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In chemistry, there are three definitions in common use of the word base, known as Arrhenius bases, Brønsted bases, and Lewis bases. All definitions agree that bases are substances that react with acids, as originally proposed by G.-F. Rouelle in the mid-18th century. In 1884,
Svante Arrhenius Svante August Arrhenius ( , ; 19 February 1859 – 2 October 1927) was a Swedish scientist. Originally a physicist, but often referred to as a chemist, Arrhenius was one of the founders of the science of physical chemistry. He received the N ...
proposed that a base is a substance which dissociates in
aqueous An aqueous solution is a solution in which the solvent is water. It is mostly shown in chemical equations by appending (aq) to the relevant chemical formula. For example, a solution of table salt, or sodium chloride (NaCl), in water would ...
solution to form
Hydroxide Hydroxide is a diatomic anion with chemical formula OH−. It consists of an oxygen and hydrogen atom held together by a single covalent bond, and carries a negative electric charge. It is an important but usually minor constituent of water ...
ions OH. These ions can react with hydrogen ions (H+ according to Arrhenius) from the dissociation of acids to form water in an
acid–base reaction An acid–base reaction is a chemical reaction that occurs between an acid and a base. It can be used to determine pH via titration. Several theoretical frameworks provide alternative conceptions of the reaction mechanisms and their applic ...
. A base was therefore a metal hydroxide such as NaOH or Ca(OH)2. Such aqueous hydroxide solutions were also described by certain characteristic properties. They are slippery to the touch, can taste
bitter Bitter may refer to: Common uses * Resentment, negative emotion or attitude, similar to being jaded, cynical or otherwise negatively affected by experience * Bitter (taste), one of the five basic tastes Books * ''Bitter (novel)'', a 2022 novel ...
and change the color of
pH indicator A pH indicator is a halochromic chemical compound added in small amounts to a solution so the pH (acidity or basicity) of the solution can be determined visually or spectroscopically by changes in absorption and/or emission properties. Hen ...
s (e.g., turn red
litmus paper Litmus is a water-soluble mixture of different dyes extracted from lichens. It is often absorbed onto filter paper to produce one of the oldest forms of pH indicator, used to test materials for acidity. It is a purple dye that is extrac ...
blue). In water, by altering the autoionization equilibrium, bases yield solutions in which the hydrogen ion activity is lower than it is in pure water, i.e., the water has a pH higher than 7.0 at standard conditions. A soluble base is called an
alkali In chemistry, an alkali (; from ar, القلوي, al-qaly, lit=ashes of the saltwort) is a basic, ionic salt of an alkali metal or an alkaline earth metal. An alkali can also be defined as a base that dissolves in water. A solution of ...
if it contains and releases OH ions quantitatively.
Metal oxide An oxide () is a chemical compound that contains at least one oxygen atom and one other element in its chemical formula. "Oxide" itself is the dianion of oxygen, an O2– (molecular) ion. with oxygen in the oxidation state of −2. Most of the E ...
s, hydroxides, and especially alkoxides are basic, and
conjugate base A conjugate acid, within the Brønsted–Lowry acid–base theory, is a chemical compound formed when an acid donates a proton () to a base—in other words, it is a base with a hydrogen ion added to it, as in the reverse reaction it loses a ...
s of
weak acid Acid strength is the tendency of an acid, symbolised by the chemical formula HA, to dissociate into a hydron (chemistry), proton, H+, and an anion, A-. The Dissociation (chemistry), dissociation of a strong acid in solution is effectively comple ...
s are weak bases. Bases and acids are seen as chemical opposites because the effect of an acid is to increase the
hydronium In chemistry, hydronium (hydroxonium in traditional British English) is the common name for the aqueous cation , the type of oxonium ion produced by protonation of water. It is often viewed as the positive ion present when an Arrhenius acid is di ...
(H3O+) concentration in water, whereas bases reduce this concentration. A reaction between aqueous solutions of an acid and a base is called neutralization, producing a solution of water and a
