Nylon-6
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Nylon-6
Nylon 6 or polycaprolactam is a polymer, in particular semicrystalline polyamide. Unlike most other nylons, nylon 6 is not a condensation polymer, but instead is formed by ring-opening polymerization; this makes it a special case in the comparison between condensation and addition polymers. Its competition with nylon 6,6 and the example it set have also shaped the economics of the synthetic fibre industry. It is sold under numerous trade names including Perlon (Germany), Dederon (former East Germany), Nylatron, Capron, Ultramid, Akulon, Kapron (former Soviet Union and satellite states), Rugopa (Turkey) and Durethan. History Polycaprolactam was developed by Paul Schlack at IG Farben in late 1930s (first synthesized in 1938) to reproduce the properties of Nylon 66 without violating the patent on its production. (Around the same time, Kohei Hoshino at Toray also succeeded in synthesizing nylon 6.) It was marketed as Perlon, and industrial production with a capacity of 3,500 tons per ...
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Nylon
Nylon is a generic designation for a family of synthetic polymers composed of polyamides ( repeating units linked by amide links).The polyamides may be aliphatic or semi-aromatic. Nylon is a silk-like thermoplastic, generally made from petroleum, that can be melt-processed into fibers, films, or shapes. Nylon polymers can be mixed with a wide variety of additives to achieve many property variations. Nylon polymers have found significant commercial applications in fabric and fibers (apparel, flooring and rubber reinforcement), in shapes (molded parts for cars, electrical equipment, etc.), and in films (mostly for food packaging). History DuPont and the invention of nylon Researchers at DuPont began developing cellulose based fibers, culminating in the synthetic fiber rayon. DuPont's experience with rayon was an important precursor to its development and marketing of nylon. DuPont's invention of nylon spanned an eleven-year period, ranging from the initial research pr ...
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Nylon 6 And Nylon 6-6
Nylon is a generic designation for a family of synthetic polymers composed of polyamides ( repeating units linked by amide links).The polyamides may be aliphatic or semi-aromatic. Nylon is a silk-like thermoplastic, generally made from petroleum, that can be melt-processed into fibers, films, or shapes. Nylon polymers can be mixed with a wide variety of additives to achieve many property variations. Nylon polymers have found significant commercial applications in fabric and fibers (apparel, flooring and rubber reinforcement), in shapes (molded parts for cars, electrical equipment, etc.), and in films (mostly for food packaging). History DuPont and the invention of nylon Researchers at DuPont began developing cellulose based fibers, culminating in the synthetic fiber rayon. DuPont's experience with rayon was an important precursor to its development and marketing of nylon. DuPont's invention of nylon spanned an eleven-year period, ranging from the initial research progr ...
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Ring-opening Polymerization
In polymer chemistry, ring-opening polymerization (ROP) is a form of chain-growth polymerization, in which the terminus of a polymer chain attacks cyclic monomers to form a longer polymer (see figure). The reactive center can be radical, anionic or cationic. Some cyclic monomers such as norbornene or cyclooctadiene can be polymerized to high molecular weight polymers by using metal catalysts. ROP is a versatile method for the synthesis of biopolymers. Ring-opening of cyclic monomers is often driven by the relief of bond-angle strain. Thus, as is the case for other types of polymerization, the enthalpy change in ring-opening is negative. Monomers Cyclic monomers that are amenable to ROP include epoxides, cyclic trisiloxanes, some lactones, lactides, cyclic carbonates, and amino acid N-carboxyanhydrides. Many strained cycloalkenes, e.g norbornene, are suitable monomers via ring-opening metathesis polymerization. History Ring-opening polymerization has been used since the ...
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Hour
An hour (symbol: h; also abbreviated hr) is a unit of time conventionally reckoned as of a day and scientifically reckoned between 3,599 and 3,601 seconds, depending on the speed of Earth's rotation. There are 60 minutes in an hour, and 24 hours in a day. The hour was initially established in the ancient Near East as a variable measure of of the night or daytime. Such seasonal, temporal, or unequal hours varied by season and latitude. Equal or equinoctial hours were taken as of the day as measured from noon to noon; the minor seasonal variations of this unit were eventually smoothed by making it of the mean solar day. Since this unit was not constant due to long term variations in the Earth's rotation, the hour was finally separated from the Earth's rotation and defined in terms of the atomic or physical second. In the modern metric system, hours are an accepted unit of time defined as 3,600 atomic seconds. However, on rare occasions an hour may incorporate a positive ...
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White Rot
A wood-decay or xylophagous fungus is any species of fungus that digests moist wood, causing it to rot. Some species of wood-decay fungi attack dead wood, such as brown rot, and some, such as ''Armillaria'' (honey fungus), are parasitic and colonize living trees. Excessive moisture above the fibre saturation point in wood is required for fungal colonization and proliferation. In nature, this process causes the breakdown of complex molecules and leads to the return of nutrients to the soil. Wood-decay fungi consume wood in various ways; for example, some attack the carbohydrates in wood and some others decay lignin. The rate of decay of wooden materials in various climates can be estimated by empirical models.Viitanen, T. et al. (2010). Towards modelling of decay risk of wooden materials. European Journal of Wood and Wood Products 68:303-313. Wood-decay fungi can be classified according to the type of decay that they cause. The best-known types are brown rot, soft rot, and whit ...
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Oligomer
In chemistry and biochemistry, an oligomer () is a molecule that consists of a few repeating units which could be derived, actually or conceptually, from smaller molecules, monomers.Quote: ''Oligomer molecule: A molecule of intermediate relative molecular mass, the structure of which essentially comprises a small plurality of units derived, actually or conceptually, from molecules of lower relative molecular mass.'' The name is composed of Greek elements '' oligo-'', "a few" and '' -mer'', "parts". An adjective form is ''oligomeric''. The oligomer concept is contrasted to that of a polymer, which is usually understood to have a large number of units, possibly thousands or millions. However, there is no sharp distinction between these two concepts. One proposed criterion is whether the molecule's properties vary significantly with the removal of one or a few of the units. An oligomer with a specific number of units is referred to by the Greek prefix denoting that number, wi ...
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Units Of Textile Measurement
Textile fibers, threads, yarns and fabrics are measured in a multiplicity of units. * A fiber, a single filament of natural material, such as cotton, linen or wool, or artificial material such as nylon, polyester, metal or mineral fiber, or man-made cellulosic fibre like viscose, Modal, Lyocell or other rayon fiber is measured in terms of linear mass density, the weight of a given length of fiber. Various units are used to refer to the measurement of a fiber, such as: the denier and tex (linear mass density of fibers), super S (fineness of wool fiber), worsted count, woolen count, linen count (wet spun) (or Number English (Ne)), cotton count (or Number English (Ne)), Number metric (Nm) and yield (the reciprocal of denier and tex). * A yarn, a spun agglomeration of fibers used for knitting, weaving or sewing, is measured in terms of cotton count and yarn density. * Thread, usually consisting of multiple yarns plied together producing a long, thin strand used in sewing or weavi ...
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Gram-force
The kilogram-force (kgf or kgF), or kilopond (kp, from la, pondus, lit=weight), is a non-standard gravitational metric unit of force. It does not comply with the International System of Units (SI) and is deprecated for most uses. The kilogram-force is equal to the magnitude of the force exerted on one kilogram of mass in a gravitational field (standard gravity, a conventional value approximating the average magnitude of gravity on Earth). That is, it is the weight of a kilogram under standard gravity. Therefore, one kilogram-force is by definition equal to .NISTbr>''Guide for the Use of the International System of Units (SI)''Special Publication 811, (1995) page 51 Similarly, a gram-force is , and a milligram-force is . Kilogram-force is a non-standard unit and is classified in the International System of Units (SI) as a unit that is not accepted for use with SI. History The gram-force and kilogram-force were never well-defined units until the CGPM adopted a ''standard acceler ...
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Tenacity (textile Strength)
The specific strength is a material's (or muscle's) Strength of materials, strength (force per unit area at failure) divided by its density. It is also known as the strength-to-weight ratio or strength/weight ratio or strength-to-mass ratio. In fiber or textile applications, Tenacity (textile strength), tenacity is the usual measure of specific strength. The SI unit for specific strength is Pascal (unit), Pa⋅metre, m3/kilogram, kg, or Newton (unit), N⋅m/kg, which is Dimensional analysis, dimensionally equivalent to m2/s2, though the latter form is rarely used. Specific strength has the same units as specific energy, and is related to the maximum specific energy of rotation that an object can have without flying apart due to centrifugal force. Another way to describe specific strength is breaking length, also known as self support length: the maximum length of a vertical column of the material (assuming a fixed cross-section) that could suspend its own weight when supported onl ...
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Amide
In organic chemistry, an amide, also known as an organic amide or a carboxamide, is a compound with the general formula , where R, R', and R″ represent organic groups or hydrogen atoms. The amide group is called a peptide bond when it is part of the main chain of a protein, and an isopeptide bond when it occurs in a side chain, such as in the amino acids asparagine and glutamine. It can be viewed as a derivative of a carboxylic acid () with the hydroxyl group () replaced by an amine group (); or, equivalently, an acyl (alkanoyl) group () joined to an amine group. Common examples of amides are acetamide (), benzamide (), and dimethylformamide (). Amides are qualified as primary, secondary, and tertiary according to whether the amine subgroup has the form , , or , where R and R' are groups other than hydrogen. The core of amides is called the amide group (specifically, carboxamide group). Amides are pervasive in nature and technology. Proteins and important plastics l ...
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Monomer
In chemistry, a monomer ( ; ''mono-'', "one" + '' -mer'', "part") is a molecule that can react together with other monomer molecules to form a larger polymer chain or three-dimensional network in a process called polymerization. Classification Monomers can be classified in many ways. They can be subdivided into two broad classes, depending on the kind of the polymer that they form. Monomers that participate in condensation polymerization have a different stoichiometry than monomers that participate in addition polymerization: : Other classifications include: *natural vs synthetic monomers, e.g. glycine vs caprolactam, respectively *polar vs nonpolar monomers, e.g. vinyl acetate vs ethylene, respectively *cyclic vs linear, e.g. ethylene oxide vs ethylene glycol, respectively The polymerization of one kind of monomer gives a homopolymer. Many polymers are copolymers, meaning that they are derived from two different monomers. In the case of condensation polymerizations, the r ...
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