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Metatorbernite
Metatorbernite (or meta-torbernite) is a radioactive phosphate mineral, and is a dehydration pseudomorph of torbernite. Chemically, it is a copper uranyl phosphate and usually occurs in the form of green platy deposits. It can form by direct deposition from a supersaturated solution, which produces true crystalline metatorbernite, with a dark green colour, translucent diaphaneity, and vitreous lustre. However, more commonly, it is formed by the dehydration of torbernite, which causes internal stress and breakage within the crystal lattice, resulting in crystals composed of microscopic powder held together using electrostatic force, and having a lighter green colour, opaque diaphaneity, and a relatively dull lustre. As with torbernite, it is named after the Swedish chemist Torbern Bergman. It is especially closely associated with torbernite, but is also found amongside autunite, meta-autunite and uraninite Uraninite, formerly pitchblende, is a radioactive, uranium-rich mineral ...
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Metatorbernite Sapin
Metatorbernite (or meta-torbernite) is a radioactive phosphate mineral, and is a dehydration pseudomorph of torbernite. Chemically, it is a copper uranyl phosphate and usually occurs in the form of green platy deposits. It can form by direct deposition from a supersaturated solution, which produces true crystalline metatorbernite, with a dark green colour, translucent diaphaneity, and vitreous lustre. However, more commonly, it is formed by the dehydration of torbernite, which causes internal stress and breakage within the crystal lattice, resulting in crystals composed of microscopic powder held together using electrostatic force, and having a lighter green colour, opaque diaphaneity, and a relatively dull lustre. As with torbernite, it is named after the Swedish chemist Torbern Bergman. It is especially closely associated with torbernite, but is also found amongside autunite, meta-autunite and uraninite Uraninite, formerly pitchblende, is a radioactive, uranium-rich mineral ...
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Torbernite
Torbernite is a radioactive, hydrated green copper uranyl phosphate mineral, found in granites and other uranium-bearing deposits as a secondary mineral. Its name derives from the Swedish chemist Torbern Bergman (1735–1784), It is also known as chalcolite. Torbernite is isostructural with the related uranium mineral, autunite. The chemical formula of torbernite is similar to that of autunite in which a Cu2+ cation replaces a Ca2+. The number of water hydration molecules can vary between 12 and 8, giving rise to the variety of metatorbernite when torbernite spontaneously dehydrates. Their respective chemical compositions are the following: ;''Torbernite'' :Cu(UO2)2(PO4)2 ;''Metatorbernite'' :Cu(UO2)2(PO4)2 Torbernite's most common alternative names are copper uranite and cupro-uranite. Uses As a radioactive mineral, torbernite has some limited significance as a uranium ore. Its vibrant green color and well-developed distinctive crystals (size: mm to a few cm) make it a sou ...
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Phosphate Minerals
Phosphate minerals contain the tetrahedrally coordinated phosphate (PO43−) anion along sometimes with arsenate (AsO43−) and vanadate (VO43−) substitutions, and chloride (Cl−), fluoride (F−), and hydroxide (OH−) anions that also fit into the crystal structure. The phosphate class of minerals is a large and diverse group, however, only a few species are relatively common. Applications Phosphate rock has high concentration of phosphate minerals, most commonly of the apatite group. It is the major resource mined to produce phosphate fertilizers for the agriculture sector. Phosphate is also used in animal feed supplements, food preservatives, anti-corrosion agents, cosmetics, fungicides, ceramics, water treatment and metallurgy. The largest use of minerals mined for their phosphate content is the production of fertilizer. Phosphate minerals are often used for control of rust and prevention of corrosion on ferrous materials applied with electrochemical conversion co ...
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Phosphate Minerals
Phosphate minerals contain the tetrahedrally coordinated phosphate (PO43−) anion along sometimes with arsenate (AsO43−) and vanadate (VO43−) substitutions, and chloride (Cl−), fluoride (F−), and hydroxide (OH−) anions that also fit into the crystal structure. The phosphate class of minerals is a large and diverse group, however, only a few species are relatively common. Applications Phosphate rock has high concentration of phosphate minerals, most commonly of the apatite group. It is the major resource mined to produce phosphate fertilizers for the agriculture sector. Phosphate is also used in animal feed supplements, food preservatives, anti-corrosion agents, cosmetics, fungicides, ceramics, water treatment and metallurgy. The largest use of minerals mined for their phosphate content is the production of fertilizer. Phosphate minerals are often used for control of rust and prevention of corrosion on ferrous materials applied with electrochemical conversion co ...
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Diaphaneity
In the field of optics, transparency (also called pellucidity or diaphaneity) is the physical property of allowing light to pass through the material without appreciable scattering of light. On a macroscopic scale (one in which the dimensions are much larger than the wavelengths of the photons in question), the photons can be said to follow Snell's law. Translucency (also called translucence or translucidity) allows light to pass through, but does not necessarily (again, on the macroscopic scale) follow Snell's law; the photons can be scattered at either of the two interfaces, or internally, where there is a change in index of refraction. In other words, a translucent material is made up of components with different indices of refraction. A transparent material is made up of components with a uniform index of refraction. Transparent materials appear clear, with the overall appearance of one color, or any combination leading up to a brilliant spectrum of every color. The opposite ...