salt Salt is a mineral composed primarily of sodium chloride (NaCl), a chemical compound belonging to the larger class of salts; salt in the form of a natural crystalline mineral is known as rock salt or halite. Salt is present in vast quanti ...
in which the salt separates into its component ions. If the aqueous solution is saturated with a given salt
solute In chemistry, a solution is a special type of homogeneous mixture composed of two or more substances. In such a mixture, a solute is a substance dissolved in another substance, known as a solvent. If the attractive forces between the solve ...
, any additional such salt
precipitate In an aqueous solution, precipitation is the process of transforming a dissolved substance into an insoluble solid from a super-saturated solution. The solid formed is called the precipitate. In case of an inorganic chemical reaction leading ...
s out of the solution. In the more general
Brønsted–Lowry acid–base theory The Brønsted–Lowry theory (also called proton theory of acids and bases) is an acid–base reaction theory which was proposed independently by Johannes Nicolaus Brønsted and Thomas Martin Lowry in 1923. The fundamental concept of this the ...
(1923), a base is a substance that can accept hydrogen cations (H+)—otherwise known as protons. This does include aqueous hydroxides since OH does react with H+ to form water, so that Arrhenius bases are a subset of Brønsted bases. However, there are also other Brønsted bases which accept protons, such as aqueous solutions of
ammonia Ammonia is an inorganic compound of nitrogen and hydrogen with the formula . A stable binary hydride, and the simplest pnictogen hydride, ammonia is a colourless gas with a distinct pungent smell. Biologically, it is a common nitrogeno ...
(NH3) or its organic derivatives (
amine In chemistry, amines (, ) are compounds and functional groups that contain a basic nitrogen atom with a lone pair. Amines are formally derivatives of ammonia (), wherein one or more hydrogen atoms have been replaced by a substituent su ...
s). These bases do not contain a hydroxide ion but nevertheless react with water, resulting in an increase in the concentration of hydroxide ion. Also, some non-aqueous solvents contain Brønsted bases which react with solvated protons. For example in liquid ammonia, NH2 is the basic ion species which accepts protons from NH4+, the acidic species in this solvent.
G. N. Lewis Gilbert Newton Lewis (October 23 or October 25, 1875 – March 23, 1946) was an American physical chemist and a Dean of the College of Chemistry at University of California, Berkeley. Lewis was best known for his discovery of the covalent bond a ...
realized that water, ammonia, and other bases can form a bond with a proton due to the unshared pair of
electron The electron (, or in nuclear reactions) is a subatomic particle with a negative one elementary electric charge. Electrons belong to the first generation of the lepton particle family, and are generally thought to be elementary partic ...
s that the bases possess. In the
Lewis theory A Lewis acid (named for the American physical chemist Gilbert N. Lewis) is a chemical species that contains an empty orbital which is capable of accepting an electron pair from a Lewis base to form a Lewis adduct. A Lewis base, then, is any spe ...
, a base is an electron pair donor which can share a pair of electrons with an electron acceptor which is described as a Lewis acid. The Lewis theory is more general than the Brønsted model because the Lewis acid is not necessarily a proton, but can be another molecule (or ion) with a vacant low-lying
orbital Orbital may refer to: Sciences Chemistry and physics * Atomic orbital * Molecular orbital * Hybrid orbital Astronomy and space flight * Orbit ** Earth orbit Medicine and physiology * Orbit (anatomy), also known as the ''orbital bone'' * Orbito ...
which can accept a pair of electrons. One notable example is
boron trifluoride Boron trifluoride is the inorganic compound with the formula BF3. This pungent, colourless, and toxic gas forms white fumes in moist air. It is a useful Lewis acid and a versatile building block for other boron compounds. Structure and bondin ...
(BF3). Some other definitions of both bases and acids have been proposed in the past, but are not commonly used today.


