toxic properties
Toxicity is the degree to which a chemical substance or a particular mixture of substances can damage an organism. Toxicity can refer to the effect on a whole organism, such as an animal, bacteria, bacterium, or plant, as well as the effect ...
of
chemical substance
A chemical substance is a form of matter having constant chemical composition and characteristic properties. Some references add that chemical substance cannot be separated into its constituent elements by physical separation methods, i.e., wi ...
s as
weapons
A weapon, arm or armament is any implement or device that can be used to deter, threaten, inflict physical damage, harm, or kill. Weapons are used to increase the efficacy and efficiency of activities such as hunting, crime, law enforcement, s ...
. This type of warfare is distinct from
nuclear warfare
Nuclear warfare, also known as atomic warfare, is a theoretical military conflict or prepared political strategy that deploys nuclear weaponry. Nuclear weapons are weapons of mass destruction; in contrast to conventional warfare, nuclear ...
,
biological warfare
Biological warfare, also known as germ warfare, is the use of biological toxins or infectious agents such as bacteria, viruses, insects, and fungi with the intent to kill, harm or incapacitate humans, animals or plants as an act of war. Bio ...
and
radiological warfare
Radiological warfare is any form of warfare involving deliberate radiation poisoning or contamination of an area with radiological sources.
Radiological weapons are normally classified as weapons of mass destruction (WMDs), although radiologic ...
, which together make up
CBRN
Chemical, biological, radiological and nuclear defence (CBRN defence) are protective measures taken in situations in which chemical, biological, radiological or nuclear warfare (including terrorism) hazards may be present. CBRN defence consi ...
, the military acronym for chemical, biological, radiological, and nuclear (warfare or weapons), all of which are considered "
weapons of mass destruction
A weapon of mass destruction (WMD) is a chemical, biological, radiological, nuclear, or any other weapon that can kill and bring significant harm to numerous individuals or cause great damage to artificial structures (e.g., buildings), natura ...
" (WMDs), a term that contrasts with
conventional weapon
The terms conventional weapons or conventional arms generally refer to weapons whose ability to damage comes from kinetic, incendiary, or explosive energy and exclude weapons of mass destruction (''e.g.'' nuclear, biological, radiological and c ...
s.
The use of chemical weapons is prohibited under
customary
Custom, customary, or consuetudinary may refer to:
Traditions, laws, and religion
* Convention (norm), a set of agreed, stipulated or generally accepted rules, norms, standards or criteria, often taking the form of a custom
* Norm (social), a r ...
international humanitarian law
International humanitarian law (IHL), also referred to as the laws of armed conflict, is the law that regulates the conduct of war (''jus in bello''). It is a branch of international law that seeks to limit the effects of armed conflict by prot ...
.
Definition
Chemical warfare is different from the use of
conventional weapon
The terms conventional weapons or conventional arms generally refer to weapons whose ability to damage comes from kinetic, incendiary, or explosive energy and exclude weapons of mass destruction (''e.g.'' nuclear, biological, radiological and c ...
s or
nuclear weapon
A nuclear weapon is an explosive device that derives its destructive force from nuclear reactions, either fission (fission bomb) or a combination of fission and fusion reactions ( thermonuclear bomb), producing a nuclear explosion. Both bom ...
s because the destructive effects of
chemical weapon
A chemical weapon (CW) is a specialized munition that uses chemicals formulated to inflict death or harm on humans. According to the Organisation for the Prohibition of Chemical Weapons (OPCW), this can be any chemical compound intended as a ...
s are not primarily due to any
explosive
An explosive (or explosive material) is a reactive substance that contains a great amount of potential energy that can produce an explosion if released suddenly, usually accompanied by the production of light, heat, sound, and pressure. An expl ...
force. The offensive use of living
organism
In biology, an organism () is any living system that functions as an individual entity. All organisms are composed of cells (cell theory). Organisms are classified by taxonomy into groups such as multicellular animals, plants, and ...
s (such as
anthrax
Anthrax is an infection caused by the bacterium ''Bacillus anthracis''. It can occur in four forms: skin, lungs, intestinal, and injection. Symptom onset occurs between one day and more than two months after the infection is contracted. The sk ...
) is considered
biological warfare
Biological warfare, also known as germ warfare, is the use of biological toxins or infectious agents such as bacteria, viruses, insects, and fungi with the intent to kill, harm or incapacitate humans, animals or plants as an act of war. Bio ...
rather than chemical warfare; however, the use of nonliving toxic products produced by living organisms (e.g.
toxin
A toxin is a naturally occurring organic poison produced by metabolic activities of living cells or organisms. Toxins occur especially as a protein or conjugated protein. The term toxin was first used by organic chemist Ludwig Brieger (1849– ...
s such as
botulinum toxin
Botulinum toxin, or botulinum neurotoxin (BoNT), is a neurotoxic protein produced by the bacterium ''Clostridium botulinum'' and related species. It prevents the release of the neurotransmitter acetylcholine from axon endings at the neuromusc ...
,
ricin
Ricin ( ) is a lectin (a carbohydrate-binding protein) and a highly potent toxin produced in the seeds of the castor oil plant, ''Ricinus communis''. The median lethal dose (LD50) of ricin for mice is around 22 micrograms per kilogram of body ...
, and
saxitoxin
Saxitoxin (STX) is a potent neurotoxin and the best-known paralytic shellfish toxin (PST). Ingestion of saxitoxin by humans, usually by consumption of shellfish contaminated by toxic algal blooms, is responsible for the illness known as paralyt ...
) ''is'' considered chemical warfare under the provisions of the
Chemical Weapons Convention
The Chemical Weapons Convention (CWC), officially the Convention on the Prohibition of the Development, Production, Stockpiling and Use of Chemical Weapons and on their Destruction, is an arms control treaty administered by the Organisation for ...
(CWC). Under this convention, any toxic chemical, regardless of its origin, is considered a chemical weapon unless it is used for purposes that are not prohibited (an important legal definition known as the General Purpose Criterion).
About 70 different chemicals have been used or stockpiled as chemical warfare agents during the 20th century. The entire class known as
Lethal Unitary Chemical Agents and Munitions
A chemical weapon (CW) is a specialized munition that uses chemicals formulated to inflict death or harm on humans. According to the Organisation for the Prohibition of Chemical Weapons (OPCW), this can be any chemical compound intended as ...
have been scheduled for elimination by the CWC.
Under the convention, chemicals that are toxic enough to be used as chemical weapons, or that may be used to manufacture such chemicals, are divided into three groups according to their purpose and treatment:
*
Schedule 1 Schedule 1 may refer to:
* Schedule I Controlled Substances within the US Controlled Substances Act
* Schedule I Controlled Drugs and Substances within the Canadian Controlled Drugs and Substances Act
* Schedule I Psychotropic Substances within t ...
– Have few, if any, legitimate uses. These may only be produced or used for research, medical, pharmaceutical or protective purposes (i.e. testing of chemical weapons sensors and protective clothing). Examples include
nerve agents
Nerve agents, sometimes also called nerve gases, are a class of organic chemicals that disrupt the mechanisms by which nerves transfer messages to organs. The disruption is caused by the blocking of acetylcholinesterase (AChE), an enzyme that ...
,
ricin
Ricin ( ) is a lectin (a carbohydrate-binding protein) and a highly potent toxin produced in the seeds of the castor oil plant, ''Ricinus communis''. The median lethal dose (LD50) of ricin for mice is around 22 micrograms per kilogram of body ...
,
lewisite
Lewisite (L) (A-243) is an organoarsenic compound. It was once manufactured in the U.S., Japan, Germany and the Soviet Union for use as a Chemical warfare, chemical weapon, acting as a vesicant (blister agent) and lung irritant. Although the substa ...
and
mustard gas
Mustard gas or sulfur mustard is a chemical compound belonging to a family of cytotoxic and blister agents known as mustard agents. The name ''mustard gas'' is technically incorrect: the substance, when dispersed, is often not actually a gas, b ...
. Any production over 100 g must be reported to the
OPCW
The Organisation for the Prohibition of Chemical Weapons (OPCW) is an intergovernmental organisation and the implementing body for the Chemical Weapons Convention (CWC), which entered into force on 29 April 1997. The OPCW, with its 193 member ...
and a country can have a stockpile of no more than one tonne of these chemicals.
* Schedule 2 – Have no large-scale industrial uses, but may have legitimate small-scale uses. Examples include
dimethyl methylphosphonate
Ethane ( , ) is an organic chemical compound with chemical formula . At standard temperature and pressure, ethane is a colorless, odorless gas. Like many hydrocarbons, ethane is isolated on an industrial scale from natural gas and as a petroc ...
, a
precursor
Precursor or Precursors may refer to:
* Precursor (religion), a forerunner, predecessor
** The Precursor, John the Baptist
Science and technology
* Precursor (bird), a hypothesized genus of fossil birds that was composed of fossilized parts of u ...
to
sarin
Sarin (NATO designation GB G-series, "B"">Nerve_agent#G-series.html" ;"title="hort for Nerve agent#G-series">G-series, "B" is an extremely toxic synthetic organophosphorus compound.flame retardant
The term flame retardants subsumes a diverse group of chemicals that are added to manufactured materials, such as plastics and textiles, and surface finishes and coatings. Flame retardants are activated by the presence of an ignition source a ...
, and
thiodiglycol
Thiodiglycol, or bis(2-hydroxyethyl)sulfide (also known as 2,2-thiodiethanol or TDE), is the organosulfur compound with the formula S(CH2CH2OH)2. It is miscible with water and polar organic solvents. It is a colorless liquid. It is structurall ...
, a precursor chemical used in the manufacture of mustard gas but also widely used as a solvent in
ink
Ink is a gel, sol, or solution that contains at least one colorant, such as a dye or pigment, and is used to color a surface to produce an image, text, or design. Ink is used for drawing or writing with a pen, brush, reed pen, or quill. Thicker ...
s.
* Schedule 3 – Have legitimate large-scale industrial uses. Examples include
phosgene
Phosgene is the organic chemical compound with the formula COCl2. It is a toxic, colorless gas; in low concentrations, its musty odor resembles that of freshly cut hay or grass. Phosgene is a valued and important industrial building block, espe ...
and
chloropicrin
Chloropicrin, also known as PS and nitrochloroform, is a chemical compound currently used as a broad-spectrum antimicrobial, fungicide, herbicide, insecticide, and nematicide. It was used as a poison gas in World War I. Its chemical structural f ...
. Both have been used as chemical weapons but phosgene is an important precursor in the manufacture of plastics and chloropicrin is used as a fumigant. The OPCW must be notified of, and may inspect, any plant producing more than 30 tons per year.
History
Simple chemical weapons were used sporadically throughout antiquity and into the Industrial age. It was not until the 19th century that the modern conception of chemical warfare emerged, as various scientists and nations proposed the use of asphyxiating or poisonous gasses.