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Radioactive Minerals
Radioactive decay (also known as nuclear decay, radioactivity, radioactive disintegration, or nuclear disintegration) is the process by which an unstable atomic nucleus loses energy by radiation. A material containing unstable nuclei is considered radioactive. Three of the most common types of decay are alpha decay ( ), beta decay ( ), and gamma decay ( ), all of which involve emitting one or more particles. The weak force is the mechanism that is responsible for beta decay, while the other two are governed by the electromagnetism and nuclear force. A fourth type of common decay is electron capture, in which an unstable nucleus captures an inner electron from one of the electron shells. The loss of that electron from the shell results in a cascade of electrons dropping down to that lower shell resulting in emission of discrete X-rays from the transitions. A common example is iodine-125 commonly used in medical settings. Radioactive decay is a stochastic (i.e. random) proc ...
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Copper(II) Minerals
Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish-orange color. Copper is used as a conductor of heat and electricity, as a building material, and as a constituent of various metal alloys, such as sterling silver used in jewelry, cupronickel used to make marine hardware and coins, and constantan used in strain gauges and thermocouples for temperature measurement. Copper is one of the few metals that can occur in nature in a directly usable metallic form (native metals). This led to very early human use in several regions, from circa 8000 BC. Thousands of years later, it was the first metal to be smelted from sulfide ores, circa 5000 BC; the first metal to be cast into a shape in a mold, c. 4000 BC; and the first metal to be purposely alloyed with another metal, tin, to create bronze, c. 350 ...
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Uranyl Compounds
The uranyl ion is an oxycation In chemistry, an oxycation is a polyatomic ion with a positive charge that contains oxygen. Examples * Dioxygenyl ion, * Nitrosonium ion, * Nitronium ion, * Vanadyl ion, VO2+, a very stable oxycation * Uranyl ion, , all natural U6+ occurs in t ... of uranium in the oxidation state +6, with the chemical formula . It has a linear structure with short U–O bonds, indicative of the presence of multiple bonds between uranium and oxygen. Four or more ligands may be bound to the uranyl ion in an equatorial plane around the uranium atom. The uranyl ion forms many complex (chemistry), complexes, particularly with ligands that have oxygen donor atoms. Complexes of the uranyl ion are important in the extraction of uranium from its ores and in nuclear fuel reprocessing. Structure and bonding The uranyl ion is linear and symmetrical, with both U–O bond lengths of about 180 pm. The bond lengths are indicative of the presence of multiple bonding between ...
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Uraninite
Uraninite, formerly pitchblende, is a radioactive, uranium-rich mineral and ore with a chemical composition that is largely UO2 but because of oxidation typically contains variable proportions of U3O8. Radioactive decay of the uranium causes the mineral to contain oxides of lead and trace amounts of helium. It may also contain thorium and rare-earth elements. Overview Uraninite used to be known as pitchblende (from '' pitch'', because of its black color, and ''blende'', from ''blenden'' meaning "to deceive", a term used by German miners to denote minerals whose density suggested metal content, but whose exploitation, at the time they were named, was either unknown or not economically feasible). The mineral has been known at least since the 15th century from silver mines in the Ore Mountains, on the German/Czech border. The type locality is the historic mining and spa town known as Joachimsthal, the modern day Jáchymov, on the Czech side of the mountains, where F. E. Brückma ...
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Autunite
Autunite (hydrated calcium uranyl phosphate), with formula Ca(UO2)2(PO4)2·10–12H2O, is a yellow-greenish fluorescent phosphate mineral with a hardness of 2–. Autunite crystallizes in the orthorhombic system and often occurs as tabular square crystals, commonly in small crusts or in fan-like masses. Due to the moderate uranium content of 48.27% it is radioactive and also used as uranium ore. Autunite fluoresces bright green to lime green under UV light. The mineral is also called calco-uranite, but this name is rarely used and effectively outdated. Autunite was discovered in 1852 near Autun, France, which is also autunite's namesake. It occurs as an oxidation product of uranium minerals in granite pegmatites and hydrothermal deposits. Associate minerals include metaautunite, torbernite, phosphuranylite, saleeite, uranophane and sabugalite. Etymology Autunite was named after the town of Autun, France, where the mineral was initially found. The mineral was named by Henry J. ...
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Torbern Bergman
Torbern Olaf (Olof) Bergman (''KVO'') (20 March 17358 July 1784) was a Swedish chemist and mineralogist noted for his 1775 ''Dissertation on Elective Attractions'', containing the largest chemical affinity tables ever published. Bergman was the first chemist to use the A, B, C, etc., system of notation for chemical species. Early life and education Torbern was born on 20 March 1735, the son of Barthold Bergman and Sara Hägg. He enrolled at the University of Uppsala at age 17. His father wished him to read either law or divinity, while he himself was anxious to study mathematics and natural science; in the effort to please both himself and his father, he overworked himself and harmed his health. During a period of enforced abstinence from study, he amused himself with field botany and entomology. He was able to send Linnaeus specimens of several new kinds of insects, and in 1756 he succeeded in proving that, contrary to the opinion of that naturalist, the so-called ''Coccus aqua ...
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