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Polychlorinated Dibenzodioxins
Polychlorinated dibenzodioxins (PCDDs), or simply dioxins, are a group of long-lived polyhalogenated compound, polyhalogenated organic compounds that are primarily anthropogenic, and contribute toxic, Persistent organic pollutant, persistent organic pollution in the environment. They are commonly but inaccurately referred to as dioxins for simplicity, because every PCDD molecule contains a dibenzo-1,4-dioxin skeletal structure, with 1,4-Dioxin, 1,4-dioxin as the central Ring (chemistry), ring. Members of the PCDD family bioaccumulation, bioaccumulate in humans and wildlife because of their lipophilicity, lipophilic properties, and may cause developmental disturbances and cancer. Because dioxins can persist in the environment for more than 100 years, the majority of PCDD pollution today is not the result of recent emissions, but the cumulative result of synthetic processes undertaken since the beginning of the 20th century, including organochloride-related manufacturing, incinera ...
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PCDD General Structure
Polychlorinated dibenzodioxins (PCDDs), or simply dioxins, are a group of long-lived polyhalogenated organic compounds that are primarily anthropogenic, and contribute toxic, persistent organic pollution in the environment. They are commonly but inaccurately referred to as dioxins for simplicity, because every PCDD molecule contains a dibenzo-1,4-dioxin skeletal structure, with 1,4-dioxin as the central ring. Members of the PCDD family bioaccumulate in humans and wildlife because of their lipophilic properties, and may cause developmental disturbances and cancer. Because dioxins can persist in the environment for more than 100 years, the majority of PCDD pollution today is not the result of recent emissions, but the cumulative result of synthetic processes undertaken since the beginning of the 20th century, including organochloride-related manufacturing, incineration of chlorine-containing substances such as polyvinyl chloride (PVC), and chlorine bleaching of paper. Forest ...
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Missouri
Missouri is a U.S. state, state in the Midwestern United States, Midwestern region of the United States. Ranking List of U.S. states and territories by area, 21st in land area, it is bordered by eight states (tied for the most with Tennessee): Iowa to the north, Illinois, Kentucky and Tennessee to the east, Arkansas to the south and Oklahoma, Kansas and Nebraska to the west. In the south are the Ozarks, a forested highland, providing timber, minerals, and recreation. The Missouri River, after which the state is named, flows through the center into the Mississippi River, which makes up the eastern border. With more than six million residents, it is the List of U.S. states and territories by population, 19th-most populous state of the country. The largest urban areas are St. Louis, Kansas City, Missouri, Kansas City, Springfield, Missouri, Springfield and Columbia, Missouri, Columbia; the Capital city, capital is Jefferson City, Missouri, Jefferson City. Humans have inhabited w ...
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Times Beach
Times Beach is a ghost town in St. Louis County, Missouri, United States, southwest of St. Louis and east of Eureka. Once home to more than two thousand people, the town was completely evacuated early in 1983 due to TCDD—also known as dioxin—contamination. It was the largest civilian exposure to the compound in the history of the United States. In 1985, the State of Missouri officially disincorporated the city of Times Beach. The site of Times Beach now houses a state park commemorating U.S. Route 66—the famous highway that stretched from Chicago, Illinois, to Santa Monica, California, and passed by the community on its southern end—as well as the history of the Times Beach area. The park opened in 1999. In 2001, the EPA removed Times Beach from its Superfund list. History Times Beach was founded in 1925 on the flood plain of the Meramec River, southwest of the river, in a promotion by the now-defunct '' St. Louis Star-Times'' newspaper. A purchase of a 20 × 100  ...
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Vietnam War
The Vietnam War (also known by #Names, other names) was a conflict in Vietnam, Laos, and Cambodia from 1 November 1955 to the fall of Saigon on 30 April 1975. It was the second of the Indochina Wars and was officially fought between North Vietnam and South Vietnam. The north was supported by the Soviet Union, China, and other communist states, while the south was United States in the Vietnam War, supported by the United States and other anti-communism, anti-communist Free World Military Forces, allies. The war is widely considered to be a Cold War-era proxy war. It lasted almost 20 years, with direct U.S. involvement ending in 1973. The conflict also spilled over into neighboring states, exacerbating the Laotian Civil War and the Cambodian Civil War, which ended with all three countries becoming communist states by 1975. After the French 1954 Geneva Conference, military withdrawal from Indochina in 1954 – following their defeat in the First Indochina War – the Viet Minh to ...
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Malayan Emergency
The Malayan Emergency, also known as the Anti–British National Liberation War was a guerrilla war fought in British Malaya between communist pro-independence fighters of the Malayan National Liberation Army (MNLA) and the military forces of the British Empire and Commonwealth. The communists fought to win independence for Malaya from the British Empire and to establish a socialist economy, while the Commonwealth forces fought to combat communism and protect British economic and colonial interests.Siver, Christi L. "The other forgotten war: understanding atrocities during the Malayan Emergency." In APSA 2009 Toronto Meeting Paper. 2009., p.36 The conflict was called the "Anti–British National Liberation War" by the MNLA, but an "Emergency" by the British, as London-based insurers would not have paid out in instances of civil wars. On 17 June 1948, Britain declared a state of emergency in Malaya following attacks on plantations, which in turn were revenge attacks for the ...
