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Transfer Matrix Method
In statistical mechanics, the transfer-matrix method is a Mathematical physics, mathematical technique which is used to write the Partition function (mathematics), partition function into a simpler form. It was introduced in 1941 by Hans Kramers and Gregory Wannier. In many one dimensional Lattice model (physics), lattice models, the partition function is first written as an ''n''-fold summation over each possible Microstate (statistical mechanics), microstate, and also contains an additional summation of each component's contribution to the energy of the system within each microstate. Overview Higher dimensional models contain even more summations. For systems with more than a few particles, such expressions can quickly become too complex to work out directly, even by computer. Instead, the partition function can be rewritten in an equivalent way. The basic idea is to write the partition function (mathematics), partition function in the form : \mathcal = \mathbf_0 \cdot \left ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Statistical Mechanics
In physics, statistical mechanics is a mathematical framework that applies statistical methods and probability theory to large assemblies of microscopic entities. It does not assume or postulate any natural laws, but explains the macroscopic behavior of nature from the behavior of such ensembles. Statistical mechanics arose out of the development of classical thermodynamics, a field for which it was successful in explaining macroscopic physical properties—such as temperature, pressure, and heat capacity—in terms of microscopic parameters that fluctuate about average values and are characterized by probability distributions. This established the fields of statistical thermodynamics and statistical physics. The founding of the field of statistical mechanics is generally credited to three physicists: *Ludwig Boltzmann, who developed the fundamental interpretation of entropy in terms of a collection of microstates *James Clerk Maxwell, who developed models of probability distr ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |