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Coal is a combustible black or brownish-black sedimentary rock, formed as
rock strata In geology and related fields, a stratum ( : strata) is a layer of rock or sediment characterized by certain lithologic properties or attributes that distinguish it from adjacent layers from which it is separated by visible surfaces known as ei ...
called coal seams. Coal is mostly carbon with variable amounts of other
elements Element or elements may refer to: Science * Chemical element, a pure substance of one type of atom * Heating element, a device that generates heat by electrical resistance * Orbital elements, parameters required to identify a specific orbit of ...
, chiefly hydrogen,
sulfur Sulfur (or sulphur in British English) is a chemical element with the symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with a chemical formula ...
, oxygen, and nitrogen. Coal is formed when dead
plant matter Organic matter, organic material, or natural organic matter refers to the large source of carbon-based compounds found within natural and engineered, terrestrial, and aquatic environments. It is matter composed of organic compounds that have c ...
decays into peat and is converted into coal by the heat and pressure of deep burial over millions of years. Vast deposits of coal originate in former wetlands called coal forests that covered much of the Earth's tropical land areas during the late
Carboniferous The Carboniferous ( ) is a geologic period and system of the Paleozoic that spans 60 million years from the end of the Devonian Period million years ago ( Mya), to the beginning of the Permian Period, million years ago. The name ''Carbonifero ...
(
Pennsylvanian Pennsylvanian may refer to: * A person or thing from Pennsylvania * Pennsylvanian (geology) The Pennsylvanian ( , also known as Upper Carboniferous or Late Carboniferous) is, in the International Commission on Stratigraphy, ICS geologic timesca ...
) and Permian times. Many significant coal deposits are younger than this and originate from the Mesozoic and
Cenozoic The Cenozoic ( ; ) is Earth's current geological era, representing the last 66million years of Earth's history. It is characterised by the dominance of mammals, birds and flowering plants, a cooling and drying climate, and the current configura ...
eras. Coal is used primarily as a fuel. While coal has been known and used for thousands of years, its usage was limited until the Industrial Revolution. With the invention of the
steam engine A steam engine is a heat engine that performs mechanical work using steam as its working fluid. The steam engine uses the force produced by steam pressure to push a piston back and forth inside a cylinder. This pushing force can be trans ...
, coal consumption increased. In 2020, coal supplied about a quarter of the world's primary energy and over a third of its electricity. Some iron and
steel Steel is an alloy made up of iron with added carbon to improve its strength and fracture resistance compared to other forms of iron. Many other elements may be present or added. Stainless steels that are corrosion- and oxidation-resistant ty ...
-making and other industrial processes burn coal. The extraction and use of coal causes premature death and illness. The use of coal damages the environment, and it is the largest
anthropogenic Anthropogenic ("human" + "generating") is an adjective that may refer to: * Anthropogeny, the study of the origins of humanity Counterintuitively, anthropogenic may also refer to things that have been generated by humans, as follows: * Human im ...
source of carbon dioxide contributing to climate change. Fourteen billion tonnes of carbon dioxide was emitted by burning coal in 2020, which is 40% of the total
fossil fuel A fossil fuel is a hydrocarbon-containing material formed naturally in the Earth's crust from the remains of dead plants and animals that is extracted and burned as a fuel. The main fossil fuels are coal, oil, and natural gas. Fossil fuels m ...
emissions and over 25% of total global greenhouse gas emissions. As part of worldwide
energy transition The energy transition is the process of downshifting fossil fuels and re-developing whole systems to operate on low carbon energy sources. More generally, an energy transition is a significant structural change in an energy system regarding ...
, many countries have reduced or eliminated their use of coal power. The United Nations Secretary General asked governments to stop building new coal plants by 2020. Global coal use peaked in 2013. To meet the
Paris Agreement The Paris Agreement (french: Accord de Paris), often referred to as the Paris Accords or the Paris Climate Accords, is an international treaty on climate change. Adopted in 2015, the agreement covers climate change mitigation, Climate change a ...
target of keeping global warming below coal use needs to halve from 2020 to 2030, and phasing out coal was agreed upon in the
Glasgow Climate Pact The Glasgow Climate Pact is an agreement reached at the 2021 United Nations Climate Change Conference (COP26). The pact is the first climate agreement explicitly planning to reduce unabated coal usage. A pledge to "phase out" coal was change ...
. The largest consumer and importer of coal in 2020 was
China China, officially the People's Republic of China (PRC), is a country in East Asia. It is the world's most populous country, with a population exceeding 1.4 billion, slightly ahead of India. China spans the equivalent of five time zones and ...
, which accounts for almost half the world's annual coal production, followed by India with about a tenth. Indonesia and
Australia Australia, officially the Commonwealth of Australia, is a Sovereign state, sovereign country comprising the mainland of the Australia (continent), Australian continent, the island of Tasmania, and numerous List of islands of Australia, sma ...
export the most, followed by Russia.


Etymology

The word originally took the form ''col'' in
Old English Old English (, ), or Anglo-Saxon, is the earliest recorded form of the English language, spoken in England and southern and eastern Scotland in the early Middle Ages. It was brought to Great Britain by Anglo-Saxon settlement of Britain, Anglo ...
, from Proto-Germanic *''kula''(''n''), which in turn is hypothesized to come from the Proto-Indo-European root *''g''(''e'')''u-lo-'' "live coal". Germanic cognates include the Old Frisian ''kole'', Middle Dutch ''cole'', Dutch ''kool'', Old High German ''chol'',
German German(s) may refer to: * Germany (of or related to) **Germania (historical use) * Germans, citizens of Germany, people of German ancestry, or native speakers of the German language ** For citizens of Germany, see also German nationality law **Ger ...
''Kohle'' and Old Norse ''kol'', and the Irish word ''gual'' is also a cognate via the Indo-European root.


Geology

Coal is composed of macerals, minerals and water.
Fossils A fossil (from Classical Latin , ) is any preserved remains, impression, or trace of any once-living thing from a past geological age. Examples include bones, shells, exoskeletons, stone imprints of animals or microbes, objects preserved in ...
and amber may be found in coal.


Formation

The conversion of dead vegetation into coal is called coalification. At various times in the geologic past, the Earth had dense forests in low-lying wetland areas. In these wetlands, the process of coalification began when dead plant matter was protected from biodegradation and oxidation, usually by mud or acidic water, and was converted into peat. This trapped the carbon in immense peat bogs that were eventually deeply buried by sediments. Then, over millions of years, the heat and pressure of deep burial caused the loss of water, methane and carbon dioxide and increased the proportion of carbon. The grade of coal produced depended on the maximum pressure and temperature reached, with
lignite Lignite, often referred to as brown coal, is a soft, brown, combustible, sedimentary rock formed from naturally compressed peat. It has a carbon content around 25–35%, and is considered the lowest rank of coal due to its relatively low heat ...
(also called "brown coal") produced under relatively mild conditions, and
sub-bituminous coal Sub-bituminous coal is a lower grade of coal that contains 35–45% carbon. The properties of this type are between those of lignite, the lowest grade of coal, and those of bituminous coal, the second-highest grade of coal. Sub-bituminous coal i ...
,
bituminous coal Bituminous coal, or black coal, is a type of coal containing a tar-like substance called bitumen or asphalt. Its coloration can be black or sometimes dark brown; often there are well-defined bands of bright and dull material within the seams. It ...
, or
anthracite coal Anthracite, also known as hard coal, and black coal, is a hard, compact variety of coal that has a submetallic luster. It has the highest carbon content, the fewest impurities, and the highest energy density of all types of coal and is the high ...
(also called "hard coal" or "black coal") produced in turn with increasing temperature and pressure. Of the factors involved in coalification, temperature is much more important than either pressure or time of burial. Subbituminous coal can form at temperatures as low as while anthracite requires a temperature of at least . Although coal is known from most geologic periods, 90% of all coal beds were deposited in the
Carboniferous The Carboniferous ( ) is a geologic period and system of the Paleozoic that spans 60 million years from the end of the Devonian Period million years ago ( Mya), to the beginning of the Permian Period, million years ago. The name ''Carbonifero ...
and Permian periods, which represent just 2% of the Earth's geologic history. Paradoxically, this was during the
Late Paleozoic icehouse The late Paleozoic icehouse, also known as the Late Paleozoic Ice Age (LPIA) and formerly known as the Karoo ice age, was an ice age that began in the Late Devonian and ended in the Late Permian, occurring from 360 to 255 million years ago (Mya), ...
, a time of global glaciation. However, the drop in global sea level accompanying the glaciation exposed
continental shelf A continental shelf is a portion of a continent that is submerged under an area of relatively shallow water, known as a shelf sea. Much of these shelves were exposed by drops in sea level during glacial periods. The shelf surrounding an island ...
s that had previously been submerged, and to these were added wide river deltas produced by increased erosion due to the drop in
base level In geology and geomorphology a base level is the lower limit for an erosion process. The modern term was introduced by John Wesley Powell in 1875. The term was subsequently appropriated by William Morris Davis who used it in his cycle of erosion ...
. These widespread areas of wetlands provided ideal conditions for coal formation. The rapid formation of coal ended with the
coal gap Coal is a combustible black or brownish-black sedimentary rock, formed as stratum, rock strata called coal seams. Coal is mostly carbon with variable amounts of other Chemical element, elements, chiefly hydrogen, sulfur, oxygen, and nitrogen ...
in the Permian–Triassic extinction event, where coal is rare. Favorable geography alone does not explain the extensive Carboniferous coal beds. Other factors contributing to rapid coal deposition were high oxygen levels, above 30%, that promoted intense wildfires and formation of
charcoal Charcoal is a lightweight black carbon residue produced by strongly heating wood (or other animal and plant materials) in minimal oxygen to remove all water and volatile constituents. In the traditional version of this pyrolysis process, cal ...
that was all but indigestible by decomposing organisms; high carbon dioxide levels that promoted plant growth; and the nature of Carboniferous forests, which included lycophyte trees whose
determinate growth In biology and botany, indeterminate growth is growth that is not terminated in contrast to determinate growth that stops once a genetically pre-determined structure has completely formed. Thus, a plant that grows and produces flowers and fruit ...
meant that carbon was not tied up in heartwood of living trees for long periods. One theory suggested that about 360 million years ago, some plants evolved the ability to produce
lignin Lignin is a class of complex organic polymers that form key structural materials in the support tissues of most plants. Lignins are particularly important in the formation of cell walls, especially in wood and bark, because they lend rigidity ...
, a complex polymer that made their cellulose stems much harder and more woody. The ability to produce lignin led to the evolution of the first trees. But bacteria and fungi did not immediately evolve the ability to decompose lignin, so the wood did not fully decay but became buried under sediment, eventually turning into coal. About 300 million years ago, mushrooms and other fungi developed this ability, ending the main coal-formation period of earth's history. Although some authors pointed at some evidence of lignin degradation during the Carboniferous, and suggested that climatic and tectonic factors were a more plausible explanation, reconstruction of ancestral enzymes by phylogenetic analysis corroborated a hypothesis that lignin degrading enzymes appeared in fungi approximately 200 MYa. One likely tectonic factor was the Central Pangean Mountains, an enormous range running along the equator that reached its greatest elevation near this time. Climate modeling suggests that the Central Pangean Mountains contributed to the deposition of vast quantities of coal in the late Carboniferous. The mountains created an area of year-round heavy precipitation, with no dry season typical of a monsoon climate. This is necessary for the preservation of peat in coal swamps. Coal is known from
Precambrian The Precambrian (or Pre-Cambrian, sometimes abbreviated pꞒ, or Cryptozoic) is the earliest part of Earth's history, set before the current Phanerozoic Eon. The Precambrian is so named because it preceded the Cambrian, the first period of the ...
strata, which predate land plants. This coal is presumed to have originated from residues of algae. Sometimes coal seams (also known as coal beds) are interbedded with other sediments in a
cyclothem In geology, cyclothems are alternating stratigraphy, stratigraphic sequences of Marine (ocean), marine and non-marine sediments, sometimes interbedded with coal seams. Historically, the term was defined by the European coal geologists who worked ...
. Cyclothems are thought to have their origin in
glacial cycle An ice age is a long period of reduction in the temperature of Earth's surface and atmosphere, resulting in the presence or expansion of continental and polar ice sheets and alpine glaciers. Earth's climate alternates between ice ages and gree ...
s that produced fluctuations in sea level, which alternately exposed and then flooded large areas of continental shelf.


Chemistry of coalification

The woody tissue of plants is composed mainly of cellulose, hemicellulose, and lignin. Modern peat is mostly lignin, with a content of cellulose and hemicellulose ranging from 5% to 40%. Various other organic compounds, such as waxes and nitrogen- and sulfur-containing compounds, are also present. Lignin has a weight composition of about 54% carbon, 6% hydrogen, and 30% oxygen, while cellulose has a weight composition of about 44% carbon, 6% hydrogen, and 49% oxygen. Bituminous coal has a composition of about 84.4% carbon, 5.4% hydrogen, 6.7% oxygen, 1.7% nitrogen, and 1.8% sulfur, on a weight basis. This implies that chemical processes during coalification must remove most of the oxygen and much of the hydrogen, leaving carbon, a process called ''carbonization''. Carbonization proceeds primarily by dehydration,
decarboxylation Decarboxylation is a chemical reaction that removes a carboxyl group and releases carbon dioxide (CO2). Usually, decarboxylation refers to a reaction of carboxylic acids, removing a carbon atom from a carbon chain. The reverse process, which is t ...
, and demethanation. Dehydration removes water molecules from the maturing coal via reactions such as :2 R–OH → R–O–R + H2O :2 R-CH2-O-CH2-R → R-CH=CH-R + H2O Decarboxylation removes carbon dioxide from the maturing coal and proceeds by reaction such as :RCOOH → RH + CO2 while demethanation proceeds by reaction such as :2 R-CH3 → R-CH2-R + CH4 :R-CH2-CH2-CH2-R → R-CH=CH-R + CH4 In each of these formulas, R represents the remainder of a cellulose or lignin molecule to which the reacting groups are attached. Dehydration and decarboxylation take place early in coalification, while demethanation begins only after the coal has already reached bituminous rank. The effect of decarboxylation is to reduce the percentage of oxygen, while demethanation reduces the percentage of hydrogen. Dehydration does both, and (together with demethanation) reduces the saturation of the carbon backbone (increasing the number of double bonds between carbon). As carbonization proceeds,
aliphatic compound In organic chemistry, hydrocarbons ( compounds composed solely of carbon and hydrogen) are divided into two classes: aromatic compounds and aliphatic compounds (; G. ''aleiphar'', fat, oil). Aliphatic compounds can be saturated, like hexane, or ...
s (carbon compounds characterized by chains of carbon atoms) are replaced by aromatic compounds (carbon compounds characterized by rings of carbon atoms) and aromatic rings begin to fuse into
polyaromatic A polycyclic aromatic hydrocarbon (PAH) is a class of organic compounds that is composed of multiple aromatic rings. The simplest representative is naphthalene, having two aromatic rings and the three-ring compounds anthracene and phenanthrene. P ...
compounds (linked rings of carbon atoms). The structure increasingly resembles graphene, the structural element of graphite. Chemical changes are accompanied by physical changes, such as decrease in average pore size. The macerals (organic particles) of lignite are composed of ''huminite'', which is earthy in appearance. As the coal matures to sub-bituminous coal, huminite begins to be replaced by vitreous (shiny) ''vitrinite''. Maturation of bituminous coal is characterized by ''bitumenization'', in which part of the coal is converted to
bitumen Asphalt, also known as bitumen (, ), is a sticky, black, highly viscous liquid or semi-solid form of petroleum. It may be found in natural deposits or may be a refined product, and is classed as a pitch. Before the 20th century, the term a ...
, a hydrocarbon-rich gel. Maturation to anthracite is characterized by ''debitumenization'' (from demethanation) and the increasing tendency of the anthracite to break with a
conchoidal fracture Conchoidal fracture describes the way that brittle materials break or fracture when they do not follow any natural planes of separation. Mindat.org defines conchoidal fracture as follows: "a fracture with smooth, curved surfaces, typically slig ...
, similar to the way thick glass breaks.


