Wakefieldite
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Wakefieldite
Wakefieldite () is an uncommon rare-earth element vanadate mineral. There are four main types described of wakefieldite- wakefieldite-(La), wakefieldite-(Ce), wakefieldite-(Nd), and wakefieldite-(Y), depending upon the dominant rare-earth metal ion present. Wakefieldite has a Mohs hardness ranging from 4 to 5. Wakefieldite forms crystals of tetragonal structure. In terms of crystal structure, it is the vanadate analog of the rare-earth phosphate mineral xenotime. Unlike xenotime, it is more favorable for wakefieldite to contain the lighter rare-earth elements over the heavier ones. Due to the lanthanide contraction, the heavier rare earths have smaller ionic radii than the lighter ones. When the phosphate anion is replaced by the larger vanadate anion, the tetragonal crystal system preferentially accommodates the larger light rare-earth elements. Wakefieldite was first described for an occurrence in the Evans Lou mine, St. Pierre de Wakefield, Quebec, Canada Canada ...
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Wakefieldite-(Y)
Wakefieldite () is an uncommon rare-earth element vanadate mineral. There are four main types described of wakefieldite- wakefieldite-(La), wakefieldite-(Ce), wakefieldite-(Nd), and wakefieldite-(Y), depending upon the dominant rare-earth metal ion present. Wakefieldite has a Mohs scale of mineral hardness, Mohs hardness ranging from 4 to 5. Wakefieldite forms crystals of tetragonal structure. In terms of crystal structure, it is the vanadate analog of the rare-earth phosphate mineral xenotime. Unlike xenotime, it is more favorable for wakefieldite to contain the lighter rare-earth elements over the heavier ones. Due to the lanthanide contraction, the heavier rare earths have smaller ionic radii than the lighter ones. When the phosphate anion is replaced by the larger vanadate anion, the tetragonal crystal system preferentially accommodates the larger light rare-earth elements. Wakefieldite was first described for an occurrence in the Evans Lou mine, Val-des-Monts, Quebec, St. Pier ...
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Wakefieldite-(Ce)
Wakefieldite-(Ce) () is the cerium analogue of the uncommon rare-earth element vanadate mineral Wakefieldite. It is a member of the xenotime group. Wakefieldite-(Ce) was first described in 1977. It was initially given the name ''kusuïte'' for its type locality in the Kusu deposit, SW of Kinshasa, Zaire Zaire (, ), officially the Republic of Zaire (french: République du Zaïre, link=no, ), was a Congolese state from 1971 to 1997 in Central Africa that was previously and is now again known as the Democratic Republic of the Congo. Zaire was, .... In 1987 it was renamed as the Ce analog of wakefieldite-Y.Handbook of MineralogyWakefieldite-(Ce) References Cerium minerals Vanadate minerals Tetragonal minerals Minerals in space group 141 Minerals described in 1977 {{mineral-stub ...
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Wakefieldite-(La)
Wakefieldite-(La) () is the lanthanum analogue of the uncommon rare-earth element vanadate mineral Wakefieldite. It is a member of the xenotime group. Wakefieldite-(La) was first described in 2008 for an occurrence in the Glücksstern mine, Gottlob Hill, Friedrichroda, Thuringia, Germany Germany,, officially the Federal Republic of Germany, is a country in Central Europe. It is the second most populous country in Europe after Russia, and the most populous member state of the European Union. Germany is situated betwe ....Webmineral dataWakefieldite-(La) References Lanthanum minerals Vanadate minerals Tetragonal minerals Minerals in space group 141 Minerals described in 2008 {{mineral-stub ...
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Wakefieldite-(Nd)
Wakefieldite-(Nd) () is the neodymium analogue of the uncommon rare-earth element vanadate mineral wakefieldite. It is a member of the xenotime group. Wakefieldite-(Nd) was first described in 2008 at the Arase mine, Kami city, Kōchi Prefecture, Shikoku Island, Japan Japan ( ja, 日本, or , and formally , ''Nihonkoku'') is an island country in East Asia. It is situated in the northwest Pacific Ocean, and is bordered on the west by the Sea of Japan, while extending from the Sea of Okhotsk in the north .... and published in 2011.


