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Polythionic Acid
Polythionic acid is an oxoacid which has a straight chain of sulfur atoms and has the chemical formula Sn(SO3H)2 (''n'' > 2). Trithionic acid (H2S3O6), tetrathionic acid (H2S4O6) are simple examples. They are the conjugate acids of polythionates. The compounds of ''n'' 2− + 2 HCl :: SCl2 + 2 → 3SS3SO3sup>2− + 2 HCl Anhydrous polythionic acids can be formed in diethyl ether solution by the following three general ways: : HSnSO3H + SO3 → H2S''n''+2O6 (''n'' = 1, 2 ... 8) : H2Sn + 2 SO3 → H2S''n''+2O6 (''n'' = 1, 2 ... 8) : 2 HSnSO3H + I2 → H2S2''n''+2O6 + 2 HI (''n'' = 1, 2 ... 6) Polythionic acids with a small number of sulfur atoms in the chain (''n'' = 3, 4, 5, 6) are the most stable. Polythionic acids are stable only in aqueous solutions, and are rapidly destroyed at higher concentrations with the release of sulfur, sulfur dioxide and - sometimes - sulfuric acid. Acid salts of polythionic acids do not exist. Polythionate ions are sign ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chain Transfer
Chain transfer is a polymerization Chemical reaction, reaction by which the activity of a growing polymer chain is transferred to another molecule. :P• + XR' → PX + R'• Chain transfer reactions reduce the average molecular weight of the final polymer. Chain transfer can be either introduced deliberately into a polymerization (by use of a ''chain transfer agent'') or it may be an unavoidable side-reaction with various components of the polymerization. Chain transfer reactions occur in most forms of addition polymerization including radical polymerization, ring-opening polymerization, coordination polymerization, and cationic polymerization, as well as anionic polymerization. Types Chain transfer reactions are usually categorized by the nature of the molecule that reacts with the growing chain. * Transfer to chain transfer agent. Chain transfer agents have at least one weak chemical bond, which therefore facilitates the chain transfer reaction. Common chain transfer age ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sulfur Oxoacids
Sulfur oxoacids are chemical compounds that contain sulfur, oxygen, and hydrogen. The best known and most important industrially used is sulfuric acid. Sulfur has several oxoacids; however, some of these are known only from their salts (these are shown in italics in the table below). The acids that have been characterised contain a variety of structural features, for example: *tetrahedral sulfur when coordinated to oxygen *terminal and bridging oxygen atoms *terminal peroxo groups *terminal S=S *chains of (−S−)''n'' See also * Chlorosulfuric acid * Fluorosulfuric acid *Nitrosylsulfuric acid *Peroxydisulfuric acid Peroxydisulfuric acid is an inorganic compound with a chemical formula . Also called Marshall's acid after Professor Hugh Marshall, who discovered it in 1891. Structure and bonding This oxoacid features sulfur in its +6 oxidation state and a ... * Sulfinic acids * Sulfonic acids References External links *{{MeSH name, Sulfur+Acids Sulfur oxoacids along wit ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Prediction Of Volcanic Activity
Prediction of volcanic activity, or volcanic eruption forecasting, is an interdisciplinary monitoring and research effort to predict the time and severity of a volcano's eruption. Of particular importance is the prediction of hazardous eruptions that could lead to catastrophic loss of life, property, and disruption of human activities. Seismic waves (seismicity) General principles of volcano seismology * Seismic activity (earthquakes and tremors) always occurs as volcanoes awaken and prepare to erupt and are a very important link to eruptions. Some volcanoes normally have continuing low-level seismic activity, but an increase may signal a greater likelihood of an eruption. The types of earthquakes that occur and where they start and end are also key signs. Volcanic seismicity has three major forms: short-period earthquake, long-period earthquake, and harmonic tremor. * Short-period earthquakes are like normal fault-generated earthquakes. They are caused by the fracturing of bri ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Volcanic Crater Lake
A volcanic crater lake is a lake in a crater that was formed by explosive activity or a collapse during a volcanic eruption. Formation Lakes in calderas fill large craters formed by the collapse of a volcano during an eruption. Lakes in maars fill medium-sized craters where an eruption deposited debris around a vent. Crater lakes form as the created depression, within the crater rim, is filled by water. The water may come from precipitation, groundwater circulation (often hydrothermal fluids in the case of volcanic craters) or melted ice. Its level rises until an equilibrium is reached between the rates of incoming and outgoing water. Sources of water loss singly or together may include evaporation, subsurface seepage, and, in places, surface leakage or overflow when the lake level reaches the lowest point on its rim. At such a saddle location, the upper portion of the lake is contained only by its adjacent natural volcanic dam; continued leakage through or surface outflow ac ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sulfites
Sulfites or sulphites are compounds that contain the sulfite ion (or the sulfate(IV) ion, from its correct systematic name), . The sulfite ion is the conjugate base of bisulfite. Although its acid (sulfurous acid) is elusive, its salts are widely used. Sulfites are substances that naturally occur in some foods and the human body. They are also used as regulated food additives. When in food or drink, sulfites are often lumped together with sulfur dioxide.SeREGULATION (EU) No 1169/2011 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL/ref> Structure The structure of the sulfite anion can be described with three equivalent resonance structures. In each resonance structure, the sulfur atom is double-bonded to one oxygen atom with a formal charge of zero (neutral), and sulfur is singly bonded to the other two oxygen atoms, which each carry a formal charge of −1, together accounting for the −2 charge on the anion. There is also a non-bonded lone pair on the sulfur, so the structure ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Amalgam (chemistry)
