining at the summit or summit ridge of a mountain. Coal seams are extracted from a mountain by removing the land, or overburden, above the seams. Thi ...
and less damaging brine extraction mining in an effort to drastically expand domestic lithium mining capacity. Environmental concerns include wildlife habitat degradation, potable water pollution including arsenic
Arsenic is a chemical element with the symbol As and atomic number 33. Arsenic occurs in many minerals, usually in combination with sulfur and metals, but also as a pure elemental crystal. Arsenic is a metalloid. It has various allotropes, ...
and antimony
Antimony is a chemical element with the symbol Sb (from la, stibium) and atomic number 51. A lustrous gray metalloid, it is found in nature mainly as the sulfide mineral stibnite (Sb2S3). Antimony compounds have been known since ancient t ...
contamination, unsustainable water table
The water table is the upper surface of the zone of saturation. The zone of saturation is where the pores and fractures of the ground are saturated with water. It can also be simply explained as the depth below which the ground is saturated.
T ...
reduction, and massive mining waste
In mining, tailings are the materials left over after the process of separating the valuable fraction from the uneconomic fraction (gangue) of an ore. Tailings are different to overburden, which is the waste rock or other material that overli ...
, including radioactive uranium
Uranium is a chemical element with the symbol U and atomic number 92. It is a silvery-grey metal in the actinide series of the periodic table. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. Uranium is weak ...
byproduct and sulfuric acid discharge.
Human rights issues
A study of relationships between lithium extraction companies and indigenous peoples in Argentina indicated that the state may not have protected indigenous peoples' right to free prior and informed consent, and that extraction companies generally controlled community access to information and set the terms for discussion of the projects and benefit sharing.
Development of the Thacker Pass lithium mine
The Thacker Pass Lithium Mine is a proposed lithium clay mining development project in Humboldt County, Nevada which is the largest known lithium deposit in the US, and one of the largest in the world. There has been significant exploration of ...
in Nevada, United States, has met with protests and lawsuits from several indigenous tribes who have said they were not provided free prior and informed consent and that the project threatens cultural and sacred sites. They have also expressed concerns that development of the project will create risks to indigenous women, because resource extraction is linked to missing and murdered indigenous women
Missing and Murdered Indigenous Women (MMIW) is an epidemic of violence against Indigenous women in Canada, the United States, and Latin America; notably those in the FNIM (First Nations in Canada, First Nations, Inuit, Métis) and Native Amer ...
. Protestors have been occupying the site of the proposed mine since January, 2021.
Applications
Batteries
In 2021, most lithium is used to make lithium-ion batteries for electric cars and mobile device
A mobile device (or handheld computer) is a computer small enough to hold and operate in the hand. Mobile devices typically have a flat LCD or OLED screen, a touchscreen interface, and digital or physical buttons. They may also have a physica ...
s.
Ceramics and glass
Lithium oxide is widely used as a flux for processing silica
Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is ...
, reducing the melting point
The melting point (or, rarely, liquefaction point) of a substance is the temperature at which it changes state from solid to liquid. At the melting point the solid and liquid phase exist in equilibrium. The melting point of a substance depen ...
and viscosity
The viscosity of a fluid is a measure of its resistance to deformation at a given rate. For liquids, it corresponds to the informal concept of "thickness": for example, syrup has a higher viscosity than water.
Viscosity quantifies the inte ...
of the material and leading to glazes with improved physical properties including low coefficients of thermal expansion. Worldwide, this is one of the largest use for lithium compounds. Glazes containing lithium oxides are used for ovenware. Lithium carbonate (Li2CO3) is generally used in this application because it converts to the oxide upon heating.
Electrical and electronic
Late in the 20th century, lithium became an important component of battery electrolytes and electrodes, because of its high electrode potential
In electrochemistry, electrode potential is the electromotive force of a galvanic cell built from a standard reference electrode and another electrode to be characterized. By convention, the reference electrode is the standard hydrogen electrode ( ...
. Because of its low atomic mass
The atomic mass (''m''a or ''m'') is the mass of an atom. Although the SI unit of mass is the kilogram (symbol: kg), atomic mass is often expressed in the non-SI unit dalton (symbol: Da) – equivalently, unified atomic mass unit (u). 1&nb ...