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Vanadate Minerals
Arsenate minerals usually refer to the naturally occurring orthoarsenates, possessing the (AsO4)3− anion group and, more rarely, other arsenates with anions like AsO3(OH)2− (also written HAsO42−) (example: pharmacolite Ca(AsO3OH).2H2O) or (very rarely) sO2(OH)2sup>− (example: andyrobertsite). Arsenite minerals are much less common. Both the Dana and the Strunz mineral classifications place the arsenates in with the phosphate minerals. Example arsenate minerals include: *Annabergite Ni3(AsO4)2·8H2O *Austinite CaZn(AsO4)(OH) *Clinoclase Cu3(AsO4)(OH)3 *Conichalcite CaCu(AsO4)(OH) *Cornubite Cu5(AsO4)2(OH)4 *Cornwallite Cu2+5(AsO4)2(OH)2 *Erythrite Co3(AsO4)2·8H2O *Mimetite Pb5(AsO4)3Cl *Olivenite Cu2(AsO4)OH Nickel–Strunz Classification -08- Phosphates IMA-CNMNC proposes a new hierarchical scheme (Mills et al., 2009). This list uses it to modify the Classification of Nickel–Strunz ( mindat.org, 10 ed, pending publication). *Abbreviations: **"*" - discredited ( ...
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Xenotime
Xenotime is a rare-earth phosphate mineral, the major component of which is yttrium orthophosphate ( Y P O4). It forms a solid solution series with chernovite-(Y) ( Y As O4) and therefore may contain trace impurities of arsenic, as well as silicon dioxide and calcium. The rare-earth elements dysprosium, erbium, terbium and ytterbium, as well as metal elements such as thorium and uranium (all replacing yttrium) are the expressive secondary components of xenotime. Due to uranium and thorium impurities, some xenotime specimens may be weakly to strongly radioactive. Lithiophyllite, monazite and purpurite are sometimes grouped with xenotime in the informal "anhydrous phosphates" group. Xenotime is used chiefly as a source of yttrium and heavy lanthanide metals (dysprosium, ytterbium, erbium and gadolinium). Occasionally, gemstones are also cut from the finest xenotime crystals. Etymology The name ''xenotime'' is from the Greek words κενός ''vain'' and τιμή ''honor'', ak ...
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Rare-earth Mineral
A rare-earth mineral contains one or more rare-earth elements as major metal constituents. Rare-earth minerals are usually found in association with alkaline to peralkaline igneous complexes, in pegmatites associated with alkaline magmas and in or associated with carbonatite intrusives. Perovskite mineral phases are common hosts to rare-earth elements within the alkaline complexes. Mantle-derived carbonate melts are also carriers of the rare earths. Hydrothermal deposits associated with alkaline magmatism contain a variety of rare-earth minerals. The following includes the relatively common hydrothermal rare-earth minerals and minerals that often contain significant rare-earth substitution: *Aeschynite-( Y or Ce) *allanite *apatite *bastnäsite *britholite * brockite *cerite * Dollaseite-(Ce) *fluocerite *fluorite * gadolinite *monazite *parisite-( Ce or La) *stillwellite *synchysite *titanite *wakefieldite *xenotime *zircon Zircon () is a mineral belonging to the grou ...
