Kozeny–Carman Equation
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The Kozeny–Carman equation (or Carman–Kozeny equation or Kozeny equation) is a relation used in the field of fluid dynamics to calculate the
pressure drop Pressure drop is defined as the difference in total pressure between two points of a fluid carrying network. A pressure drop occurs when frictional forces, caused by the resistance to flow, act on a fluid as it flows through the tube. The main de ...
of a fluid flowing through a packed bed of solids. It is named after Josef Kozeny and Philip C. Carman. The equation is only valid for
creeping flow Stokes flow (named after George Gabriel Stokes), also named creeping flow or creeping motion,Kim, S. & Karrila, S. J. (2005) ''Microhydrodynamics: Principles and Selected Applications'', Dover. . is a type of fluid flow where advection, advec ...
, i.e. in the slowest limit of laminar flow. The equation was derived by Kozeny (1927) and Carman (1937, 1956) from a starting point of (a) modelling fluid flow in a packed bed as laminar fluid flow in a collection of curving passages/tubes crossing the packed bed and (b) Poiseuille's law describing laminar fluid flow in straight, circular section pipes.


Equation

The equation is given as: :\frac = - \frac\fracu_\mathrm where: *\Delta p is the pressure drop; *L is the total height of the bed; *u_\mathrm is the superficial or "empty-tower" velocity; *\mu is the
viscosity The viscosity of a fluid is a measure of its resistance to deformation at a given rate. For liquids, it corresponds to the informal concept of "thickness": for example, syrup has a higher viscosity than water. Viscosity quantifies the inte ...
of the fluid; *\epsilon is the
porosity Porosity or void fraction is a measure of the void (i.e. "empty") spaces in a material, and is a fraction of the volume of voids over the total volume, between 0 and 1, or as a percentage between 0% and 100%. Strictly speaking, some tests measur ...
of the bed; *\mathit_\mathrm is the
sphericity Sphericity is a measure of how closely the shape of an object resembles that of a perfect sphere. For example, the sphericity of the balls inside a ball bearing determines the quality of the bearing, such as the load it can bear or the speed a ...
of the particles in the packed bed; *D_\mathrm is the diameter of the volume equivalent spherical particle. This equation holds for flow through packed beds with particle Reynolds numbers up to approximately 1.0, after which point frequent shifting of flow channels in the bed causes considerable
kinetic energy In physics, the kinetic energy of an object is the energy that it possesses due to its motion. It is defined as the work needed to accelerate a body of a given mass from rest to its stated velocity. Having gained this energy during its acc ...
losses. This equation is a partial case of the
Darcy's law Darcy's law is an equation that describes the flow of a fluid through a porous medium. The law was formulated by Henry Darcy based on results of experiments on the flow of water through beds of sand, forming the basis of hydrogeology, a branch of ...
stating that "''flow is proportional to the pressure drop and inversely proportional to the fluid viscosity''". : v_\mathrm = - \frac \frac Combining these equations gives the final Kozeny equation for absolute (single phase) permeability : \kappa = \mathit_\mathrm^2 \frac *\epsilon is the
porosity Porosity or void fraction is a measure of the void (i.e. "empty") spaces in a material, and is a fraction of the volume of voids over the total volume, between 0 and 1, or as a percentage between 0% and 100%. Strictly speaking, some tests measur ...
of the bed (or core plug) raction*D_\mathrm is average diameter of sand grains *\kappa is absolute (i.e. single phase) permeability ^2*\mathit_\mathrm is the phericityof the particles in the packed bed = 1 for spherical particles The combined proportionality and unity factor a has typically average value of 0.8E6 /1.0135 from measuring many naturally occurring core plug samples, ranging from high to low clay content, but it may reach a value of 3.2E6 /1.0135 for clean sand. The denominator is included explicitly to remind us that permeability is defined using tmas pressure unit while reservoir engineering calculations and reservoir simulations typically use aras pressure unit.


History

The equation was firstRobert P. Chapuis and Michel Aubertin, "PREDICTING THE COEFFICIENT OF PERMEABILITY OF SOILS USING THE KOZENY-CARMAN EQUATION", Report EPM–RT–2003-03, Département des génies civil, géologique et des mines; École Polytechnique de Montréal, January 2003 https://publications.polymtl.ca/2605/1/EPM-RT-2003-03_Chapuis.pdf (accessed 2011-02-05) proposed by Kozeny (1927)J. Kozeny,
Ueber kapillare Leitung des Wassers im Boden
" Sitzungsber Akad. Wiss., Wien, 136(2a): 271-306, 1927.
and later modified by Carman (1937, 1956).P.C. Carman, "Fluid flow through granular beds." Transactions, Institution of Chemical Engineers, London, 15: 150-166, 1937.P.C. Carman, "Flow of gases through porous media." Butterworths, London, 1956. A similar equation was derived independently by Fair and Hatch in 1933. G.M. Fair, L.P. Hatch, Fundamental factors governing the streamline flow of water through sand, J. AWWA 25 (1933) 1551–1565. A comprehensive review of other equations has been published E. Erdim, Ö. Akgiray and İ. Demir, A revisit of pressure drop-flow rate correlations for packed beds of spheres, Powder Technology Volume 283, October 2015, Pages 488-504


See also

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Fractionating column A fractionating column or fractional column is an essential item used in the distillation of liquid mixtures to separate the mixture into its component parts, or fractions, based on the differences in volatilities. Fractionating columns are used in ...
*
Random close pack Random close packing (RCP) of spheres is an empirical parameter used to characterize the maximum volume fraction of solid objects obtained when they are packed randomly. For example, when a solid container is filled with grain, shaking the containe ...
*
Raschig ring Raschig rings are pieces of tube, approximately equal in length and diameter, used in large numbers as a packed bed within columns for distillations and other chemical engineering processes. They are usually ceramic, metal or glass and provide a la ...
*
Ergun equation The Ergun equation, derived by the Turkish chemical engineer Sabri Ergun in 1952, expresses the friction factor in a packed column as a function of the modified Reynolds number. Equation f_p = \frac +1.75 where f_p and Gr_p are defined as ...


References

{{DEFAULTSORT:Kozeny-Carman equation Equations of fluid dynamics Unit operations Porous media