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Agent Orange
Agent Orange is a chemical herbicide and defoliant, one of the "tactical use" Rainbow Herbicides. It was used by the U.S. military as part of its herbicidal warfare program, Operation Ranch Hand, during the Vietnam War from 1961 to 1971. It is a mixture of equal parts of two herbicides, 2,4,5-T and 2,4-D. In addition to its damaging environmental effects, traces of dioxin (mainly TCDD, the most toxic of its type) found in the mixture have caused major health problems for many individuals who were exposed, and their offspring. Agent Orange was produced in the United States from the late 1940s and was used in industrial agriculture and was also sprayed along railroads and power lines to control undergrowth in forests. During the Vietnam War, the U.S. military procured over 20 million gallons consisting of a fifty-fifty mixture of 2,4-D and dioxin-contaminated 2,4,5-T. Nine chemical companies produced it: Dow Chemical Company, Monsanto Company, Diamond Shamrock Corporation, ...
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2,3,7,8-Tetrachlorodibenzodioxin
2,3,7,8-Tetrachlorodibenzo-''p-''dioxin (TCDD) is a polychlorinated dibenzo''-p-''dioxin (sometimes shortened, though inaccurately, to simply 'dioxin')Tuomisto, Jouko (2019) Dioxins and dioxin-like compounds: toxicity in humans and animals, sources, and behaviour in the environment. WikiJournal of Medicine 6(1): 8 , https://doi.org/10.15347/wjm/2019.008 with the chemical formula CHClO. Pure TCDD is a colorless solid with no distinguishable odor at room temperature. It is usually formed as an unwanted product in burning processes of organic materials or as a side product in organic synthesis. TCDD is the most potent compound ( congener) of its series (polychlorinated dibenzodioxins, known as PCDDs or simply dioxins) and became known as a contaminant in Agent Orange, a herbicide used in the Vietnam War. TCDD was released into the environment in the Seveso disaster. It is a persistent organic pollutant. Mechanism of action TCDD and dioxin-like compounds act via a specific ...
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Leblanc Process
The Leblanc process (pronounced leh-blaank) was an early industrial process for making ''soda ash'' (sodium carbonate) used throughout the 19th century, named after its inventor, Nicolas Leblanc. It involved two stages: making sodium sulfate from sodium chloride, followed by reacting the sodium sulfate with coal and calcium carbonate to make sodium carbonate. The process gradually became obsolete after the development of the Solvay process. Background Soda ash (sodium carbonate) and potash (potassium carbonate), collectively termed ''alkali'', are vital chemicals in the glass, textile, soap, and paper industries. The traditional source of alkali in western Europe had been potash obtained from wood ashes. However, by the 13th century, deforestation had rendered this means of production uneconomical, and alkali had to be imported. Potash was imported from North America, Scandinavia, and Russia, where large forests still stood. Soda ash was imported from Spain and the Canary I ...
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Industrialization
Industrialisation ( alternatively spelled industrialization) is the period of social and economic change that transforms a human group from an agrarian society into an industrial society. This involves an extensive re-organisation of an economy for the purpose of manufacturing. Historically industrialization is associated with increase of polluting industries heavily dependent on fossil fuels. With the increasing focus on sustainable development and green industrial policy practices, industrialization increasingly includes technological leapfrogging, with direct investment in more advanced, cleaner technologies. The reorganization of the economy has many unintended consequences both economically and socially. As industrial workers' incomes rise, markets for consumer goods and services of all kinds tend to expand and provide a further stimulus to industrial investment and economic growth. Moreover, family structures tend to shift as extended families tend to no longer live ...
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Congener (chemistry)
In chemistry, congeners are chemical substances "related to each other by origin, structure, or function". Common origin and structure Any significant quantity of a polyhalogenated compound is by default a blend of multiple molecule types because each molecule forms independently, and chlorine and bromine do not strongly select which site(s) they bond to. *Polychlorinated biphenyls (PCBs) are a family of 209 congeners. * Polybrominated biphenyls and polychlorinated diphenyl ethers are also families of 209 congeners. Similarly polychlorinated dibenzodioxins, polychlorinated dibenzofurans, polychlorinated terphenyls, polychlorinated naphthalene, polychloro phenoxy phenol, and polybrominated diphenyl ethers (PBDEs) ( pentabromodiphenyl ether, octabromodiphenyl ether, decabromodiphenyl ether), etc. are also groups of congeners. Common origin *Congener (alcohol), substances other than alcohol (desirable or undesirable) also produced during fermentation. *Congeners of oleic acids ca ...
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