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Thermodynamic Process
Classical thermodynamics considers three main kinds of thermodynamic processes: (1) changes in a system, (2) cycles in a system, and (3) flow processes. (1) A Thermodynamic process is a process in which the thermodynamic state of a system is changed. A change in a system is defined by a passage from an initial to a final state of thermodynamic equilibrium. In classical thermodynamics, the actual course of the process is not the primary concern, and often is ignored. A state of thermodynamic equilibrium endures unchangingly unless it is interrupted by a thermodynamic operation that initiates a thermodynamic process. The equilibrium states are each respectively fully specified by a suitable set of thermodynamic state variables, that depend only on the current state of the system, not on the path taken by the processes that produce the state. In general, during the actual course of a thermodynamic process, the system may pass through physical states which are not describable as th ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Thermodynamic System
A thermodynamic system is a body of matter and/or radiation separate from its surroundings that can be studied using the laws of thermodynamics. Thermodynamic systems can be passive and active according to internal processes. According to internal processes, passive systems and active systems are distinguished: passive, in which there is a redistribution of available energy, active, in which one type of energy is converted into another. Depending on its interaction with the environment, a thermodynamic system may be an isolated system, a Closed system#In thermodynamics, closed system, or an Open system (systems theory), open system. An isolated system does not exchange matter or energy with its surroundings. A closed system may exchange heat, experience forces, and exert forces, but does not exchange matter. An open system can interact with its surroundings by exchanging both matter and energy. The physical condition of a thermodynamic system at a given time is described by its ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Work (thermodynamics)
Thermodynamic work is one of the principal kinds of process by which a thermodynamic system can interact with and transfer energy to its surroundings. This results in externally measurable macroscopic forces on the system's surroundings, which can cause mechanical work, to lift a weight, for example,Kittel, C. Kroemer, H. (1980). ''Thermal Physics'', second edition, W.H. Freeman, San Francisco, or cause changes in electromagnetic,Guggenheim, E.A. (1985). ''Thermodynamics. An Advanced Treatment for Chemists and Physicists'', seventh edition, North Holland, Amsterdam, .Jackson, J.D. (1975). ''Classical Electrodynamics'', second edition, John Wiley and Sons, New York, .Konopinski, E.J. (1981). ''Electromagnetic Fields and Relativistic Particles'', McGraw-Hill, New York, . or gravitationalNorth, G.R., Erukhimova, T.L. (2009). ''Atmospheric Thermodynamics. Elementary Physics and Chemistry'', Cambridge University Press, Cambridge (UK), . variables. Also, the surroundings can perform t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Enthalpy
Enthalpy () is the sum of a thermodynamic system's internal energy and the product of its pressure and volume. It is a state function in thermodynamics used in many measurements in chemical, biological, and physical systems at a constant external pressure, which is conveniently provided by the large ambient atmosphere. The pressure–volume term expresses the work (physics), work W that was done against constant external pressure P_\text to establish the system's physical dimensions from V_\text=0 to some final volume V_\text (as W=P_\text\Delta V), i.e. to make room for it by displacing its surroundings. The pressure-volume term is very small for solids and liquids at common conditions, and fairly small for gases. Therefore, enthalpy is a stand-in for energy in chemical systems; Bond energy, bond, Lattice energy, lattice, solvation, and other chemical "energies" are actually enthalpy differences. As a state function, enthalpy depends only on the final configuration of internal e ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Isenthalpic Process
An isenthalpic process or isoenthalpic process is a process that proceeds without any change in enthalpy, ''H''; or specific enthalpy, ''h''. Overview If a steady-state, steady-flow process is analysed using a control volume, everything outside the control volume is considered to be the ''surroundings''.G. J. Van Wylen and R. E. Sonntag, ''Fundamentals of Classical Thermodynamics'', Section 2.1 (3rd edition). Such a process will be isenthalpic if there is no transfer of heat to or from the surroundings, no work done on or by the surroundings, and no change in the kinetic energy of the fluid.G. J. Van Wylen and R. E. Sonntag, ''Fundamentals of Classical Thermodynamics'', Section 5.13 (3rd edition). This is a sufficient but not necessary condition for isoenthalpy. The necessary condition for a process to be isoenthalpic is that the sum of each of the terms of the energy balance other than enthalpy (work, heat, changes in kinetic energy, etc.) cancel each other, so that the enthalpy ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Thermodynamic Potential
Thermodynamics is a branch of physics that deals with heat, Work (thermodynamics), work, and temperature, and their relation to energy, entropy, and the physical properties of matter and radiation. The behavior of these quantities is governed by the four laws of thermodynamics, which convey a quantitative description using measurable macroscopic physical quantity, physical quantities but may be explained in terms of microscopic constituents by statistical mechanics. Thermodynamics applies to various topics in science and engineering, especially physical chemistry, biochemistry, chemical engineering, and mechanical engineering, as well as other complex fields such as meteorology. Historically, thermodynamics developed out of a desire to increase the thermodynamic efficiency, efficiency of early steam engines, particularly through the work of French physicist Nicolas Léonard Sadi Carnot, Sadi Carnot (1824) who believed that engine efficiency was the key that could help France win ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Particle Number