An amalgam is an alloy of mercury with another metal A metal (from Greek μέταλλον ''métallon'', "mine, quarry, metal") is a material that, when freshly prepared, polished, or fractured, shows a lustrous appearance, and conducts electricity and heat relatively well. Metals are typicall .... It may be a liquid, a soft paste or a solid, depending upon the proportion of mercury. These alloys are formed through metallic bonding, with the electrostatic attractive force of the conduction electrons working to bind all the positively charged metal ions together into a Crystal structure, crystal lattice structure. Almost all metals can form amalgams with mercury, the notable exceptions being iron, platinum, tungsten, and tantalum. Silver-mercury amalgam (dentistry), amalgams are important in dentistry, and gold-mercury amalgam is used in the Gold extraction, extraction of gold from ore. Dentistry has used alloys of mercury with metals such as silver, copper, indium, tin a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sulfate
The sulfate or sulphate ion is a polyatomic anion with the empirical formula . Salts, acid derivatives, and peroxides of sulfate are widely used in industry. Sulfates occur widely in everyday life. Sulfates are salts of sulfuric acid and many are prepared from that acid. Spelling "Sulfate" is the spelling recommended by IUPAC, but "sulphate" was traditionally used in British English. Structure The sulfate anion consists of a central sulfur atom surrounded by four equivalent oxygen atoms in a tetrahedral arrangement. The symmetry is the same as that of methane. The sulfur atom is in the +6 oxidation state while the four oxygen atoms are each in the −2 state. The sulfate ion carries an overall charge of −2 and it is the conjugate base of the bisulfate (or hydrogensulfate) ion, , which is in turn the conjugate base of , sulfuric acid. Organic sulfate esters, such as dimethyl sulfate, are covalent compounds and esters of sulfuric acid. The tetrahedral molecular geometry of th ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Potassium Dichromate
Potassium dichromate, , is a common inorganic chemical reagent, most commonly used as an oxidizing agent in various laboratory and industrial applications. As with all hexavalent chromium compounds, it is acutely and chronically harmful to health. It is a crystalline ionic solid with a very bright, red-orange color. The salt is popular in the laboratory because it is not deliquescent, in contrast to the more industrially relevant salt sodium dichromate.Gerd Anger, Jost Halstenberg, Klaus Hochgeschwender, Christoph Scherhag, Ulrich Korallus, Herbert Knopf, Peter Schmidt, Manfred Ohlinger, "Chromium Compounds" in Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH, Weinheim, 2005. Chemistry Production Potassium dichromate is usually prepared by the reaction of potassium chloride on sodium dichromate. Alternatively, it can be also obtained from potassium chromate by roasting chromite ore with potassium hydroxide. It is soluble in water and in the dissolution process it io ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Potassium Permanganate
Potassium permanganate is an inorganic compound with the chemical formula KMnO4. It is a purplish-black crystalline salt, that dissolves in water as K+ and , an intensely pink to purple solution. Potassium permanganate is widely used in the chemical industry and laboratories as a strong oxidizing agent, and also as a medication for dermatitis, for cleaning wounds, and general disinfection. It is on the World Health Organization's List of Essential Medicines. In 2000, worldwide production was estimated at 30,000 tonnes. Properties Potassium permanganate is the potassium salt of the tetrahedral transition metal oxo complex permanganate, in which four O2- ligands are bound to a manganese(VII) center. Structure KMnO4 forms orthorhombic crystals with constants: ''a'' = 910.5 pm, ''b'' = 572.0 pm, ''c'' = 742.5 pm. The overall motif is similar to that for barium sulfate, with which it forms solid solutions. In the solid (as in solution), each MnO4− centre is t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Diethyl Ether
Diethyl ether, or simply ether, is an organic compound in the ether class with the formula , sometimes abbreviated as (see Pseudoelement symbols). It is a colourless, highly volatile, sweet-smelling ("ethereal odour"), extremely flammable liquid. It is commonly used as a solvent in laboratories and as a starting fluid for some engines. It was formerly used as a general anesthetic, until non-flammable drugs were developed, such as halothane. It has been used as a recreational drug to cause intoxication. Production Most diethyl ether is produced as a byproduct of the vapor-phase hydration of ethylene to make ethanol. This process uses solid-supported phosphoric acid catalysts and can be adjusted to make more ether if the need arises. Vapor-phase dehydration of ethanol over some alumina catalysts can give diethyl ether yields of up to 95%. Diethyl ether can be prepared both in laboratories and on an industrial scale by the acid ether synthesis. Ethanol is mixed with a stro ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sulfuric Acid
Sulfuric acid (American spelling and the preferred IUPAC name) or sulphuric acid ( Commonwealth spelling), known in antiquity as oil of vitriol, is a mineral acid composed of the elements sulfur, oxygen and hydrogen, with the molecular formula . It is a colorless, odorless and viscous liquid that is miscible with water. Pure sulfuric acid does not exist naturally on Earth due to its strong affinity to water vapor; it is hygroscopic and readily absorbs water vapor from the air. Concentrated sulfuric acid is highly corrosive towards other materials, from rocks to metals, since it is an oxidant with powerful dehydrating properties. Phosphorus pentoxide is a notable exception in that it is not dehydrated by sulfuric acid, but to the contrary dehydrates sulfuric acid to sulfur trioxide. Upon addition of sulfuric acid to water, a considerable amount of heat is released; thus the reverse procedure of adding water to the acid should not be performed since the heat released may boi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
