chemical element
A chemical element is a species of atoms that have a given number of protons in their nuclei, including the pure substance consisting only of that species. Unlike chemical compounds, chemical elements cannot be broken down into simpler sub ...
atomic number
The atomic number or nuclear charge number (symbol ''Z'') of a chemical element is the charge number of an atomic nucleus. For ordinary nuclei, this is equal to the proton number (''n''p) or the number of protons found in the nucleus of every ...
56. It is the fifth element in group 2 and is a soft, silvery
alkaline earth metal
The alkaline earth metals are six chemical elements in group 2 of the periodic table. They are beryllium (Be), magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba), and radium (Ra).. The elements have very similar properties: they are all ...
. Because of its high chemical reactivity, barium is never found in nature as a free element.
The most common minerals of barium are baryte ( barium sulfate, BaSO4) and
witherite
Witherite is a barium carbonate mineral, Ba C O3, in the aragonite group. Witherite crystallizes in the orthorhombic system and virtually always is twinned. The mineral is colorless, milky-white, grey, pale-yellow, green, to pale-brown. The spec ...
(
barium carbonate
Barium carbonate is the inorganic compound with the formula BaCO3. Like most alkaline earth metal carbonates, it is a white salt that is poorly soluble in water. It occurs as the mineral known as witherite. In a commercial sense, it is one of ...
, BaCO3). The name ''barium'' originates from the alchemical derivative "baryta", from
Greek
Greek may refer to:
Greece
Anything of, from, or related to Greece, a country in Southern Europe:
*Greeks, an ethnic group.
*Greek language, a branch of the Indo-European language family.
**Proto-Greek language, the assumed last common ancestor ...
(), meaning 'heavy'. ''Baric'' is the adjectival form of barium. Barium was identified as a new element in 1774, but not reduced to a metal until 1808 with the advent of electrolysis.
Barium has few industrial applications. Historically, it was used as a
getter
A getter is a deposit of reactive material that is placed inside a vacuum system to complete and maintain the vacuum. When gas molecules strike the getter material, they combine with it chemically or by . Thus the getter removes small amounts of ...
for
vacuum tube
A vacuum tube, electron tube, valve (British usage), or tube (North America), is a device that controls electric current flow in a high vacuum between electrodes to which an electric potential difference has been applied.
The type known as ...
YBCO
Yttrium barium copper oxide (YBCO) is a family of crystalline chemical compounds that display high-temperature superconductivity; it includes the first material ever discovered to become superconducting above the boiling point of liquid nitrogen ...
(
high-temperature superconductors
High-temperature superconductors (abbreviated high-c or HTS) are defined as materials that behave as superconductors at temperatures above , the boiling point of liquid nitrogen. The adjective "high temperature" is only in respect to previo ...
) and electroceramics, and is added to steel and cast iron to reduce the size of carbon grains within the microstructure. Barium compounds are added to fireworks to impart a green color. Barium sulfate is used as an insoluble additive to oil well
drilling fluid
In geotechnical engineering, drilling fluid, also called drilling mud, is used to aid the drilling of boreholes into the earth. Often used while drilling oil and natural gas wells and on exploration drilling rigs, drilling fluids are als ...
. In a purer form it is used as X-ray
radiocontrast agent
Radiocontrast agents are substances used to enhance the visibility of internal structures in X-ray-based imaging techniques such as computed tomography ( contrast CT), projectional radiography, and fluoroscopy. Radiocontrast agents are typically i ...
s for imaging the human gastrointestinal tract. Water-soluble barium compounds are poisonous and have been used as
rodenticide
Rodenticides are chemicals made and sold for the purpose of killing rodents. While commonly referred to as "rat poison", rodenticides are also used to kill mice, squirrels, woodchucks, chipmunks, porcupines, nutria, beavers, and voles. Despi ...
s.
Characteristics
Physical properties
Barium is a soft, silvery-white metal, with a slight golden shade when ultrapure. The silvery-white color of barium metal rapidly vanishes upon
oxidation
Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or a ...
in air yielding a dark gray layer containing the oxide. Barium has a medium
specific weight
The specific weight, also known as the unit weight, is the weight per unit volume of a material.
A commonly used value is the specific weight of water on Earth at , which is .National Council of Examiners for Engineering and Surveying (2005). ''Fu ...
and high electrical conductivity. Because barium is difficult to purify, many of its properties have not been accurately determined.
At room temperature and pressure, barium metal adopts a
body-centered cubic
In crystallography, the cubic (or isometric) crystal system is a crystal system where the unit cell is in the shape of a cube. This is one of the most common and simplest shapes found in crystals and minerals.
