Berlinite (
aluminium phosphate
Aluminium phosphate is a chemical compound. In nature it occurs as the mineral berlinite. Many synthetic forms of aluminium phosphate are known. They have framework structures similar to zeolites and some are used as catalysts, ion-exchangers or ...
, chemical formula
AlPO
4 or Al(PO
4)) is a rare high-temperature
hydrothermal
Hydrothermal circulation in its most general sense is the circulation of hot water (Ancient Greek ὕδωρ, ''water'',Liddell, H.G. & Scott, R. (1940). ''A Greek-English Lexicon. revised and augmented throughout by Sir Henry Stuart Jones. with th ...
or
metasomatic
Metasomatism (from the Greek μετά ''metá'' "change" and σῶμα ''sôma'' "body") is the chemical alteration of a rock by hydrothermal and other fluids. It is the replacement of one rock by another of different mineralogical and chemical com ...
phosphate mineral
Phosphate minerals contain the tetrahedrally coordinated phosphate (PO43−) anion along sometimes with arsenate (AsO43−) and vanadate (VO43−) substitutions, and chloride (Cl−), fluoride (F−), and hydroxide (OH−) anions that also fit i ...
.
It has the same crystal structure as
quartz
Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical form ...
with a low temperature
polytype
In materials science, polymorphism describes the existence of a solid material in more than one form or crystal structure. Polymorphism is a form of isomerism. Any crystalline material can exhibit the phenomenon. Allotropy refers to polymorphism ...
isostructural with α–quartz and a high temperature polytype isostructural with β–quartz.
[ Berlinite can vary from colorless to greyish or pale pink and has translucent crystals.][
It was first described in 1868 for an occurrence in the ]Västanå
Västanå is a village situated in Bromölla Municipality, Skåne County, Sweden with 130 inhabitants in 2005.
Västanå iron mine
In 1800 an iron ore deposit was discovered and mining began in 1804. Till the closure in 1917, 1500 tonnes of iro ...
iron mine, Scania
Scania, also known by its native name of Skåne (, ), is the southernmost of the historical provinces of Sweden, provinces (''landskap'') of Sweden. Located in the south tip of the geographical region of Götaland, the province is roughly conte ...
, Sweden
Sweden, formally the Kingdom of Sweden,The United Nations Group of Experts on Geographical Names states that the country's formal name is the Kingdom of SwedenUNGEGN World Geographical Names, Sweden./ref> is a Nordic country located on ...
and named for Nils Johan Berlin
Nils Johan Berlin (Nils Johannes Berlin) (18 February 1812 – 27 December 1891) was a Swedish chemist and physician, who held various professorships at the University of Lund from 1843 to 1864. Berlin was the first chemist who took the initiativ ...
(1812–1891) of Lund University
, motto = Ad utrumque
, mottoeng = Prepared for both
, established =
, type = Public research university
, budget = SEK 9 billion [hydrothermal
Hydrothermal circulation in its most general sense is the circulation of hot water (Ancient Greek ὕδωρ, ''water'',Liddell, H.G. & Scott, R. (1940). ''A Greek-English Lexicon. revised and augmented throughout by Sir Henry Stuart Jones. with th ...]
or metasomatic
Metasomatism (from the Greek μετά ''metá'' "change" and σῶμα ''sôma'' "body") is the chemical alteration of a rock by hydrothermal and other fluids. It is the replacement of one rock by another of different mineralogical and chemical com ...
deposits.[ Associated minerals include ]augelite
Augelite is an aluminium phosphate mineral with formula: Al2( P O4)(O H)3. The shade varies from colorless to white, yellow or rose. Its crystal system is monoclinic.Richard V. Gaines, H. Catherine W. Skinner, Eugene E. Foord, Brian Mason, and Ab ...
, attakolite, kyanite
Kyanite is a typically blue aluminosilicate mineral, found in aluminium-rich metamorphic pegmatites and sedimentary rock. It is the high pressure polymorph of andalusite and sillimanite, and the presence of kyanite in metamorphic rocks gener ...
, pyrophyllite
Pyrophyllite is a phyllosilicate mineral composed of aluminium silicate hydroxide: Al2Si4O10(OH)2. It occurs in two forms (habits): crystalline folia and compact masses; distinct crystals are not known.
The folia have a pronounced pearly luste ...
, scorzalite
Scorzalite () is a dark blue phosphate mineral containing iron, magnesium, and aluminium phosphate. Scorzalite forms one endmember of a solid solution series with the lighter, more magnesium-rich lazulite.
Scorzalite crystallizes in the monoclini ...
, lazulite
Lazulite () is a blue, phosphate mineral containing magnesium, iron, and aluminium phosphate. Lazulite forms one endmember of a solid solution series with the darker iron rich scorzalite.