Types

As geological processes apply pressure to dead biotic material over time, under suitable conditions, its
metamorphic grade Metamorphism is the transformation of existing rock (the protolith) to rock with a different mineral composition or texture. Metamorphism takes place at temperatures in excess of , and often also at elevated pressure or in the presence of chem ...
or rank increases successively into: * Peat, a precursor of coal *
Lignite Lignite, often referred to as brown coal, is a soft, brown, combustible, sedimentary rock formed from naturally compressed peat. It has a carbon content around 25–35%, and is considered the lowest rank of coal due to its relatively low heat ...
, or brown coal, the lowest rank of coal, most harmful to health, used almost exclusively as fuel for electric power generation **
Jet Jet, Jets, or The Jet(s) may refer to: Aerospace * Jet aircraft, an aircraft propelled by jet engines ** Jet airliner ** Jet engine ** Jet fuel * Jet Airways, an Indian airline * Wind Jet (ICAO: JET), an Italian airline * Journey to Enceladus a ...
, a compact form of lignite, sometimes polished; used as an ornamental stone since the Upper Palaeolithic *
Sub-bituminous coal Sub-bituminous coal is a lower grade of coal that contains 35–45% carbon. The properties of this type are between those of lignite, the lowest grade of coal, and those of bituminous coal, the second-highest grade of coal. Sub-bituminous coal i ...
, whose properties range between those of lignite and those of bituminous coal, is used primarily as fuel for steam-electric power generation. *
Bituminous coal Bituminous coal, or black coal, is a type of coal containing a tar-like substance called bitumen or asphalt. Its coloration can be black or sometimes dark brown; often there are well-defined bands of bright and dull material within the seams. It ...
, a dense sedimentary rock, usually black, but sometimes dark brown, often with well-defined bands of bright and dull material. It is used primarily as fuel in steam-electric power generation and to make coke. Known as steam coal in the UK, and historically used to raise steam in steam locomotives and ships *
Anthracite coal Anthracite, also known as hard coal, and black coal, is a hard, compact variety of coal that has a submetallic luster. It has the highest carbon content, the fewest impurities, and the highest energy density of all types of coal and is the high ...
, the highest rank of coal, is a harder, glossy black coal used primarily for residential and commercial space heating. * Graphite is difficult to ignite and not commonly used as fuel; it is most used in pencils, or powdered for
lubrication Lubrication is the process or technique of using a lubricant to reduce friction and wear and tear in a contact between two surfaces. The study of lubrication is a discipline in the field of tribology. Lubrication mechanisms such as fluid-lubric ...
. *
Cannel coal Cannel coal or candle coal is a type of bituminous coal, also classified as terrestrial type oil shale. Hutton(1987) Dyni (2006), pp. 3–4 Speight (2012), pp. 6–7 Due to its physical morphology and low mineral content cannel coal is considered ...
(sometimes called "candle coal") is a variety of fine-grained, high-rank coal with significant hydrogen content, which consists primarily of
liptinite In coal geology, liptinite is the finely-ground and macerated remains found in coal deposits. It replaced the term exinite as one of the four categories of kerogen. Liptinites were originally formed by spores, pollen, dinoflagellate cysts, leaf cu ...
. There are several international standards for coal. The classification of coal is generally based on the content of
volatiles Volatiles are the group of chemical elements and chemical compounds that can be readily vaporized. In contrast with volatiles, elements and compounds that are not readily vaporized are known as refractory substances. On planet Earth, the term ' ...
. However the most important distinction is between thermal coal (also known as steam coal), which is burnt to generate electricity via steam; and metallurgical coal (also known as coking coal), which is burnt at high temperature to make
steel Steel is an alloy made up of iron with added carbon to improve its strength and fracture resistance compared to other forms of iron. Many other elements may be present or added. Stainless steels that are corrosion- and oxidation-resistant ty ...
.
Hilt's law Hilt's law is a geological law that states the deeper the coal, the higher its rank (grade). The law holds true if the thermal gradient is entirely vertical, but metamorphism may cause lateral changes of rank, irrespective of depth. Increasing d ...
is a geological observation that (within a small area) the deeper the coal is found, the higher its rank (or grade). It applies if the thermal gradient is entirely vertical; however, metamorphism may cause lateral changes of rank, irrespective of depth. For example, some of the coal seams of the Madrid, New Mexico coal field were partially converted to anthracite by contact metamorphism from an igneous
sill Sill may refer to: * Sill (dock), a weir at the low water mark retaining water within a dock * Sill (geology), a subhorizontal sheet intrusion of molten or solidified magma * Sill (geostatistics) * Sill (river), a river in Austria * Sill plate, a ...
while the remainder of the seams remained as bituminous coal.


History

The earliest recognized use is from the
Shenyang Shenyang (, ; ; Mandarin pronunciation: ), formerly known as Fengtian () or by its Manchu language, Manchu name Mukden, is a major China, Chinese sub-provincial city and the List of capitals in China#Province capitals, provincial capital of Lia ...
area of China where by 4000 BC Neolithic inhabitants had begun carving ornaments from black lignite. Coal from the Fushun mine in northeastern China was used to smelt copper as early as 1000 BC.
Marco Polo Marco Polo (, , ; 8 January 1324) was a Venetian merchant, explorer and writer who travelled through Asia along the Silk Road between 1271 and 1295. His travels are recorded in ''The Travels of Marco Polo'' (also known as ''Book of the Marv ...
, the Italian who traveled to China in the 13th century, described coal as "black stones ... which burn like logs", and said coal was so plentiful, people could take three hot baths a week. In Europe, the earliest reference to the use of coal as fuel is from the geological treatise ''On Stones'' (Lap. 16) by the Greek scientist Theophrastus (c. 371–287 BC): Outcrop coal was used in Britain during the Bronze Age (3000–2000 BC), where it formed part of
funeral A funeral is a ceremony connected with the final disposition of a corpse, such as a burial or cremation, with the attendant observances. Funerary customs comprise the complex of beliefs and practices used by a culture to remember and respect th ...
pyres.Britannica 2004: ''Coal mining: ancient use of outcropping coal'' In Roman Britain, with the exception of two modern fields, "the Romans were exploiting coals in all the major coalfields in England and Wales by the end of the second century AD". Evidence of trade in coal, dated to about AD 200, has been found at the Roman settlement at Heronbridge, near
Chester Chester is a cathedral city and the county town of Cheshire, England. It is located on the River Dee, close to the English–Welsh border. With a population of 79,645 in 2011,"2011 Census results: People and Population Profile: Chester Loca ...
; and in the Fenlands of
East Anglia East Anglia is an area in the East of England, often defined as including the counties of Norfolk, Suffolk and Cambridgeshire. The name derives from the Anglo-Saxon kingdom of the East Angles, a people whose name originated in Anglia, in ...
, where coal from the
Midlands The Midlands (also referred to as Central England) are a part of England that broadly correspond to the Kingdom of Mercia of the Early Middle Ages, bordered by Wales, Northern England and Southern England. The Midlands were important in the Ind ...
was transported via the Car Dyke for use in drying grain. Coal cinders have been found in the hearths of
villas Villas may refer to: Places * Villas, Florida, United States * Villas, Illinois, United States * Villas, New Jersey, United States * Las Villas, a region of Spain * Las Villas (Cuba), a former Cuban Province * The Villas, a housing estate in Stok ...
and Roman forts, particularly in Northumberland, dated to around AD 400. In the west of England, contemporary writers described the wonder of a permanent brazier of coal on the altar of Minerva at Aquae Sulis (modern day
Bath Bath may refer to: * Bathing, immersion in a fluid ** Bathtub, a large open container for water, in which a person may wash their body ** Public bathing, a public place where people bathe * Thermae, ancient Roman public bathing facilities Plac ...
), although in fact easily accessible surface coal from what became the Somerset coalfield was in common use in quite lowly dwellings locally. Evidence of coal's use for iron-working in the city during the Roman period has been found. In Eschweiler, Rhineland, deposits of
bituminous coal Bituminous coal, or black coal, is a type of coal containing a tar-like substance called bitumen or asphalt. Its coloration can be black or sometimes dark brown; often there are well-defined bands of bright and dull material within the seams. It ...
were used by the Romans for the smelting of
iron ore Iron ores are rocks and minerals from which metallic iron can be economically extracted. The ores are usually rich in iron oxides and vary in color from dark grey, bright yellow, or deep purple to rusty red. The iron is usually found in the fo ...
. No evidence exists of coal being of great importance in Britain before about AD 1000, the High Middle Ages. Coal came to be referred to as "seacoal" in the 13th century; the wharf where the material arrived in London was known as Seacoal Lane, so identified in a charter of King Henry III granted in 1253. Initially, the name was given because much coal was found on the shore, having fallen from the exposed coal seams on cliffs above or washed out of underwater coal outcrops, but by the time of
Henry VIII Henry VIII (28 June 149128 January 1547) was King of England from 22 April 1509 until his death in 1547. Henry is best known for his six marriages, and for his efforts to have his first marriage (to Catherine of Aragon) annulled. His disa ...
, it was understood to derive from the way it was carried to London by sea. In 1257–1259, coal from Newcastle upon Tyne was shipped to London for the smiths and lime-burners building Westminster Abbey. Seacoal Lane and Newcastle Lane, where coal was unloaded at wharves along the River Fleet, still exist. These easily accessible sources had largely become exhausted (or could not meet the growing demand) by the 13th century, when underground extraction by shaft mining or adits was developed. The alternative name was "pitcoal", because it came from mines. Cooking and home heating with coal (in addition to firewood or instead of it) has been done in various times and places throughout human history, especially in times and places where ground-surface coal was available and firewood was scarce, but a widespread reliance on coal for home hearths probably never existed until such a switch in fuels happened in London in the late sixteenth and early seventeenth centuries. Historian
Ruth Goodman Ruth Ellen Goodman (born 5 October 1963) is a British freelance historian of the early modern period, specialising in offering advice to museums and heritage attractions. She is a specialist in British social history and after presenting the 2 ...
has traced the socioeconomic effects of that switch and its later spread throughout Britain and suggested that its importance in shaping the industrial adoption of coal has been previously underappreciated. The development of the Industrial Revolution led to the large-scale use of coal, as the
steam engine A steam engine is a heat engine that performs mechanical work using steam as its working fluid. The steam engine uses the force produced by steam pressure to push a piston back and forth inside a cylinder. This pushing force can be trans ...
took over from the water wheel. In 1700, five-sixths of the world's coal was mined in Britain. Britain would have run out of suitable sites for watermills by the 1830s if coal had not been available as a source of energy. In 1947 there were some 750,000 miners in Britain but the last deep coal mine in the UK closed in 2015. A grade between bituminous coal and anthracite was once known as "steam coal" as it was widely used as a fuel for
steam locomotive A steam locomotive is a locomotive that provides the force to move itself and other vehicles by means of the expansion of steam. It is fuelled by burning combustible material (usually coal, oil or, rarely, wood) to heat water in the locomot ...
s. In this specialized use, it is sometimes known as "sea coal" in the United States. Small "steam coal", also called ''dry small steam nuts'' (DSSN), was used as a fuel for domestic
water heating Water heating is a heat transfer process that uses an energy source to heat water above its initial temperature. Typical domestic uses of hot water include cooking, cleaning, bathing, and space heating. In industry, hot water and water heated t ...
. Coal played an important role in industry in the 19th and 20th century. The predecessor of the European Union, the
European Coal and Steel Community The European Coal and Steel Community (ECSC) was a European organization created after World War II to regulate the coal and steel industries. It was formally established in 1951 by the Treaty of Paris, signed by Belgium, France, Italy, Luxembo ...
, was based on the trading of this commodity. Coal continues to arrive on beaches around the world from both natural erosion of exposed coal seams and windswept spills from cargo ships. Many homes in such areas gather this coal as a significant, and sometimes primary, source of home heating fuel.