There are three main varieties of ...
structure, with a barium–barium distance of 503
picometer
The picometre (international spelling as used by the International Bureau of Weights and Measures; SI symbol: pm) or picometer (American spelling) is a unit of length in the International System of Units (SI), equal to , or one trillionth of ...
s, expanding with heating at a rate of approximately 1.8/°C. It is a very soft metal with a
Mohs hardness
The Mohs scale of mineral hardness () is a qualitative ordinal scale, from 1 to 10, characterizing scratch resistance of various minerals through the ability of harder material to scratch softer material.
The scale was introduced in 1812 by t ...
of 1.25. Its melting temperature of is intermediate between those of the lighter strontium () and heavier radium (); however, its boiling point of exceeds that of strontium (). The density (3.62 g/cm3) is again intermediate between those of strontium (2.36 g/cm3) and radium (≈5 g/cm3).
Chemical reactivity
Barium is chemically similar to magnesium, calcium, and strontium, but even more reactive. It is usually found in the +2 oxidation state. Most exceptions are in a few rare and unstable molecular species that are only characterised in the gas phase such as BaF, but recently a barium(I) species has been reported in a graphite intercalation compound. Reactions with
chalcogen
The chalcogens (ore forming) ( ) are the chemical elements in group 16 of the periodic table. This group is also known as the oxygen family. Group 16 consists of the elements oxygen (O), sulfur (S), selenium (Se), tellurium (Te), and the radioac ...
s are highly exothermic (release energy); the reaction with oxygen or air occurs at room temperature. For this reason, metallic barium is often stored under oil or in an inert atmosphere. Reactions with other nonmetals, such as carbon, nitrogen, phosphorus, silicon, and hydrogen, are generally exothermic and proceed upon heating. Reactions with water and alcohols are very exothermic and release hydrogen gas:
: Ba + 2 ROH → Ba(OR)2 + H2↑ (R is an alkyl group or a hydrogen atom)
Barium reacts with
ammonia
Ammonia is an inorganic compound of nitrogen and hydrogen with the formula . A stable binary hydride, and the simplest pnictogen hydride, ammonia is a colourless gas with a distinct pungent smell. Biologically, it is a common nitrogenous wa ...
to form complexes such as Ba(NH3)6.
The metal is readily attacked by acids. Sulfuric acid is a notable exception because passivation stops the reaction by forming the insoluble barium sulfate on the surface. Barium combines with several other metals, including
aluminium
Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. I ...
,
zinc
Zinc is a chemical element with the symbol Zn and atomic number 30. Zinc is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodi ...
,
lead
Lead is a chemical element with the symbol Pb (from the Latin ) and atomic number 82. It is a heavy metal that is denser than most common materials. Lead is soft and malleable, and also has a relatively low melting point. When freshly cu ...
, and
tin
Tin is a chemical element with the symbol Sn (from la, stannum) and atomic number 50. Tin is a silvery-coloured metal.
Tin is soft enough to be cut with little force and a bar of tin can be bent by hand with little effort. When bent, t ...
Barium salts are typically white when solid and colorless when dissolved. They are denser than the strontium or
calcium
Calcium is a chemical element with the symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar t ...
zinc
Zinc is a chemical element with the symbol Zn and atomic number 30. Zinc is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodi ...
is given for comparison).
Barium hydroxide
Barium hydroxide is a chemical compound with the chemical formula Ba(OH)2. The monohydrate (''x'' = 1), known as baryta or baryta-water, is one of the principal compounds of barium. This white granular monohydrate is the usual commercial form.
...
("baryta") was known to alchemists, who produced it by heating barium carbonate. Unlike calcium hydroxide, it absorbs very little CO2 in aqueous solutions and is therefore insensitive to atmospheric fluctuations. This property is used in calibrating pH equipment.
Volatile barium compounds burn with a green to pale green
flame
A flame (from Latin '' flamma'') is the visible, gaseous part of a fire. It is caused by a highly exothermic chemical reaction taking place in a thin zone. When flames are hot enough to have ionized gaseous components of sufficient density they ...
, which is an efficient test to detect a barium compound. The color results from
spectral line
A spectral line is a dark or bright line in an otherwise uniform and continuous spectrum, resulting from emission or absorption of light in a narrow frequency range, compared with the nearby frequencies. Spectral lines are often used to iden ...
s at 455.4, 493.4, 553.6, and 611.1 nm.Organobarium compounds are a growing field of knowledge: recently discovered are dialkylbariums and alkylhalobariums.