Multiple international treaties were passed banning chemical weapons based upon the alarm of nations and scientists. This however did not prevent the extensive use of chemical weapons in World War I. The development of
chlorine gas
Chlorine is a chemical element with the symbol Cl and atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the periodic table and its properties are mostly intermediate between them. Chlorine is ...
, among others, was used by both sides to try to break the stalemate of
trench warfare
Trench warfare is a type of land warfare using occupied lines largely comprising military trenches, in which troops are well-protected from the enemy's small arms fire and are substantially sheltered from artillery. Trench warfare became a ...
. Though largely ineffective over the long run, it decidedly changed the nature of the war. In many cases the gasses used did not kill, but instead horribly maimed, injured, or disfigured casualties. Some 1.3 million gas casualties were recorded, which may have included up to 260,000 civilian casualties.
The interwar years saw occasional use of chemical weapons, mainly to put down rebellions."Chemical Weapons" in ''Historical Dictionary of Ethiopia'', 2d ed. (eds. David H. Shinn & Thomas P. Ofcansky: Scarecrow Press, 2013). In Nazi Germany, much research went into developing new chemical weapons, such as potent
nerve agent
Nerve agents, sometimes also called nerve gases, are a class of organic chemicals that disrupt the mechanisms by which nerves transfer messages to organs. The disruption is caused by the blocking of acetylcholinesterase (AChE), an enzyme that ...
s. However, chemical weapons saw little battlefield use in World War II. Both sides were prepared to use such weapons, but the Allied powers never did, and the Axis used them only very sparingly. The reason for the lack of use by the Nazis, despite the considerable efforts that had gone into developing new varieties, might have been a lack of technical ability or fears that the Allies would retaliate with their own chemical weapons. Those fears were not unfounded: the Allies made comprehensive plans for defensive and retaliatory use of chemical weapons, and stockpiled large quantities."Paxman and Harris" Pakistan p. 132–135.Callum Borchers Sean Spicer takes his questionable claims to a new level in Hitler-Assad comparison ''The Washington Post'' (April 11, 2017). Japanese forces used them more widely, though only against their Asian enemies, as they also feared that using it on Western powers would result in retaliation. Chemical weapons were frequently used against
Kuomintang
The Kuomintang (KMT), also referred to as the Guomindang (GMD), the Nationalist Party of China (NPC) or the Chinese Nationalist Party (CNP), is a major political party in the Republic of China, initially on the Chinese mainland and in Tai ...
and Chinese communist troops. However, the Nazis did extensively use poison gas against civilians in
The Holocaust
The Holocaust, also known as the Shoah, was the genocide of European Jews during World War II. Between 1941 and 1945, Nazi Germany and its collaborators systematically murdered some six million Jews across German-occupied Europe; a ...
. Vast quantities of
Zyklon B
Zyklon B (; translated Cyclone B) was the trade name of a cyanide-based pesticide invented in Germany in the early 1920s. It consisted of hydrogen cyanide (prussic acid), as well as a cautionary eye irritant and one of several adsorbents such ...
gas and carbon monoxide were used in the gas chambers of Nazi extermination camps, resulting in the overwhelming majority of some three million deaths. This remains the deadliest use of poison gas in history.Patrick Coffey, ''American Arsenal: A Century of Weapon Technology and Strategy'' (Oxford University Press, 2014), pp. 152–154.James J. Wirtz, "Weapons of Mass Destruction" in ''Contemporary Security Studies'' (4th ed.), ed. Alan Collins, ''Contemporary Security Studies'' (Oxford University Press, 2016), p. 302.
The post-war era has seen limited, though devastating, use of chemical weapons. During the Vietnam War, between 1962 and 1971, the United States military sprayed nearly 20,000,000 U.S. gallons (76,000 m3) of various chemicals – the "
rainbow herbicides
The Rainbow Herbicides are a group of tactical-use chemicals used by the United States military in Southeast Asia during the Vietnam War. Success with Project AGILE field tests with herbicides in South Vietnam in 1961 and inspiration by the Briti ...
" and defoliants – in Vietnam, eastern Laos, and parts of Cambodia as part of
Operation Ranch Hand
Operation Ranch Hand was a U.S. military operation during the Vietnam War, lasting from 1962 until 1971. Largely inspired by the British use of 2,4,5-T and 2,4-D ( Agent Orange) during the Malayan Emergency in the 1950s, it was part of the ov ...
, reaching its peak from 1967 to 1969. Some 100,000 Iranian troops were casualties of Iraqi chemical weapons during the
Iran–Iraq War
The Iran–Iraq War was an armed conflict between Iran and Iraq that lasted from September 1980 to August 1988. It began with the Iraqi invasion of Iran and lasted for almost eight years, until the acceptance of United Nations Security Council ...
. Iraq used mustard gas and nerve agents against its own civilians in the 1988
Halabja chemical attack
The Halabja massacre ( ku, Kêmyabarana Helebce کیمیابارانی ھەڵەبجە), also known as the Halabja chemical attack, was a massacre of Kurdish people that took place on 16 March 1988, during the closing days of the Iran–Iraq War ...
.On this day: 1988: Thousands die in Halabja gas attack BBC News (March 16, 1988). The
Cuban intervention in Angola
The Cuban intervention in Angola (codenamed Operation Carlota) began on 5 November 1975, when Cuba sent combat troops in support of the communist-aligned People's Movement for the Liberation of Angola (MPLA) against the pro-western National Uni ...
saw limited use of
organophosphate
In organic chemistry, organophosphates (also known as phosphate esters, or OPEs) are a class of organophosphorus compounds with the general structure , a central phosphate molecule with alkyl or aromatic substituents. They can be considered a ...
s. The Syrian government has used
sarin
Sarin (NATO designation GB G-series, "B"">Nerve_agent#G-series.html" ;"title="hort for Nerve agent#G-series">G-series, "B" is an extremely toxic synthetic organophosphorus compound.Syrian civil war generally against civilians. Terrorist groups have also used chemical weapons, notably in the
Tokyo subway sarin attack
The was an act of domestic terrorism perpetrated on 20 March 1995, in Tokyo, Japan, by members of the cult movement Aum Shinrikyo. In five coordinated attacks, the perpetrators released sarin on three lines of the Tokyo Metro (then ''Teito Rapi ...
chemical terrorism
Chemical terrorism is the form of terrorism that uses the toxic effects of chemicals to kill, injure, or otherwise adversely affect the interests of its targets. It can broadly be considered a form of chemical warfare.
Incidents
Use by LTTE in ...
.
Technology
Although crude chemical warfare has been employed in many parts of the world for thousands of years, "modern" chemical warfare began during
World War I
World War I (28 July 1914 11 November 1918), often abbreviated as WWI, was one of the deadliest global conflicts in history. Belligerents included much of Europe, the Russian Empire, the United States, and the Ottoman Empire, with fightin ...
– see
Chemical weapons in World War I
The use of toxic chemicals as weapons dates back thousands of years, but the first large scale use of chemical weapons was during World War I. They were primarily used to demoralize, injure, and kill entrenched defenders, against whom the indisc ...
.
Initially, only well-known commercially available chemicals and their variants were used. These included
chlorine
Chlorine is a chemical element with the Symbol (chemistry), symbol Cl and atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the periodic table and its properties are mostly intermediate betwee ...
and
phosgene
Phosgene is the organic chemical compound with the formula COCl2. It is a toxic, colorless gas; in low concentrations, its musty odor resembles that of freshly cut hay or grass. Phosgene is a valued and important industrial building block, espe ...
gas. The methods used to disperse these agents during battle were relatively unrefined and inefficient. Even so, casualties could be heavy, due to the mainly static troop positions which were characteristic features of
trench warfare
Trench warfare is a type of land warfare using occupied lines largely comprising military trenches, in which troops are well-protected from the enemy's small arms fire and are substantially sheltered from artillery. Trench warfare became a ...
.
Germany
Germany,, officially the Federal Republic of Germany, is a country in Central Europe. It is the second most populous country in Europe after Russia, and the most populous member state of the European Union. Germany is situated betwe ...
, the first side to employ chemical warfare on the battlefield, simply opened canisters of chlorine upwind of the opposing side and let the
prevailing winds
In meteorology, prevailing wind in a region of the Earth's surface is a surface wind that blows predominantly from a particular direction. The dominant winds are the trends in direction of wind with the highest speed over a particular point on ...
do the dissemination. Soon after, the French modified
artillery
Artillery is a class of heavy military ranged weapons that launch munitions far beyond the range and power of infantry firearms. Early artillery development focused on the ability to breach defensive walls and fortifications during siege ...
munition
Ammunition (informally ammo) is the material fired, scattered, dropped, or detonated from any weapon or weapon system. Ammunition is both expendable weapons (e.g., bombs, missiles, grenades, land mines) and the component parts of other weapo ...
s to contain phosgene – a much more effective method that became the principal means of delivery.
Since the development of modern chemical warfare in World War I, nations have pursued
research and development
Research and development (R&D or R+D), known in Europe as research and technological development (RTD), is the set of innovative activities undertaken by corporations or governments in developing new services or products, and improving existi ...
on chemical weapons that falls into four major categories: new and more deadly agents; more efficient methods of delivering agents to the target (dissemination); more reliable means of defense against chemical weapons; and more sensitive and accurate means of detecting chemical agents.
Chemical warfare agents
The chemical used in warfare is called a ''chemical warfare agent'' (''CWA''). About 70 different chemicals have been used or stockpiled as chemical warfare agents during the 20th and 21st centuries. These agents may be in liquid, gas or solid form. Liquid agents that evaporate quickly are said to be ''volatile'' or have a ''high
vapor pressure
Vapor pressure (or vapour pressure in English-speaking countries other than the US; see spelling differences) or equilibrium vapor pressure is defined as the pressure exerted by a vapor in thermodynamic equilibrium with its condensed phases ...
''. Many chemical agents are made volatile so they can be dispersed over a large region quickly.
The earliest target of chemical warfare agent research was not toxicity, but development of agents that can affect a target through the skin and clothing, rendering protective
gas mask
A gas mask is a mask used to protect the wearer from inhaling airborne pollutants and toxic gases. The mask forms a sealed cover over the nose and mouth, but may also cover the eyes and other vulnerable soft tissues of the face. Most gas mask ...
s useless. In July 1917, the Germans employed
sulfur mustard
Mustard gas or sulfur mustard is a chemical compound belonging to a family of cytotoxic and blister agents known as mustard agents. The name ''mustard gas'' is technically incorrect: the substance, when dispersed, is often not actually a gas, b ...
. Mustard agents easily penetrate leather and fabric to inflict painful burns on the skin.