, it has a high charge- and power-to-weight ratio. A typical lithium-ion battery
A lithium-ion or Li-ion battery is a type of rechargeable battery which uses the reversible reduction of lithium ions to store energy. It is the predominant battery type used in portable consumer electronics and electric vehicles. It also s ...
can generate approximately 3 volt
The volt (symbol: V) is the unit of electric potential, electric potential difference (voltage), and electromotive force in the International System of Units (SI). It is named after the Italian physicist Alessandro Volta (1745–1827).
Defin ...
s per cell, compared with 2.1 volts for lead-acid and 1.5 volts for zinc-carbon. Lithium-ion batteries, which are rechargeable and have a high energy density, differ from lithium metal batteries, which are disposable
A disposable (also called disposable product) is a product designed for a single use after which it is recycled or is disposed as solid waste. The term is also sometimes used for products that may last several months (e.g. disposable air filte ...
( primary) batteries with lithium or its compounds as the anode
An anode is an electrode of a polarized electrical device through which conventional current enters the device. This contrasts with a cathode, an electrode of the device through which conventional current leaves the device. A common mnemonic ...
. Other rechargeable batteries that use lithium include the lithium-ion polymer battery
A lithium polymer battery, or more correctly lithium-ion polymer battery (abbreviated as LiPo, LIP, Li-poly, lithium-poly and others), is a rechargeable battery of lithium-ion technology using a polymer electrolyte instead of a liquid electrolyt ...
, lithium iron phosphate battery
The lithium iron phosphate battery (LFP (lithium ferro-phosphate), or Li-IP) is a type of lithium-ion battery using lithium iron phosphate () as the cathode material, and a graphitic carbon electrode with a metallic backing as the anode.
Beca ...
, and the nanowire battery
A nanowire battery uses nanowires to increase the surface area of one or both of its electrodes. Some designs (silicon, germanium and transition metal oxides), variations of the lithium-ion battery have been announced, although none are commerciall ...
.
Over the years opinions have been differing about potential growth. A 2008 study concluded that "realistically achievable lithium carbonate production would be sufficient for only a small fraction of future PHEV
A plug-in hybrid electric vehicle (PHEV) is a hybrid electric vehicle whose battery pack can be recharged by plugging a charging cable into an external electric power source, in addition to internally by its on-board internal combustion engin ...
and EV global market requirements", that "demand from the portable electronics sector will absorb much of the planned production increases in the next decade", and that "mass production of lithium carbonate is not environmentally sound, it will cause irreparable ecological damage to ecosystems that should be protected and that LiIon propulsion is incompatible with the notion of the 'Green Car'".
Lubricating greases
The third most common use of lithium is in greases. Lithium hydroxide is a strong base and, when heated with a fat, produces a soap made of lithium stearate
Lithium stearate is a chemical compound with the formula LiO2C(CH2)16CH3. It is formally classified as a soap (a salt of a fatty acid). Lithium stearate is a white soft solid, prepared by the reaction of lithium hydroxide and stearic acid.
Lithiu ...
. Lithium soap has the ability to thicken oils, and it is used to manufacture all-purpose, high-temperature lubricating greases.
Metallurgy
Lithium (e.g. as lithium carbonate) is used as an additive to continuous casting
Continuous casting, also called strand casting, is the process whereby molten metal is solidified into a "semifinished" billet, bloom, or slab for subsequent rolling in the finishing mills. Prior to the introduction of continuous casting in the ...
mould flux slags where it increases fluidity, a use which accounts for 5% of global lithium use (2011). Lithium compounds are also used as additives (fluxes) to foundry sand Molding sand, also known as foundry sand, is a sand that when moistened and compressed or oiled or heated tends to pack well and hold its shape. It is used in the process of sand casting for preparing the mold cavity.
Green sand
Green sand is an a ...
for iron casting to reduce veining.
Lithium (as lithium fluoride
Lithium fluoride is an inorganic compound with the chemical formula LiF. It is a colorless solid, that transitions to white with decreasing crystal size. Although odorless, lithium fluoride has a bitter-saline taste. Its structure is analogous to ...
) is used as an additive to aluminium smelters (Hall–Héroult process
The Hall–Héroult process is the major industrial process for smelting aluminium. It involves dissolving aluminium oxide (alumina) (obtained most often from bauxite, aluminium's chief ore, through the Bayer process) in molten cryolite, and el ...
), reducing melting temperature and increasing electrical resistance, a use which accounts for 3% of production (2011).
