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Carmine ()also called cochineal (when it is extracted from the cochineal insect), cochineal extract, crimson
lake A lake is an area filled with water, localized in a basin, surrounded by land, and distinct from any river or other outlet that serves to feed or drain the lake. Lakes lie on land and are not part of the ocean, although, like the much large ...
, or carmine lake is a
pigment A pigment is a colored material that is completely or nearly insoluble in water. In contrast, dyes are typically soluble, at least at some stage in their use. Generally dyes are often organic compounds whereas pigments are often inorganic compo ...
of a bright-
red Red is the color at the long wavelength end of the visible spectrum of light, next to orange and opposite violet. It has a dominant wavelength of approximately 625–740 nanometres. It is a primary color in the RGB color model and a secondar ...
color obtained from the aluminium complex derived from
carminic acid Carminic acid (C22H20O13) is a red glucosidal hydroxyanthrapurin that occurs naturally in some scale insects, such as the cochineal, Armenian cochineal, and Polish cochineal. The insects produce the acid as a deterrent to predators. An aluminu ...
. Specific code names for the pigment include natural red 4, C.I. 75470, or
E120 E120 most often refers to: * Carmine, a food colourant with the E number E120 * Unbinilium, also known as element 120 or eka-radium, a predicted chemical element not yet observed It may also refer to: * E120 bomblet, a U.S. Cold War biological clu ...
. ''Carmine'' is also a general term for a particularly deep-red color.


Etymology

The English word "carmine" is derived from the French word ''carmin'' (12th century), from
Medieval Latin Medieval Latin was the form of Literary Latin used in Roman Catholic Western Europe during the Middle Ages. In this region it served as the primary written language, though local languages were also written to varying degrees. Latin functioned ...
''carminium'', from
Persian Persian may refer to: * People and things from Iran, historically called ''Persia'' in the English language ** Persians, the majority ethnic group in Iran, not to be conflated with the Iranic peoples ** Persian language, an Iranian language of the ...
''qirmiz'' ("crimson"), which itself derives from
Middle Persian Middle Persian or Pahlavi, also known by its endonym Pārsīk or Pārsīg () in its later form, is a Western Middle Iranian language which became the literary language of the Sasanian Empire. For some time after the Sasanian collapse, Middle Per ...
''carmir'' ("red, crimson"). The Persian term ''carmir'' is likely cognate with
Sanskrit Sanskrit (; attributively , ; nominally , , ) is a classical language belonging to the Indo-Aryan branch of the Indo-European languages. It arose in South Asia after its predecessor languages had diffused there from the northwest in the late ...
''krimiga'' ("insect-produced"), from ''krmi'' ("worm, insect"). The Persian word for "worm, insect" is ''kirm'', and in
Iran Iran, officially the Islamic Republic of Iran, and also called Persia, is a country located in Western Asia. It is bordered by Iraq and Turkey to the west, by Azerbaijan and Armenia to the northwest, by the Caspian Sea and Turkmeni ...
(
Persia Iran, officially the Islamic Republic of Iran, and also called Persia, is a country located in Western Asia. It is bordered by Iraq and Turkey to the west, by Azerbaijan and Armenia to the northwest, by the Caspian Sea and Turkmeni ...
) the red colorant carmine was extracted from the bodies of dead female insects such as ''
Kermes vermilio ''Kermes vermilio'' is a species of '' Kermes'' so which feeds on trees. Some of the species are used by humans to make vermilion; though an at-similar-time-of-discovery mineral form in many cultures is cinnabar (HgS, Mercury Sulphide, crystalli ...
'' and
cochineal The cochineal ( , ; ''Dactylopius coccus'') is a scale insect in the suborder Sternorrhyncha, from which the natural dye carmine is derived. A primarily sessility (motility), sessile parasitism, parasite native to tropical and subtropical Sout ...
. The form of the term may also have been influenced in Latin by ''minium'' ("red lead, cinnabar"), said to be of Iberian origin. The word "carmine" has been used as a color name as early as 1799. It is a popular food color, used in
yogurt Yogurt (; , from tr, yoğurt, also spelled yoghurt, yogourt or yoghourt) is a food produced by bacterial Fermentation (food), fermentation of milk. The bacteria used to make yogurt are known as ''yogurt cultures''. Fermentation of sugars in t ...
,
candy Candy, also called sweets (British English) or lollies (Australian English Australian English (AusE, AusEng, AuE, AuEng, en-AU) is the set of varieties of the English language native to Australia. It is the country's common language an ...
,
gelatin Gelatin or gelatine (from la, gelatus meaning "stiff" or "frozen") is a translucent, colorless, flavorless food ingredient, commonly derived from collagen taken from animal body parts. It is brittle when dry and rubbery when moist. It may also ...
,
meat Meat is animal flesh that is eaten as food. Humans have hunted, farmed, and scavenged animals for meat since prehistoric times. The establishment of settlements in the Neolithic Revolution allowed the domestication of animals such as chic ...
, and beverages including fruit juices.


