Pinene Oxide
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Pinene Oxide
Pinene is a collection of unsaturated bicyclic monoterpenes. Two geometric isomers of pinene are found in nature, Alpha-Pinene, α-pinene and Beta-pinene, β-pinene. Both are chiral. As the name suggests, pinenes are found in pines. Specifically, pinene is the major component of the liquid extracts of Pinophyta, conifers. Pinenes are also found in many non-coniferous plants such as camphorweed (''Heterotheca'') and big sagebrush (''Artemisia tridentata''). Isomers Biosynthesis α-Pinene and β-pinene are both produced from geranyl pyrophosphate, via cyclisation of linalool, linaloyl pyrophosphate followed by loss of a proton from the carbocation equivalent. Researchers at the Georgia Institute of Technology and the Joint BioEnergy Institute have been able to synthetically produce pinene with a bacterium. Plants Alpha-pinene is the most widely encountered terpenoid in nature and is highly repellent to insects. Alpha-pinene appears in conifers and numerous other plants. Pi ...
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Monoterpene
Monoterpenes are a class of terpenes that consist of two isoprene units and have the molecular formula C10H16. Monoterpenes may be linear (acyclic) or contain rings (monocyclic and bicyclic). Modified terpenes, such as those containing oxygen functionality or missing a methyl group, are called monoterpenoids. Monoterpenes and monoterpenoids are diverse. They have relevance to the pharmaceutical, cosmetic, agricultural, and food industries. Biosynthesis Monoterpenes are derived biosynthetically from units of isopentenyl pyrophosphate, which is formed from acetyl-CoA via the intermediacy of mevalonic acid in the HMG-CoA reductase pathway. An alternative, unrelated biosynthesis pathway of IPP is known in some bacterial groups and the plastids of plants, the so-called MEP-(2-methyl-D-erythritol-4-phosphate) pathway, which is initiated from C5 sugars. In both pathways, IPP is isomerized to DMAPP by the enzyme isopentenyl pyrophosphate isomerase. Geranyl pyrophosphate is the precurso ...
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Pine Nuts
Pine nuts, also called piñón (), pinoli (), pignoli or chilgoza (), are the edible seeds of pines (family Pinaceae, genus ''Pinus''). According to the Food and Agriculture Organization, only 29 species provide edible nuts, while 20 are traded locally or internationally owing to their seed size being large enough to be worth harvesting; in other pines, the seeds are also edible, but are too small to be of notable value as a human food. Species and geographic spread In Asia, two species in particular are widely harvested: Korean pine (''Pinus koraiensis'') in northeast Asia (the most important species in international trade) and chilgoza pine (''Pinus gerardiana'') in the western Himalaya. Four other species, Siberian pine (''Pinus sibirica''), Siberian dwarf pine (''Pinus pumila''), Chinese white pine (''Pinus armandii'') and lacebark pine (''Pinus bungeana''), are also used to a lesser extent. Russia is the largest producer of ''Pinus sibirica'' nuts in the world, followed b ...
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Pistacia Terebinthus
''Pistacia terebinthus'' also called the terebinth and the turpentine tree, is a deciduous tree species of the genus ''Pistacia'', native to the Mediterranean region from the western regions of Morocco and Portugal to Greece and western and southeastern Turkey. At one time terebinths growing on the eastern shores of the Mediterranean Sea (in Syria, Lebanon and Israel) were regarded as a separate species, ''Pistacia palaestina'', but these are now considered to be a synonym (taxonomy), synonym of ''P. terebinthus''. Description The terebinth is a deciduous In the fields of horticulture and Botany, the term ''deciduous'' () means "falling off at maturity" and "tending to fall off", in reference to trees and shrubs that seasonally shed leaves, usually in the autumn; to the shedding of petals, aft ... flowering plant belonging to the cashew family, Anacardiaceae; a small tree or large shrub, it grows to tall. The Leaf, leaves are compound, long, odd pinnate with five to e ...
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Cannabis
''Cannabis'' () is a genus of flowering plants in the family Cannabaceae. The number of species within the genus is disputed. Three species may be recognized: ''Cannabis sativa'', '' C. indica'', and '' C. ruderalis''. Alternatively, ''C. ruderalis'' may be included within ''C. sativa'', all three may be treated as subspecies of ''C. sativa'', or ''C. sativa'' may be accepted as a single undivided species. The genus is widely accepted as being indigenous to and originating from Asia. The plant is also known as hemp, although this term is often used to refer only to varieties of ''Cannabis'' cultivated for non-drug use. Cannabis has long been used for hemp fibre, hemp seeds and their oils, hemp leaves for use as vegetables and as juice, medicinal purposes, and as a recreational drug. Industrial hemp products are made from cannabis plants selected to produce an abundance of fibre. Various cannabis strains have been bred, often selectively to pro ...