Chemical warfare agents are divided into ''lethal'' and ''incapacitating'' categories. A substance is classified as incapacitating if less than 1/100 of the
lethal dose
In toxicology, the lethal dose (LD) is an indication of the lethal toxicity of a given substance or type of radiation. Because resistance varies from one individual to another, the "lethal dose" represents a dose (usually recorded as dose per kilog ...
causes incapacitation, e.g., through nausea or visual problems. The distinction between lethal and incapacitating substances is not fixed, but relies on a statistical average called the .
Persistency
Chemical warfare agents can be classified according to their ''persistency'', a measure of the length of time that a chemical agent remains effective after dissemination. Chemical agents are classified as ''persistent'' or ''nonpersistent''.
Agents classified as ''nonpersistent'' lose effectiveness after only a few minutes or hours or even only a few seconds. Purely gaseous agents such as chlorine are nonpersistent, as are highly volatile agents such as
sarin
Sarin (NATO designation GB G-series, "B"">Nerve_agent#G-series.html" ;"title="hort for Nerve agent#G-series">G-series, "B" is an extremely toxic synthetic organophosphorus compound.VX nerve agent, do not easily evaporate into a gas, and therefore present primarily a contact hazard.
The droplet size used for persistent delivery goes up to 1 mm increasing the falling speed and therefore about 80% of the deployed agent reaches the ground, resulting in heavy contamination. Deployment of persistent agents is intended to constrain enemy operations by denying access to contaminated areas.
Possible targets include enemy flank positions (averting possible counterattacks), artillery regiments, command posts or supply lines. Because it is not necessary to deliver large quantities of the agent in a short period of time, a wide variety of weapons systems can be used.
A special form of persistent agents are thickened agents. These comprise a common agent mixed with thickeners to provide gelatinous, sticky agents. Primary targets for this kind of use include airfields, due to the increased persistency and difficulty of decontaminating affected areas.
Classes
Chemical weapons are agents that come in four categories:
choking
Choking, also known as foreign body airway obstruction (FBAO), is a phenomenon that occurs when breathing is impeded by a blockage inside of the respiratory tract. An obstruction that prevents oxygen from entering the lungs results in oxygen de ...
,
blister
A blister is a small pocket of body fluid (lymph, serum, plasma, blood, or pus) within the upper layers of the skin, usually caused by forceful rubbing (friction), burning, freezing, chemical exposure or infection. Most blisters are filled wi ...
,
blood
Blood is a body fluid in the circulatory system of humans and other vertebrates that delivers necessary substances such as nutrients and oxygen to the cells, and transports metabolic waste products away from those same cells. Blood in the c ...
and
nerve
A nerve is an enclosed, cable-like bundle of nerve fibers (called axons) in the peripheral nervous system.
A nerve transmits electrical impulses. It is the basic unit of the peripheral nervous system. A nerve provides a common pathway for the e ...
. The agents are organized into several categories according to the manner in which they affect the human body. The names and number of categories varies slightly from source to source, but in general, types of chemical warfare agents are as follows:
There are other chemicals used militarily that are not scheduled by the
Chemical Weapons Convention
The Chemical Weapons Convention (CWC), officially the Convention on the Prohibition of the Development, Production, Stockpiling and Use of Chemical Weapons and on their Destruction, is an arms control treaty administered by the Organisation for ...
, and thus are not controlled under the CWC treaties. These include:
*
Defoliant
A defoliant is any herbicidal chemical sprayed or dusted on plants to cause their leaves to fall off. Defoliants are widely used for the selective removal of weeds in managing croplands and lawns. Worldwide use of defoliants, along with the ...
s and
herbicide
Herbicides (, ), also commonly known as weedkillers, are substances used to control undesired plants, also known as weeds.EPA. February 201Pesticides Industry. Sales and Usage 2006 and 2007: Market Estimates. Summary in press releasMain page fo ...
s that destroy vegetation, but are not immediately toxic or poisonous to human beings. Their use is classified as herbicidal warfare. Some batches of
Agent Orange
Agent Orange is a chemical herbicide and defoliant, one of the "tactical use" Rainbow Herbicides. It was used by the U.S. military as part of its herbicidal warfare program, Operation Ranch Hand, during the Vietnam War from 1961 to 1971. It ...
, for instance, used by the British during the
Malayan Emergency
The Malayan Emergency, also known as the Anti–British National Liberation War was a guerrilla war fought in British Malaya between communist pro-independence fighters of the Malayan National Liberation Army (MNLA) and the military forces o ...
and the United States during the
Vietnam War
The Vietnam War (also known by #Names, other names) was a conflict in Vietnam, Laos, and Cambodia from 1 November 1955 to the fall of Saigon on 30 April 1975. It was the second of the Indochina Wars and was officially fought between North Vie ...
, contained dioxins as manufacturing impurities. Dioxins, rather than Agent Orange itself, have long-term cancer effects and for causing genetic damage leading to serious birth defects.
* Incendiary or
explosive
An explosive (or explosive material) is a reactive substance that contains a great amount of potential energy that can produce an explosion if released suddenly, usually accompanied by the production of light, heat, sound, and pressure. An expl ...
chemicals (such as
napalm
Napalm is an incendiary mixture of a gelling agent and a volatile petrochemical (usually gasoline (petrol) or diesel fuel). The name is a portmanteau of two of the constituents of the original thickening and gelling agents: coprecipitated al ...
, extensively used by the United States during the
Korean War
, date = {{Ubl, 25 June 1950 – 27 July 1953 (''de facto'')({{Age in years, months, weeks and days, month1=6, day1=25, year1=1950, month2=7, day2=27, year2=1953), 25 June 1950 – present (''de jure'')({{Age in years, months, weeks a ...
and the Vietnam War, or
dynamite
Dynamite is an explosive made of nitroglycerin, sorbents (such as powdered shells or clay), and Stabilizer (chemistry), stabilizers. It was invented by the Swedish people, Swedish chemist and engineer Alfred Nobel in Geesthacht, Northern Germa ...
) because their destructive effects are primarily due to fire or explosive force, and not direct chemical action. Their use is classified as
conventional warfare
Conventional warfare is a form of warfare conducted by using conventional weapons and battlefield tactics between two or more states in open confrontation. The forces on each side are well-defined and fight by using weapons that target primari ...
.
*
Virus
A virus is a submicroscopic infectious agent that replicates only inside the living cells of an organism. Viruses infect all life forms, from animals and plants to microorganisms, including bacteria and archaea.
Since Dmitri Ivanovsky's 1 ...
es,
bacteria
Bacteria (; singular: bacterium) are ubiquitous, mostly free-living organisms often consisting of one biological cell. They constitute a large domain of prokaryotic microorganisms. Typically a few micrometres in length, bacteria were among ...
, or other organisms. Their use is classified as
biological warfare
Biological warfare, also known as germ warfare, is the use of biological toxins or infectious agents such as bacteria, viruses, insects, and fungi with the intent to kill, harm or incapacitate humans, animals or plants as an act of war. Bio ...
.
Toxin
A toxin is a naturally occurring organic poison produced by metabolic activities of living cells or organisms. Toxins occur especially as a protein or conjugated protein. The term toxin was first used by organic chemist Ludwig Brieger (1849– ...
s produced by living organisms are considered chemical weapons, although the boundary is blurry. Toxins are covered by the
Biological Weapons Convention
The Biological Weapons Convention (BWC), or Biological and Toxin Weapons Convention (BTWC), is a disarmament treaty that effectively bans biological and toxin weapons by prohibiting their development, production, acquisition, transfer, stockpil ...
.
Designations
Most chemical weapons are assigned a one- to three-letter "
NATO
The North Atlantic Treaty Organization (NATO, ; french: Organisation du traité de l'Atlantique nord, ), also called the North Atlantic Alliance, is an intergovernmental military alliance between 30 member states – 28 European and two No ...
weapon designation" in addition to, or in place of, a common name. Binary munitions, in which precursors for chemical warfare agents are automatically mixed in shell to produce the agent just prior to its use, are indicated by a "-2" following the agent's designation (for example, GB-2 and VX-2).
Some examples are given below:
Delivery
The most important factor in the effectiveness of chemical weapons is the efficiency of its delivery, or dissemination, to a target. The most common techniques include munitions (such as bombs, projectiles, warheads) that allow dissemination at a distance and spray tanks which disseminate from low-flying aircraft. Developments in the techniques of filling and storage of munitions have also been important.
Although there have been many advances in chemical weapon delivery since World War I, it is still difficult to achieve effective dispersion. The dissemination is highly dependent on atmospheric conditions because many chemical agents act in gaseous form. Thus, weather observations and forecasting are essential to optimize weapon delivery and reduce the risk of injuring friendly forces.
Dispersion
Dispersion is placing the chemical agent upon or adjacent to a target immediately before dissemination, so that the material is most efficiently used. Dispersion is the simplest technique of delivering an agent to its target. The most common techniques are munitions, bombs, projectiles, spray tanks and warheads.
World War I
World War I (28 July 1914 11 November 1918), often abbreviated as WWI, was one of the deadliest global conflicts in history. Belligerents included much of Europe, the Russian Empire, the United States, and the Ottoman Empire, with fightin ...
saw the earliest implementation of this technique. The actual first chemical ammunition was the French 26 mm cartouche suffocante
rifle grenade
A rifle grenade is a grenade that uses a rifle-based launcher to permit a longer effective range than would be possible if the grenade were thrown by hand.
The practice of projecting grenades with rifle-mounted launchers was first widely used du ...
contrarily tried to increase the effect of 10.5 cm
shrapnel shell
Shrapnel shells were anti-personnel artillery munitions which carried many individual bullets close to a target area and then ejected them to allow them to continue along the shell's trajectory and strike targets individually. They relied almo ...
s by adding an irritant – dianisidine chlorosulfonate. Its use went unnoticed by the British when it was used against them at
Neuve Chapelle
Neuve-Chapelle ( vls, Nieuwkappel) is a commune in the Pas-de-Calais department in the Hauts-de-France region of France. It was the site of a First World War battle in 1915.
Geography
Neuve-Chapelle is situated some northeast of Béthune and ...
in October 1914. Hans Tappen, a chemist in the Heavy Artillery Department of the War Ministry, suggested to his brother, the Chief of the Operations Branch at German General Headquarters, the use of the tear-gases
benzyl bromide
Benzyl bromide is an organic compound with the formula . The molecule consists of a benzene ring substituted with a bromomethyl group. It is a colorless liquid with lachrymatory properties. The compound is a reagent for introducing benzyl groups ...
or
xylyl bromide
Xylyl bromide, also known as methylbenzyl bromide or T-stoff ('substance-T'), is any member or a mixture of organic chemical compounds with the molecular formula C6 H4(CH3)(CH2 Br). The mixture was formerly used as a tear gas and has an odor r ...
.