Chemistry


Composition

The composition of coal is reported either as a
proximate analysis Proximates are used in the analysis of biological materials as a decomposition of a human-consumable good into its major constituents. They are a good approximation of the contents of packaged comestible goods and serve as a cost-effective and ea ...
(moisture, volatile matter, fixed carbon, and ash) or an
ultimate analysis Ultimate or Ultimates may refer to: Arts, entertainment, and media Music Albums * ''Ultimate'' (Jolin Tsai album) * ''Ultimate'' (Pet Shop Boys album) *''Ultimate!'', an album by The Yardbirds *'' The Ultimate (Bryan Adams Album)'', a compilati ...
(ash, carbon, hydrogen, nitrogen, oxygen, and sulfur). The "volatile matter" does not exist by itself (except for some adsorbed methane) but designates the volatile compounds that are produced and driven off by heating the coal. A typical bituminous coal may have an ultimate analysis on a dry, ash-free basis of 84.4% carbon, 5.4% hydrogen, 6.7% oxygen, 1.7% nitrogen, and 1.8% sulfur, on a weight basis. The composition of ash, given in terms of oxides, varies: Other minor components include:


Coking coal and use of coke to smelt iron

Coke is a solid carbonaceous residue derived from
coking coal Metallurgical coal or coking coal is a grade of coal that can be used to produce good-quality coke. Coke is an essential fuel and reactant in the blast furnace process for primary steelmaking. The demand for metallurgical coal is highly coupled ...
(a low-ash, low-sulfur bituminous coal, also known as ''metallurgical coal''), which is used in manufacturing steel and other iron products. Coke is made from coking coal by baking in an oven without oxygen at temperatures as high as 1,000 °C, driving off the volatile constituents and fusing together the fixed carbon and residual ash. Metallurgical coke is used as a fuel and as a reducing agent in smelting iron ore in a
blast furnace A blast furnace is a type of metallurgical furnace used for smelting to produce industrial metals, generally pig iron, but also others such as lead or copper. ''Blast'' refers to the combustion air being "forced" or supplied above atmospheric ...
. The carbon monoxide produced by its combustion reduces
hematite Hematite (), also spelled as haematite, is a common iron oxide compound with the formula, Fe2O3 and is widely found in rocks and soils. Hematite crystals belong to the rhombohedral lattice system which is designated the alpha polymorph of . ...
(an
iron oxide Iron oxides are chemical compounds composed of iron and oxygen. Several iron oxides are recognized. All are black magnetic solids. Often they are non-stoichiometric. Oxyhydroxides are a related class of compounds, perhaps the best known of whic ...
) to iron. Waste carbon dioxide is also produced together with
pig iron Pig iron, also known as crude iron, is an intermediate product of the iron industry in the production of steel which is obtained by smelting iron ore in a blast furnace. Pig iron has a high carbon content, typically 3.8–4.7%, along with silic ...
, which is too rich in dissolved carbon so must be treated further to make steel. Coking coal should be low in ash,
sulfur Sulfur (or sulphur in British English) is a chemical element with the symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with a chemical formula ...
, and phosphorus, so that these do not migrate to the metal. The coke must be strong enough to resist the weight of overburden in the blast furnace, which is why coking coal is so important in making steel using the conventional route. Coke from coal is grey, hard, and porous and has a heating value of 29.6 MJ/kg. Some cokemaking processes produce byproducts, including coal tar, ammonia, light oils, and
coal gas Coal gas is a flammable gaseous fuel made from coal and supplied to the user via a piped distribution system. It is produced when coal is heated strongly in the absence of air. Town gas is a more general term referring to manufactured gaseous ...
. Petroleum coke (petcoke) is the solid residue obtained in
oil refining An oil refinery or petroleum refinery is an industrial process plant where petroleum (crude oil) is transformed and refined into useful products such as gasoline (petrol), diesel fuel, asphalt base, fuel oils, heating oil, kerosene, liquefie ...
, which resembles coke but contains too many impurities to be useful in metallurgical applications.


Use in foundry components

Finely ground bituminous coal, known in this application as sea coal, is a constituent of
foundry sand Molding sand, also known as foundry sand, is a sand that when moistened and compressed or oiled or heated tends to pack well and hold its shape. It is used in the process of sand casting for preparing the mold cavity. Green sand Green sand is an a ...
. While the molten metal is in the
mould A mold () or mould () is one of the structures certain fungi can form. The dust-like, colored appearance of molds is due to the formation of spores containing fungal secondary metabolites. The spores are the dispersal units of the fungi. No ...
, the coal burns slowly, releasing reducing gases at pressure, and so preventing the metal from penetrating the pores of the sand. It is also contained in 'mould wash', a paste or liquid with the same function applied to the mould before casting. Sea coal can be mixed with the clay lining (the "bod") used for the bottom of a
cupola furnace A cupola or cupola furnace is a melting device used in foundries that can be used to melt cast iron, Ni-resist iron and some bronzes. The cupola can be made almost any practical size. The size of a cupola is expressed in diameters and can range f ...
. When heated, the coal decomposes and the bod becomes slightly friable, easing the process of breaking open holes for tapping the molten metal.


Alternatives to coke

Scrap steel can be recycled in an electric arc furnace; and an alternative to making iron by smelting is direct reduced iron, where any carbonaceous fuel can be used to make sponge or pelletised iron. To lessen carbon dioxide emissions hydrogen can be used as the reducing agent and
biomass Biomass is plant-based material used as a fuel for heat or electricity production. It can be in the form of wood, wood residues, energy crops, agricultural residues, and waste from industry, farms, and households. Some people use the terms bi ...
or waste as the source of carbon. Historically, charcoal has been used as an alternative to coke in a blast furnace, with the resultant iron being known as charcoal iron.


Gasification

Coal gasification, as part of an integrated gasification combined cycle (IGCC) coal-fired power station, is used to produce
syngas Syngas, or synthesis gas, is a mixture of hydrogen and carbon monoxide, in various ratios. The gas often contains some carbon dioxide and methane. It is principly used for producing ammonia or methanol. Syngas is combustible and can be used as ...
, a mixture of carbon monoxide (CO) and hydrogen (H2) gas to fire gas turbines to produce electricity. Syngas can also be converted into transportation fuels, such as gasoline and
diesel Diesel may refer to: * Diesel engine, an internal combustion engine where ignition is caused by compression * Diesel fuel, a liquid fuel used in diesel engines * Diesel locomotive, a railway locomotive in which the prime mover is a diesel engin ...
, through the Fischer–Tropsch process; alternatively, syngas can be converted into
methanol Methanol (also called methyl alcohol and wood spirit, amongst other names) is an organic chemical and the simplest aliphatic alcohol, with the formula C H3 O H (a methyl group linked to a hydroxyl group, often abbreviated as MeOH). It is a ...
, which can be blended into fuel directly or converted to gasoline via the methanol to gasoline process. Gasification combined with Fischer–Tropsch technology was used by the Sasol chemical company of South Africa to make chemicals and motor vehicle fuels from coal. During gasification, the coal is mixed with oxygen and
steam Steam is a substance containing water in the gas phase, and sometimes also an aerosol of liquid water droplets, or air. This may occur due to evaporation or due to boiling, where heat is applied until water reaches the enthalpy of vaporization ...
while also being heated and pressurized. During the reaction, oxygen and water molecules oxidize the coal into carbon monoxide (CO), while also releasing hydrogen gas (H2). This used to be done in underground coal mines, and also to make town gas, which was piped to customers to burn for illumination, heating, and cooking. : 3C (''as Coal'') + O2 + H2O → H2 + 3CO If the refiner wants to produce gasoline, the syngas is routed into a Fischer–Tropsch reaction. This is known as indirect coal liquefaction. If hydrogen is the desired end-product, however, the syngas is fed into the water gas shift reaction, where more hydrogen is liberated: : CO + H2O → CO2 + H2


Liquefaction

Coal can be converted directly into synthetic fuels equivalent to gasoline or diesel by hydrogenation or carbonization. Coal liquefaction emits more carbon dioxide than liquid fuel production from
crude oil Petroleum, also known as crude oil, or simply oil, is a naturally occurring yellowish-black liquid mixture of mainly hydrocarbons, and is found in geological formations. The name ''petroleum'' covers both naturally occurring unprocessed crude ...
. Mixing in biomass and using CCS would emit slightly less than the oil process but at a high cost. State owned
China Energy Investment China Energy Investment Corporation, more commonly known as China Energy (), is a state-owned mining and energy company administrated by the SASAC of the State Council of the People's Republic of China. History On August 28, 2017, SASAC announce ...
runs a coal liquefaction plant and plans to build 2 more. Coal liquefaction may also refer to the cargo hazard when shipping coal.