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Salvia
''Salvia'' () is the largest genus of plants in the sage family Lamiaceae, with nearly 1000 species of shrubs, herbaceous plant, herbaceous perennial plant, perennials, and annual plant, annuals. Within the Lamiaceae, ''Salvia'' is part of the tribe Mentheae within the subfamily Nepetoideae. One of several genera commonly referred to as sage, it includes two widely used herbs, ''Salvia officinalis'' (common sage, or just "sage") and ''Salvia rosmarinus'' (rosemary, formerly ''Rosmarinus officinalis''). The genus is distributed throughout the Old World and the Americas (over 900 total species), with three distinct regions of diversity: Central America and South America (approximately 600 species); Central Asia and the Mediterranean (250 species); Eastern Asia (90 species). Etymology The name ''Salvia'' derives from Latin (sage), from (safe, secure, healthy), an adjective related to (health, well-being, prosperity or salvation), and (to feel healthy, to heal). Pliny the Eld ...
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Sideritis
''Sideritis'', also known as ironwort, mountain tea, and shepherd's tea, is a genus of flowering plants known for their use as herbal medicine, commonly as an herbal tea. They are abundant in Mediterranean regions, the Balkans, the Iberian Peninsula and Macaronesia, but can also be found in Central Europe and temperate Asia. History and etymology In Greek, "sideritis" ( Gr: σιδηρίτις) can be literally translated as "he who is made of iron". The plant was known to ancient Greeks, specifically Pedanius Dioscorides and Theophrastus. Although Dioscorides describes three species, only one (probably ''S. scordioides'') is thought to belong to ''Sideritis''. In ancient times "sideritis" was a generic reference for plants capable of healing wounds caused by iron weapons during battles. However, others hold that the name stems from the shape of the sepal, which resembles the tip of a spear. Taxonomy In 2002, molecular phylogenetic research found ''Sideritis'' and five other ge ...
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Conifers
Conifers are a group of cone-bearing seed plants, a subset of gymnosperms. Scientifically, they make up the division Pinophyta (), also known as Coniferophyta () or Coniferae. The division contains a single extant class, Pinopsida. All extant conifers are perennial woody plants with secondary growth. The great majority are trees, though a few are shrubs. Examples include cedars, Douglas-firs, cypresses, firs, junipers, kauri, larches, pines, hemlocks, redwoods, spruces, and yews.Campbell, Reece, "Phylum Coniferophyta". Biology. 7th. 2005. Print. P. 595 As of 1998, the division Pinophyta was estimated to contain eight families, 68 genera, and 629 living species. Although the total number of species is relatively small, conifers are ecologically important. They are the dominant plants over large areas of land, most notably the taiga of the Northern Hemisphere, but also in similar cool climates in mountains further south. Boreal conifers have many wintertime adaptations. The ...
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Alpha-pinene
α-Pinene is an organic compound of the terpene class, one of two isomers of pinene. It is an alkene and it contains a reactive four-membered ring. It is found in the oils of many species of many coniferous trees, notably the pine. It is also found in the essential oil of rosemary (''Rosmarinus officinalis'') and '' Satureja myrtifolia'' (also known as ''Zoufa'' in some regions). Both enantiomers are known in nature; (1''S'',5''S'')- or (−)-α-pinene is more common in European pines, whereas the (1''R'',5''R'')- or (+)-α-isomer is more common in North America. The racemic mixture is present in some oils such as eucalyptus oil and orange peel oil. Reactivity : Commercially important derivatives of alpha-pinene are linalool, geraniol, nerol, a-terpineol, and camphene. α-Pinene 1 is reactive owing to the presence of the four-membered ring adjacent to the alkene. The compound is prone to skeletal rearrangements such as the Wagner–Meerwein rearrangement. Acids typ ...
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Pinene Biosynthesis En
Pinene is a collection of unsaturated bicyclic monoterpenes. Two geometric isomers of pinene are found in nature, α-pinene and β-pinene. Both are chiral. As the name suggests, pinenes are found in pines. Specifically, pinene is the major component of the liquid extracts of conifers. Pinenes are also found in many non-coniferous plants such as camphorweed (''Heterotheca'') and big sagebrush (''Artemisia tridentata''). Isomers Biosynthesis α-Pinene and β-pinene are both produced from geranyl pyrophosphate, via cyclisation of linaloyl pyrophosphate followed by loss of a proton from the carbocation equivalent. Researchers at the Georgia Institute of Technology and the Joint BioEnergy Institute have been able to synthetically produce pinene with a bacterium. Plants Alpha-pinene is the most widely encountered terpenoid in nature and is highly repellent to insects. Alpha-pinene appears in conifers and numerous other plants. Pinene is a major component of the essential oil ...
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Linalool
Linalool () refers to two enantiomers of a naturally occurring terpene alcohol found in many flowers and spice plants. Linalool has multiple commercial applications, the majority of which are based on its pleasant scent (floral, with a touch of spiciness). A colorless oil, linalool is classified as an acyclic monoterpenoid. In plants, it is a metabolite, a volatile oil component, an antimicrobial agent, and an aroma compound. Linalool has uses in manufacturing of soaps, fragrances, food additives as flavors, household products, and insecticides. Esters of linalool are referred to as linalyl, e.g. linalyl pyrophosphate, an isomer of geranyl pyrophosphate. The word ''linalool'' is based on '' linaloe'' (a type of wood) and the suffix '. In food manufacturing, it may be called ''coriandrol''. Occurrence Both enantiomeric forms are found in nature: (''S'')-linalool is found, for example, as a major constituent of the essential oils of coriander (''Coriandrum sativum'' L.), cymbopo ...
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