When used as a flux for welding
Welding is a fabrication process that joins materials, usually metals or thermoplastics, by using high heat to melt the parts together and allowing them to cool, causing fusion. Welding is distinct from lower temperature techniques such as bra ...
or soldering
Soldering (; ) is a process in which two or more items are joined by melting and putting a filler metal (solder) into the joint, the filler metal having a lower melting point than the adjoining metal. Unlike welding, soldering does not involv ...
, metallic lithium promotes the fusing of metals during the process and eliminates the forming of oxides by absorbing impurities. Alloy
An alloy is a mixture of chemical elements of which at least one is a metal. Unlike chemical compounds with metallic bases, an alloy will retain all the properties of a metal in the resulting material, such as electrical conductivity, ductilit ...
s of the metal with aluminium, cadmium
Cadmium is a chemical element with the symbol Cd and atomic number 48. This soft, silvery-white metal is chemically similar to the two other stable metals in group 12, zinc and mercury. Like zinc, it demonstrates oxidation state +2 in most of ...
, copper and manganese
Manganese is a chemical element with the symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese is a transition metal with a multifaceted array of industrial alloy use ...
are used to make high-performance, low density aircraft parts (see also Lithium-aluminium alloys).
Silicon nano-welding
Lithium has been found effective in assisting the perfection of silicon nano-welds in electronic components for electric batteries and other devices.
Pyrotechnics
Lithium compounds are used as pyrotechnic colorant
A pyrotechnic colorant is a chemical compound which causes a flame to burn with a particular color. These are used to create the colors in pyrotechnic compositions like fireworks and colored fires. The color-producing species are usually creat ...
s and oxidizers in red fireworks
Fireworks are a class of low explosive pyrotechnic devices used for aesthetic and entertainment purposes. They are most commonly used in fireworks displays (also called a fireworks show or pyrotechnics), combining a large number of devices ...
and flares.
Air purification
Lithium chloride
Lithium chloride is a chemical compound with the formula Li Cl. The salt is a typical ionic compound (with certain covalent characteristics), although the small size of the Li+ ion gives rise to properties not seen for other alkali metal chlorid ...
and lithium bromide
Lithium bromide (LiBr) is a chemical compound of lithium and bromine. Its extreme hygroscopic character makes LiBr useful as a desiccant in certain air conditioning systems.Wietelmann, Ulrich and Bauer, Richard J. (2005) "Lithium and Lithium Compo ...
are hygroscopic
Hygroscopy is the phenomenon of attracting and holding water molecules via either absorption or adsorption from the surrounding environment, which is usually at normal or room temperature. If water molecules become suspended among the substan ...
and are used as desiccants for gas streams. Lithium hydroxide and lithium peroxide
Lithium peroxide is the inorganic compound with the formula Li2 O2. It is a white, nonhygroscopic solid. Because of its high oxygen:mass and oxygen:volume ratios, the solid has been used to remove CO2 from the atmosphere in spacecraft.
Preparat ...
are the salts most used in confined areas, such as aboard spacecraft
A spacecraft is a vehicle or machine designed to fly in outer space. A type of artificial satellite, spacecraft are used for a variety of purposes, including communications, Earth observation, meteorology, navigation, space colonization, p ...
and submarines, for carbon dioxide removal and air purification. Lithium hydroxide absorbs carbon dioxide
Carbon dioxide ( chemical formula ) is a chemical compound made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in the gas state at room temperature. In the air, carbon dioxide is trans ...
from the air by forming lithium carbonate, and is preferred over other alkaline hydroxides for its low weight.
Lithium peroxide (Li2O2) in presence of moisture not only reacts with carbon dioxide to form lithium carbonate, but also releases oxygen. The reaction is as follows:
:2 Li2O2 + 2 CO2 → 2 Li2CO3 + O2.
Some of the aforementioned compounds, as well as lithium perchlorate
Lithium perchlorate is the inorganic compound with the formula LiClO4. This white or colourless crystalline salt is noteworthy for its high solubility in many solvents. It exists both in anhydrous form and as a trihydrate.
Applications Inorga ...
, are used in oxygen candles that supply submarines with oxygen
Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as ...
. These can also include small amounts of boron, magnesium
Magnesium is a chemical element with the symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 of the periodic ta ...
, aluminum
Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. It ha ...
, silicon
Silicon is a chemical element with the symbol Si and atomic number 14. It is a hard, brittle crystalline solid with a blue-grey metallic luster, and is a tetravalent metalloid and semiconductor. It is a member of group 14 in the periodic ta ...