Production of chemicals

Chemicals have been produced from coal since the 1950s. Coal can be used as a feedstock in the production of a wide range of chemical fertilizers and other chemical products. The main route to these products was
coal gasification Coal gasification is the process of producing syngas—a mixture consisting primarily of carbon monoxide (CO), hydrogen (H2), carbon dioxide (CO2), methane (CH4), and water vapour (H2O)—from coal and water, air and/or oxygen. Historically, coal ...
to produce
syngas Syngas, or synthesis gas, is a mixture of hydrogen and carbon monoxide, in various ratios. The gas often contains some carbon dioxide and methane. It is principly used for producing ammonia or methanol. Syngas is combustible and can be used as ...
. Primary chemicals that are produced directly from the syngas include
methanol Methanol (also called methyl alcohol and wood spirit, amongst other names) is an organic chemical and the simplest aliphatic alcohol, with the formula C H3 O H (a methyl group linked to a hydroxyl group, often abbreviated as MeOH). It is a ...
, hydrogen and carbon monoxide, which are the chemical building blocks from which a whole spectrum of derivative chemicals are manufactured, including
olefins In organic chemistry, an alkene is a hydrocarbon containing a carbon–carbon double bond. Alkene is often used as synonym of olefin, that is, any hydrocarbon containing one or more double bonds.H. Stephen Stoker (2015): General, Organic, an ...
,
acetic acid Acetic acid , systematically named ethanoic acid , is an acidic, colourless liquid and organic compound with the chemical formula (also written as , , or ). Vinegar is at least 4% acetic acid by volume, making acetic acid the main component ...
, formaldehyde, ammonia, urea and others. The versatility of
syngas Syngas, or synthesis gas, is a mixture of hydrogen and carbon monoxide, in various ratios. The gas often contains some carbon dioxide and methane. It is principly used for producing ammonia or methanol. Syngas is combustible and can be used as ...
as a precursor to primary chemicals and high-value derivative products provides the option of using coal to produce a wide range of commodities. In the 21st century, however, the use of
coal bed methane Coalbed methane (CBM or coal-bed methane), coalbed gas, coal seam gas (CSG), or coal-mine methane (CMM) is a form of natural gas extracted from coal beds. In recent decades it has become an important source of energy in United States, Canada, Au ...
is becoming more important. Because the slate of chemical products that can be made via coal gasification can in general also use feedstocks derived from natural gas and petroleum, the chemical industry tends to use whatever feedstocks are most cost-effective. Therefore, interest in using coal tended to increase for higher oil and natural gas prices and during periods of high global economic growth that might have strained oil and gas production. Coal to chemical processes require substantial quantities of water. Much coal to chemical production is in China where coal dependent provinces such as
Shanxi Shanxi (; ; formerly romanised as Shansi) is a landlocked province of the People's Republic of China and is part of the North China region. The capital and largest city of the province is Taiyuan, while its next most populated prefecture-lev ...
are struggling to control its pollution.


Electricity generation


Energy density

The
energy density In physics, energy density is the amount of energy stored in a given system or region of space per unit volume. It is sometimes confused with energy per unit mass which is properly called specific energy or . Often only the ''useful'' or extract ...
of coal is roughly 24
megajoule The joule ( , ; symbol: J) is the unit of energy in the International System of Units (SI). It is equal to the amount of work done when a force of 1 newton displaces a mass through a distance of 1 metre in the direction of the force applied. ...
s per kilogram (approximately 6.7 kilowatt-hours per kg). For a coal power plant with a 40% efficiency, it takes an estimated of coal to power a 100 W lightbulb for one year. 27.6% of world energy was supplied by coal in 2017 and Asia used almost three-quarters of it.


Precombustion treatment

Refined coal is the product of a coal-upgrading technology that removes moisture and certain pollutants from lower-rank coals such as sub-bituminous and lignite (brown) coals. It is one form of several precombustion treatments and processes for coal that alter coal's characteristics before it is burned. Thermal efficiency improvements are achievable by improved pre-drying (especially relevant with high-moisture fuel such as lignite or biomass). The goals of precombustion coal technologies are to increase efficiency and reduce emissions when the coal is burned. Precombustion technology can sometimes be used as a supplement to postcombustion technologies to control emissions from coal-fueled boilers.


Power plant combustion

Coal burnt as a
solid fuel Solid fuel refers to various forms of solid material that can be burnt to release energy, providing heat and light through the process of combustion. Solid fuels can be contrasted with liquid fuels and gaseous fuels. Common examples of solid fuels ...
in coal power stations to generate electricity is called thermal coal. Coal is also used to produce very high temperatures through combustion. Early deaths due to air pollution have been estimated at 200 per GW-year, however they may be higher around power plants where scrubbers are not used or lower if they are far from cities. Efforts around the world to reduce the use of coal have led some regions to switch to natural gas and electricity from lower carbon sources. When coal is used for electricity generation, it is usually pulverized and then burned in a furnace with a boiler (see also Pulverized coal-fired boiler).Total World Electricity Generation by Fuel (2006)
. Source: IEA 2008.
The furnace heat converts boiler water to
steam Steam is a substance containing water in the gas phase, and sometimes also an aerosol of liquid water droplets, or air. This may occur due to evaporation or due to boiling, where heat is applied until water reaches the enthalpy of vaporization ...
, which is then used to spin turbines which turn generators and create electricity. The thermodynamic efficiency of this process varies between about 25% and 50% depending on the pre-combustion treatment, turbine technology (e.g. supercritical steam generator) and the age of the plant. A few integrated gasification combined cycle (IGCC) power plants have been built, which burn coal more efficiently. Instead of pulverizing the coal and burning it directly as fuel in the steam-generating boiler, the coal is gasified to create
syngas Syngas, or synthesis gas, is a mixture of hydrogen and carbon monoxide, in various ratios. The gas often contains some carbon dioxide and methane. It is principly used for producing ammonia or methanol. Syngas is combustible and can be used as ...
, which is burned in a gas turbine to produce electricity (just like natural gas is burned in a turbine). Hot exhaust gases from the turbine are used to raise steam in a heat recovery steam generator which powers a supplemental
steam turbine A steam turbine is a machine that extracts thermal energy from pressurized steam and uses it to do mechanical work on a rotating output shaft. Its modern manifestation was invented by Charles Parsons in 1884. Fabrication of a modern steam turbin ...
. The overall plant efficiency when used to provide
combined heat and power Cogeneration or combined heat and power (CHP) is the use of a heat engine or power station to generate electricity and useful heat at the same time. Cogeneration is a more efficient use of fuel or heat, because otherwise- wasted heat from elect ...
can reach as much as 94%. IGCC power plants emit less local pollution than conventional pulverized coal-fueled plants; however the technology for carbon capture and storage after gasification and before burning has so far proved to be too expensive to use with coal. Other ways to use coal are as coal-water slurry fuel (CWS), which was developed in the Soviet Union, or in an MHD topping cycle. However these are not widely used due to lack of profit. In 2017 38% of the world's electricity came from coal, the same percentage as 30 years previously. In 2018 global installed capacity was 2 TW (of which 1TW is in China) which was 30% of total electricity generation capacity. The most dependent major country is South Africa, with over 80% of its electricity generated by coal; but China alone generates more than half of the world's coal-generated electricity. Maximum use of coal was reached in 2013. In 2018 coal-fired power station capacity factor averaged 51%, that is they operated for about half their available operating hours.


Coal industry


Mining

About 8000 Mt of coal are produced annually, about 90% of which is hard coal and 10% lignite. just over half is from underground mines. More accidents occur during underground mining than surface mining. Not all countries publish mining accident statistics so worldwide figures are uncertain, but it is thought that most deaths occur in coal mining accidents in China: in 2017 there were 375 coal mining related deaths in China. Most coal mined is thermal coal (also called steam coal as it is used to make steam to generate electricity) but metallurgical coal (also called "metcoal" or "coking coal" as it is used to make coke to make iron) accounts for 10% to 15% of global coal use.