Shells were tested successfully at the Wahn artillery range near
Cologne
Cologne ( ; german: Köln ; ksh, Kölle ) is the largest city of the German western States of Germany, state of North Rhine-Westphalia (NRW) and the List of cities in Germany by population, fourth-most populous city of Germany with 1.1 m ...
on January 9, 1915, and an order was placed for 15 cm
howitzer
A howitzer () is a long- ranged weapon, falling between a cannon (also known as an artillery gun in the United States), which fires shells at flat trajectories, and a mortar, which fires at high angles of ascent and descent. Howitzers, like ot ...
shells, designated 'T-shells' after Tappen. A shortage of shells limited the first use against the Russians at Bolimów on January 31, 1915; the liquid failed to vaporize in the cold weather, and again the experiment went unnoticed by the Allies.
The first effective use were when the German forces at the
Second Battle of Ypres
During the First World War, the Second Battle of Ypres was fought from for control of the tactically important high ground to the east and south of the Flemish town of Ypres in western Belgium. The First Battle of Ypres had been fought the pr ...
simply opened cylinders of
chlorine
Chlorine is a chemical element with the Symbol (chemistry), symbol Cl and atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the periodic table and its properties are mostly intermediate betwee ...
and allowed the
wind
Wind is the natural movement of air or other gases relative to a planet's surface. Winds occur on a range of scales, from thunderstorm flows lasting tens of minutes, to local breezes generated by heating of land surfaces and lasting a few hou ...
to carry the gas across enemy lines. While simple, this technique had numerous disadvantages. Moving large numbers of heavy gas cylinders to the front-line positions from where the gas would be released was a lengthy and difficult logistical task.
Stockpiles of cylinders had to be stored at the front line, posing a great risk if hit by artillery shells. Gas delivery depended greatly on
wind speed
In meteorology, wind speed, or wind flow speed, is a fundamental atmospheric quantity caused by air moving from high to low pressure, usually due to changes in temperature. Wind speed is now commonly measured with an anemometer.
Wind speed ...
and direction. If the wind was fickle, as at Loos, the gas could blow back, causing friendly casualties.
Gas clouds gave plenty of warning, allowing the enemy time to protect themselves, though many soldiers found the sight of a creeping gas cloud unnerving. This made the gas doubly effective, as, in addition to damaging the enemy physically, it also had a psychological effect on the intended victims.
Another disadvantage was that gas clouds had limited penetration, capable only of affecting the front-line trenches before dissipating. Although it produced limited results in World War I, this technique shows how simple chemical weapon dissemination ''can'' be.
Shortly after this "open canister" dissemination, French forces developed a technique for delivery of
phosgene
Phosgene is the organic chemical compound with the formula COCl2. It is a toxic, colorless gas; in low concentrations, its musty odor resembles that of freshly cut hay or grass. Phosgene is a valued and important industrial building block, espe ...
in a non-explosive
artillery
Artillery is a class of heavy military ranged weapons that launch munitions far beyond the range and power of infantry firearms. Early artillery development focused on the ability to breach defensive walls and fortifications during siege ...
shell. This technique overcame many of the risks of dealing with gas in cylinders. First, gas shells were independent of the wind and increased the effective range of gas, making any target within reach of guns vulnerable. Second, gas shells could be delivered without warning, especially the clear, nearly odorless phosgenethere are numerous accounts of gas shells, landing with a "plop" rather than exploding, being initially dismissed as dud
high explosive
An explosive (or explosive material) is a reactive substance that contains a great amount of potential energy that can produce an explosion if released suddenly, usually accompanied by the production of light, heat, sound, and pressure. An exp ...
or
shrapnel shell
Shrapnel shells were anti-personnel artillery munitions which carried many individual bullets close to a target area and then ejected them to allow them to continue along the shell's trajectory and strike targets individually. They relied almo ...
s, giving the gas time to work before the soldiers were alerted and took precautions.
The major drawback of artillery delivery was the difficulty of achieving a killing concentration. Each shell had a small gas payload and an area would have to be subjected to saturation bombardment to produce a cloud to match cylinder delivery. A British solution to the problem was the
Livens Projector
The Livens Projector was a simple mortar-like weapon that could throw large drums filled with flammable or toxic chemicals.
In the First World War, the Livens Projector became the standard means of delivering gas attacks by the British Army a ...
. This was effectively a large-bore mortar, dug into the ground that used the gas cylinders themselves as projectiles – firing a 14 kg cylinder up to 1500 m. This combined the gas volume of cylinders with the range of artillery.
Over the years, there were some refinements in this technique. In the 1950s and early 1960s, chemical artillery rockets and
cluster bomb
A cluster munition is a form of air-dropped or ground-launched explosive weapon that releases or ejects smaller submunitions. Commonly, this is a cluster bomb that ejects explosive bomblets that are designed to kill personnel and destroy vehicl ...
s contained a multitude of submunitions, so that a large number of small clouds of the chemical agent would form directly on the target.
Thermal dissemination
Thermal dissemination is the use of
explosive
An explosive (or explosive material) is a reactive substance that contains a great amount of potential energy that can produce an explosion if released suddenly, usually accompanied by the production of light, heat, sound, and pressure. An expl ...
s or
pyrotechnic
Pyrotechnics is the science and craft of creating such things as fireworks, safety matches, oxygen candles, explosive bolts and other fasteners, parts of automotive airbags, as well as gas-pressure blasting in mining, quarrying, and demolition. ...
s to deliver chemical agents. This technique, developed in the 1920s, was a major improvement over earlier dispersal techniques, in that it allowed significant quantities of an agent to be disseminated over a considerable distance. Thermal dissemination remains the principal method of disseminating chemical agents today.
Most thermal dissemination devices consist of a
bomb
A bomb is an explosive weapon that uses the Exothermic process, exothermic reaction of an explosive material to provide an extremely sudden and violent release of energy. Detonations inflict damage principally through ground- and atmosphere-t ...
or projectile shell that contains a chemical agent and a central "burster" charge; when the burster detonates, the agent is expelled laterally.
Thermal dissemination devices, though common, are not particularly efficient. First, a percentage of the agent is lost by incineration in the initial blast and by being forced onto the ground. Second, the sizes of the particles vary greatly because explosive dissemination produces a mixture of liquid droplets of variable and difficult to control sizes.
The efficacy of thermal detonation is greatly limited by the flammability of some agents. For flammable
aerosols
An aerosol is a suspension of fine solid particles or liquid droplets in air or another gas. Aerosols can be natural or anthropogenic. Examples of natural aerosols are fog or mist, dust, forest exudates, and geyser steam. Examples of anthrop ...
, the cloud is sometimes totally or partially ignited by the disseminating explosion in a phenomenon called ''flashing''. Explosively disseminated VX will ignite roughly one third of the time. Despite a great deal of study, flashing is still not fully understood, and a solution to the problem would be a major technological advance.
Despite the limitations of central bursters, most nations use this method in the early stages of chemical weapon development, in part because standard munitions can be adapted to carry the agents.
Aerodynamic dissemination
Aerodynamic dissemination is the non-explosive delivery of a chemical agent from an aircraft, allowing aerodynamic stress to disseminate the agent. This technique is the most recent major development in chemical agent dissemination, originating in the mid-1960s.
This technique eliminates many of the limitations of thermal dissemination by eliminating the flashing effect and theoretically allowing precise control of particle size. In actuality, the altitude of dissemination, wind direction and velocity, and the direction and velocity of the aircraft greatly influence particle size. There are other drawbacks as well; ideal deployment requires precise knowledge of
aerodynamics
Aerodynamics, from grc, ἀήρ ''aero'' (air) + grc, δυναμική (dynamics), is the study of the motion of air, particularly when affected by a solid object, such as an airplane wing. It involves topics covered in the field of fluid dyn ...
and
fluid dynamics
In physics and engineering, fluid dynamics is a subdiscipline of fluid mechanics that describes the flow of fluids— liquids and gases. It has several subdisciplines, including ''aerodynamics'' (the study of air and other gases in motion) an ...
, and because the agent must usually be dispersed within the
boundary layer
In physics and fluid mechanics, a boundary layer is the thin layer of fluid in the immediate vicinity of a bounding surface formed by the fluid flowing along the surface. The fluid's interaction with the wall induces a no-slip boundary condi ...
(less than above the ground), it puts pilots at risk.
Significant research is still being applied toward this technique. For example, by modifying the properties of the liquid, its breakup when subjected to aerodynamic stress can be controlled and an idealized particle distribution achieved, even at
supersonic speed
Supersonic speed is the speed of an object that exceeds the speed of sound ( Mach 1). For objects traveling in dry air of a temperature of 20 °C (68 °F) at sea level, this speed is approximately . Speeds greater than five times ...
. Additionally, advances in fluid dynamics,
computer model
Computer simulation is the process of mathematical modelling, performed on a computer, which is designed to predict the behaviour of, or the outcome of, a real-world or physical system. The reliability of some mathematical models can be deter ...
ing, and
weather forecasting
Weather forecasting is the application of science and technology forecasting, to predict the conditions of the Earth's atmosphere, atmosphere for a given location and time. People have attempted to predict the weather informally for millennia a ...
allow an ideal direction, speed, and altitude to be calculated, such that warfare agent of a predetermined particle size can predictably and reliably hit a target.
Protection against chemical warfare
Ideal protection begins with nonproliferation treaties such as the
Chemical Weapons Convention
The Chemical Weapons Convention (CWC), officially the Convention on the Prohibition of the Development, Production, Stockpiling and Use of Chemical Weapons and on their Destruction, is an arms control treaty administered by the Organisation for ...
, and detecting, very early, the ''signatures'' of someone building a chemical weapons capability. These include a wide range of intelligence disciplines, such as economic analysis of exports of
dual-use
In politics, diplomacy and export control, dual-use items refers to goods, software and technology that can be used for both civilian and military applications.
chemicals and equipment, human intelligence (
HUMINT
Human intelligence (abbreviated HUMINT and pronounced as ''hyoo-mint'') is Intelligence (information gathering), intelligence gathered by means of interpersonal contact, as opposed to the List of intelligence gathering disciplines, more technical ...
) such as diplomatic, refugee, and agent reports; photography from satellites, aircraft and drones (
IMINT
Imagery intelligence (IMINT), pronounced as either as ''Im-Int'' or ''I-Mint'', is an intelligence gathering discipline wherein imagery is analyzed (or "exploited") to identify information of intelligence value. Imagery used for defense intelli ...
); examination of captured equipment (
TECHINT
Techint is an Argentine conglomerate founded in Milan in 1945 by Italian industrialist Agostino Rocca and headquartered in Milan (Italy) and Buenos Aires (Argentina). As of 2019 the Techint Group is composed of six main companies in the followin ...
); communications intercepts (
COMINT
Signals intelligence (SIGINT) is intelligence-gathering by interception of '' signals'', whether communications between people (communications intelligence—abbreviated to COMINT) or from electronic signals not directly used in communication ...