, titanium
Titanium is a chemical element with the Symbol (chemistry), symbol Ti and atomic number 22. Found in nature only as an oxide, it can be reduced to produce a lustrous transition metal with a silver color, low density, and high strength, resista ...
, manganese
Manganese is a chemical element with the symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese is a transition metal with a multifaceted array of industrial alloy use ...
, and iron
Iron () is a chemical element with Symbol (chemistry), symbol Fe (from la, Wikt:ferrum, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 element, group 8 of the periodic table. It is, Abundanc ...
.
Optics
Lithium fluoride
Lithium fluoride is an inorganic compound with the chemical formula LiF. It is a colorless solid, that transitions to white with decreasing crystal size. Although odorless, lithium fluoride has a bitter-saline taste. Its structure is analogous to ...
, artificially grown as crystal
A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macro ...
, is clear and transparent and often used in specialist optics for IR, UV and VUV (vacuum UV
Ultraviolet (UV) is a form of electromagnetic radiation with wavelength from 10 nm (with a corresponding frequency around 30 PHz) to 400 nm (750 THz), shorter than that of visible light, but longer than X-rays. UV radiation i ...
) applications. It has one of the lowest refractive index
In optics, the refractive index (or refraction index) of an optical medium is a dimensionless number that gives the indication of the light bending ability of that medium.
The refractive index determines how much the path of light is bent, or ...
es and the furthest transmission range in the deep UV of most common materials. Finely divided lithium fluoride powder has been used for thermoluminescent radiation dosimetry (TLD): when a sample of such is exposed to radiation, it accumulates crystal defect
A crystallographic defect is an interruption of the regular patterns of arrangement of atoms or molecules in crystalline solids. The positions and orientations of particles, which are repeating at fixed distances determined by the unit cell para ...
s which, when heated, resolve via a release of bluish light whose intensity is proportional to the absorbed dose, thus allowing this to be quantified. Lithium fluoride is sometimes used in focal lenses of telescope
A telescope is a device used to observe distant objects by their emission, absorption, or reflection of electromagnetic radiation. Originally meaning only an optical instrument using lenses, curved mirrors, or a combination of both to observ ...
s.
The high non-linearity of lithium niobate
Lithium niobate () is a non-naturally-occurring salt consisting of niobium, lithium, and oxygen. Its single crystals are an important material for optical waveguides, mobile phones, piezoelectric sensors, optical modulators and various other linea ...
also makes it useful in non-linear optics applications. It is used extensively in telecommunication products such as mobile phones and optical modulator
An optical modulator is a device which is used to modulate a beam of light. The beam may be carried over free space, or propagated through an optical waveguide (optical fibre). Depending on the parameter of a light beam which is manipulated, modul ...
s, for such components as resonant crystals. Lithium applications are used in more than 60% of mobile phones.
Organic and polymer chemistry
Organolithium compounds are widely used in the production of polymer and fine-chemicals. In the polymer industry, which is the dominant consumer of these reagents, alkyl lithium compounds are catalyst
Catalysis () is the process of increasing the rate of a chemical reaction by adding a substance known as a catalyst (). Catalysts are not consumed in the reaction and remain unchanged after it. If the reaction is rapid and the catalyst recyc ...
s/ initiators. in anionic polymerization
In polymer chemistry, anionic addition polymerization is a form of chain-growth polymerization or addition polymerization that involves the polymerization of monomers initiated with anions. The type of reaction has many manifestations, but tradi ...
of unfunctionalized olefins. For the production of fine chemicals, organolithium compounds function as strong bases and as reagents for the formation of carbon-carbon bonds. Organolithium compounds are prepared from lithium metal and alkyl halides.
Many other lithium compounds are used as reagents to prepare organic compounds. Some popular compounds include lithium aluminium hydride (LiAlH4), lithium triethylborohydride
Lithium triethylborohydride is the organoboron compound with the formula Li Et3 BH. Commonly referred to as LiTEBH or Superhydride, it is a powerful reducing agent used in organometallic and organic chemistry. It is a colorless or white liquid bu ...
, n-butyllithium
''n''-Butyllithium C4H9Li (abbreviated ''n''-BuLi) is an organolithium reagent. It is widely used as a polymerization initiator in the production of elastomers such as polybutadiene or styrene-butadiene-styrene (SBS). Also, it is broadly emp ...
and tert-butyllithium
''tert''-Butyllithium is a chemical compound with the formula (CH3)3CLi. As an organolithium compound, it has applications in organic synthesis since it is a strong base, capable of deprotonating many carbon molecules, including benzene. ''tert ...
