Purpurite
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Purpurite
Purpurite is a mineral, manganese phosphate, MnPO4 with varying amounts of iron depending upon its source. It occurs in color ranges from brownish black via purple and violet to dark red. Purpurite forms a series with the iron-bearing endmember heterosite, FePO4. See also *Manganese violet Manganese violet is the common name for ammonium manganese(III) pyrophosphate, an inorganic compound composed of ammonium (), manganese in the +3 oxidation state, and the pyrophosphate anion (). It is prepared by heating a mixture of manganese(I ... References Manganese(III) minerals Iron(III) minerals Phosphate minerals Orthorhombic minerals Minerals in space group 53 {{Phosphate-mineral-stub ...
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Phosphate Minerals
Phosphate minerals contain the tetrahedrally coordinated phosphate (PO43−) anion along sometimes with arsenate (AsO43−) and vanadate (VO43−) substitutions, and chloride (Cl−), fluoride (F−), and hydroxide (OH−) anions that also fit into the crystal structure. The phosphate class of minerals is a large and diverse group, however, only a few species are relatively common. Applications Phosphate rock has high concentration of phosphate minerals, most commonly of the apatite group. It is the major resource mined to produce phosphate fertilizers for the agriculture sector. Phosphate is also used in animal feed supplements, food preservatives, anti-corrosion agents, cosmetics, fungicides, ceramics, water treatment and metallurgy. The largest use of minerals mined for their phosphate content is the production of fertilizer. Phosphate minerals are often used for control of rust and prevention of corrosion on ferrous materials applied with electrochemical conversion co ...
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Orthorhombic
In crystallography, the orthorhombic crystal system is one of the 7 crystal systems. Orthorhombic lattices result from stretching a cubic lattice along two of its orthogonal pairs by two different factors, resulting in a rectangular prism with a rectangular base (''a'' by ''b'') and height (''c''), such that ''a'', ''b'', and ''c'' are distinct. All three bases intersect at 90° angles, so the three lattice vectors remain mutually orthogonal. Bravais lattices There are four orthorhombic Bravais lattices: primitive orthorhombic, base-centered orthorhombic, body-centered orthorhombic, and face-centered orthorhombic. For the base-centered orthorhombic lattice, the primitive cell has the shape of a right rhombic prism;See , row oC, column Primitive, where the cell parameters are given as a1 = a2, α = β = 90° it can be constructed because the two-dimensional centered rectangular base layer can also be described with primitive rhombic axes. Note that the length a of the primit ...
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Manganese
Manganese is a chemical element with the symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese is a transition metal with a multifaceted array of industrial alloy uses, particularly in stainless steels. It improves strength, workability, and resistance to wear. Manganese oxide is used as an oxidising agent; as a rubber additive; and in glass making, fertilisers, and ceramics. Manganese sulfate can be used as a fungicide. Manganese is also an essential human dietary element, important in macronutrient metabolism, bone formation, and free radical defense systems. It is a critical component in dozens of proteins and enzymes. It is found mostly in the bones, but also the liver, kidneys, and brain. In the human brain, the manganese is bound to manganese metalloproteins, most notably glutamine synthetase in astrocytes. Manganese was first isolated in 1774. It is familiar in the laboratory in the form of the ...
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Phosphate
In chemistry, a phosphate is an anion, salt, functional group or ester derived from a phosphoric acid. It most commonly means orthophosphate, a derivative of orthophosphoric acid . The phosphate or orthophosphate ion is derived from phosphoric acid by the removal of three protons . Removal of one or two protons gives the dihydrogen phosphate ion and the hydrogen phosphate ion ion, respectively. These names are also used for salts of those anions, such as ammonium dihydrogen phosphate and trisodium phosphate. File:3-phosphoric-acid-3D-balls.png, Phosphoricacid File:2-dihydrogenphosphate-3D-balls.png, Dihydrogenphosphate File:1-hydrogenphosphate-3D-balls.png, Hydrogenphosphate File:0-phosphate-3D-balls.png, Phosphate In organic chemistry, phosphate or orthophosphate is an organophosphate, an ester of orthophosphoric acid of the form where one or more hydrogen atoms are replaced by organic groups. An example is trimethyl phosphate, . The term also refers to the triv ...
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Manganese Violet
Manganese violet is the common name for ammonium manganese(III) pyrophosphate, an inorganic compound composed of ammonium (), manganese in the +3 oxidation state, and the pyrophosphate anion (). It is prepared by heating a mixture of manganese(III) oxide (), diammonium phosphate, and phosphoric acid. This material is a popular inorganic pigment.Hugo Müller, Wolfgang Müller, Manfred Wehner, Heike Liewald "Artists' Colors" in Ullmann's Encyclopedia of Industrial Chemistry 2002, Wiley-VCH, Weinheim. Chemical structure Two polymorphs are known, referred to as the α- and β-forms, but in each case the structures are similar. The Mn(III) centres occupy distorted octahedral sites, being surrounded by six oxygens provided by the pyrophosphate ligands. Spectra IR-spectra, reflectance, and fluorescence spectra can be found at ColourLex. Use Manganese violet is used in eye liner pencils, eye shadow, lipstick, nail enamel, and oil paint. See also *List of inorganic pigments The fo ...
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Manganese(III) Minerals
Manganese is a chemical element with the symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese is a transition metal with a multifaceted array of industrial alloy uses, particularly in stainless steels. It improves strength, workability, and resistance to wear. Manganese oxide is used as an oxidising agent; as a rubber additive; and in glass making, fertilisers, and ceramics. Manganese sulfate can be used as a fungicide. Manganese is also an essential human dietary element, important in macronutrient metabolism, bone formation, and free radical defense systems. It is a critical component in dozens of proteins and enzymes. It is found mostly in the bones, but also the liver, kidneys, and brain. In the human brain, the manganese is bound to manganese metalloproteins, most notably glutamine synthetase in astrocytes. Manganese was first isolated in 1774. It is familiar in the laboratory in the form of t ...
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Iron(III) Minerals
Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in front of oxygen (32.1% and 30.1%, respectively), forming much of Earth's outer and inner core. It is the fourth most common element in the Earth's crust. In its metallic state, iron is rare in the Earth's crust, limited mainly to deposition by meteorites. Iron ores, by contrast, are among the most abundant in the Earth's crust, although extracting usable metal from them requires kilns or furnaces capable of reaching or higher, about higher than that required to smelt copper. Humans started to master that process in Eurasia during the 2nd millennium BCE and the use of iron tools and weapons began to displace copper alloys, in some regions, only around 1200 BCE. That event is considered the transition from the Bronze Age to the Iron Age. ...
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Orthorhombic Minerals
In crystallography, the orthorhombic crystal system is one of the 7 crystal systems. Orthorhombic lattices result from stretching a cubic lattice along two of its orthogonal pairs by two different factors, resulting in a rectangular prism with a rectangular base (''a'' by ''b'') and height (''c''), such that ''a'', ''b'', and ''c'' are distinct. All three bases intersect at 90° angles, so the three lattice vectors remain mutually orthogonal. Bravais lattices There are four orthorhombic Bravais lattices: primitive orthorhombic, base-centered orthorhombic, body-centered orthorhombic, and face-centered orthorhombic. For the base-centered orthorhombic lattice, the primitive cell has the shape of a right rhombic prism;See , row oC, column Primitive, where the cell parameters are given as a1 = a2, α = β = 90° it can be constructed because the two-dimensional centered rectangular base layer can also be described with primitive rhombic axes. Note that the length a of the primiti ...
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