Xenotime-(Y)
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Xenotime-(Y)
Xenotime is a rare-earth phosphate mineral, the major component of which is yttrium orthophosphate ( Y P O4). It forms a solid solution series with chernovite-(Y) ( Y As O4) and therefore may contain trace impurities of arsenic, as well as silicon dioxide and calcium. The rare-earth elements dysprosium, erbium, terbium and ytterbium, as well as metal elements such as thorium and uranium (all replacing yttrium) are the expressive secondary components of xenotime. Due to uranium and thorium impurities, some xenotime specimens may be weakly to strongly radioactive. Lithiophyllite, monazite and purpurite are sometimes grouped with xenotime in the informal "anhydrous phosphates" group. Xenotime is used chiefly as a source of yttrium and heavy lanthanide metals (dysprosium, ytterbium, erbium and gadolinium). Occasionally, gemstones are also cut from the finest xenotime crystals. Etymology The name ''xenotime'' is from the Greek words κενός ''vain'' and τιμή ''honor'', akin to ...
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Yttrium
Yttrium is a chemical element with the symbol Y and atomic number 39. It is a silvery-metallic transition metal chemically similar to the lanthanides and has often been classified as a "rare-earth element". Yttrium is almost always found in combination with lanthanide elements in rare-earth minerals, and is never found in nature as a free element. 89Y is the only stable isotope, and the only isotope found in the Earth's crust. The most important uses of yttrium are LEDs and phosphors, particularly the red phosphors in television set cathode ray tube displays. Yttrium is also used in the production of electrodes, electrolytes, electronic filters, lasers, superconductors, various medical applications, and tracing various materials to enhance their properties. Yttrium has no known biological role. Exposure to yttrium compounds can cause lung disease in humans. The element is named after '' ytterbite'', a mineral first identified in 1787 by the chemist Carl Axel Arrhenius. He n ...
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Phosphate Minerals
Phosphate minerals contain the tetrahedrally coordinated phosphate (PO43−) anion along sometimes with arsenate (AsO43−) and vanadate (VO43−) substitutions, and chloride (Cl−), fluoride (F−), and hydroxide (OH−) anions that also fit into the crystal structure. The phosphate class of minerals is a large and diverse group, however, only a few species are relatively common. Applications Phosphate rock has high concentration of phosphate minerals, most commonly of the apatite group. It is the major resource mined to produce phosphate fertilizers for the agriculture sector. Phosphate is also used in animal feed supplements, food preservatives, anti-corrosion agents, cosmetics, fungicides, ceramics, water treatment and metallurgy. The largest use of minerals mined for their phosphate content is the production of fertilizer. Phosphate minerals are often used for control of rust and prevention of corrosion on ferrous materials applied with electrochemical conversion co ...
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Terbium
Terbium is a chemical element with the symbol Tb and atomic number 65. It is a silvery-white, rare earth metal that is malleable, and ductile. The ninth member of the lanthanide series, terbium is a fairly electropositive metal that reacts with water, evolving hydrogen gas. Terbium is never found in nature as a free element, but it is contained in many minerals, including cerite, gadolinite, monazite, xenotime and euxenite. Swedish chemist Carl Gustaf Mosander discovered terbium as a chemical element in 1843. He detected it as an impurity in yttrium oxide, . Yttrium and terbium, as well as erbium and ytterbium, are named after the village of Ytterby in Sweden. Terbium was not isolated in pure form until the advent of ion exchange techniques. Terbium is used to dope calcium fluoride, calcium tungstate and strontium molybdate in solid-state devices, and as a crystal stabilizer of fuel cells that operate at elevated temperatures. As a component of Terfenol-D (an alloy that expands ...
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Chemical Element
A chemical element is a species of atoms that have a given number of protons in their nuclei, including the pure substance consisting only of that species. Unlike chemical compounds, chemical elements cannot be broken down into simpler substances by any chemical reaction. The number of protons in the nucleus is the defining property of an element, and is referred to as its atomic number (represented by the symbol ''Z'') – all atoms with the same atomic number are atoms of the same element. Almost all of the baryonic matter of the universe is composed of chemical elements (among rare exceptions are neutron stars). When different elements undergo chemical reactions, atoms are rearranged into new compounds held together by chemical bonds. Only a minority of elements, such as silver and gold, are found uncombined as relatively pure native element minerals. Nearly all other naturally occurring elements occur in the Earth as compounds or mixtures. Air is primarily a mixture o ...
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Jöns Jacob Berzelius
Baron Jöns Jacob Berzelius (; by himself and his contemporaries named only Jacob Berzelius, 20 August 1779 – 7 August 1848) was a Swedish chemist. Berzelius is considered, along with Robert Boyle, John Dalton, and Antoine Lavoisier, to be one of the founders of modern chemistry. Berzelius became a member of the Royal Swedish Academy of Sciences in 1808 and served from 1818 as its principal functionary. He is known in Sweden as the "Father of Swedish Chemistry". Berzelius Day is celebrated on 20 August in honour of him. Although Berzelius began his career as a physician, his enduring contributions were in the fields of electrochemistry, chemical bonding and stoichiometry. In particular, he is noted for his determination of atomic weights and his experiments that led to a more complete understanding of the principles of stoichiometry, which is the branch of chemistry pertaining to the quantitative relationships between elements in chemical compounds and chemical reactions and ...
