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Manganese Violet
Manganese violet is the common name for ammonium manganese(III) pyrophosphate, an inorganic compound composed of ammonium (), manganese in the +3 oxidation state, and the pyrophosphate anion (). It is prepared by heating a mixture of manganese(III) oxide (), diammonium phosphate, and phosphoric acid. This material is a popular inorganic pigment.Hugo Müller, Wolfgang Müller, Manfred Wehner, Heike Liewald "Artists' Colors" in Ullmann's Encyclopedia of Industrial Chemistry 2002, Wiley-VCH, Weinheim. Chemical structure Two polymorphs are known, referred to as the α- and β-forms, but in each case the structures are similar. The Mn(III) centres occupy distorted octahedral sites, being surrounded by six oxygens provided by the pyrophosphate ligands. Spectra IR-spectra, reflectance, and fluorescence spectra can be found at ColourLex. Use Manganese violet is used in eye liner pencils, eye shadow, lipstick, nail enamel, and oil paint. See also *List of inorganic pigments The fo ...
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Inorganic Compound
In chemistry, an inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds, that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as '' inorganic chemistry''. Inorganic compounds comprise most of the Earth's crust, although the compositions of the deep mantle remain active areas of investigation. Some simple carbon compounds are often considered inorganic. Examples include the allotropes of carbon (graphite, diamond, buckminsterfullerene, etc.), carbon monoxide, carbon dioxide, carbides, and the following salts of inorganic anions: carbonates, cyanides, cyanates, and thiocyanates. Many of these are normal parts of mostly organic systems, including organisms; describing a chemical as inorganic does not necessarily mean that it does not occur within living things. History Friedrich Wöhler's conversion of ammonium cyanate into urea in 1828 is often cited as the starting point of modern ...
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Eye Liner
Eye liner or eyeliner is a cosmetic used to define the eyes. It is applied around the contours of the eye(s). It is often used to create various aesthetic effects. History Eye liner was first used in ancient India, ancient Egypt and Mesopotamia as a dark black line around the eyes. As early as 10,000 BC, Egyptians and Mesopotamians wore various cosmetics including eye liner not only for aesthetics but to protect the skin from the desert sun. Research has also speculated that eye liner was worn to protect the wearer from the evil eye. The characteristic of having heavily lined eyes has been frequently depicted in ancient Egyptian art. They produced eye liner with a variety of materials, including copper ore and antimony. Ancient Egyptian kohl contained galena, which was imported from nearby regions in the Land of Punt, Coptos and Western Asia.''Studies in Ancient Technology'', Volume III, (Brill Archive), p.18. In the 1960s, liquid eye liner was used to create thick black and ...
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Manganese(III) Compounds
Manganese is a chemical element with the symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese is a transition metal with a multifaceted array of industrial alloy uses, particularly in stainless steels. It improves strength, workability, and resistance to wear. Manganese oxide is used as an oxidising agent; as a rubber additive; and in glass making, fertilisers, and ceramics. Manganese sulfate can be used as a fungicide. Manganese is also an essential human dietary element, important in macronutrient metabolism, bone formation, and free radical defense systems. It is a critical component in dozens of proteins and enzymes. It is found mostly in the bones, but also the liver, kidneys, and brain. In the human brain, the manganese is bound to manganese metalloproteins, most notably glutamine synthetase in astrocytes. Manganese was first isolated in 1774. It is familiar in the laboratory in the form of t ...
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List Of Inorganic Pigments
The following list includes commercially or artistically important inorganic pigments of natural and synthetic origin.. Purple pigments Aluminum pigments * Ultramarine violet: (PV15) - a synthetic or naturally occurring sulfur containing silicate mineral. Copper pigments *Han purple: BaCuSi2O6. Cobalt pigments *Cobalt violet: (PV14) Co3(PO4)2. Manganese pigments *Manganese violet: NH4MnP2O7 (PV16) manganic ammonium pyrophosphate. Gold pigments *Purple of Cassius: Gold nanoparticles suspended in tin dioxide - Aux • SnO2. Blue pigments Aluminum pigments *Ultramarine (PB29): a synthetic or naturally occurring sulfur containing silicate mineral - (generalized formula) *Persian blue: made by grinding up the mineral Lapis lazuli. The most important mineral component of lapis lazuli is lazurite (25% to 40%), a feldspathoid silicate mineral with the formula . Cobalt pigments *Cobalt blue (PB28): cobalt(II) aluminate. * Cerulean blue (PB35): cobalt(II) stannate. *Cerium ura ...
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Oil Paint
Oil paint is a type of slow-drying paint that consists of particles of pigment suspended in a drying oil, commonly linseed oil. The viscosity of the paint may be modified by the addition of a solvent such as turpentine or white spirit, and varnish may be added to increase the glossiness of the dried oil paint film. The addition of oil or alkyd medium can also be used to modify the viscosity and drying time of oil paint. Oil paints were first used in Asia as early as the 7th century AD and can be seen in examples of Buddhist paintings in Afghanistan. Oil-based paints made their way to Europe by the 12th century and were used for simple decoration, but oil painting did not begin to be adopted as an artistic medium there until the early 15th century. Common modern applications of oil paint are in finishing and protection of wood in buildings and exposed metal structures such as ships and bridges. Its hard-wearing properties and luminous colors make it desirable for both interior ...