); and detection of chemical manufacturing and chemical agents themselves (
MASINT
Measurement and signature intelligence (MASINT) is a technical branch of intelligence gathering, which serves to detect, track, identify or describe the distinctive characteristics (signatures) of fixed or dynamic target sources. This often incl ...
).
If all the preventive measures fail and there is a clear and present danger, then there is a need for detection of chemical attacks,
collective protection, and decontamination. Since industrial accidents can cause dangerous chemical releases (e.g., the
Bhopal disaster
The Bhopal disaster, also referred to as the Bhopal gas tragedy, was a chemical accident on the night of 2–3 December 1984 at the Union Carbide India Limited (UCIL) pesticide plant in Bhopal, Madhya Pradesh, India. Considered the world's ...
), these activities are things that civilian, as well as military, organizations must be prepared to carry out. In civilian situations in
developed countries
A developed country (or industrialized country, high-income country, more economically developed country (MEDC), advanced country) is a sovereign state that has a high quality of life, developed economy and advanced technological infrastruct ...
, these are duties of
HAZMAT
Dangerous goods, abbreviated DG, are substances that when transported are a risk to health, safety, property or the environment. Certain dangerous goods that pose risks even when not being transported are known as hazardous materials ( syllabi ...
organizations, which most commonly are part of fire departments.
Detection has been referred to above, as a technical
MASINT
Measurement and signature intelligence (MASINT) is a technical branch of intelligence gathering, which serves to detect, track, identify or describe the distinctive characteristics (signatures) of fixed or dynamic target sources. This often incl ...
discipline; specific military procedures, which are usually the model for civilian procedures, depend on the equipment, expertise, and personnel available. When chemical agents are detected, an
alarm
An alarm device is a mechanism that gives an audible, visual or other kind of alarm signal to alert someone to a problem or condition that requires urgent attention.
Alphabetical musical instruments
Etymology
The word ''alarm'' comes from th ...
needs to sound, with specific warnings over emergency broadcasts and the like. There may be a warning to expect an attack.
If, for example, the captain of a
US Navy
The United States Navy (USN) is the maritime service branch of the United States Armed Forces and one of the eight uniformed services of the United States. It is the largest and most powerful navy in the world, with the estimated tonnage of ...
ship believes there is a serious threat of chemical, biological, or radiological attack, the crew may be ordered to set Circle William, which means closing all openings to outside air, running breathing air through filters, and possibly starting a system that continually washes down the exterior surfaces. Civilian authorities dealing with an attack or a toxic chemical accident will invoke the
Incident Command System
The Incident Command System (ICS) is a standardized approach to the command, control, and coordination of emergency response providing a common hierarchy within which responders from multiple agencies can be effective.
ICS was initially develo ...
, or local equivalent, to coordinate defensive measures.
Individual protection starts with a
gas mask
A gas mask is a mask used to protect the wearer from inhaling airborne pollutants and toxic gases. The mask forms a sealed cover over the nose and mouth, but may also cover the eyes and other vulnerable soft tissues of the face. Most gas mask ...
and, depending on the nature of the threat, through various levels of protective clothing up to a complete chemical-resistant suit with a self-contained air supply. The US military defines various levels of MOPP (mission-oriented protective posture) from mask to full chemical resistant suits;
Hazmat suit
A hazmat suit (hazardous materials suit) is a piece of personal protective equipment that consists of an impermeable whole-body garment worn as protection against hazardous materials. Such suits are often combined with self-contained breathing ...
s are the civilian equivalent, but go farther to include a fully independent air supply, rather than the filters of a gas mask.
Collective protection allows continued functioning of groups of people in buildings or shelters, the latter which may be fixed, mobile, or improvised. With ordinary buildings, this may be as basic as plastic sheeting and tape, although if the protection needs to be continued for any appreciable length of time, there will need to be an air supply, typically an enhanced gas mask.
Decontamination
Decontamination varies with the particular chemical agent used. Some ''nonpersistent'' agents, including most pulmonary agents (
chlorine
Chlorine is a chemical element with the Symbol (chemistry), symbol Cl and atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the periodic table and its properties are mostly intermediate betwee ...
,
phosgene
Phosgene is the organic chemical compound with the formula COCl2. It is a toxic, colorless gas; in low concentrations, its musty odor resembles that of freshly cut hay or grass. Phosgene is a valued and important industrial building block, espe ...
, and so on),
blood gases
An arterial blood gas (ABG) test, or arterial blood gas analysis (ABGA) measures the amounts of arterial gases, such as oxygen and carbon dioxide. An ABG test requires that a small volume of blood be drawn from the radial artery with a syringe an ...
, and nonpersistent nerve gases (e.g., GB), will dissipate from open areas, although powerful exhaust fans may be needed to clear out buildings where they have accumulated.
In some cases, it might be necessary to neutralize them chemically, as with
ammonia
Ammonia is an inorganic compound of nitrogen and hydrogen with the formula . A stable binary hydride, and the simplest pnictogen hydride, ammonia is a colourless gas with a distinct pungent smell. Biologically, it is a common nitrogenous was ...
as a neutralizer for
hydrogen cyanide
Hydrogen cyanide, sometimes called prussic acid, is a chemical compound with the formula HCN and structure . It is a colorless, extremely poisonous, and flammable liquid that boils slightly above room temperature, at . HCN is produced on an ...
or
chlorine
Chlorine is a chemical element with the Symbol (chemistry), symbol Cl and atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the periodic table and its properties are mostly intermediate betwee ...
. Riot control agents such as CS will dissipate in an open area, but things contaminated with CS powder need to be aired out, washed by people wearing protective gear, or safely discarded.
Mass decontamination
Mass decontamination (abbreviated mass decon) is the decontamination of large numbers of people, in the event of industrial, accidental, or intentional contamination by toxic, infective, caustic, polluted, or otherwise unhealthful or damaging su ...
is a less common requirement for people than equipment, since people may be immediately affected and treatment is the action required. It is a requirement when people have been contaminated with persistent agents. Treatment and decontamination may need to be simultaneous, with the medical personnel protecting themselves so they can function.
There may need to be immediate intervention to prevent death, such as injection of
atropine
Atropine is a tropane alkaloid and anticholinergic medication used to treat certain types of nerve agent and pesticide poisonings as well as some types of slow heart rate, and to decrease saliva production during surgery. It is typically given i ...
for nerve agents. Decontamination is especially important for people contaminated with persistent agents; many of the fatalities after the explosion of a WWII US ammunition ship carrying sulfur mustard, in the harbor of Bari, Italy, after a German bombing on December 2, 1943, came when rescue workers, not knowing of the contamination, bundled cold, wet seamen in tight-fitting blankets.
For decontaminating equipment and buildings exposed to persistent agents, such as
blister agent
A blister agent (or vesicant), is a chemical compound that causes severe skin, eye and mucosal pain and irritation. They are named for their ability to cause severe chemical burns, resulting in painful water blisters on the bodies of those affe ...
s, VX or other agents made persistent by mixing with a thickener, special equipment and materials might be needed. Some type of neutralizing agent will be needed; e.g. in the form of a spraying device with neutralizing agents such as Chlorine, Fichlor, strong alkaline solutions or enzymes. In other cases, a specific chemical decontaminant will be required.
Sociopolitical climate
There are many instances of the use of chemical weapons in battles documented in Greek and Roman historical texts; the earliest example was the deliberate poisoning of Kirrha's water supply with
hellebore
Commonly known as hellebores (), the Eurasian genus ''Helleborus'' consists of approximately 20 species of herbaceous or evergreen perennial flowering plants in the family Ranunculaceae, within which it gave its name to the tribe of Helleboreae. ...
in the
First Sacred War
The First Sacred War, or Cirraean War, was fought between the Amphictyonic League of Delphi and the city of Kirrha. At the beginning of the 6th century BC the Pylaeo-Delphic Amphictyony, controlled by the Thessalians, attempted to take hold of the ...
, Greece, about 590 BC.
One of the earliest reactions to the use of chemical agents was from
Rome
, established_title = Founded
, established_date = 753 BC
, founder = King Romulus (legendary)
, image_map = Map of comune of Rome (metropolitan city of Capital Rome, region Lazio, Italy).svg
, map_caption ...
. Struggling to defend themselves from the
Roman legion
The Roman legion ( la, legiō, ) was the largest military unit of the Roman army, composed of 5,200 infantry and 300 equites (cavalry) in the period of the Roman Republic (509 BC–27 BC) and of 5,600 infantry and 200 auxilia in the period of ...
s, Germanic tribes poisoned the wells of their enemies, with Roman jurists having been recorded as declaring "armis bella non venenis geri", meaning "war is fought with
weapon
A weapon, arm or armament is any implement or device that can be used to deter, threaten, inflict physical damage, harm, or kill. Weapons are used to increase the efficacy and efficiency of activities such as hunting, crime, law enforcement, s ...
s, not with
poison
Poison is a chemical substance that has a detrimental effect to life. The term is used in a wide range of scientific fields and industries, where it is often specifically defined. It may also be applied colloquially or figuratively, with a broa ...
s." Yet the Romans themselves resorted to poisoning wells of besieged cities in Anatolia in the 2nd century BCE.Mayor 2003
Before 1915 the use of poisonous chemicals in battle was typically the result of local initiative, and not the result of an active government chemical weapons program. There are many reports of the isolated use of chemical agents in individual battles or
siege
A siege is a military blockade of a city, or fortress, with the intent of conquering by attrition warfare, attrition, or a well-prepared assault. This derives from la, sedere, lit=to sit. Siege warfare is a form of constant, low-intensity con ...
s, but there was no true tradition of their use outside of
incendiaries
Incendiary weapons, incendiary devices, incendiary munitions, or incendiary bombs are weapons designed to start fires or destroy sensitive equipment using fire (and sometimes used as anti-personnel weaponry), that use materials such as napalm, th ...
and smoke. Despite this tendency, there have been several attempts to initiate large-scale implementation of poison gas in several wars, but with the notable exception of World War I, the responsible authorities generally rejected the proposals for ethical reasons or fears of retaliation.
For example, in 1854
Lyon Playfair
Lyon Playfair, 1st Baron Playfair (1 May 1818 – 29 May 1898) was a British scientist and Liberal politician who was Postmaster-General from 1873 to 1874.
Early life
Playfair was born at Chunar, Bengal, the son of George Playfair (1782-1846) ...
(later 1st Baron Playfair, GCB, PC, FRS (1818–1898), a
British
British may refer to:
Peoples, culture, and language
* British people, nationals or natives of the United Kingdom, British Overseas Territories, and Crown Dependencies.
** Britishness, the British identity and common culture
* British English, ...
chemist, proposed using a
cacodyl cyanide
Cacodyl cyanide is a highly poisonous organoarsenic compound discovered by Robert Bunsen in the 1840s. It is very volatile and flammable, as it shares the chemical properties of both arsenic and cyanide.
Synthesis
Cacodyl cyanide can be prepared ...