Isotopes
Barium found in the Earth's crust is a mixture of seven primordial nuclides, barium-130, 132, and 134 through 138. Barium-130 undergoes very slow radioactive decay to
xenon
Xenon is a chemical element with the symbol Xe and atomic number 54. It is a dense, colorless, odorless noble gas found in Earth's atmosphere in trace amounts. Although generally unreactive, it can undergo a few chemical reactions such as the ...
-130 by double
beta plus decay
Positron emission, beta plus decay, or β+ decay is a subtype of radioactive decay called beta decay, in which a proton inside a radionuclide nucleus is converted into a neutron while releasing a positron and an electron neutrino (). Positron ...
, with a half-life of (0.5–2.7)×1021 years (about 1011 times the age of the universe). Its abundance is ≈0.1% that of natural barium. Theoretically, barium-132 can similarly undergo double beta decay to xenon-132; this decay has not been detected. The radioactivity of these isotopes is so weak that they pose no danger to life.
Of the stable isotopes, barium-138 composes 71.7% of all barium; other isotopes have decreasing abundance with decreasing
mass number
The mass number (symbol ''A'', from the German word ''Atomgewicht'' tomic weight, also called atomic mass number or nucleon number, is the total number of protons and neutrons (together known as nucleons) in an atomic nucleus. It is approxima ...
.
In total, barium has 40 known isotopes, ranging in mass between 114 and 153. The most stable artificial radioisotope is barium-133 with a half-life of approximately 10.51 years. Five other isotopes have half-lives longer than a day. Barium also has 10
meta state
A nuclear isomer is a metastable state of an atomic nucleus, in which one or more nucleons (protons or neutrons) occupy higher energy levels than in the ground state of the same nucleus. "Metastable" describes nuclei whose excited states have ...
s, of which barium-133m1 is the most stable with a half-life of about 39 hours.
History
Alchemists in the early Middle Ages knew about some barium minerals. Smooth pebble-like stones of mineral baryte were found in volcanic rock near
Bologna
Bologna (, , ; egl, label=Emilian language, Emilian, Bulåggna ; lat, Bononia) is the capital and largest city of the Emilia-Romagna region in Northern Italy. It is the seventh most populous city in Italy with about 400,000 inhabitants and 1 ...
,
Italy
Italy ( it, Italia ), officially the Italian Republic, ) or the Republic of Italy, is a country in Southern Europe. It is located in the middle of the Mediterranean Sea, and its territory largely coincides with the homonymous geographical ...
, and so were called "Bologna stones". Alchemists were attracted to them because after exposure to light they would glow for years. The phosphorescent properties of baryte heated with organics were described by V. Casciorolus in 1602.
Carl Scheele
Carl Wilhelm Scheele (, ; 9 December 1742 – 21 May 1786) was a Swedish German pharmaceutical chemist.
Scheele discovered oxygen (although Joseph Priestley published his findings first), and identified molybdenum, tungsten, barium, hydro ...
determined that baryte contained a new element in 1774, but could not isolate barium, only
barium oxide
Barium oxide, also known as baria, is a white hygroscopic non-flammable compound with the formula BaO. It has a cubic structure and is used in cathode ray tubes, crown glass, and catalysts. It is harmful to human skin and if swallowed in larg ...
.
Johan Gottlieb Gahn
Johan Gottlieb Gahn (19 August 1745 – 8 December 1818) was a Swedish chemist and metallurgist who isolated manganese in 1774.
Gahn studied in Uppsala 1762 – 1770 and became acquainted with chemists Torbern Bergman and Carl Wilhelm Scheele. 177 ...
also isolated
barium oxide
Barium oxide, also known as baria, is a white hygroscopic non-flammable compound with the formula BaO. It has a cubic structure and is used in cathode ray tubes, crown glass, and catalysts. It is harmful to human skin and if swallowed in larg ...
two years later in similar studies. Oxidized barium was at first called "barote" by
Guyton de Morveau
Louis-Bernard Guyton, Baron de Morveau (also Louis-Bernard Guyton-Morveau after the French Revolution; 4 January 1737 – 2 January 1816) was a French chemist, politician, and aeronaut. He is credited with producing the first systematic method o ...
, a name that was changed by
Antoine Lavoisier
Antoine-Laurent de Lavoisier ( , ; ; 26 August 17438 May 1794), CNRS (
William Withering
William Withering FRS (17 March 1741 – 6 October 1799) was an English botanist, geologist, chemist, physician and first systematic investigator of the bioactivity of digitalis.
Withering was born in Wellington, Shropshire, the son of a surg ...
noted a heavy mineral in the lead mines of Cumberland, now known to be
witherite
Witherite is a barium carbonate mineral, Ba C O3, in the aragonite group. Witherite crystallizes in the orthorhombic system and virtually always is twinned. The mineral is colorless, milky-white, grey, pale-yellow, green, to pale-brown. The spec ...