Properties

General properties of bases include: *Concentrated or strong bases are caustic on organic matter and react violently with acidic substances. *Aqueous solutions or molten bases dissociate in ions and conduct electricity. *Reactions with
indicators Indicator may refer to: Biology * Environmental indicator of environmental health (pressures, conditions and responses) * Ecological indicator of ecosystem health (ecological processes) * Health indicator, which is used to describe the health ...
: bases turn red litmus paper blue, phenolphthalein pink, keep bromothymol blue in its natural colour of blue, and turn methyl orange-yellow. *The pH of a basic solution at standard conditions is greater than seven. *Bases are bitter.


Reactions between bases and water

The following reaction represents the general reaction between a base (B) and water to produce a conjugate acid (BH+) and a conjugate base (OH):_ + _ <=> _ + _The equilibrium constant, Kb, for this reaction can be found using the following general equation: : K_b = \frac In this equation, the base (B) and the extremely strong base (the conjugate base OH) compete for the proton. As a result, bases that react with water have relatively small equilibrium constant values. The base is weaker when it has a lower equilibrium constant value.


Neutralization of acids

Bases react with acids to neutralize each other at a fast rate both in water and in alcohol. When dissolved in water, the strong base
sodium hydroxide Sodium hydroxide, also known as lye and caustic soda, is an inorganic compound with the formula NaOH. It is a white solid ionic compound consisting of sodium cations and hydroxide anions . Sodium hydroxide is a highly caustic base and alkal ...
ionizes into hydroxide and sodium ions: :NaOH -> Na+ + OH- and similarly, in water the acid
hydrogen chloride The compound hydrogen chloride has the chemical formula and as such is a hydrogen halide. At room temperature, it is a colourless gas, which forms white fumes of hydrochloric acid upon contact with atmospheric water vapor. Hydrogen chloride g ...
forms hydronium and chloride ions: :HCl + H2O -> H3O+ + Cl- When the two solutions are mixed, the and ions combine to form water molecules: :H3O+ + OH- -> 2H2O If equal quantities of NaOH and HCl are dissolved, the base and the acid neutralize exactly, leaving only NaCl, effectively table salt, in solution. Weak bases, such as baking soda or egg white, should be used to neutralize any acid spills. Neutralizing acid spills with strong bases, such as
sodium hydroxide Sodium hydroxide, also known as lye and caustic soda, is an inorganic compound with the formula NaOH. It is a white solid ionic compound consisting of sodium cations and hydroxide anions . Sodium hydroxide is a highly caustic base and alkal ...
or
potassium hydroxide Potassium hydroxide is an inorganic compound with the formula K OH, and is commonly called caustic potash. Along with sodium hydroxide (NaOH), KOH is a prototypical strong base. It has many industrial and niche applications, most of which expl ...
, can cause a violent exothermic reaction, and the base itself can cause just as much damage as the original acid spill.


Alkalinity of non-hydroxides

Bases are generally compounds that can neutralize an amount of acid. Both sodium carbonate and
ammonia Ammonia is an inorganic compound of nitrogen and hydrogen with the formula . A stable binary hydride, and the simplest pnictogen hydride, ammonia is a colourless gas with a distinct pungent smell. Biologically, it is a common nitrogeno ...
are bases, although neither of these substances contains groups. Both compounds accept H+ when dissolved in protic solvents such as water: :Na2CO3 + H2O -> 2Na+ + HCO3- + OH- :NH3 + H2O -> NH4+ + OH- From this, a pH, or acidity, can be calculated for aqueous solutions of bases. A base is also defined as a molecule that has the ability to accept an electron pair bond by entering another atom's valence shell through its possession of one electron pair. There are a limited number of elements that have atoms with the ability to provide a molecule with basic properties.
Carbon Carbon () is a chemical element with the symbol C and atomic number 6. It is nonmetallic and tetravalent—its atom making four electrons available to form covalent chemical bonds. It belongs to group 14 of the periodic table. Carbon makes ...
can act as a base as well as
nitrogen Nitrogen is the chemical element with the symbol N and atomic number 7. Nitrogen is a nonmetal and the lightest member of group 15 of the periodic table, often called the pnictogens. It is a common element in the universe, estimated at seve ...
and
oxygen Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as we ...
. Fluorine and sometimes rare gases possess this ability as well. This occurs typically in compounds such as butyl lithium, alkoxides, and metal amides such as sodium amide. Bases of carbon, nitrogen and oxygen without
resonance Resonance describes the phenomenon of increased amplitude that occurs when the frequency of an applied periodic force (or a Fourier component of it) is equal or close to a natural frequency of the system on which it acts. When an oscillat ...
stabilization are usually very strong, or superbases, which cannot exist in a water solution due to the acidity of water. Resonance stabilization, however, enables weaker bases such as carboxylates; for example,
sodium acetate Sodium acetate, CH3COONa, also abbreviated Na O Ac, is the sodium salt of acetic acid. This colorless deliquescent salt has a wide range of uses. Applications Biotechnological Sodium acetate is used as the carbon source for culturing bacteria ...
is a weak base.