.
Military
Metallic lithium and its complex hydride
In chemistry, a hydride is formally the anion of hydrogen( H−). The term is applied loosely. At one extreme, all compounds containing covalently bound H atoms are called hydrides: water (H2O) is a hydride of oxygen, ammonia is a hydride ...
s, such as Li 4">lH4 are used as high-energy additives to rocket propellants. Lithium aluminum hydride can also be used by itself as a solid fuel.
The Mark 50 torpedo
The Mark 50 torpedo is a U.S. Navy advanced lightweight torpedo for use against fast, deep-diving submarines. The Mk 50 can be launched from all anti-submarine aircraft and from torpedo tubes aboard surface combatant ships. The Mk 50 was intended ...
stored chemical energy propulsion system (SCEPS) uses a small tank of sulfur hexafluoride, which is sprayed over a block of solid lithium. The reaction generates heat, creating steam to propel the torpedo in a closed Rankine cycle
The Rankine cycle is an idealized thermodynamic cycle describing the process by which certain heat engines, such as steam turbines or reciprocating steam engines, allow mechanical work to be extracted from a fluid as it moves between a heat sourc ...
.
Lithium hydride
Lithium hydride is an inorganic compound with the formula Li H. This alkali metal hydride is a colorless solid, although commercial samples are grey. Characteristic of a salt-like (ionic) hydride, it has a high melting point, and it is not solub ...
containing lithium-6 is used in thermonuclear weapon
A thermonuclear weapon, fusion weapon or hydrogen bomb (H bomb) is a second-generation nuclear weapon design. Its greater sophistication affords it vastly greater destructive power than first-generation nuclear bombs, a more compact size, a low ...
s, where it serves as fuel for the fusion stage of the bomb.
Nuclear
Lithium-6 is valued as a source material for tritium
Tritium ( or , ) or hydrogen-3 (symbol T or H) is a rare and radioactive isotope of hydrogen with half-life about 12 years. The nucleus of tritium (t, sometimes called a ''triton'') contains one proton and two neutrons, whereas the nucleus of ...
production and as a neutron absorber
In applications such as nuclear reactors, a neutron poison (also called a neutron absorber or a nuclear poison) is a substance with a large neutron absorption cross-section. In such applications, absorbing neutrons is normally an undesirable eff ...
in nuclear fusion
Nuclear fusion is a reaction in which two or more atomic nuclei are combined to form one or more different atomic nuclei and subatomic particles ( neutrons or protons). The difference in mass between the reactants and products is manife ...
. Natural lithium contains about 7.5% lithium-6 from which large amounts of lithium-6 have been produced by isotope separation
Isotope separation is the process of concentrating specific isotopes of a chemical element by removing other isotopes. The use of the nuclides produced is varied. The largest variety is used in research (e.g. in chemistry where atoms of "marker" n ...
for use in nuclear weapon
A nuclear weapon is an explosive device that derives its destructive force from nuclear reactions, either fission (fission bomb) or a combination of fission and fusion reactions ( thermonuclear bomb), producing a nuclear explosion. Both bom ...
s. Lithium-7 gained interest for use in nuclear reactor
A nuclear reactor is a device used to initiate and control a fission nuclear chain reaction or nuclear fusion reactions. Nuclear reactors are used at nuclear power plants for electricity generation and in nuclear marine propulsion. Heat fr ...
coolant
A coolant is a substance, typically liquid, that is used to reduce or regulate the temperature of a system. An ideal coolant has high thermal capacity, low viscosity, is low-cost, non-toxic, chemically inert and neither causes nor promotes corrosi ...
s.
Lithium deuteride
Lithium hydride is an inorganic compound with the formula Li H. This alkali metal hydride is a colorless solid, although commercial samples are grey. Characteristic of a salt-like (ionic) hydride, it has a high melting point, and it is not sol ...
was the fusion fuel of choice in early versions of the hydrogen bomb. When bombarded by neutron
The neutron is a subatomic particle, symbol or , which has a neutral (not positive or negative) charge, and a mass slightly greater than that of a proton. Protons and neutrons constitute the nuclei of atoms. Since protons and neutrons beh ...
s, both 6Li and 7Li produce tritium
Tritium ( or , ) or hydrogen-3 (symbol T or H) is a rare and radioactive isotope of hydrogen with half-life about 12 years. The nucleus of tritium (t, sometimes called a ''triton'') contains one proton and two neutrons, whereas the nucleus of ...