. Barium was first isolated by electrolysis of molten barium salts in 1808 by Sir
Humphry Davy
Sir Humphry Davy, 1st Baronet, (17 December 177829 May 1829) was a British chemist and inventor who invented the Davy lamp and a very early form of arc lamp. He is also remembered for isolating, by using electricity, several elements for t ...
in
England
England is a country that is part of the United Kingdom. It shares land borders with Wales to its west and Scotland to its north. The Irish Sea lies northwest and the Celtic Sea to the southwest. It is separated from continental Europe b ...
. Davy, by analogy with
calcium
Calcium is a chemical element with the symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar t ...
, named "barium" after baryta, with the "-ium" ending signifying a metallic element.
Robert Bunsen
Robert Wilhelm Eberhard Bunsen (;
30 March 1811
– 16 August 1899) was a German chemist. He investigated emission spectra of heated elements, and discovered caesium (in 1860) and rubidium (in 1861) with the physicist Gustav Kirchhoff. The Bu ...
and
Augustus Matthiessen
Augustus Matthiessen, FRS (2 January 1831, in London – 6 October 1870, in London), the son of a merchant, was a British chemist and physicist who obtained his PhD in Germany at the University of Gießen in 1852 with Johann Heinrich Buff. He ...
obtained pure barium by electrolysis of a molten mixture of
barium chloride
Barium chloride is an inorganic compound with the formula Ba Cl2. It is one of the most common water-soluble salts of barium. Like most other water-soluble barium salts, it is white, highly toxic, and imparts a yellow-green coloration to a flame. ...
and ammonium chloride.
The production of pure oxygen in the Brin process was a large-scale application of barium peroxide in the 1880s, before it was replaced by electrolysis and fractional distillation of liquefied air in the early 1900s. In this process barium oxide reacts at with air to form barium peroxide, which decomposes above by releasing oxygen:
:2 BaO + O2 ⇌ 2 BaO2
Barium sulfate was first applied as a
radiocontrast
Radiocontrast agents are substances used to enhance the visibility of internal structures in X-ray-based imaging techniques such as computed tomography ( contrast CT), projectional radiography, and fluoroscopy. Radiocontrast agents are typically i ...
agent in
X-ray imaging
Radiography is an imaging technique using X-rays, gamma rays, or similar ionizing radiation and non-ionizing radiation to view the internal form of an object. Applications of radiography include medical radiography ("diagnostic" and "therapeut ...
of the digestive system in 1908.
Occurrence and production
The abundance of barium is 0.0425% in the Earth's crust and 13 μg/L in sea water. The primary commercial source of barium is baryte (also called barytes or heavy spar), a barium sulfate mineral. with deposits in many parts of the world. Another commercial source, far less important than baryte, is
witherite
Witherite is a barium carbonate mineral, Ba C O3, in the aragonite group. Witherite crystallizes in the orthorhombic system and virtually always is twinned. The mineral is colorless, milky-white, grey, pale-yellow, green, to pale-brown. The spec ...
, barium carbonate. The main deposits are located in Britain, Romania, and the former USSR.
The baryte reserves are estimated between 0.7 and 2 billion
tonne
The tonne ( or ; symbol: t) is a unit of mass equal to 1000 kilograms. It is a non-SI unit accepted for use with SI. It is also referred to as a metric ton to distinguish it from the non-metric units of the short ton ( United State ...
s. The maximum production, 8.3 million tonnes, was produced in 1981, but only 7–8% was used for barium metal or compounds. Baryte production has risen since the second half of the 1990s from 5.6 million tonnes in 1996 to 7.6 in 2005 and 7.8 in 2011. China accounts for more than 50% of this output, followed by India (14% in 2011), Morocco (8.3%), US (8.2%), Turkey (2.5%), Iran and Kazakhstan (2.6% each).
The mined ore is washed, crushed, classified, and separated from quartz. If the quartz penetrates too deeply into the ore, or the iron, zinc, or lead content is abnormally high, then
froth flotation
Froth flotation is a process for selectively separating hydrophobic materials from hydrophilic. This is used in mineral processing, paper recycling and waste-water treatment industries. Historically this was first used in the mining industry, wher ...
is used. The product is a 98% pure baryte (by mass); the purity should be no less than 95%, with a minimal content of iron and
silicon dioxide
Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is one ...
. It is then reduced by carbon to
barium sulfide
Barium sulfide is the inorganic compound with the formula Ba S. BaS is the barium compound produced on the largest scale. It is an important precursor to other barium compounds including BaCO3 and the pigment lithopone, ZnS/BaSO4. Like other ...