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François Sulpice Beudant
François Sulpice Beudant (5 September 1787 – 10 December 1850), was a French mineralogist and geologist. The mineral beudantite was named after him. Life He was born in Paris. He was educated at the Ecole Polytechnique and Ecole Normale, and in 1811 was appointed professor of mathematics at the lycée of Avignon. Thence he was called, in 1813, to the lycée of Marseilles to fill the post of professor of physics, where he carried out the first measurements of the speed of sound in seawater. In the following year the royal mineralogical cabinet was committed to his charge to be conveyed into England, and from that time his attention was directed principally towards geology and cognate sciences. In 1817 he published a paper on the phenomena of crystallization, treating especially of the variety of forms assumed by the same mineral substance. In 1818 he undertook, at the expense of the French government, a geological journey through Hungary, and the results of his researches ...
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Greek Language
Greek ( el, label=Modern Greek, Ελληνικά, Elliniká, ; grc, Ἑλληνική, Hellēnikḗ) is an independent branch of the Indo-European family of languages, native to Greece, Cyprus, southern Italy (Calabria and Salento), southern Albania, and other regions of the Balkans, the Black Sea coast, Asia Minor, and the Eastern Mediterranean. It has the longest documented history of any Indo-European language, spanning at least 3,400 years of written records. Its writing system is the Greek alphabet, which has been used for approximately 2,800 years; previously, Greek was recorded in writing systems such as Linear B and the Cypriot syllabary. The alphabet arose from the Phoenician script and was in turn the basis of the Latin, Cyrillic, Armenian, Coptic, Gothic, and many other writing systems. The Greek language holds a very important place in the history of the Western world. Beginning with the epics of Homer, ancient Greek literature includes many works of lasting impo ...
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Gemstone
A gemstone (also called a fine gem, jewel, precious stone, or semiprecious stone) is a piece of mineral crystal which, in cut and polished form, is used to make jewelry or other adornments. However, certain rocks (such as lapis lazuli, opal, and obsidian) and occasionally organic materials that are not minerals (such as amber, jet, and pearl) are also used for jewelry and are therefore often considered to be gemstones as well. Most gemstones are hard, but some soft minerals are used in jewelry because of their luster or other physical properties that have aesthetic value. Rarity and notoriety are other characteristics that lend value to gemstones. Apart from jewelry, from earliest antiquity engraved gems and hardstone carvings, such as cups, were major luxury art forms. A gem expert is a gemologist, a gem maker is called a lapidarist or gemcutter; a diamond cutter is called a diamantaire. Characteristics and classification The traditional classification in the West, wh ...
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Lanthanide
The lanthanide () or lanthanoid () series of chemical elements comprises the 15 metallic chemical elements with atomic numbers 57–71, from lanthanum through lutetium. These elements, along with the chemically similar elements scandium and yttrium, are often collectively known as the rare-earth elements or rare-earth metals. The informal chemical symbol Ln is used in general discussions of lanthanide chemistry to refer to any lanthanide. All but one of the lanthanides are f-block elements, corresponding to the filling of the 4f electron shell. There is some dispute on whether lanthanum or lutetium is a d-block element, but lutetium is usually considered so by those who study the matter; it is included due to its chemical similarities with the other 14. All lanthanide elements form trivalent cations, Ln3+, whose chemistry is largely determined by the ionic radius, which decreases steadily from lanthanum to lutetium. These elements are called lanthanides because the elements i ...
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Purpurite
Purpurite is a mineral, manganese phosphate, MnPO4 with varying amounts of iron depending upon its source. It occurs in color ranges from brownish black via purple and violet to dark red. Purpurite forms a series with the iron-bearing endmember heterosite, FePO4. See also *Manganese violet Manganese violet is the common name for ammonium manganese(III) pyrophosphate, an inorganic compound composed of ammonium (), manganese in the +3 oxidation state, and the pyrophosphate anion (). It is prepared by heating a mixture of manganese(I ... References Manganese(III) minerals Iron(III) minerals Phosphate minerals Orthorhombic minerals Minerals in space group 53 {{Phosphate-mineral-stub ...
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Monazite
Monazite is a primarily reddish-brown phosphate mineral that contains rare-earth elements. Due to variability in composition, monazite is considered a group of minerals. The most common species of the group is monazite-(Ce), that is, the cerium-dominant member of the group. It occurs usually in small isolated crystals. It has a hardness of 5.0 to 5.5 on the Mohs scale of mineral hardness and is relatively dense, about 4.6 to 5.7 g/cm3. There are five different most common species of monazite, depending on the relative amounts of the rare earth elements in the mineral: * monazite-(Ce), ( Ce, La, Nd, Th) PO4 (the most common member), * monazite-(La), (La,Ce,Nd)PO4, * monazite-(Nd), (Nd,La,Ce)PO4, * monazite-(Sm), ( Sm, Gd,Ce,Th)PO4, * monazite-(Pr), ( Pr,Ce,Nd,Th)PO4. The elements in parentheses are listed in the order of their relative proportion within the mineral: lanthanum is the most common rare-earth element in monazite-(La), and so forth. Silica (SiO2) is present in trace a ...
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Lithiophyllite
Lithiophilite is a mineral containing the element lithium. It is lithium manganese(II) phosphate with chemical formula . It occurs in pegmatites often associated with triphylite, the iron end member in a solid solution series. The mineral with intermediate composition is known as sicklerite and has the chemical formula ). The name lithiophilite is derived from the Greek philos (φιλός) "friend," as lithiophilite is usually found with lithium. Lithiophylite is a resinous reddish to yellowish brown mineral crystallizing in the orthorhombic system often as slender prisms. It is usually associated with lepidolite, beryl, quartz, albite, amblygonite, and spodumene of pegmatitic origin. It rather readily weathers to a variety of secondary manganese phosphates and oxides. It is a late-stage mineral in some complex granite pegmatites. Members of the triphylite-lithiophilite series readily alter to secondary minerals. The type locality is the Branchville Quarry, Branchville, Fairfie ...
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