— this reaction, which was not fully understood when hydrogen bombs
A thermonuclear weapon, fusion weapon or hydrogen bomb (H bomb) is a second-generation nuclear weapon design. Its greater sophistication affords it vastly greater destructive power than first-generation nuclear bombs, a more compact size, a lowe ...
were first tested, was responsible for the runaway yield of the Castle Bravo
Castle Bravo was the first in a series of high-yield thermonuclear weapon design tests conducted by the United States at Bikini Atoll, Marshall Islands, as part of '' Operation Castle''. Detonated on March 1, 1954, the device was the most powerful ...
nuclear test
Nuclear weapons tests are experiments carried out to determine nuclear weapons' effectiveness, Nuclear weapon yield, yield, and explosive capability. Testing nuclear weapons offers practical information about how the weapons function, how detona ...
. Tritium fuses with deuterium
Deuterium (or hydrogen-2, symbol or deuterium, also known as heavy hydrogen) is one of two stable isotopes of hydrogen (the other being protium, or hydrogen-1). The nucleus of a deuterium atom, called a deuteron, contains one proton and one ...
in a fusion
Fusion, or synthesis, is the process of combining two or more distinct entities into a new whole.
Fusion may also refer to:
Science and technology Physics
*Nuclear fusion, multiple atomic nuclei combining to form one or more different atomic nucl ...
reaction that is relatively easy to achieve. Although details remain secret, lithium-6 deuteride apparently still plays a role in modern nuclear weapons as a fusion material.
Lithium fluoride
Lithium fluoride is an inorganic compound with the chemical formula LiF. It is a colorless solid, that transitions to white with decreasing crystal size. Although odorless, lithium fluoride has a bitter-saline taste. Its structure is analogous to ...
, when highly enriched in the lithium-7 isotope, forms the basic constituent of the fluoride salt mixture LiF- BeF2 used in liquid fluoride nuclear reactors. Lithium fluoride is exceptionally chemically stable and LiF-BeF2 mixtures have low melting points. In addition, 7Li, Be, and F are among the few nuclides with low enough thermal neutron capture cross-sections not to poison the fission reactions inside a nuclear fission reactor.[Beryllium and fluorine occur only as one isotope, 9Be and 19F respectively. These two, together with 7Li, as well as 2H, 11B, 15N, 209Bi, and the stable isotopes of C, and O, are the only nuclides with low enough thermal neutron capture cross sections aside from ]actinide
The actinide () or actinoid () series encompasses the 15 metallic chemical elements with atomic numbers from 89 to 103, actinium through lawrencium. The actinide series derives its name from the first element in the series, actinium. The info ...
s to serve as major constituents of a molten salt breeder reactor fuel.
In conceptualized (hypothetical) nuclear fusion power
Fusion power is a proposed form of power generation that would generate electricity by using heat from nuclear fusion reactions. In a fusion process, two lighter atomic nuclei combine to form a heavier nucleus, while releasing energy. Devices de ...
plants, lithium will be used to produce tritium in magnetically confined reactors using deuterium
Deuterium (or hydrogen-2, symbol or deuterium, also known as heavy hydrogen) is one of two stable isotopes of hydrogen (the other being protium, or hydrogen-1). The nucleus of a deuterium atom, called a deuteron, contains one proton and one ...
and tritium
Tritium ( or , ) or hydrogen-3 (symbol T or H) is a rare and radioactive isotope of hydrogen with half-life about 12 years. The nucleus of tritium (t, sometimes called a ''triton'') contains one proton and two neutrons, whereas the nucleus of ...
as the fuel. Naturally occurring tritium is extremely rare, and must be synthetically produced by surrounding the reacting plasma with a 'blanket' containing lithium where neutrons from the deuterium-tritium reaction in the plasma will fission the lithium to produce more tritium:
:6Li + n → 4He + 3H.