:
:BaSO4 + 2 C → BaS + 2 CO2
The water-soluble barium sulfide is the starting point for other compounds: treating BaS with oxygen produces the sulfate, with nitric acid the nitrate, with aqueous carbon dioxide the carbonate, and so on. The nitrate can be thermally decomposed to yield the oxide. Barium metal is produced by reduction with
aluminium
Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. I ...
at . The
intermetallic compound
An intermetallic (also called an intermetallic compound, intermetallic alloy, ordered intermetallic alloy, and a long-range-ordered alloy) is a type of metallic bonding, metallic alloy that forms an ordered solid-state Chemical compound, compoun ...
BaAl4 is produced first:
:3 BaO + 14 Al → 3 BaAl4 + Al2O3
BaAl4 is an intermediate reacted with barium oxide to produce the metal. Note that not all barium is reduced.
:8 BaO + BaAl4 → Ba↓ + 7 BaAl2O4
The remaining barium oxide reacts with the formed aluminium oxide:
:BaO + Al2O3 → BaAl2O4
and the overall reaction is
:4 BaO + 2 Al → 3 Ba↓ + BaAl2O4
Barium vapor is condensed and packed into molds in an atmosphere of argon. This method is used commercially, yielding ultrapure barium. Commonly sold barium is about 99% pure, with main impurities being strontium and calcium (up to 0.8% and 0.25%) and other contaminants contributing less than 0.1%.
A similar reaction with silicon at yields barium and
barium metasilicate
Barium is a chemical element with the symbol Ba and atomic number 56. It is the fifth element in group 2 and is a soft, silvery alkaline earth metal. Because of its high chemical reactivity, barium is never found in nature as a free element.
Th ...
. Electrolysis is not used because barium readily dissolves in molten halides and the product is rather impure.
Gemstone
The barium mineral,
benitoite
Benitoite () is a rare blue barium titanium cyclosilicate, found in hydrothermally altered serpentinite. It forms in low temperature, high pressure environments typical of subduction zones at convergent plate boundaries. Benitoite fluoresces ...
(barium titanium silicate), occurs as a very rare blue fluorescent gemstone, and is the official state gem of
California
California is a state in the Western United States, located along the Pacific Coast. With nearly 39.2million residents across a total area of approximately , it is the most populous U.S. state and the 3rd largest by area. It is also the m ...
.
Barium in seawater
Barium exists in seawater as the Ba2+ ion with an average oceanic concentration of 109 nmol/kg. Barium also exists in the ocean as BaSO4, or barite. Barium has a nutrient-like profile with a residence time of 10,000 years.
Barium shows a relatively consistent concentration in upper ocean seawater, excepting regions of high river inputs and regions with strong upwelling. There’s little depletion of barium concentrations in the upper ocean for an ion with a nutrient-like profile, thus lateral mixing is important. Barium isotopic values show basin-scale balances instead of local or short-term processes.
Applications
Metal and alloys
Barium, as a metal or when alloyed with aluminium, is used to remove unwanted gases (
getter
A getter is a deposit of reactive material that is placed inside a vacuum system to complete and maintain the vacuum. When gas molecules strike the getter material, they combine with it chemically or by . Thus the getter removes small amounts of ...
ing) from vacuum tubes, such as TV picture tubes. Barium is suitable for this purpose because of its low
vapor pressure
Vapor pressure (or vapour pressure in English-speaking countries other than the US; see spelling differences) or equilibrium vapor pressure is defined as the pressure exerted by a vapor in thermodynamic equilibrium with its condensed phas ...
and reactivity towards oxygen, nitrogen, carbon dioxide, and water; it can even partly remove noble gases by dissolving them in the crystal lattice. This application is gradually disappearing due to the rising popularity of the tubeless LCD and plasma sets.
Other uses of elemental barium are minor and include an additive to
silumin
Silumin is a general name for a group of lightweight, high-strength aluminium alloys based on an aluminum–silicon system. Aluminium-silicon alloys typically contain 3 to 25% silicon content. Casting is the primary use of aluminum-silicon alloys, ...
(aluminium–silicon alloys) that refines their structure, as well as
*
bearing alloy
Bearing(s) may refer to:
* Bearing (angle), a term for direction
* Bearing (mechanical), a component that separates moving parts and takes a load
* Bridge bearing, a component separating a bridge pier and deck
* Bearing BTS Station in Bangkok
* ' ...
s;
* lead–tin
solder
Solder (; NA: ) is a fusible metal alloy used to create a permanent bond between metal workpieces. Solder is melted in order to wet the parts of the joint, where it adheres to and connects the pieces after cooling. Metals or alloys suitable ...
ing alloys – to increase the creep resistance;
* alloy with nickel for spark plugs;
* additive to steel and cast iron as an inoculant;
* alloys with calcium, manganese, silicon, and aluminium as high-grade steel deoxidizers.
Barium sulfate and baryte
Barium sulfate (the mineral baryte, BaSO4) is important to the petroleum industry as a
drilling fluid
In geotechnical engineering, drilling fluid, also called drilling mud, is used to aid the drilling of boreholes into the earth. Often used while drilling oil and natural gas wells and on exploration drilling rigs, drilling fluids are als ...
in oil and gas wells. The precipitate of the compound (called "blanc fixe", from the French for "permanent white") is used in paints and varnishes; as a filler in ringing ink, plastics, and rubbers; as a paper coating pigment; and in
nanoparticle
A nanoparticle or ultrafine particle is usually defined as a particle of matter that is between 1 and 100 nanometres (nm) in diameter. The term is sometimes used for larger particles, up to 500 nm, or fibers and tubes that are less than 10 ...
s, to improve physical properties of some polymers, such as epoxies.
Barium sulfate has a low toxicity and relatively high density of ca. 4.5 g/cm3 (and thus opacity to X-rays). For this reason it is used as a
radiocontrast
Radiocontrast agents are substances used to enhance the visibility of internal structures in X-ray-based imaging techniques such as computed tomography ( contrast CT), projectional radiography, and fluoroscopy. Radiocontrast agents are typically i ...
agent in
X-ray imaging
Radiography is an imaging technique using X-rays, gamma rays, or similar ionizing radiation and non-ionizing radiation to view the internal form of an object. Applications of radiography include medical radiography ("diagnostic" and "therapeut ...
of the digestive system ("
barium meal
An upper gastrointestinal series, also called a barium swallow, barium study, or barium meal, is a series of radiographs used to examine the gastrointestinal tract for abnormalities. A contrast medium, usually a radiocontrast agent such as ba ...
Lithopone
Lithopone, C.I. Pigment White 5, is a mixture of inorganic compounds, widely used as a white pigment powder. It is composed of a mixture of barium sulfate and zinc sulfide. These insoluble compounds blend well with organic compounds and confer op ...
, a
pigment
A pigment is a colored material that is completely or nearly insoluble in water. In contrast, dyes are typically soluble, at least at some stage in their use. Generally dyes are often organic compounds whereas pigments are often inorganic compo ...
that contains barium sulfate and
zinc sulfide
Zinc sulfide (or zinc sulphide) is an inorganic compound with the chemical formula of ZnS. This is the main form of zinc found in nature, where it mainly occurs as the mineral sphalerite. Although this mineral is usually black because of various i ...
, is a permanent white with good covering power that does not darken when exposed to sulfides.
Other barium compounds
Other compounds of barium find only niche applications, limited by the toxicity of Ba2+ ions (barium carbonate is a
rat poison
Rodenticides are chemicals made and sold for the purpose of killing rodents. While commonly referred to as "rat poison", rodenticides are also used to kill mice, squirrels, woodchucks, chipmunks, porcupines, nutria, beavers, and voles. Despite ...
), which is not a problem for the insoluble BaSO4.
*
Barium oxide
Barium oxide, also known as baria, is a white hygroscopic non-flammable compound with the formula BaO. It has a cubic structure and is used in cathode ray tubes, crown glass, and catalysts. It is harmful to human skin and if swallowed in large q ...
coating on the
electrode
An electrode is an electrical conductor used to make contact with a nonmetallic part of a circuit (e.g. a semiconductor, an electrolyte, a vacuum or air). Electrodes are essential parts of batteries that can consist of a variety of materials de ...
s of
fluorescent lamp
A fluorescent lamp, or fluorescent tube, is a low-pressure mercury-vapor gas-discharge lamp that uses fluorescence to produce visible light. An electric current in the gas excites mercury vapor, which produces short-wave ultraviolet lig ...
s facilitates the release of
electron
The electron ( or ) is a subatomic particle with a negative one elementary electric charge. Electrons belong to the first generation of the lepton particle family,
and are generally thought to be elementary particles because they have no kn ...
s.
* By its great atomic density,
barium carbonate
Barium carbonate is the inorganic compound with the formula BaCO3. Like most alkaline earth metal carbonates, it is a white salt that is poorly soluble in water. It occurs as the mineral known as witherite. In a commercial sense, it is one of ...
increases the
refractive index
In optics, the refractive index (or refraction index) of an optical medium is a dimensionless number that gives the indication of the light bending ability of that medium.