Production

The pigment is produced from
carminic acid Carminic acid (C22H20O13) is a red glucosidal hydroxyanthrapurin that occurs naturally in some scale insects, such as the cochineal, Armenian cochineal, and Polish cochineal. The insects produce the acid as a deterrent to predators. An aluminu ...
, which is extracted from some
scale insect Scale insects are small insects of the order Hemiptera, suborder Sternorrhyncha. Of dramatically variable appearance and extreme sexual dimorphism, they comprise the infraorder Coccomorpha which is considered a more convenient grouping than the ...
s such as the
cochineal The cochineal ( , ; ''Dactylopius coccus'') is a scale insect in the suborder Sternorrhyncha, from which the natural dye carmine is derived. A primarily sessility (motility), sessile parasitism, parasite native to tropical and subtropical Sout ...
scale (''Dactylopius coccus''), and certain ''
Porphyrophora The scale insect genus ''Porphyrophora'' is a large group in the family Margarodidae, which includes the insects Polish cochineal and Armenian cochineal formerly used in dye A dye is a colored substance that chemically bonds to the substra ...
'' species (
Armenian cochineal The Armenian cochineal (''Porphyrophora hamelii''), also known as the Ararat cochineal or Ararat scale, is a scale insect indigenous to the Ararat plain and Aras (Araks) River valley in the Armenian Highlands and in Turkey. It was formerly u ...
and Polish cochineal). Carmine is a colorant used in the manufacture of artificial flowers, paints,
crimson Crimson is a rich, deep red color, inclining to purple. It originally meant the color of the kermes dye produced from a scale insect, ''Kermes vermilio'', but the name is now sometimes also used as a generic term for slightly bluish-red colo ...
ink, rouge and other cosmetics, and some medications. To prepare carmine, the powdered scale insect bodies are boiled in an
ammonia Ammonia is an inorganic compound of nitrogen and hydrogen with the formula . A stable binary hydride, and the simplest pnictogen hydride, ammonia is a colourless gas with a distinct pungent smell. Biologically, it is a common nitrogenous was ...
or
sodium carbonate Sodium carbonate, , (also known as washing soda, soda ash and soda crystals) is the inorganic compound with the formula Na2CO3 and its various hydrates. All forms are white, odourless, water-soluble salts that yield moderately alkaline solutions ...
solution. After separating the insoluble matter, the extract is treated with
alum An alum () is a type of chemical compound, usually a hydrated double salt, double sulfate salt (chemistry), salt of aluminium with the general chemical formula, formula , where is a valence (chemistry), monovalent cation such as potassium or a ...
to precipitate the red solid. This precipitate is called "carmine lake" or "crimson lake". Purity of color is ensured by the absence of
iron Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in f ...
. Stannous chloride,
citric acid Citric acid is an organic compound with the chemical formula HOC(CO2H)(CH2CO2H)2. It is a colorless weak organic acid. It occurs naturally in citrus fruits. In biochemistry, it is an intermediate in the citric acid cycle, which occurs in t ...
,
borax Borax is a salt (ionic compound), a hydrated borate of sodium, with chemical formula often written . It is a colorless crystalline solid, that dissolves in water to make a basic solution. It is commonly available in powder or granular form, ...
, or
gelatin Gelatin or gelatine (from la, gelatus meaning "stiff" or "frozen") is a translucent, colorless, flavorless food ingredient, commonly derived from collagen taken from animal body parts. It is brittle when dry and rubbery when moist. It may also ...
may be added to modify the precipitation. The traditional crimson color is affected not only by carminic acid but also by choice of its chelating metal salt ion. For shades of purple,
lime Lime commonly refers to: * Lime (fruit), a green citrus fruit * Lime (material), inorganic materials containing calcium, usually calcium oxide or calcium hydroxide * Lime (color), a color between yellow and green Lime may also refer to: Botany ...
is added to the alum. File:Cochinel Zapotec nests.jpg, Zapotec nests on '' Opuntia ficus-indica'' host
cacti A cactus (, or less commonly, cactus) is a member of the plant family Cactaceae, a family comprising about 127 genera with some 1750 known species of the order Caryophyllales. The word ''cactus'' derives, through Latin, from the Ancient Greek ...
File:Pseudorhabdosynochus morrhua.jpg, upUse of carmine as a
staining Staining is a technique used to enhance contrast in samples, generally at the microscopic level. Stains and dyes are frequently used in histology (microscopic study of biological tissues), in cytology (microscopic study of cells), and in the ...
agent in
histology Histology, also known as microscopic anatomy or microanatomy, is the branch of biology which studies the microscopic anatomy of biological tissues. Histology is the microscopic counterpart to gross anatomy, which looks at larger structures vis ...
(here on a
flatworm The flatworms, flat worms, Platyhelminthes, or platyhelminths (from the Greek πλατύ, ''platy'', meaning "flat" and ἕλμινς (root: ἑλμινθ-), ''helminth-'', meaning "worm") are a phylum of relatively simple bilaterian, unsegment ...
)