-filled
artillery
Artillery is a class of heavy military ranged weapons that launch munitions far beyond the range and power of infantry firearms. Early artillery development focused on the ability to breach defensive walls and fortifications during siege ...
shell against enemy ships during the
Crimean War
The Crimean War, , was fought from October 1853 to February 1856 between Russia and an ultimately victorious alliance of the Ottoman Empire, France, the United Kingdom and Piedmont-Sardinia.
Geopolitical causes of the war included the de ...
. The British Ordnance Department rejected the proposal as "as bad a mode of warfare as poisoning the wells of the enemy."
Efforts to eradicate chemical weapons
* August 27, 1874: The
Brussels Declaration
Brussels (french: Bruxelles or ; nl, Brussel ), officially the Brussels-Capital Region (All text and all but one graphic show the English name as Brussels-Capital Region.) (french: link=no, Région de Bruxelles-Capitale; nl, link=no, Bruss ...
Concerning the Laws and Customs of War is signed, specifically forbidding the "employment of poison or poisoned weapons", although the treaty was not adopted by any nation whatsoever and it never went into effect.
* September 4, 1900: The First Hague Convention, which includes a declaration banning the "use of projectiles the object of which is the diffusion of asphyxiating or deleterious gases," enters into force.
* January 26, 1910: The Second Hague Convention enters into force, prohibiting the use of "poison or poisoned weapons" in warfare.
* February 6, 1922: After World War I, the Washington Arms Conference Treaty prohibited the use of asphyxiating, poisonous or other gases. It was signed by the United States, Britain, Japan, France, and Italy, but France objected to other provisions in the treaty and it never went into effect.
* February 8, 1928: The
Geneva Protocol
The Protocol for the Prohibition of the Use in War of Asphyxiating, Poisonous or other Gases, and of Bacteriological Methods of Warfare, usually called the Geneva Protocol, is a treaty prohibiting the use of chemical and biological weapons in ...
enters into force, prohibiting the use of "asphyxiating, poisonous or other gases, and of all analogous liquids, materials or devices" and "bacteriological methods of warfare".
Chemical weapon proliferation
Despite numerous efforts to reduce or eliminate them, some nations continue to research and/or stockpile chemical warfare agents. To the right is a summary of the nations that have either declared weapon stockpiles or are suspected of secretly stockpiling or possessing CW research programs. Notable examples include
United States
The United States of America (U.S.A. or USA), commonly known as the United States (U.S. or US) or America, is a country primarily located in North America. It consists of 50 states, a federal district, five major unincorporated territorie ...
and
Russia
Russia (, , ), or the Russian Federation, is a List of transcontinental countries, transcontinental country spanning Eastern Europe and North Asia, Northern Asia. It is the List of countries and dependencies by area, largest country in the ...
.
In 1997, future
US Vice President
The vice president of the United States (VPOTUS) is the second-highest officer in the executive branch of the U.S. federal government, after the president of the United States, and ranks first in the presidential line of succession. The vice pr ...
Dick Cheney
Richard Bruce Cheney ( ; born January 30, 1941) is an American politician and businessman who served as the 46th vice president of the United States from 2001 to 2009 under President George W. Bush. He is currently the oldest living former U ...
opposed the signing ratification of a treaty banning the use of chemical weapons, a recently unearthed letter shows. In a letter dated April 8, 1997, then Halliburton-CEO Cheney told Sen.
Jesse Helms
Jesse Alexander Helms Jr. (October 18, 1921 – July 4, 2008) was an American politician. A leader in the conservative movement, he served as a senator from North Carolina from 1973 to 2003. As chairman of the Senate Foreign Relations Committee ...
, the chairman of the
Senate Foreign Relations Committee
The United States Senate Committee on Foreign Relations is a standing committee of the U.S. Senate charged with leading foreign-policy legislation and debate in the Senate. It is generally responsible for overseeing and funding foreign aid p ...
, that it would be a mistake for America to join the convention. "Those nations most likely to comply with the
Chemical Weapons Convention
The Chemical Weapons Convention (CWC), officially the Convention on the Prohibition of the Development, Production, Stockpiling and Use of Chemical Weapons and on their Destruction, is an arms control treaty administered by the Organisation for ...
are not likely to ever constitute a military threat to the United States. The governments we should be concerned about are likely to cheat on the CWC, even if they do participate," reads the letter, published by the
Federation of American Scientists
The Federation of American Scientists (FAS) is an American nonprofit global policy think tank with the stated intent of using science and scientific analysis to attempt to make the world more secure. FAS was founded in 1946 by scientists who wo ...
.
The CWC was ratified by the Senate that same month. Since then, Albania, Libya, Russia, the United States, and India have declared over 71,000 metric tons of chemical weapon stockpiles, and destroyed about a third of them. Under the terms of the agreement, the United States and Russia agreed to eliminate the rest of their supplies of chemical weapons by 2012. Not having met its goal, the U.S. government estimates remaining stocks will be destroyed by 2017.
Chemical weapons destruction
India
In June 1997, India declared that it had a stockpile of 1044 tons of sulphur mustard in its possession. India's declaration of its stockpile came after its entry into the
Chemical Weapons Convention
The Chemical Weapons Convention (CWC), officially the Convention on the Prohibition of the Development, Production, Stockpiling and Use of Chemical Weapons and on their Destruction, is an arms control treaty administered by the Organisation for ...
, that created the
Organisation for the Prohibition of Chemical Weapons
The Organisation for the Prohibition of Chemical Weapons (OPCW) is an intergovernmental organisation and the implementing body for the Chemical Weapons Convention (CWC), which entered into force on 29 April 1997. The OPCW, with its 193 member ...
, and on January 14, 1993, India became one of the original signatories to the
Chemical Weapons Convention
The Chemical Weapons Convention (CWC), officially the Convention on the Prohibition of the Development, Production, Stockpiling and Use of Chemical Weapons and on their Destruction, is an arms control treaty administered by the Organisation for ...
. By 2005, from among six nations that had declared their possession of chemical weapons, India was the only country to meet its deadline for chemical weapons destruction and for inspection of its facilities by the
Organisation for the Prohibition of Chemical Weapons
The Organisation for the Prohibition of Chemical Weapons (OPCW) is an intergovernmental organisation and the implementing body for the Chemical Weapons Convention (CWC), which entered into force on 29 April 1997. The OPCW, with its 193 member ...
. By 2006, India had destroyed more than 75 percent of its chemical weapons and material stockpile and was granted an extension to complete a 100 percent destruction of its stocks by April 2009. On May 14, 2009, India informed the
United Nations
The United Nations (UN) is an intergovernmental organization whose stated purposes are to maintain international peace and international security, security, develop friendly relations among nations, achieve international cooperation, and be ...
that it has completely destroyed its stockpile of chemical weapons.
Iraq
The Director-General of the
Organisation for the Prohibition of Chemical Weapons
The Organisation for the Prohibition of Chemical Weapons (OPCW) is an intergovernmental organisation and the implementing body for the Chemical Weapons Convention (CWC), which entered into force on 29 April 1997. The OPCW, with its 193 member ...
, Ambassador Rogelio Pfirter, welcomed Iraq's decision to join the OPCW as a significant step to strengthening global and regional efforts to prevent the spread and use of chemical weapons. The OPCW announced "The government of Iraq has deposited its instrument of accession to the Chemical Weapons Convention with the Secretary General of the United Nations and within 30 days, on 12 February 2009, will become the 186th State Party to the Convention". Iraq has also declared stockpiles of chemical weapons, and because of their recent accession is the only State Party exempted from the destruction time-line.
Japan
During the
Second Sino-Japanese War
The Second Sino-Japanese War (1937–1945) or War of Resistance (Chinese term) was a military conflict that was primarily waged between the Republic of China and the Empire of Japan. The war made up the Chinese theater of the wider Pacific Th ...
(1937–1945) Japan stored chemical weapons on the territory of
mainland China
"Mainland China" is a geopolitical term defined as the territory governed by the People's Republic of China (including islands like Hainan or Chongming), excluding dependent territories of the PRC, and other territories within Greater China. ...
. The weapon stock mostly containing sulfur mustard-lewisite mixture. The weapons are classified as abandoned chemical weapons under the
Chemical Weapons Convention
The Chemical Weapons Convention (CWC), officially the Convention on the Prohibition of the Development, Production, Stockpiling and Use of Chemical Weapons and on their Destruction, is an arms control treaty administered by the Organisation for ...
, and from September 2010 Japan has started their destruction in Nanjing using mobile destruction facilities in order to do so.
Russia
Russia signed into the
Chemical Weapons Convention
The Chemical Weapons Convention (CWC), officially the Convention on the Prohibition of the Development, Production, Stockpiling and Use of Chemical Weapons and on their Destruction, is an arms control treaty administered by the Organisation for ...
on January 13, 1993, and ratified it on November 5, 1995. Declaring an arsenal of 39,967 tons of chemical weapons in 1997, by far the largest arsenal, consisting of blister agents:
Lewisite
Lewisite (L) (A-243) is an organoarsenic compound. It was once manufactured in the U.S., Japan, Germany and the Soviet Union for use as a Chemical warfare, chemical weapon, acting as a vesicant (blister agent) and lung irritant. Although the substa ...
,
Sulfur mustard
Mustard gas or sulfur mustard is a chemical compound belonging to a family of cytotoxic and blister agents known as mustard agents. The name ''mustard gas'' is technically incorrect: the substance, when dispersed, is often not actually a gas, b ...
, Lewisite-mustard mix, and nerve agents:
Sarin
Sarin (NATO designation GB G-series, "B"">Nerve_agent#G-series.html" ;"title="hort for Nerve agent#G-series">G-series, "B" is an extremely toxic synthetic organophosphorus compound.Soman
Soman (or GD, EA 1210, Zoman, PFMP, A-255, systematic name: ''O''-pinacolyl methylphosphonofluoridate) is an extremely toxic chemical substance. It is a nerve agent, interfering with normal functioning of the mammalian nervous system by inhibiti ...
, and VX. Russia met its treaty obligations by destroying 1 percent of its chemical agents by the 2002 deadline set out by the Chemical Weapons Convention, but requested an extension on the deadlines of 2004 and 2007 due to technical, financial, and environmental challenges of chemical disposal. Since, Russia has received help from other countries such as Canada which donated C$100,000, plus a further C$100,000 already donated, to the Russian Chemical Weapons Destruction Program. This money will be used to complete work at Shchuch'ye and support the construction of a chemical weapons destruction facility at Kizner (Russia), where the destruction of nearly 5,700 tons of nerve agent, stored in approximately 2 million artillery shells and munitions, will be undertaken. Canadian funds are also being used for the operation of a Green Cross Public Outreach Office, to keep the civilian population informed on the progress made in chemical weapons destruction activities.