The refractive index determines how much the path of light is bent, or ...
and luster of glass and reduces leaks of X-rays from
cathode ray tubes
A cathode-ray tube (CRT) is a vacuum tube containing one or more electron guns, which emit electron beams that are manipulated to display images on a phosphorescent screen. The images may represent electrical waveforms (oscilloscope), pictur ...
(CRT) TV sets.
* Barium, typically as
barium nitrate
Barium nitrate is the inorganic compound with the chemical formula Ba( NO3)2. It, like most barium salts, is colorless, toxic, and water-soluble. It burns with a green flame and is an oxidizer; the compound is commonly used in pyrotechnics.
Man ...
imparts a yellow or "apple" green color to fireworks; for brilliant green barium monochloride is used.
*
Barium peroxide
Barium peroxide is the inorganic compound with the formula Ba O2. This white solid (gray when impure) is one of the most common inorganic peroxides, and it was the first peroxide compound discovered. Being an oxidizer and giving a vivid green c ...
is a catalyst in the
aluminothermic reaction
Aluminothermic reactions are exothermic chemical reactions using aluminum as the reducing agent at high temperature. The process is industrially useful for production of alloys of iron. The most prominent example is the thermite reaction between ...
(
thermite
Thermite () is a pyrotechnic composition of metal powder and metal oxide. When ignited by heat or chemical reaction, thermite undergoes an exothermic reduction-oxidation (redox) reaction. Most varieties are not explosive, but can create brief ...
) for welding rail tracks. It is also a green flare in
tracer ammunition
Tracer ammunition (AMO) (Tracers) are bullets or cannon-caliber projectiles that are built with a small pyrotechnic charge in their base. When fired, the pyrotechnic composition is ignited by the burning powder and burns very brightly, making t ...
and a bleaching agent.
*
Barium titanate
Barium titanate (BTO) is an inorganic compound with chemical formula BaTiO3. Barium titanate appears white as a powder and is transparent when prepared as large crystals. It is a Ferroelectricity, ferroelectric, Pyroelectricity, pyroelectric, and ...
is a promising
electroceramic Electroceramics is a class of ceramic materials used primarily for their electrical properties.
While ceramics have traditionally been admired and used for their mechanical, thermal and chemical stability, their unique electrical, optical and magn ...
.
*
Barium fluoride
Barium fluoride (BaF2) is an inorganic compound with the formula BaF2. It is a colorless solid that occurs in nature as the rare mineral frankdicksonite. Under standard conditions it adopts the fluorite structure and at high pressure the PbCl2 s ...
is used for optics in infrared applications because of its wide transparency range of 0.15–12 micrometers.
*
YBCO
Yttrium barium copper oxide (YBCO) is a family of crystalline chemical compounds that display high-temperature superconductivity; it includes the first material ever discovered to become superconducting above the boiling point of liquid nitrogen ...
was the first
high-temperature superconductor
High-temperature superconductors (abbreviated high-c or HTS) are defined as materials that behave as superconductors at temperatures above , the boiling point of liquid nitrogen. The adjective "high temperature" is only in respect to previ ...
cooled by liquid nitrogen, with a transition temperature of that exceeded the boiling point of nitrogen ().
* Ferrite, a type of sintered ceramic composed of iron oxide (Fe2O3) and barium oxide (BaO), is both electrically nonconductive and
ferrimagnetic
A ferrimagnetic material is a material that has populations of atoms with opposing magnetic moments, as in antiferromagnetism, but these moments are unequal in magnitude so a spontaneous magnetization remains. This can for example occur when ...
, and can be temporarily or permanently magnetized.
Palaeoceanography
The lateral mixing of barium is caused by water mass mixing and ocean circulation. Global ocean circulation reveals a strong correlation between dissolved barium and silicic acid. The large-scale ocean circulation combined with remineralization of barium show a similar correlation between dissolved barium and ocean alkalinity.
Dissolved barium's correlation with silicic acid can be seen both vertically and spatially. Particulate barium shows a strong correlation with
particulate organic carbon
Particulate organic matter (POM) is a fraction of total organic matter operationally defined as that which does not pass through a filter pore size that typically ranges in size from 0.053 to 2 millimeters.
Particulate organic carbon (POC) is ...
or POC. Barium is becoming more popular to be used a base for palaeoceanographic proxies. With both dissolved and particulate barium's links with silicic acid and POC, it can be used to determine historical variations in the biological pump, carbon cycle, and global climate.