Strong bases

A strong base is a basic chemical compound that can remove a proton (H+) from (or '' deprotonate'') a molecule of even a very weak acid (such as water) in an acid–base reaction. Common examples of strong bases include hydroxides of alkali metals and alkaline earth metals, like NaOH and , respectively. Due to their low solubility, some bases, such as alkaline earth hydroxides, can be used when the solubility factor is not taken into account. One advantage of this low solubility is that "many antacids were suspensions of metal hydroxides such as aluminium hydroxide and magnesium hydroxide." These compounds have low solubility and have the ability to stop an increase in the concentration of the hydroxide ion, preventing the harm of the tissues in the mouth, oesophagus, and stomach. As the reaction continues and the salts dissolve, the stomach acid reacts with the hydroxide produced by the suspensions. Strong bases hydrolyze in water almost completely, resulting in the
leveling effect Leveling effect or solvent leveling refers to the effect of solvent on the properties of acids and bases. The strength of a strong acid is limited ("leveled") by the basicity of the solvent. Similarly the strength of a strong base is leveled by ...
." In this process, the water molecule combines with a strong base, due to the water's amphoteric ability; and, a hydroxide ion is released. Very strong bases can even deprotonate very weakly acidic C–H groups in the absence of water. Here is a list of several strong bases: The cations of these strong bases appear in the first and second groups of the periodic table (alkali and earth alkali metals). Tetraalkylated ammonium hydroxides are also strong bases since they dissociate completely in water. Guanidine is a special case of a species that is exceptionally stable when protonated, analogously to the reason that makes
perchloric acid Perchloric acid is a mineral acid with the formula H Cl O4. Usually found as an aqueous solution, this colorless compound is a stronger acid than sulfuric acid, nitric acid and hydrochloric acid. It is a powerful oxidizer when hot, but aqueous s ...
and sulfuric acid very strong acids. Acids with a p''Ka'' of more than about 13 are considered very weak, and their
conjugate base A conjugate acid, within the Brønsted–Lowry acid–base theory, is a chemical compound formed when an acid donates a proton () to a base—in other words, it is a base with a hydrogen ion added to it, as in the reverse reaction it loses a ...
s are strong bases.