As a traded commodity

China mines almost half the world's coal, followed by India with about a tenth.
Australia Australia, officially the Commonwealth of Australia, is a Sovereign state, sovereign country comprising the mainland of the Australia (continent), Australian continent, the island of Tasmania, and numerous List of islands of Australia, sma ...
accounts for about a third of world coal exports, followed by Indonesia and Russia, while the largest importers are
Japan Japan ( ja, 日本, or , and formally , ''Nihonkoku'') is an island country in East Asia. It is situated in the northwest Pacific Ocean, and is bordered on the west by the Sea of Japan, while extending from the Sea of Okhotsk in the north ...
and India. The price of metallurgical coal is volatile and much higher than the price of thermal coal because metallurgical coal must be lower in sulfur and requires more cleaning. Coal futures contracts provide coal producers and the electric power industry an important tool for hedging and risk management. In some countries new onshore wind or
solar Solar may refer to: Astronomy * Of or relating to the Sun ** Solar telescope, a special purpose telescope used to observe the Sun ** A device that utilizes solar energy (e.g. "solar panels") ** Solar calendar, a calendar whose dates indicate t ...
generation already costs less than coal power from existing plants. However, for China this is forecast for the early 2020s and for southeast Asia not until the late 2020s. In India building new plants is uneconomic and, despite being subsidized, existing plants are losing market share to renewables.


Market trends

Of the countries which produce coal China mines by far the most, almost half the world's coal, followed by less than 10% by India. China is also by far the largest consumer. Therefore, market trends depend on Chinese energy policy. Although the effort to reduce pollution means that the global long-term trend is to burn less coal, the short and medium term trends may differ, in part due to Chinese financing of new coal-fired power plants in other countries.


Major producers

Countries with annual production higher than 300 million tonnes are shown.


Major consumers

Countries with annual consumption higher than 500 million tonnes are shown. Shares are based on data expressed in tonnes oil equivalent.


Major exporters

Exporters are at risk of a reduction in import demand from India and China.


Major importers


Damage to human health

The use of coal as fuel causes ill health and deaths. Mining and processing of coal causes air and water pollution. Coal-powered plants emit nitrogen oxides, sulfur dioxide, particulate pollution and heavy metals, which adversely affect human health.
Coal bed methane extraction Coalbed methane extraction (CBM extraction) is a method for extracting methane from a coal deposit. Coal bed methane (CBM) is one of the factors restricting safe production of coal in underground coal mines. It is also a form of high-quality energ ...
is important to avoid mining accidents. The deadly London smog was caused primarily by the heavy use of coal. Globally coal is estimated to cause 800,000 premature deaths every year, mostly in India and China. Burning coal is a major emitter of
sulfur dioxide Sulfur dioxide (IUPAC-recommended spelling) or sulphur dioxide (traditional Commonwealth English) is the chemical compound with the formula . It is a toxic gas responsible for the odor of burnt matches. It is released naturally by volcanic activ ...
, which creates PM2.5 particulates, the most dangerous form of air pollution. Coal smokestack emissions cause asthma, strokes, reduced intelligence, artery blockages, heart attacks, congestive heart failure,
cardiac arrhythmias Arrhythmias, also known as cardiac arrhythmias, heart arrhythmias, or dysrhythmias, are irregularities in the heartbeat, including when it is too fast or too slow. A resting heart rate that is too fast – above 100 beats per minute in adults ...
,
mercury poisoning Mercury poisoning is a type of metal poisoning due to exposure to mercury. Symptoms depend upon the type, dose, method, and duration of exposure. They may include muscle weakness, poor coordination, numbness in the hands and feet, skin rashe ...
,
arterial occlusion Arterial occlusion is a condition involving partial or complete blockage of blood flow through an artery. Arteries are blood vessels that carry oxygenated blood to body tissues. An occlusion of arteries disrupts oxygen and blood supply to tissues, l ...
, and lung cancer.Coal Pollution Damages Human Health at Every Stage of Coal Life Cycle, Reports Physicians for Social Responsibility
. ''Physicians for Social Responsibility''. psr.org (18 November 2009)
Annual health costs in Europe from use of coal to generate electricity are estimated at up to €43 billion. In China, improvements to air quality and human health would increase with more stringent climate policies, mainly because the country's energy is so heavily reliant on coal. And there would be a net economic benefit. A 2017 study in the '' Economic Journal'' found that for Britain during the period 1851–1860, "a one standard deviation increase in coal use raised infant mortality by 6–8% and that industrial coal use explains roughly one-third of the urban mortality penalty observed during this period." Breathing in coal dust causes
coalworker's pneumoconiosis Coal workers' pneumoconiosis (CWP), also known as black lung disease or black lung, is an occupational type of pneumoconiosis caused by long-term exposure to coal dust. It is common in coal miners and others who work with coal. It is similar to b ...
or "black lung", so called because the coal dust literally turns the lungs black from their usual pink color. In the US alone, it is estimated that 1,500 former employees of the coal industry die every year from the effects of breathing in coal mine dust. Huge amounts of coal ash and other waste is produced annually. Use of coal generates hundreds of millions of tons of ash and other waste products every year. These include
fly ash Fly ash, flue ash, coal ash, or pulverised fuel ash (in the UK) plurale tantum: coal combustion residuals (CCRs)is a coal combustion product that is composed of the particulates (fine particles of burned fuel) that are driven out of coal-fired ...
,
bottom ash Bottom ash is part of the non-combustible residue of combustion in a power plant, boiler, furnace or incinerator. In an industrial context, it has traditionally referred to coal combustion and comprises traces of combustibles embedded in formin ...
, and
flue-gas desulfurization Flue-gas desulfurization (FGD) is a set of technologies used to remove sulfur dioxide () from exhaust flue gases of fossil-fuel power plants, and from the emissions of other sulfur oxide emitting processes such as waste incineration. Methods ...
sludge, that contain
mercury Mercury commonly refers to: * Mercury (planet), the nearest planet to the Sun * Mercury (element), a metallic chemical element with the symbol Hg * Mercury (mythology), a Roman god Mercury or The Mercury may also refer to: Companies * Merc ...
, uranium, thorium, arsenic, and other
heavy metals upright=1.2, Crystals of osmium, a heavy metal nearly twice as dense as lead">lead.html" ;"title="osmium, a heavy metal nearly twice as dense as lead">osmium, a heavy metal nearly twice as dense as lead Heavy metals are generally defined as ...
, along with non-metals such as selenium. Around 10% of coal is ash:
coal ash Coal is a combustible black or brownish-black sedimentary rock, formed as rock strata called coal seams. Coal is mostly carbon with variable amounts of other elements, chiefly hydrogen, sulfur, oxygen, and nitrogen. Coal is formed when de ...
is hazardous and toxic to human beings and some other living things. Coal ash contains the radioactive elements uranium and thorium. Coal ash and other solid combustion byproducts are stored locally and escape in various ways that expose those living near coal plants to radiation and environmental toxics.


Damage to the environment

Coal mining Coal mining is the process of extracting coal from the ground. Coal is valued for its energy content and since the 1880s has been widely used to generate electricity. Steel and cement industries use coal as a fuel for extraction of iron from ...
and coal fueling of power stations and industrial processes can cause major environmental damage. Water systems are affected by coal mining. For example, mining affects groundwater and water table levels and acidity. Spills of fly ash, such as the
Kingston Fossil Plant coal fly ash slurry spill The Kingston Fossil Plant coal fly ash slurry spill was an environmental and industrial disaster that occurred on Monday December 22, 2008, when a dike ruptured at a coal ash pond at the Tennessee Valley Authority's Kingston Fossil Plant in Roan ...
, can also contaminate land and waterways, and destroy homes. Power stations that burn coal also consume large quantities of water. This can affect the flows of rivers, and has consequential impacts on other land uses. In areas of water scarcity, such as the Thar Desert in Pakistan, coal mining and coal power plants would use significant quantities of water. One of the earliest known impacts of coal on the water cycle was
acid rain Acid rain is rain or any other form of precipitation that is unusually acidic, meaning that it has elevated levels of hydrogen ions (low pH). Most water, including drinking water, has a neutral pH that exists between 6.5 and 8.5, but acid ...
. In 2014 approximately 100 Tg/S of
sulfur dioxide Sulfur dioxide (IUPAC-recommended spelling) or sulphur dioxide (traditional Commonwealth English) is the chemical compound with the formula . It is a toxic gas responsible for the odor of burnt matches. It is released naturally by volcanic activ ...
(SO2) was released, over half of which was from burning coal. After release, the sulfur dioxide is oxidized to H2SO4 which scatters solar radiation, hence its increase in the atmosphere exerts a cooling effect on climate. This beneficially masks some of the warming caused by increased greenhouse gases. However, the sulfur is precipitated out of the atmosphere as acid rain in a matter of weeks, whereas carbon dioxide remains in the atmosphere for hundreds of years. Release of SO2 also contributes to the widespread acidification of ecosystems. Disused coal mines can also cause issues. Subsidence can occur above tunnels, causing damage to infrastructure or cropland. Coal mining can also cause long lasting fires, and it has been estimated that thousands of
coal seam fire A coal-seam fire is a burning of an outcrop or underground coal seam. Most coal-seam fires exhibit smouldering combustion, particularly underground coal-seam fires, because of limited atmospheric oxygen availability. Coal-seam fire instances ...
s are burning at any given time. For example,
Brennender Berg The Brennender Berg (Burning Mountain) is a natural monument located in a deep and narrow gorge between Dudweiler and Sulzbach in Saarland, Germany. It is a smouldering coal-seam fire that ignited in 1668 and continues to burn today. History ...
has been burning since 1668 and is still burning in the 21st century. The production of coke from coal produces ammonia, coal tar, and gaseous compounds as byproducts which if discharged to land, air or waterways can pollute the environment. The Whyalla steelworks is one example of a coke producing facility where liquid ammonia was discharged to the marine environment.