As of July 2011, Russia has destroyed 48 percent (18,241 tons) of its stockpile at destruction facilities located in Gorny (Saratov Oblast) and Kambarka (Udmurt Republic) – where operations have finished – and Schuch'ye (Kurgan Oblast), Maradykovsky (Kirov Oblast), Leonidovka (Penza Oblast) whilst installations are under construction in Pochep (Bryansk Oblast) and Kizner (Udmurt Republic). As August 2013, 76 percent (30,500 tons) were destroyed, and Russia leaves the Cooperative Threat Reduction (CTR) Program, which partially funded chemical weapons destruction.
In September 2017, OPCW announced that Russia had destroyed its entire chemical weapons stockpile.
United States
On November 25, 1969, President
Richard Nixon
Richard Milhous Nixon (January 9, 1913April 22, 1994) was the 37th president of the United States, serving from 1969 to 1974. A member of the Republican Party, he previously served as a representative and senator from California and was ...
Operation CHASE Operation CHASE (an acronym for "Cut Holes And Sink 'Em") was a United States Department of Defense program for the disposal of unwanted munitions at sea from May 1964 until the early 1970s.Kurak, Steve "Operation Chase" ''United States Naval Instit ...
, a
United States Department of Defense
The United States Department of Defense (DoD, USDOD or DOD) is an executive branch department of the federal government charged with coordinating and supervising all agencies and functions of the government directly related to national secu ...
program that aimed to dispose of chemical weapons by sinking ships laden with the weapons in the deep Atlantic. After the
Marine Protection, Research, and Sanctuaries Act of 1972
Marine Protection, Research and Sanctuaries Act of 1972 (MPRSA) or Ocean Dumping Act is one of several key environmental laws passed by the US Congress in 1972. The Act has two essential aims: to regulate intentional ocean disposal of materials, ...
, Operation Chase was scrapped and safer disposal methods for chemical weapons were researched, with the U.S. destroying several thousand tons of sulfur mustard by incineration at the Rocky Mountain Arsenal, and nearly 4,200 tons of nerve agent by chemical neutralisation at Tooele Army Depot.
The U.S. began stockpile reductions in the 1980s with the removal of outdated munitions and destroying its entire stock of 3-Quinuclidinyl benzilate (BZ or Agent 15) at the beginning of 1988. In June 1990 the
Johnston Atoll Chemical Agent Disposal System
Johnston Atoll Chemical Agent Disposal System (JACADS) was the U.S. Army's first chemical munitions disposal facility. It was located on Johnston Island, at Johnston Atoll and completed its mission and ceased operation in 2000.
Background
Prior ...
began destruction of chemical agents stored on the
Johnston Atoll
Johnston Atoll is an Unincorporated territories of the United States, unincorporated territory of the United States, currently administered by the United States Fish and Wildlife Service (USFWS). Johnston Atoll is a National Wildlife Refuge and ...
in the Pacific, seven years before the Chemical Weapons Treaty came into effect. In 1986 President Ronald Reagan made an agreement with the Chancellor, Helmut Kohl to remove the U.S. stockpile of chemical weapons from Germany. In 1990, as part of
Operation Steel Box
Operation Steel Box, also known as Operation Golden Python (German name for the transport in Germany: Aktion Lindwurm), was a 1990 joint U.S.-West German operation which moved over 100,000 U.S. chemical weapons from Germany to Johnston Atoll.
Ba ...
, two ships were loaded with over 100,000 shells containing
Sarin
Sarin (NATO designation GB G-series, "B"">Nerve_agent#G-series.html" ;"title="hort for Nerve agent#G-series">G-series, "B" is an extremely toxic synthetic organophosphorus compound.VX were taken from the U.S. Army weapons storage depots such as Miesau and then-classified FSTS (Forward Storage / Transportation Sites) and transported from Bremerhaven, Germany to Johnston Atoll in the Pacific, a 46-day nonstop journey.
In the 1980s, Congress, at the urging of the
Reagan administration
Ronald Reagan's tenure as the 40th president of the United States began with his first inauguration on January 20, 1981, and ended on January 20, 1989. Reagan, a Republican from California, took office following a landslide victory over D ...
, Congress provided funding for the manufacture of binary chemical weapons (sarin artillery shells) from 1987 until 1990, but this was halted after the U.S. and the
Soviet Union
The Soviet Union,. officially the Union of Soviet Socialist Republics. (USSR),. was a transcontinental country that spanned much of Eurasia from 1922 to 1991. A flagship communist state, it was nominally a federal union of fifteen national ...
entered into a bilateral agreement in June 1990. In the 1990 agreement, the U.S. and Soviet Union agreed to begin destroying their chemical weapons stockpiles before 1993 and to reduce them to no more than 5,000 agent tons each by the end of 2002. The agreement also provided for exchanges of data and inspections of sites to verify destruction.Andrew Glass Deal reached curbing chemical weapons, June 1, 1990 ''Politico'' (June 1, 2017). Following the
collapse of the Soviet Union
The dissolution of the Soviet Union, also negatively connoted as rus, Разва́л Сове́тского Сою́за, r=Razvál Sovétskogo Soyúza, ''Ruining of the Soviet Union''. was the process of internal disintegration within the Sov ...
, the U.S.'s
Nunn–Lugar Cooperative Threat Reduction
As the collapse of the Soviet Union appeared imminent, the United States and their NATO allies grew concerned of the risk of nuclear weapons held in the Republics of the Soviet Union, Soviet republics falling into enemy hands. The Cooperative Thr ...
program helped eliminate some of the chemical, biological and nuclear stockpiles of the
former Soviet Union
The post-Soviet states, also known as the former Soviet Union (FSU), the former Soviet Republics and in Russia as the near abroad (russian: links=no, ближнее зарубежье, blizhneye zarubezhye), are the 15 sovereign states that wer ...
.
The
United Nations
The United Nations (UN) is an intergovernmental organization whose stated purposes are to maintain international peace and international security, security, develop friendly relations among nations, achieve international cooperation, and be ...
Conference on Disarmament
The Conference on Disarmament (CD) is a multilateral disarmament forum established by the international community to negotiate arms control and disarmament agreements based at the Palais des Nations in Geneva. The Conference meets annually i ...
in
Geneva
Geneva ( ; french: Genève ) frp, Genèva ; german: link=no, Genf ; it, Ginevra ; rm, Genevra is the List of cities in Switzerland, second-most populous city in Switzerland (after Zürich) and the most populous city of Romandy, the French-speaki ...
in 1980 led to the development of the
Chemical Weapons Convention
The Chemical Weapons Convention (CWC), officially the Convention on the Prohibition of the Development, Production, Stockpiling and Use of Chemical Weapons and on their Destruction, is an arms control treaty administered by the Organisation for ...
(CWC), a
multilateral treaty
A multilateral treaty is a treaty to which two or more sovereign states are parties. Each party owes the same obligations to all other parties, except to the extent that they have stated reservation (law), reservations. Examples of multilateral tre ...
that prohibited the development, production, stockpiling, and use of chemical weapons, and required the elimination of existing stockpiles.Jonathan B. Tucker Case Study 4, U.S. Ratification of the Chemical Weapons Convention ''Case Studies Series'', Center for the Study of Weapons of Mass Destruction,
National Defense University
The National Defense University (NDU) is an institution of higher education funded by the United States Department of Defense, intended to facilitate high-level education, training, and professional development of national security leaders. As ...
(December 2011). The treaty expressly prohibited state parties from making reservations (unilateral caveats). During the Reagan administration and the George H. W. Bush administration, the U.S. participated in the negotiations toward the CWC. The CWC was concluded on September 3, 1992, and opened for signature on January 13, 1993. The U.S. became one of 87 original state parties to the CWC. President
Bill Clinton
William Jefferson Clinton ( né Blythe III; born August 19, 1946) is an American politician who served as the 42nd president of the United States from 1993 to 2001. He previously served as governor of Arkansas from 1979 to 1981 and agai ...
submitted it to the
U.S. Senate
The United States Senate is the upper chamber of the United States Congress, with the House of Representatives being the lower chamber. Together they compose the national bicameral legislature of the United States.
The composition and powe ...
for ratification on November 23, 1993. Ratification was blocked in the Senate for years, largely as a result of opposition from Senator
Jesse Helms
Jesse Alexander Helms Jr. (October 18, 1921 – July 4, 2008) was an American politician. A leader in the conservative movement, he served as a senator from North Carolina from 1973 to 2003. As chairman of the Senate Foreign Relations Committee ...
, the chairman of the
Senate Foreign Relations Committee
The United States Senate Committee on Foreign Relations is a standing committee of the U.S. Senate charged with leading foreign-policy legislation and debate in the Senate. It is generally responsible for overseeing and funding foreign aid p ...
. On April 24, 1997, the Senate gave its consent to ratification of the CWC by a 74–26 vote (satisfying the required two-thirds majority). The U.S. deposited its instrument of ratification at the United Nations on April 25, 1997, a few days before the CWC entered into force. The U.S. ratification allowed the U.S. to participate in the
Organisation for the Prohibition of Chemical Weapons
The Organisation for the Prohibition of Chemical Weapons (OPCW) is an intergovernmental organisation and the implementing body for the Chemical Weapons Convention (CWC), which entered into force on 29 April 1997. The OPCW, with its 193 member ...
, the organization based in
The Hague
The Hague ( ; nl, Den Haag or ) is a city and municipality of the Netherlands, situated on the west coast facing the North Sea. The Hague is the country's administrative centre and its seat of government, and while the official capital of ...
that oversees implementation of the CWC.
Upon U.S. ratification of the CWC, the U.S. declared a total of 29,918 tons of chemical weapons, and committed to destroying all of the U.S.'s chemical weapons and bulk agent.Owen LeGrone U.S. Begins Final CW Destruction ''Arms Controls Today'', Arms Control Association (July/August 2019). The U.S. was one of eight states to declare a stockpile of chemical weapons and to commit to their safe elimination.US Chemical Weapons Stockpile Elimination: Progress Update Arms Control Association (September 23, 2021). The U.S. committed in the CWC to destroy its entire chemical arsenal within 10 years of the entry into force (''i.e.'', by April 29, 2007), However, at a 2012 conference, Centers for Disease Control and Prevention (January 6, 2014). the parties to the CWC parties agreed to extend the U.S. deadline to 2023. By 2012, stockpiles had been eliminated at seven of the U.S.'s nine chemical weapons depots and 89.75% of the 1997 stockpile was destroyed.Army Agency Completes Mission to Destroy Chemical Weapons , USCMA, January 21, 2012 The depots were the Aberdeen Chemical Agent Disposal Facility, Anniston Chemical Disposal Facility,
Johnston Atoll
Johnston Atoll is an Unincorporated territories of the United States, unincorporated territory of the United States, currently administered by the United States Fish and Wildlife Service (USFWS). Johnston Atoll is a National Wildlife Refuge and ...