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Nail Enamel
Nail polish (also known as nail varnish or nail enamel) is a lacquer that can be applied to the human fingernail or toenails to decorate and protect the nail plates. The formula has been revised repeatedly to enhance its decorative properties and to suppress cracking or peeling. Nail polish consists of a mix of an organic polymer and several other components that give it colors and textures. Nail polishes come in all color shades and play a significant part in manicures and pedicures. History Nail polish originated in China and dates back to 3000 BCE. Around 600 BCE, during the Zhou dynasty, the royal house preferred the colors gold and silver. However, red and black eventually replaced these metallic colors as royal favorites. During the Ming dynasty, nail polish was often made from a mixture that included beeswax, egg whites, gelatin, vegetable dyes, and gum arabic. In Egypt, the lower classes wore pale colors, whereas high society painted their nails reddish brown, w ...
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Lipstick
Lipstick is a cosmetic product used to apply coloration and texture to lips, often made of wax and oil. Different pigments are used to produce color, and minerals such as silica may be used to provide texture. The use of lipstick dates back to early civilizations such as Sumer and the Indus Valley Civilisation, and was popularized in the Western world in the 16th century. Some lipsticks contain traces of toxic materials, such as lead and PFAS, which prompted health concerns and regulation. Lipstick has been prominent in several women's fashion trends, often associated with women's sexuality. The color of lipstick has aesthetic and cultural significance as different colors carry different connotations. Red lipstick has historically been associated with sensuality or women's independence while black lipstick is worn by both men and women in alternative subcultures, especially punk and goth. Celebrities such as Elizabeth Taylor, Madonna, and Taylor Swift have contributed to the p ...
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Eye Shadow
Eye shadow (or eyeshadow) is a cosmetic applied primarily to the eyelids to attract attention to the wearer's eyes, making them stand out or look more attractive. Eye shadow can also be applied under the eyes, on the cheeks, or to brow bones. Civilizations around the world use eye shadow predominantly on females but also occasionally on males. In Western society, it is seen as a feminine cosmetic, even when used by men. In Gothic fashion, black or similarly dark-colored eye shadow and other types of eye makeup are popular among both sexes. In ancient Egypt, it was customarily used by both sexes Kohl, an ancient eye cosmetic, played a prominent role in various cultures and religious practices. The use of eye shadow attempts to replicate the natural eyelid coloration that some women exhibit due to a natural contrasting pigmentation on their eyelids. Natural eye shadow can range anywhere from a glossy shine on one's eyelids, to a pinkish tone, or even a silver look. Use Eye sha ...
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Octahedral Molecular Geometry
In chemistry, octahedral molecular geometry, also called square bipyramidal, describes the shape of compounds with six atoms or groups of atoms or ligands symmetrically arranged around a central atom, defining the vertices of an octahedron. The octahedron has eight faces, hence the prefix ''octa''. The octahedron is one of the Platonic solids, although octahedral molecules typically have an atom in their centre and no bonds between the ligand atoms. A perfect octahedron belongs to the point group Oh. Examples of octahedral compounds are sulfur hexafluoride SF6 and molybdenum hexacarbonyl Mo(CO)6. The term "octahedral" is used somewhat loosely by chemists, focusing on the geometry of the bonds to the central atom and not considering differences among the ligands themselves. For example, , which is not octahedral in the mathematical sense due to the orientation of the bonds, is referred to as octahedral. The concept of octahedral coordination geometry was developed by Alfred Wern ...
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Ammonium
The ammonium cation is a positively-charged polyatomic ion with the chemical formula or . It is formed by the protonation of ammonia (). Ammonium is also a general name for positively charged or protonated substituted amines and quaternary ammonium cations (), where one or more hydrogen atoms are replaced by organic groups (indicated by R). Acid–base properties The ammonium ion is generated when ammonia, a weak base, reacts with Brønsted acids (proton donors): :H+ + NH3 -> H4 The ammonium ion is mildly acidic, reacting with Brønsted bases to return to the uncharged ammonia molecule: : H4 + B- -> HB + NH3 Thus, treatment of concentrated solutions of ammonium salts with strong base gives ammonia. When ammonia is dissolved in water, a tiny amount of it converts to ammonium ions: :H2O + NH3 OH- + H4 The degree to which ammonia forms the ammonium ion depends on the pH of the solution. If the pH is low, the equilibrium shifts to the right: more ammonia molecules are co ...
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Polymorphism (materials Science)
In materials science, polymorphism describes the existence of a solid material in more than one form or crystal structure. Polymorphism is a form of isomerism. Any crystalline material can exhibit the phenomenon. Allotropy refers to polymorphism for chemical elements. Polymorphism is of practical relevance to pharmaceuticals, agrochemicals, pigments, dyestuffs, foods, and explosives. According to IUPAC, a polymorphic transition is "A reversible transition of a solid crystalline phase at a certain temperature and pressure (the inversion point) to another phase of the same chemical composition with a different crystal structure." According to McCrone, polymorphs are "different in crystal structure but identical in the liquid or vapor states." Materials with two polymorphs are called dimorphic, with three polymorphs, trimorphic, etc. Examples Many compounds exhibit polymorphism. It has been claimed that "every compound has different polymorphic forms, and that, in general, the n ...
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