The barium particulate barite (BaSO4), as one of many proxies, can be used to provide a host of historical information on processes in different oceanic settings (water column, sediments, and hydrothermal sites). In each setting there are differences in isotopic and elemental composition of the barite particulate. Barite in the water column, known as marine or pelagic barite, reveals information on seawater chemistry variation over time. Barite in sediments, known as diagenetic or cold seeps barite, gives information about sedimentary redox processes. Barite formed via hydrothermal activity at hydrothermal vents, known as hydrothermal barite, reveals alterations in the condition of the earth's crust around those vents.
Toxicity
Because of the high reactivity of the metal, toxicological data are available only for compounds. Soluble barium compounds are poisonous. In low doses, barium ions act as a muscle stimulant, and higher doses affect the
nervous system
In biology, the nervous system is the highly complex part of an animal that coordinates its actions and sensory information by transmitting signals to and from different parts of its body. The nervous system detects environmental changes th ...
anxiety
Anxiety is an emotion which is characterized by an unpleasant state of inner turmoil and includes feelings of dread over anticipated events. Anxiety is different than fear in that the former is defined as the anticipation of a future threat wh ...
,
shortness of breath
Shortness of breath (SOB), also medically known as dyspnea (in AmE) or dyspnoea (in BrE), is an uncomfortable feeling of not being able to breathe well enough. The American Thoracic Society defines it as "a subjective experience of breathing disc ...
, and
paralysis
Paralysis (also known as plegia) is a loss of motor function in one or more muscles. Paralysis can also be accompanied by a loss of feeling (sensory loss) in the affected area if there is sensory damage. In the United States, roughly 1 in 50 ...
. This toxicity may be caused by Ba2+blockingpotassium ion channels, which are critical to the proper function of the nervous system. Other organs damaged by water-soluble barium compounds (i.e., barium ions) are the eyes, immune system, heart, respiratory system, and skin causing, for example, blindness and sensitization.
Barium is not carcinogenic and does not
bioaccumulate
Bioaccumulation is the gradual accumulation of substances, such as pesticides or other chemicals, in an organism. Bioaccumulation occurs when an organism absorbs a substance at a rate faster than that at which the substance is lost or eliminated ...
. Inhaled dust containing insoluble barium compounds can accumulate in the lungs, causing a
benign
Malignancy () is the tendency of a medical condition to become progressively worse.
Malignancy is most familiar as a characterization of cancer. A ''malignant'' tumor contrasts with a non-cancerous benign tumor, ''benign'' tumor in that a malign ...
condition called
baritosis
Baritosis is a benign type of pneumoconiosis, which is caused by long-term exposure to barium dust.
Barium has a high radio-opacity and the disease may develop after few months of exposure. Extremely dense, discrete small opacities of 2–4  ...
. The insoluble sulfate is nontoxic and is not classified as a dangerous goods in transport regulations.
To avoid a potentially vigorous chemical reaction, barium metal is kept in an
argon
Argon is a chemical element with the symbol Ar and atomic number 18. It is in group 18 of the periodic table and is a noble gas. Argon is the third-most abundant gas in Earth's atmosphere, at 0.934% (9340 ppmv). It is more than twice as abu ...
atmosphere or under
mineral oil
Mineral oil is any of various colorless, odorless, light mixtures of higher alkanes from a mineral source, particularly a distillate of petroleum, as distinct from usually edible vegetable oils.
The name 'mineral oil' by itself is imprecise, ...
s. Contact with air is dangerous and may cause ignition. Moisture, friction, heat, sparks, flames, shocks, static electricity, and exposure to oxidizers and acids should be avoided. Anything that may contact with barium should be electrically grounded. Anyone who works with the metal should wear pre-cleaned non-sparking shoes, flame-resistant rubber clothes, rubber gloves, apron, goggles, and a gas mask. Smoking in the working area is typically forbidden. Thorough washing is required after handling barium.
See also
*
Han purple and Han blue
Han purple and Han blue (also called Chinese purple and Chinese blue) are synthetic barium copper silicate pigments developed in China and used in ancient and imperial China from the Western Zhou period (1045–771 BC) until the end of the Han ...
– synthetic barium
copper
Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkis ...
silicate
In chemistry, a silicate is any member of a family of polyatomic anions consisting of silicon and oxygen, usually with the general formula , where . The family includes orthosilicate (), metasilicate (), and pyrosilicate (, ). The name is al ...
pigments developed and used in ancient and imperial
China
China, officially the People's Republic of China (PRC), is a country in East Asia. It is the world's most populous country, with a population exceeding 1.4 billion, slightly ahead of India. China spans the equivalent of five time zones and ...
The Periodic Table of Videos
''Periodic Videos'' (also known as ''The Periodic Table of Videos'') is a video project and YouTube channel on chemistry. It consists of a series of videos about chemical elements and the periodic table, with additional videos on other topics i ...