Emission intensity

Emission intensity is the greenhouse gas emitted over the life of a generator per unit of electricity generated. The emission intensity of coal power stations is high, as they emit around 1000 g of CO2eq for each kWh generated, while natural gas is medium-emission intensity at around 500 g CO2eq per kWh. The emission intensity of coal varies with type and generator technology and exceeds 1200 g per kWh in some countries.


Underground fires

Thousands of coal fires are burning around the world. Those burning underground can be difficult to locate and many cannot be extinguished. Fires can cause the ground above to subside, their combustion gases are dangerous to life, and breaking out to the surface can initiate surface wildfires. Coal seams can be set on fire by spontaneous combustion or contact with a
mine fire A coal-seam fire is a burning of an outcrop or underground coal seam. Most coal-seam fires exhibit smouldering combustion, particularly underground coal-seam fires, because of limited atmospheric oxygen availability. Coal-seam fire instances ...
or surface fire. Lightning strikes are an important source of ignition. The coal continues to burn slowly back into the seam until oxygen (air) can no longer reach the flame front. A grass fire in a coal area can set dozens of coal seams on fire. Coal fires in China burn an estimated 120 million tons of coal a year, emitting 360 million metric tons of CO2, amounting to 2–3% of the annual worldwide production of CO2 from
fossil fuel A fossil fuel is a hydrocarbon-containing material formed naturally in the Earth's crust from the remains of dead plants and animals that is extracted and burned as a fuel. The main fossil fuels are coal, oil, and natural gas. Fossil fuels m ...
s. In Centralia, Pennsylvania (a borough located in the
Coal Region The Coal Region is a region of Northeastern Pennsylvania. It is known for being home to the largest known deposits of anthracite, anthracite coal in the world with an estimated reserve of seven billion short tons. The region is typically define ...
of the U.S.), an exposed vein of anthracite ignited in 1962 due to a trash fire in the borough landfill, located in an abandoned
anthracite Anthracite, also known as hard coal, and black coal, is a hard, compact variety of coal that has a submetallic luster. It has the highest carbon content, the fewest impurities, and the highest energy density of all types of coal and is the hig ...
strip mine pit. Attempts to extinguish the fire were unsuccessful, and it continues to burn underground to this day. The Australian
Burning Mountain Burning Mountain, the common name for Mount Wingen, is a hill near Wingen, New South Wales, Australia, approximately north of Sydney just off the New England Highway. It takes its name from a smouldering coal seam running underground through t ...
was originally believed to be a volcano, but the smoke and ash come from a coal fire that has been burning for some 6,000 years. At Kuh i Malik in Yagnob Valley, Tajikistan, coal deposits have been burning for thousands of years, creating vast underground labyrinths full of unique minerals, some of them very beautiful. The reddish siltstone rock that caps many ridges and buttes in the Powder River Basin in Wyoming and in western North Dakota is called ''porcelanite'', which resembles the coal burning waste "clinker" or volcanic " scoria". Clinker is rock that has been fused by the natural burning of coal. In the Powder River Basin approximately 27 to 54 billion tons of coal burned within the past three million years. Wild coal fires in the area were reported by the Lewis and Clark Expedition as well as explorers and settlers in the area.


Climate change

The largest and most long-term effect of coal use is the release of carbon dioxide, a
greenhouse gas A greenhouse gas (GHG or GhG) is a gas that Absorption (electromagnetic radiation), absorbs and Emission (electromagnetic radiation), emits radiant energy within the thermal infrared range, causing the greenhouse effect. The primary greenhouse ...
that causes climate change. Coal-fired power plants were the single largest contributor to the growth in global CO2 emissions in 2018,Gençsü (2019), p. 8 40% of the total fossil fuel emissions, and more than a quarter of total emissions. Coal mining can emit methane, another greenhouse gas. In 2016 world gross carbon dioxide emissions from coal usage were 14.5 gigatonnes. For every megawatt-hour generated, coal-fired electric power generation emits around a tonne of carbon dioxide, which is double the approximately 500 kg of carbon dioxide released by a natural gas-fired electric plant. In 2013, the head of the UN climate agency advised that most of the world's coal reserves should be left in the ground to avoid catastrophic global warming. To keep global warming below 1.5 °C or 2 °C hundreds, or possibly thousands, of coal-fired power plants will need to be retired early.


Pollution mitigation


Standards

Local pollution standards include GB13223-2011 (China), India, the Industrial Emissions Directive (EU) and the
Clean Air Act (United States) The Clean Air Act (CAA) is the United States' primary federal air quality law, intended to reduce and control air pollution nationwide. Initially enacted in 1963 and amended many times since, it is one of the United States' first and most infl ...
.


Satellite monitoring

Satellite monitoring is now used to crosscheck national data, for example Sentinel-5 Precursor has shown that Chinese control of SO2 has only been partially successful. It has also revealed that low use of technology such as SCR has resulted in high NO2 emissions in South Africa and India.


Combined cycle power plants

A few Integrated gasification combined cycle (IGCC) coal-fired power plants have been built with
coal gasification Coal gasification is the process of producing syngas—a mixture consisting primarily of carbon monoxide (CO), hydrogen (H2), carbon dioxide (CO2), methane (CH4), and water vapour (H2O)—from coal and water, air and/or oxygen. Historically, coal ...
. Although they burn coal more efficiently and therefore emit less pollution, the technology has not generally proved economically viable for coal, except possibly in Japan although this is controversial.


Carbon capture and storage

Although still being intensively researched and considered economically viable for some uses other than with coal; carbon capture and storage has been tested at the
Petra Nova The Petra Nova project is a coal-energy-sector/clean-energy project designed to reduce carbon emissions from one of the boilers of a Fossil fuel power station, coal burning power plant in Thompsons, Texas. It is a multi-million dollar project take ...
and Boundary Dam coal-fired power plants and has been found to be technically feasible but not economically viable for use with coal, due to reductions in the cost of solar PV technology.


Economics

In 2018 was invested in coal supply but almost all for sustaining production levels rather than opening new mines. In the long term coal and oil could cost the world trillions of dollars per year. Coal alone may cost Australia billions, whereas costs to some smaller companies or cities could be on the scale of millions of dollars. The economies most damaged by coal (via climate change) may be India and the US as they are the countries with the highest social cost of carbon. Bank loans to finance coal are a risk to the Indian economy. China is the largest producer of coal in the world. It is the world's largest energy consumer, and
coal in China China is the largest producer and consumer of coal in the world. It is also the largest user of coal-generated electricity, with over a thousand coal-fired power stations. The share of coal in the energy mix declined during the 2010s, falli ...
supplies 60% of its primary energy. However two fifths of China's coal power stations are estimated to be loss-making. Air pollution from coal storage and handling costs the US almost 200 dollars for every extra ton stored, due to PM2.5. Coal pollution costs the each year. Measures to cut air pollution benefit individuals financially and the economies of countries such as China.


Subsidies

Subsidies for coal in 2021 have been estimated at , not including electricity subsidies, and are expected to rise in 2022. G20 countries provide at least of government support per year for the production of coal, including coal-fired power: many subsidies are impossible to quantify but they include in domestic and international public finance, in fiscal support, and in state-owned enterprise (SOE) investments per year. In the EU state aid to new coal-fired plants is banned from 2020, and to existing coal-fired plants from 2025. As of 2018, government funding for new coal power plants was supplied by Exim Bank of China, the
Japan Bank for International Cooperation The , JBIC, is a Japanese public financial institution and export credit agency that was created on October 1, 1999, through the merger of the Japan Export-Import Bank (JEXIM) and the Overseas Economic Cooperation Fund (OECF). JBIC became the in ...
and Indian public sector banks. Coal in Kazakhstan was the main recipient of coal consumption subsidies totalling US$2 billion in 2017. Coal in Turkey benefited from substantial subsidies in 2021.