Lithium is also used as a source for alpha particle
Alpha particles, also called alpha rays or alpha radiation, consist of two protons and two neutrons bound together into a particle identical to a helium-4 nucleus. They are generally produced in the process of alpha decay, but may also be pr ...
s, or helium
Helium (from el, ἥλιος, helios, lit=sun) is a chemical element with the symbol He and atomic number 2. It is a colorless, odorless, tasteless, non-toxic, inert, monatomic gas and the first in the noble gas group in the periodic table. ...
nuclei. When 7Li is bombarded by accelerated protons 8 Be is formed, which almost immediately undergoes fission to form two alpha particles. This feat, called "splitting the atom" at the time, was the first fully man-made nuclear reaction
In nuclear physics and nuclear chemistry, a nuclear reaction is a process in which two nuclei, or a nucleus and an external subatomic particle, collide to produce one or more new nuclides. Thus, a nuclear reaction must cause a transformatio ...
. It was produced by Cockroft and Walton Walton may refer to:
People
* Walton (given name)
* Walton (surname)
* Susana, Lady Walton (1926–2010), Argentine writer
Places
Canada
* Walton, Nova Scotia, a community
** Walton River (Nova Scotia)
*Walton, Ontario, a hamlet
United Kingdo ...
in 1932.
In 2013, the US Government Accountability Office said a shortage of lithium-7 critical to the operation of 65 out of 100 American nuclear reactors "places their ability to continue to provide electricity at some risk". Castle Bravo
Castle Bravo was the first in a series of high-yield thermonuclear weapon design tests conducted by the United States at Bikini Atoll, Marshall Islands, as part of '' Operation Castle''. Detonated on March 1, 1954, the device was the most powerful ...
first used lithium-7, in the ''Shrimp'', its first device, which weighed only 10 tons, and generated massive nuclear atmospheric contamination of Bikini Atoll
Bikini Atoll ( or ; Marshallese: , , meaning "coconut place"), sometimes known as Eschscholtz Atoll between the 1800s and 1946 is a coral reef in the Marshall Islands consisting of 23 islands surrounding a central lagoon. After the Seco ...
. This perhaps accounts for the decline of US nuclear infrastructure. The equipment needed to separate lithium-6 from lithium-7 is mostly a cold war leftover. The US shut down most of this machinery in 1963, when it had a huge surplus of separated lithium, mostly consumed during the twentieth century. The report said it would take five years and $10 million to $12 million to reestablish the ability to separate lithium-6 from lithium-7.
Reactors that use lithium-7 heat water under high pressure and transfer heat through heat exchangers that are prone to corrosion. The reactors use lithium to counteract the corrosive effects of boric acid
Boric acid, more specifically orthoboric acid, is a compound of boron, oxygen, and hydrogen with formula . It may also be called hydrogen borate or boracic acid. It is usually encountered as colorless crystals or a white powder, that dissolve ...
, which is added to the water to absorb excess neutrons.
Medicine
Lithium is useful in the treatment of bipolar disorder
Bipolar disorder, previously known as manic depression, is a mental disorder characterized by periods of depression and periods of abnormally elevated mood that last from days to weeks each. If the elevated mood is severe or associated with ...
. Lithium salts may also be helpful for related diagnoses, such as schizoaffective disorder
Schizoaffective disorder (SZA, SZD or SAD) is a mental disorder characterized by abnormal thought processes and an unstable mood. This diagnosis is made when the person has symptoms of both schizophrenia (usually psychosis) and a mood disorder: ...
and cyclic major depression
Major depressive disorder (MDD), also known as clinical depression, is a mental disorder characterized by at least two weeks of pervasive low mood, low self-esteem, and loss of interest or pleasure in normally enjoyable activities. Introdu ...
. The active part of these salts is the lithium ion Li+. Lithium may increase the risk of developing Ebstein's cardiac anomaly in infants born to women who take lithium during the first trimester of pregnancy.
A 2022 review indicated that lithium therapy during treatment of bipolar disorder does not affect body weight.
Precautions
Lithium metal is corrosive
A corrosive substance is one that will damage or destroy other substances with which it comes into contact by means of a chemical reaction.
Etymology
The word ''corrosive'' is derived from the Latin verb ''corrodere'', which means ''to gnaw'', ...
and requires special handling to avoid skin contact. Breathing lithium dust or lithium compounds (which are often alkaline) initially irritate the nose
A nose is a protuberance in vertebrates that houses the nostrils, or nares, which receive and expel air for respiration alongside the mouth. Behind the nose are the olfactory mucosa and the sinuses. Behind the nasal cavity, air next passes ...
and throat, while higher exposure can cause a buildup of fluid in the lungs, leading to pulmonary edema
Pulmonary edema, also known as pulmonary congestion, is excessive liquid accumulation in the tissue and air spaces (usually alveoli) of the lungs. It leads to impaired gas exchange and may cause hypoxemia and respiratory failure. It is due t ...