Properties and uses

As confirmed by reflectance spectroscopy, carmine reflects mostly red light, i.e., wavelengths longer than about 603  nm. Carmine can be used in
histology Histology, also known as microscopic anatomy or microanatomy, is the branch of biology which studies the microscopic anatomy of biological tissues. Histology is the microscopic counterpart to gross anatomy, which looks at larger structures vis ...
, as ''Best's carmine'' to stain
glycogen Glycogen is a multibranched polysaccharide of glucose that serves as a form of energy storage in animals, fungi, and bacteria. The polysaccharide structure represents the main storage form of glucose in the body. Glycogen functions as one o ...
, ''mucicarmine'' to stain acidic mucopolysaccharides, and ''carmalum'' to stain cell nuclei. In these applications, it is applied together with a
mordant A mordant or dye fixative is a substance used to set (i.e. bind) dyes on fabrics by forming a coordination complex with the dye, which then attaches to the fabric (or tissue). It may be used for dyeing fabrics or for intensifying stains in ...
, usually an Al(III) salt. Carmine was used in dyeing textiles and in painting since antiquity. It is not very stable in oil paint, and its use ceased after new and better red pigments became available. Jacopo Tintoretto used carmine in several of his paintings, including ''Portrait of Vincenzo Morosini'' and ''Christ Washing the Feet of the Disciples''.


Regulations for use in foods


United States

In January 2006, the United States Food and Drug Administration (FDA) evaluated a proposal that would require food products containing carmine to list it by name on the ingredient label. It was also announced that the FDA will separately review the ingredient labels of prescription drugs that contain colorings derived from carmine. A request from the Center for Science in the Public Interest urging the FDA to require ingredient labels to explicitly state that carmine is derived from insects and may cause severe allergic reactions and anaphylactic shock was declined by the FDA. Food industries were aggressively opposed to the idea of writing "insect-based" on the label, and the FDA agreed to allow "cochineal extract" or "carmine".


European Union

In the
European Union The European Union (EU) is a supranational political and economic union of member states that are located primarily in Europe. The union has a total area of and an estimated total population of about 447million. The EU has often been des ...
(EU), the use of carmine in foods is regulated under the
European Commission The European Commission (EC) is the executive of the European Union (EU). It operates as a cabinet government, with 27 members of the Commission (informally known as "Commissioners") headed by a President. It includes an administrative body o ...
's directives governing food additives in general and food dyes in particular and listed under the names ''Cochineal'', ''Carminic acid'', ''Carmines'' and ''Natural Red 4'' as additive E 120 in the list of EU-approved food additives. The directive governing food dyes approves the use of carmine for certain groups of foods only and specifies a maximum amount which is permitted or restricts it to the
quantum satis Quantum satis (abbreviation q.s. or Q.S.) is a Latin term meaning the amount which is enough. It has its origins as a quantity specification in medicine and pharmacology, where a similar term ''quantum sufficit'' ("as much as is sufficient") has b ...
. The EU-Directive 2000/13/EC on food labeling mandates that carmines (like all food additives) must be included in the list of ingredients of a food product with its additive category and listed name or additive number, that is either as ''Food colour carmines'' or as ''Food colour E 120'' in the local language(s) of the market(s) the product is sold in. , EFSA has changed the way they allow use of Carmine E120 for pharmaceutical products. The EFSA had raised concerns over the increasing number of allergic reactions to carmine derived from insects (E120.360), when used within the '' British Pharmacopoeia''. Pharmaceutical products which had previously contained insect-derived carmine, have been replaced with a synthesized version of the food colorant. Internal studies have shown that the new formulations of popular anti-nausea and weight-gain liquid medication had a significantly lower risk in terms of allergic reactions. The new formulation is known to be of plant origin, using
calcium oxide Calcium oxide (CaO), commonly known as quicklime or burnt lime, is a widely used chemical compound. It is a white, Caustic (substance), caustic, alkaline, crystalline solid at room temperature. The broadly used term "''lime (material), lime''" co ...
to gauge color depth.


References

; Attribution *


See also

*
Red pigments Red pigments are materials, usually made from minerals, used to create the red colors in painting and other arts. The color of red and other pigments is determined by the way it absorbs certain parts of the spectrum of visible light and reflects ...


Further reading

* *


External links


Carmine as pigment in painting
at ColourLex {{Authority control Animal dyes Food colorings Insect products Biological pigments Organic pigments Staining dyes Polyketides