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Lanthanide Contraction
The lanthanide contraction is the greater-than-expected decrease in atomic radii/ionic radii of the elements in the lanthanide series from atomic number 57, lanthanum, to 71, lutetium, which results in smaller than otherwise expected atomic radii/ionic radii for the subsequent elements starting with 72, hafnium. Jolly, William L. ''Modern Inorganic Chemistry'', McGraw-Hill 1984, p. 22 The term was coined by the Norwegian geochemist Victor Goldschmidt in his series "Geochemische Verteilungsgesetze der Elemente" (Geochemical distribution laws of the elements). Goldschmidt, Victor M. "Geochemische Verteilungsgesetze der Elemente", Part V "Isomorphie und Polymorphie der Sesquioxyde. Die Lanthaniden-Kontraktion und ihre Konsequenzen", Oslo, 1925 Cause The effect results from poor shielding of nuclear charge (nuclear attractive force on electrons) by 4f electrons; the 6s electrons are drawn towards the nucleus, thus resulting in a smaller atomic radius. In single-electron atoms ...
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Lanthanide Minerals
The lanthanide () or lanthanoid () series of chemical elements comprises the 15 metallic chemical elements with atomic numbers 57–71, from lanthanum through lutetium. These elements, along with the chemically similar elements scandium and yttrium, are often collectively known as the rare-earth elements or rare-earth metals. The informal chemical symbol Ln is used in general discussions of lanthanide chemistry to refer to any lanthanide. All but one of the lanthanides are f-block elements, corresponding to the filling of the 4f electron shell. There is some dispute on whether lanthanum or lutetium is a d-block element, but lutetium is usually considered so by those who study the matter; it is included due to its chemical similarities with the other 14. All lanthanide elements form trivalent cations, Ln3+, whose chemistry is largely determined by the ionic radius, which decreases steadily from lanthanum to lutetium. These elements are called lanthanides because the elements in ...
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Canada
Canada is a country in North America. Its ten provinces and three territories extend from the Atlantic Ocean to the Pacific Ocean and northward into the Arctic Ocean, covering over , making it the world's second-largest country by total area. Its southern and western border with the United States, stretching , is the world's longest binational land border. Canada's capital is Ottawa, and its three largest metropolitan areas are Toronto, Montreal, and Vancouver. Indigenous peoples have continuously inhabited what is now Canada for thousands of years. Beginning in the 16th century, British and French expeditions explored and later settled along the Atlantic coast. As a consequence of various armed conflicts, France ceded nearly all of its colonies in North America in 1763. In 1867, with the union of three British North American colonies through Confederation, Canada was formed as a federal dominion of four provinces. This began an accretion of provinces an ...
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Quebec
Quebec ( ; )According to the Canadian government, ''Québec'' (with the acute accent) is the official name in Canadian French and ''Quebec'' (without the accent) is the province's official name in Canadian English is one of the thirteen provinces and territories of Canada. It is the largest province by area and the second-largest by population. Much of the population lives in urban areas along the St. Lawrence River, between the most populous city, Montreal, and the provincial capital, Quebec City. Quebec is the home of the Québécois nation. Located in Central Canada, the province shares land borders with Ontario to the west, Newfoundland and Labrador to the northeast, New Brunswick to the southeast, and a coastal border with Nunavut; in the south it borders Maine, New Hampshire, Vermont, and New York in the United States. Between 1534 and 1763, Quebec was called ''Canada'' and was the most developed colony in New France. Following the Seven Years' War, Quebec b ...
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Val-des-Monts, Quebec
Val-des-Monts is a municipality in the Outaouais region of Quebec, Canada, located about north of Ottawa, Ontario. It has a population of 13,328 residents in 2021. Formed in 1975 by the merger of the towns of Perkins, Saint-Pierre-de-Wakefield and Poltimore, it consists mainly of farms and mountainous forests. Many of its residents commute to Ottawa or Gatineau for work. Due to its numerous lakes, its population is boosted during summers by people living in cottages. Most of the people in Val-des-Monts live in the village of Perkins. Toponymy The name of Val-des-Monts is from the French words ''Val'' which means "small valley" and ''Monts'' which means "mounts". This name is a reference to the fact that the territory of the municipality includes several valleys and mountains. Geography The municipality of Val-des-Monts is located at approximately 10 km north of Gatineau and 220 km west of Montreal. It is part of Les Collines-de-l'Outaouais Regional County Municipality ...
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