Lazulite crystallizes in the monoclinic system. Crystal ...
, gatumbaite, burangaite, amblygonite
Amblygonite () is a fluorophosphate mineral, , composed of lithium, sodium, aluminium, phosphate, fluoride and hydroxide. The mineral occurs in pegmatite deposits and is easily mistaken for albite and other feldspars. Its density, cleavage and ...
, phosphosiderite
Phosphosiderite is a rare mineral named for its main components, phosphate and iron. The siderite at the end of phosphosiderite comes from the word "sideros", the Greek word for iron. It was published in 1890, and has been a valid species since p ...
, purpurite
Purpurite is a mineral, manganese phosphate, MnPO4 with varying amounts of iron depending upon its source. It occurs in color ranges from brownish black via purple and violet to dark red.
Purpurite forms a series with the iron-bearing endmember ...
, apatite
Apatite is a group of phosphate minerals, usually hydroxyapatite, fluorapatite and chlorapatite, with high concentrations of OH−, F− and Cl− ions, respectively, in the crystal. The formula of the admixture of the three most common e ...
, muscovite
Muscovite (also known as common mica, isinglass, or potash mica) is a hydrated phyllosilicate mineral of aluminium and potassium with formula K Al2(Al Si3 O10)( F,O H)2, or ( KF)2( Al2O3)3( SiO2)6( H2O). It has a highly perfect basal cleavag ...
, quartz
Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical form ...
, hematite
Hematite (), also spelled as haematite, is a common iron oxide compound with the formula, Fe2O3 and is widely found in rocks and soils. Hematite crystals belong to the rhombohedral lattice system which is designated the alpha polymorph of . ...
in granite
Granite () is a coarse-grained (phaneritic) intrusive igneous rock composed mostly of quartz, alkali feldspar, and plagioclase. It forms from magma with a high content of silica and alkali metal oxides that slowly cools and solidifies undergro ...
pegmatite
A pegmatite is an igneous rock showing a very coarse texture, with large interlocking crystals usually greater in size than and sometimes greater than . Most pegmatites are composed of quartz, feldspar, and mica, having a similar silicic com ...
s. It also occurs with alunite, aragonite
Aragonite is a carbonate mineral, one of the three most common naturally occurring crystal forms of calcium carbonate, (the other forms being the minerals calcite and vaterite). It is formed by biological and physical processes, including prec ...
, collophane
Apatite is a group of phosphate minerals, usually hydroxyapatite, fluorapatite and chlorapatite, with high concentrations of Hydroxide, OH−, Fluoride, F− and Chloride, Cl− ions, respectively, in the crystal. The formula of the admixture ...
, crandallite
Crandallite is a calcium aluminium basic phosphate mineral. It has ideal formula .
Crandallite was named after Milan L. Crandall, Jr, who worked for Knight Syndicate.
This mineral is found in laterite and in alteration products of phosphate rich ...
, francoanellite, gypsum
Gypsum is a soft sulfate mineral composed of calcium sulfate dihydrate, with the chemical formula . It is widely mined and is used as a fertilizer and as the main constituent in many forms of plaster, blackboard or sidewalk chalk, and drywall. ...
, huntite
Huntite is a carbonate mineral with the chemical formula Mg3Ca(CO3)4. Huntite crystallizes in the trigonal system and typically occurs as platy crystals and powdery masses. For most of recorded history its main use was as a white pigment. Today ...
, hydromagnesite
Hydromagnesite is a hydrated magnesium carbonate mineral with the formula Mg5(CO3)4(OH)2·4H2O.
It generally occurs associated with the weathering products of magnesium containing minerals such as serpentine or brucite. It occurs as incrustations ...
, leucophosphite, nesquehonite
Magnesium carbonate, (archaic name magnesia alba), is an inorganic salt that is a colourless or white solid. Several hydrated and basic forms of magnesium carbonate also exist as minerals.
Forms
The most common magnesium carbonate forms are ...
, niter
Niter or nitre is the mineral form of potassium nitrate, KNO3. It is a soft, white, highly soluble mineral found primarily in arid climates or cave deposits.
Historically, the term ''niter'' was not well differentiated from natron, both of w ...
, and nitrocalcite in the Paddy's River copper mine in the Brindabella Mountains of Australia
Australia, officially the Commonwealth of Australia, is a Sovereign state, sovereign country comprising the mainland of the Australia (continent), Australian continent, the island of Tasmania, and numerous List of islands of Australia, sma ...
.[
]
References
Further reading
*
Phosphate minerals
Trigonal minerals
Minerals in space group 152 or 154
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