Firestain is a layer of

oxides An oxide () is a chemical compound that contains at least one oxygen atom and one other element in its chemical formula. "Oxide" itself is the dianion of oxygen, an O2– (molecular) ion. with oxygen in the oxidation state of −2. Most of the E ...

that is visible on the surface of objects made of metal alloys containing copper when the object is heated, as by a jeweler heating a ring to apply

solder Solder (; NA: ) is a fusible metal alloy used to create a permanent bond between metal workpieces. Solder is melted in order to wet the parts of the joint, where it adheres to and connects the pieces after cooling. Metals or alloys suitable ...

during a repair. On copper-containing alloys of gold or of

silver Silver is a chemical element with the Symbol (chemistry), symbol Ag (from the Latin ', derived from the Proto-Indo-European wikt:Reconstruction:Proto-Indo-European/h₂erǵ-, ''h₂erǵ'': "shiny" or "white") and atomic number 47. A soft, whi ...

(such as

sterling silver Sterling silver is an alloy of silver containing 92.5% by weight of silver and 7.5% by weight of other metals, usually copper. The sterling silver standard has a minimum millesimal fineness of 925. ''Fine silver'', which is 99.9% pure silver, is r ...

), it presents as a red or purple stain. This is because at high temperatures,

oxygen Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as wel ...

mixes with the copper to form

cuprous oxide Copper(I) oxide or cuprous oxide is the inorganic compound with the formula Cu2O. It is one of the principal oxides of copper, the other being or copper(II) oxide or cupric oxide (CuO). This red-coloured solid is a component of some antifouling ...

and then

cupric oxide Copper(II) oxide or cupric oxide is an inorganic compound with the formula CuO. A black solid, it is one of the two stable oxides of copper, the other being Cu2O or copper(I) oxide (cuprous oxide). As a mineral, it is known as tenorite. It i ...

, both of which disrupt the bright polished surface of the finished piece. It is sometimes referred to incorrectly as 'Firescale'; 'Firescale' is a flaky deposit that can occur on the surface of non ferrous metals when heated, on ferrous metals this is known as

Mill scale Mill scale, often shortened to just scale, is the flaky surface of hot rolled steel, consisting of the mixed iron oxides iron(II) oxide (FeO), iron(III) oxide (), and iron(II,III) oxide (, magnetite). Mill scale is formed on the outer surfaces o ...

. Attempts to reduce the problem of firestain include preventative and curative ones. Firestain can be largely prevented by heating the object in an atmosphere in which the oxygen has been replaced with another combustive gas such as

hydrogen Hydrogen is the chemical element with the symbol H and atomic number 1. Hydrogen is the lightest element. At standard conditions hydrogen is a gas of diatomic molecules having the formula . It is colorless, odorless, tasteless, non-toxic, an ...

ammonia Ammonia is an inorganic compound of nitrogen and hydrogen with the formula . A stable binary hydride, and the simplest pnictogen hydride, ammonia is a colourless gas with a distinct pungent smell. Biologically, it is a common nitrogenous was ...

. On the curative side, firestain can sometimes be removed by polishing, sanding, grinding, filing, wire brushing, and the like. As the layer firestain is often not very deep, this approach, with sufficient effort and time, may be able to remove it. However, this inevitably results in a loss of material to the piece, and will cause any fine details to the piece to be lost. However, it does not involve the use of any special gasses or changes to the heating atmosphere around the piece. As another cure, objects can also be "bombed" or electrostripped. This involves placing them in a bath of a usually

cyanide Cyanide is a naturally occurring, rapidly acting, toxic chemical that can exist in many different forms. In chemistry, a cyanide () is a chemical compound that contains a functional group. This group, known as the cyano group, consists of ...

-based solution (sometimes

nitric acid Nitric acid is the inorganic compound with the formula . It is a highly corrosive mineral acid. The compound is colorless, but older samples tend to be yellow cast due to decomposition into oxides of nitrogen. Most commercially available nitri ...

may be used instead, as well as other solutions) and applying a high-density electric current arranged so that the work piece functions as an

anode An anode is an electrode of a polarized electrical device through which conventional current enters the device. This contrasts with a cathode, an electrode of the device through which conventional current leaves the device. A common mnemonic is ...

. Other approaches include

electroplating Electroplating, also known as electrochemical deposition or electrodeposition, is a process for producing a metal coating on a solid substrate through the reduction of cations of that metal by means of a direct electric current. The part to be ...

the object with a layer of the principal metal of the alloy, as well as, for sterling and similar grades of silver,

depletion silvering Depletion may refer to: Environment * Resource depletion, decline of resources * Gas depletion, decline of oil supply * Nutrient depletion, loss of nutrients in a habitat * Oil depletion, decline of oil supply * Overdrafting, extracting groundwate ...

the piece, and for gold-copper alloys, a

sodium dichromate Sodium dichromate is the inorganic compound with the formula Na2 Cr2 O7. However, the salt is usually handled as its dihydrate Na2Cr2O7·2 H2O. Virtually all chromium ore is processed via conversion to sodium dichromate and virtually all compound ...

pickle solution with a low percentage of

sulfuric acid Sulfuric acid (American spelling and the preferred IUPAC name) or sulphuric acid ( Commonwealth spelling), known in antiquity as oil of vitriol, is a mineral acid composed of the elements sulfur, oxygen and hydrogen, with the molecular formu ...

has been occasionally found effective. These approaches, however, are temporary fixes in that all they do is cover up the firestain: over time, it will almost always reemerge through the thin layer of overlying metal deposit. The only long-term techniques to prevent the appearance of firestain are through its time-consuming physical removal or preventing its formation in the first place (which is often expensive and requires specialized equipment/ gasses/ tools).

References

Jewellery making Silversmithing {{Metalworking-stub

See also

References