,
Newport Chemical Agent Disposal Facility
The Newport Chemical Depot, previously known as the Wabash River Ordnance Works and the Newport Army Ammunition Plant, was a bulk chemical storage and destruction facility that was operated by the United States Army. It is located near Newpor ...
Deseret Chemical Depot
The Deseret Chemical Depot () was a U.S. Army chemical weapon storage area located in Utah, 60 miles (100 km) southwest of Salt Lake City. It is related to the Tooele Chemical Agent Disposal Facility.
History
The area was used to store c ...
. The U.S. closed each site after the completion of stockpile destruction. In 2019, the U.S. began to eliminate its chemical-weapon stockpile at the last of the nine U.S. chemical weapons storage facilities: the
Blue Grass Army Depot
Blue Grass Army Depot (BGAD) is a U.S. Army Joint Munitions Command storage facility for conventional munitions and chemical weapons. The facility is located in east central Kentucky, southeast of the cities of Lexington and Richmond, Kentucky. ...
in Kentucky. By May 2021, the U.S. destroyed all of its Category 2 and Category 3 chemical weapons and 96.52% of its Category 1 chemical weapons. The U.S. is scheduled to complete the elimination of all its chemical weapons by the September 2023 deadline.
The U.S. has maintained a " calculated ambiguity" policy that warns potential adversaries that a chemical or biological attack against the U.S. or its allies will prompt a "overwhelming and devastating" response. The policy deliberately leaves open the question of whether the U.S. would respond to a chemical attempt with
nuclear
Nuclear may refer to:
Physics
Relating to the nucleus of the atom:
* Nuclear engineering
*Nuclear physics
*Nuclear power
*Nuclear reactor
*Nuclear weapon
*Nuclear medicine
*Radiation therapy
*Nuclear warfare
Mathematics
*Nuclear space
*Nuclear ...
retaliation
Revenge is committing a harmful action against a person or group in response to a grievance, be it real or perceived. Francis Bacon described revenge as a kind of "wild justice" that "does... offend the law ndputteth the law out of office." Pr ...
. Commentators have noted that this policy gives policymakers more flexibility, at the possible cost of decreased strategic unpreparedness.
Anti-agriculture
Herbicidal warfare
Although herbicidal warfare use
chemical substance
A chemical substance is a form of matter having constant chemical composition and characteristic properties. Some references add that chemical substance cannot be separated into its constituent elements by physical separation methods, i.e., wi ...
s, its main purpose is to disrupt agricultural food production and/or to destroy plants which provide cover or concealment to the enemy.
The use of
herbicide
Herbicides (, ), also commonly known as weedkillers, are substances used to control undesired plants, also known as weeds.EPA. February 201Pesticides Industry. Sales and Usage 2006 and 2007: Market Estimates. Summary in press releasMain page fo ...
s by the
U.S. military
The United States Armed Forces are the military forces of the United States. The armed forces consists of six service branches: the Army, Marine Corps, Navy, Air Force, Space Force, and Coast Guard. The president of the United States is the ...
during the
Vietnam War
The Vietnam War (also known by #Names, other names) was a conflict in Vietnam, Laos, and Cambodia from 1 November 1955 to the fall of Saigon on 30 April 1975. It was the second of the Indochina Wars and was officially fought between North Vie ...
has left tangible, long-term impacts upon the Vietnamese people and U.S. veterans of the war. The government of Vietnam says that around 24% of the forests of Southern Vietnam were defoliated and up to four million people in Vietnam were exposed to Agent Orange. They state that as many as three million people have developed illness because of Agent Orange while the Red Cross of Vietnam estimates that up to one million people were disabled or have health problems associated with Agent Orange. The United States government has described these figures as unreliable.
During the war, the U.S. fought the North Vietnamese and their allies in
Laos
Laos (, ''Lāo'' )), officially the Lao People's Democratic Republic ( Lao: ສາທາລະນະລັດ ປະຊາທິປະໄຕ ປະຊາຊົນລາວ, French: République démocratique populaire lao), is a socialist ...
and
Cambodia
Cambodia (; also Kampuchea ; km, កម្ពុជា, UNGEGN: ), officially the Kingdom of Cambodia, is a country located in the southern portion of the Indochinese Peninsula in Southeast Asia, spanning an area of , bordered by Thailand t ...
Mau Mau Uprising
The Mau Mau rebellion (1952–1960), also known as the Mau Mau uprising, Mau Mau revolt or Kenya Emergency, was a war in the British Kenya Colony (1920–1963) between the Kenya Land and Freedom Army (KLFA), also known as the ''Mau Mau'', an ...
in 1952, the poisonous
latex
Latex is an emulsion (stable dispersion) of polymer microparticles in water. Latexes are found in nature, but synthetic latexes are common as well.
In nature, latex is found as a milky fluid found in 10% of all flowering plants (angiosperms ...
Ali Hassan al-Majid
Ali Hassan Abd al-Majid al-Tikriti ( ar, علي حسن عبد المجيد التكريت, ʿAlī Ḥasan ʿAbd al-Majīd al-Tikrītī; 30 November 1941 – 25 January 2010), nicknamed Chemical Ali ( ar, علي الكيمياوي, ʿAlī al-Kīm ...
*
Area denial weapon
An area denial weapon is a defensive device used to prevent an adversary from occupying or traversing an area of land, sea or air. The specific method used does not have to be totally effective in preventing passage (and sometimes is not) as lo ...
Gas chamber
A gas chamber is an apparatus for killing humans or other animals with gas, consisting of a sealed chamber into which a poisonous or asphyxiant gas is introduced. Poisonous agents used include hydrogen cyanide and carbon monoxide.
Histor ...
*
List of CBRN warfare forces
Many countries around the world maintain military units that are specifically trained to cope with CBRN (Chemical, Biological, Radiological, Nuclear) threats. Beside this specialized units, most modern armed forces undergo generalized basic CBRN s ...
*
List of chemical warfare agents
A ''chemical weapon agent (CWA), or chemical warfare agent,'' is a chemical substance whose toxin, toxic chemical property, properties are meant to kill, injure or incapacitate Human, human beings. About 70 different chemicals have been used or ...
*
List of highly toxic gases
Many gases have toxic properties, which are often assessed using the LC50 (median lethal dose) measure. In the United States, many of these gases have been assigned an NFPA 704 health rating of 4 (may be fatal) or 3 (may cause serious or perman ...
*
Ronald Maddison
Leading Aircraftman Ronald George Maddison (23 January 1933 – 6 May 1953) was a twenty-year-old Royal Air Force engineer who was unlawfully killed as the result of exposure to nerve agents while acting as a voluntary test subject at Porton Dow ...
Saint Julien Memorial
The St. Julien Memorial, also known as The Brooding Soldier, is a Canadian war memorial and small commemorative park located in the village of Saint-Julien, Langemark ( vls, Sint-Juliaan), Belgium. The memorial commemorates the Canadian First Di ...
Stink bomb
A stink bomb, sometimes called a stinkpot, is a device designed to create an unpleasant smell. They range in effectiveness from being used as simple pranks to military grade malodorants or riot control chemical agents.
History
A stink bomb ...
*
United States Army Medical Research Institute of Chemical Defense
The United States Army Medical Research Institute of Chemical Defense (USAMRICD) is a military medical research institute located at Aberdeen Proving Ground, Maryland, US. It is the leading science and technology laboratory of the Department of Def ...
* Leo P. Brophy and George J. B. Fisher; ''The Chemical Warfare Service: Organizing for War''
Office of the Chief of Military History
The United States Army Center of Military History (CMH) is a directorate within the United States Army Training and Doctrine Command. The Institute of Heraldry remains within the Office of the Administrative Assistant to the Secretary of the Arm ...
, 1959; L. P. Brophy, W. D. Miles and C. C. Cochrane, ''The Chemical Warfare Service: From Laboratory to Field'' (1959); and B. E. Kleber and D. Birdsell, ''The Chemical Warfare Service in Combat'' (1966). official US history;
* Glenn Cross, ''Dirty War: Rhodesia and Chemical Biological Warfare, 1975–1980'', Helion & Company, 2017
* Gordon M. Burck and Charles C. Flowerree; ''International Handbook on Chemical Weapons Proliferation'' 1991
* L. F. Haber. ''The Poisonous Cloud: Chemical Warfare in the First World War'' Oxford University Press: 1986
* James W. Hammond Jr; ''Poison Gas: The Myths Versus Reality'' Greenwood Press, 1999
* Jiri Janata Role of Analytical Chemistry in Defense Strategies Against Chemical and Biological Attack ''Annual Review of Analytical Chemistry,'' 2009
* Ishmael Jones, ''The Human Factor: Inside the CIA's Dysfunctional Intelligence Culture'', Encounter Books, New York 2008, revised 2010, . WMD espionage.
* Benoit Morel and Kyle Olson; ''Shadows and Substance: The Chemical Weapons Convention'' Westview Press, 1993
* Adrienne Mayor, "Greek Fire, Poison Arrows & Scorpion Bombs: Biological and Chemical Warfare in the Ancient World" Overlook-Duckworth, 2003, rev ed with new Introduction 2008
* Geoff Plunkett, Chemical Warfare in Australia: Australia's Involvement In Chemical Warfare 1914 – Today, (2nd Edition), 2013. '. Leech Cup Books. A volume in the Army Military History Series published in association with the Army History Unit.
*
Jonathan B. Tucker
Jonathan B. Tucker (August 2, 1954 – July 31, 2011) was a United States chemical weapons, chemical and biological weapons expert.
Early life and education
Tucker was born on August 2, 1954 in Boston, Massachusetts to Deborah Tucker. Tucker ear ...
. ''Chemical Warfare from World War I to Al-Qaeda'' (2006)
Organisation for the Prohibition of Chemical Weapons
The Organisation for the Prohibition of Chemical Weapons (OPCW) is an intergovernmental organisation and the implementing body for the Chemical Weapons Convention (CWC), which entered into force on 29 April 1997. The OPCW, with its 193 member ...
international humanitarian law
International humanitarian law (IHL), also referred to as the laws of armed conflict, is the law that regulates the conduct of war (''jus in bello''). It is a branch of international law that seeks to limit the effects of armed conflict by prot ...
conducted by the
International Committee of the Red Cross
The International Committee of the Red Cross (ICRC; french: Comité international de la Croix-Rouge) is a humanitarian organization which is based in Geneva, Switzerland, and it is also a three-time Nobel Prize Laureate. State parties (signato ...
(ICRC) and originally published by
Cambridge University Press
Cambridge University Press is the university press of the University of Cambridge. Granted letters patent by Henry VIII of England, King Henry VIII in 1534, it is the oldest university press
A university press is an academic publishing hou ...
U.S. National Library of Medicine
The United States National Library of Medicine (NLM), operated by the United States federal government, is the world's largest medical library.
Located in Bethesda, Maryland, the NLM is an institute within the National Institutes of Health. Its ...