In thermodynamics, the particle number (symbol ) of a thermodynamic system is the number of constituent particles in that system. The particle number is a fundamental thermodynamic property which is conjugate to the chemical potential. Unlike most physical quantities, the particle number is a dimensionless quantity, specifically a countable quantity. It is an extensive property, as it is directly proportional to the size of the system under consideration and thus meaningful only for closed systems. A constituent particle is one that cannot be broken into smaller pieces at the scale of energy involved in the process (where is the Boltzmann constant and is the temperature). For example, in a thermodynamic system consisting of a piston containing water vapour, the particle number is the number of water molecules in the system. The meaning of constituent particles, and thereby of particle numbers, is thus temperature-dependent. Determining the particle number The concept of pa ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chemical Potential
In thermodynamics, the chemical potential of a Chemical specie, species is the energy that can be absorbed or released due to a change of the particle number of the given species, e.g. in a chemical reaction or phase transition. The chemical potential of a species in a mixture is defined as the rate of change of Thermodynamic free energy, free energy of a thermodynamic system with respect to the change in the number of atoms or molecules of the species that are added to the system. Thus, it is the partial derivative of the free energy with respect to the amount of the species, all other species' concentrations in the mixture remaining constant. When both temperature and pressure are held constant, and the number of particles is expressed in moles, the chemical potential is the partial Molar concentration, molar Gibbs free energy. At chemical equilibrium or in phase equilibrium, the total sum of the product of chemical potentials and stoichiometric coefficients is zero, as the free en ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Isentropic Process
An isentropic process is an idealized thermodynamic process that is both Adiabatic process, adiabatic and Reversible process (thermodynamics), reversible. The work (physics), work transfers of the system are friction, frictionless, and there is no net transfer of heat or matter. Such an idealized process is useful in engineering as a model of and basis of comparison for real processes. This process is idealized because reversible processes do not occur in reality; thinking of a process as both adiabatic and reversible would show that the initial and final entropies are the same, thus, the reason it is called isentropic (entropy does not change). Thermodynamics, Thermodynamic processes are named based on the effect they would have on the system (ex. isovolumetric: constant volume, isenthalpic: constant enthalpy). Even though in reality it is not necessarily possible to carry out an isentropic process, some may be approximated as such. The word "isentropic" derives from the proc ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Adiabatic Process
An adiabatic process (''adiabatic'' ) is a type of thermodynamic process that occurs without transferring heat between the thermodynamic system and its Environment (systems), environment. Unlike an isothermal process, an adiabatic process transfers energy to the surroundings only as Work (thermodynamics), work and/or mass flow.. A translation may be founhere. Also a mostly reliabltranslation is to be foundin As a key concept in thermodynamics, the adiabatic process supports the theory that explains the first law of thermodynamics. The opposite term to "adiabatic" is ''diabatic''. Some chemical and physical processes occur too rapidly for energy to enter or leave the system as heat, allowing a convenient "adiabatic approximation".Bailyn, M. (1994), pp. 52–53. For example, the adiabatic flame temperature uses this approximation to calculate the upper limit of fire, flame temperature by assuming combustion loses no heat to its surroundings. In meteorology, adiabatic expansion an ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Isothermal Process
An isothermal process is a type of thermodynamic process in which the temperature ''T'' of a system remains constant: Δ''T'' = 0. This typically occurs when a system is in contact with an outside thermal reservoir, and a change in the system occurs slowly enough to allow the system to be continuously adjusted to the temperature of the reservoir through heat exchange (see quasi-equilibrium). In contrast, an '' adiabatic process'' is where a system exchanges no heat with its surroundings (''Q'' = 0). Simply, we can say that in an isothermal process * T = \text * \Delta T = 0 * dT = 0 * For ideal gases only, internal energy \Delta U = 0 while in adiabatic processes: * Q = 0. Etymology The noun '' isotherm'' is derived from the Ancient Greek words (), meaning "equal", and (), meaning "heat". Examples Isothermal processes can occur in any kind of system that has some means of regulating the temperature, including highly structured machines, and even living ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Isobaric Process
In thermodynamics, an isobaric process is a type of thermodynamic process in which the pressure of the Thermodynamic system, system stays constant: Δ''P'' = 0. The heat transferred to the system does work (thermodynamics), work, but also changes the internal energy (''U'') of the system. This article uses the physics sign convention for work, where positive work is work (thermodynamics)#Sign convention, work done by the system. Using this convention, by the first law of thermodynamics, : Q = \Delta U + W\, where ''W'' is work, ''U'' is internal energy, and ''Q'' is heat. Pressure-volume work by the closed system is defined as: :W = \int \! p \,dV \, where Δ means change over the whole process, whereas ''d'' denotes a differential. Since pressure is constant, this means that : W = p \Delta V\, . Applying the ideal gas law, this becomes : W = n\,R\,\Delta T with ''R'' representing the gas constant, and ''n'' representing the amount of substance, which is ass ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