Superbases

Group 1 salts of
carbanion In organic chemistry, a carbanion is an anion in which carbon is trivalent (forms three bonds) and bears a formal negative charge (in at least one significant resonance form). Formally, a carbanion is the conjugate base of a carbon acid: :R3CH ...
s, amide ions, and hydrides tend to be even stronger bases due to the extreme weakness of their conjugate acids, which are stable hydrocarbons, amines, and dihydrogen. Usually, these bases are created by adding pure alkali metals such as sodium into the conjugate acid. They are called '' superbases'', and it is impossible to keep them in aqueous solutions because they are stronger bases than the
hydroxide Hydroxide is a diatomic anion with chemical formula OH−. It consists of an oxygen and hydrogen atom held together by a single covalent bond, and carries a negative electric charge. It is an important but usually minor constituent of water ...
ion (See the
leveling effect Leveling effect or solvent leveling refers to the effect of solvent on the properties of acids and bases. The strength of a strong acid is limited ("leveled") by the basicity of the solvent. Similarly the strength of a strong base is leveled by ...
.) For example, the ethoxide ion (conjugate base of ethanol) undergoes this reaction quantitatively in presence of water. :CH3CH2O- + H2O -> CH3CH2OH + OH- Examples of common superbases are: * Butyl lithium (n-C4H9Li) * Lithium diisopropylamide (LDA) CH3)2CHsub>2NLi *
Lithium diethylamide Lithium (from el, λίθος, lithos, lit=stone) is a chemical element with the symbol Li and atomic number 3. It is a soft, silvery-white alkali metal. Under standard conditions, it is the least dense metal and the least dense solid ele ...
(LDEA) * Sodium amide (NaNH2) *
Sodium hydride Sodium hydride is the chemical compound with the empirical formula Na H. This alkali metal hydride is primarily used as a strong yet combustible base in organic synthesis. NaH is a saline (salt-like) hydride, composed of Na+ and H− ions, in ...
(NaH) * Lithium bis(trimethylsilyl)amide Strongest superbases are synthesised in only gas phase: *
Ortho-diethynylbenzene dianion In organic chemistry, a diethynylbenzene dianion is an anion consisting of two ethynyl anions as substituents on a benzene ring. With the chemical formula , three positional isomers are possible, differing in the relative positions of the t ...
(C6H4(C2)2)2− (This is the strongest superbase ever synthesized) *
Meta-diethynylbenzene dianion In organic chemistry, a diethynylbenzene dianion is an anion consisting of two ethynyl anions as substituents on a benzene ring. With the chemical formula , three positional isomers are possible, differing in the relative positions of the t ...
(C6H4(C2)2)2− (second strongest superbase) *
Para-diethynylbenzene dianion In organic chemistry, a diethynylbenzene dianion is an anion consisting of two ethynyl anions as substituents on a benzene ring. With the chemical formula , three positional isomers are possible, differing in the relative positions of the t ...
(C6H4(C2)2)2− (third strongest superbase) * Lithium monoxide anion (LiO) was considered the strongest superbase before diethynylbenzene dianions were created.


Weak bases

A weak base is one which does not fully ionize in an
aqueous solution An aqueous solution is a solution in which the solvent is water. It is mostly shown in chemical equations by appending (aq) to the relevant chemical formula. For example, a solution of table salt, or sodium chloride (NaCl), in water would ...
, or in which
protonation In chemistry, protonation (or hydronation) is the adding of a proton (or hydron, or hydrogen cation), (H+) to an atom, molecule, or ion, forming a conjugate acid. (The complementary process, when a proton is removed from a Brønsted–Lowry acid ...
is incomplete. For example,
ammonia Ammonia is an inorganic compound of nitrogen and hydrogen with the formula . A stable binary hydride, and the simplest pnictogen hydride, ammonia is a colourless gas with a distinct pungent smell. Biologically, it is a common nitrogeno ...
transfers a proton to water according to the equation :NH_3(aq) + H_2O(l) \rightleftharpoons NH_4^+(aq) + OH^-(aq) The equilibrium constant for this reaction at 25 °C is 1.8 x 10−5, such that the extent of reaction or degree of ionization is quite small.


Lewis bases

A Lewis base or ''electron-pair donor'' is a molecule with one or more high-energy
lone pair In chemistry, a lone pair refers to a pair of valence electrons that are not shared with another atom in a covalent bondIUPAC '' Gold Book'' definition''lone (electron) pair''/ref> and is sometimes called an unshared pair or non-bonding pair. L ...
s of electrons which can be shared with a low-energy vacant orbital in an acceptor molecule to form an
adduct An adduct (from the Latin ''adductus'', "drawn toward" alternatively, a contraction of "addition product") is a product of a direct addition of two or more distinct molecules, resulting in a single reaction product containing all atoms of all co ...
. In addition to H+, possible ''electron-pair acceptors'' (Lewis acids) include neutral molecules such as BF3 and high oxidation state metal ions such as Ag2+, Fe3+ and Mn7+. Adducts involving metal ions are usually described as
coordination complex A coordination complex consists of a central atom or ion, which is usually metallic and is called the ''coordination centre'', and a surrounding array of bound molecules or ions, that are in turn known as ''ligands'' or complexing agents. Many ...
es. According to the original formulation of Lewis, when a neutral base forms a bond with a neutral acid, a condition of electric stress occurs. The acid and the base share the electron pair that formerly belonged to the base. As a result, a high dipole moment is created, which can only be decreased to zero by rearranging the molecules.