Stranded assets

Some coal-fired power stations could become
stranded assets Stranded assets are "assets that have suffered from unanticipated or premature write-downs, devaluations or conversion to liabilities". Stranded assets can be caused by a variety of factors and are a phenomenon inherent in the 'creative destructi ...
, for example
China Energy Investment China Energy Investment Corporation, more commonly known as China Energy (), is a state-owned mining and energy company administrated by the SASAC of the State Council of the People's Republic of China. History On August 28, 2017, SASAC announce ...
, the world's largest power company, risks losing half its capital. However, state-owned electricity utilities such as Eskom in South Africa,
Perusahaan Listrik Negara PT Perusahaan Listrik Negara (Persero) ( 'State Electricity Company', abbreviated as PLN) is an Indonesian government-owned corporation which has a monopoly on electric power distribution in Indonesia and generates the majority of the country' ...
in Indonesia,
Sarawak Energy Sarawak Energy is the electric utility company of the Malaysian state of Sarawak. It is one of Malaysia's three electrical companies, the other two being Tenaga Nasional, supplying the Peninsular Malaysia, and Sabah Electricity, which serves t ...
in Malaysia, Taipower in Taiwan,
EGAT The Electricity Generating Authority of Thailand (EGAT) ( th, การไฟฟ้าฝ่ายผลิตแห่งประเทศไทย; ) is a state enterprise, managed by the Ministry of Energy, responsible for electric power ge ...
in Thailand, Vietnam Electricity and
EÜAŞ The Electricity Generation Company ( tr, Elektrik Üretim A.Ş.; EÜAŞ) is the largest electric power company in Turkey. Owned by the government, it produces and trades electricity throughout the country. History EÜAŞ was founded by the gov ...
in Turkey are building or planning new plants. As of 2021 this may be helping to cause a
carbon bubble The carbon bubble is a hypothesized bubble in the valuation of companies dependent on fossil-fuel-based energy production, resulting from future decreases in value of fossil fuel reserves as they become unusable in order to meet carbon budget ...
which could cause financial instability if it bursts.


Politics

Countries building or financing new coal-fired power stations, such as China, India, Indonesia, Vietnam, Turkey and Bangladesh, face mounting international criticism for obstructing the aims of the
Paris Agreement The Paris Agreement (french: Accord de Paris), often referred to as the Paris Accords or the Paris Climate Accords, is an international treaty on climate change. Adopted in 2015, the agreement covers climate change mitigation, Climate change a ...
. In 2019, the Pacific Island nations (in particular Vanuatu and
Fiji Fiji ( , ,; fj, Viti, ; Fiji Hindi: फ़िजी, ''Fijī''), officially the Republic of Fiji, is an island country in Melanesia, part of Oceania in the South Pacific Ocean. It lies about north-northeast of New Zealand. Fiji consists ...
) criticized Australia for failing to cut their emissions at a faster rate than they were, citing concerns about coastal inundation and erosion. In May 2021, the G7 members agreed to end new direct government support for international coal power generation.


Opposition to coal

Opposition to coal pollution was one of the main reasons the modern environmental movement started in the 19th century.


Transition away from coal

In order to meet global climate goals and provide power to those that do not currently have it coal power must be reduced from nearly 10,000 TWh to less than 2,000 TWh by 2040. Phasing out coal has short-term health and environmental benefits which exceed the costs, but some countries still favor coal, and there is much disagreement about how quickly it should be phased out. However many countries, such as the
Powering Past Coal Alliance The Powering Past Coal Alliance (PPCA) is a group of 166 countries, cities, regions and organisations aiming to accelerate the fossil-fuel phase out of coal-fired power stations, except the very few which have carbon capture and storage. It ha ...
, have already or are transitioned away from coal; the largest transition announced so far being Germany, which is due to shut down its last coal-fired power station between 2035 and 2038. Some countries use the ideas of a "
Just Transition Just transition is a framework developed by the trade union movement to encompass a range of social interventions needed to secure workers' rights and livelihoods when economies are shifting to sustainable production, primarily combating climat ...
", for example to use some of the benefits of transition to provide early pensions for coal miners. However, low-lying
Pacific Islands Collectively called the Pacific Islands, the islands in the Pacific Ocean are further categorized into three major island groups: Melanesia, Micronesia, and Polynesia. Depending on the context, the term ''Pacific Islands'' may refer to one of se ...
are concerned the transition is not fast enough and that they will be inundated by sea level rise, so they have called for OECD countries to completely phase out coal by 2030 and other countries by 2040. In 2020, although China built some plants, globally more coal power was retired than built: the UN Secretary General has also said that OECD countries should stop generating electricity from coal by 2030 and the rest of the world by 2040. Phasing down coal was agreed at
COP26 The 2021 United Nations Climate Change Conference, more commonly referred to as COP26, was the 26th United Nations Climate Change conference, held at the SEC Centre in Glasgow, Scotland, United Kingdom, from 31 October to 13 November 2021. The ...
in the
Glasgow Climate Pact The Glasgow Climate Pact is an agreement reached at the 2021 United Nations Climate Change Conference (COP26). The pact is the first climate agreement explicitly planning to reduce unabated coal usage. A pledge to "phase out" coal was change ...
.


Peak coal


Switch to cleaner fuels and lower carbon electricity generation

Coal-fired generation puts out about twice as much carbon dioxide—around a tonne for every megawatt hour generated—as electricity generated by burning natural gas at 500 kg of
greenhouse gas A greenhouse gas (GHG or GhG) is a gas that Absorption (electromagnetic radiation), absorbs and Emission (electromagnetic radiation), emits radiant energy within the thermal infrared range, causing the greenhouse effect. The primary greenhouse ...
per megawatt hour. In addition to generating electricity, natural gas is also popular in some countries for heating and as an automotive fuel. The use of
coal in the United Kingdom Coal is a combustible black or brownish-black sedimentary rock, formed as rock strata called coal seams. Coal is mostly carbon with variable amounts of other elements, chiefly hydrogen, sulfur, oxygen, and nitrogen. Coal is formed when de ...
declined as a result of the development of North Sea oil and the subsequent dash for gas during the 1990s. In Canada some coal power plants, such as the Hearn Generating Station, switched from coal to natural gas. In 2017,
coal power in the US Coal generated about 22% of the Electricity sector of the United States, electricity at utility-scale facilities in the United States in 2021, down from 39% in 2014. In 2021, coal supplied of primary energy to electric power plants, which ...
provided 30% of the electricity, down from approximately 49% in 2008, due to plentiful supplies of low cost natural gas obtained by
hydraulic fracturing Fracking (also known as hydraulic fracturing, hydrofracturing, or hydrofracking) is a well stimulation technique involving the fracturing of bedrock formations by a pressurized liquid. The process involves the high-pressure injection of "frack ...
of tight shale formations.


Coal regions in transition

Some
coal-mining region Coal mining regions are significant Natural resource#Extraction, resource extraction industries in many parts of the world. They provide a large amount of the fossil fuel energy in the world economy. The China, People's Republic of China is the la ...
s are highly dependent on coal.


Employment

Some coal miners are concerned their jobs may be lost in the transition. A
just transition Just transition is a framework developed by the trade union movement to encompass a range of social interventions needed to secure workers' rights and livelihoods when economies are shifting to sustainable production, primarily combating climat ...
from coal is supported by the
European Bank for Reconstruction and Development The European Bank for Reconstruction and Development (EBRD) is an international financial institution founded in 1991. As a multilateral developmental investment bank, the EBRD uses investment as a tool to build market economies. Initially focus ...
.


Bioremediation

The white rot fungus '' Trametes versicolor'' can grow on and metabolize naturally occurring coal. The bacteria Diplococcus has been found to degrade coal, raising its temperature.


Cultural usage

Coal is the official state mineral of Kentucky and the official state rock of Utah; both US states have a historic link to coal mining. Some cultures hold that children who misbehave will receive only a lump of coal from
Santa Claus Santa Claus, also known as Father Christmas, Saint Nicholas, Saint Nick, Kris Kringle, or simply Santa, is a Legend, legendary figure originating in Western Christianity, Western Christian culture who is said to Christmas gift-bringer, bring ...
for Christmas in their stockings instead of presents. It is also customary and considered lucky in Scotland and the
North of England Northern England, also known as the North of England, the North Country, or simply the North, is the northern area of England. It broadly corresponds to the former borders of Angle Northumbria, the Anglo-Scandinavian Kingdom of Jorvik, and the ...
to give coal as a gift on
New Year's Day New Year's Day is a festival observed in most of the world on 1 January, the first day of the year in the modern Gregorian calendar. 1 January is also New Year's Day on the Julian calendar, but this is not the same day as the Gregorian one. Wh ...
. This occurs as part of
first-footing In Scottish, Northern English, and Manx folklore, the first-foot ( gd, ciad-chuairt, gv, quaaltagh/qualtagh) is the first person to enter the home of a household on New Year's Day and is seen as a bringer of good fortune for the coming year. Simi ...
and represents warmth for the year to come.


See also

* * * * * * (stratigraphic unit) * * * * * * * * *


Notes


References


Sources

*


Further reading

* * *


External links


Coal Transitions

World Coal Association

Coal – International Energy Agency

Coal Online – International Energy Agency

CoalExit

European Association for Coal and Lignite

Coal news and industry magazine

Global Coal Plant Tracker

Centre for Research on Energy and Clean Air
* * * {{Authority control Coal mining Economic geology Fuels Sedimentary rocks Solid fuels