. The metal itself is a handling hazard because contact with moisture produces the caustic
Caustic most commonly refers to:
* Causticity, a property of various corrosive substances
** Sodium hydroxide, sometimes called ''caustic soda''
** Potassium hydroxide, sometimes called ''caustic potash''
** Calcium oxide, sometimes called ''caus ...
lithium hydroxide
Lithium hydroxide is an inorganic compound with the formula LiOH. It can exist as anhydrous or hydrated, and both forms are white hygroscopic solids. They are soluble in water and slightly soluble in ethanol. Both are available commercially. While ...
. Lithium is safely stored in non-reactive compounds such as naphtha
Naphtha ( or ) is a flammable liquid hydrocarbon mixture.
Mixtures labelled ''naphtha'' have been produced from natural gas condensates, petroleum distillates, and the distillation of coal tar and peat. In different industries and regions ' ...
.
See also
* Cosmological lithium problem
In astronomy, the lithium problem or lithium discrepancy refers to the discrepancy between the primordial abundance of lithium as inferred from observations of metal-poor (Population II) halo stars in our galaxy and the amount that should theoret ...
* Dilithium
Dilithium, Li2, is a strongly electrophilic, diatomic molecule comprising two lithium atoms covalently bonded together. Li2 is known in the gas phase.
It has a bond order of 1, an internuclear separation of 267.3 pm and a bond energy o ...
* Halo nucleus
In nuclear physics, an atomic nucleus is called a halo nucleus or is said to have a nuclear halo when it has a core nucleus surrounded by a "halo" of orbiting protons or neutrons, which makes the radius of the nucleus appreciably larger than that ...
* Isotopes of lithium
Naturally occurring lithium (3Li) is composed of two stable isotopes, lithium-6 and lithium-7, with the latter being far more abundant on Earth. Both of the natural isotopes have an unexpectedly low nuclear binding energy per nucleon ( for lit ...
* List of countries by lithium production
This is a list of countries by lithium
Lithium (from el, λίθος, lithos, lit=stone) is a chemical element with the symbol Li and atomic number 3. It is a soft, silvery-white alkali metal. Under standard conditions, it is the le ...
* Lithia water
Lithia water is defined as a type of mineral water characterized by the presence of lithium salts (such as the carbonate, chloride, or citrate of lithium). Natural lithia mineral spring waters are rare, and there are few commercially bottled lith ...
* Lithium–air battery
The lithium–air battery (Li–air) is a metal–air electrochemical cell or battery chemistry that uses oxidation of lithium at the anode and reduction of oxygen at the cathode to induce a current flow.
Pairing lithium and ambient oxygen ca ...
* Lithium burning
Lithium burning is a nucleosynthetic process in which lithium is depleted in a star. Lithium is generally present in brown dwarfs and not in older low-mass stars. Stars, which by definition must achieve the high temperature (2.5 × 106 K) necessa ...
* Lithium compounds (category)
* Lithium-ion battery
A lithium-ion or Li-ion battery is a type of rechargeable battery which uses the reversible reduction of lithium ions to store energy. It is the predominant battery type used in portable consumer electronics and electric vehicles. It also s ...
* Lithium Tokamak Experiment
The Lithium Tokamak Experiment (LTX), and its predecessor, the Current Drive Experiment-Upgrade (CDX-U), are devices dedicated to the study of liquid lithium as a plasma-facing component (PFC) at Princeton Plasma Physics Laboratory.
Benefits of ...
Notes
References
External links
McKinsey review of 2018
at ''The Periodic Table of Videos
''Periodic Videos'' (also known as ''The Periodic Table of Videos'') is a video project and YouTube channel on chemistry. It consists of a series of videos about chemical elements and the periodic table, with additional videos on other topics i ...
'' (University of Nottingham)
International Lithium Alliance
USGS: Lithium Statistics and Information
Lithium Supply & Markets 2009 IM Conference 2009 Sustainable lithium supplies through 2020 in the face of sustainable market growth
University of Southampton, Mountbatten Centre for International Studies, Nuclear History Working Paper No5.
Lithium preserves by Country at investingnews.com
{{Authority control
Chemical elements
Alkali metals
Reducing agents
Chemical elements with body-centered cubic structure