Solid bases

Examples of solid bases include: * Oxide mixtures: SiO2, Al2O3; MgO, SiO2; CaO, SiO2 * Mounted bases: LiCO3 on silica; NR3, NH3, KNH2 on alumina; NaOH, KOH mounted on silica on alumina * Inorganic chemicals: BaO, KNaCO3, BeO, MgO, CaO, KCN * Anion exchange resins *Charcoal that has been treated at 900 degrees Celsius or activates with N2O, NH3, ZnCl2-NH4Cl-CO2 Depending on a solid surface's ability to successfully form a conjugate base by absorbing an electrically neutral acid, basic strength of the surface is determined. The "number of basic sites per unit surface area of the solid" is used to express how much basic strength is found on a solid base catalyst. Scientists have developed two methods to measure the amount of basic sites: one, titration with benzoic acid using indicators and gaseous acid adsorption. A solid with enough basic strength will absorb an electrically neutral acidic indicator and cause the acidic indicator's color to change to the color of its conjugate base. When performing the gaseous acid adsorption method,
nitric oxide Nitric oxide (nitrogen oxide or nitrogen monoxide) is a colorless gas with the formula . It is one of the principal oxides of nitrogen. Nitric oxide is a free radical: it has an unpaired electron, which is sometimes denoted by a dot in its ...
is used. The basic sites are then determined by calculating the amount of carbon dioxide that is absorbed.


Bases as catalysts

Basic substances can be used as
insoluble In chemistry, solubility is the ability of a substance, the solute, to form a solution with another substance, the solvent. Insolubility is the opposite property, the inability of the solute to form such a solution. The extent of the solub ...
heterogeneous
catalyst Catalysis () is the process of increasing the rate of a chemical reaction by adding a substance known as a catalyst (). Catalysts are not consumed in the reaction and remain unchanged after it. If the reaction is rapid and the catalyst recyc ...
s for
chemical reaction A chemical reaction is a process that leads to the chemical transformation of one set of chemical substances to another. Classically, chemical reactions encompass changes that only involve the positions of electrons in the forming and break ...
s. Some examples are metal oxides such as
magnesium oxide Magnesium oxide ( Mg O), or magnesia, is a white hygroscopic solid mineral that occurs naturally as periclase and is a source of magnesium (see also oxide). It has an empirical formula of MgO and consists of a lattice of Mg2+ ions and O2− ...
,
calcium oxide Calcium oxide (CaO), commonly known as quicklime or burnt lime, is a widely used chemical compound. It is a white, caustic, alkaline, crystalline solid at room temperature. The broadly used term "'' lime''" connotes calcium-containing inorganic ...
, and
barium oxide Barium oxide, also known as baria, is a white hygroscopic non-flammable compound with the formula BaO. It has a cubic structure and is used in cathode ray tubes, crown glass, and catalysts. It is harmful to human skin and if swallowed in large ...
as well as potassium fluoride on alumina and some
zeolite Zeolites are microporous, crystalline aluminosilicate materials commonly used as commercial adsorbents and catalysts. They mainly consist of silicon, aluminium, oxygen, and have the general formula ・y where is either a metal ion or H+. These ...
s. Many
transition metal In chemistry, a transition metal (or transition element) is a chemical element in the d-block of the periodic table (groups 3 to 12), though the elements of group 12 (and less often group 3) are sometimes excluded. They are the elements that c ...
s make good catalysts, many of which form basic substances. Basic catalysts are used for
hydrogenation Hydrogenation is a chemical reaction between molecular hydrogen (H2) and another compound or element, usually in the presence of a catalyst such as nickel, palladium or platinum. The process is commonly employed to reduce or saturate org ...
, the migration of
double bond In chemistry, a double bond is a covalent bond between two atoms involving four bonding electrons as opposed to two in a single bond. Double bonds occur most commonly between two carbon atoms, for example in alkenes. Many double bonds exist betw ...
s, in the Meerwein-Ponndorf-Verley reduction, the
Michael reaction In organic chemistry, the Michael reaction or Michael addition is a reaction between a Michael donor (an enolate or other nucleophile) and a Michael acceptor (usually an α,β-unsaturated carbonyl) to produce a Michael adduct by creating a carbo ...
, and many others. Both CaO and BaO can be highly active catalysts if they are heated to high temperatures.


Uses of bases

*Sodium hydroxide is used in the manufacture of soap, paper, and the synthetic fiber
rayon Rayon is a semi-synthetic fiber, made from natural sources of regenerated cellulose, such as wood and related agricultural products. It has the same molecular structure as cellulose. It is also called viscose. Many types and grades of viscose ...
. *Calcium hydroxide (slaked lime) is used in the manufacture of bleaching powder. *Calcium hydroxide is also used to clean the sulfur dioxide, which is caused by the exhaust, that is found in power plants and factories. *Magnesium hydroxide is used as an 'antacid' to neutralize excess acid in the stomach and cure indigestion. * Sodium carbonate is used as washing soda and for softening hard water. * Sodium bicarbonate (or sodium hydrogen carbonate) is used as baking soda in cooking food, for making baking powders, as an antacid to cure indigestion and in soda acid fire extinguisher. *
Ammonium hydroxide Ammonia solution, also known as ammonia water, ammonium hydroxide, ammoniacal liquor, ammonia liquor, aqua ammonia, aqueous ammonia, or (inaccurately) ammonia, is a solution of ammonia in water. It can be denoted by the symbols NH3(aq). Although ...
is used to remove grease stains from clothes


Monoprotic and polyprotic bases

Bases with only one
ionizable Ionization, or Ionisation is the process by which an atom or a molecule acquires a negative or positive charge by gaining or losing electrons, often in conjunction with other chemical changes. The resulting electrically charged atom or molecule i ...
hydroxide Hydroxide is a diatomic anion with chemical formula OH−. It consists of an oxygen and hydrogen atom held together by a single covalent bond, and carries a negative electric charge. It is an important but usually minor constituent of water ...
(OH) ion per formula unit are called monoprotic since they can accept one proton (H+). Bases with more than one OH- per formula unit are polyprotic. The number of
ionizable Ionization, or Ionisation is the process by which an atom or a molecule acquires a negative or positive charge by gaining or losing electrons, often in conjunction with other chemical changes. The resulting electrically charged atom or molecule i ...
hydroxide Hydroxide is a diatomic anion with chemical formula OH−. It consists of an oxygen and hydrogen atom held together by a single covalent bond, and carries a negative electric charge. It is an important but usually minor constituent of water ...
(OH) ions present in one formula unit of a base is also called the acidity of the base. On the basis of acidity bases can be classified into three types: monoacidic, diacidic and triacidic.


Monoacidic bases

When one molecule of a base via complete
ionization Ionization, or Ionisation is the process by which an atom or a molecule acquires a negative or positive Electric charge, charge by gaining or losing electrons, often in conjunction with other chemical changes. The resulting electrically charged a ...
produces one
hydroxide Hydroxide is a diatomic anion with chemical formula OH−. It consists of an oxygen and hydrogen atom held together by a single covalent bond, and carries a negative electric charge. It is an important but usually minor constituent of water ...
ion, the base is said to be a monoacidic or monoprotic base. Examples of monoacidic bases are:
Sodium hydroxide Sodium hydroxide, also known as lye and caustic soda, is an inorganic compound with the formula NaOH. It is a white solid ionic compound consisting of sodium cations and hydroxide anions . Sodium hydroxide is a highly caustic base and alkal ...
,
potassium hydroxide Potassium hydroxide is an inorganic compound with the formula K OH, and is commonly called caustic potash. Along with sodium hydroxide (NaOH), KOH is a prototypical strong base. It has many industrial and niche applications, most of which expl ...
, silver hydroxide,
ammonium hydroxide Ammonia solution, also known as ammonia water, ammonium hydroxide, ammoniacal liquor, ammonia liquor, aqua ammonia, aqueous ammonia, or (inaccurately) ammonia, is a solution of ammonia in water. It can be denoted by the symbols NH3(aq). Although ...
, etc


Diacidic bases

When one molecule of base via complete
ionization Ionization, or Ionisation is the process by which an atom or a molecule acquires a negative or positive Electric charge, charge by gaining or losing electrons, often in conjunction with other chemical changes. The resulting electrically charged a ...
produces two
hydroxide Hydroxide is a diatomic anion with chemical formula OH−. It consists of an oxygen and hydrogen atom held together by a single covalent bond, and carries a negative electric charge. It is an important but usually minor constituent of water ...
ions, the base is said to be diacidic or diprotic. Examples of diacidic bases are: Barium hydroxide, magnesium hydroxide,
calcium hydroxide Calcium hydroxide (traditionally called slaked lime) is an inorganic compound with the chemical formula Ca( OH)2. It is a colorless crystal or white powder and is produced when quicklime ( calcium oxide) is mixed or slaked with water. It has m ...
,
zinc hydroxide Zinc hydroxide Zn( OH)2 is an inorganic chemical compound. It also occurs naturally as 3 rare minerals: wülfingite (orthorhombic), ashoverite and sweetite (both tetragonal). Like the hydroxides of other metals, such as lead, aluminium, b ...
, iron(II) hydroxide,
tin(II) hydroxide Tin(II) hydroxide, Sn(OH)2, also known as ''stannous hydroxide'', is an inorganic compound tin(II). The only related material for which definitive information is available is the oxy hydroxide Sn6O4(OH)4, but other related materials are claimed. ...
,
lead(II) hydroxide Lead(II) hydroxide, Pb(OH)2, is a hydroxide of lead, with lead in oxidation state +2. In 1964 it was believed that such a simple compound did not exist, as lead basic carbonate (2PbCO3·Pb(OH)2) or lead(II) oxide (PbO) was encountered where lead ...
, copper(II) hydroxide, etc.


Triacidic bases

When one molecule of base via complete
ionization Ionization, or Ionisation is the process by which an atom or a molecule acquires a negative or positive Electric charge, charge by gaining or losing electrons, often in conjunction with other chemical changes. The resulting electrically charged a ...
produces three
hydroxide Hydroxide is a diatomic anion with chemical formula OH−. It consists of an oxygen and hydrogen atom held together by a single covalent bond, and carries a negative electric charge. It is an important but usually minor constituent of water ...
ions, the base is said to be triacidic or triprotic. Examples of triacidic bases are:
Aluminium hydroxide Aluminium hydroxide, Al(OH)3, is found in nature as the mineral gibbsite (also known as hydrargillite) and its three much rarer Polymorphism (materials science), polymorphs: bayerite, doyleite, and nordstrandite. Aluminium hydroxide is Amphoter ...
, ferrous hydroxide, Gold Trihydroxide,


Etymology of the term

The concept of base stems from an older
alchemical Alchemy (from Arabic: ''al-kīmiyā''; from Ancient Greek: χυμεία, ''khumeía'') is an ancient branch of natural philosophy, a philosophical and protoscientific tradition that was historically practiced in China, India, the Muslim wor ...
notion of "the matrix":


See also

* Acids *
Acid–base reaction An acid–base reaction is a chemical reaction that occurs between an acid and a base. It can be used to determine pH via titration. Several theoretical frameworks provide alternative conceptions of the reaction mechanisms and their applic ...
s * Base-richness (used in ecology, referring to environments) *
Conjugate base A conjugate acid, within the Brønsted–Lowry acid–base theory, is a chemical compound formed when an acid donates a proton () to a base—in other words, it is a base with a hydrogen ion added to it, as in the reverse reaction it loses a ...
*
Lewis acids and bases A Lewis acid (named for the American physical chemist Gilbert N. Lewis) is a chemical species that contains an empty orbital which is capable of accepting an electron pair from a Lewis base to form a Lewis adduct. A Lewis base, then, is any spe ...
*
Titration Titration (also known as titrimetry and volumetric analysis) is a common laboratory method of quantitative chemical analysis to determine the concentration of an identified analyte (a substance to be analyzed). A reagent, termed the ''titrant ...


References

* * {{DEFAULTSORT:Base (Chemistry) Chemical compounds